PROTECTIVE TUBE, TEMPERATURE MEASUREMENT ARRANGEMENTS AND METHODS FOR TEMPERATURE MEASUREMENTS IN A PROCESS VESSEL
20230016861 · 2023-01-19
Assignee
Inventors
Cpc classification
G01K1/026
PHYSICS
G01K7/026
PHYSICS
G01K1/14
PHYSICS
G01K13/02
PHYSICS
International classification
Abstract
A protective tube for sealed introduction into a process vessel at a process vessel port, the protective tube comprising a sealing base element which is connected onto the process vessel port and an elongate body with a bore. The elongate body comprises a closed distal end and an open proximal end, which is sealingly connected onto the sealing base element. The protective tube also comprises a receiving part, which is connected or attached onto the elongate body inside the process vessel so as to receive and hold a secondary temperature sensor from inside the process vessel. In addition, a reference temperature sensor is insertable into the bore from outside the process vessel. Also provided is a temperature measurement arrangement and a method for a temperature measurement in a process vessel.
Claims
1. A protective tube for sealed introduction into a process vessel at a process vessel port, the protective tube comprising: a sealing base element adapted to connect onto the process vessel port; an elongate body having a bore, the bore comprising a closed distal end and an open proximal end, which is sealingly connected onto the sealing base element, wherein a reference temperature sensor is insertable into the bore and extractable from the bore from outside the process vessel; and a receiving member that is adapted to be connected or attached onto the elongate body inside the process vessel, the receiving member being adapted to receive and hold a secondary temperature sensor from inside the process vessel.
2. The protective tube according to claim 1, wherein characterized in that the reference temperature sensor is a high-accuracy temperature sensor and/or the accuracy of the reference temperature sensor is higher than the accuracy of the secondary temperature sensor and/or the reference temperature sensor is of a different kind from the secondary temperature sensor.
3. The protective tube according to claim 1, wherein the receiving member comprises a tubular body with a bore and an open first end, wherein the secondary temperature sensor is inserted into the bore through the open first end, and/or the receiving member is oriented substantially in parallel to a longitudinal axis of the elongate body or substantially perpendicular to the longitudinal axis of the elongate body, and/or the receiving member is connected onto the elongate body at a lateral surface of the elongate body or at the closed distal end.
4. The protective tube according to claim 1, wherein the receiving member and/or the closed distal end at least partially comprise a material with high thermal conductivity.
5. The protective tube according to claim 1, wherein the receiving member is set up to receive at least two secondary temperature sensors and/or at least a second receiving member is attached or connected onto the elongate body inside the process vessel for receiving and holding at least another secondary temperature sensor.
6. The protective tube according to claim 1, wherein the open proximal end of the elongate body is sealingly closeable from outside of the process vessel, and/or the bore is in fluid communication with a pressure gauge or pressure sensor for monitoring the internal pressure inside the bore, and/or a gas analyzer for monitoring the composition of the air inside the bore, and/or an inert gas purging arrangement for purging the air inside the bore.
7. A temperature sensor arrangement for temperature measurements within a process vessel, the process vessel comprising at least two process vessel ports at different locations of the process vessel, wherein at or through each process vessel port a temperature sensor assembly is inserted into the process vessel, wherein each temperature sensor assembly comprises at least one primary temperature sensor, which is positioned at a measurement location within the process vessel, wherein at least one of the temperature sensor assemblies comprises at least one secondary temperature sensor, wherein each of the secondary temperature sensors of that temperature sensor assembly is positioned close to the measurement location of one of the primary temperature sensors from a different one of the temperature sensor assemblies, or close to a reference location of one of the secondary temperature sensors from a different one of the temperature sensor assemblies.
8. The temperature sensor arrangement according to claim 7, wherein at least one of the secondary temperature sensors of one of the temperature sensor assemblies is in direct mechanical contact with the primary temperature sensor or the secondary temperature sensor from a different one of the temperature sensor assemblies, that it is positioned close to.
9. The temperature sensor arrangement according to claim 7, further comprising a protective tube comprising: a sealing base element, which connects onto the process vessel port; and an elongate body with a bore, the elongate body comprising a closed distal end, and an open proximal end that is sealingly connected onto the sealing base element, wherein a reference temperature sensor is adapted to be insertable into the bore and extractable from the bore from outside the process vessel, wherein a receiving member, which is connected or attached onto the elongate body inside the process vessel, is adapted to receive and hold a secondary temperature sensor from inside the process vessel, wherein at or through a first temperature sensor connection the protective tube is inserted into the process vessel, wherein at or through the first temperature sensor connection or at or through at least one other temperature sensor connection a temperature sensor assembly is inserted into the process vessel, wherein each temperature sensor assembly comprises at least one primary temperature sensor that is positioned at a measurement location inside the process vessel, wherein at least one of the temperature sensor assemblies comprises at least one secondary temperature sensor, wherein the at least one secondary temperature sensor is routed inside the process vessel to reach the receiving member of the protective tube, and wherein the receiving member receives and holds the secondary temperature sensor close to the reference temperature sensor inside the bore of the protective tube.
10. The temperature sensor arrangement according to claim 9, wherein the protective tube is arranged in and introduced into the process vessel through the same one of the process vessel ports, where also one of the temperature sensor assemblies is inserted into the process vessel, and wherein a short primary temperature sensor of that temperature sensor assembly is received and held by the receiving member of the protective tube.
11. The temperature sensor arrangement according to claim 7, wherein at least one temperature sensor assembly comprises a sheathed single-point thermocouple temperature sensor, wherein a thermocouple junction within the sheath forms one of the primary temperature sensors or one of the secondary temperature sensors and/or at least one temperature sensor assembly comprises a sheathed multi-point thermocouple temperature sensor with a sheath, and wherein a series of thermocouple junctions within the sheath are arranged and distributed over a length of the sheath and form a series of the primary temperature sensors or a series of the secondary temperature sensors.
12. The temperature sensor arrangement according to claim 7, wherein at least one temperature sensor assembly comprises a bundle of at least two sheathed thermocouple temperature sensors and/or at least one temperature sensor assembly comprises at least two primary temperature sensors which are arranged at different measurement locations, and wherein the measurement locations are arranged and distributed along a line essentially parallel or essentially perpendicular to a longitudinal axis of the process vessel or the measurement locations are distributed within a plane that is arranged essentially perpendicular to the longitudinal axis of the process vessel.
13. The temperature sensor arrangement according to claim 7, wherein the primary temperature sensors and/or the secondary temperature sensors of one of the temperature sensor assemblies are of a different type than the primary temperature sensors and/or the secondary temperature sensors of one of the other temperature sensor assemblies.
14. A method for temperature measurements within a process vessel with a temperature measurement arrangement according to claim 7, the method comprising: taking measurement values of primary temperature sensors and secondary temperature sensors within the process vessel; determining a measurement value difference of primary temperature sensors and secondary temperature sensors of different temperature sensor assemblies that are positioned close to each other at certain measurement locations or of secondary temperature sensors of different temperature sensor assemblies that are positioned close to each other at certain reference locations; storing the determined measurement value differences as reference values; repeating, at a later point in time, the steps of taking the measurement values and determining a measurement value difference; and comparing the newly determined measurement value differences to the initially stored reference values to detect a discrepancy in measurement values and/or sensor condition.
15. Method for temperature measurements within a process vessel, the process vessel comprising at least two process vessel ports at different locations, the method comprising: inserting a temperature sensor assembly at or through each process vessel port into the process vessel, each temperature sensor assembly comprising at least one primary temperature sensor; positioning each primary temperature sensor at a measurement location inside the process vessel, at least one of the temperature sensor assemblies comprising at least one secondary temperature sensor; positioning each secondary temperature sensor of that temperature sensor assembly close to the measurement location of one of the primary temperature sensors from a different one of the temperature sensor assemblies or close to a reference measurement location of one of the secondary temperature sensors from a different one of the temperature sensor assemblies; taking measurement values of primary temperature sensors and secondary temperature sensors within the process vessel; determining a measurement value difference of primary temperature sensors and secondary temperature sensors of different temperature sensor assemblies that are positioned close to each other at certain measurement locations or of secondary temperature sensors of different temperature sensor assemblies that are positioned close to each other at certain reference locations to detect measurement value discrepancies of individual temperature sensors and/or individual temperature sensor assemblies; inserting a standard temperature sensor with a known accuracy into a protective tube inserted into the process vessel as a primary temperature sensor without interrupting the process in the process vessel, at the same time recording measurement values of that primary temperature sensor and one or more secondary temperature sensors located at the same or adjacent location; and comparing the measurement values of the primary temperature sensor and the one or more secondary temperature sensors to determine measurement errors of the secondary temperature sensors.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0046] The present invention will become more fully understood from the detailed description given hereinbelow and the accompanying drawings which are given by way of illustration only, and thus, are not limitive of the present invention, and wherein:
[0047]
[0048]
[0049]
[0050]
[0051]
[0052]
DETAILED DESCRIPTION
[0053]
[0054] The temperature sensor assemblies 400, 400′ respectively comprise a secondary temperature sensor 601, 602, 601′ and 602′. The secondary temperature sensors 601, 602, 601′, 602′ of each temperature sensor assembly 400, 400′ are positioned close to the measurement location 901, 902, 903, 901′, 902′, 903′ of one of the primary temperature sensors of a different one of the temperature sensor assemblies 400, 400′, or positioned close to a reference location 1001, 1001′ of one of the secondary temperature sensors of a different one of the temperature sensor assemblies 400, 400′.
[0055] As shown in
[0056] In this arrangement, the secondary temperature sensors are fixed close to the primary or secondary temperature sensor from another adjacent temperature sensor assembly within the process vessel 200. This arrangement can also be referred to as “cross installation” in this application. An advantage of this arrangement is that the installation of such redundant sensors is more reliable, because when one primary temperature sensor is damaged, the nearby secondary temperature sensors thereof can still work. Furthermore, measurement values of primary and/or secondary sensors from different sensor assemblies, that are positioned close to each other, can be compared to detect signs of measurement value discrepancies, aging, signal drift and/or failure or one of the sensors.
[0057] Preferably, at least one secondary temperature sensor of one temperature sensor assembly is in direct mechanical contact with the primary temperature sensor or the secondary temperature sensor of another temperature sensor assembly. This further improves the advantage above, because the two temperature sensors will experience almost the same temperature.
[0058]
[0059] The protective tube 700 comprises a sealing base element 701 connected onto the process vessel port 300′″ and an elongate body 702 with a bore 703. The elongate body is preferably a thermowell. The elongate body 702 comprises a closed distal end 704 and an open proximal end 705, which is sealingly connected onto the sealing base element 701. Therefore, this bore 703 or an internal volume is accessible from the outside of the process vessel 200 through an opening 705 in the sealing base element 701.
[0060] A reference temperature sensor 800 is insertable into the bore 703 from the outside of the process vessel 200. Similarly, the reference temperature sensor 800 is also extractable from the protective tube 700 from the outside of the process vessel 200, and such insertion and extraction need not stop or shutdown of the process in the process vessel 200.
[0061] The protective tube 700 also comprises one or more receiving members 706 which is/are connected or attached onto the elongate body 702 inside the process vessel 200 so as to receive and hold the secondary temperature sensors (referring to
[0062] Preferably, the reference temperature sensor 800 is a high-accuracy temperature sensor. Preferably, the accuracy of the reference temperature sensor is higher than that of the secondary temperature sensor 601, 601′. Preferably, the reference temperature sensor 800 is of a different type from the secondary temperature sensors 601, 601′. Said different type means that if the secondary temperature sensor 601, 601′ is a thermocouple sensor, the reference temperature sensor 800 can be a different type of thermocouple sensors (for example, K, J, N, T type), or they belong to different types of sensors, for example one is a thermocouple sensor and the other one is resistance temperature sensor, for example, a Pt100 temperature sensor.
[0063] The receiving member 706 comprises a tubular body with a bore and an open first end. The secondary temperature sensors 601 and 601′ are insertable into the bore through the open first end. This means that due to the arrangement and function of the receiving member 706, in contrast to the reference temperature sensor 800, the secondary temperature sensors can at least partially operate inside the process vessel 200 before reaching and completely entering the receiving member 706.
[0064] The other end of the tubular body can be closed or open. In the case of an open end, a temperature sensor for measurement may protrude from the open second end (referring to
[0065] However, it is preferable that the second end is closed, so that a sensor element of the temperature sensor for measurement can be surrounded by the receiving member 706. In this way, good thermal conductivity, mechanical protection and temperature stability between the temperature sensor for measurement and the reference temperature sensor can be realized through heat transfer characteristics of the receiving member and the protective tube.
[0066] Other details and examples of the receiving member will be further described later.
[0067]
[0068] In this embodiment, a sealing base element 701 is preferably a flange element. Correspondingly, a process vessel port can be a flange connection. Primary temperature sensors 501, 502 and 503 of a temperature sensor assembly 400 extend into the process vessel through the sealing base element 701. This means that the temperature sensor assembly 400 and a protective tube 700 are inserted into the process vessel from the same process vessel port.
[0069] An open proximal end 705 of the protective tube 700 is sealingly connected onto the sealing base element 701. A reference temperature sensor 800 is inserted from the open proximal end 705 of the protective tube 700 via a bore 703.
[0070] A receiving member 706 is oriented parallel to a longitudinal axis of the elongate body 702 of the protective tube 700 and is connected onto the elongate body 702 at a closed distal end 704 of the elongate body 702 of the protective tube 700.
[0071] A short primary temperature sensor 504 of the temperature sensor assembly 400 is received and held by the receiving member 706 of the protective tube 700 and is close to the reference temperature sensor 800 within the bore of the protective tube 700.
[0072] In an example, the receiving member 706 may at least partially comprise a material with high thermal conductivity. It is also possible that the closed distal end 704 also at least partially comprises a material with thermal conductivity. In this case, it is possible to quickly balance a temperature change or a temperature difference between the secondary temperature sensors 601, 602, 601′, 602′, 603′, 601″ or the short primary temperature sensor 504 and the reference temperature sensors 800, 800′.
[0073] The open proximal end 705 of the elongate body 702 is sealingly closable from the outside of the process vessel 200. Especially, when the reference temperature sensors 800, 800′ are not inserted, or even when the reference temperature sensors 800, 800′ have been inserted for a long time, or when the reference temperature sensors have existed or operated within the process vessel for a long time, the open proximal end 705 can be closed to prevent the risk that the elongate body 702 may be damaged. In this case, no fluid can leave the process vessel 200.
[0074] The bore 703 of the protective tube 700 may be in fluid communication with a pressure gauge or a pressure sensor for monitoring the internal pressure within the bore 703. The pressure gauge may be arranged outside the process vessel 200 and in fluid communication with the bore 703, or the pressure sensor can also be installed outside the process vessel 200 or even integrated into the elongate body 702.
[0075] The bore 703 of the protective tube 700 may also be in fluid communication with a gas analyzer for monitoring the gas composition within the bore 703.
[0076] The bore 703 of the protective tube 700 may also be in fluid communication with an inert gas purging arrangement for purging the gas within the bore 703.
[0077] In these cases above, the integrity of the protective tube 700 can be monitored. In addition, for example, when the open proximal end 705 is closed, and the pressure within the bore 703 rises or the concentration of a process medium in the gas within the bore 703 rises, it indicates that there may be a leakage, and that as long as the process is going on, the protective tube 700 should not be opened from the outside of the process vessel 200.
[0078]
[0079] The embodiment shown in
[0080] In the embodiment shown in
[0081]
[0082] Two reference temperature sensors 800, 800′ are inserted into the elongate body 702. Secondary temperature sensors 604′ and 604″ are close to a respective reference temperature sensor 800, 800′ respectively.
[0083]
[0084] In
[0085] In this embodiment, a temperature sensor assembly 400 with two primary temperature sensors 501, 502 and two secondary temperature sensors 601, 602 is introduced into the process vessel 200 through a process vessel port 300. Among them, the primary temperature sensor 501 is positioned at a measurement location 901 within the process vessel 200.
[0086] A first protective tube 700 receiving a reference temperature sensor 800 and having two receiving members 706 is introduced into the process vessel 200 through a process vessel port 300′″ and arranged within the process vessel 200. The receiving members 706 are arranged on both sides of the first protective tube 700 in parallel to the longitudinal axis of the first protective tube 700, and respectively receive and hold the secondary temperature sensor 602 of the temperature sensor assembly 400 and the secondary temperature sensor 602′ of the temperature sensor assembly 400′ independently. The secondary temperature sensors 602, 602′ are close to the reference temperature sensor 800, which is inserted into protective tube 700 from the outside of the process vessel 200.
[0087] A temperature sensor assembly 400′ with two primary temperature sensors 501′, 502′ and three secondary temperature sensors 601′, 602′, 603′ is introduced into the process vessel 200 through a process vessel port 300′. Among them, the primary temperature sensor 501′ is positioned at a measurement location 902′ within the process vessel 200.
[0088] The secondary temperature sensor 601′ of the temperature sensor assembly 400′ is positioned within the process vessel 200 close to the primary temperature sensor 501 of the temperature sensor assembly 400, i.e. close to the measurement location 901 of the primary temperature sensor 501. A point for a measurement value comparison between the two temperature sensor assemblies 400, 400 is therefore formed at that measurement location 901.
[0089] The primary temperature sensor 502′ of the temperature sensor assembly 400′ is positioned within the process vessel 200 close to the secondary temperature sensor 601 of the temperature sensor assembly 400, or the secondary temperature sensor 601 of the temperature sensor assembly 400 is close to the measurement location 902′ of the primary temperature sensor 502′. A point for a measurement value comparison between the two temperature sensor assemblies 400, 400 is therefore formed at that measurement location 902′.
[0090] In addition, the secondary temperature sensor 602 of the temperature sensor assembly 400 and the secondary temperature sensor 602′ of the temperature sensor assembly 400′ both reach the first protective tube 700 within the process vessel 200 and are received and held by the receiving members 706 of the first protective tube 700. The two secondary temperature sensors 602, 602′ are both close to the reference temperature sensor 800 inserted into the bore of the first protective tube 700. Therefore, the two secondary temperature sensors 602, 602′ can be calibrated by the reference temperature sensor 800. At the same time, this arrangement forms a reference location 1001, at which measurement values of the two secondary temperature sensors 602 and 602′ can be compared.
[0091] A temperature sensor assembly 400″ with two primary temperature sensors 501″, 502″ and one secondary temperature sensor 601″ is introduced into the process vessel 200 through a process vessel port 300″. The temperature sensor assembly 400″ also comprises a second protective tube 700′, which is inserted into the process vessel 200 at the same process vessel port 300″.
[0092] The secondary temperature sensor 601″ of the temperature sensor assembly 400″ and the secondary temperature sensor 603′ of the temperature sensor assembly 400′ are close to each other at a reference location 1001′ within the process vessel 200. A point for a measurement value comparison between the two temperature sensor assemblies 400′, 400″ is formed at this reference location 1001′.
[0093] Another short primary temperature sensor 504″ of the temperature sensor assembly 400″ can be received and held by a receiving member 706′ of the second protective tube 700′. The short primary temperature sensor 504″ can be close to a reference temperature sensor 800′ inserted into the second protective tube 700′, and can be calibrated by the reference temperature sensor 800′.
[0094] With these exemplary combinations, a plurality of temperature sensor assemblies 400, 400′, 400″ can be calibrated and measurement values of these temperature sensor assemblies can be easily compared. The secondary temperature sensors can be used to detect a discrepancy between sensor signals, such as an offset of a single sensor, signs of aging, signal drift and/or failure. In addition, this signal discrepancy can be calibrated by the reference temperature sensors that can be inserted into the protective tubes.
[0095] Next, taking all the above embodiments and combinations thereof as examples, a method for a temperature measurement in a process vessel 200 will be explained:
[0096] For the process vessel 200 with the above temperature measurement arrangement, firstly, measurement values of the primary temperature sensors 501, 502, 503, 501′, 502′, 503′, 501″, 502″ and the secondary temperature sensors 601, 602, 601′, 602′, 603′, 601″ within the process vessel 200 are taken.
[0097] Then, a measurement value difference of the primary temperature sensors 501, 502, 503, 501′, 502′, 503′, 501″, 502″ and the secondary temperature sensors 601, 602, 601′, 602′, 603′, 601″ of different temperature sensor assemblies 400, 400′, 400″, which are positioned close to each other at certain measurement locations 901, 902, 903, 901′, 902′, 903′, 901″, 902″, is determined, ora measurement value difference of the secondary temperature sensors 601, 602, 601′, 602′, 603′, 601″ of different temperature sensor assemblies 400, 400′, 400″, which are positioned close to each other at certain reference locations 1001, 1001′, is determined.
[0098] Then, the determined measurement value differences are stored as reference values.
[0099] Then, at a later point in time, the above-mentioned steps of taking the measurement values and determining the measurement value differences are repeated.
[0100] Finally, the newly determined measurement value differences are compared with the initially stored reference values to detect a discrepancy in measurement values and/or sensor condition.
[0101] In an example of the above mentioned method, the steps of repeating to take the measurement values and determine the measurement value differences and comparing the new measurement value differences with the initially stored reference values, may be automatically executed periodically or may be carried out continuously.
[0102] For a process vessel comprising at least two process vessel ports 300, 300′, and 300″ at different locations, a method for a temperature measurement inside a process vessel 200 comprises following steps in detail:
[0103] Firstly, A temperature sensor assembly 400, 400′, 400″ is inserted into the process vessel 200 at or through each process vessel port 300, 300′, 300″.
[0104] Each temperature sensor assembly comprises at least one primary temperature sensor 501, 502, 503, 501′, 502′, 503′, 501″, 502″.
[0105] Then, each primary temperature sensor 501, 502, 503, 501′, 502′, 503′, 501″, 502″ is positioned at a measurement location 901, 902, 903, 901′, 902′, 903′, 901″, 902″ inside the process vessel 200.
[0106] Then, each secondary temperature sensor 601, 602, 601′, 602′, 603′, 601″ of each temperature sensor assembly 400, 400″ is positioned close to the measurement location 901, 902, 903, 901′, 902′, 903, 901″, 902″ of one of the primary temperature sensors 501, 502, 503, 501′, 502′, 503′, 501″, 502″ from a different one of the temperature sensor assemblies 400, 400′, 400″, or close to a reference location 1001, 1001′ of one of the secondary temperature sensors 601, 602, 601′, 602′, 603′, 601″ from a different one of the temperature sensor assemblies 400, 400′, 400″.
[0107] Then, measurement values of the primary temperature sensors 501, 502, 503, 501′, 502′, 503′ and the secondary temperature sensors 601, 602, 601′, 602′ within the process vessel 200 are taken.
[0108] Finally, a measurement value difference of the primary temperature sensors 501, 502, 503, 501′, 502′, 503′, 501″, 502″ and the secondary temperature sensors 601, 602, 601′, 602′, 603′, 601″ of different temperature sensor assemblies 400, 400′, 400″, which are positioned close to each other at certain measurement locations 901, 902, 903, 901′, 902′, 903′, 901″, 902″, is determined, ora measurement value difference of the secondary temperature sensors 601, 602, 601′, 602′, 603′, 601″ of different temperature sensor assemblies 400, 400′, 400″, which are positioned close to each other at certain reference locations 1001, 1001′, is determined. Thereby, measurement value discrepancies of individual temperature sensors and/or individual temperature sensor assemblies are detected.
[0109]
[0110] Especially, in applications where the secondary temperature sensors 601, 601′, 602, 602′, 603, 603′ do not need to be mechanically shielded or protected, the receiving member 706 can only be presented as a clamp, an annular body or a similar bracket, so that the secondary temperature sensors are simply fastened on the lateral surface of the elongate body 702.
[0111]
[0112] In this embodiment, the secondary temperature sensors or the short primary temperature sensor held by the receiving member 706 is not particularly protected. Therefore, the sensors thus arranged are exposed to and influenced by the environment existed in the process vessel 200, just like all the primary temperature sensors 501, 502, 503, 501′, 502′, 503′ arranged within the process vessel 200. Therefore, in this case, if the sensors thus arranged are influenced for some reason or in some way, such as being polluted and/or influenced by a sensor drift, this influence can be detected by comparing with the measurement value of the reference temperature sensor (not shown in this figure) arranged within the protective tube 700, thereby protecting the secondary temperature sensors or the short temperature sensor from such influence and/or at least enabling the operator of a temperature sensor arrangement to detect signs of such influences early and plan maintenance accordingly.
[0113]
[0114] The embodiment shown in
[0115] Embodiments, examples, variations or drawings of the present invention, including their different views or corresponding unique features, can be used independently of each other or in any combination. The features described in connection with one embodiment is applicable to all embodiments as long as these features are not mutually exclusive.
[0116] The invention being thus described, it will be obvious that the same may be varied in many ways. Such variations are not to be regarded as a departure from the spirit and scope of the invention, and all such modifications as would be obvious to one skilled in the art are to be included within the scope of the following claims.