FUEL CELL INFORMATION MONITOR AND DATA TRANSFER
20240047708 ยท 2024-02-08
Assignee
Inventors
Cpc classification
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M8/0269
ELECTRICITY
International classification
H01M8/0202
ELECTRICITY
Abstract
A fuel cell includes a membrane electrode assembly, a first plate separator and a second plate separator on opposite sides of the membrane electrode assembly and a voltage sensor for detecting a cell voltage relative to opposite sides of the membrane electrode assembly. A transmitter is coupled to the sensor and configured to wirelessly transmit an indication of the cell voltage.
Claims
1. A fuel cell system comprising: a membrane electrode assembly; a first plate separator and a second plate separator on opposite sides of said membrane electrode assembly; a voltage sensor for detecting a cell voltage relative to opposite sides of said membrane electrode assembly a transmitter coupled to said sensor and configured to wirelessly transmit an indication of the cell voltage.
2. The system of claim 1 wherein the indication comprises an emission of light by said transmitter.
3. The system of claim 2 wherein the indication comprises an emission of light by said transmitter when the cell voltage is greater than a predefined voltage minimum.
4. The system of claim 1 wherein said voltage sensor is electrically connected to said first plate separator and said second plate separator, said first plate separator and said second plate separator comprising bipolar fuel cell plates.
5. The system of claim 1 further comprising a plurality of fuel cells, and wherein a first fuel cell of said plurality of fuel cells comprises said first plate separator, said second plate separator and said membrane electrode assembly.
6. The system of claim 5 wherein said voltage sensor is electrically connected to a second fuel cell of said plurality of fuel cells, and the voltage sensor is configured to detect the cell voltage relative to a first side of said membrane electrode assembly and a second side of a second membrane electrode assembly of the second fuel cell.
7. The system of claim 6 wherein the transmitter is configured to transmit information relative to a location of the first fuel cell in the fuel cell stack.
8. The system of claim 6 further comprising a third fuel cell between the fuel cell and the second fuel cell.
9. The system of claim 1 wherein the transmitter comprises an LED.
10. The system of claim 1 wherein the transmitter transmits the indication via digital communication.
11. The system of claim 1 wherein the transmitter transmits the indication and a location of the first plate separator and/or the second plate separator via digital communication.
12. The system of claim 1 wherein the transmitter comprises an LED transmitting the indication via light emitted by the LED using digital communication.
13. The system of claim 1 wherein the transmitter transmits the indication by emitting light at a predefined brightness based on the voltage.
14. The system of claim 1 further comprising a receiver spaced from the transmitter and configured to wirelessly receive the indication from the transmitter.
15. A method for use in monitoring a fuel cell comprising: a voltage sensor detecting a cell voltage relative to opposite sides of a membrane electrode assembly of a fuel cell; a transmitter coupled to said sensor and receiving an indication of the cell voltage from the voltage sensor; and the transmitter wirelessly transmitting an indication of the cell voltage.
16. The method of claim 15 wherein the transmitting the indication comprises the transmitter emitting light to transmit the indication.
17. The method of claim 15 wherein the transmitting the indication comprises the transmitter emitting light when the cell voltage is greater than a predefined voltage minimum.
18. The method of claim 15 wherein the fuel cell is a first fuel cell of a plurality of fuel cells and the detecting the cell voltage comprises detecting the cell voltage of relative to the first fuel cell and a second fuel cell of the plurality of fuel cells.
19. The method of claim 15 wherein the transmitter transmits the indication via digital communication.
20. The method of claim 18 further comprising a receiver spaced from the transmitter and wirelessly receiving the indication.
21. The method of claim 15 further comprising a receiver spaced from the transmitter and wirelessly receiving the indication.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0012] The subject matter which is regarded as the invention is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The foregoing and other features and advantages of the invention will be readily understood from the following detailed description of the preferred embodiments taken in conjunction with the accompanying drawings in which:
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DETAILED DESCRIPTION OF THE INVENTION
[0034] The present invention will be discussed hereinafter in detail in terms of various exemplary embodiments according to the present invention with reference to the accompanying drawings. In the following detailed description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. It will be obvious, however, to those skilled in the art that the present invention may be practiced without these specific details. In other instances, well-known structures are not shown in detail in order to avoid unnecessary obscuring of the present invention.
[0035] Thus, all the implementations described below are exemplary implementations provided to enable persons skilled in the art to make or use the embodiments of the disclosure and are not intended to limit the scope of the disclosure, which is defined by the claims. As used herein, the word exemplary or illustrative means serving as an example, instance, or illustration. Any implementation described herein as exemplary or illustrative is not necessarily to be construed as preferred or advantageous over other implementations. Moreover, in the present description, the terms upper, lower, left, rear, right, front, vertical, horizontal, and derivatives thereof shall relate to the invention as oriented in
[0036] Furthermore, there is no intention to be bound by any expressed or implied theory presented in the preceding technical field, background, brief summary or the following detailed description. It is also to be understood that the specific devices and processes illustrated in the attached drawings, and described in the following specification, are simply exemplary embodiments of the inventive concepts defined in the appended claims. Hence, specific dimensions and other physical characteristics relating to the embodiments disclosed herein are not to be considered as limiting, unless the claims expressly state otherwise.
[0037] In accordance with the principals of the present invention, fuel cell systems and methods for manufacturing a fuel cell stack are provided. In an example depicted in
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[0039] MEA 130 includes a membrane 140 (e.g., an ion conducting membrane) between a cathode side catalyst layer 125 and an anode side catalyst layer 135. A cathode side gas diffusion layer (GDL) 122 is located between cathode side catalyst layer 125 of the membrane electrode assembly and plate separator 110. An anode side gas diffusion layer 145 is located between anode side catalyst layer 135 of the membrane electrode assembly and plate separator 160. Seal 120 and seal 150 may be received in a channel of on an inner side of plate separator 110 and plate separator 160, respectively. In another example, such seals may be injection molded around an MEA (e.g., MEA 130) or another fuel cell component as described below. In another example, such seals may be injection molded around an MEA (e.g., MEA 130) or another fuel cell to provide a sealing function, such as between an MEA and fuel cell plate separators.
[0040] In an example depicted in
[0041] Sensor 900 may detect and/or measure a voltage potential between plate separator 110 and plate separator 160. Sensor 900 may be electrically connected to a transmitter 910 which may be configured to wirelessly transmit an indication of the voltage detection or measurement.
[0042] Although depicted separately, in an example sensor 900 and transmitter 910 could be a same device, such as a light emitting diode (LED). When a voltage exists between opposing bipolar plates, e.g., plate separator 110 and plate separator 160 of a certain predefined amount (e.g., as per the specifications of a particular LED), a light may be emitted by transmitter 910 (e.g., an LED) which may provide an indication to a user that a voltage is acceptable between the indicated plate separators. For example, such an LED may only light up when a particular amount of voltage (e.g., above about 0.6V) is present thereby informing a user that a voltage of at least the particular amount has been detected by the sensor. A sensor and a transmitter (e.g., an LED) could also be separate devices electrically connected to each other, as depicted.
[0043] As depicted in
[0044] In another example, the transmission or emission of information by transmitter 910 (e.g., light emitted by an LED) coupled to sensor 900 may be received by a receiver 920 coupled to a controller 930 configured to control aspects of system 101 and/or stack 20, as depicted in
[0045] As described, a transmitter (e.g., transmitter 910) including an LED may merely transfer light to indicate a fuel cell or set of fuel cells is operating acceptably or not operating acceptably. In other examples, additional information may be transferred via the particular transmission of light. For example, via pulse width modulation, information may be transferred from the transmitter (e.g., transmitter 910) to the receiver (e.g., receiver 920) and controller (e.g., controller 930) including a particular voltage provided or other information provided to the sensor and/or transmitter from other sources within a fuel cell stack. For example, a particular location of particular fuel cells, or groups of fuel cells, within a fuel cell stack (e.g., fuel cell stack 20) may be coupled with the particular voltages of each cell and may be transmitted wirelessly (e.g., via pulse width modulation) from a transmitter to a receiver. In such situation, a user may be apprised of a voltage of particular cells within a fuel cell stack. This may allow maintenance on particular fuel cells within the stack to be performed and/or other maintenance to be performed or planned.
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[0048] As indicated, membrane 140 may be received in opening 146 of subgasket 300 which may be formed of a nonconductive material, such as a polymer. As depicted, MEA 130 may be attached to anode GDL 145 and a combined MEA 130-GDL 145 may be sandwiched with GDL 122 around subgasket 300 such that the components are attached to each other. For example, the combination may be formed by hot pressing aligned anode and cathode portions (e.g., MEA 130-GDL 145 and GDL 122) to attach such portions to subgasket 300. In an example, heated platens may hold the gas diffusion layers (gas diffusion layer 122, gas diffusion layer 145) and membrane electrode assembly 130 while bonding (e.g., via heat sensitive adhesive or bonding gas diffusion layers to the MEA) occurs to subgasket 300.
[0049] In an example depicted in
[0050] Traces 200 may include electrical connectors 201 (e.g., formed of a conductive metal or a same material as traces 200) on ends thereof opposite the GDLs (e.g., GDL 122 and GDL 145) to allow an electrical connection of the traces (e.g., traces 200) and thus the GDLs to one or more controllers, sensors, or other devices external to subassembly 100. For example, the traces may be connected to a voltage sensor or computerized controller.
[0051] As described above, traces 200 may connect to the GDLs (e.g., GDL 122 and GDL 145) to provide an electrical connection between the GDLs and connectors 201 to allow an external connection to the GDLs for purposes of monitoring and or controlling subassembly 100 and fuel cell stack 20. For example, subgasket 300 and traces 200 may extend from GDL 122 and/or GDL 145 toward an exterior of subassembly 100. Subgasket 300 and traces 200 may extend outwardly past an outermost or exterior end 111 of plate separator 110 and/or an outermost or exterior end 161 of plate separator 160, for example. Connectors 201 could be located to an exterior of outer end 111 and/or outer end 161 as depicted. The location of the connectors outside the plate separators and seal 120 and/or seal 150 may allow additional spacing (due to the exterior location) to facilitate an easier connection of the connectors to external devices, such as sensors and controllers.
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[0053] In another example, depicted in
[0054] In a further example depicted in
[0055] In an example depicted in
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[0059] In an example depicted in
[0060] As depicted in
[0061] In an example depicted in
[0062] As indicated above, transmitters (e.g., transmitter 910, LEDs 1000, transmitter 1210) connected to sensors (e.g., sensor 900, integrated circuit 1190) for providing indication of cell voltage among one or more fuel cells of a fuel cell stack may be LEDs or another wireless transmitter that may be wirelessly coupled to a receiver (e.g., receiver 930, receivers 1100, receiver 1220) or merely provide a visible indication of such voltage (e.g., via a color LED). The use of LEDs as compared to other methods of transmission of fuel cell information from a fuel cell to a position remote from such a fuel cell provides a low forward voltage, e.g., (1.2V-3.0V), with a diode of the LED resisting reverse current. LEDs avoid radio frequency interference issues and allow simple signal processing. LEDs may further be small in size and include low-cost circuitry with existing commercial components.
[0063] Various other time-based digital transmission technologies may be utilized between a voltage sensor (e.g., sensor 900, integrated circuit 1190) and/or a transmitter (e.g., transmitter 910, transmitter 1210) and a receiver (e.g., receiver 930, receivers 1100 receiver 1220) via an LED coupled with a controller (e.g., a portion of sensor 1190) to generate digital communication between such a transmitter and receiver. For example, such communication technologies could include pulse width modulation (PWM) which may be time-based and limited to a single analog value. In another example, such digital communication could be by frequency modulation where a frequency of pulsing carries an analog value. Asynchronous digital communication may pass data (e.g., voltage, status, serial number) with a single LED. Synchronous (i.e., clocked) digital communication utilizes at least a second LED to allow a clocking of data (e.g., voltage, status, serial number). Various types of information may be transmitted from a sensor, and received by a receiver coupled to a controller, via digital communication technologies, as described above. Voltages or other information (e.g., temperature, impedance, gas concentrations, part numbers, or quality control information such as a lot number, supplier, and other manufacturing information) may also be transmitted from an integrated circuit on a fuel cell stack sending voltages to receivers remote from such fuel cell stacks, or remote from particular portions of such fuel cell stacks, via inductive transmitter and receiver coils, RF transmitters and receivers, NFC transmitters and receivers, Bluetooth transmitters and receivers, Wi-Fi transmitters and receivers, or other such wireless technologies.
[0064] In another example, a transmitter (e.g., transmitter 910, transmitter 1210) for transmitting information about a fuel cell remote from the fuel cell could be a low voltage incandescent bulb or a liquid crystal configured to emit an amount of light or brightness based on an amount of voltage or other parameter detected by a sensor (e.g., sensor 900, integrated circuit 1190), and a receiver (e.g., receiver 930, receivers 1100, receiver 1220) may be configured to monitor such brightness corresponding to the amount of the voltage or other such information. A receiver (e.g., receiver 930, receivers 1100, receiver 1220) could be Si photodiode arrays for detecting a location or other information from an illuminated LED, for example. Further, the above described transmitters and receivers could be located within a fuel cell housing holding a fuel cell stack (e.g., fuel cell stack 20) or such transmitters could be located within the fuel cell stack and the transmitters could be located remote from the stack but within a range and otherwise located (e.g., within a line of sight for optical transmission) to allow allowing wireless transmission of information therebetween.
[0065] In an example not depicted, tabs (e.g., tab 340, tab 510) could have outermost edges or lateral edges which may be conductive (e.g., conductive material, such as metal, may be printed or otherwise deposited thereon) and connected to traces (e.g., traces 205, 208, 208, 310, 560) such as those described above which may connect to interior aspects of a fuel cell stack (e.g., fuel cell stack 20). Such conductive tabs may be vertically aligned to allow electrical connections therebetween tabs to allow electrical connection between vertical or lateral portions of a fuel cell stack (e.g., fuel cell stack) to facilitate the connection of sensors and/or controllers to such various portions of a stack as described above.
[0066] Fuel cell subassembly 100 may be manufactured using a method based on using a web or plastic sheet which connects components of a fuel cell stack (e.g., fuel cell stack 20) during its manufacture as described in co-owned U.S. patent application Ser. No. 17/572,679 filed Jan. 11, 2022. Alternatively, the manufacture of assembly 100 and portions thereof may be performed manually or a combination of such automated and manual methods.
[0067] Although the above-described examples of conductive traces (e.g., trace 200, trace 205, trace 207, trace 208, trace 310, trace 560) refer to such traces being printed, deposited or otherwise located on, connected to, or adjacent, plate separator 110, GDL 122 and membrane 140, the methods of connection of such traces may be utilized with other plate separators, GDLs and systems described herein. For example, such traces may be located on other subgaskets connected to MEAs in multiple fuel cells in a fuel cell stack (e.g., fuel cell stack 20).
[0068] While several aspects of the present invention have been described and depicted herein, alternative aspects may be affected by those skilled in the art to accomplish the same objectives. Accordingly, it is intended by the appended claims to cover all such alternative aspects as being within the true spirit and scope of the invention.