A SYNERGISTIC PERFUMING COMPOSITION

Abstract

The present invention relates to the field of perfumery. More particularly, it concerns perfuming composition of matter as defined above. Following what is mentioned herein, the invention's perfuming composition matter as a part of a perfuming composition or a perfumed consumer product and the use of the invention's perfuming composition are also objects of the invention.

Claims

1. A perfuming composition of matter comprising a) at least one compound selected from the group consisting of 2-methyl-3-[4-(2-methyl-2-propanyl)phenyl]propanal, 3-(4-isobutyl-2-methylphenyl)propanal, 9-hydroxy-5,9-dimethyl-4-decenal, 1-(4-isopropyl-1-cyclohexyl)-1-ethanol, 2,2-dimethyl-3-(3-methylphenyl)-1-propanol, 7-hydroxy-3,7-dimethyloctanal, 4-(2-propanyl)cyclohexyl]methanol, 3-(4-methoxyphenyl)-2-methylpropanal, 3-(4-tert-butylphenyl)propanal, 3-(4-isopropylphenyl)-2-methylpropanal, (4E)-4-methyl-5-(4-methylphenyl)-4-pentenal, 3/4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carbaldehyde, tetrahydro-2-isobutyl-4-methyl-4(2H)-pyranol, (2,5-Dimethyl-2,3-dihydro-1H-inden-2-yl)methanol, (+)-8,8-dimethyl-1,2,3,4,5,6,7,8-octahydro-2-naphthalenecarbaldehyde, (+)-8,8-dimethyl-1,2,3,5,6,7,8,8a-octahydro-2-naphthalenecarbaldehyde, (+)-8,8-dimethyl-1,2,3,4,6,7,8,8a-octahydro-2-naphthalenecarbaldehyde, (+)-2,2-dimethyltricyclo[6.2.1.0.sup.1,6]undecan-7-one and a mixture thereof; b) at least one compound selected from the group consisting of tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate, tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate, benzyl propanoate, 2-cyclohexylethyl acetate, cyclohexyl acetate, tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl acetate, tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl acetate and a mixture thereof; c) at least one compound selected from the group consisting of 1-((2RS,3RS)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethanone, 1-[(2RS,3RS,8aRS)-2,3,8,8-tetramethyl-1,2,3,5,6,7,8,8a-octahydro-2-naphthalenyl]ethanone, 1-[(2RS,3RS,8aRS)-2,3,8,8-tetramethyl-1,2,3,4,6,7,8,8a-octahydro-2-naphthalenyl]ethanone, 1-[(1RS,2RS)-1,2,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydro-2-naphthalenyl]ethanone, 1-[(1RS,2RS,8aSR)-1,2,8,8-tetramethyl-1,2,3,5,6,7,8,8a-octahydro-2-naphthalenyl]ethenone, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8,-tetramethyl-2-naphthyl)ethan-1-one, (1-ethoxyethoxy)cyclododecane, (ethoxymethoxy)cyclododecane and a mixture thereof; d) at least one compound selected from the group consisting of cyclohexyl 2-hydroxybenzoate, 2-methylbutyl salicylate, pentyl salicylate, 2-phenylethyl 2-hydroxybenzoate, hexyl 2-hydroxybenzoate, benzyl salicylate, (3Z)-3-hexen-1-yl salicylate, (Z)-3-hexen-1-yl benzoate and a mixture thereof; e) at least one compound selected from the group consisting of cyclohexylidene(phenyl)acetonitrile, dodecanenitrile, 3,7-dimethyl-6-octenenitrile, 2,6-nonadienenitrile, 2-tridecenenitrile, 3-tridecenenitrile 3,7-dimethyl-2,6-nonadienenitrile, 2-phenyl-2-hexenenitrile, 3,12-tridecadienenitrile, 3-methyl-5-phenyl-2-pentenenitrile, 2-methyldecanenitrile and a mixture thereof; f) at least one compound selected from the group consisting of (+)-2-methylundecanal, 2-methyldecanal and a mixture thereof; g) at least one compound selected from the group consisting of patchouli oil, (1R,3R,6S,7S,8S)-2,2,6,8-tetramethyltricyclo[5.3.1.0.sup.3,8]undecan-3-ol and a mixture thereof; h) at least one compound selected from the group consisting of (+)-3-(4-methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehyde, (+)-4-(4-methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehyde, 3-methyl-5-phenylpentanal, 4-decenal, 2-decenal and a mixture thereof; i) at least one compound selected from the group consisting of (2E)-1-[(1RS,2SR)-2,6,6-trimethyl-3-cyclohexen-1-yl]-2-buten-1-one, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-buten-1-one, 1-(2,4,4-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one, 1-(2,4,4-trimethyl-1-cyclohexen-1-yl)-2-buten-1-one, 1-(2,2-dimethyl-6-methylenecyclohexyl)-2-buten-1-one and a mixture thereof; j) at least one compound selected from the group consisting of limonene, 2,4,4,7-tetramethyl-6,8-nonadien-3-one oxime, 2-(4-methyl-3-cyclohexen-1-yl)-2-propanethiol, orange oil and a mixture thereof; k) at least one compound selected from the group consisting of 2-methoxynaphthalene, methyl n-(2-hexyl-3-phenyl-2-propenylidene)anthranilate, methyl n-(3,5,5-trimethylhexylidene)anthranilate, methyl 2-((2,4-dimethylcyclohex-3-enylidene)methylamino)benzoate, methyl n-(1-octenyl)anthranilate, methyl n-(4-methoxybenzylidene)anthranilate, methyl n-[3-(4-tert-butylphenyl)-2-methyl-1-propenyl]anthranilate, methyl 2-({[3/4-(4-hydroxy-4-methylpentyl)-3-cyclohexen-1-ylidene]methyl}amino)benzoate, methyl n-benzylideneanthranilate, methyl n-(2-phenylethylidene)anthranilate, methyl n-[3-(1,3-benzodioxo1-5-yl)-2-methyl-1-propenyl]anthranilate, methyl n-[2-(4-methoxybenzyl)-1-propenyl]anthranilate, methyl n-(7-hydroxy-3,7-dimethyl-1-octenyl)anthranilate, methyl 2-(((E)-3-phenylallylidene)amino)benzoate, methyl 2-(decylideneamino)benzoate, methyl [3/4-(4-hydroxy-4-methylpentyl)-3-cyclohexen-1-yl]methyleneanthranilate, methyl 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]benzoate, methyl (3S)-n-(7-hydroxy-3,7-dimethyloctylidene)anthranilate, methyl n-[2-(4-methoxybenzyl)propylidene]anthranilate, ethyl 2-{[(2,4/3,5-dimethyl-3-cyclohexen-1-yl)methyl]amino}benzoate, ethyl 2-{[(1E)-(4-tert-butylphenyl)methylene]amino}benzoate, methyl n-(octylidene)anthranilate, methyl n-[3-(p-tert-butylphenyl)-2-methylpropylidene]anthranilate, methyl n-[3-(4-isopropyl-1-phenyl)-2-methylpropylidene]anthranilate, 2-ethoxynaphthalene, 1-(5,6,7,8-tetrahydro-2-naphthalenyl)ethanone, 1-(3-methyl-1-benzofuran-2-yl)ethanone, 1-(1-naphthyl)ethanone, 1-(2-naphthyl)ethanone, methyl 2-aminobenzoate, methyl n-(7-hydroxy-3,7-dimethyl-1-octenyl)anthranilate, methyl 2-(methylamino)benzoate and a mixture thereof; l) at least one compound selected from the group consisting of oxacyclohexadecan-2-one, oxacycloheptadecan-2-one, 1-oxa-12-cyclohexadecen-2-one, 1-oxa-13-cyclohexadecen-2-one and a mixture thereof; m) at least one compound selected from the group consisting of dodecahydro-3a,6,6,9a-tetramethyl-naphtho[2,1-b]furan or any of its stereoisomers and a mixture thereof; n) at least one compound selected from the group consisting of 1,1-oxydibenzene, 4-methyl-2-phenyltetrahydro-2H-pyran, tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-1H-pyran, (+)-4-methylene-2-phenyltetrahydro-2H-pyran, (+)-4-methyl-6-phenyl-3,6-dihydro-2H-pyran, (+)-4-methyl-2-phenyl-3,6-dihydro-2H-pyran and a mixture thereof; and o) at least one compound selected from the group consisting of 10-undecenal, 9-undecenal, decanal and a mixture thereof.

2. The perfuming composition according to claim 1, wherein the perfuming composition of matter comprises a) at least one compound selected from the group consisting of 2-methyl-3-[4-(2-methyl-2-propanyl)phenyl]propanal, 3-(4-isobutyl-2-methylphenyl)propanal, 9-hydroxy-5,9-dimethyl-4-decenal, 1-(4-isopropyl-1-cyclohexyl)-1-ethanol, 2,2-dimethyl-3-(3-methylphenyl)-1-propanol, 7-hydroxy-3,7-dimethyloctanal, 4-(2-propanyl)cyclohexyl]methanol, 3-(4-methoxyphenyl)-2-methylpropanal, 3-(4-tert-butylphenyl)propanal, 3-(4-isopropylphenyl)-2-methylpropanal, (4E)-4-methyl-5-(4-methylphenyl)-4-pentenal, 3/4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carbaldehyde, tetrahydro-2-isobutyl-4-methyl-4(2H)-pyranol, (2,5-Dimethyl-2,3-dihydro-1H-inden-2-yl)methanol, (+)-8,8-dimethyl-1,2,3,4,5,6,7,8-octahydro-2-naphthalenecarbaldehyde, (+)-8,8-dimethyl-1,2,3,5,6,7,8,8a-octahydro-2-naphthalenecarbaldehyde, (+)-8,8-dimethyl-1,2,3,4,6,7,8,8a-octahydro-2-naphthalenecarbaldehyde, (+)-2,2-dimethyltricyclo[6.2.1.0.sup.1,6]undecan-7-one and a mixture thereof; b) at least two compounds selected from the group consisting of tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate, tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate, benzyl propanoate, 2-cyclohexylethyl acetate, cyclohexyl acetate, tricyclo[5.2.1.0.sup.2,6]dec-3-en-8-yl acetate, tricyclo[5.2.1.0.sup.2,6]dec-4-en-8-yl acetate and a mixture thereof; c) at least three compounds selected from the group consisting of 1-((2RS,3RS)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethanone, 1-[(2RS,3RS,8aRS)-2,3,8,8-tetramethyl-1,2,3,5,6,7,8,8a-octahydro-2-naphthalenyl]ethanone, 1-[(2RS,3RS,8aRS)-2,3,8,8-tetramethyl-1,2,3,4,6,7,8,8a- octahydro-2-naphthalenyl]ethanone, 1-[(1RS,2RS)-1,2,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydro-2-naphthalenyl]ethanone, 1-[(1RS,2RS,8aSR)-1,2,8,8-tetramethyl-1,2,3,5,6,7,8,8a-octahydro-2-naphthalenyl]ethenone, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8,-tetramethyl-2-naphthyl)ethan-1-one, (1-ethoxyethoxy)cyclododecane, (ethoxymethoxy)cyclododecane and a mixture thereof; d) at least three compounds selected from the group consisting of cyclohexyl 2-hydroxybenzoate, 2-methylbutyl salicylate, pentyl salicylate, 2-phenylethyl 2-hydroxybenzoate, hexyl 2-hydroxybenzoate, benzyl salicylate, (3Z)-3-hexen-1-yl salicylate, (Z)-3-hexen-1-yl benzoate and a mixture thereof; e) at least one compound selected from the group consisting of cyclohexylidene(phenyl)acetonitrile, dodecanenitrile, 3,7-dimethyl-6-octenenitrile, 2,6-nonadienenitrile, 2-tridecenenitrile, 3-tridecenenitrile 3,7-dimethyl-2,6-nonadienenitrile, 2-phenyl-2-hexenenitrile, 3,12-tridecadienenitrile, 3-methyl-5-phenyl-2-pentenenitrile, 2-methyldecanenitrile and a mixture thereof; f) at least one compound selected from the group consisting of (+)-2-methylundecanal, 2-methyldecanal and a mixture thereof; g) at least one compound selected from the group consisting of patchouli oil, (1R,3R,6S,7S,8S)-2,2,6,8-tetramethyltricyclo[5.3.1.0.sup.3,8]undecan-3-ol and a mixture thereof; h) at least two compounds selected from the group consisting of (+)-3-(4-methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehyde, (+)-4-(4-methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehyde, 3-methyl-5-phenylpentanal, 4-decenal, 2-decenal and a mixture thereof; i) at least one compound selected from the group consisting of (2E)-1-[(1RS,2SR)-2,6,6-trimethyl-3-cyclohexen-1-yl]-2-buten-1-one, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-buten-1-one, 1-(2,4,4-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one, 1-(2,4,4-trimethyl-1-cyclohexen-1-yl)-2-buten-1-one, 1-(2,2-dimethyl-6-methylenecyclohexyl)-2-buten-1-one and a mixture thereof; j) at least two compounds selected from the group consisting of limonene, 2,4,4,7-tetramethyl-6,8-nonadien-3-one oxime, 2-(4-methyl-3-cyclohexen-1-yl)-2-propanethiol, orange oil and a mixture thereof; k) at least one compound selected from the group consisting of 2-methoxynaphthalene, methyl n-(2-hexyl-3-phenyl-2-propenylidene)anthranilate, methyl n-(3,5,5-trimethylhexylidene)anthranilate, methyl 2-((2,4-dimethylcyclohex-3-enylidene)methylamino)benzoate, methyl n-(1-octenyl)anthranilate, methyl n-(4-methoxybenzylidene)anthranilate, methyl n-[3-(4-tert-butylphenyl)-2-methyl-1-propenyl]anthranilate, methyl 2-({[3/4-(4-hydroxy-4-methylpentyl)-3-cyclohexen-1-ylidene]methyl}amino)benzoate, methyl n-benzylideneanthranilate, methyl n-(2-phenylethylidene)anthranilate, methyl n-[3-(1,3-benzodioxol-5-yl)-2-methyl-1-propenyl]anthranilate, methyl n-[2-(4-methoxybenzyl)-1-propenyl]anthranilate, methyl n-(7-hydroxy-3,7-dimethyl-1-octenyl)anthranilate, methyl 2-(((E)-3-phenylallylidene)amino)benzoate, methyl 2-(decylideneamino)benzoate, methyl [3/4-(4-hydroxy-4-methylpentyl)-3-cyclohexen-1-yl]methyleneanthranilate, methyl 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]benzoate, methyl (3S)-n-(7-hydroxy-3,7-dimethyloctylidene)anthranilate, methyl n-[2-(4-methoxybenzyl)propylidene]anthranilate, ethyl 2-{[(2,4/3,5-dimethyl-3-cyclohexen-1-yl)methyl]amino}benzoate, ethyl 2-{[(1E)-(4-tert-butylphenyl)methylene]amino}benzoate, methyl n-(octylidene)anthranilate, methyl n-[3-(p-tert-butylphenyl)-2-methylpropylidene]anthranilate, methyl n-[3-(4-isopropyl-1-phenyl)-2-methylpropylidene]anthranilate, 2-ethoxynaphthalene, 1-(5,6,7,8-tetrahydro-2-naphthalenyl)ethanone, 1-(3-methyl-1-benzofuran-2-yl)ethanone, 1-(1-naphthyl)ethanone, 1-(2-naphthyl)ethanone, methyl 2-aminobenzoate, methyl n-(7-hydroxy-3,7-dimethyl-1-octenyl)anthranilate, methyl 2-(methylamino)benzoate and a mixture thereof; l) at least two or three compounds selected from the group consisting of oxacyclohexadecan-2-one, oxacycloheptadecan-2-one, 1-oxa-12-cyclohexadecen-2-one, 1-oxa-13-cyclohexadecen-2-one and a mixture thereof; m) at least one compound selected from the group consisting of dodecahydro-3a,6,6,9a-tetramethyl-naphtho[2,1-b]furan or any of its stereoisomers and a mixture thereof; n) at least one compound selected from the group consisting of 1,1-oxydibenzene, 4-methyl-2-phenyltetrahydro-2H-pyran, tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2H-pyran, (+)-4-methylene-2-phenyltetrahydro-2H-pyran, (+)-4-methyl-6-phenyl-3,6-dihydro-2H-pyran, (+)-4-methyl-2-phenyl-3,6-dihydro-2H-pyran and a mixture thereof; and o) at least two compounds selected from the group consisting of 10-undecenal, 9-undecenal, decanal and a mixture thereof.

3. The perfuming composition according to claim 1, wherein the perfuming composition of matter comprises 2-methyl-3-[4-(2-methyl-2-propanyl)phenyl]propanal, tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate, tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate, 1-((2RS,3RS)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethanone, 1-[(2RS,3RS,8aRS)-2,3,8,8-tetramethyl-1,2,3,5,6,7,8,8a-octahydro-2-naphthalenyl]ethanone, 1-[(2RS,3RS,8aRS)-2,3,8,8-tetramethyl-1,2,3,4,6,7,8,8a-octahydro-2-naphthalenyl]ethanone, cyclohexyl 2-hydroxybenzoate, hexyl 2-hydroxybenzoate, cyclohexylidene(phenyl)acetonitrile, 1-oxa-12-cyclohexadecen-2-one, 1-oxa-13-cyclohexadecen-2-one, (+)-2-methylundecanal, (3Z)-3-hexen-1-yl salicylate, patchouli oil, (+)-3-(4-methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehyde, (+)-4-(4-methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehyde, (2E)-1-[(1RS,2SR)-2,6,6-trimethyl-3-cyclohexen-1-yl]-2-buten-1-one, limonene, 2-methoxynaphthalene, dodecahydro-3a,6,6,9a-tetramethyl-naphtho[2,1-b]furan or any of its stereoisomers, orange oil, tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2H-pyran, (1-ethoxyethoxy)cyclododecane, 10-undecenal and 9-undecenal.

4. The perfuming composition according to claim 1, wherein the perfuming composition of matter further comprises isopropyl myristate or isopropyl palmitate.

5. A perfuming composition comprising: i) as perfuming ingredient, an invention's perfuming composition of matter as defined in claim 1; ii) at least one ingredient selected from the group consisting of a perfumery carrier and a perfumery base; and iii) optionally at least one perfumery adjuvant.

6. The perfuming composition according to claim 5, wherein the perfumery base comprises at least one properfume selected from the group consisting of 3-(dodecylthio)-1-(2,6,6-trimethylcyclohex-3-en-1-yl)butan-1-one, 2-(dodecylthio)-4-octanone, 2-(dodecylsulfonyl)octan-4-one, 3-(dodecylthio)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)butan-1-one, 3-(dodecylsulfonyl)-1-(2,6,6-trimethylcyclohex-3-en-1-yl)butan-1-one, 4-(dodecylthio)-4-(2,6,6-trimethylcyclohex-2-en-1-yl)butan-2-one, 4-(dodecylthio)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)butan-2-one, a linear polysiloxane co-polymer of 3-((3-(dimethoxy(methyl)silyl)propyl)thio)-2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-one, 4-oxooctan-2-yl dodecanoate, 2-phenylethyl oxo(phenyl)acetate, 3,7-dimethylocta-2,6-dien-1-yl oxo(phenyl)acetate, (Z)-hex-3-en-1-yl oxo(phenyl)acetate, 3,7-dimethyl-2,6-octadien-1-yl hexadecanoate, bis(3,7-dimethylocta-2,6-dien-1-yl) succinate, 3-methyl-5-phenylpentyl palmitate, (2-((2-methylundec-1-en-1-yl)oxy)ethyl)benzene, 1-methoxy-4-(3-methyl-4-phenethoxybut-3-en-1-yl)benzene, (3-methyl-4-phenethoxybut-3-en-1-yl)benzene, 1-(((Z)-hex-3-en-1-yl)oxy)-2-methylundec-1-ene, (2-((2-methylundec-1-en-1-yl)oxy)ethoxy)benzene, 2-methyl-1-(octan-3-yloxy)undec-1-ene, 1-methoxy-4-(1-phenethoxyprop-1-en-2-yl)benzene, 1-methyl-4-(1-phenethoxyprop-1-en-2-yl)benzene, 2-(1-phenethoxyprop-1-en-2-yl)naphthalene, (2-phenethoxyvinyl)benzene, 2-(1-(3,7-dimethyloct-6-en-1-yl)oxy)prop-1-en-2-yl)naphthalene, 4-allyl-2-methoxy-1-((2-methoxy-2-phenylvinyl)oxy)benzene, (2-((2-pentylcyclopentylidene)methoxy)ethyl)benzene, (2-((2-heptylcyclopentylidene)methoxy)ethyl)benzene, (2-((2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-1-en-1-yl)oxy)ethyl)benzene, 1-methoxy-4-(1-phenethoxyprop-1-en-2-yl)benzene, 1-methoxy-4-(2-methyl-3-phenethoxyallyl)benzene, (2-((2-isopropyl-5-methylcyclohexylidene)methoxy)ethyl)benzene, 1-isopropyl-4-methyl-2-((2-pentylcyclopentylidene)methoxy)benzene, 2-methoxy-1-((2-methoxy-2-phenylvinyl)oxy)-4-propylbenzene, 2-ethoxy-1-((2-methoxy-2-phenylvinyl)oxy)-4-methylbenzene, 3-methoxy-4-((2-methoxy-2-phenylvinyl)oxy)benzaldehyde, 1-isopropyl-2-((2-methoxy-2-phenylvinyl)oxy)-4-methylbenzene, 4-((2-(hexyloxy)-2-phenylvinyl)oxy)-3-methoxybenzaldehyde and a mixture thereof.

7. A perfumed consumer product comprising a perfuming composition of matter as defined in claim 1.

8. The perfumed consumer product according to claim 7, characterized in that the perfumery consumer product is a perfume, a fabric care product, a body-care product, a cosmetic preparation, a skin-care product, an air care product or a home care product.

9. The perfumed consumer product according to claim 8, characterized in that the perfumery consumer product is a fine perfume, a splash or eau de parfum, a cologne, a shave or after-shave lotion, a liquid, pod or solid detergent or tablet, a fabric softener, a liquid or solid scent booster, a dryer sheet, a fabric refresher, an ironing water, a paper, a bleach, a carpet cleaner, a curtain-care product, a shampoo, a leave-on or rinse-off hair conditioner, a coloring preparation, a color care product, a hair shaping product, a dental care product, a disinfectant, an intimate care product, a hair spray, a skin cream or lotion, a vanishing cream, a deodorant or antiperspirant, a hair remover, a tanning or sun or after sun product, a nail product, a skin cleansing, a makeup, a perfumed soap, a shower or bath mousse, oil or gel, a foot/hand care product, a hygiene product, an air freshener, a ready to use powdered air freshener, a mold remover, a furnisher care, a wipe, a dish detergent or a hard-surface detergent, a leather care product, or a car care product.

10-11. (canceled)

12. A method for conferring, improving, enhancing or modifying fragrance intensity of the fragrance composition on a skin, surface or in the air surrounding of the skin or the surface over a prolonged period of time under ambient conditions, wherein the method comprises the step of applying the perfuming composition of matter as defined in claim 1 to a skin, surface or air.

13. A method to confer, enhance, improve or modify the odor properties of a perfuming composition or of a perfumed article, which method comprises adding to said composition or article an effective amount of the perfuming composition of matter as defined in claim 1.

14. The method according to claim 12, wherein the prolonged period of time is more than 72 hours.

15. A perfuming composition comprising: i) as perfuming ingredient, a perfuming composition of matter as defined in claim 2; ii) at least one ingredient selected from the group consisting of a perfumery carrier and a perfumery base; and iii) optionally at least one perfumery adjuvant.

16. The perfuming composition according to claim 15, wherein the perfumery base comprises at least one properfume selected from the group consisting of 3-(dodecylthio)-1-(2,6,6-trimethylcyclohex-3-en-1-yl)butan-1-one, 2-(dodecylthio)-4-octanone, 2-(dodecylsulfonyl)octan-4-one, 3-(dodecylthio)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)butan-1-one, 3-(dodecyl sulfonyl)-1-(2,6,6-trimethylcyclohex-3-en-1-yl)butan-1-one, 4-(dodecylthio)-4-(2,6,6-trimethylcyclohex-2-en-1-yl)butan-2-one, 4-(dodecylthio)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)butan-2-one, a linear polysiloxane co-polymer of 3-((3-(dimethoxy(methyl)silyl)propyl)thio)-2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-one, 4-oxooctan-2-yl dodecanoate, 2-phenylethyl oxo(phenyl)acetate, 3,7-dimethylocta-2,6-dien-1-yl oxo(phenyl)acetate, (Z)-hex-3-en-1-yl oxo(phenyl)acetate, 3,7-dimethyl-2,6-octadien-1-yl hexadecanoate, bis(3,7-dimethylocta-2,6-dien-1-yl) succinate, 3-methyl-5-phenylpentyl palmitate, (2-((2-methylundec-1-en-1-yl)oxy)ethyl)benzene, 1-methoxy-4-(3-methyl-4-phenethoxybut-3-en-1-yl)benzene, (3-methyl-4-phenethoxybut-3-en-1-yl)benzene, 1-(((Z)-hex-3-en-1-yl)oxy)-2-methylundec-1-ene, (2-((2-methylundec-1-en-1-yl)oxy)ethoxy)benzene, 2-methyl-1-(octan-3-yloxy)undec-1-ene, 1-methoxy-4-(1-phenethoxyprop-1-en-2-yl)benzene, 1-methyl-4-(1-phenethoxyprop-1-en-2-yl)benzene, 2-(1-phenethoxyprop-1-en-2-yl)naphthalene, (2-phenethoxyvinyl)benzene, 2-(1-((3,7-dimethyloct-6-en-1-yl)oxy)prop-1-en-2-yl)naphthalene, 4-allyl-2-methoxy-1-((2-methoxy-2-phenylvinyl)oxy)benzene, (2-((2-pentylcyclopentylidene)methoxy)ethyl)benzene, (2-((2-heptylcyclopentylidene)methoxy)ethyl)benzene, (2-((2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-1-en-1-yl)oxy)ethyl)benzene, 1-methoxy-4-(1-phenethoxyprop-1-en-2-yl)benzene, 1-methoxy-4-(2-methyl-3-phenethoxyallyl)benzene, (2-((2-isopropyl-5-methylcyclohexylidene)methoxy)ethyl)benzene, 1-isopropyl-4-methyl-2-((2-pentylcyclopentylidene)methoxy)benzene, 2-methoxy-1-((2-methoxy-2-phenylvinyl)oxy)-4-propylbenzene, 2-ethoxy-1-((2-methoxy-2-phenylvinyl)oxy)-4-methylbenzene, 3-methoxy-4-((2-methoxy-2-phenylvinyl)oxy)benzaldehyde, 1-isopropyl-2-((2-methoxy-2-phenylvinyl)oxy)-4-methylbenzene, 4-((2-(hexyloxy)-2-phenylvinyl)oxy)-3-methoxybenzaldehyde and a mixture thereof.

17. A perfumed consumer product comprising a perfuming composition of matter as defined in claim 2.

18. The perfumed consumer product according to claim 17, characterized in that the perfumery consumer product is a perfume, a fabric care product, a body-care product, a cosmetic preparation, a skin-care product, an air care product or a home care product.

19. The perfumed consumer product according to claim 18, characterized in that the perfumery consumer product is a fine perfume, a splash or eau de parfum, a cologne, a shave or after-shave lotion, a liquid, pod or solid detergent or tablet, a fabric softener, a liquid or solid scent booster, a dryer sheet, a fabric refresher, an ironing water, a paper, a bleach, a carpet cleaner, a curtain-care product, a shampoo, a leave-on or rinse-off hair conditioner, a coloring preparation, a color care product, a hair shaping product, a dental care product, a disinfectant, an intimate care product, a hair spray, a skin cream or lotion, a vanishing cream, a deodorant or antiperspirant, a hair remover, a tanning or sun or after sun product, a nail product, a skin cleansing, a makeup, a perfumed soap, a shower or bath mousse, oil or gel, a foot/hand care product, a hygiene product, an air freshener, a ready to use powdered air freshener, a mold remover, a furnisher care, a wipe, a dish detergent or a hard-surface detergent, a leather care product, or a car care product.

20. A method for conferring, improving, enhancing or modifying fragrance intensity of the fragrance composition on a skin, surface or in the air surrounding of the skin or the surface over a prolonged period of time under ambient conditions, wherein the method comprises the step of applying the perfuming composition of matter as defined in claim 2 to a skin, surface or air.

21. The method according to claim 20, wherein the prolonged period of time is more than 72 hours.

22. A method to confer, enhance, improve or modify the odor properties of a perfuming composition or of a perfumed article, which method comprises adding to said composition or article an effective amount of the perfuming composition of matter as defined in claim 2.

Description

EXAMPLES

[0153] The invention will now be described in further detail by way of the following examples, wherein the abbreviations have the usual meaning in the art, the temperatures are indicated in degrees centigrade ( C.).

Example 1

Preparation of a Invention's Perfuming Composition of Matter and Comparative Perfuming Composition

[0154] Perfuming compositions of matter were prepared by admixing the following ingredients:

TABLE-US-00001 TABLE 1 Composition of perfuming composition of matter A to C Perfuming composition of matter Part by Weight Ingredients A.sup.1) B.sup.2) C.sup.1) (+)-2-methylundecanal 400 400 9/10-undecenal 20 20 (3aRS,5aSR,9aSR,9bRS)-3a,6,6,9a- 70 tetramethyldodecahydronaphtho[2,1-b]furan and (3aRS,5aSR,9aSR,9bSR)-3a,6,6,9a- tetramethyldodecahydronaphtho[2,1-b]furan 2-methylbutyl salicylate and pentyl salicylate 650 1-((2RS,3RS)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8- 665 octahydronaphthalen-2-yl)ethanone, 1-[(2RS,3RS,8aRS)- 2,3,8,8-tetramethyl-1,2,3,5,6,7,8,8a-octahydro-2- naphthalenyllethanone, 1-[(2RS,3RS,8aRS)-2,3,8,8- tetramethyl-1,2,3,4,6,7,8,8a-octahydro-2-naphthalenyl]ethanone benzyl salicylate 630 (3aRS,5aSR,9aSR,9bRS)-3a,6,6,9a- 70 tetramethyldodecahydronaphtho[2,1-b]furan (3Z)-3-hexen-1-yl salicylate 400 400 400 patchouli oil.sup.3) 400 cyclohexyl 2-hydroxybenzoate 650 650 (2E)-1-[(1RS,2SR)-2,6,6-trimethyl-3-cyclohexen-1-yl]-2-buten- 275 275 1-one (1-ethoxyethoxy)cyclododecane 75 limonene 250 250 250 1-oxa-12/13-cyclohexadecen-2-one 600 600 hexyl 2-hydroxybenzoate 630 630 isopropyl myristate 200 200 570 2-methyl-3-[4-(2-methyl-2-propanyl)phenyl]propanal 1540 1540 3/4-(4-methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehyde 300 300 300 orange oil 25 25 25 patchouli oil 400 cyclohexylidene(phenyl)acetonitrile 500 500 500 tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2H-pyran 50 50 1-[(1RS,2RS)-1,2,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydro-2- 370 naphthalenyl]ethanone, 1-((2RS,3RS)-2,3,8,8-tetramethyl- 1,2,3,4,5,6,7,8-octahydronaphthalen-2- yl)ethanone,[(2RS,3RS,8aRS)-2,3,8,8-tetramethyl- 1,2,3,5,6,7,8,8a-octahydro-2-naphthalenyl]ethanone, 1- [(1RS,2RS,8aSR)-1,2,8,8-tetramethyl-1,2,3,5,6,7,8,8a- octahydro-2-naphthalenyl]ethanone, 1-[(2RS,3RS,8aRS)- 2,3,8,8-tetramethyl-1,2,3,4,6,7,8,8a-octahydro-2- naphthalenyllethanone tricyclo[5.2.1.0~2,6~]dec-3-en-8-yl acetate and 750 tricyclo[5.2.1.0~2,6~]dec-4-en-8-yl acetate tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate and 750 750 tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate 2-methoxynaphthalene 200 200 TOTAL 8000 3705 8000 .sup.1)Invention's perfuming composition of matter .sup.2)Compartive perfuming composition of matter .sup.3)Clearwood; origin: Firmenich SA, Geneva, Switzerland

Example 2

Performance of a Liquid Detergent Comprising the Invention's Composition of Matter and Comparative Composition of Matter

[0155] A model liquid detergent was prepared in a generally known manner with the following composition:

TABLE-US-00002 TABLE 2 Composition of the liquid detergent Ingredients Concentration [wt %] Sodium C14-17 Alkyl Sec Sulfonate.sup.1) 7 Fatty acids, C12-18 and C18-unsaturated.sup.2) 7.5 C12/14 fatty alcohol polyglycol ether with 7 17 mol EO.sup.3) Triethanolamine 7.5 Propylene Glycol 11 Citric acid 6.5 Potassium Hydroxyde 9.5 Protease 0.2 Amylase 0.2 Mannanase 0.2 Acrylates/Steareth-20 Methacrylate 6 structuring Crosspolymer.sup.4) Deionized Water 27.4 .sup.1)Hostapur SAS 60; Origin: Clariant .sup.2)Edenor K 12-18; Origin: Cognis .sup.3)Genapol LA 070; Origin: Clariant .sup.4)Aculyn 88; Origin: Dow Chemical

[0156] Three perfumed liquid detergents were prepared by dispersing 0.25 g of perfuming composition of matter A, B or C in the liquid detergent (dosage in application=0.5%). The sample was mixed well and allowed to macerate for 1 day.

[0157] Fabrics (1.7 kg of 30*cotton terry towels) were washed at 35 C. in standard American top loader machine. There were dispensed 50 g of liquid detergent at the start of the wash. After the washing cycle was finished the fabrics were tumble-dried for 45 minutes. The odor intensity of the cotton towels were evaluated by a panel of 8 trained panelists at different times as indicated in Table 3. The panelists were asked to rate the odor intensity of the towels on a scale from 0 to 10, 0 corresponding to no odor and 10 corresponding to extremely strong odor. The results obtained are summarized in Table 3.

TABLE-US-00003 TABLE 3 Expert panel evaluation in a liquid detergent Overall Perfume Intensity Wet Fresh Dry 4 days Dry Liquid detergent comprising perfuming 4.33 1 4 composition A Liquid detergent comprising perfuming 4 2.75 3.07 composition B Liquid detergent comprising perfuming 5.33 4.75 4.29 composition C

[0158] Olfactive performance on dry fabrics after 4 days was perceived significantly more intense for liquid detergent comprising perfuming composition A and C (invention's composition) compared to perfuming composition B (comparative composition).

Example 3

Preparation of a Granulated PEG Base Comprising the Invention's Composition of Matter

[0159]

TABLE-US-00004 TABLE 4 Composition of the granulated PEG base Bead 1 Ingredients (%) PEG 4000-7500 65 Dextrose 27 Perfume A or B of Example 1 8 1) DETE-2624 Alkaline Lipase for detergent , powder form, from creative Enzyme

[0160] To the PEG base, dextrose were added and the mixture was melted at 80 C. Then perfuming composition of Example were added. The mixture was then pelletized while cooling, by pouring a thin film of the molten mixture onto a flat surface, and cutting it in smaller pieces after solidification.

Example 4

Preparation of a Softener Formulation Comprising the Invention's Composition of Matter

[0161] A typical unperfumed softener formulation is listed in Table 5. The unperfumed softener was prepared by weighting Methyl bis[ethyl (tallowate)]-2-hydroxyethyl ammonium methyl sulfate which was heated at 65 C. Then, Water and 1,2-benzisothiazolin-3-one were placed in the reactor and were heated at 65 C. under stirring. To the above mixture was added Methyl bis [ethyl (tallowate)]-2-hydroxyethyl ammonium methyl sulfate. The mixture was stirred 15 minutes and CaCl.sub.2 was added.

TABLE-US-00005 TABLE 5 Composition of a typical unperfumed softener formulation. Ingredients Amount (% wt) Function Methyl bis[ethyl(tallowate)]- 12.2 Softening agent 2-hydroxyethyl ammonium methyl sulfate.sup.1) Calcium chloride sol 10% 0.4 Viscosity modifier 1,2-benzisothiazolin-3-one.sup.2) 0.04 Preservative Water 87.36 .sup.1)Stepantex VL 90A-Stepan .sup.2)Proxel GXL-Arch

[0162] The perfumed softener formulation is then obtained by adding, under gentle shaking, a perfumed composition of Example 1 (0.05 to 1.5% by weight relative to the total weight of the unperfumed softener formulation) into the unperfumed softener formulation listed in Table 5.

Example 5

Preparation of Transparent Isotropic Shampoo Formulations Comprising Invention's Perfumed Composition

[0163] A typical unperfumed transparent isotropic shampoo formulation is listed in Table 6. The unperfumed shampoo formulation is prepared by dispersing Polyquaternium-10 in water. The remaining ingredients of Phase A are mixed separately by addition of one after the other while mixing well after each adjunction. This pre-mix is added to the Polyquaternium-10 dispersion and mixed for another 5 min. Then, the premixed Phase B and the premixed Phase C are added (Monomuls 90L-12 is heated to melt in Texapon NSO IS) while agitating. Phase D and Phase E are added while agitating. The pH is adjusted with a citric acid solution to 5.5-6.0.

TABLE-US-00006 TABLE 6 Composition of a typical unperfumed transparent isotropic shampoo formulation. Phase Ingredients Amount [wt %] A Deionized water 44.4 Polyquaternium-10 .sup.(1) 0.3 Glycerin 85% .sup.(2) 1.0 DMDM Hydantoin .sup.(3) 0.2 B Sodium laureth sulfate .sup.(4) 28.0 Cocamidopropyl betaine .sup.(5) 3.2 Disodium cocoamphodiacetate .sup.(6) 4.0 Ethoxy (20) stearyl alcohol .sup.(7) 1.0 C Sodium laureth sulfate .sup.(4) 3.0 Glyceryl laureate .sup.(8) 0.2 D Deionized water 1.0 Sodium methylparaben .sup.(9) 0.1 E Sodium chloride (10% aqueous solution) 15.0 Citric acid (10% aqueous solution to pH 5.5-6.0) q.s. .sup.(1) Ucare Polymer JR-400; origin: Noveon .sup.(2) Origin: Brenntag Schweizerhall AG .sup.(3) Glydant; origin: Lonza .sup.(4) Texapon NSO IS; origin: Cognis .sup.(5) Tego Betain F 50; origin: Evonik .sup.(6) Amphotensid GB 2009; origin: Zschimmer & Schwarz .sup.(7) Brij S20; origin: Croda .sup.(8) Monomuls 90 L-12; origin: Gruenau GmbH .sup.(9) Nipagin Monosodium; origin: NIPA

[0164] The perfumed shampoo formulation is then obtained by adding, under gentle shaking, a perfumed composition of Example 1 (0.05 to 1.3% by weight relative to the total weight of the unperfumed shampoo formulation) into the unperfumed shampoo formulation listed in Table 6.

Example 6

Preparation of Pearly Shampoo Formulations Comprising Invention's Perfumed Composition

[0165] A typical unperfumed pearly shampoo formulation is listed in Table 7. The unperfumed shampoo formulation is prepared by dispersing Tetrasodium EDTA, Guar hydroxypropyltrimonium chloride and Polyquaternium-10 in water. NaOH (10% aqueous solution, Phase B) is added once Phase A is homogeneous. Then, the premixed Phase C is added, and the mixture heated to 75 C. Phase D ingredients are added and mixed until the mixture is homogeneous. The mixture is cooled. At 45 C., Phase E ingredients are added while mixing. The final viscosity is adjusted with NaCl (25% aqueous solution) and a pH of 5.5-6.0 is adjusted with NaOH (10% aqueous solution).

TABLE-US-00007 TABLE 7 Composition of a typical pearly shampoo formulation. Phase Ingredients Amount [wt %] A Deionized water 45.97 Tetrasodium EDTA .sup.(1) 0.05 Guar hydroxypropyl-trimonium chloride .sup.(2) 0.05 Polyquaternium-10 .sup.(3) 0.075 B NaOH (10% aqueous solution) 0.30 C Ammonium lauryl sulfate .sup.(4) 34.00 Ammonium laureth sulfate .sup.(5) 9.25 Cocamidopropyl betaine .sup.(6) 2.00 Dimethicone (&) C.sub.12-13 pareth-4 (&) C.sub.12-13 2.50 pareth-23 (&) salicylic acid .sup.(7) D Cetyl alcohol .sup.(8) 1.20 Cocamide MEA .sup.(9) 1.50 Glycol distearate .sup.(10) 2.00 E Methylchloroisothiazolinone & 0.10 methylisothiazolinone .sup.(11) D-Panthenol 75% .sup.(12) 0.10 Deionized water 0.30 F Sodium chloride (25% aqueous solution) 0.60 .sup.(1) EDETA B Powder; origin: BASF .sup.(2) Jaguar C14 S; origin: Rhodia .sup.(3) Ucare Polymer JR-400; origin: Noveon .sup.(4) Sulfetal LA B-E; origin: Zschimmer & Schwarz .sup.(5) Zetesol LA; origin: Zschimmer & Schwarz .sup.(6) Tego Betain F 50; origin: Evonik .sup.(7) Xiameter MEM-1691; origin: Dow Corning .sup.(8) Lanette 16; origin: BASF .sup.(9) Comperlan 100; origin: Cognis .sup.(10) Cutina AGS; origin: Cognis .sup.(11) Kathon CG; origin: Rohm & Haas .sup.(12) D-Panthenol; origin: Roche

[0166] A perfumed pearly shampoo formulation is then obtained by adding, under gentle shaking, a perfumed composition of Example 1 to 3 (0.05 to 1.3% by weight relative to the total weight of the unperfumed shampoo formulation) into the unperfumed pearly shampoo formulation listed in Table 7.

Example 7

Preparation of Rinse-Off Hair Conditioner Formulations Comprising an Invention's Perfumed Composition

[0167] A typical unperfumed rinse-off hair conditioner formulation is listed in Table 8. The unperfumed rinse-off hair conditioner formulation is prepared by mixing the ingredients of Phase A until an uniform mixture was obtained. Tylose is allowed to completely dissolve. Then the mixture is heated to 70-75 C. The ingredients of Phase B are combined and melted at 70-75 C. Then the ingredients of Phase B are added to Phase A with good agitation, and the mixing is continued until that the mixture has a temperature of 60 C. Then, the ingredients of Phase C are added while agitating and keeping mixing until the mixture cooled to 40 C. The pH is adjusted with a citric acid solution to 3.5-4.0.

TABLE-US-00008 TABLE 8 Composition of a typical rinse-off hair conditioner formulation. Amount Phase Ingredients [wt %] A Deionized water 81.8 Behentrimonium chloride .sup.(1) 2.5 Hydroxyethylcellulose .sup.(2) 1.5 B Cetearyl alcohol .sup.(3) 4.0 Glyceryl stearate (and) PEG-100 stearate .sup.(4) 2.0 Behentrimonium metho-sulfate (and) cetyl alcohol 4.0 (and) butylene glycol .sup.(5) Ethoxy (20) stearyl alcohol .sup.(6) 1.0 C Amodimethicone (and) Trideceth-12 (and) Cetrimonium 3.0 chloride .sup.(7) Chlorhexidine digluconate (20% aqueous solution) .sup.(8) 0.2 D Citric acid (10% aqueous solution tol pH 3.5-4.0) q.s. .sup.(1) Genamin KDMP; origin: Clariant .sup.(2) Tylose H10 Y G4; origin: Shin Etsu .sup.(3) Lanette O; origin: BASF .sup.(4) Arlacel 165; origin: Croda .sup.(5) Incroquat Behenyl TMS-50-PA- (MH); origin: Croda .sup.(6) Brij S20; origin: Croda .sup.(7) Xiameter MEM-949; origin: Dow Corning .sup.(8) Origin: Alfa Aesar

[0168] A perfumed rinse-off hair conditioner formulation is then obtained by adding, under gentle shaking, a perfumed composition of Example 1 (0.05 to 1.5% by weight relative to the total weight of the unperfumed conditioner formulation) into the unperfumed rinse-off hair conditioner formulation listed in Table 8.

Example 8

Preparation of Structured Shower Gel Formulations Comprising an Invention's Perfumed Composition

[0169] A typical unperfumed structured shower gel formulation is listed in Table 9. A perfumed structured shower gel is prepared by adding, under gentle shaking, a perfumed composition of Example 1 (0.05 to 2% by weight relative to the total weight of the structured shower gel) into the unperfumed structured shower gel formulation of Table 9.

TABLE-US-00009 TABLE 9 Composition of a typical unperfumed structured shower gel formulation. Ingredients Amount [wt %] Deionized water 49.35 Tetrasodium EDTA .sup.(1) 0.05 Acrylates co-polymer .sup.(2) 6.00 Sodium C.sub.12-15 pareth sulfate .sup.(3) 35.00 Sodium hydroxide (20% aqueous solution) 1.00 Cocamidopropyl betaine .sup.(4) 8.00 Methylchloroisothiazolinone and 0.10 methylisothiazolinone .sup.(5) Citric acid (40% aqueous solution) 0.50 .sup.(1) EDETA B powder; origin: BASF .sup.(2) Carbopol Aqua SF-1 polymer; origin: Noveon .sup.(3) Zetesol AO 328 U; origin: Zschimmer & Schwarz .sup.(4) Tego Betain F 50; origin: Goldschmidt .sup.(5) Kathon CG; origin: Rohm & Haas

Example 9

[0170] Preparation of Transparent Shower Gel Formulations Comprising an Invention's Perfumed Composition

[0171] A typical unperfumed transparent shower gel formulation is listed in Table 10. A perfumed transparent shower gel is prepared by adding, under gentle shaking, a perfumed composition of Example 1 (0.05 to 2% by weight relative to the total weight of the transparent shower gel) into the unperfumed transparent shower gel formulation of Table 10.

TABLE-US-00010 TABLE 10 Composition of a typical unperfumed transparent shower gel formulation Ingredients Amount [wt %] Deionized water 52.40 Tetrasodium EDTA .sup.(1) 0.10 Sodium benzoate 0.50 Propylene glycol 2.00 Sodium C.sub.12-15 pareth sulfate .sup.(2) 35.00 Cocamidopropyl betaine .sup.(3) 8.00 Polyquaternium-7 .sup.(4) 0.20 Citric acid (40% aqueous solution) 1.00 Sodium chloride 0.80 .sup.(1) EDETA B powder; origin: BASF .sup.(2) Zetesol AO 328 U; origin: Zschimmer & Schwarz .sup.(3) Tego Betain F 50; origin: Goldschmidt .sup.(4) Merquat 550; origin: Lubrizol

Example 10

Preparation of Milky Shower Gel Formulations Comprising an Invention's Perfumed Composition

[0172] A typical unperfumed milky shower gel formulation is listed in Table 11. A perfumed milky shower gel is prepared by adding, under gentle shaking, a perfumed composition of Example 1 (0.05 to 2% by weight relative to the total weight of the milky shower gel) into the unperfumed milky shower gel formulation of Table 11.

TABLE-US-00011 TABLE 11 Composition of a typical unperfumed milky shower gel formulation. Ingredients Amount [wt %] Deionized water 50.95 Tetrasodium EDTA .sup.(1) 0.05 Sodium benzoate 0.50 Glycerin (86% aqueous solution) 3.50 Sodium laureth sulfate .sup.(2) 27.00 Polyquaternium-7 .sup.(3) 1.00 Coco-betaine .sup.(4) 6.00 PEG-120 Methyl glucose trioleate .sup.(5) 1.00 Citric acid (40% aqueous solution) 1.00 Glycol distearate & laureth-4 & cocamidopropyl 3.00 betaine .sup.(6) Sodium chloride (20% aqueous solution) 5.00 PEG-40 hydrogenated castor oil .sup.(7) 1.00 .sup.(1) EDETA B powder; origin: BASF .sup.(2) Texapon NSO IS; origin: Cognis .sup.(3) Merquat 550; origin: Lubrizol .sup.(4) Dehyton AB-30; origin: Cognis .sup.(5) Glucamate LT; origin: Lubrizol .sup.(6) Euperlan PK 3000 AM; origin: Cognis .sup.(7) Cremophor RH 40; origin: BASF

Example 11

Preparation of Anhydrous Antiperspirant Spray Formulations Comprising an Invention's Perfumed Composition

[0173] A typical unperfumed anhydrous antiperspirant spray formulation is listed in Table 12. The anhydrous antiperspirant spray formulation is prepared by using a high-speed stirrer. Silica and Quaternium-18-hectorite are added to the mixture of isopropyl myristate and cyclomethicone. Once completely swollen, aluminium chlorohydrate is added portion-wise under stirring until the mixture becomes homogeneous and without lumps.

TABLE-US-00012 TABLE 12 Composition of a typical unperfumed anhydrous antiperspirant spray. Ingredients Amount [wt %] Cyclomethicone .sup.(1) 53.51 Isopropyl myristate 9.04 Silica .sup.(2) 1.03 Quaternium-18-hectorite .sup.(3) 3.36 Aluminium chlorohydrate .sup.(4) 33.06 .sup.(1) Dow Corning 345 Fluid; origin: Dow Corning .sup.(2) Aerosil 200 ; origin: Evonik .sup.(3) Bentone 38; origin: Elementis Specialities .sup.(4) Micro Dry Ultrafine; origin: Reheis

[0174] The perfumed formulation is then obtained by adding a perfumed composition of Example (0.05 to 2% by weight relative to the total weight of the antiperspirant spray formulation) into the unperfumed antiperspirant spray formulation of Table 12.

[0175] The aerosol cans were filled with 25% Suspension of the suspension and 75% of Propane/Butane (2.5 bar).

Example 12

Preparation of Deodorant Spray Emulsion Formulations Comprising an Invention's Perfumed Composition

[0176] A typical deodorant spray emulsion formulation is prepared by mixing and dissolving all the ingredients according to the sequence of Table 13. Then a perfumed composition of Example 1 (0.05 to 2% by weight relative to the total weight of the deodorant spray formulation) are added under gentle shaking. Then aerosol cans are filled, and the propellant is crimped and added. Aerosol filling: 40% active solution 60% propane/butane (2.5 bar).

TABLE-US-00013 TABLE 13 Composition of a typical unperfumed deodorant spray formulation. Ingredients Amount [wt %] Ethanol (95%) 90.65 Triclosan .sup.(1) 0.26 Isopropyl myristate 9.09 .sup.(1) Irgasan DP 300; origin: BASF

Example 13

Preparation of Deodorant Stick Formulations Comprising an Invention's Perfumed Composition

[0177] A typical unperfumed deodorant stick formulation is listed in Table 14. The deodorant stick formulation is obtained by weighing all the components of Part A and heating to 70-75 C. Ceteareth-25 is added once the other Part A ingredients are mixed and heated. Once the Ceteareth-25 is dissolved, stearic acid is added. Part B is prepared by dissolving Triclosan in 1,2-propylene glycol. Evaporated water is compensated. Then, slowly, under mixing, Part B is poured into Part A.

TABLE-US-00014 TABLE 14 Composition of a typical unperfumed deodorant stick formulation. Phase Ingredients Amount [wt %] A Stearic acid 5.05 1,2-Propylene glycol 41.87 Sodium hydroxide (20% aqueous solution) 4.24 Water 30.30 Tetrasodium EDTA .sup.(1) 0.10 Ceteareth-25 .sup.(2) 1.52 PPG-3 Myristyl ether .sup.(3) 1.52 B 1,2-Propylene glycol 15.14 Triclosan .sup.(4) 0.25 .sup.(1) Edeta B Power; origin: BASF .sup.(2) Cremophor A25; origin: BASF .sup.(3) Tegosoft APM; origin: Evonik .sup.(4) Irgasan DP 300; origin: BASF

[0178] The perfumed deodorant stick formulation is then obtained by adding a perfumed composition of Example 1 (0.05 to 2% by weight relative to the total weight of the deodorant stick formulation) under gentle shaking. To stock, a plastic bag is put into the bucket to be sealed after cooling. Moulds were filled at about 70 C.

Example 14

Preparation of Deodorant Roll-On Formulations Comprising an Invention's Perfumed Composition

[0179] A typical unperfumed deodorant roll-on formulation is listed in Table 15. Part A is prepared by sprinkling little-by-little the hydroxyethylcellulose into the water, whilst rapidly stirring with a turbine until the hydroxyethylcellulose is entirely swollen giving a limpid gel. Part B is slowly poured into Part A, whilst continuing stirring until the entire mixture is homogeneous. Then Part C is added.

TABLE-US-00015 TABLE 15 Composition of a typical unperfumed deodorant roll-on formulation. Phase Ingredients Amount [wt %] A Water 50.51 Hydroxyethylcellulose .sup.(1) 0.71 B Ethanol (95%) 40.40 1,2-Propylene glycol 5.05 Triclosan .sup.(2) 0.30 C PEG-40 hydrogenated castor oil .sup.(3) 3.03 .sup.(1) Natrosol 250 H; origin: Ashland .sup.(2) Irgasan DP 300; origin: BASF .sup.(3) Cremophor RH 40; origin: BASF

[0180] The perfumed deodorant, roll-on formulation is then obtained by adding a perfumed composition of Example 1 (0.05 to 2% by weight relative to the total weight of the deodorant, stick formulation) under gentle shaking.

Example 15

Preparation of Day Cream Base O/W Emulsions Comprising an Invention's Perfumed Composition

[0181] A typical day cream base O/W emulsion formulation is listed in Table 16. Phases A and B are heated separately to 70-75 C., then Phase A is added to Phase B and vacuum is applied. The mixture is stirred and cooled to 55 C. for 15 min. After cooling to room temperature, phenoxyethanol (and) piroctone olamine (Phase C) are added when a temperature of 45 C. is reached. The mixture is stirred for 5 min before sodium carbomer (Phase D), a perfumed composition of Example 1 (Phase E) are added. The mixture is stirred for 3 min, then the stirring was stopped for 15 min. When the temperature of the mixture reaches 30 C., the stirring is resumed for another 15 min until the cream becomes homogeneous, glossy and without lumps. If necessary the pH is adjusted to 6.70-7.20 with Glydant, Phenonip or Nipaguard PO5 or to 6.30-7.00 with Nikkoguard.

TABLE-US-00016 TABLE 16 Composition of a typical day cream base O/W emulsion. Phase Ingredients Amount [wt %] A Steareth-2 (and) PEG-8 Distearate.sup.(1) 5.0 Cetyl alcohol 0.5 Ceteth-20 (and) glyceryl stearate (and) 4.0 PEG-6 stearate (and) Steareth-20 .sup.(2) Squalan .sup.(3) 1.0 Paraffin oil .sup.(4) 2.0 Petrolatum .sup.(5) 5.5 B Deionized water 75.9 Propylene glycol 5.0 C Phenoxyethanol (and) Piroctone olamine .sup.(6) 0.6 D Sodium carbomer .sup.(7) 0.2 E Perfumed composition of Example 1 0.05 to 2 .sup.(1)Arlacel 985; origin: Croda .sup.(2) Tefose 2561; origin: Gattefoss .sup.(3) Biolip P 90; origin: Gattefoss .sup.(4) Mineral oil 30-40 CPS .sup.(5) Petroleum jelly .sup.(6) Nipaguard PO 5; origin: Clariant .sup.(7) PNC 400

Example 16

Preparation of Hand Dishwash Formulations Comprising an Invention's Perfumed Composition

[0182] A typical unperfumed hand dishwash formulation is listed in Table 17. The unperfumed hand dishwash is prepared by mixing water with sodium hydroxide and diethanolamide. Then the linear alkylbenzene sulfonic acid is added. After neutralizing, the remaining ingredients are added and the pH is adjusted to 7-8 if necessary.

TABLE-US-00017 TABLE 17 Composition of a typical unperfumed hand dishwash formulation. Ingredients Amount [wt %] Linear alkylbenzene sulfonic acid .sup.(1) 20.0 Diethanolamide .sup.(2) 3.5 Sodium hydroxide (50%) .sup.(3) 3.4 Secondary alcohol ethoxolate .sup.(4) 2.5 Sodium xylene sulfonate 6.3 Water 64.3 .sup.(1) Biosoft S-118; origin: Stepan .sup.(2) Ninol 40-CO; origin: Stepan .sup.(3) Stepanate SXS; origin: Stepan .sup.(4) Tergitol 15-S-9; origin: Dow Chemicals

[0183] The perfumed hand dishwash formulation is then obtained by adding a perfumed composition of Example 1 (0.05 to 2% by weight relative to the total weight of the hand dishwash formulation) under gentle shaking into the unperfumed hand dishwash formulation of Table 17.

Example 17

Preparation of an All-Purpose Hard Surface Cleaner Formulations Comprising an Invention's Perfumed Composition

[0184] The unperfumed all-purpose hard surface cleaner is prepared by mixing ingredients listed below:

TABLE-US-00018 Neodol 91-8 (origin: Shell Chemicals) 5.0% by weight Marlon A 375 (origin: Hls AG) 4.0% by weight Sodium cumolsulphonate 2.0% by weight Kathon CG (origin: Rohm and Haas) 0.2% by weight Deionized water 88.8% by weight

[0185] The perfumed all-purpose hard surface cleaner formulation is then obtained by adding a perfumed composition of Example 1 (0.05 to 2% by weight relative to the total weight of the all-purpose hard surface cleaner formulation) under gentle shaking into the unperfumed all-purpose hard surface cleaner formulation mentioned above.

Example 18

Preparation of Powder Detergent Formulations Comprising an Invention's Perfumed Composition

[0186] A typical unperfumed powder detergent formulation comprises sodium sulfate, sodium carbonate, sodium dodecylbenzensulfonate, sodium silicate, zeolite, C.sub.12-15 pareth-7, bentonite, citric acid, Sodium Acrylic Acid/MA Copolymer, sodium carbonate peroxide, tetrasodium etidronate, sodium chloride, sodium bicarbonate, cellulose gum, Disodium Anilinomorpholinotriazinylaminostilbenesulfonate, Phenylpropyl Dimethicone, enzyme, dye. The base with bleach contained the same as above plus the following additional ingredients: perborate & TAED. The concentrations of each ingredient are indicated in Table 18.

TABLE-US-00019 TABLE 18 Typical ranges of ingredients comprised in powder detergent: Ingredient % for bleach formulation Anionic surfactant 5-25% Non ionic surfactant 2-15% Builder: 20-50% Percarborate 5-20% TAED 1-8% Polymer 3-10% Optical brightener 0.1-0.5% Enzyme, Dye .sup.<2%

[0187] The perfumed powder detergent formulation is then obtained by adding a perfumed composition of Example 1 (0.05 to 2% by weight relative to the total weight of the powder detergent formulation) under gentle shaking into the unperfumed powder detergent as indicated above.

Example 19

Preparation of Bleach-Free Powder Detergent Formulations Comprising an Invention's Perfumed Composition

[0188] A typical unperfumed bleach-free powder detergent formulation comprises sodium sulfate, sodium carbonate, sodium dodecylbenzensulfonate, sodium silicate, zeolite, C.sub.12-15 pareth-7, bentonite, citric acid, Sodium Acrylic Acid/MA Copolymer, sodium carbonate peroxide, tetrasodium etidronate, sodium chloride, sodium bicarbonate, cellulose gum, Disodium Anilinomorpholinotriazinylaminostilbenesulfonate, Phenylpropyl Dimethicone, enzyme, dye. The concentrations of each ingredient are indicated in Table 19.

TABLE-US-00020 TABLE 19 Typical ranges of ingredients comprised in powder detergent: Ingredient % for bleach formulation Anionic surfactant 5-25% Non ionic surfactant 2-15% Builder: 20-50% Percarborate 5-20% TAED 1-8% Polymer 3-10% Optical brightener 0.1-0.5% Enzyme, Dye .sup.<2%

[0189] The perfumed bleach-free powder detergent formulation is then obtained by adding a perfumed composition of Example 1 (0.05 to 2% by weight relative to the total weight of the bleach-free powder detergent formulation) under gentle shaking into the unperfumed powder detergent as indicated above.