SURFACE MATERIAL ATTENUATION OF RAREFACTION SHOCK WAVES TO ENHANCE SHAPED-CHARGES
20240068767 ยท 2024-02-29
Assignee
Inventors
- Ian B. Vabnick (Fredericksburg, VA, US)
- Lee R. Foltz (Indian Head, MD, US)
- Daniel E. McCARTHY (La Plata, MD, US)
Cpc classification
F41B9/0046
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F42B1/032
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F42B1/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F41B9/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F42B1/028
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
Provided herein are shaped-charges for focusing a filler, such as a fluid mass, and related methods of using the shaped-charges for disruption of an explosive target. The shaped-charge comprises an attenuating body positioned and configured to attenuate rarefaction waves to increase filler, including a fluid mass, explosively driven out of the container toward a target while also maintaining and enhancing fluid jet integrity. To further control impact and impulse forces on a target, additional layers may be used, including a foam layer and a jet-clipping layer positioned between the shaped-charge and the target surface. Also provided are propellant driven liquid disrupters having special attenuating bodies to improve liquid jet column characteristics.
Claims
1. A shaped-charge for focusing a filler comprising: a container having an interior volume formed from a container surface to contain a shell and the filler, the container surface having a container distal surface, a container proximal surface, and a container sidewall connecting the container distal surface and the container proximal surface; a shell having a surface with a geometric shape configured to support a shape-conforming explosive or contain an explosive volume, wherein the geometric shape has a central longitudinal axis or a bisecting symmetry plane and the shell surface has: a shell distal end; a shell proximal end that faces the container distal end; a shell sidewall that connects the shell distal end to the shell proximal end for the shell that contains the explosive volume; an attenuating body connected to or forming at least a portion of the container surface, the attenuating body having an attenuating body thickness of between 0.03 and 2; wherein the shell longitudinal axis or bisecting symmetry plane is longitudinally aligned or centrally positioned relative to the attenuating body and the corresponding container surface; an initiator contact point connected to the shape conforming explosive or the explosive volume configured to initiate detonation of the shape conforming explosive or the explosive volume; wherein the attenuating body has an attenuating body parameter configured to provide reflected shock wave attenuation after detonation of the shape-conforming explosive or the explosive volume and explosively drive filler from the interior volume of the container toward a target as a filler jet.
2. The shaped-charge of claim 1, wherein the filler comprises a fluid mass and/or a granular solid.
3. The shaped-charge of claim 1, wherein the filler comprises water, metal shot, steel shot, copper shot, lead shot, ceramic particles, garnet, salt, hydrocarbon, glass, sand or a HEET fluid.
4. The shaped-charge of claim 1, wherein the container is formed of the attenuating body.
5. The shaped-charge of claim 1, wherein the attenuating body parameter is selected from the group consisting of attenuating body thickness, material composition, bulk density, heterogeneity, geometry, one of the shock Hugoniot parameters such as bulk speed of sound or s number, location on the container surface, and any combination thereof.
6. The shaped-charge of claim 1, wherein the attenuating body is formed of a material selected from the group consisting of: plastic; foam; wood; clay; wax; rubber (natural or synthetic); aerogel; and any combination thereof.
7. The shaped-charge of claim 1, wherein the attenuating body is connected to: at least a portion of the container sidewall; at least a portion of the container distal end; at least a portion of the container proximal end; or the container sidewall, the container distal end, and the container proximal end, to cover the container surface.
8. The shaped-charge of claim 1, comprising a plurality of shells.
9. The shaped-charge of claim 1, wherein the shell is formed of a plastic material and the geometric shape comprises: a truncated cone having an open distal end and a closed proximal end, the closed proximal end having a smoothly-curved concave shape; wherein the geometric shape is axially-symmetric about a central longitudinal axis.
10. The shaped-charge of claim 1, wherein the attenuating body comprises an AB layer that at least partially covers the container distal surface, including an inner-facing and/or an outer-facing surface of the container distal surface.
11. The shaped-charge of claim 1, wherein the attenuating body is an AB layer positioned in the container volume and occupies a fraction of the container volume, wherein the AB layer is sealingly connected to the container.
12. The shaped-charge of claim 1, further comprising a second attenuating body corresponding to an AB layer having an AB layer thickness connected to an outer surface or an inner surface of the attenuating body, including container sidewall, wherein the sum of the AB layer thickness and the attenuating body thickness is between 0.25 and 1.5.
13. The shaped-charge of claim 1, wherein the attenuating comprises an AB layer formed from: natural rubber; silicone, Teflon?, neoprene, sorbothane, nitrile PVC, vinyl or polyurethane.
14. The shaped-charge of claim 1, wherein the attenuating body comprises a multilayer.
15. The shaped-charge of claim 1, wherein the attenuating body is configured to: slip over an outer surface of the container; adhere to an outer surface of the container with an adhesive layer positioned between the liner and the outer surface of the attenuating body; and/or wrap around an outer surface of the container.
16. The shaped-charge of claim 1, wherein the attenuating body thickness spatially-varies.
17. The shaped-charge of claim 1, wherein the attenuating body: at least partially covers the container sidewall; at least partially covers the container proximal end; at least partially covers the container distal end and has a spatially-varying thickness; at least partially covers the container distal end and has a spatially-constant thickness; at least partially covers the container sidewall and the container distal end; covers the entire container surface; covers the entire shell surface; or any combination thereof.
18. The shaped-charge of claim 1, further comprising: a foam having a density less than 0.5 g/cm.sup.3 positioned to fill a gap between the shaped-charge and a target, wherein the foam reduces water gasification and reduces a liquid jet forward velocity gradient; and/or a jet clipper layer adjacent or in contact with a target surface, wherein the jet clipper layer has a density of between 0.5 g/cm.sup.3 to 2 g/cm.sup.3.
19. A method of explosively driving a filler to disrupt a target, the method comprising the steps of: providing the shaped-charge of claim 1 with the filler positioned in the interior volume, wherein the shell and explosive is immersed in the filler; aligning the shaped-charge with a target; initiating detonation of the shape-conforming explosive or the explosives volume to initiate a detonation wave that travels substantially parallel to the longitudinal axis or bisecting plane, wherein the geometric shape and position of the shell and the attenuating body are configured to generate a tamp and timing of rarefaction waves to increase a pressure duration and amplitude to drive the filler as the filler jet toward the explosive target and increase a bulk mass of the filler jet; thereby disrupting the target.
20. The method of claim 19, further comprising the step of adjusting a jet characteristic of the filler jet by adjusting an attenuating body characteristic without changing a shaped-charge geometry or filler container geometry.
21. The method of claim 20, further comprising the step of positioning the attenuating body on the shaped-charge at an incident site, wherein the positioning comprises slipping and/or adhering the attenuating body that is a liner to an outer surface of the container.
22. The method of claim 19, further comprising the step of: applying a jet-clipper layer having a density of between 0.5 g/cm.sup.3 to 2.0 g/cm.sup.3 on or adjacent to a barrier surface of the explosive target; and/or applying a foam having a density less than 0.25 g/cm.sup.3 to at least partially fill a gap between the container distal surface and the explosive target.
23. A shaped-charge for focusing a filler comprising: a container having an interior volume formed from a container surface to contain an explosive, the filler, and an attenuating body; the container surface having a container distal surface, a container proximal surface, and a container sidewall connecting the distal surface the proximal surface; a liner positioned in the container volume, the liner having a distal surface and a proximal surface, wherein: the distal surface defines an attenuating body volume configured to contain the attenuating body; the proximal surface defines an explosive volume configured to contain the explosive; the liner has a geometric shape that at a distal end is sealingly connected to the container sidewall and tapers to a minimum distance toward the container proximal surface: the filler comprising: particles positioned in the liner between the liner distal surface and the liner proximal surface; and/or a unitary and continuous material formed from a ductile material; wherein the attenuating body has an attenuating body parameter configured to provide reflected shock wave attenuation after detonation of the explosives to explosively drive the particles from the interior volume of the container.
24. (canceled)
25. A propellant driven fluid disrupter comprising: a barrel having a bore with a barrel proximal end and a barrel distal end; a breech chamber operably connected to the barrel proximal end a fluid at least partially filling the bore; at least one or both of : an AB breech plug positioned toward the barrel proximal end, such that the fluid extends from the AB breech plug toward the barrel distal end; an AB muzzle plug positioned at the barrel distal end, wherein the AB muzzle plug and the AB breech plug that are both present fluidically seal the fluid in the barrel between the AB muzzle plug and the AB breech plug; a blank cartridge positioned in the breech chamber and facing the attenuating body breech plug when present; wherein: the AB breech plug has one or more attenuating body breech plug material properties configured to reduce primary shock and the AB muzzle plug has one or more attenuating body muzzle plug material properties to reduce rarefaction waves upon detonation of explosives in the blank cartridge.
26. (canceled)
27. (canceled)
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
[0097] In the following description, numerous specific details of the devices, device components and methods of the present invention are set forth in order to provide a thorough explanation of the precise nature of the invention. It will be apparent, however, to those of skill in the art that the invention can be practiced without these specific details.
[0098] In general, the terms and phrases used herein have their art-recognized meaning, which can be found by reference to standard texts, journal references and contexts known to those skilled in the art. The following definitions are provided to clarify their specific use in the context of the invention.
[0099] Filler is used broadly herein to refer to a material that is able to fill the interior volume of the container or a layer that itself define explosive volume from an attenuating body volume, immersing a shell surface, and that is capable of being explosively driven in a jet geometry toward a target. The filler can be solid-based plurality of particles, liquid-based or a combination of solid(s) and liquid(s). Fluid refers to a liquid-based material that is contained in the interior volume of the container and that immerses the shell surface. Particle refers to fine solid particles configured to form a jet toward a target after explosive propulsion. The solid particles may fuse under explosive pressures to form a unit mass that flows hydrodynamically. The shaped-charges are compatible with any number of liquids, including water and high-density liquids, such as corn syrup. As described herein and at U.S. Pat. No. 11,187,487, the fluid may be a high energy efficient (HEET) fluid. The fluid may comprise solid particles suspended in a liquid medium.
[0100] Attenuating body refers to one or more layers of material that are connected to the shaped-charge to provide desired control of the fluid or solid jet generated upon detonation of the explosives associated with the shell or liner. That attenuating body is also referred herein as SMART. The attenuating body may correspond to an AB layer that is configured to be positioned on another surface. In this aspect connected refers to an attenuating body that is connected to the shaped-charge in a manner that the functionality of the components of the shaped-charge is maintained. For example, an attenuating body connected to a container wall does not impact the ability of the wall to contain the liquid. The connection may be direct or indirect. For example, there may be an adhesive applied to adhesively connect the attenuating body to a surface. There may be an intervening attenuating body, such as an attenuating body layer, between a surface of the shaped-charge and an attenuating body. This is also described herein as an attenuating body multilayer configuration. One function of the attenuating body is to functionally adjust a wall surface thickness so as to impact reflected shock waves that are propagated in the contained liquid and interact with liquid/wall interfaces. The thickness of the attenuating body is selected to achieve the desired fluid jet outcome and, as explained, depends on various parameters. Exemplary thicknesses include ranges between 0.03 and 1. The thickness of an attenuating body may be spatially constant or spatially vary. A spatially-varying attenuating body thickness is also referred herein as a contoured attenuating body. The attenuating body may be conformable to a surface. In this manner, the attenuating body has a flexibility such that it can deform and conform to a surface, including a curved surface or a sharp-edged surface. The container material can be the attenuating body and thus the container thickness can be varied and contoured at various locations to provide improved jet characteristics. The container may also have a bisecting symmetry plane.
[0101] The attenuating body may correspond to a foam. Foam refers to a material that is formed by trapping pockets of gas in a liquid or a solid. A solid foam can be closed-cell or open-cell, depending on whether the pockets are completely surrounded by the solid material. In an open-cell foam, gas pockets connect to each other, including via pores. In a closed-cell, gas pockets are not connected to each other. The foam is polydisperse and is characterized as not uniform and stochastic. Foams efficiently attenuate shockwaves because of the heterogeneous structure in combination with low bulk density. In this manner, pressure waves are broken up and dispersed, thereby providing good shock tamping. Depending on the application of interest, which influences the desired liquid jet characteristics, the foam can be made from any of a range of materials, such as plastic, rubber (natural or synthetic), aluminum or other metals. For example, blasting cap protectors are made from aluminum foam because an aluminum foam absorbs the shock. The attenuating body may also be an aerogel. Aerogel refers to a synthetic porous material derived from a gel, where the liquid component has been replaced with a gas without significant collapse of the gel structure. Exemplary aerogels include, but are not limited to, solid smoke, solid air, solid cloud, blue smoke, silica aerogels, carbon aerogels, polymer-based aerogels, metal-oxide aerogels, and the like.
[0102] AB layer is used broadly to refer to an AB providing functional benefit of the shaped charge. The AB layer may be a layer of material affixed to and/or adjacent to another material. For example, the AB layer may be a shape-conforming material that is effectively wrapped around another surface. The AB layer may be a sleeve of material that slides over a container surface, such as container side-wall outer facing surface. The AB layer may be adhered to a surface by a layer of adhesive, such as an inner or outer-facing container surface. The AB layer may be provided with a substantial thickness so that the AB layer is effectively an AB volume that occupies a fraction of the container volume, such as up to 10%, up to 20% or up to 30% of the container volume. The AB layer may be adjacent to, in physical contact with, or connected to the distal surface of the container volume. In this manner, the AB platform described herein is versatile and can be used in a number of various configurations, depending on the application of interest. The AB layer may be a sheet of constant thickness that is contoured to the proximal container face or may be flexible and bendable such that it conforms to a contoured surface. An AB layer may be an air cell or a low density foam. The AB layer may be a volume of material that has curvature on its distal surface, and occupies a significant volume. This aspect is generally characterized as an AB layer having a substantial thickness that results in the AB layer being an AB body volume.
[0103] Focusing refers to the ability to force liquid in a desired direction with desired properties related to jet formation, stability, and impact pressure or force against a target, including post-barrier penetration.
[0104] The term substantially matched refers to two components that are similar. In the context of a geometric shape, it refers to a deviation from absolute correspondence that does not adversely impact functional properties associated with the fluid jet and target disruption. The term is intended to reflect that the shaped-charges provided herein are able to tolerate differences between surfaces (e.g., plastic shell surface and cylindrical plastic body distal end) without significant degradation in a liquid jet parameter. As desired, the term may be optionally quantitatively defined, such as curve parameters that differ by less than 10% from each other, such as curvature, distances, and any parameters associated with a corresponding curve fit, such as:
where the parameter a is within 10% for each of the two best-fit curves (with surface then formed as a rotation of the function about the central longitudinal axis). In a similar manner, best-fitting of any of the curves or corresponding surfaces may be performed to define whether two surfaces are substantially matched.
[0105] Unless otherwise defined, approximately or substantially refers to a value that is within 10% of a desired or true value, and can correspondingly include identically matched.
[0106] Proximal and distal are relative to the detonator and target. A distal position is further from the detonator and closer to the target than a proximal position. In other words, distal is toward the direction of a target, and proximal more away from the target. The terms are useful in describing relative positions of components.
[0107] The terms central longitudinal axis and bisecting symmetry plane are used to refer to relative positions with respect to the shaped-charge and associated target. In general, a longitudinal axis corresponds to the notional line leading from the shaped-charge toward a target, and is relevant for shells that have a container volume for containing an explosive. A bisecting symmetry plane is generally relevant for a shell having a surface to support a surface-conforming explosive. For desired fluid jet characteristics, the surface has a plane of symmetry, referred herein as a bisecting symmetry plane, where the distal shell surface faces toward the target through the container distal end.
[0108] The invention can be further understood by the following non-limiting examples.
[0109] Referring to
[0110] The shell 30 has a shell distal end 33, a shell proximal end 34 and a shell sidewall 35 that connects the shell distal end surface with the shell proximal surface, with shell bisecting symmetry plane illustrated by 120 in
[0111] As discussed herein, the attenuating body 11 is selected and positioned to provide desired filler or fluid mass expulsion characteristics by controllably manipulating reflected shock waves upon detonation of the explosives positioned in the container with attendant fluid shock wave/wall surface interaction. Particularly relevant attenuating body characteristics are material composition and body thickness 12. Preferred thicknesses include a thickness between 0.03 and 1 or between 0.75 mm and 2.6 cm. The attenuating body may contact an outer and/or inner surface of container 25. In some embodiments, attenuating body 11 may contact at least a portion of a surface of the shell 30, including contacting both a container surface and a shell surface, or only one of a shell surface or a container surface. In a preferred embodiment, the contact is to an outer surface of the container 25. The container 11 surfaces may include container distal 210, proximal 220 and side surface 205. A stem 42 may accommodate channel 250 through which an explosive initiator operably connects, such as an electrical line for an electronically-triggered explosive, with a fluid jet directed to a target 1700. In this manner, there is an initiator contact point 251 configured to initiate detonation of the explosive (whether explosive volume or shape-conforming) to drive filler out the distal end of the container toward a target in the form of a filler jet 2110 (see, e.g.,
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Example 1: Methods to Reduce Water Gasification and Atomization in High Explosive Mass-Focusing Shaped-Charges
[0113] The shaped-charges and related methods of using an attenuation body, such as by lining the side-wall or the front-face of a jetting water high explosive shaped-charge with specific materials and thicknesses, increases the fluid jet efficiency. Side-wall lining with an attenuating body increases the measured relative work, impulse and penetration by up to 50%. Water gasification is reduced and a slight increase in inertial tamping increases the jet velocity. Alternatively, using an attenuating body on the front face has a different beneficial effect. Front-face attenuating body having a low density and optionally contoured material dramatically increases the charge's effectiveness at greater standoffs by lowering the rate of jet stretch.
[0114] Water and other fluids (e.g., HEET) can be driven explosively using shaped-charges to form liquid jets which move at relatively high velocity and can perform work on a target. Explosives are shaped and immersed in the fluid (e.g., water) or placed on the outside of a water container. The explosives' detonation produces shock waves that move through the water. Typically, to create a jet, the charge is configured such that the shocks along a central axis or a bisecting plane converge and form a Mach stem. The pressure is higher in the center compared to the sides. A pressure gradient results in the water accelerating differentially as its position moves away from the center. The result is a jet that has a velocity profile with faster water at its front and the gradient is such that the water slows as one moves towards the explosive gas products.
[0115] The attenuating body provided herein stabilizes the fluid and reduces gasification and atomization resulting from shock waves in the fluid. This maximizes the amount of liquid fluid propagating in the jet and increases the distance the jet will travel in air or inside a medium before it breaks apart. Most jets fail to propagate beyond a few feet in air. The work function and impulse are highly dependent on the velocity of the jetting liquid and the mass of fluid during impact with an object.
[0116] In the arts of improvised explosive device (IED) neutralization or ordnance disposal, jetting fluids can be used to break apart bombs. Containers are accessed, fuze components are destroyed, and explosives and components are expelled and separated. If the purpose of the jetting water is to neutralize IEDs, the fluid mass focusing shaped-charge is referred to as a high explosives disrupter. These tools can also be used to breech structures such as bomb casings, vehicle bodies or buildings.
[0117] When a shaped-charge is initiated, the detonation wave couples to the fluid and it generates shock waves inside of the fluid. These shocks are essential in creating a particle forward velocity gradient which macroscopically causes the formation of a fluid jet. Without the velocity gradient, the fluid tends to move as a unit mass and not jet. These jetting fluid can do work cutting through materials such as steel and low strength continuous media. Fluid jets, due to their relatively low density and high heat capacity, are preferred to access and disable IEDs. The relatively low impact pressures have a reduced risk of shock initiating explosives inside an IED or bomb. In addition, due to a fluid jet's resistance to compression, including for water, high mass, inviscid and inelastic nature, the duration of loading is very long, resulting in maximized momentum and energy transfer to impacted targets.
[0118] Unfortunately, the very same shock waves that are necessary to form the fluid jet ultimately result in its destruction. They cause the fluid to atomize and to gasify, thereby adversely impacting jet integrity and attendant energy transfer. Liquid fluids, including water, cannot withstand tensor or hoop stress and thus forms droplets as the jet expands radially and stretches apart from lengthening. Furthermore, at room temperature, water boils at relatively low pressures. For example, at 25? C., water boils when the atmospheric pressure above liquid water surface drops to below approximately 0.5 psi. After the explosion, because of the water's high heat capacity, the bulk of the water in the charge container remains at room temperature. As explained below, water vapor bubbles form inside the water projectile region and these bubbles progressively grow. Generally, a vapor bubble forms along the symmetry axis or plane of the water-filled charge and at the corners. The bubbles can destroy the jet early in its formation so that the bulk density of the jet is too low to perform work. The water is transformed into gas rather than forming a jetting liquid.
[0119] The water gasification results from the shock waves associated with detonation of the explosive that reflect at the container walls, and water-air boundaries. The shock wave unloads and the reflected wave is a rarefaction wave also known as a release wave. Unlike the primary compressive shock wave caused by the explosion, rarefaction waves are tensor waves and are negative pressure waves. At the front face, due to the intensity of the primary shock wave, the reflective wave can be at the critical pressure to induce water bubble formation. The tension is amplified when the rarefaction waves collide. The tensor stress causes a void in the water which then creates a surface for the water to boil at the interface with the void. This is the reason the explosive's distance from the container front-face and tamp-back wall is critical to allow the principle shock to attenuate. At the corners, the shocks reflected off the side and the front converge and amplify also causing gasification at the corner of the jet. Once a water vapor bubble forms there is a second water-gas boundary and now shock reflections occur at this interface. The process results in the continual growth of the gas bubble until the shocks dissipate.
[0120] The amplitude of the reflected shocks and the decompression of the fluid (e.g., water) is dependent on the shock impedance and the shock Hugoniot properties of the container, air, and fluid (e.g., water). Two well defined properties are the bulk speed of sound and the pre-shock density. Generally, the container shell thickness for most mass-focusing shaped-charges is uniform and very thin because of the cost and the plastic material molding process. Typical container wall thicknesses are between 0.01 and 0.08 and thus do not contribute much to the shock effects. However, we recently observed that changing the plastic wall thickness to between 0.25 and 0.5 on the sides of a container can be beneficial. However, increasing the front wall thickness can be highly detrimental for two main reasons. The first is the plastic fragments can be driven at high velocity and shock initiate explosives when they impact an IED. The second effect is not so obvious and that is the dramatic reduction of the forward velocity gradient. The fluid is projected forward as a low velocity slug rather than forming a jet. Understanding and accommodating these effects are important for the configuration, positioning and use of attenuating body to better control and improve fluid jets with attendant functional benefit of tailored impact to the target.
[0121] Experimentation and CTH hydrocode modeling further clarify the reason for the improved jetting properties of manipulating the high explosive disrupter container side-wall material and thickness. Using 0.25 thick ASA 3D printed plastic side wall to the CAT shaped-charge results in a 50% increase in cavitation and in penetration, and a 40% increase in impulse. 3D printed ASA material is considered a non-ideal material in that it is inhomogeneous in structure and density and as a result is similar to foams, which are known to attenuate shocks. Shock attenuation is also dependent on the speed of sound and the density. Generally, lower speed of sound materials and/or lower density materials will attenuate shocks more efficiently. The ASA has the approximate density of water and is a form of acrylic which has similar sound speed to water. There is not a significant inertial tamping benefit. The improvement in performance is believed to be due to the shocks on the side-wall attenuating through the plastic and also due to the timing mismatch of the release waves traveling back into the water compared to the front.
[0122] Experiments with an attenuating body corresponding to a 0.25 thick silicone rubber lining the side-wall has similar results to the ASA material. The silicone rubber has a measured density of 1.25 g/cm.sup.3 and the ASA material is reported to have a density of approximately 1 g/cm.sup.3. If density was a primary contributor due to increased inertial tamp then a 25% increase in density should show a measurable increase in performance, but it did not improve penetration in a multi-layered panel penetration test. The observed results are consistent with the theory of shock attenuation in the sidewall and reduction of the Mach stem effect at the front corner due to timing mismatch created by differing wall thickness at the front and side. The front corner region is predicted to be the most sensitive zone to add side-wall material. To validate this, a band of silicone rubber was placed only on the sides of the projectile region of the water and not the back tamp water in the container. In the multi-layered spaced panel test, the partially covered sidewall performed similarly to the completely lined sidewall.
[0123] To assess the benefits of inertial tamping and using a high strength material to further confine the water, CTH modeling was conducted for the CAT mass-focusing shaped-charge using a 0.25 thick steel sidewall liner. Steel is approximately 8 times the density of water. The result was poor jet formation and gasification of the water in the projectile region. The high speed of sound in steel, above 5,500 m/sec, and the impedance mismatch at the steel-water boundary, transitioning from a high Z to a low Z material resulted in amplification of the rarefaction wave effects. From this, we conclude that the preferred attenuating body material is a low Z material compared to water and a lower speed of sound material, non-ideal. Representative ranges of low Z values as comparing the acoustic impedance difference to water: silicone rubber ?27%, polyethylene foam ?22.6%, natural gum rubber ?1%, LDPE 19%, polyurethane 20%, neoprene 31%, HDPE 55%, polypropylene 60%, and PVC 118%. In contrast, steel is a high Z material and its acoustic impedance difference compared to water is 2998%. The materials relative shock impedance difference to water is similar to their acoustic impedances. Shock impedance is more complex because it will change with the shock velocity, which depends on the quantity of explosives used.
[0124] High percent elongation materials would hold together longer as they stretch from the radial expansion after the explosion. The shocks are reflected repeatedly in the water and a material that stays in contact with the water for a longer duration would further improve their effectiveness. Natural gum rubber has a relatively low sound speed, 1,500 m/s, comparable to water at 1,480 m/s at room temperature. Rubbers are well known for very large percentage elongation, and natural rubber is reported to stretch to 500% without failure. A36 mild steel, in contrast, has an approximate percent elongation of 20%-40%.
[0125] Experiments are conducted by wrapping the axisymmetric CAT shaped-charge side wall with 0.25 and 0.5 thickness natural gum rubber sheet as the attenuating body. This performs slightly better than the silicone rubber sheet attenuating body but has a density of approximately 1 g/cm.sup.3. In a multi-layered spaced panel test in which the layers were separated by a 3 spacing, the CAT shaped-charge covered with the 0.25 thickness sheet showed a 50% increase in penetration compared to the tool with no wrapping. The 0.5 thick natural rubber sheet showed a 30% increase in penetration compared to the control and the average hole diameter in the panels is slightly larger. Furthermore, only covering the water slug region of the CAT with the attenuating body has similar results compared to the sidewall completely lined with the attenuating body.
[0126] CTH in silico modeling experiments were completed on a linear mass focusing shaped-charge with an attenuating body made from various materials such as silicone, Teflon?, neoprene, PVC, and polyurethane. For polyurethane, the density was varied. The attenuating body thickness was 0.25 thick or 0.5 thick in the CTH simulations. In all cases, the experiments show a slight increase in jet tip velocity and a jet with reduced gasification compared the control simulation without an attenuating body. In addition, substituting an attenuating body with the equivalent volume of water did not improve the jet or reduce gasification.
[0127] The benefits of a sidewall attenuating body applies to all axisymmetric and linear mass-focusing shaped-charges. The lining that is the attenuating body does not measurably increase the weight or the dimensions of the charges. This makes the attenuating body a practical way to improve efficiency by optimizing the amount of fluid (e.g., water) contributing to penetration, cavitation and impulse for the same net explosive weight. The practical deployment of the high explosive disrupters is not adversely impacted and optionally the attenuating body can be added at the incident site simplifying deployment. For example, the attenuating body can be an AB layer that is positioned over an outer surface, and any portions thereof, of the shaped-charge container. Rapid application can be done by using a pre-applied high strength tape such as 3M VHB Transfer Tape. The cost of most rubbers and plastics such as PVC are reasonable making volume production of AB layers affordable. The velocity will not increase significantly which means there is no increase in the risk of shock initiation due to the jet impacting an IED in a region containing explosives. Several commercially available high explosive disrupters would receive immediate benefits from the attenuating bodies and related methods described herein.
[0128] Placing an attenuating body at the front (e.g., distal surface) of a high explosive mass focusing shaped-charge has a very different effect than placing an attenuating body on the container sidewall. CTH simulations of polyurethane foams placed on a charge face of varying density from 0.015 g/cm.sup.3 to 1 g/cm.sup.3 were examined. The thickness was one inch for all densities. The lowest density had no observable effect. At the 1 g/cm.sup.3 density the jet did not form and the water moved as a unit mass and there was a reduction in gasification at the jet central plane. At 0.5 g/cm.sup.3, gasification at the jet central plane was reduced and the jet stretch was significantly slowed. The forward velocity gradient was reduced. At the one charge diameter distance, the jet was wide and the length shortened. The CTH stimulations predict that the jet would produce large cavities but low penetration through medium at typical standoffs of one charge diameter. A reduced forward velocity gradient has the benefit that the rate of jet lengthening is slower and thus the high explosive disrupter produces jets that remained intact at significantly larger standoffs before the jet is stretched apart into droplets.
[0129] Experiments with GreatStuff? foam, 0.016 g/cm.sup.3, of approximately 1-inch thickness at the charge face did not show a loss in penetration in the multi-layered separated panel tests. These observations are consistent with CTH simulations.
[0130] Underwater tests indicate there is a dramatically reduced performance of commercially available mass-focusing shaped-charges. The effectively infinite medium of water at the front of the charge may have similar effects as the CTH modeled 1 g/cm.sup.3 foam materials that are placed against the charge front face. The jet will not form and the water in the charge will move as a unit mass. In addition, the ideal penetration equation predicts that in a fluid-fluid interaction, water jet erosion pushing through water dramatically reduces the distance the jet will travel before being completely ablated. We have shown in underwater experiments that placing a foam, such as 0.15 g/cm.sup.3 density Styrofoam?, between the charge face and the target results in jet formation and perforation of thin steel barriers. Furthermore, the jet penetrates through a medium of gun powder placed adjacent to the steel barrier. In one embodiment, we use a hemi-cylindrical mass-focusing linear shaped-charge.
[0131] Multiple layers of materials are beneficial in controlling the shock impact effects on explosives inside of IEDs, including at the disrupter distal surface that faces toward the IED. Accordingly, provided herein is an attenuating body formed from a plurality of attenuating body layers. We demonstrate the limits to the quantity of explosives that should be used to drive water to neutralize bombs. Water jets from disrupters can shock initiate common IED explosives after impacting the skin of a bomb. Disrupter standoff may need to be adjusted such that the jet tip erodes in flight. At the time of arrival, the velocity on impact is lower due to the forward velocity gradient for longer standoff distances. This results in the impact pressure, which is proportional to the square of the jet velocity, to be reduced below the critical pressure of initiation of the IED's explosives. Furthermore, jet stretch causes the fluid tip to narrow which also reduces the shock impulse. This increase in the distance to traverse to the target causes the jet to stretch and atomize and thus results in reduced performance such as lower target cavitation and impulse. Based on this, provided herein are shaped-charges and related methods that avoids the need to change the standoff by using an optional low-density foam to fill the gap between the shaped-charge distal surface and the target. The low-density foam is coupled with a layer of higher density material near or in contact with the bomb barrier. The higher density material can be a density of 0.5 g/cm.sup.3 to 2 g/cm.sup.3 and adjacent to the target. This material clips the jet and exploits the shock impedance of the materials and the process of shock attenuation to reduce the impact pressures and compressive heating of the IED explosives that are on the other side of the bomb barrier. We refer to this layer as a jet clipper layer and is further helpful in IED defeat. The jet clipper layer can be used with or without a low-density foam medium and has been experimentally shown to reduce the probability of shock initiation of IED explosives (see, e.g.,
[0132] Using attenuating bodies greatly improves the efficiency of high explosive shaped-charges that drive a fluid, including water. For a given explosive weight the relative work and penetration is readily increased by 50% through the use of attenuating bodies compared to an equivalent fluid mass focusing shaped-charge without an attenuating body. The increase in the mass of the jet because of preservation of liquid water contributed to a 40% increase in impulse. Attenuating bodies, including AB layers, are cost effective and can be prefabricated into the charge design through molds or connected to the sidewalls by various connectors, such as clips, fasteners and/or adhesives. For axisymmetric charges, the attenuating body can be slipped onto the body, including on an outer surface of the container. Molds for plastics and synthetic rubbers such as polyurethane can be made such that the container sidewall is of an optimized thickness compared to the front. The front of the container (distal container surface) should be as thin as possible for maximum work, penetration and impulse. Also, the thin-walled distal container surface reduces plastic impacting the target. Foams at the jet front can be used to preserve liquid water by reducing water gasification and dramatically reduce the forward velocity gradient. Foaming the disrupter front by providing foam to the container distal surface, or anywhere between the target and container distal surface, improves the jet's effective working distance because the jet will form more slowly and thus be intact at greater standoff distances. Attenuating body materials, including an AB layer, are affordable and do not drastically increase the cost of the charge. The attenuating body may be an AB layer that is formed from distinct attenuating body layers. The total additional volume and weight does not greatly increase and so portability of the charge is not adversely affected. For the first time, a high explosive disrupter's jet characteristics can be modified without changing the charge geometry or the shaped-charge container that contains the fluid. Examples include, but are not limited to, wraps, sleeves, appliques such as spray or painted on materials, which can be provided on-site or ahead of time.
Example 2: Shaped-Charge Theory and Application
[0133] A Catenary Advanced Technology (CAT) disrupter is a mass focusing shaped-charge that explosively drives a large volume of water, or other liquid such as Highly Efficient Energy Transfer (HEET) fluid as described in any of U.S. patent application Ser. No. 15/731,874, U.S. Pat. No. 10,451,378, U.S. Pub. No. 2020/0025508, each to Vabnick et al. The liquids jet at relatively high velocity to disrupt improvised explosive devices (IEDs). The jet may perforate the barrier(s) of a bomb, destroy fusing components and cause separation of the firing train to include expulsion of the explosive main charge. The CAT disrupter has an axially symmetric geometry. The shell may be formed of a plastic material, that shapes the explosives (also referred herein as an HE former) is a hybridization of a truncated cone at the opening which transitions to a smooth-curved surface such as a parabola at the closed end. Sheet explosives are mated to the surface of the HE former. An enhanced water charge (EWC) was previously developed using a plastic bowl lined with sheet explosives or lined with overlapping wraps of detonation cord. As with all mass focusing shaped-charges, the CAT disrupter uses a Mach-stem effect to cause a higher pressure field along its axis of longitudinal symmetry. The water near the center is accelerated more than the water in the periphery. The CAT disrupter fluid jet tip can be explosively propelled in a range from transonic to supersonic velocities. The jet velocity can be controlled by the amount of explosives applied to the explosive former or by modifying disrupter geometric parameters to include cone angle and tamper mass-to-projectile mass ratio. Due to the HE former's parabolic base, the water is collimated and has a greatly reduced forward velocity gradient (FVG) compared to other mass focusing charges. This results in unprecedented penetration and effective working distance. The CAT shaped-charge can disrupt IEDs up to four times farther than other fluid mass focusing disrupters of comparable size. Modification of the cone angle can also be used to change the jet profile including the cross-sectional area at any point along its length.
[0134] One embodiment of the CAT disrupter has a container volume of approximately 64 ounces and drives a water slug that is 5 to 10 times the volume of the water projectile in a propellant-driven water cannon/dearmer such as the percussion actuated non-electric (PAN) disrupter (U.S. Pat. No. 4,957,027) or similar dearmer.
[0135] The CAT disrupter jet profile in cross section is similar to the jet formed by the PAN with the Reverse Velocity Jet Tamper (ReVJeT) disrupter enhancer adapter (U.S. Pat. No. 10,451,378). The CAT disrupter average jet cross sectional area is significantly larger and travels at higher velocity. Using the maximum explosive load tested, the velocity of the CAT disrupter jet tip averages five times faster than that of a PAN jet.
[0136] Several inefficiencies in mass focusing explosive shaped-charges are minimized in the design of the CAT disrupter. A dominant destructive hydrodynamic factor in all mass focusing high explosive tools is the FVG. The jet will break up into droplets or particles, thus losing the jet's effective density and its ability to transfer momentum and energy. The FVG can be explained qualitatively by dividing the jet into discrete elements. Proceeding from the rear of the jet to its front, each element is progressively faster. The rate of jet stretch increases with explosive load. The FVG can be complex and may not be linear. The jet stretches apart by this hydrodynamic stress. Atomization also occurs from the turbulence inside the jet and air drag along its front and sides. The CAT disrupter FVG is considerably reduced compared to other disrupter high explosive shaped-charges described herein. As described, further improvements are provided by attenuating body, including on the container distal surface, foam and a jet-clipper layer positioned toward the target, including adjacent the target surface.
[0137] The disrupter can also be used to drive HEET fluids (U.S. patent application Ser. No. 15/731,874 titled High Energy Efficient Transfer Fluids filed Aug. 18, 2017). There are experimentally demonstrated advantages which show that higher density liquids have improved penetration, notable increases in bulk work and momentum transfer and, due to their higher mass can lower jet velocities. The latter is important when impact sensitive explosives are present inside an IED. Due to the hydrodynamic characteristics of the jet, the impact pressures have a squared dependence with jet velocity. The shock Hugoniot properties of the HEET fluids also may contribute to the reduced risk of shock initiation of explosives inside an IED when they are impacted by a disrupter jet. In addition, experiments showed HEET-filled disrupters had increase performance with respect to stand off.
[0138] An initiator comprising a detonator can be coaxially seated in contact with charge apex and initiated. The resultant detonation wave shock couples into the water and shock waves move inside the fluid. Due to shock impedance at the water-container interface, the shock rarefaction waves reflect back into the water slug which can further contribute to water movement. In one embodiment of the CAT disrupter, the sidewalls of the fluid container were three times thicker than the front face and used higher density PVC compared to the front face which was made from ASA material. Tests of CAT disrupters constructed from uniformly thick ASA sidewalls and front were less efficient at penetration and impulse than the CAT disrupter embodiment using a thick PVC side wall. Provided is a method of using inertial confinement and shock impedance to increase the efficiency of the CAT disrupter. Thus, PETE plastic on the side wall can further improve the efficiency of the CAT disrupter given it is of higher density than PVC. PVC and PETE are 1.35 and 1.5 times the density of ASA, respectively. As described herein, and illustrated in
[0139] We observed that thickening the wall on the front face of the charge and using a high strength, brittle plastic had negative effects on performance. High explosive disrupters whose front surface are made from low ultimate tensile strength and high tensile elongation plastics such as low-density polyethylene (LDPE), high density polyethylene (HDPE), or polypropylene (PP) should have better performance with respect to jet velocity, penetration and impulse. Wall thicknesses between 0.02 inches and 0.08 inches result in good performance. Brittle plastics that have similar densities to water fracture into particles that travel along with the jet and resulted in explosive initiation on impact with targets filled with common explosives. The attenuating bodies provided herein can address these issues.
[0140] Due to the normalized velocity profile of the CAT jet, a high strength, high durometer (80-95) polyurethane ball can be placed at the axial center of the shock wave dampener. The ball can be used as a jet stabilizing projectile (JSP) (U.S. Pat. Pub. No. 2021/0041205 (published Feb. 11, 2021; now U.S. Pat. No. 11,262,155, incorporated by reference herein) titled Fluid Jet Stabilizing Projectile for Enhanced IED) and behaves similarly to the JSP used with the PAN disrupter and ReVJeT adapter. Such a ball is particularly useful for jet tip shapes that are annular, as such a shape promotes hydraulic trapping of the polyurethane ball. The polyball seats inside the hollow region of the jet and is trapped by the jet due to its flow properties. The ball causes a slip stream such that air drag is reduced around the jet tip and a low-pressure zone behind the ball will cause the water to flow forward around the rear surface of the ball creating hydraulic stabilization of its flight. The advantages of a JSP for bomb disablement is increased barrier limit thickness and the reduced surface area on impact which is known to lower shock impulse as previously described. Polyurethane has similar shock Hugoniot properties as water and thus reduces the risk of shock initiation of explosives due to shock impedance. The JSP should be 10% to 50% of the CAT container diameter to produce the air drag benefits. In comparison, Rock et al. (U.S. Pat. No. 8,677,902) propose using a small metallic bead in the apex of the hollow void (shock cavity) of their LIFT charge. They propose the small bead material to be copper, steel, lead or depleted uranium, which are at least nine times the density of water. The small bead is explosively driven forward, but does not ride the jet tip. There is an extreme forward velocity gradient in a conical LIFT and the metal bead would not behave like a JSP. The JSP can be encased in an attenuating body on the distal face of a high explosive disrupter. The attenuating body may have a recess to optionally seat a JSP. See also, U.S. Pat. No. 11,421,971 (incorporated by reference herein).
Example 3: Geometrical Configurations
[0141] In one embodiment, the shell is specially configured to have a desired geometric shape to achieve the desired functional benefits described herein with respect to a subsequently generated fluid projectile. The shaped-charges provided herein are compatible with a range of shell types and shapes. For example, more generic shapes are reflected in
[0142] In terms of geometrical shape having curvatures,
[0143]
[0144] The position of the shell surface 40 along the central plane can be adjusted by changing the position of the shell stem 42 that accommodates channel 250 for the initiator detonator.
[0145] A channel 250 is configured to operably connect to an initiator detonator for detonating shape-confirming explosive that is at least partially mated to shell surface 40.
[0146] The shell 30 has a specially configured surface to ensure appropriate forces on the filler (including a liquid fluid mass) 20 contained in the container interior volume 27 of the container 25 upon detonation of explosives supported by the shell surface. In an embodiment, the shell is a plastic shell. A shape-conforming explosive is positioned on the shell surface, wherein the plastic shell surface has the desired three-dimensional geometry. The plastic shell surface can be concave-shaped. The concave-shaped surface is a catenary paraboloid, such as generally illustrated in
[0147] As illustrated in
[0148] Optionally, the shell distal end has one or more scores to facilitate, after detonation, well-controlled separation of the distal end to further reduce risk of unwanted detonation.
[0149] Various additional embodiments are illustrated in
[0150]
[0151]
Example 4: Fluid Jet Characteristics
[0152]
Example 5: Solid Particle Filler
[0153] The devices and methods provided herein are compatible with a filler which comprises solid particles, such as solid particles that have fluid-like characteristics. The solid particles are sized and have characteristics such that they may flow under an applied shear. Accordingly, the filler may be described as being formed of fine particles. Fine refers to an average particle diameter that is sufficiently small such that the filler, as a whole, has fluid-like capabilities including flowing under an applied shear force and forming a jet from the shaped-charges described herein, and that can move in a manner so as to fill a desired volume. For example, the particles may have an average characteristic diameter that is less than or equal to 5 mm, 1 mm, 500 ?m, or 40 ?m. Exemplary materials from which particles may be formed include, but are not limited to, shot (e.g., S70 shot), glass, garnet, sand, ceramic, plastic, metal (e.g., copper, brass, or lead), hydrocarbons, sugar, and/or salt.
[0154] Any of the devices and methods may have a container with a built-in funnel so that solid particles may be poured into the container, including within a liner positioned in the container. The SMART devices and methods provided herein can be applied for a filler that comprises solid particles, including for liners having any of a variety of geometries that contain the solid particles, including conical-shaped, portion of a cone, linear (wedge-shaped), hemi-cylindrical; hemi-spherical; and symmetrically curved side surfaces that optionally extend from a central flat region that is a flat surface (trumpet-shaped). Because solid particles cannot withstand hoop stress or any tensor stress, and certainly not to the extent a filler that is liquid can, incorporating SMART is particularly beneficial in the context of a filler comprising fine solid particles to reduce those stresses and provide an improved jet comprising solid particles.
[0155] Provided herein are liner-based shaped charges wherein the fill comprises particles, including solid particles positioned within the liner, and/or a unitary and continuous material formed from a ductile material with a wall thickness of up to 0.25, with an attenuating body (SMART) material positioned adjacent to a distal liner surface. Use of such a SMART-liner configuration beneficially provides an increased efficiency of the shaped charges. This provides an important functional benefit of reducing the required quantity of explosives that would otherwise be needed and attendant dramatic decrease in costs. Applications include mining applications. In addition, in a breaching application, use of such a SMART-liner configuration has the added benefit of reducing or avoiding hazardous fragments from conventional breach tools that have metal skins.
[0156]
[0157]
[0158] Adjacent to the liner proximal surface 2630, explosives are positioned in the explosive volume 2640 defined by the liner proximal surface 2630 and container 25 walls. Liner distal end 2650 is sealingly connected to the container sidewall, including by attenuating body 11, or a separate seal layer, such as a ring, positioned around the region between the liner distal end 2650 and container 25. As desired, additional attenuating body 11a may be positioned adjacent to the container sidewall to further influence jet characteristics. Attenuating body 11a and 11 may be the same or may be a different material, such as a layer material 11a and a foam material for 11. The geometry of the liner refers to the liner narrowing to a minimum distance 2660 at the proximal-most position of the liner corresponding to the minimum distance between liner and container 25 proximal end. Filler corresponding to particles 2670 are positioned in the liner, illustrated as liner volume 2675, and may be filled via a funnel 2300 (see, e.g.,
[0159]
[0160] Instead of comprising particles, the liner can alternatively comprise a unit mass of material, including a conventional classical shaped charge liner. Exemplary liners include, but are not limited to, a shaped sheet of a ductile materials, such as copper, steel, or the like, of defined wall thickness up to 0.25.
Example 6: Propellant Driven Disrupters with Attenuating Body Plug
[0161] An AB can be used as the breech (e.g., chamber) plug and as the muzzle plug of a gun disrupter, namely a propellant-driven liquid disrupter. In this manner, a plug formed of an AB material can be used as a shock decoupler between the water column in the barrel and the explosive cartridge, including a blank cartridge, used to propel water out of the barrel in a water jet. Such disrupter platforms generate waves that can adversely impact and even destroy the water jet, as confirmed by high-speed video and in flash X-ray. See, e.g., U.S. Pat. Nos. 10,451,378 and 10,760,872, describing a ReVJeT device useful in enhancing liquid jet parameters. Addressing and avoiding pressure waves are beneficial. When the pressure wave arrives at a water-air interface, it reflects back into the water column as a rarefaction wave (tensor wave). It has the same damaging effect, but to a lesser degree, than the high explosives generated rarefaction waves. Any time there is a transition of a high impedance material (water) to an extremely low impedance material (air) the reflected wave pressure amplitude changes sign. Thus, when the rarefaction wave arrives at the proximal (chamber side) of the water column, it reflects back into the water as a compressive wave. We see the effect as rings of water spraying radially because water cannot withstand hoop stress. The damaging pressure waves are even more pronounced in shorter barrels.
[0162] The AB (e.g., SMART material) attenuates the explosive wave at the proximal end of liquid in the disrupter barrel and then the AB positioned at the muzzle end of the disrupter barrel further attenuates the reflected wave at the distal side of the water column, in a manner similar to that explained in the earlier examples related to the high explosive shaped charges. The tensor wave amplitude is lower.
[0163] In conventional systems having a breech plug that is not an AB, the non-AB plug, due to the muzzle blast, appears to be driven up through the center of the water column of the water jet. It is similar to driving a nail through the middle of the water column, with the result being that the water column is hollowed out. In contrast, a plug formed of an AB, such as a foam material, will break up and atomize. This avoids the problem of a conventional non-AB plug that is driven up the center of the water column and thus degrades and even destroys it and adversely impacts a desired jet parameter useful for target disruption. This reflects the fact that a tube of water has much less penetration than a rod of water.
[0164] In addition, to the advantages of using an AB described for the above mass focusing shaped charges, specially configured and positioned AB provides important functional benefits for water cannons, described herein as a propellant driven disrupters that explosively drive a jet of liquid from a barrel to a target. Referring to
[0165] Breech plug AB can have any of a variety of geometries, including but not limited to, a geometry that is a half-capsule 2761 (
[0166]
[0167]
[0168]
[0169] A cylindrical 2762 (right-angle) AB plug is illustrated in
[0170] The invention is compatible with use of at least one of an AB muzzle plug and AB breech plug. For example, the AB muzzle plug could instead be a JSP, including any of the JSP's provided in U.S. Pat. No. 11,262,155, which is specifically incorporated by reference herein for the JSP geometry, compositions, and uses.
[0171]
STATEMENTS REGARDING INCORPORATION BY REFERENCE AND VARIATIONS
[0172] All references throughout this application, for example patent documents including issued or granted patents or equivalents; patent application publications; and non-patent literature documents or other source material; are hereby incorporated by reference herein in their entireties, as though individually incorporated by reference, to the extent each reference is at least partially not inconsistent with the disclosure in this application (for example, a reference that is partially inconsistent is incorporated by reference except for the partially inconsistent portion of the reference).
[0173] The terms and expressions which have been employed herein are used as terms of description and not of limitation, and there is no intention in the use of such terms and expressions of excluding any equivalents of the features shown and described or portions thereof, but it is recognized that various modifications are possible within the scope of the invention claimed. Thus, it should be understood that although the present invention has been specifically disclosed by preferred embodiments, exemplary embodiments and optional features, modification and variation of the concepts herein disclosed may be resorted to by those skilled in the art, and that such modifications and variations are considered to be within the scope of this invention as defined by the appended claims. The specific embodiments provided herein are examples of useful embodiments of the present invention and it will be apparent to one skilled in the art that the present invention may be carried out using a large number of variations of the devices, device components, methods steps set forth in the present description. As will be obvious to one of skill in the art, methods and devices useful for the present methods can include a large number of optional composition and processing elements and steps.
[0174] As used herein and in the appended claims, the singular forms a, an, and the include plural reference unless the context clearly dictates otherwise. Thus, for example, reference to a cell includes a plurality of such cells and equivalents thereof known to those skilled in the art. As well, the terms a (or an), one or more and at least one can be used interchangeably herein. It is also to be noted that the terms comprising, including, and having can be used interchangeably. The expression of any of claims XX-YY (wherein XX and YY refer to claim numbers) is intended to provide a multiple dependent claim in the alternative form, and in some embodiments is interchangeable with the expression as in any one of claims XX-YY.
[0175] When a group of substituents is disclosed herein, it is understood that all individual members of that group and all subgroups, are disclosed separately. When a Markush group or other grouping is used herein, all individual members of the group and all combinations and subcombinations possible of the group are intended to be individually included in the disclosure.
[0176] Every device, system, formulation, combination of components, or method described or exemplified herein can be used to practice the invention, unless otherwise stated.
[0177] Whenever a range is given in the specification, for example, a temperature range, a time range, or a composition or concentration range, all intermediate ranges and subranges, as well as all individual values included in the ranges given are intended to be included in the disclosure. It will be understood that any subranges or individual values in a range or subrange that are included in the description herein can be excluded from the claims herein.
[0178] All patents and publications mentioned in the specification are indicative of the levels of skill of those skilled in the art to which the invention pertains. References cited herein are incorporated by reference herein in their entirety to indicate the state of the art as of their publication or filing date and it is intended that this information can be employed herein, if needed, to exclude specific embodiments that are in the prior art. For example, when composition of matter are claimed, it should be understood that compounds known and available in the art prior to Applicant's invention, including compounds for which an enabling disclosure is provided in the references cited herein, are not intended to be included in the composition of matter claims herein.
[0179] As used herein, comprising is synonymous with including, containing, or characterized by, and is inclusive or open-ended and does not exclude additional, unrecited elements or method steps. As used herein, consisting of excludes any element, step, or ingredient not specified in the claim element. As used herein, consisting essentially of does not exclude materials or steps that do not materially affect the basic and novel characteristics of the claim. In each instance herein any of the terms comprising, consisting essentially of and consisting of may be replaced with either of the other two terms. The invention illustratively described herein suitably may be practiced in the absence of any element or elements, limitation or limitations which is not specifically disclosed herein.
[0180] One of ordinary skill in the art will appreciate that starting materials, biological materials, reagents, synthetic methods, purification methods, analytical methods, assay methods, and biological methods other than those specifically exemplified can be employed in the practice of the invention without resort to undue experimentation. All art-known functional equivalents, of any such materials and methods are intended to be included in this invention. The terms and expressions which have been employed are used as terms of description and not of limitation, and there is no intention that in the use of such terms and expressions of excluding any equivalents of the features shown and described or portions thereof, but it is recognized that various modifications are possible within the scope of the invention claimed. Thus, it should be understood that although the present invention has been specifically disclosed by preferred embodiments and optional features, modification and variation of the concepts herein disclosed may be resorted to by those skilled in the art, and that such modifications and variations are considered to be within the scope of this invention as defined by the appended claims.