MULTICOLOUR CERMET AND/OR CERAMIC ARTICLE AND MANUFACTURING METHOD THEREOF

Abstract

Provided is a multicolour cermet and/or ceramic article, and in particular a bezel of a timepiece, made by a method for injecting at least two materials of distinct colours, said article comprising a relief decoration of a colour different from the rest of the article, said decoration being made by laser ablation after injection of the two materials.

Claims

1. A method for manufacturing by injection a multicolour cermet and/or ceramic article with a relief decoration (11), said method comprising the following steps: providing at least one first material (2) and one second material (3), said first material (2) being distinguished from the second material (3) by its colour, said first (2) and second (3) materials being either a ceramic or a cermet, providing a mould (5) with a pattern cavity (6) comprising a portion (7) including a relief or hollow structure intended to form a hooking surface on the first material (2) after injection, injecting said first material (2) into the pattern cavity (6) provided with the portion (7) so as to print the structure on a portion of the first material (2) and thus form the hooking surface on said portion, injecting the second material (3) onto the first material (2) at least at the hooking surface to form a green body (8), sintering the green body (8) to form a movement-blank, machining, by laser ablation, the second material (3) on the green body (8) or on the movement-blank to make the relief decoration (11), said second material (3) being hollowed out by laser ablation at least to the first material (2) to reveal said first material (2) and obtain the relief decoration (11) in said second material (3) standing on the first material (2), finishing the movement-blank to obtain the article.

2. The manufacturing method according to claim 1, wherein the structure of the portion (7) is discontinuous.

3. The manufacturing method according to claim 1, wherein the structure of the portion (7) is in relief.

4. The manufacturing method according to the preceding claim, wherein the structure of the portion (7) is formed of a multitude of studs (7a).

5. The manufacturing method according to claim 1, wherein the structure of the portion (7) is hollow and formed of a multitude of recesses.

6. The manufacturing method according to claim 1, wherein the second material (3) is injected onto the first material (2) to form the green body (8) comprising two superimposed layers with a layer of the first material (2) and a layer of the second material (3), said layers being interlocked with each other at the hooking surface.

7. The manufacturing method according to claim 1, wherein the first material (2) is partially hollowed out to remove the hooking surface.

8. A multicolour ceramic and/or cermet article with a relief decoration (11) of a colour distinct from the rest of the article, said article being obtained with the manufacturing method according to claim 1, wherein the relief decoration (11) is formed in one piece with the rest of the article, said decoration (11) as well as the rest of the article being tinted in the mass with a uniform colour for each colour.

9. The article according to the preceding claim, wherein the article is a horological external or movement component.

10. The article according to claim 8, wherein the horological external or movement component is selected from the list comprising a middle, a bottom, a bezel, a bezel insert, a push-piece, a crown, a bracelet link, a buckle, a dial, a hand, a dial index, an oscillating weight and a plate.

11. The article according to the preceding claim, wherein the article is the bezel (1) with the relief decoration (11) formed at least by indexes and numerals.

12. The article according to claim 10, wherein the article is the crown with the relief decoration (11) formed by an acronym.

13. The article according to claim 8, wherein the decoration (11) is made of a white zirconia and the rest of the article of a black zirconia.

Description

BRIEF DESCRIPTION OF THE FIGURES

[0019] FIG. 1 represents a three-dimensional view of the double pattern cavity of the fixed portion of the mould with one of the two pattern cavities comprising an insert with a relief structure according to the invention.

[0020] FIG. 2 represents a three-dimensional view of the insert with the relief structure.

[0021] FIG. 3 represents a sectional view of the mould during respectively the injection of the first material on the right and the second material on the left.

[0022] FIG. 4 represents a three-dimensional view of the green body resulting from the bi-injection of materials.

[0023] FIG. 5 represents a partial view of the green body of FIG. 4.

[0024] FIG. 6 represents a three-dimensional view of a decorated bezel resulting from the manufacturing method according to the invention.

[0025] FIG. 7 represents a plan view of a decorated bezel resulting from the manufacturing method according to the invention.

DETAILED DESCRIPTION

[0026] The present invention relates to a manufacturing method by injection of an article made with at least two distinct materials which are either a cermet or a ceramic. The term “distinct materials” means materials being differentiated by their aesthetic appearance, and in particular their colour. This results in differences in chemical compositions. It can be the same base material with different pigments to change the colour or different base materials. By way of example, it may be the same zirconium oxide base material with, on the one hand, a black pigment to obtain a black material and, on the other hand, alumina to obtain the white colour. More generally, the ceramics can be nitrides, carbides and/or oxides. Similarly, cermets may include a ceramic phase including carbides, nitrides and/or oxides and a phase of a metal binder selected, for example, from precious elements such as ruthenium, rhodium, palladium, osmium, iridium, platinum, gold and silver.

[0027] The article according to the invention can be a decorative article such as a constituent element of watches, jewelry, bracelets, etc. In the watchmaking field, this article can be an external component such as a middle, a bottom, a bezel, a bezel insert, a push-piece, a crown, a bracelet link, a buckle, a dial, a hand, a dial index, etc. It can also be a movement component such as an oscillating weight, a plate, etc. By way of illustration, the article is a bezel 1 made with two ceramics of different colours, for example black and white, with one colour which forms the bottom and another colour which forms the decoration 11 as represented in FIGS. 6 and 7. Still by way of example, it could be an acronym on a watch crown.

[0028] The article is made by injecting different materials to form a green body and by sintering said green body. The manufacturing method is illustrated below for an article comprising two distinct materials, but it could be an article comprising 3,4, etc. different materials with creation of a hooking surface for each of the successive injected materials. Similarly, it is illustrated for an article with a decoration of the same colour while there might be decorations of different colours.

[0029] The manufacturing method includes the following steps with reference to FIGS. 1 to 7: [0030] Providing at least one first material 2 and one second material 3, said first material being distinguished from the second material by its colour and therefore by its chemical composition, said first and second materials being either a ceramic or a cermet. Thus, the first and second materials can both be a ceramic or both a cermet or else one material can be a ceramic and the other a cermet, [0031] Providing a mould 5 with a pattern cavity 6 comprising a portion 7, also called insert, including a relief or hollow structure intended to form a hooking surface on the first injected material (FIG. 1). Preferably, said structure is in relief. This structure is preferentially discontinuous. It can thus be formed of a multitude of studs 7a (FIG. 2) or recesses. This discontinuous structure is preferred relative to a continuous structure such as a groove or a tab for better material retention. Preferably, the recesses or studs respectively have a depth or a height of at least 0.2 mm. Preferably, the studs or recesses are 1 to 10 in number, more preferably 1 to 3 per 10 mm.sup.2 of surface. [0032] Injecting said first material 2 into the pattern cavity 6 provided with the insert 7 so as to print the structure on a portion of the first material 2 and thus form the hooking structure for the second material 3, [0033] Injecting the second material 3 onto the first material 2 at least at the hooking surface to form a green body 8 (FIG. 3 and FIG. 4), [0034] Sintering the green body 8 to form a movement-blank, [0035] Machining, by laser ablation, at least the second material 3 of the green body 8 or of the movement-blank to make a decoration 11 standing on the first material 2 of the movement-blank, the second material 3 being hollowed out to the first material 2 to reveal the latter and leaving only a decoration 11 in said second material 3, [0036] Finishing the movement-blank to obtain the article.

[0037] During the machining step, the first material can also be slightly hollowed out to remove the material at the hooking zone which would have remained visible next to the decoration. In other words, it concerns removing the structure printed on a portion of the first material which would be visible next to the decoration. In the presence of more than two materials of different colours, the different materials can be hollowed out to draw decorations of different colours. Thus, in the presence of a third material injected onto the second material, the third material can be hollowed out to the second material or even to the first material to form a decoration standing on the second material or on the first material or partially on the second material and on the first material.

[0038] The laser ablation machining step can be carried out before sintering, i.e. on the green body, or after sintering, i.e. on the movement-blank.

[0039] The laser ablation is preferably carried out with a pulsed laser such as a picosecond, nanosecond or femtosecond laser.

[0040] The method may further include another machining step, also called second machining step, intended to size the green body and/or the movement-blank. Preferably, it is operated on the green body before sintering so that the material is not too hard. The present invention does not exclude this machining step being carried out partly before sintering and partly after sintering.

[0041] The method can optionally include a debinding step before the sintering step if the materials have been injected with a system of organic binders (paraffin, polyethylene, etc.).

[0042] After machining by laser ablation, the manufacturing method includes a finishing step such as polishing, satin finishing, mattifying, etc.

[0043] In the illustrated example, the injection device includes a mould 5 with a fixed portion 5a formed by two pattern cavities 6 with a first pattern cavity 6a intended for the injection of the first material 2 and a second pattern cavity 6b intended for the injection of the second material 3 (FIG. 1). The first pattern cavity 6a includes the insert 7 with the relief structure. In the example, the insert is directly mounted to the pattern cavity, but it could also be in one-piece with the rest of the pattern cavity. During injection, the first material 2 is injected into the mould 5 formed of the fixed portion 5a and the movable portion 5b as shown in FIG. 3 on the right. Then, the movable portion 5a with the first injected material 2 is displaced above the fixed portion 5b of the other pattern cavity 6b to carry out the injection of the second material 3 (FIG. 3 on the left). The insert 7 with a structure in relief is intended to print recesses 2a in the first material 2 which will be used as a hook during the injection of the second material 3. FIG. 4 represents the green body 8 resulting from the bi-injection with the second material 3 which is superimposed on the first material 2. The green body as well as the movement-blank at the end of the sintering includes a portion 4 where the two materials 2 and 3 are superimposed and more specifically interlocked (FIG. 5). The term “interlocking” means that one of the two materials has, on the surface thereof, a structure filled by the other material. In FIG. 5, there is shown the two materials 2 and 3 which are superimposed with the interlocking of one in the recesses 2a formed on the surface of the other.

[0044] In order to form a bezel, the sprue 10 is cut and the inner diameter of the bezel is hollowed out during the second machining step. Before or after, the second material is hollowed out by laser ablation to the at least the first material to form the decoration 11 in a colour distinct from the substrate formed by the bezel.

[0045] Typically, a bezel 1 according to FIGS. 6 and 7 is obtained by injection of a white zirconia and a black zirconia and by sintering at a temperature of 1400° C. for a time of 48 hours in an oxidizing atmosphere.

LEGEND

[0046] (1) Article, horological component or bezel [0047] (2) First material, also called ceramic [0048] a. Recess [0049] (3) Second material, also called ceramic [0050] (4) Portion of the article [0051] (5) Mould [0052] a. Fixed portion [0053] b. Movable portion [0054] (6) Pattern cavity [0055] a. First pattern cavity [0056] b. Second pattern cavity [0057] (7) Insert, also called portion of the pattern cavity [0058] a. Stud [0059] (8) Green body [0060] (9) Sprue of the green Body [0061] (10) Decoration