DISC BRAKE PAD AND METHOD FOR THE MANUFACTURING THEREOF
20240052897 ยท 2024-02-15
Assignee
Inventors
Cpc classification
F16D69/023
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C04B35/573
CHEMISTRY; METALLURGY
C04B2235/616
CHEMISTRY; METALLURGY
F16D2200/0047
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B32B18/00
PERFORMING OPERATIONS; TRANSPORTING
C04B35/80
CHEMISTRY; METALLURGY
F16D2069/002
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16D65/092
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C04B2235/483
CHEMISTRY; METALLURGY
C04B2235/80
CHEMISTRY; METALLURGY
International classification
F16D65/092
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16D69/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A pad for disc brakes, a method for the manufacturing thereof, and a braking system with the pad are disclosed. The pad for disc brakes has a thickness y and a first surface cooperating with actuating means of a disc brake. The pad also has a second tribologically active friction surface that cooperates with the disc of the disc brake. The pad also has a first portion and a second portion, where the first portion of the pad extends for a thickness y.sub.1 from the first surface, and the second portion of the pad extends for a thickness y.sub.2 from the second tribologically active friction surface. The first surface and the first portion of the pad are made of carboceramic material, while the second surface and the second portion of the pad are made of carbonaceous material C/C.
Claims
1-20. (canceled)
21. A pad for disc brakes, having a thickness y and comprising: a first surface intended to cooperate with actuating means of a disc brake, a second tribologically active friction surface, opposite to said first surface, intended to cooperate with the disc of a disc brake, a first portion of the pad and a second portion of the pad, wherein said first portion of the pad extends for a thickness y.sub.1 starting from said first surface within said pad, and said second portion of the pad extends for a thickness y.sub.2 starting from said second tribologically active friction surface (3) within said pad, said pad being characterized in that: said first surface and said first portion of the pad are made of a carboceramic material comprising carbon and silicon carbide, and said second tribologically active friction surface and said second portion of the pad are made of a carbon-based material named Carbon-Carbon or C/C.
22. The pad according to claim 21, wherein said first portion of the pad and said second portion of the pad extend across the entire surface area of said pad.
23. The pad according to claim 21, wherein said first surface and said first portion of the pad have a composition by weight which varies within the following ranges: carbon fibers 20-70%, preferably about 30-50% carbon matrix 20-70%, preferably about 30-50% silicon 0-10%, preferably about 0-5% SiC 10-40%, preferably 15-25%.
24. The pad according to claim 21, wherein said first surface and said first portion of the pad have a porosity lower than 3%, preferably lower than 2%, even more preferably lower than 1%, and/or a density comprised between 1.6 g/cm.sup.3 and 2.3 g/cm.sup.3, preferably comprised between 1.7 g/cm.sup.3 and 2.2 g/cm.sup.3, more preferably comprised between 1.8 g/cm.sup.3 and 1.9 g/cm.sup.3.
25. The pad according to claim 21, wherein said second surface and said second portion of the pad have a composition by weight which varies within the following ranges: carbon fibers 25-75%, preferably 40-60% carbon matrix 25-75%, preferably 40-60%.
26. The pad according to claim 21, wherein said second surface and said second portion of the pad have a porosity comprised between 5% and 20%, preferably between 5% and 10%, and/or a density comprised between 1.5 g/cm.sup.3 and 1.9 g/cm.sup.3, preferably comprised between 1.6 g/cm.sup.3 and 1.8 g/cm.sup.3.
27. The pad according to claim 21, wherein the thickness y.sub.1 of said first portion of the pad is comprised between 5% and 90%, between 5% and 70%, between 7% and 50%, between 10% and 30%, of the thickness y of said pad.
28. The pad according to claim 21, wherein the thickness y.sub.2 of said first portion of the pad is comprised between 10% and 95%, between 30% and 95%, between 60% and 90%, between 75% and 85%, preferably is at least 70% or at least 80%, of the thickness y of said pad.
29. A method for manufacturing the pad for disc brakes according to claim 21, comprising the following steps: a) preparing a pad made of C/C material comprising a first surface intended to cooperate with the actuating means of a disc brake and a second surface intended to cooperate with the disc of a disc brake, said pad having a thickness equal to y; b) contacting the pad obtained in step a) with silicon so that at least part of the silicon infiltrates said pad for a thickness equal to y.sub.1 starting from said first surface, said thickness y.sub.1 being less than the thickness y of the pad; c) subjecting the pad obtained in step b) to dry and/or wet finishing.
30. The method according to claim 29, wherein said thickness y.sub.1 of silicon infiltration is comprised between 5% and 90%, between 5% and 70%, between 7% and 50%, between 10% and 30%, of the thickness y of the pad.
31. The method according to claim 29, wherein during said step b), the second surface of the pad intended to cooperate with the disc of a disc brake and a pad portion extending for a thickness y.sub.2 starting from said second surface are not infiltrated with the silicon, said thickness y.sub.2 being preferably comprised between 10% and 95%, between 30% and 95%, between 60% and 90%, between 75% and 85%, more preferably being at least 70% or at least 80%, of the thickness y of said pad.
32. The method according to claim 29, wherein step a) of preparing the pad made of C/C material comprises the following steps: a1) preparing a preform of carbon-densified C/C material; and a2) molding the preform obtained in step a1) into a mold for disc brake pads.
33. The method according to claim 29, wherein the silicon with which the pad is contacted during step b) is in an amount between 3% and 60% by weight, between 3% and 50% by weight, between 3% and 40% by weight, between 5% and 20% by weight, between 5% and 15% by weight, relative to the weight of the pad.
34. The method according to claim 29, wherein said step b) comprises the following steps: b1) arranging the pad obtained in step a) on a layer comprising silicon on the side of said first surface; b2) subjecting the pad arranged on said layer comprising silicon to a temperature so that at least part of the silicon infiltrates by capillarity into the pad for said thickness equal to y.sub.1 starting from said first surface.
35. The method according to claim 34, wherein the layer on which the pad is deposited during step b1) contains solid silicon.
36. The method according to claim 34, wherein step b2) comprises a liquid silicon infiltration (LSI) process conducted at a temperature above the melting temperature of the silicon, preferably at a temperature above 1410 C., more preferably comprised between 1420 C. and 1700 C., and/or at a pressure comprised between 20 mbar and 150 mbar, preferably between 80 mbar and 120 mbar.
37. The method according to claim 29, wherein said step b) comprises the following steps: b1) immersing the pad obtained in step a) in a bath comprising a silicone resin for a thickness substantially equal to y.sub.1 starting from said first surface, said thickness substantially equal to y.sub.1 being less than the thickness y of the pad; b2) subjecting the pad partially immersed in said bath to a temperature such that said pad is impregnated with at least part of said silicone resin to a thickness equal to y.sub.1 starting from said first surface.
38. The method according to claim 37, wherein step b2) comprises a process of impregnating the pad with the resin, said process being conducted at a temperature comprised between 750 C. and 1500 C., preferably comprised between 800 C. and 900 C.
39. A pad for disc brakes as obtainable by the method according to claim 29.
40. A braking system for disc brakes comprising a disc and a pad according to claim 21, said disc being made of C/C material and said pad being intended to cooperate with said disc.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0032]
[0033]
DETAILED DESCRIPTION OF THE INVENTION
[0034] It is an object of the present invention to provide a disc brake pad comprising a first surface intended to cooperate with actuating means of a disc brake and a second surface intended to cooperate with the disc of a disc brake, wherein the first surface and a portion of the pad extending for a given thickness from said first surface are made of a carboceramic material comprising carbon and silicon carbide, while the second surface and a portion of the pad which extends for a given thickness from said second surface are made of a C/C carbonaceous material.
[0035] Surprisingly, it has been found that the portion delimited by the first surface of the pad (named first portion) acts as a mechanical support for the carbonaceous material C/C of the portion delimited by the second surface (named second portion) which defines the tribologically active part of the pad, increasing the stiffness and the compressive strength of the pad itself and making the use of external ceramic or metal plates unnecessary, thus avoiding all the disadvantages associated therewith. Additionally, said second portion advantageously maintains the performances in terms of friction coefficient that are characteristic of C/C materials, which make it suitable to collaborate with a disc also made of carbonaceous material.
[0036] Furthermore, by virtue of the increased stiffness of the pad of the present invention, it has been surprisingly found that it is possible to increase the number of the ventilation openings and, therefore, the heat exchange, of the pad. Also by virtue of a better heat dissipation, the pad according to the present invention is suitable for use in braking systems of sport and high-performance cars.
[0037] A cross-section of the pad object of the present invention is shown in
[0038] The pad 1 shown in
[0039] The pad 1 has a thickness y and is divided into two portions along the transverse axis of the pad itself. In particular, said pad 1 is divided into a first portion 4 and a second portion 5.
[0040] Said first portion 4 is delimited by the surface 2 of the pad and extends inside the pad for a thickness equal to y.sub.1. Said first portion 4 is made of a carboceramic material comprising carbon and silicon carbide.
[0041] Said second portion 5 is delimited by the surface 3 of the pad and extends inside the pad for a thickness equal to y.sub.2. Said second portion 5 is made of a carbonaceous material C/C.
[0042] Preferably, said first portion 4 and said second portion 5 extend across the entire surface area of the pad. In other words, the surface 2 of the pad intended to cooperate with actuating means of a disc brake coincides with the surface of the first portion of the pad, and the surface 3 of the pad intended to cooperate with the disc of a disc brake coincides with the surface of the second portion of the pad.
[0043] The second surface 3 of the pad, thus the second portion 5 of the pad as well, are subject to wear. The thickness y.sub.1 of the first portion 4 of the pad is function of the minimum worn out thickness K admissible for a specific pad. The expression minimum worn out thickness K denotes the minimum admissible thickness of a worn out pad, i.e., worn due to friction of the second surface 3 against the disc of a disc brake. In other words, the thickness of the pad which is worn out, namely consumed, over time corresponds to the dimension (yK). The thickness y.sub.1 of the first portion 4 of the pad is advantageously less than said thickness K (y.sub.1<K) and the thickness y.sub.2 of the second portion 5 of the pad is advantageously always greater than zero (y.sub.2>0) even after wear of the pad.
[0044] The thickness y.sub.1 of said first portion of the pad is comprised preferably between 5% and 90%, between 5% and 70%, between 7% and 50%, between 10% and 30%, of the thickness y of said pad.
[0045] The thickness y.sub.2 of the second portion of the pad is comprised preferably between 10% and 95%, between 30% and 95%, between 60% and 90%, between 75% and 85%, more preferably is at least 70% or at least 80%, of the thickness y of said pad.
[0046] In a preferred embodiment, said first surface and said first portion of the pad, which are made of carboceramic material, comprise silicon, carbon, and silicon carbide.
[0047] Preferably, said first surface and said first portion of the pad have a composition, expressed as weight percentages, which varies in the ranges shown below: [0048] carbon fibers 20-70%, preferably about 30-50% [0049] carbon matrix 20-70%, preferably about 30-50% [0050] silicon 0-10%, preferably about 0-5% [0051] SiC 10-40%, preferably 15-25%.
[0052] According to an embodiment, said first surface contains a higher weight percentage amount of silicon carbide (SiC) and, optionally, of silicon than that contained in the first portion of the pad.
[0053] According to an embodiment, said first portion of the pad contains a greater percentage amount by weight of silicon carbide (SiC) and, optionally, of silicon near the first surface and a gradually decreasing amount thereof as one moves away from said first surface.
[0054] In a preferred embodiment, said second portion of the pad, which is made of C/C material, has a composition, expressed as percentages by weight, which may vary in the ranges shown below: [0055] carbon fibers 25-75%, preferably 40-60% [0056] carbon matrix 25-75%, preferably 40-60%.
[0057] Said first surface and said first portion of the pad, which are made of carboceramic material, have a porosity preferably lower than 3%, more preferably lower than 2%, even more preferably lower than 1%.
[0058] Said first surface and said first portion of the pad, which are made of carboceramic material, have a density preferably comprised between 1.6 g/cm.sup.3 and 2.3 g/cm.sup.3, more preferably comprised between 1.7 g/cm.sup.3 and 2.2 g/cm.sup.3, even more preferably comprised between 1.8 g/cm.sup.3 and 1.9 g/cm.sup.3.
[0059] Such porosity and density values confer the appropriate stiffness characteristics to the carboceramic material of the first surface and of the first portion of the pad so that they can work as mechanical support for the second surface and the second portion of the pad. Advantageously, the pad according to the present invention does not comprise a support plate, e.g., made of a ceramic or metallic material.
[0060] The second tribologically active friction surface and the second portion of the pad have a porosity preferably comprised between 5% and 20%, more preferably comprised between 5% and 10%, and a density preferably comprised between 1.5 g/cm.sup.3 and 1.9 g/cm.sup.3, more preferably comprised between 1.6 g/cm.sup.3 and 1.8 g/cm.sup.3, able to impart lightness to the pad.
[0061] The pad object of the present invention has surprisingly exhibited an optimal weight-to-stiffness ratio.
[0062] In a first embodiment of the invention, the sum of the thickness y.sub.1 of said first portion and the thickness y.sub.2 of said second portion coincides with the thickness y of the pad.
[0063] In a further embodiment, said pad comprises a layer of material intermediate between said first portion and said second portion which possesses characteristics intermediate between the carboceramic material of the first portion and the C/C material of the second portion.
[0064] Preferably, said layer of material comprises carbon fibers, a carbon matrix, silicon carbide and, optionally, silicon. Preferably, said layer of material comprises silicon and silicon carbide in an amount lower than that contained in the first portion of the pad, preferably comprises silicon in an amount by weight lower than 5% and/or silicon carbide in an amount by weight lower than 10%.
[0065] The pad according to the present invention is obtained by a method according to the claims.
[0066] In a preferred embodiment, the step a) of the aforesaid method regarding the manufacturing of a pad made of C/C material comprises the following steps: [0067] a1) preparing a preform of carbon-densified C/C material; and [0068] a2) molding the preform obtained in step a1) into a mold for disc brake pads.
[0069] In a preferred embodiment, the aforesaid step a1) comprises the following steps: [0070] i) printing layers of resin-impregnated two-dimensional fabric to form a preform model; [0071] ii) optionally, printing short fibers impregnated with resin to form a preform model; [0072] iii) optionally, printing short fibers mixed with resins, said resins being liquid or in powder form, to form a preform model; [0073] iv) optionally, needling the aforesaid layers of fabric stacked to form an entangled three-dimensional structure; [0074] v) optionally, needling the aforesaid short fibers to form an entangled three-dimensional structure; [0075] vi) optionally, pyrolyzing the preform model obtained in one of the steps i), ii) or iii); [0076] vii) optionally, impregnating with resins and/or pitches the preform model obtained in one of the steps iv) or v); [0077] viii) optionally, subjecting the preform model obtained in one of the steps i), ii), iii), iv), v), vi) or vii) to a thermal pretreatment; [0078] ix) subjecting the preform model obtained in one of the steps i), ii), iii), iv), v), vi), vii), or viii) to a carbon densification process until obtaining a material density greater than 1.5 g/cm.sup.3, preferably greater than 1.7 g/cm.sup.3; [0079] x) optionally, subjecting the preform model obtained in step v) to a heat treatment.
[0080] In a preferred embodiment, the fabric used in step i) is a carbon fiber fabric.
[0081] The needling of step iv) can be conducted using conventional methods, which involve the use of appropriate needles which engage part of the fibers directing them axially to the pad and allowing three-dimensional structures to be obtained.
[0082] The resins of steps i), ii), iii) and vii) are selected, for example, from the group consisting of phenolic resins, acrylic resins, polystyrene, furan resins, or cyanoesters.
[0083] According to different embodiments, the carbon-densification process according to step ix) is conducted by means of different methods.
[0084] A first method is CVD (Chemical Vapor Deposition) or CVI (Chemical Vapor Infiltration), depending on whether only a coating or an infiltration of carbon in vapor form is desired. Typically, if the material is fibrous and thus has a high porosity, this method is referred to as Chemical Vapor Infiltration (CVI). These methods involve the use of hydrocarbon mixtures (e.g., methane and propane) and the exposure of the material to be treated to such mixtures at high temperatures and low pressures. The operating temperatures are in the range of 900-1200 C., preferably 1000-1100 C., and pressures lower than 300 mbar are used, preferably of a few tens of mbar. The hydrocarbon mixtures decompose to form elemental carbon, which is then deposited or infiltrated into the matrix of the material being treated. This method, which requires the use of dedicated furnaces, involves the deposition of a thin layer (typically a few microns) on the fibers; therefore, several cycles of infiltration and overall coatings on the fibers higher than ten microns (typically 10-20 microns) are required in order to obtain the desired densification.
[0085] A different method, known as LPI (Liquid Polymer Infiltration) or PIP (Polymer Infiltration and Pyrolysis) involves the infiltration of the matrix of the material to be treated with a liquid polymer and the subsequent high-temperature heat treatment (pyrolysis) which causes the carbonization of the polymer deposited on the carbon fibers. Also in this case, several steps of infiltration and pyrolysis are required before appropriate densification of the preform is achieved.
[0086] Regardless of the method used for the step ix) of carbon densification, the density of the material of the preform is typically greater than 1.5 g/cm.sup.3.
[0087] In a preferred embodiment, the step a2) of molding the preform obtained during the previous step a1) is performed by operating at a temperature comprised between 80 C. and 200 C., preferably between 120 C. and 180 C. Preferably, said step a2) of molding is performed by operating at a pressure comprised between 25 and 300 bar, more preferably between 35 and 150 bar.
[0088] During step b), the pad is contacted with silicon so that at least part of the silicon infiltrates the pad for a thickness equal to y.sub.1 starting from the first surface intended to cooperate with actuating means of a disc brake.
[0089] Advantageously, at least said first surface of the pad is contacted with silicon. Advantageously, the second surface of the pad is not contacted with silicon.
[0090] According to a first embodiment, said step b) comprises the following steps: [0091] b1) arranging the pad obtained in step a) on a layer comprising silicon on the side of said first surface; [0092] b2) subjecting the pad arranged on said layer comprising silicon to a temperature so that at least part of the silicon infiltrates by capillarity into the pad for said thickness equal to y.sub.1 starting from said first surface.
[0093] According to a second embodiment, said step b) comprises the following steps: [0094] b1) immersing the pad obtained in step a) in a bath comprising a silicone resin for a thickness substantially equal to y.sub.1 starting from said first surface, said thickness substantially equal to y.sub.1 being less than the thickness y of the pad; [0095] b2) subjecting the pad partially immersed in said bath to a temperature such that said pad is impregnated with at least part of said silicone resin to a thickness equal to y.sub.1 starting from said first surface.
First Embodiment (Layer Comprising Silicon)
[0096] In a first embodiment, said layer comprises solid silicon. Said layer may comprise one or more materials in addition to solid silicon, e.g. boron carbide (B.sub.4C). According to this embodiment, the boron carbide is present in the aforesaid layer in a percentage by weight preferably comprised between 5% and 50%, more preferably comprised between 5% and 20%.
[0097] In a second embodiment, said layer consists of solid silicon.
[0098] According to different embodiments, the solid silicon is in pure form or in the form of silicon/aluminum or silicon/copper alloy and is in granules or powder form.
[0099] Hereafter, the term silicon layer is used both with reference to a layer comprising solid silicon and with reference to a layer consisting of solid silicon.
[0100] In an embodiment, during step b1) said pad is deposited directly on the silicon layer. The term directly refers to the fact that said pad is in contact with the silicon layer and there are no additional means or elements interposed between the pad and the silicon layer.
[0101] In a further embodiment, during step b1) said pad is deposited on the silicon layer through external means or elements, e.g. porous partitions, such as felts, pyrolyzed wood elements, or pegs. According to this embodiment, during step b1) the pad is not in contact with the silicon comprised in the layer. According to this embodiment, the pad will come into contact with the silicon during the step b2) of infiltration.
[0102] The step b2) of infiltration with silicon is conducted in an appropriate treatment chamber, provided with vents for the gases that are released during the treatment.
[0103] Said step b2) of infiltration advantageously comprises a liquid silicon infiltration (LSI) process, during which the silicon layer is subjected to a temperature above the melting temperature of the silicon, such that the silicon melts and infiltrates by capillarity into said pad for a thickness equal to y.sub.1, as defined above.
[0104] According to this embodiment, the treatment chamber is introduced into a conventional type furnace, which is heated to a temperature preferably above 1410 C., more preferably comprised between 1420 C. and 1700 C., e.g. at about 1500 C. At these temperatures, the silicon melts and infiltrates the pores of the pad surface which is in contact with the silicon and reacts with part of the carbon of the carbon fibers and/or of the carbon matrix to form silicon carbide (SiC). Preferably, a portion of the molten silicon reacts with the carbon to give silicon carbide and a portion of the silicon remains unreacted. The unreacted silicon solidifies within the material of the pad during a step of cooling. Both the heating to the temperature of treatment and the successive cooling are conducted gradually. For example, it can take up to 8 or more hours to reach a temperature of treatment of about 1500 C. and a similar amount of time to cool the infiltrated pad.
[0105] Preferably, said step b2) of silicon infiltration is conducted at a reduced pressure comprised between 20 mbar and 150 mbar, more preferably between 80 mbar and 120 mbar.
Second Embodiment (Bath Comprising Silicone Resin)
[0106] As mentioned above, step b1) involves immersing the pad in a bath comprising a silicone resin for a thickness substantially equal to y.sub.1 starting from said first surface.
[0107] The term silicone resin refers to an inorganic polymer based on a siliconoxygen chain and organic functional groups bonded to the silicon atoms.
[0108] As mentioned above, step b2) comprises a process of impregnating the pad with the silicone resin.
[0109] Preferably, said process of impregnating the pad with the silicone resin is conducted at a temperature comprised between 750 C. and 1500 C., more preferably comprised between 800 C. and 900 C.
[0110] For example, said process of impregnating the pad with the silicone resin is conducted at atmospheric pressure.
[0111] Under these process conditions, the silicon in the form of a resin infiltrates the pores of the pad and reacts with part of the carbon of the silicone resin and/or with part of the carbon of the carbon fibers and/or with part of the carbon of the carbon matrix to form silicon carbide (SiC). Preferably, a portion of the silicon reacts with the carbon to give silicon carbide and a portion of the silicon remains unreacted.
[0112] The term substantially equal to y.sub.1 denotes a thickness such that at the end of step b2) the pad is impregnated with the silicone resin to a thickness equal to y.sub.1.
[0113] The description below applies to both embodiments.
[0114] The amount of silicon with which the pad is contacted during step b) is preferably comprised between 3% and 60% by weight, between 3% and 50% by weight, between 3% and 40% by weight, between 5% and 20% by weight, between 5% and 15% by weight, relative to the total weight of the pad. Said amount refers, respectively, to the silicon present in the silicon layer as defined above (first embodiment) and to the silicon present in the silicone resin (second embodiment).
[0115] The amount of silicon with which the pad is contacted in step b) is that required to partially fill the porosity of the C/C material which constitutes the pad. In particular, said amount of silicon is the amount required to at least partially fill the porosity of the first surface, through which the pad is deposited on said silicon layer or immersed in said silicone resin bath, and of a first portion of the pad extending through said thickness y.sub.1 starting from said first surface. In particular, said amount of silicon is such to fill neither the porosity of the second surface of the pad, opposite to said first surface, nor the porosity of a second portion of the pad extending for a thickness y.sub.2 starting from said second surface.
[0116] Preferably, the silicon infiltration thickness y.sub.1 is comprised between 5% and 90%, between 5% and 70%, between 7% and 50%, between 10% and 30%, of the thickness y of the pad.
[0117] Preferably, the thickness y.sub.2 is comprised between 10% and 95%, between 30% and 95%, between 60% and 90%, between 75% and 85%, more preferably is at least 70% or at least 80%, of the thickness y of the pad.
[0118] Preferably, the amount of silicon with which the pad is contacted is the amount required to fill from 30% to 100% of the porosity of the C/C material which constitutes the first surface and the first portion of the pad having thickness y.sub.1. Said first surface and said first portion of the pad having thickness y.sub.1 thus result densified with the silicon carbide and optionally with the silicon, and the resulting porosity of said first surface and said first portion of the pad is preferably lower than 3%, more preferably lower than 2%, even more preferably lower than 1%.
[0119] In other words, the amount of silicon present in said layer or in said bath is less than that required to completely infiltrate the pad.
[0120] The process parameters described above with reference to step b2) (temperature and pressure) are such as to promote a partial ascent by capillarity (first embodiment) or a partial impregnation (second embodiment) of the silicon through the pad, in particular for a thickness equal to y.sub.1 starting from the first surface of the pad. Said thickness y.sub.1 of the pad results densified with the silicon carbide and optionally with the silicon, which close the porosity of the material which constitutes said thickness y.sub.1 to values preferably lower than 3%, more preferably lower than 2%, even more preferably lower than 1%.
[0121] The thickness y.sub.1 of silicon infiltration, and thus also the amount of silicon with which the pad is contacted in step b), depends on the final application of the pad and its degree of wear. For example, in a pad with an initial thickness of 25 mm (dimension y in
[0122] Said thickness y.sub.1 of infiltration is monitored, for example, by analyzing a section of the pad by SEM microscopy.
[0123] Advantageously, the tribologically active friction surface of the pad intended to cooperate with the disc does not contain, or contains a negligible amount of, silicon carbide and optionally silicon. The term negligible denotes an amount of silicon carbide and, optionally, silicon which does not alter the coefficient of friction of the C/C material, preferably an amount less than 0.5%, more preferably less than 0.3%, even more preferably less than 0.1%, than the weight of the pad.
[0124] Advantageously, the second portion of the pad delimited by said tribologically active friction surface does not contain, or contains a negligible amount of, silicon carbide and optionally silicon. In this case, the term negligible denotes a quantity of silicon carbide and, optionally, silicon such that the tribologically active friction surface maintains its coefficient of friction unchanged even after wear of the pad and detachment from it of part of the C/C material with which this surface is made.
[0125] During the step c) of finishing, each surface deformation is removed from the two surfaces. Such a finishing treatment is preferably conducted dry, e.g., by diamond polishing.
[0126] The pad obtained according to the method of the present invention has demonstrated extremely advantageous properties.
EXAMPLE
[0127] A pad made of C/C material having an initial thickness of 20 mm and an initial weight of about 250 g was subjected to the method according to the present invention.
[0128] In particular, said pad made of C/C material was deposited on a layer consisting of solid silicon. The starting dose of solid silicon is 7.5% by weight relative to the weight of the pad.
[0129] Said pad was then subjected to a stage of LSI (Liquid Silicon Infiltration), conducted at a maximum temperature of 1500 C. and a pressure of 100 mbar.
[0130] Compared to the pad made of C/C material, the pad resulting from the above method of partial infiltration exhibited a stiffness increase of 75% and a weight increase of 6%. The increase in stiffness more than compensated for the increase in pad weight, so the pad exhibits an optimal weight-to-stiffness ratio.
[0131] The chart in
[0132] It is clear that what has been described is just a particular embodiment of the present invention. The person skilled in the art will be able to bring any necessary modifications both to the pad and the method for obtaining it in order to adapt them to particular conditions, without however departing from the scope of protection as defined in the attached claims.