Melt tank and glass melting plant
11939256 ยท 2024-03-26
Assignee
Inventors
Cpc classification
Y02P40/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
Abstract
A melt tank for the production of a glass melt having a low portion of bubbles. The melt tank includes an inlet opening, an outlet opening, a floor, at least two side walls that adjoin the floor, a roof. The glass melt having a first bath depth in a melting segment, a second bath depth in a refining segment, and a third bath depth over a threshold between and smaller than the first and second bath depths. An electrically produced first heat energy is supplied via a multiplicity of electrodes that extend into the glass melt and a second heat energy is produced by the combustion of fossil fuel via at least one burner. Also, a method for producing a glass melt.
Claims
1. A melt tank for the production of a glass melt from at least one solid starting material, the melt tank comprising: an inlet opening for a supply of the at least one solid starting material, an outlet opening for an outflow of a molten glass, the melt tank configured in such a way that the glass melt flows in a direction of flow from the inlet opening to the outlet opening during the melt process; a floor that limits the melt tank at a bottom; at least two side walls that adjoin the floor and that laterally limit the melt tank; and, a roof that is connected to the side walls and that limits the melt tank at a top, wherein the melt tank includes a melting segment and a refining segment, the glass melt first passing through the melting segment and subsequently through the refining segment when flowing in the direction of flow, wherein an atmosphere above the glass melt in the melting segment is in communication with an atmosphere above the glass melt in the refining segment, the glass melt having a first bath depth B1 in the melting segment and having a second bath depth B2 in the refining segment, a threshold running transverse to the direction of flow being situated in the floor of the melt tank in a transition area of the melt tank between the melting segment and the refining segment, a third bath depth B5 over the threshold being smaller than the first bath depth B1 and smaller than the second bath depth B2, wherein the threshold forms a highest raised part in the floor of the melting tank with a smallest bath depth, the melt tank being configured such that for the melting of the at least one starting material of the glass melt: an electrically produced, first heat energy portion (Q.sub.elec) is supplied via a multiplicity of electrodes that extend into the glass melt, and a second heat energy portion (Q.sub.fossil), produced by a combustion of fossil fuel, is supplied in at least one burner situated in a side wall, in the roof, or both, above the glass melt, a total supplied heat energy being made up of the first heat energy portion and the second heat energy portion, wherein the melt tank is configured in such a way that the first heat energy portion comprises at least 30% of the total supplied heat energy, and, wherein a first row of electrodes is situated in the floor of the melt tank on the threshold, in the glass melt flow, the first row of electrodes including a multiplicity of electrodes and the first row of electrodes running transverse to the direction of flow.
2. The melt tank as recited in claim 1, wherein a second row of electrodes, is situated in the floor of the melt tank at a distance L2 after the first row of electrodes in the direction of flow, wherein the second row of electrodes including a multiplicity of electrodes and the second row of electrodes running transverse to the direction of flow and, and the second row of electrodes also being situated on the threshold.
3. The melt tank of claim 2, wherein the distance L2 is between 500 mm and 1000 mm.
4. The melt tank of claim 1, wherein the third bath depth B5 over the threshold is between 200 mm and 1000 mm.
5. The melt tank of claim 1, wherein the first bath depth B1 in the melting segment is between 1100 mm and 2000 mm, and the second bath depth B2 in the refining segment is between 700 mm and 2800 mm.
6. The melt tank of claim 5, wherein the first bath depth B1 in the melting segment (10) is between 1400 mm and 2000 mm.
7. The melt tank of claim 1, wherein the multiplicity of electrodes situated on the threshold are rod electrodes and/or block electrodes.
8. The melt tank of claim 1, wherein the length L4 of the threshold is between 700 mm and 3000 mm in the direction of flow.
9. The melt tank as recited of claim 1, wherein the at least one burner for supplying the second heat energy portion is situated exclusively in the melting segment.
10. The melt tank of claim 9, further comprising: a multiplicity of burners situated in a side wall running in the direction of flow.
11. The melt tank of claim 1, wherein the at least one burner is controllable in such a way that the second heat energy portion (Q.sub.fossil) produced by the at least one burner corresponds to a loss of heat energy (Q.sub.wall) that is emitted to an outside via the melt tank.
12. The melt tank of claim 1, characterized in that a multiplicity of electrodes is situated in the melting segment in the floor of the melt tank.
13. The melt tank of claim 1, wherein a radiation wall is situated on the roof, at the melting segment, at the transition area between the melting segment and the refining segment, or at both, the radiation wall running transverse to the direction of flow.
14. The melt tank of claim 1, wherein a further row of electrodes is situated in the floor of the melt tank, before the threshold in the floor of the melt tank in the direction of flow of the glass melt, the further row of electrodes including a multiplicity of electrodes and the further row of electrodes running transverse to the direction of flow.
15. A glass melting plant comprising: a melt tank of claim 1, a constriction region following the melt tank, a conditioning region, and a channel.
16. The glass melting plant as recited in claim 15, wherein at least one cooling element is situated in the constriction region, on a cover of the constriction region.
17. The melt tank of claim 1, wherein a multiplicity of electrodes is situated in the melting segment in the floor of the melt tank in at least one third row of electrodes, the at least one third row of electrodes running in the direction of flow.
18. A melt tank for the production of a glass melt from at least one solid starting material, the melt tank comprising: an inlet opening for a supply of the at least one solid starting material, an outlet opening for an outflow of a molten glass, the melt tank configured in such a way that the glass melt flows in a direction of flow from the inlet opening to the outlet opening during the melt process; a floor that limits the melt tank at a bottom; at least two side walls that adjoin the floor and that laterally limit the melt tank; and, a roof that is connected to the side walls and that limits the melt tank at a top, wherein the melt tank includes a melting segment and a refining segment, the glass melt first passing through the melting segment and subsequently through the refining segment when flowing in the direction of flow, wherein an atmosphere above the glass melt in the melting segment is in communication with an atmosphere above the glass melt in the refining segment, the glass melt having a first bath depth B1 in the melting segment and having a second bath depth B2 in the refining segment, a threshold running transverse to the direction of flow being situated in the floor of the melt tank in a transition area of the melt tank between the melting segment and the refining segment, a third bath depth B5 over the threshold being smaller than the first bath depth B1 and smaller than the second bath depth B2, wherein the threshold forms a highest raised part in the floor of the melting tank with a smallest bath depth, the melt tank being configured such that for the melting of the at least one starting material of the glass melt: an electrically produced, first heat energy portion (Q.sub.elec) is supplied via a multiplicity of electrodes that extend into the glass melt, and a second heat energy portion (Q.sub.fossil), produced by a combustion of fossil fuel, is supplied in at least one burner situated in a side wall, in the roof, or both, above the glass melt, a total supplied heat energy being made up of the first heat energy portion and the second heat energy portion, wherein the melt tank is configured in such a way that the first heat energy portion comprises at least 30% of the total supplied heat energy, wherein a first row of electrodes is situated in the floor of the melt tank on the threshold, in the glass melt flow, the first row of electrodes including a multiplicity of electrodes and the first row of electrodes running transverse to the direction of flow, and wherein a section of the roof is configured such that a lower surface of the section is distanced from the glass melt surface, wherein the section comprises the melting segment to a beginning of the threshold.
Description
DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
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(12) The melt tank includes the segments melting segment 10 and refining segment 20. The melt tank is followed by a constriction region 30, a conditioning region 40, and a channel 50. The starting materials for the production of the glass melt (primary raw materials and, possibly, shards) are continuously supplied at inlet opening 11 of the melt tank by a feed device (not shown). The starting materials are in particular melted in the melting segment 10 of the melt tank, and move (flow) together with glass melt 60 through refining segment 20, to outlet opening 12 of the melt tank, and further through constriction region 30, conditioning region 40, and channel 50, until they reach glass outlet opening 52. The direction of flow of glass melt 60 is indicated by an arrow 5 in
(13) The melt tank has a floor 13, a roof 15 that is situated opposite floor 13, and side walls 16. In the exemplary embodiment shown in
(14) Floor 13 of the melt tank has a rising step 17 and a falling step 28 that run transverse to the direction of flow of the glass melt, in particular perpendicular to the direction of flow, and are situated in the area of transition between melting segment 10 and refining segment 20. The two steps 17, 28 together form a threshold 27. Step 17 is in a sense the beginning of refining segment 20. Bath depth B1 in melting segment 10, which is the minimum of all bath depths in melting segment 10, is greater than bath depth B2 in the direction of flow after falling step 28, i.e. in refining segment 20. Bath depth B2 is the minimum of all bath depths in refining segment 20, the bath depths over threshold 27 and the electrodes that may be situated there not being taken into account in the ascertaining of the minima in the refining segment and in the melting segment.
(15) In the direction of flow of the glass melt after first step 17, i.e. at threshold 27 in the transition area between melting segment 10 and refining segment 20, a first row of electrodes 21, having a multiplicity of electrodes situated alongside each other, and a second row of electrodes 22, also having a multiplicity of electrodes situated alongside each other, are provided. The electrodes, realized as rod electrodes, each go out perpendicularly upward from floor 13 of the melt tank and extend into glass melt 60. Alternatively, the electrodes of rows of electrodes 21, 22 can be realized at least partly as block electrodes; a block electrode is shown in section in
(16) For the heating of glass melt 60 using electrical energy, a third row of electrodes 19a and a fourth row of electrodes 19b are provided in melting segment 10, each also having a multiplicity of electrodes (e.g. rod electrodes) situated alongside one another, which extend from floor 13 into glass melt 16. Third row of electrodes 19a and fourth row of electrodes 19b each run in the direction of flow (arrow 5) of glass melt 60. Correspondingly, the orientation of third and fourth rows of electrodes 19a and 19b is perpendicular to the orientation of first and second rows of electrodes 21, 22. It is also possible for more than two rows of electrodes running in the direction of flow of the glass melt to be provided in melting segment 10.
(17) Before step 17, in the direction of flow of the glass melt, there can be situated a further row of electrodes 23 having a multiplicity of electrodes (e.g. rod electrodes) situated alongside one another, transverse to the direction of flow, and extending upward from floor 13 of the melt tank into melt 60. Accordingly, the further row of electrodes 23 runs parallel to first row of electrodes 21 and to second row of electrodes 22. Further row of electrodes 23 is situated at a distance of for example 500 mm to 1500 mm, e.g. 800 mm, before the upper edge of the first step, i.e. still in the melting segment. The electrodes of further row of electrodes 23 are configured offset to the electrodes of the rows of electrodes 21, 22 provided on threshold 27.
(18) In addition, in each of the two side walls 16 that run parallel to the direction of flow of glass melt 60, there are situated for example two burners 19c that supply heat energy to glass melt 60, the energy being produced by combustion of the fossil fuel gas using an oxidant in combustion chamber 18. The openings of burners 19c are situated in side walls 16 above the surface of glass melt 60, so that the burners heat the melt from above via combustion chamber 18. One burner 19c is situated above threshold 27.
(19) In addition, a radiation wall 25 that runs downward from roof 15 in the direction of glass melt 60 can be provided in refining segment 20, above first row of electrodes 21 or second row of electrodes 22, or between these rows of electrodes 21, 22, as shown in
(20) In the region of constriction 30, in addition a cooling element 32 is situated that protrudes downward from the cover 15 of constriction region 30 and is immersed in glass melt 60. Cooling element 32 is for example cooled by water, and has the shape of a plate.
(21) In conditioning region 40 and channel 50, bath depths B3 and B4, as shown in
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(23) In the specific embodiments shown in
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(25) In the melt tank shown in
(26) The design of the present invention has been tested in extensive modeling calculations, in particular for throughput quantities of from 300 t to 800 t glass melt per day. For high throughput quantities, the dimensions in melting segment 10 and in refining segment 20, (i.e. length and width of the melt tank) have to be adapted. In contrast, the bath depths and the width of threshold 27 in the direction of flow, and the height of threshold 27, are not changed. Of course, the width of threshold 27 transverse to the direction of flow is matched to the width of the melt tank in melting segment 10 and in refining segment 20. Correspondingly, the number of electrodes situated alongside one another in rows of electrodes 21, 22, 23 also increases.
(27) In
(28) According to the present invention, it is decisive that the dimensioning of threshold 27, including the dimensioning of the electrodes situated on the threshold, ensures that bubbles that have a particular minimum diameter will move to the surface. In the following Table 1, suitable geometrical relations are shown for bubbles having a size >0.2 mm Here, the rise of the bubbles is calculated according to Stoke's Law. From Table 1, it can be seen that for all three calculated throughput quantities, bubbles having a standard diameter >0.23 mm had enough time to reach the surface of the glass melt. Here, the rise time is equal to the dwell time of the glass melt in refining segment 20, in the upper layer of the glass melt.
(29) TABLE-US-00001 TABLE 1 Throughput kg/day 400,000 500,000 700,000 Melt density kg/m.sup.3 2400 2400 2400 Melt bath ? C. 1480 1480 1480 temperature Melt bath Pascal 6.4 6.4 6.4 viscosity (kg/m*s) Bubble mm 0.23 0.23 0.23 diameter Rise speed m/s 4.21E?05 4.21E?05 4.21E?05 Refining zone Basin length m 6.2 7.2 8.2 Basin width m 7.4 8.45 9.5 Pre-flow layer m 0.135 0.135 0.135 thickness Melt dwell min 53.51 51.61 51.92 time in refining part Bubble rise min 53.5 51.6 52 time
(30) The following Table 2 contains, in each column, three examples of the realization of a glass melting plant according to the present invention that corresponds to the exemplary embodiment according to
(31) TABLE-US-00002 TABLE 2 Glass type/product Container Container Flat glass glass glass Melt output t glass/day 350.00 160.00 110.00 Melt surface m.sup.2 135.42 80.04 90.00 Melt tank length m 18.30 13.80 15.08 Melt tank width m 7.40 5.80 6.00 Length of the m 2.50 1.96 2.10 electrode wall Melting part (10) m 13.00 10.80 9.17 Refining part (20) m 5.40 4.00 5.91 Bath depth melting m 1.40 1.30 1.40 part (B1) Bath depth refining m 1.75 1.60 1.25 part (B2) Glass over electrode m 0.825 0.825 0.85 wall (B5) Number of 36 24 24 electrodes in the melting part Number of el. on 6 6 6 the electrode wall Portion of boosting % 80 64 76 in total energy Electrical energy kW 9330 5500 5250 Fossil energy m.sup.3/h 235 300 155 (natural gas Heat value natural kWh/m.sup.3 10 10.56 10 gas
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(33) The same also results from the results of simulation calculations shown in
(34) The simulations showed that an adequately high temperature at the glass bath surface (see
(35) The mathematical simulation makes it possible to also evaluate the refining performance. For this purpose, in the model bubbles having smaller size are defined in a layer below the glass melt surface in the melting region. These correspond to the bubbles that occur when the carbonates are decomposed during the melting of the raw materials. These bubbles move through the melt tank with the flow. The temperature increase along this path is the cause of the growth in size of the bubbles (expansion of the gas) and the increasing rise speed, in accordance with Stoke's Law; this is taken into account in the mathematical simulation calculation. In the model, it can be seen that the bubbles will grow and rise to such an extent that the glass melt is free of bubbles after the barrier only if a threshold is used having electrodes situated on the surface of the threshold. In the two other cases, a significant number of bubbles move across the barrier into the output glass flow, or into the product. The calculation has confirmed that adequate glass quality is ensured only given the use of a heated threshold with a large portion of electrical energy relative to the total supplied heat energyunder the constraint that the energy input from fossil fuels is significantly limited.
(36) The above observations are illustrated in
(37) As explained above, the bubbles become larger along their path in circulating glass melt 60. It will be seen that all bubbles rise to the surface. Their escape at the surface is identified by a point at the end of the line of movement of each bubble. For all the bubbles calculated in the model, there is no path that extends up to outlet opening 12. The simulation shows the case of a model having a heated threshold and a high portion of electrical energy in the total supplied heat energy.
(38) In the cases shown in