METHOD AND EQUIPMENT FOR COOLING ON A REVERSING HOT ROLLING MILL
20230219125 · 2023-07-13
Inventors
- Vincent DUHOUX (Coublevie, FR)
- Gilles GUIGLIONDA (Seyssinet-Pariset, FR)
- Romain-Fabrice BERNES (Issoire, FR)
- Bruno MAGNIN (Saint-Aupre, FR)
- Erin DEDA (Ypsilanti, MI, US)
- Xavier UNTERFINGER (Colmar, FR)
- John M. EVANS (Muscle Shoals, AL, US)
- Trevor GILMORE (Waterloo, AL, US)
Cpc classification
B21B3/00
PERFORMING OPERATIONS; TRANSPORTING
B21B37/44
PERFORMING OPERATIONS; TRANSPORTING
International classification
B21B37/44
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The invention relates to a hot reversing mill equipped with one or more cooling systems consisting of bars of nozzles spraying an aluminum blank. It also relates to the hot rolling process associated with this hot reversing mill wherein the cooling system serves at least once making it possible to produce aluminum sheets advantageously. It also relates to the process for rolling an AA6xxx series aluminum alloy wherein a blank is cooled during the hot rolling and a sheet obtained with this process. The invention makes it possible to enhance the productivity of reversing mills by enhancing the metallurgical quality and/or the productivity of the other fabrication steps. The invention is particularly useful for providing superior quality 6xxx alloy sheets intended for the automotive industry.
Claims
1. A hot reversing mill comprising two work rolls, a top work roll and a bottom work roll, and at least one cooling system intended to cool a blank, said blank moving on reels and passing through the hot reversing mill between the two work rolls and, said cooling system consisting of two cooling devices: a top cooling device of the blank and a bottom cooling device of the blank wherein: the top cooling device comprises at least one bar of nozzles disposed substantially parallel with the axis of the top work roll, the nozzles spraying with jets of cooling fluid the top face of the blank, The bottom cooling device comprises at least one bar of nozzles disposed between the reels or between the bottom work roll and the nearest reel, substantially parallel with the axis of the bottom work roll, the nozzles spraying with jets of cooling fluid the bottom face of the blank, the axis of the jets of cooling fluid being oriented substantially perpendicularly to the bottom surface of the blank.
2. The hot reversing mill according to claim 1 wherein the intersection between the top surfaces sprayed directly with the jets of cooling fluid with the top face of the edge is empty at the start of hot rolling, optionally for the entire duration of the hot rolling, and/or the intersection between the bottom surfaces sprayed directly by the jets of cooling fluids with the bottom face of the edge is empty at the start of hot rolling, optionally for the entire duration of the hot rolling.
3. The hot reversing mill according to claim 1 wherein the intersection between the top surfaces sprayed directly with the jets of cooling fluid with the top face of the ends is empty at the start of hot rolling, optionally for the entire duration of the hot rolling and/or the intersection between the bottom surfaces sprayed directly by the jets of cooling fluids with the bottom face of the ends is empty at the start of hot rolling, optionally for the entire duration of the hot rolling.
4. The hot reversing mill according to claim 1 wherein the bottom nozzles produce jets of cooling fluid (46) which do not reach either the reels or the roll directly in the presence of the blank and which are preferentially almost tangent to the reels and the distance D67 whereof, which is the minimum of the distance from any point of the convex envelope with the line C2 which is the projection of the axis of the roll on the bottom surface of the blank, less the radius R2 of the roll, is optionally greater than a radius of the bottom roll, optionally than the diameter of the bottom roll and/or the top nozzles produce jets of cooling fluid which do not reach the top work roll directly, optionally the distance D57, which is the minimum of the distance from any point of the convex envelope with the line C1 which is the projection of the axis of the roll on the top surface of the blank, less the radius R1 of the roll, is greater than the radius of the top roll, optionally the distance D57 is greater than the diameter of the top roll.
5. (canceled)
6. The hot reversing mill according to claim 1 wherein each nozzle and is supplied individually by a rapid response valve the response time whereof is optionally less than 1 s, optionally less than 0.5 s, and optionally less than 0.2 s.
7. (canceled)
8. (canceled)
9. (canceled)
10. (canceled)
11. The hot reversing mill according to claim 1 wherein the nozzles in the vicinity of the top work roll produce jets of cooling fluid of which all the movement components, projected on the direction S of movement of the blank, are oriented toward the work rolls and of the mill.
12. The hot reversing mill according to claim 1 wherein the top sprayed convex envelope and the bottom sprayed convex envelope are in the vicinity of the rolls of the mill; the maximum distances D55 and D65, D55 being the maximum of the distance from any point of the convex envelope with the line C1 which is the projection of the axis of the roll on the top surface of the blank, less the radius R1 of the roll, D65 being the maximum of the distance from any point of the convex envelope with the line C2 which is the projection of the axis of the roll on the bottom surface of the blank, less the radius R2 of the roll, are less than 3 times the largest of the diameters of the work rolls and and/or the lengths D56 and D66, D56 being the subtraction of the length D57 from the length D55, D66 being the subtraction of the length D67 from the length D65, of said convex envelopes are less than two diameters, optionally one diameter of the largest of the work rolls.
13. The hot reversing mill according to claim 1 comprising a second cooling system on the other side of said hot reversing mill, the second cooling system being optionally symmetrical to the first with respect to a plane passing through the axes of the work rolls.
14. The hot reversing mill according claim 1 wherein the top cooling device comprises at least one pair of bars of nozzles, optionally 3 pairs of bars, in each pair of bars, the jets of cooling fluid being oriented in opposition, the difference β−α/2 being positive or zero, optionally zero, α being the cone angle of the jet of cooling fluid produced by the nozzles and β being the angle of inclination formed by the axis of the nozzles with the line V perpendicular to the top face of the blank, the sprayed surfaces of the blank by the jets overlapping optionally by a factor between ⅓ and ⅔, optionally ½, and the bottom cooling device comprises at least one bar of nozzles, optionally 8 bars, the jets of cooling fluid whereof are conical and of axis substantially normal to the blank.
15. The hot reversing mill according claim 1 wherein the top cooling device comprises at least one bar, optionally 6 bars, of nozzles and the bottom cooling device comprises at least one bar, optionally 8 bars, of nozzles, all producing conical jets of cooling fluid and the axes whereof are substantially perpendicular to the blank, and the cone angle α of the jets of the top nozzles whereof is less than 20°, optionally the cone angle α of the jets of the top nozzles is substantially 15°.
16. The hot reversing mill according to claim 14 wherein the hot reversing mill is part of a hot table wherein the hot reversing mill is followed by a second hot mill, the cooling system of the hot reversing mill being placed between the hot reversing mill and the second hot mill, optionally the distance between the cooling system and the second hot mill is sufficient such that the cooling system and the second hot mill operate independently.
17. A process for hot rolling an aluminum alloy comprising a. providing a rolling ingot made of optionally clad aluminum alloy at a hot rolling input temperature, b. carrying out a plurality of hot rolling and/or cooling passes with the hot mill according to claim 1, the cooling system serving at least once, c. transferring a blank or finished product in sheet or strip form at a hot rolling output temperature for remainder of the hot fabrication process.
18. (canceled)
19. (canceled)
20. (canceled)
21. The process according to claim 17 wherein mean cooling rate V of mean temperature of the blank during passage of the blank between top and bottom convex envelopes is V=C/e, where V is in ° C./s, e is the thickness of the blank in mm, and C is a constant value which equals between 400 and 1000° C./s*mm, optionally between 600 and 900° C./s*mm, optionally between 700 and 800° C./s*mm.
22. (canceled)
23. A process comprising a. providing a rolling ingot made of optionally clad aluminum alloy at a hot rolling input temperature, b. carrying out a plurality of hot rolling and/or cooling passes with the hot mill according to claim 14, the cooling system serving at least once, c. transferring the blank or the finished product in sheet or strip form at a hot rolling output temperature for the remainder of the hot fabrication process.
24. (canceled)
25. A process for hot rolling an AA6xxx series aluminum alloy comprising: a. casting a rolling ingot made of AA6xxx series alloy, b. homogenizing the rolling ingot, optionally followed by a reheating, c. first hot rolling to convert the rolling ingot into a blank having a first output thickness from a first hot rolling starting temperature, d. cooling the blank obtained with a mean cooling rate of the mean temperature of the blank of V=C/e up to a second starting temperature of second hot rolling, where V is in ° C./s, e is the thickness of the blank in mm, and C is a constant which equals between 400 and 1000° C./s*mm, optionally between 600 and 900° C./s*mm, more optionally between 700 and 800° C./s*mm, e. second hot rolling to convert the blank obtained into a strip at the final hot rolling thickness under deformation and temperature conditions such that the strip is recrystallized to at least 50%, f. cold rolling the strip into a sheet.
26. The process according to claim 25 wherein the first hot rolling and the cooling are performed with a hot mill and/or during cooling of d, the cooling system is used optionally once so as to reduce mean temperature of the blank by at least 50° C. to a mean temperature greater than 400° C.
27. The process according to claim 25 wherein the temperature during the first hot rolling is maintained above 450° C., optionally above 470° C. and optionally above 490° C. and/or the first output thickness is between 90 mm and 140 mm, optionally between 100 and 130 mm, and optionally between 110 mm and 120 mm and/or the output temperature of the second hot rolling is at least 345° C., optionally at least 350° C. and optionally at least 355° C. and/or the reduction of the final pass of the second hot rolling is at least 25%, optionally at least 30%, optionally 40%, and optionally at least 45% and/or the reduction by cold rolling is between 70% and 80%, or greater than 80%.
28. The process according to claim 25 wherein after f, further comprising g. solution heat treatment and quenching of a sheet thus obtained in a continuous heat treat furnace, optionally the continuous heat treatment furnace operates such that equivalent hold time at 560° C., t.sub.eq.sup.560° is less than 30 s, optionally less than 25 s and optionally less than 20 s, equivalent hold time being calculated using equation
29. The process according to claim 28 wherein after the solution heat treatment and the quenching, a pre-ageing is optionally performed, and the sheet ages at ambient temperature, so as to attain temper T4, is cut out and formed until a final shape thereof is obtained, is painted and hardened by curing.
30. A sheet obtained according to the process according to claim 25, such that after solution heat treatment in a continuous heat treat furnace operating such that equivalent hold time at 560° C., t.sub.eq.sup.560°, is less than 20 s, equivalent hold time being calculated using equation Q being
Description
DESCRIPTION OF THE FIGURES
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DESCRIPTION OF THE INVENTION
[0073] All the aluminum alloys in question hereinafter are described, unless specified otherwise, according to the rules and descriptions defined by the “Aluminum Association” in the “Registration Record Series” published regularly thereby.
[0074] The tempers in question are described as per the European standard EN-515.
[0075] The tensile static mechanical characteristics are determined by means of a tensile test as per the standard NF EN ISO 6892-1.
[0076] Unless specified otherwise, the definitions of the standard EN 12258 apply.
[0077] Blank denotes herein an intermediate aluminum alloy product obtained by rolling a rolling ingot such as an ingot or a foundry slab, optionally scalped, optionally clad with one or more aluminum alloys, intended for manufacturing a finished product in the form of strip sheets or foils made of aluminum alloy, optionally clad with one or more aluminum alloys. A blank is therefore a rolled product, the thickness whereof is intermediate between the rolling ingot and the finished product.
[0078] Unless specified otherwise, the term “mill” refers herein to a “reversing mill”.
[0079] Unlike the prior art wherein either the productivity of reversing mills is increased by increasing the capacity of the mill in terms of rolling load and/or torque, or the productivity of the prior or subsequent steps are enhanced, the present inventors succeeded in enhancing the productivity of the reversing mills without using these solutions.
[0080] The present inventors particularly observed that given the hardness thereof, most aluminum alloys tend to overheat excessively at each stepover. It is then necessary to slow the mill by performing less substantial stepovers for example or by leaving a waiting time between each rolling pass.
[0081] According to the invention, it was observed that cooling the blank during the hot rolling step makes it possible to enhance the productivity of a hot mill or create more economical novel manufacturing processes by removing production steps, while retaining an identical or enhanced metallurgical quality of the products. Thus, cooling the blank during rolling on reversing mills can also surprisingly make it possible to give the finished rolled product additional physical properties, such as mechanical properties, surface condition or corrosion resistance.
[0082] The hot reversing mill according to the invention comprises two work rolls, a top work roll (21) and a bottom work roll (22), and at least one cooling system intended to cool a blank (11), said blank (11) moving on reels (23) and passing through the hot reversing mill between the two work rolls (21) and (22), said cooling system consisting of two cooling devices: a top cooling device of the blank (11) and a bottom cooling device of the blank (11). The numerous other parts and systems of the hot mill well-known to those skilled in the art, for example, non-restrictively, back up rolls, motors, columns, spindles, are not represented in the figures.
[0083] The top cooling device comprises at least one bar (30) of nozzles (35) disposed substantially parallel with the axis of the top work roll (21), the nozzles (35) spraying with jets of cooling fluid (36) the top face of the blank (11). The bottom cooling device comprises at least one bar (40) of nozzles (45) disposed between the reels (23) or between the bottom work roll (22) and the nearest reel (23), substantially parallel with the axis of the bottom work roll (22), the nozzles (45) spraying with jets of cooling fluid (46) the bottom face of the blank (11), the axis of the jets of cooling fluid (46) being oriented substantially perpendicularly to the bottom surface of the blank (11).
[0084]
[0085] The ends (112) correspond to the part of the blank (11) which is engaged first or which is disengaged last from the roll bite of the rolls (21) and (22). The ends (112) are represented in
[0086] For each cooling system, a top (52) respectively bottom (62) convex envelope is defined as the convex envelope of the surfaces (51) respectively (61) sprayed directly by the jets of cooling fluid (36) respectively (46) upon the first impact thereof on the blank (11). An example of convex envelope (52, 62) of the sprayed surfaces (51, 61) is illustrated by
[0087] As illustrated by
[0088] As illustrated by
[0089] As illustrated by
[0090] As illustrated by
[0091] For each cooling system, the zone opposite the mill (54) and the zone next to the mill (53) are surfaces which are part of a half-plane which contains the top convex envelope (52) of the blank (11) considered as the simplified parallelepiped in
[0092] For each cooling system, as illustrated in
[0093] For each cooling system, the zone next to the mill (53) is delimited by the line C1 and by the line D1 which is parallel with the line C1 and at the minimum distance D57 plus the radius R1 of roll (21) of the line C1.
[0094] The direction S is that of the movement of the blank (11).
[0095] According to
[0096] According to
[0097] In the embodiment illustrated in a non-limiting manner by
[0098] The embodiments illustrated in a non-limiting manner for example by
[0099] Preferentially, the bottom nozzles (45) produce jets of cooling fluid (46) which do not reach either the reels (23) or the roll (22) directly in the presence of the blank (11) and which are preferentially almost tangent to the reels (23) and the distance D67 whereof is preferentially greater than a radius of the bottom roll (22), more preferentially than the diameter of the bottom roll (22) and/or the top nozzles (35) produce jets of cooling fluid (36) which do not reach the top work roll (21) directly, preferentially the distance D57 is greater than the radius of the top roll (21), more preferentially the distance D57 is greater than the diameter of the top roll (21). In an embodiment illustrated by
[0100] Nozzles (24) illustrated in
[0101] Preferably, the bottom nozzles (45) are below the plane passing through the axes of rotation of the reels (23) located in the vicinity of said nozzles (45) and/or the bottom nozzles (45) are protected by a component (47) having openings to allow the jets of cooling fluid (46) to pass and/or the top nozzles (35) are protected by a component (37) having openings to allow the jets of cooling fluid (36) to pass. Protecting the nozzles (35) and (45) is advantageous as hot rolling can cause an opening of the ends (112) of the blank (11) called “crocodiling” by those skilled in the art and which strikes the nozzles. The blanks (11) can also during the hot rolling form bridges or boats, i.e. the blank (11) instead of being substantially planar can curve in the longitudinal direction on coming out of the mill, the ends of the blank (11) pointing upward or downward. Protecting the nozzles (35) and (45) from the blanks (11) is therefore advantageous to prevent damage of said nozzles. A non-limiting example of the components (37) and (47) protecting the nozzles (35) and (45) is illustrated in
[0102] Preferentially, each nozzle (35) and (45) is supplied individually by a rapid response valve (49) the response time whereof is advantageously less than 1 s, preferentially less than 0.5 s, and more preferentially less than 0.2 s.
[0103] In an embodiment, the nozzles (35) and (45) are suitable for producing jets of cooling fluid (36) and (46) in a flat and/or conical and/or cylindrical shape. If the shape of the jets is cylindrical, the cross-section of the roll is preferentially circular. In an embodiment, the nozzles (35) and (45) are suitable for producing jets of cooling fluid (36) and (46) by prilling, preferentially the nozzles (35) and (45) are suitable for producing jets of cooling fluid (36) and (46) by prilling, in a solid cone shape, referred to as conical jets. Conical jets (46) and (36) are a better configuration than flat or cylindrical jets. Indeed, conical jets enable a better distribution of the cooling fluid on the blank (11). This thus enables a more homogeneous heat exchange and it is thus possible to obtain a blank (11) with for example temperature heterogeneity of less than 20° C., preferentially of less than 10° C.
[0104] Preferentially, the conical jets of cooling fluid (46) have a cone angle of 90°. This angle can be limited, for example to 60°, by the presence of the reels (23) so as not to spray them in particular when the nozzles (45) are below the plane passing through the axes of rotation of the reels (23). If the reels (23) are very close, it can be preferable to place the nozzles (45) above the plane passing through the axes of the reels (23) to spray a larger surface area (61). In
[0105] Preferentially, for each cooling system, at least one device (38) for discharging the cooling fluid from the top surface of the blank (11) is installed above the blank. Non-limiting examples of this device (38) are given with
[0106] In an embodiment, the conical jets of the top cooling device (36) have a cone angle α of at most 20°, preferentially substantially 15° or less and the cones of said conical jets have a substantially vertical axis. This configuration makes it possible to limit the runoff of the cooling fluid onto the blank (11). Preferentially, the cooling system having at least one such conical jet is framed by a device for discharging the cooling fluid (38) as illustrated in a non-limiting manner by
[0107] In a further embodiment, the conical jets of the top cooling device (36) are inclined with respect to the vertical. The angle of inclination β is illustrated by
[0108]
[0109]
[0110]
[0111]
[0112] Preferentially, for each cooling system, the top sprayed convex envelope (52) is facing with a tolerance of twice preferentially once the dimension of the diameter of the top work roll (21) of the bottom sprayed convex envelope (62), preferentially said convex envelopes (52, 62) are substantially facing. The determination of the convex envelopes is conducted by separating the different cooling systems according to the invention.
[0113] Preferentially, all of the nozzles (35) and (46) are suitable for supplying a surface flow per face of the blank (11) of cooling fluid of 1500 I/min/m.sup.2 maximum, preferentially of 600 to 1200 I/min/m.sup.2. This fluid can be propelled by a propellant gas. The cooling fluid can be water, deionized water, an optionally liquefied gas, preferentially the emulsion of water, preferentially deionized, and oil and rolling additives, used for lubrication of the rolls (21) and (22) with the blank (11). Preferentially, the deionized water has a resistivity greater than 105 kΩcm.
[0114] In an embodiment, the nozzles of the top cooling device (35) are movable and maintained at constant distance from the top surface of the blank (11), preferentially while being attached to the mechanism maintaining the roll (21). This makes it possible to ensure a better repeatability of the cooling of the blank (11). In a further embodiment, the nozzles (35) are not movable. In this less costly non-movable embodiment, it is necessary hence to pilot the nozzles (35) spraying the edges (111) or in the vicinity of the edges (111) for example in the case where the nozzles (35) produce conical jets (36). Indeed, in the case of the conical jets (36) sprayed by fixed nozzles (35), the distribution of cooling fluid onto the edges (111) widens as the thickness of the blank decreases during successive passes of the hot reversing rolling diagram.
[0115] In a preferred embodiment, illustrated by way of non-limiting example in
[0116] In a preferred embodiment illustrated by the non-limiting example in
[0117] In a preferred embodiment illustrated by a non-limiting example of
[0118] In a further preferred embodiment illustrated by a non-limiting example in
[0119] In a further preferred embodiment represented schematically in a non-limiting manner in
[0120] In a further embodiment illustrated in a non-limiting manner by
[0121] The invention also relates to a process for hot rolling aluminum alloys comprising the successive steps of [0122] a. providing a rolling ingot made of optionally clad aluminum alloy at a hot rolling input temperature, [0123] b. carrying out a plurality of hot rolling and/or cooling passes with the reversing hot mill according to the invention, the cooling system serving at least once, [0124] c. transferring the blank (11) or the finished product in sheet or strip form at a hot rolling output temperature for the remainder of the hot fabrication process.
[0125] The minimum width of the blank (11) can typically take the values of 100 mm, 200 mm, 300 mm, 400 mm,500 mm, 700 mm, 800 mm, 900 mm, and 1000 mm. The maximum width of the blank (11) can typically take the values of 1500 mm, 2000 mm, 2500 mm, 3000 mm, 3500 mm, 4000 mm, 4500 mm, and 5000 mm.
[0126] The minimum thickness of the blank (11) can typically take the values of 5 mm, 6.35 mm, 10 mm, 12 mm, 12.7 mm, 15 mm, 20 mm, 30 mm, 40 mm, 50 mm, 60 mm, 70 mm, 80 mm, 90 mm 100 mm, 110 mm 120 mm, 130 mm, 150 mm, 200 mm, and 250 mm. The maximum width of the blank (11), which typically is similar to that of the cast ingot, can typically take the values of 300 mm, 350 mm, 400 mm, 450 mm, 500 mm, 550 mm, 600 mm, 650 mm, 700 mm, and 800 mm.
[0127] The minimum length of the blank (11) can typically take the values of 2 m, 3 m, 4 m, 5 m. The maximum length of the blank (11) can typically take the values of 6 m, 7 m, 8 m, 9 m 10 m, 15 m, 20 m, 30 m, 40 m, 50 m, 75 m, 100 m, 150 m, 200 m, 300 m, 400 m. Two constraints apply to limit the maximum length of the blank (11). The first is the quantity of metal of the rolling ingot before the start of hot rolling. The order of magnitude of the maximum length will be in this case the length of the ingot before the start of the hot rolling divided by the thickness of the blank at the end of the hot rolling multiplied by the thickness of the ingot before the start of the hot rolling. The second limitation of the length of the blank is dependent on the industrial installation wherein the hot mill is installed. By way of non-limiting example, if the industrial installation consists of a hot reversing mill followed by a hot mill in tandem or a second hot reversing mill, the maximum length is set by the distance between the reversing mill according to the invention and the tandem mill or the second hot reversing mill. This implies that all the configurations of lengths, thickness, before and after hot rolling listed above may not all be feasible according to the industrial installation.
[0128] The ingot is provided at a hot rolling input temperature. It may have been reheated and/or homogenized.
[0129] The hot reversing mill according to the invention carries out a plurality of hot rolling and/or cooling passes with the hot mill. There can therefore be cooling passes without rolling, therefore with no reduction of the thickness of the blank. This function is advantageous as it makes it possible to increase the cooling capacity of the cooling system if required. There can therefore be rolling passes without cooling, but the process according to the invention comprises at least one pass with a cooling with the cooling system according to the invention. The ingot being provided at the hot rolling input temperature, there is preferably no cooling before the first rolling pass. The operations such as cutting the ends, edge trimming, cutting the blank into several smaller blanks, placing the blank on standby, rotating the blank to change the orientation of the hot rolling of the blank (11) or the ingot are routine operations during hot rolling. The examples of the steps mentioned are not limiting. The presence of said routine operations is not an interruption of the hot rolling and does not limit the scope of the invention as they belong to routine hot rolling operations.
[0130] The blank is then transferred at a hot rolling output temperature of the reversing mill according to the invention. The hot rolling output temperature is preferably at least 200° C., preferably at least 220° C., preferably at least 240° C. and preferentially at least 260° C. This hot rolling output temperature is a compatible temperature for carrying out a second hot rolling. The blank (11) can be transferred to any routine step on a hot table: hot tandem mill, second hot reversing mill, hot coiling, or hot cutting to length.
[0131] Preferentially, the blank comprises an AA6xxx, AA5xxx, AA7xxx, AA3xxx, AA2xxx series aluminum alloy. Preferentially, the blank comprises an alloy chosen from AA3003, AA3004, AA3207, AA3104, AA4017, AA4025, AA5006, AA5052, AA5083, AA5086, AA5088, AA5154, AA5182, AA5251, AA5383, AA5754, AA5844, AA6005, AA6009, AA6013, AA6014, AA6016, AA6022, AA6056, AA6061, AA6111, AA6181, AA6216, AA6316, AA6451, AA6501, AA6502, AA6603, AA6605, AA6607, AA7072 AA7075, and an alloy of composition, as a % by weight, Si<0.5, preferably <0.3, Fe<0.7, preferably <0.3, Mn<1.9, preferably 1-1.5, Cu<1.5, preferably 0.5-1, preferably 0.5-0.8, Ti<0.15, preferably <0.1, Mg<0.5, preferably <0.3, preferably <0.05, the remainder aluminum and unavoidable impurities, 0.05 maximum each and 0.15 the total thereof. Optionally, the blank is clad on one or two faces, with one or more aluminum alloys of the AA1xxx, AA4xxx or AA7xxxx series, and preferentially AA4004, AA4104, AA4045, AA4343, AA7072.
[0132] Preferentially, the heterogeneity of the surface temperature of the blank (11) after the release thereof from the roll bite of the mill and the cooling device is less than 20° C. and preferentially less than 10° C. This feature, obtained thanks to the cooling system according to the invention, is useful for enhancing the repeatability of the metallurgical properties of the products. The heterogeneity of the blank (11) is defined as the difference between the temperature of the hottest point of the blank (11) with the temperature of the coldest point of the blank (11) except on the edges (111) and/or except on the ends (112) and alternatively as the difference between the temperature of the hottest point of the blank (11) with the temperature of the coldest point of the blank (11).
[0133] With a hot mill which is not equipped with the invention, the edges (111) are naturally colder than the rest of the blank (11) given the heat exchange surface area of the edge (1111). The bottom temperature of the edges (111) is a cause of tears or cracks on the edges which reduce the useful width of the blank or which can cause the fracture thereof. The edges (111) of the blank (11) are therefore preferentially cooled less than the rest of the blank by spraying the edges less than the rest of the blank (11). Preferentially, the nozzles (35) and (45) wherein the jets (36) and (46) could spray the edges (111) are closed so as not to spray said edges (111).
[0134] With a hot mill which is not equipped with the invention, the ends (112) are naturally colder than the rest of the blank (11) given the additional heat exchange surface area at the ends. The bottom temperature of the ends (112) is a cause of refusal of engagement of the blank during hot rolling. With a roll which is equipped with the invention, the ends (112) are therefore preferentially cooled less than the rest of the blank by spraying the ends (112) less than the rest of the blank (11). Preferentially, the nozzles (35) and (45) wherein the jets (36) and (46) could spray the ends (112) are closed during the passage of these ends. This function is preferentially feasible by the individual supply of each nozzle (35) and (45) by a rapid response valve (49) the response time whereof is advantageously less than 1 s, preferentially less than 0.5 s, and more preferentially less than 0.2 s. The rapid response valves (49) are illustrated by the non-limiting example of
[0135] The cooling fluid is preferentially in calefaction on the blank. Calefaction is a thin layer of vapor that appears between a fluid on a surface the temperature whereof is sufficiently high (Leidenfrost effect). This is advantageous as this ensures a homogeneous heat exchange with respect to the scenario where there are zones of the surface whereon the fluid is not in calefaction.
[0136] Preferentially, a thermal model calculates the spraying width and selects the cooling mode at the ends (112), preferentially the thermal model presets the hydraulic system which supplies the bars (30) and (40), then at each pass the thermal model compares the desired temperature with the calculated or measured temperature of the blank (11), and the thermal model controls the valves (49) of the nozzles (35) and (45) according to the position of the blank (11), preferentially the thermal model manages the top (35) and bottom (45) nozzles differently.
[0137] Preferentially, the control principle of the cooling system is as represented schematically in
[0138] The maximum level of temperature heterogeneity of the blank (11) desired with or without the edges (111) and/or the ends (112), the desired temperature are metallurgical choices dependent on the products to be produced. Preferentially, the control of the cooling system is integrated in the control system of the hot reversing mill which controls the rolling parameters.
[0139] Preferentially, the thermal device does not cool the surface of the blank (11) below the Leidenfrost temperature of the cooling fluid. The Leidenfrost temperature is the temperature above which the cooling fluid is in calefaction. The Leidenfrost temperature of the cooling liquid prilled on the blank is dependent on the nature of the cooling liquid and the surface flow thereof. The value of this temperature is typically and approximately about 300° C. for the typical cooling fluid, an emulsion and oil and rolling additives, which is less than the usual hot rolling temperatures on a reversing mill. The cooling system can cause substantial temperature heterogeneity between the surface and the core of the blank (11). By spraying the blank (11) for too long or too intensely, the surface temperature of the blank (11) is liable to be momentarily less than the Leidenfrost temperature, which would increase the risk of loss of thermal control in terms of mean value and homogeneity of the blank (11) cooled. The thermal model therefore checks at each pass that the spraying envisaged at the next pass is not at a risk of generating a blank temperature less than the Leidenfrost temperature.
[0140] Preferentially, the typical mean cooling rate V of the mean temperature of the blank (11) during the passage of the blank (11) between the top (52) and bottom (62) convex envelopes is of the order of V=C/e, where V is in ° C./s, e is the thickness of the blank in mm, and C is a constant value which equals between 400 and 1000° C./s*mm, preferentially between 600 and 900° C./s*mm, more preferentially between 700 and 800° C./s*mm. The formula V=C/e is an approximation which particularly requires that the surface of the blank (11) remain greater than the Leidenfrost temperature. The mean temperature decrease DT in degrees ° C. of the blank (11) after having traversed the top (52) and bottom (62) convex envelopes of the cooling system is typically of the order DT=C/e*d, d being the passage time of a point of the blank (11) between said convex envelopes, the speed of the blank (11) being constant. This formula is an approximation which particularly requires that the surface of the blank (11) remain greater than the Leidenfrost temperature. Preferentially, the thickness range of the blank (11) for the application of said formulas has a minimum of 25 mm, preferentially 50, preferentially 75 mm, preferentially 100 mm, preferentially 110 mm and has a maximum of 200 mm, preferentially 175 mm, preferentially 150 mm, preferentially 140 mm, preferentially 130 mm, preferentially 125 mm, preferentially 120 mm.
[0141] In a preferred embodiment, the hot rolling cycle time of a blank (11) made of AA6xxx alloy, preferentially of AA6016 alloy, is reduced by at least 30 seconds, preferentially at least 60 seconds, more preferentially at least 90 seconds with the process according to the invention, with respect to rolling without the assistance of said process. In a preferred embodiment, the hot rolling cycle time of a blank (11) made of AA5182 alloy is preferentially reduced by at least 15 seconds, preferentially 20 s, more preferentially 45 s, with respect to rolling without the assistance of said process. The cycle time is the time between the start of the first pass and the end of the final hot rolling pass with the hot reversing mill according to the invention.
[0142] In a further preferred embodiment, the cooling system is used preferentially once so as to reduce the mean temperature of the blank by at least 50° C. to a mean temperature greater than 400° C., in less than 10 seconds preferentially in less than 8 seconds for a blank (11) of a thickness of at most 114 mm.
[0143] In an embodiment, the cooling system makes it possible to control the temperature of the blank (11) on a predefined thermal path during the hot rolling. The thermal path is the progression of the temperature of the blank (11) for the duration of the hot rolling. The thermal path is a metallurgical choice dependent on the alloy, the desired properties of the finished product, and the capacities of the hot mill.
[0144] In a preferred embodiment, the cooling system makes it possible to control the blank (11) on an isothermal thermal path. A thermal path is isothermal if the temperature of the blank (11) during the hot rolling does not vary by plus or minus 10° C. with respect to the temperature of the ingot immediately prior to the start of hot rolling. Preferentially, the temperature of the blank (11) remains substantially equal to the temperature of the ingot before the start of hot rolling.
Detailed Description of Certain Embodiments
[0145] In a first embodiment illustrated by
[0146] In this first embodiment, there is preferentially a second cooling system on the other side of said hot reversing mill of which
[0147] This system is advantageous as it enables better control of the temperature of the blank during the reversing rolling thereof at each pass, which is beneficial for the metallurgical quality of the product and for the productivity of said reversing mill.
[0148] Further non-limiting examples of the first embodiment are given by
[0149] In the first preferred embodiment, the hot rolling cycle time of the blank (11) is preferentially reduced by at least 30 seconds for AA6xxx alloys, preferentially for AA6016 alloy, preferentially 60 s, more preferentially 90 s.
[0150] In the first preferred embodiment, the hot rolling cycle time of a blank (11) is preferentially reduced by at least 15 seconds for AA5182 alloy, preferentially 20 s, more preferentially 45 s.
[0151] A second embodiment is a cooling system suitable for rapidly cooling a blank (11) during a hot rolling.
[0152] This embodiment is designed to spray each point of the blank (11) for 10 s, preferentially 8 seconds. Those skilled in the art will be able to adapt the features hereinafter to their specific mill and to the speed of the blank (11).
[0153] In a preferred embodiment of the second preferred embodiment, illustrated in a non-limiting manner by
[0154] In a further preferred embodiment of the second preferred embodiment, illustrated in a non-limiting manner by
[0155] In the second preferred embodiment, the cooling system is used preferentially once so as to reduce the mean temperature of the blank (11) by at least 50° C. to a mean temperature greater than 400° C., in less than 10 seconds preferentially in less than 8 seconds for a blank (11) of a thickness of at most 114 mm as shown in
[0156] In a further embodiment, it is possible to cool the blank (11) more for example by carrying out two passages under the cooling system.
[0157] In a further embodiment, it is possible to cool a thicker blank by 50° C. by reducing the passage speed of the blank (11) or by increasing the length of the sprayed surfaces (51) and (61). By way of non-limiting example, a 140 mm blank (11) can be cooled by 50° C. in at least 15 seconds, preferentially at least 10 seconds as shown in
[0158] In a further embodiment, the typical mean cooling rate V of the mean temperature of the blank (11) during the passage of the blank (11) between the top (52) and bottom (62) convex envelopes is of the order of V=C/e, where V is in ° C./s, e is the thickness of the blank in mm, and C is a constant value which equals between 400 and 1000, preferentially between 600 and 900, more preferentially between 700 and 800. The formula V=C/e is an approximation which particularly requires that the surface of the blank (11) remain greater than the Leidenfrost temperature. The mean temperature decrease DT in degrees ° C. of the blank (11) after having traversed the top (52) and bottom (62) convex envelopes of the cooling system is typically of the order DT=C/e*d, d being the passage time of a point of the blank (11) between said convex envelopes, the speed of the blank (11) being constant. This formula is an approximation which particularly requires that the surface of the blank (11) remain greater than the Leidenfrost temperature. Preferentially, the thickness range of the blank (11) for the application of said formulas has a minimum of 25 mm, preferentially 50, preferentially 75 mm, preferentially 100 mm, preferentially 110 mm and has a maximum of 200 mm, preferentially 175 mm, preferentially 150 mm, preferentially 140 mm, preferentially 130 mm, preferentially 125 mm, preferentially 120 mm.
[0159] A third preferred embodiment is a process for hot rolling an AA6xxx series aluminum alloy comprising the steps of: [0160] a. casting a rolling ingot made of AA6xxx series alloy, [0161] b. homogenizing the rolling ingot, optionally followed by a reheating, [0162] c. first hot rolling to convert the rolling ingot into a blank having a first output thickness from a first hot rolling starting temperature, [0163] d. cooling the blank obtained with a typical mean cooling rate of the mean temperature of the blank of the order of V=C/e up to a second starting temperature of second hot rolling, where V is in ° C./s, e is the thickness of the blank in mm, and C is a constant which equals between 400 and 1000° C./s*mm, preferentially between 600 and 900° C./s*mm, more preferentially between 700 and 800° C./s*mm, [0164] e. second hot rolling to convert the blank obtained into a strip at the final hot rolling thickness under deformation and temperature conditions such that the strip is recrystallized to at least 50%, [0165] f. cold rolling the strip into a sheet.
[0166] The first hot rolling and the cooling are performed preferably with a hot reversing mill according to the invention. During the cooling of step d, the cooling system is preferentially used once so as to reduce preferentially the mean temperature with a typical mean cooling rate of the mean temperature of the blank by at least 50° C. to a mean temperature greater than 400° C. Preferentially, the thickness range of the blank during this cooling has a minimum of 25 mm, preferentially 50, preferentially 75 mm, preferentially 100 mm, preferentially 110 mm and has a maximum of 200 mm, preferentially 175 mm, preferentially 150 mm, preferentially 140 mm, preferentially 130 mm, preferentially 125 mm, preferentially 120 mm.
[0167] In an embodiment of the third preferred embodiment, during the cooling of step d, the cooling system is used preferentially once so as to reduce the mean temperature of the blank by at least 50° C. to a mean temperature greater than 400° C., in less than 10 seconds preferentially in less than 8 seconds for a blank (11) of a thickness of at most 114 mm.
[0168] The inventors discovered surprisingly that this process makes it possible to enhance productivity while retaining mechanical, surface quality and corrosion resistance properties at least equal to those obtained without the process according to the invention. These products can be particularly useful in the automotive industry in particular for producing external car body components.
[0169] In the third preferred embodiment, among the AA6xxx series alloys, the preferred alloys are AA6005, AA6009, AA6013, AA6014, AA6016, AA6022, AA6056, AA6061, AA6111, AA6181, AA6216, AA6316, AA6451, AA6501, AA6502, AA6603, AA6605, AA6607.
[0170] In an embodiment of the third preferred embodiment, the composition of the AA6xxx series alloy ingot is an alloy comprising as a % by weight: Si: 0.5-0.8; Mg: 0.3-0.8; Cu: maximum 0.3; Mn: maximum 0.3; Fe maximum 0.5; Ti: maximum 0.15, the remainder aluminum and unavoidable impurities 0.05 maximum each and 0.15 the total thereof, and preferably Si: 0.6-0.75; Mg: 0.5-0.6; Cu: maximum 0.1; Mn maximum 0.1; Fe 0.1-0.25; Ti: maximum 0.05, the remainder aluminum and unavoidable impurities 0.05 maximum each and 0.15 the total thereof.
[0171] In a further embodiment of the third preferred embodiment, the composition of the AA6xxx series alloy ingot is an alloy comprising as a % by weight: Si 0.7-1.3; Mg: 0.1-0.8; Cu: maximum 0.3; Mn: maximum 0.3; Fe maximum 0.5; Ti: maximum 0.15, the remainder aluminum and unavoidable impurities 0.05 maximum each and 0.15 the total thereof, and preferably Si: 0.8-1.1; Mg: 0.2-0.6; Cu: maximum 0.1; Mn maximum 0.2; Fe 0.1-0.4; Ti: maximum 0.1, the remainder aluminum and inevitable impurities 0.05 maximum each and 0.15 the total thereof.
[0172] After casting, the ingot is preferentially homogenized at a temperature between 500 and 570° C., and preferably between 540 and 560° C. typically for a time of at least 4 hours, and preferably for at least 8 hours. In a preferred embodiment, the maximum homogenizing temperature is at most 555° C. The homogenizing can be in one step or in several steps with increasing temperatures to reduce the risk of incipient melting.
[0173] In the third preferred embodiment, the ingot is then rolled into a blank during a first hot rolling on a reversing mill. The rolling starting temperature of the first hot rolling is preferentially greater than 470° C., more preferably above 490° C., and even more preferably above 500° C. Preferably, during this first hot rolling, the temperature is maintained above 450° C., preferably above 470° C. and more preferably above 490° C. Preferably, the first output thickness is between 90 mm and 140 mm, preferentially between 100 and 130 mm, and more preferentially between 110 mm and 120 mm.
[0174] This blank thickness is particularly advantageous in factories wherein the hot rolling table consists successively of two hot reversing mills and optionally a hot tandem mill. Indeed, this blank thickness corresponds to the thickness of the blank during the transfer thereof between the first reversing mill and the second reversing mill. Cooling can then be carried out without losing any time.
[0175] The blank is then cooled according to a cooling rate of at least 5° C./s from the mean blank temperature to a second starting temperature of second hot rolling. Advantageously, the first hot rolling and the cooling are performed with a hot reversing mill according to the invention, as illustrated particularly by
[0176] After cooling, the blank is rolled with a second hot mill into a strip. The second hot rolling can be carried out successively on several hot mills, for example a second hot reversing mill followed by a tandem mill or on the hot reversing mill having been used for the first hot rolling followed by a tandem mill. Preferably, the starting temperature of the second hot rolling is between 380 and 450° C., more preferably between 400 and 440° C., and more preferably between 420 and 435° C. The strip is rolled to a final hot rolling thickness under conditions such that the strip after cooling is recrystallized to at least 50%, preferably at least 80%, and more preferably at least 90%, and particularly preferentially at least 98%. A recrystallization of at least respectively 50%, 80%, 90% and 98% means that the recrystallization rate measured through the thickness and in at least 3 points of the width is respectively at least 50%, 80%, 90% and 98%. Typically, the recrystallization varies through the thickness and can be complete on the surface and incomplete at mid-thickness. The preferred recrystallization rate is dependent on the alloy of the strip.
[0177] To obtain said recrystallization, it is advantageous that the output temperature of the second hot rolling be at least 345° C., preferably at least 350° C. and more preferentially at least 355° C. The reduction in thickness during the final pass of the second rolling is a parameter to ensure recrystallization. Said reduction of the final pass of the second hot rolling is at least 25%, preferentially at least 30%, preferentially 40%, and more preferentially at least 45%. The typical thickness of the strip obtained with the second hot rolling is between 4 and 10 mm.
[0178] The strip is then cold rolled into a sheet. With the method according to the invention, it is not necessary to perform an annealing and/or a solution heat treatment between the hot rolling and the cold rolling or during cold rolling to obtain mechanical, formability, surface condition or corrosion properties. Preferably, an annealing and/or a solution heat treatment is not carried out between the hot rolling and the cold rolling or during cold rolling. The sheet has a thickness typically between 0.5 and 2 mm. In a preferred embodiment, the reduction by cold rolling is between 70% and 80%. In a further preferred embodiment, the reduction rate between the strip and the sheet is at least 80% to obtain the most advantageous surface quality.
[0179] Preferentially, after step f, an additional step can be carried out [0180] g: solution heat treatment and quenching of the sheet thus obtained in a continuous heat treat furnace.
[0181] Said continuous heat treat furnace operates preferentially such that the equivalent hold time at 560° C., t.sub.eq.sup.560° less than 30 s, preferably less than 25 s and more preferably less than 20 s, the equivalent hold time being calculated using the equation
[0182] Q being an activation energy of 200 kJ/mol and R=8.314 J/mol/K
[0183] Preferentially, after the solution heat treatment and the quenching, a pre-ageing is optionally performed, and the sheet ages at ambient temperature, so as to attain the temper T4, is cut out and formed until the final shape thereof is obtained, is painted, and hardened by curing
[0184] The sheet, after solution heat treatment in a continuous heat treat furnace operating such that the equivalent hold time at 560° C., t.sub.eq.sup.560°, is less than 20 s, the equivalent hold time being calculated using the equation
[0185] Q being an activation energy of 200 kJ/mol and R=8.314 J/mol/K,
[0186] attains a tensile strength of at least 90% and preferably at least 95% of the maximum tensile strength obtained after solution heat treatment with an equivalent hold time at 560° C., t.sub.eq.sup.560°, of 98 s.
[0187] The sheet obtained from the cold rolling is particularly advantageous if only because it is easy to treat by solution heat treatment. Conventional procedures aimed at obtaining a satisfactory surface condition, compatible with a quality for external car body sheets, generally include an additional heat treatment during the fabrication procedure with respect to the sheet obtained according to the invention. The presence of this additional heat treatment means that those skilled in the art need to use high temperatures and substantial equivalent hold times on the solution heat treatment lines with continuous annealing in order to obtain sufficiently high mechanical strengths in the tempers as supplied and after curing the paints. On the contrary, the cold-rolled sheet according to the invention can use a solution heat treatment in a continuous annealing line operating such that the equivalent hold time at 560° C., t.sub.eq.sup.560°, is short, typically less than 25 s, the equivalent hold time being calculated using the equation
[0188] Q being an activation energy of 200 kJ/mol and R=8.314 J/mol/K.
[0189] Generally, the continuous annealing line operates such that the heating rate of the sheet is greater than or equal to 10° C./s for a metal temperature less than 400° C., the time spent at over 530° C. is between 15 s and 90 s, and the quench rate is greater than or equal to 10° C./s, preferably greater than or equal to 15° C./s for a thickness of 0.9 to 1.1 mm. The solution heat treatment ensures that the metal reaches a temperature below but close to the solidus temperature, that is to say generally greater than 530° C. and less than 570° C. The coiling temperature after the solution heat treatment is preferably between 50° C. and 90° C., and preferably between 60° C. and 80° C.
[0190] After the solution heat treatment and the quenching, the sheet can age so as to attain the temper T4, before being cut out and formed until the final geometry thereof is obtained, painted, and hardened by curing.
[0191] The process according to the invention is particularly useful for manufacturing sheets intended for the automotive industry which combine a high tensile yield strength and a formability suitable for cold drawing operations, as well as an excellent component surface quality and a high corrosion resistance with a high productivity.
[0192] In a fourth preferred embodiment, the hot mill combines the first preferred embodiment and the second embodiment.
[0193] A non-limiting example is given in
EXAMPLES
Example 1
[0194] A hot reversing mill according to the invention illustrated by
[0195] A 500 mm thick ingot was hot-rolled with a cooling according to the invention at each hot rolling pass.
[0196] An identical ingot of the same alloy was also hot-rolled but without the use of a cooling system according to the invention.
[0197] In addition to the noteworthy improvement of the thermal uniformity of the blank using the invention with respect to practice without using the invention, the cooling of the blank during the rolling procedure makes it possible to reduce the hot reversing rolling cycle time by 90 seconds.
[0198] Two ingots made of AA5182 alloy, 1480 mm wide and 510 mm thick, were hot-rolled with the invention, the first with the invention and the second without the invention. The hot rolling cycle time of the first ingot was 64 s shorter compared to the second.
Example 2
[0199] A hot mill according to the invention comprising work rolls (21, 22) and a cooling system having six top bars (30) of nozzles (35) and eight bottom bars (40) of nozzles (45) is represented in
[0200] The system is capable of cooling a 114 mm thick sheet from a temperature of 470° C. to a mean temperature of 420° C. in 8 seconds as shown on the graph in
TABLE-US-00001 TABLE 1 D E Example D Example E A B C according according to Reference Reference Reference to the the example A example B example C invention- invention- Composition (% by weight) Si 0.66 0.67 0.70 0.69 0.69 Fe 0.14 0.15 0.14 0.15 0.15 Cu 0.01 0.01 0.01 0.01 0.01 Mn 0.08 0.07 0.09 0.07 0.07 Mg 0.64 0.64 0.52 0.54 0.56 Cr 0.01 0.01 0.01 0.01 0.01 Ti 0.03 0.04 0.05 0.05 0.04 Ingot heat treatment homogenizing 6.5 h 554° C. 6.7 h 554° C. 30 h 554° C. 20 h 554° C. 16 h 554° C. cooling N/A N/A ambient N/A N/A temperature reheating N/A N/A at rolling N/A N/A temperature First hot rolling rolling starting 554 553 393 511 537 temperature (° C.) Final thickness (mm) 114 114 114 114 109 rolling end 524 523 360 481 507 temperature (° C.) cooling cooling rate N/A N/A N/A 5° C./s 5° C./s second hot rolling rolling starting 519 519 356 424 432 temperature (° C.) Final hot rolling 3.05 3.05 6.35 5.08 5.08 thickness (mm) reduction at final hot pass 41% 39% 44% 47% 47% coiling temperature (° C.) 332 327 343 352 357 Cold roll cold reduction (%) 73.7 73.8 85.0 81.3 81.3 final thickness (mm) 0.8 0.8 0.95 0.95 0.95
[0201] Five ingots, the compositions whereof are given in table 1 as a % by weight, were cast. Table 1 also details the fabrication process. Columns A and B describe an ingot and the fabrication steps thereof into a blank then into a strip then into a sheet to produce internal car body elements which have no requirements in terms of surface quality. Column C describes an ingot and the typical fabrication steps thereof into a blank then into a strip then into a sheet to produce external car body elements which have substantial requirements in terms of surface quality. These are reference examples wherein cooling is not carried out during the hot rolling. Columns D and E are examples of the invention.
[0202] The 5 ingots A, B C D and E were homogenized with the conditions of table 1. Ingots A, B, D and E were transferred to the first hot reversing rolling. Ingot C was cooled to ambient temperature then reheated to the starting temperature of the first hot rolling and transferred to the first hot reversing rolling. The 5 ingots were hot-rolled by the first hot mill into a 114 mm thick blank except ingot E which was rolled into a 109 mm thick blank. The 5 blanks were then transferred to the second hot reversing mill through the cooling system of the first hot mill. Blanks A, B and C passed through the cooling system without being sprayed, and only underwent natural air cooling during the transfer thereof to the second hot reversing mill. Blanks D and E passed through the cooling system in operation and were therefore cooled to the surface temperature indicated in table 1. The 5 blanks were then rolled with the second hot reversing mill, then with a hot tandem mill into a strip. On leaving the hot tandem mill, the strips were coiled according to the characteristics in table 1. After cooling, the 5 coils were cold-rolled into sheets.
[0203] Samples from strips C, D and E were taken after the final hot rolling pass and before coiling. These samples were cooled quickly by immersing them in a water tank at ambient temperature. Then recrystallization kinetics were carried out in a laboratory by heating each sample to different temperatures, then the samples are cooled similarly to the cooling of a coil after hot rolling. Metallographs were then produced (
TABLE-US-00002 TABLE 2 Heating temperature 310° C. 321° C. 332° C. 343° C. 355° C. 365° C. C Ref 0% 75% 98% 100% 100% 100% example D invention 0% 15% 33% 44% 95% 100% E invention 0% 6% 43% 94% 99% 100%
[0204] The roping surface condition quality was characterized on sheets A, B, D and E. The roping is measured as follows. A sample measuring about 270 mm (in the transversal direction to the rolling direction) by 50 mm (in the rolling direction) is cut out from the sheet. A tensile pre-deformation of 15%, perpendicular to the rolling direction, i.e. in the direction of the length of the sample, is then applied. The sample is then subjected to the action of a P800 type sandpaper in order to reveal the roping.
[0205] Sheets D and E, produced according to the invention, have a compliant surface quality for producing external car body elements as shown in
[0206] To evaluate the solution heat treatment kinetics of the 3 sheets C, D and E, the following characterizations were conducted. Samples were taken after cold rolling to the final thickness on the 3 sheets C, D and E. Various solution heat treatments were first performed on the samples by varying the solution heat treatment times of the samples in a fluidized bed furnace at 570° C. A long immersion period of 90 s at 570° C. was used for the complete solution heat treatment of the samples. The time of 90 s at 570° C. is equivalent to a time of 98 s at 560° C. using the formula
[0207] Q being an activation energy of 200 kJ/mol and R=8.314 J/mol/K.
[0208] Shorter solution heat treatment times in the fluidized bed furnace at 570° C. were used to obtain an incomplete solution heat treatment of the alloys. These solution heat treatments were all followed by a water quenching to 80° C. and a pre-ageing treatment of 8 hours at 80° C. After these different solution heat treatments, followed by quenching then pre-ageing, the samples were annealed for 2 hours at 205° C. in an oil bath in order to attain the temper T6.
[0209] Tensile tests were then performed. The yield strength (Rp0.2) obtained after the final annealing treatment in the temper T6 is used an indicator of the solution heat treatment quality of the samples. Indeed, according to the precipitation state existing in the sheets, the solution heat treatment time at the solution heat treatment temperature (herein 570° C.) required to dissolve these precipitates varies. For productivity reasons on the production machines carrying out the solution heat treatment, it is advantageous that the solution heat treatment time be as short as possible.
[0210] The results of the tensile tests of the 3 sheets C, D and E are indicated in table 3 and in
[0211]
TABLE-US-00003 TABLE 3 Yield strength in temper T6 divided by Immersion time in the maximum yield fluidized bed (s) yield strength strength in temper T6 at 570° C. (T6YS − MPa) (T6YS/T6YS max) D invention 1 10 143 0.52 D invention 1 20 264 0.96 D invention 1 30 271 0.98 D invention 1 50 275 1.00 D invention 1 90 276 1.00 E Invention 2 10 134 0.49 E Invention 2 20 262 0.96 E Invention 2 30 271 0.99 E Invention 2 50 274 1.00 E Invention 2 90 274 1.00 C ref example 3 30 264 0.96 C ref example 3 50 271 0.98 C ref example 3 90 275 1.00