Deodorant composition comprising a mixture of alpha, beta, and gamma cyclodextrin

Abstract

This invention relates to an odour-absorbing composition comprising a mixture of -, -, and -cyclodextrins, wherein the amount of one of said -, -, and -cyclodextrins is equal to or higher than the total amount of the other two cyclodextrins.

Claims

1. An odor-absorbing composition comprising a mixture of -, -, and -cyclodextrins, wherein the amount of one of said -, -, and -cyclodextrins is equal to or higher than the total amount of the other two cyclodextrins, wherein the weight ratio of the amount of said -cyclodextrins to the amount of said -, and -cyclodextrins ranges from 4:1 to 1:1.

2. The odor-absorbing composition according to claim 1, wherein said composition comprises an amount of said -, -, and -cyclodextrins in a weight ratio of about 1:2:1.

3. The odor-absorbing composition according to claim 1, wherein the amount of said -cyclodextrins is higher than the amount of said -cyclodextrins.

4. The odor-absorbing composition according to claim 3, wherein the the weight ratio of the amount of said -cyclodextrins to said -cyclodextrins ranges from 4:1 to 1.5:1.

5. The odor-absorbing composition according to claim 4, wherein the weight ratio of the amount of said -cyclodextrins to the amount of said -, and -cyclodextrins ranges from 2:1 to 1:1.

6. The odor-absorbing composition according to claim 3, wherein said composition comprises an amount of said -, -, and -cyclodextrins in a weight ratio of about: 1:1.5:0.5.

7. The odor-absorbing composition according to claim 1, wherein the weight ratio of the amount of said -cyclodextrins to the amount of said -, and -cyclodextrins ranges from 2:1 to 1:1.

Description

BRIEF DESCRIPTION OF THE FIGURES

(1) FIG. 1 represents a bar chart comparing the evaluations of the sniff test after 1 hour.

(2) FIG. 2 represents a bar chart comparing the evaluations of the sniff test after 4 hour.

(3) FIG. 3 represents a bar chart comparing the evaluations of the sniff test after 8 hour.

DETAILED DESCRIPTION OF THE INVENTION

(4) The present invention relates to an odour-absorbing composition comprising a mixture of -, -, and -cyclodextrins, wherein the amount of one of said -, -, and -cyclodextrins is equal to or higher than the total amount of the other two cyclodextrins.

(5) As used herein, the term cyclodextrin includes any of the known cyclodextrins such as unsubstituted cyclodextrins containing from six to twelve glucose units, and/or their derivatives and/or mixtures thereof.

(6) Preferred, the cyclodextrins used in the present invention are highly water-soluble -cyclodextrin and/or derivatives thereof, -cyclodextrin and/or derivatives thereof, and -gamma-cyclodextrin and/or derivatives thereof, and/or mixtures thereof.

(7) The derivatives of cyclodextrin consist mainly of molecules wherein some of the OH groups are converted to OR groups, wherein R is an alkyl group having from 1 to 6 carbon atoms, preferably from 1 to 3 carbon atoms.

(8) Highly water-soluble cyclodextrins are those having water solubility of at least about 10 g in 100 ml of water at room temperature, preferably at least about 20 g in 100 ml of water, more preferably at least about 25 g in 100 ml of water at room temperature.

(9) The concentration of cyclodextrins in the odour-absorbing composition of the present invention can be from about 0.1% to about 5%, preferably from about 0.2% to about 4%, more preferably from about 0.3% to about 3%, most preferably from about 0.4% to about 2%, by weight, based on the total weight of the odour-absorbing composition.

(10) Concentrated compositions can also be used. When a concentrated product is used, i.e., when the concentration of cyclodextrin used in the odour-absorbing composition of the present invention is from about 3% to about 5%, it is preferable to dilute the composition before applying to the skin in order to avoid tacky skin feel and/or an undesirable amount of residue. Preferably the cyclodextrin is diluted with about 50% to about 2000%, more preferably with about 60% to about 1000%, most preferably with about 75% to about 500%, by weight of the composition of water.

(11) In a first preferred embodiment of the present invention, the odour-absorbing composition comprises an amount of -cyclodextrins equal to or higher than the total amount of -, and -cyclodextrins.

(12) Preferably, the weight ratio of the amount of -cyclodextrins, to the amount of -, and -cyclodextrins ranges from 4:1 to 1:1, more preferably from 2:1 to 1:1.

(13) Advantageously, the odour-absorbing composition comprises an amount of -, -, and -cyclodextrins in a weight ratio of about 2:1:1.

(14) In a second preferred embodiment of the present invention, the odour-absorbing composition comprises an amount of -cyclodextrins equal to or higher than the total amount of -, and -cyclodextrins.

(15) Preferably, the weight ratio of the amount of -cyclodextrins, to the amount of -, and -cyclodextrins ranges from 4:1 to 1:1, more preferably from 2:1 to 1:1.

(16) Advantageously, the odour-absorbing composition comprises an amount of -, -, and -cyclodextrins in a weight ratio of about 1:2:1.

(17) In a third preferred embodiment of the present invention, the odour-absorbing composition comprises an amount of -cyclodextrins equal to or higher than the total amount of -, and -cyclodextrins.

(18) Preferably, the weight ratio of the amount of -cyclodextrins, to the amount of -, and -cyclodextrins ranges from 4:1 to 1:1, more preferably from 2:1 to 1:1.

(19) Advantageously, the odour-absorbing composition comprises an amount of -, -, and -cyclodextrins in a weight ratio of about 1:1:2.

(20) In a fourth preferred embodiment of the present invention, the odour-absorbing composition comprises an amount of -cyclodextrins equal to or higher than the total amount of -, and -cyclodextrins, and an amount of -cyclodextrins higher than the amount of -cyclodextrins.

(21) Preferably, the weight ratio of the amount of -cyclodextrins, to the amount of -, and -cyclodextrins ranges from 4:1 to 1:1, more preferably from 2:1 to 1:1, and the weight ratio of the amount of -cyclodextrins to -cyclodextrins ranges from 4:1 to 1.5:1.

(22) Advantageously, the odour-absorbing composition comprises an amount of -, -, and -cyclodextrins in a weight ratio of about: 1:1.5:0.5.

(23) The complexation between cyclodextrin and odorous molecules occurs rapidly in the presence of water when the solubilized cyclodextrins are first applied to the skin. Additionally, cyclodextrins which dry on the skin surfaces will once again achieve enhanced absorption capabilities when rewetted with body fluids. This is convenient for the user because the cyclodextrins, while on dry skin, will not fill their cavities with other environmental odours which would otherwise render them less efficient for absorbing body odours. More particularly, upon solubilisation of the cyclodextrins by the body fluids, the isolated cavities become available to form inclusion complexes with the body odour molecules. Thus, ultimately, the availability of solubilized uncomplexed cyclodextrin is essential for an effective and efficient odour control performance.

(24) The odour-absorbing composition of the present invention can contain a variety of other optional components suitable for rendering such compositions more cosmetically or aesthetically acceptable or to provide them with addition usage benefits. Such conventional optional ingredients are well-known to those skilled in the art. These include any cosmetically acceptable ingredients such as those found in the CTFA International Cosmetic Ingredient Dictionary and Handbook, 7th edition, edited by Wenninger and McEwen, (The Cosmetic, Toiletry, and Fragrance Association, Inc., Washington, D.C., 1997). As used herein cosmetically acceptable means a material (e. g., compound or composition) which is suitable for use in contact with skin, hair or other suitable substrate as defined hereinbelow.

(25) Cosmetically acceptable ingredients useful in the present invention includes cosmetically acceptable carriers, volatile and non-volatile solvents, water, and other additional ingredients, such as surfactants, preservatives, absorbents, chelating agents, lubricants, moisturizers water repellents, anti-oxidants, UV absorbers, anti-irritants, vitamins, trace metals, anti-microbial agents, perfumes, dyes and colour ingredients, and/or structuring agents

(26) The expression cosmetically acceptable carrier, as used herein, means one or more compatible solid or liquid fillers, diluents, extenders and the like, which are cosmetically acceptable as defined hereinabove. The term compatible, as used herein, means that the components of the compositions of this invention are capable of being combined with the primary actives of the present invention, and with each other, in a manner such that there is no interaction which would substantially reduce the efficacy of the composition under ordinary use situations. The type of carrier utilized in the present invention depends on the type of product desired.

(27) The compositions useful in the present invention may be a wide variety of product forms. These include, but are not limited to, lotions, creams, gels, sticks, sprays, ointments, pastes, mousses and cosmetics (e. g., solid, semi-solid, or liquid make-up, including foundations).

(28) These product forms may comprise several types of carriers including, but not limited to, solutions, aerosols, emulsions (including oil-in-water or water-in-oil), gels, solids, and liposomes.

(29) The compositions of the present invention may comprise water, in different amounts depending on the form of the composition. The amount of water, if present, can range from less than 1% to more than 99% by weight with respect to the weight of total composition.

(30) Solid compositions, spray compositions, and water-in-oil creams usually comprise amounts of water lower than 10%, more preferably lower than 5% by weight with respect to the total weight of the composition. Roll-on compositions, aqueous compositions, and deodorant usually comprises amount of water of from about 15% to about 99%, more preferably from about 30% to about 90%, even more preferably about 50% to about 80%, by weight with respect to the total weight of the composition.

(31) The compositions of the present invention may also comprise silicones. If present, the silicones will generally be at a level of from about 30% to about 85%, more preferably from about 40% to about 75%, even more preferably about 50% to about 65%, by weight with respect to the total weight of the composition. The silicones useful herein are preferably cyclic siloxanes such as octamethyl cyclotetrasiloxane, decamethylcyclopentasiloxane, and.

(32) The silicones useful herein are preferably linear or cyclic silicones having from 2 to 7 silicone atoms, these silicones being optionally substituted with alkyl or alkoxy groups of 1 to 10 carbon atoms. Suitable silicones include dodecamethylcyclohexasiloxane, cyclopentasiloxane, decamethylcyclopentasiloxane, cyclotetrasiloxane, heptamethyloctyltri-siloxane, hexamethyldisiloxane, decamethyltetrasiloxane, dodeca-methylpentasiloxane octamethyltetrasiloxane and mixtures thereof.

(33) The compositions of the present invention may comprise one or more volatile solvent. If present, the volatile solvent or mixture of solvents will generally be at a level of from about 10% to about 90%, more preferably from about 25% to about 75%, even more preferably about 35% to about 65%, by weight with respect to the total weight of the composition. The solvents useful herein are preferably organic volatile solvents.

(34) As used herein, volatile refers to substances with a significant amount of vapour pressure under ambient conditions, as is understood by those in the art.

(35) The volatile solvents for use herein will preferably have a vapour pressure of about 2 kPa or more, more preferably about 6 kPa or more, at 25 C. The volatile solvents for use herein will preferably have a boiling point under normal atmosphere (1 atm) of less than about 150 C., more preferably less than about 100 C., even more preferably less than about 90 C., even more preferably still less than about 80 C.

(36) Preferably the volatile solvents for use herein will be relatively odourless and safe for use on human skin. Suitable volatile solvents include, but are not limited to C.sub.1-C.sub.4 alcohols, volatile silicones and mixtures thereof. Preferred volatile solvents are C.sub.1-C.sub.4 alcohols and mixtures thereof. More preferred for use herein is ethanol.

(37) The compositions of the present invention may also comprise one or more non-volatile solvent. If present, the non-volatile solvent or mixture of solvents will generally be at a level of from about 1% to about 20%, more preferably from about 2% to about 10%, even more preferably from about 3% to about 5%, by weight with respect to the total weight of the composition. Suitable non-volatile solvents include, but are not limited to, benzyl benzoate, cetearyl alcohol, cetyl alcohol, diethyl phthalate, isopropyl myristate, dimethicone, caprylylmethicone, and mixtures thereof.

(38) Several other additional ingredients can be present in the compositions of the present invention. These include, but are not limited to, hydrophilic polymers selected from polyethylene glycols (PEGs), polyvinylpyrrolidones (PVP), hydroxypropyl methylcellulose (HPMC) and poloxamers; UV stabilizers such as benzophenone-3; antioxidants such as tocopheryl acetate; preservatives such as phenoxyethanol, benzyl alcohol, methyl paraben, propyl paraben; pH adjusting agents such as lactic acid, citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; deodorants and anti-microbials, such as farnesol, zinc phenolsulphonate, and ethylhexylglycerin; humectants such as tribehenin, glycerine; skin conditioning agents such as allantoin; cooling agents such as trimethyl isopropyl butanamide and menthol; hair conditioning ingredients such as panthenol, panthetine, pantotheine, panthenyl ethyl ether, and combinations thereof; propellants such as propane, isopropane, butane, and isobutene; salts in general, such as potassium acetate and sodium chloride and mixtures thereof; perfumes and dyes.

(39) If present, these additional ingredients will preferably be present at a level of less than 10%, more preferably of less than 5%, by weight with respect to the total weight of the composition.

(40) The following examples serve to illustrate the invention without however restricting it.

EXAMPLE 1

(41) Several mixtures of , , and -cyclodextrins were analysed by sniff test to evaluate their ability to mask body malodour. The composition of the cyclodextrin mixtures are reported in the following Table 1.

(42) TABLE-US-00001 TABLE 1 Sample % -cyclodextrin % -cyclodextrin % -cyclodextrin DEO1 1.50 0.75 0.75 DEO2 0.75 1.50 0.75 DEO3 0.75 0.75 1.50 DEO4 1.00 1.50 0.50

(43) A blend of malodour compounds, named CFM13668, simulating the component of body sweat which produces malodour, was obtained from CFF S.p.A., Opera, Italy (www.creative-flavours-fragrances.com). The CFM13668 basic sweat contained the malodour compounds as reported in the following Table 2.

(44) TABLE-US-00002 TABLE 2 CAS Number Compound 101-94-0 p-cresyl phenylacetate 120-72-9 indol 103-82-2 phenylacetic acid 55066-56-3 p-cresyl isovalerate 68-11-1 thioglycolic acid 107-92-6 N-butyric acid 142-62-1 caproic acid 25265-71-8 dipropylene glycol 590-86-3 isovaleraldehyde 503-74-2 isovaleric acid

(45) Four specific sweats, simulating a life period and a sexual gender, were prepared by adding to the basic sweat two compounds specific for a life cycle or sexual gender, as reported in the following Table 3.

(46) TABLE-US-00003 TABLE 3 Sweat A Sweat B Sweat C Sweat D Teenager Woman Man Elderly Testosterone 250 pmoli/L Dihydrotestosterone 150-200 pmoli/L 3-methyl-2- 7-10 g/L 7-10 g/L hexanoic acid Androstenol 100-150 pmoli/L Androsterone 100-150 pmoli/L 2-nonenal 0.2-0.4% nonanal 0.2-0.4%

(47) Five drops of the basic sweat were added to 400 mL of a NaCl 0.9% physiological solution, diluted 1:3 with distilled water. This mixture was used as reference for the sniff test.

(48) Five drops of each Sweat A to D and five drops of each DEO 1 to 4 were added to 400 mL of a NaCl 0.9% physiological solution, diluted 1:3 with distilled water. Sixteen solutions were obtained, each having a volume of about 400 ml and containing a specific Sweat (A to D) in combination with a specific DEO (1 to 4).

(49) All the mixtures were stirred for 5 minutes. The pH was adjusted to 5.5. Aliquots of 2 mL of each mixture were transferred to Pyrex tubes and sealed with sealing plugs.

(50) A sniff test was performed by 8 trained judges after 1, 4 and 8 hours. The judges evaluated the intensity of malodour according to a grading scale, reported in Table 4, where the reference had a score of 5.

(51) TABLE-US-00004 TABLE 4 Grade Malodour intensity 1 Much lower than the reference 2 Lower than the reference 3 Moderately lower than the reference 4 Slightly lower than the reference 5 Equal to reference 6 Slightly higher than the reference 7 Moderately higher than the reference 8 Higher than the reference 9 Much higher than the reference

(52) The results of the sniff tests after 1, 4 and 8 hours have been reported in the following Tables 5 to 7, and graphically represented in the attached FIGS. 1 to 3.

(53) TABLE-US-00005 TABLE 5 SNIFF TEST AFTER 1 HOUR SWEAT A SD SWEAT B SD SWEAT C SD SWEAT D SD DEO 1 4.20 0.21 4.75 0.17 4.30 0.25 4.00 0.18 DEO 2 4.00 0.13 4.69 0.12 3.78 0.19 3.83 0.23 DEO 3 3.81 0.18 4.06 0.16 3.51 0.23 4.83 0.18 DEO 4 4.06 0.11 4.50 0.13 4.44 0.20 4.19 0.13 Reference 4.94 0.14 5.06 0.11 5.02 0.12 4.94 0.09 SD: Standard Deviation

(54) TABLE-US-00006 TABLE 6 SNIFF TEST AFTER 4 HOUR SWEAT A SD SWEAT B SD SWEAT C SD SWEAT D SD DEO 1 3.83 0.15 4.00 0.15 4.00 0.18 3.44 0.17 DEO 2 3.81 0.11 4.06 0.21 3.67 0.22 3.33 0.21 DEO 3 3.69 0.23 3.06 0.11 3.45 0.16 4.33 0.26 DEO 4 3.25 0.15 4.25 0.17 4.19 0.20 3.81 0.16 Reference 4.88 0.12 5.00 0.09 4.97 0.23 4.96 0.08 SD: Standard Deviation

(55) TABLE-US-00007 TABLE 7 SNIFF TEST AFTER 8 HOUR SWEAT A SD SWEAT B SD SWEAT C SD SWEAT D SD DEO 1 3.45 0.22 3.94 0.14 3.85 0.19 3.35 0.18 DEO 2 3.63 0.13 4.00 0.15 3.55 0.23 3.17 0.19 DEO 3 3.50 0.15 3.00 0.13 3.40 0.25 4.17 0.20 DEO 4 2.88 0.11 4.00 0.09 3.94 0.06 3.56 0.12 Reference 5.00 0.16 5.06 0.11 5.05 0.20 5.04 0.12 SD: Standard Deviation

(56) The results of Tables 5 to 7 have clearly demonstrated the better efficacy of DEO 4 in masking the malodour of teenagers (Sweat A) compared to the efficacy in masking the malodour of elderly people and adult people (Sweats B-D).

(57) Further, the results of Tables 5 to 7 have clearly demonstrated the better efficacy of DEO 3 in masking the malodour of women (Sweat B) compared to the efficacy in masking the malodour of teenagers, men and elderly people (Sweats A and C-D).

(58) The efficacy of DEO 2 was demonstrated comparable to that of DEO3 in masking the malodour of men (Sweat C), even if the results of Table 5 to 7 are slightly inferior.

(59) Similarly, the efficacy of DEO 1 was demonstrated comparable to that of DEO 2 in masking the malodour of elderly people (Sweat D), even if the results of Table 5 to 7 are slightly inferior.

EXAMPLE 2

(60) The following Tables 8 to 17 provide several examples of preferred embodiment of odour-absorbing compositions according to the present invention. All compositions can be preferably realized with a weight ratio of -, -, and -cyclodextrins of 1:1.5:0.5 when intended for teenagers, 1:1:2 when intended for women, 1:1:2 or, preferably, 1:2:1 when intended for men, and 1:2:1 or, preferably, 2:1:1 when intended for elderly people.

(61) TABLE-US-00008 TABLE 8 Cream deodorant 1 Ingredients Range % Water from 50 to 80% Aluminum chlorohydrate from 0 to 20% Cetearyl alcohol from 2 to 5% -, -, and -cyclodextrins from 0 to 5% Cetyl alcohol from 1 to 3% Dimethicone from 1 to 3% Caprylyl methicone from 1 to 3% Cyclopentasiloxane from 1 to 3% Parfum from 0.5 to 2% Ceteareth-20 from 0 to 1% Polysilicone-11 from 0 to 1% 2-Methyl 5-cyclohexylpentanol less than 1% Guar hydroxypropyltrimonium chloride less than 1% Cetrimonium chloride less than 1% Sodium hydroxide less than 1%

(62) TABLE-US-00009 TABLE 9 Cream deodorant 2 Ingredients Range % Cyclopentasiloxane from 53 to 64% Aluminum zirconium tetrachlorohydrex gly from 16 to 30% Dimethicone from 3 to 8% Tribehenin from 3 to 8% -, -, and -cyclodextrins from 0 to 5% Water from 1 to 3% C18-36 acid triglyceride from 1 to 2% Parfum from 0.5 to 2% Panthenyl triacetate less than 2% Tocopheryl acetate less than 1% Parfum less than 1%

(63) TABLE-US-00010 TABLE 10 Roll-on deodorant 1 Ingredients Range % Water from 40 to 60% Aluminum chlorohydrate from 0 to 30% Ethylhexyl stearate from 1 to 8% PPG-15 stearyl ether from 0 to 5% -, -, and -cyclodextrins from 0 to 5% Ceteareth-25 from 1 to 3% Glyceryl stearate from 1 to 3% Stearoxy dimethicone from 1 to 3% Dimethicone from 1 to 3% Glycerin from 0 to 3% Parfum from 0.5 to 2% Triethyl citrate from 0 to 2% Phenoxyethanol from 0 to 1% Stearyl Alcohol less than 1%

(64) TABLE-US-00011 TABLE 11 Roll-on deodorant 2 Ingredients Range % Water from 55 to 85% Aluminum chlorohydrate from 0 to 30% PPG-15 stearyl ether from 1 to 5% Steareth-2 from 1 to 3% Steareth-20 from 1 to 3% Parfum from 0.5 to 2% Isohexadecane from 0 to 2% Dipropylene Glycol from 0 to 2% Glycerin from 0 to 2% Triethyl citrate from 0 to 2% Zinc Phenolsulfonate from 0 to 1% Phenoxyethanol less than 1% 2-Methyl 5-cyclohexylpentanol less than 1% Decylene glycol less than 1% -, -, and -cyclodextrins from 0 to 5%

(65) TABLE-US-00012 TABLE 12 Spray deodorant 1 Ingredients Range % Butane from 30 to 65% Isobutane from 12 to 23% Propane from 11 to 21% Cyclopentasiloxane from 5 to 25% Aluminum chlorohydrate from 0 to 8% -, -, and -cyclodextrins from 0 to 5% Dimethicone less than 2% Parfum from 0.5 to 2% Disteardimonium hectorite less than 2% Triethyl citrate from 0 to 2% Phenoxyethanol from 0 to 1% 2-Methyl 5-cyclohexylpentanol from 0 to 1% Ethylhexylglycerin from 0 to 1% Water from 0 to 1%

(66) TABLE-US-00013 TABLE 13 Spray deodorant 2 Ingredients Range % Butane from 35 to 65% Isobutane from 13 to 25% Propane from 12 to 22% Water from 4 to 11% Aluminum chlorohydrate from 2 to 5% -, -, and -cyclodextrins from 0 to 5% Cyclopentasiloxane from 1 to 4% Parfum from 0.5 to 2% C12-13 alkyl lactate less than 1% PEG/PPG-18/18 dimethicone less than 1% Caprylyl glycol less than 1% Ethyl hexylglycerin less than 1%

(67) TABLE-US-00014 TABLE 14 Stick deodorant 1 Ingredients Range % Cyclopentasiloxane from 23 to 42% Stearyl alcohol from 11 to 21% Aluminum chlorohydrate from 10 to 18% C12-15 alkyl benzoate from 5 to 15% PPG-14 butyl ether from 3 to 9% Talc from 3 to 9% Hydrogenated castor oil from 2 to 7% -, -, and -cyclodextrins from 0 to 5% Paraffinum liquidum from 2 to 5% Petrolatum from 2 to 5% Parfum from 0.5 to 2% Water less than 1% Behenyl alcohol less than 1%

(68) TABLE-US-00015 TABLE 15 Stick deodorant 2 Ingredients Range % Dipropylene glycol from 25 to 50% Water from 15 to 35% PEG-200 from 14 to 26% Glycerin from 5 to 15% Sodium stearate from 3 to 8% -, -, and -cyclodextrins from 0 to 5% Parfum from 0.5 to 2% PPG-3 myristyl ether less than 2% Isopropyl myristate less than 1% BHT less than 1% Sodium hydroxide less than 1%

(69) TABLE-US-00016 TABLE 16 Deo vapo 1 Ingredients Range % Alcohol denaturated from 28 to 52% Cyclopentasiloxane from 19 to 36% PPG-3 myristyl ether from 11 to 20% C12-15 alkyl benzoate from 5 to 14% Water from 2 to 5% -, -, and -cyclodextrins from 0 to 5% Parfum from 0.5 to 3% Dimethicone less than 2% Zinc phenolsulfonate less than 2%

(70) TABLE-US-00017 TABLE 17 Deo vapo 2 Ingredients Range % Water from 79 to 97% PEG-40 hydrogenated castor oil from 2 to 5% -, -, and -cyclodextrins from 0 to 5% Dipropylene glycol from 1 to 3% Ceteareth-20 from 1 to 2% Parfum from 0.5 to 2% Triethyl citrate less than 2% Glycerin less than 2% Phenoxyethanol less than 1% 2-Methyl 5-cyclohexylpentanol less than 1% Ethylhexylglycerin less than 1% Propylene glycol less than 1% Decylene glycol less than 1% Dicaprylyl ether less than 1%