METHOD FOR CLEANING THE EXHAUST AIR OF A GRANULATING SYSTEM FOR PRODUCING A UREA-CONTAINING GRANULATE

Abstract

A process for purifying exhaust air from a granulation plant for producing a urea-containing granulate may involve causing a gas stream containing a urea-containing dust and ammonia to contact a sulfuric acid solution or a nitric acid solution in a scrubbing process. The scrubbing process may comprise scrubbing the gas stream with a first weakly acidic scrubbing solution in a first scrubbing stage and then scrubbing the gas stream exiting the first scrubbing stage with a second scrubbing solution having a lower pH than the first weakly acidic scrubbing solution in a second scrubbing stage. The acidic scrubbing solution generated in the second scrubbing stage may be recycled into the first scrubbing stage via a conduit and used therein as the first weakly acidic scrubbing solution. A pre-scrubbing stage where dust is scrubbed out of the gas stream may additionally be arranged upstream of the first scrubbing stage.

Claims

1.-15. (canceled)

16. A process for purifying exhaust air from a granulation plant for producing a urea-containing granulate, the process comprising: causing a gas stream containing a urea-containing dust and ammonia to contact a sulfuric acid solution or a nitric acid solution in a scrubbing process, wherein the scrubbing process comprises at least two separate sequential scrubbing stages including: pre-scrubbing dust out of the gas stream in a pre-scrubbing stage, scrubbing the gas stream with a first weakly acidic scrubbing solution in a first scrubbing stage downstream of the pre-scrubbing stage, and scrubbing the gas stream exiting the first scrubbing stage with a second scrubbing solution having a lower pH than the first weakly acidic scrubbing solution in a second scrubbing stage.

17. The process of claim 16 comprising recycling an acidic scrubbing solution generated in the second scrubbing stage into the first scrubbing stage as the first weakly acidic scrubbing solution.

18. The process of claim 16 wherein the first weakly acidic scrubbing solution is a urea- and ammonium sulfate-containing solution or an ammonium nitrate-containing solution having a pH in a range from 3.5 to 6.1.

19. The process of claim 16 wherein the second scrubbing solution has a pH of less than 2.

20. The process of claim 16 wherein the first scrubbing solution in the first scrubbing stage is run in crosscurrent with the gas stream to be scrubbed.

21. The process of claim 16 comprising discharging an ammonium sulfate-containing solution or an ammonium nitrate-containing solution having a pH of more than 7 from the first scrubbing stage.

22. The process of claim 16 comprising scrubbing the gas stream with a dilute urea solution in the pre-scrubbing stage.

23. The process of claim 16 comprising passing a neutralized ammonium sulfate solution or a neutralized ammonium nitrate solution from the first scrubbing stage into the pre-scrubbing stage.

24. The process of claim 16 comprising discharging a neutralized ammonium sulfate solution or a neutralized ammonium nitrate solution from the first scrubbing stage.

25. The process of claim 16 comprising supplying the second scrubbing stage with a condensate from a concentration apparatus for the urea-containing and ammonium sulfate-containing or ammonium nitrate-containing solutions.

26. The process of claim 16 comprising supplying the pre-scrubbing stage with a condensate from a concentration apparatus for the urea-containing and ammonium sulfate-containing solutions.

27. An installation for purifying exhaust air from a granulation plant for producing a urea-containing granulate, the installation comprising: a first scrubbing apparatus in which a gas stream containing a urea-containing dust and ammonia from the granulation plant is scrubbed using a first acidic scrubbing solution; a second scrubbing apparatus in operative connection with the first scrubbing apparatus in which a gas stream exiting the first scrubbing apparatus is scrubbed with a second acidic scrubbing solution having a lower pH than the first acidic scrubbing solution; and a third scrubbing apparatus disposed upstream of the first scrubbing apparatus in a flow path, wherein pre-scrubbing occurs in the third scrubbing apparatus for scrubbing out dust from the gas stream.

28. The installation of claim 27 comprising a recycling conduit by way of which a weakly acidic solution generated in the second scrubbing apparatus is configured to be recycled into the first scrubbing apparatus as the first acidic scrubbing solution.

29. The installation of claim 27 comprising: an exhaust air conduit that extends from the granulation plant into the third scrubbing apparatus; a first outlet-side gas conduit exiting the third scrubbing apparatus for exhaust air purified in the third scrubbing apparatus that leads from the third scrubbing apparatus to the first scrubbing apparatus; and a second outlet-side gas conduit exiting the first scrubbing apparatus for exhaust air purified in the first scrubbing apparatus that leads from the first scrubbing apparatus to the second scrubbing apparatus.

30. The installation of claim 27 comprising: a recycling conduit for a urea-containing solution that extends from the third scrubbing apparatus to a concentration apparatus in which the urea-containing solution is concentrated; and means for recycling recovered concentrated urea-containing solution into the granulation plant.

Description

[0027] The present invention is more particularly elucidated hereinbelow by means of an exemplary embodiment and with reference to the accompanying FIGURE.

[0028] FIG. 1 shows a simplified schematic diagram of an exemplary installation according to the invention for purifying the exhaust air of a granulation plant for producing a urea-containing granulate.

[0029] An exemplary embodiment of the present invention is more particularly elucidated hereinbelow with reference to FIG. 1. The diagram shows a simplified process scheme and only the plant parts relevant in the context of the present invention are shown. Via an inlet conduit 10 the to-be-purified exhaust air from a granulation plant for producing a urea-containing granulate arrives in a scrubbing apparatus 11 which serves as a pre-scrubbing to scrub out the predominant proportion of the urea-containing dust from the exhaust air stream. In the present application this pre-scrubbing is also referred to as third scrubbing apparatus 11. A condensate from the concentration apparatus for the generated urea-containing and ammonium sulfate-containing solutions may be supplied to the scrubbing apparatus 11 via a conduit 12. Employed as the scrubbing medium in this scrubbing apparatus 11 is a urea-containing solution supplied to the scrubbing apparatus via the inlet conduit 13. The scrubbing procedure generates a urea-enriched solution which may contain urea in a concentration of 45% for example and which is discharged from the scrubbing apparatus 11 via the outlet conduit 14 and supplied to a concentration apparatus in which the water present in the solution is largely evaporated in order that the highly concentrated urea-containing solution may subsequently be recycled into the granulation plant for producing a urea-containing granulate.

[0030] After the scrubbing procedure in the prescrubber 11 the gas stream largely freed of dust exits the scrubbing apparatus 11 via the gas conduit 15 and is then supplied to a scrubbing apparatus 16 in which the gas stream is scrubbed with a weakly acidic solution, wherein in the present application this scrubbing apparatus 16 is described as the first scrubbing apparatus. The weakly acidic scrubbing solution used in this first scrubbing apparatus which has a pH of 4.8 for example and which is essentially a weakly acidic aqueous solution of urea and ammonium sulfate or ammonium nitrate is supplied to the scrubbing apparatus 16 via the inlet conduit 17. In the scrubbing apparatus 16 the weakly acidic scrubbing solution is run in crosscurrent with the gas stream introduced via the conduit 15. As is apparent from FIG. 1 this inlet conduit 17 for supplying the scrubbing solution into the first scrubbing apparatus 16 is an outlet conduit from a second scrubbing apparatus 19 as elucidated hereinbelow.

[0031] The gas stream that has been scrubbed in the first scrubbing apparatus 16 exits this first scrubbing apparatus via the gas conduit 18 and is then introduced into the second scrubbing apparatus 19 in which the gas stream is scrubbed again, namely with an acidic scrubbing solution which is more strongly acidic than the weakly acidic scrubbing solution used in the first scrubbing apparatus 16. For this scrubbing operation in the second scrubbing apparatus 19 concentrated sulfuric acid or nitric acid is introduced into the second scrubbing apparatus 19 via an input conduit 20. A condensate from the process may also be supplied to the second scrubbing apparatus 19 via the input conduit 21. In the second scrubbing apparatus 19 the acidic scrubbing operation is carried out for example with a scrubbing solution having a pH in the range of about 1.5. After this rescrubbing in the second scrubbing apparatus 19 the purified exhaust air stream is discharged via the outlet conduit 22 and may in principle be released to the atmosphere since it is virtually dust free and virtually no longer contains any ammonia.

[0032] Since the gas stream introduced into this second scrubbing apparatus still contains ammonia this scrubbing operation of the gas stream in the second scrubbing apparatus 19 forms ammonium sulfate or ammonium nitrate by reaction with the sulfuric acid or nitric acid introduced via the conduit 20. Since a partial neutralization with the ammonia from the gas stream takes place in the second scrubbing apparatus the scrubbing operation produces a solution which contains ammonium sulfate or ammonium nitrate and residual urea and has a weakly acidic pH of for example 4.8. This weakly acidic urea/ammonium sulfate or urea/ammonium nitrate solution is then recycled via the outlet conduit 17 of the second scrubbing apparatus 19 into the first scrubbing apparatus 16 and used therein as a scrubbing solution which is run in crosscurrent with the gas stream introduced via the conduit 15 and effects gas scrubbing in the first scrubbing apparatus 16. The conduit 17 is thus simultaneously the inlet conduit for scrubbing solution in the first scrubbing apparatus 16 through which the gas stream flows first. A first gas scrubbing with a first weakly acidic solutions thus takes place in the first scrubbing apparatus 16 and subsequently a second gas scrubbing with a more strongly acidic scrubbing solution takes place in the second scrubbing apparatus 19.

[0033] Since a further neutralization process takes place therein through reaction of the weakly acidic scrubbing solution with ammonia present in the gas stream it is possible to discharge, from the first scrubbing apparatus 16 via the outlet conduit 23, a substantially neutralized aqueous solution which contains a proportion of dissolved ammonium sulfate or ammonium nitrate, contains residual urea and has a pH of greater than 7.

[0034] In a variant shown in the exemplary embodiment according to FIG. 1 of the invention the neutralized ammonium sulfate solution or ammonium nitrate solution may also for example be passed from the first scrubbing stage 16 into a third scrubbing stage (pre-scrubbing 11) via the conduit 24.

[0035] The setup according to the invention thus comprises three scrubbing stages for purifying the exhaust air released from the granulator of dust (pre-scrubbing stage) and two subsequent stages for removing ammonia and simultaneously raising the pH into a range less corrosive for the conduits in the first and second scrubbing stage.

LIST OF REFERENCE NUMERALS

[0036] 10 Inlet conduit [0037] 11 Pre-scrubbing (third scrubbing apparatus) [0038] 12 Conduit for condensate [0039] 13 Inlet conduit for urea-containing scrubbing solution [0040] 14 Outlet conduit for urea-containing solution [0041] 15 Gas conduit [0042] 16 First scrubbing apparatus [0043] 17 Inlet conduit for scrubbing solution [0044] 18 Gas conduit [0045] 19 Second scrubbing apparatus [0046] 20 Inlet conduit for sulfuric acid or nitric acid [0047] 21 Inlet conduit for condensate [0048] 22 Outlet conduit for purified exhaust gas stream [0049] 23 Outlet conduit for neutralized ammonium sulfate solution or neutralized ammonium nitrate solution [0050] 24 Outlet conduit for neutralized ammonium sulfate solution or neutralized ammonium nitrate solution