Process and facility for the treatment of livestock waste
10508050 · 2019-12-17
Assignee
Inventors
Cpc classification
C05F7/00
CHEMISTRY; METALLURGY
Y02P20/145
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C02F11/04
CHEMISTRY; METALLURGY
C02F2209/005
CHEMISTRY; METALLURGY
Y02W30/40
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C05F17/50
CHEMISTRY; METALLURGY
Y02A40/20
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C02F9/00
CHEMISTRY; METALLURGY
C05F17/00
CHEMISTRY; METALLURGY
C02F2209/10
CHEMISTRY; METALLURGY
C05F3/00
CHEMISTRY; METALLURGY
Y02W10/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C02F2203/006
CHEMISTRY; METALLURGY
Y02W10/20
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E50/30
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02W10/30
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
C02F11/04
CHEMISTRY; METALLURGY
C05F17/00
CHEMISTRY; METALLURGY
C05F7/00
CHEMISTRY; METALLURGY
Abstract
The invention provides an efficient system for treating livestock waste, particularly waste from cattle or pig farming. The new facility and method employ special transfers of slurry streams through ASBR, SBR, and a unique pretreatment reactor, resulting in treated water, quality compost, and biogas.
Claims
1. A facility for treating a daily volume of livestock waste water, comprising a) a collecting basin for continually collecting and stirring raw livestock liquid wastes; b) a pretreatment channel having an inlet end and an outlet end, capable to contain at least said daily volume of waste water, connected at said inlet end with said collecting basin and accepting said raw wastes, which flow through the channel and form a pretreated waste water while allowing for partial settling of dispersed solids and enriching the lower part of the channel with said solids relatively to the upper part; c) an anaerobic reactor connected with said channel at said outlet end and accepting said pretreated waste water from the upper part of said channel in separate batches through a connecting pipe, each batch allowed to react in the reactor and partially settle, forming anaerobically treated waste water being enriched with solids in the lower part of the reactor relatively to the upper part, wherein a portion of said anaerobically treated waste water from said lower part is fed to said channel at said inlet end where it combines with said raw wastes, said connecting pipe being branched to enable a part of said pretreated waste water to flow to an aerobic stirred reactor; d) the aerobic stirred reactor connected with said anaerobic reactor and accepting said anaerobically treated water from the upper part of said anaerobic reactor in separate batches, each batch allowed to react in the aerobic reactor and partially settle, forming aerobically treated waste water being enriched with solids in the lower part of the aerobic reactor relatively to the upper part, wherein a portion of said aerobically treated waste water from said lower part is fed back to said anaerobic reactor, and said aerobically treated water from the upper part being removed as a safe water product, the aerobic reactor connected to said connecting pipe, which pipe is provided with a valve enabling to divide the flow of said pretreated waste water from the upper part of said channel between said anaerobic reactor and said aerobic reactor; and e) a compost basin to which cellulose based solid waste is fed, connected with said pretreatment channel at said outlet end and accepting said pretreated waste water from the lower part of said channel, the basin provided with mixing means, whereby providing a quality compost; wherein said daily volume of livestock waste water is converted to a quality compost and safe water for release into municipal system or for use in agriculture.
2. The facility of claim 1, wherein a) said collecting basin has a volume to contain at least two of said daily volumes of waste water; b) said pretreatment channel has a length of at least 10 times greater than its width, and a volume to contain at least two of said daily volumes of waste water; c) said anaerobic reactor has a volume to contain at least one said daily volume of waste water, and is provided with collecting means to collect and process biogas to provide energy for running the facility; d) said aerobic reactor has a volume to contain at least one said daily volume of waste water, and is provided with air dispersing means; and e) said compost basin has a volume to contain at least ten of said daily volumes, and is provided with mixing means which regularly mix said cellulose waste and said waste water, and transport means which transport the cellulose waste into the basin and the compost out; wherein said daily volume of livestock waste water is converted to a quality compost, biogas, and safe water for use in agriculture.
3. The facility according to claim 1, wherein the capacity of the facility is from 50 to 400 m.sup.3 per day.
4. The facility according to claim 1, wherein said anaerobic reactor is anaerobic sequencing batch reactor (ASBR) and said aerobic reactor is sequencing batch reactor (SBR).
5. The facility according to claim 1, further comprising transfer means for transferring the treated liquid from said collector, via said channel and said anaerobic reactor, into said aerobic reactor and to said compost basin.
6. The facility of claim 5, wherein said means comprise pumps and gravity driven means.
7. The facility of claim 1, further comprising analytical means for automatic sampling and measuring the concentration of components, including the amount of solids, in the treated water.
8. The facility of claim 7, wherein said means measure the concentration of solids along the height of said anaerobic and aerobic reactors.
9. The facility of claim 7, wherein the results of said measurements are fed to a microprocessor which manages transferring materials in the system facility.
10. The facility of claim 1, for processing waste water from a pig or cattle farm.
11. The facility of claim 1, further comprising a sand filter for processing water provided by said aerobic stirred reactor.
12. The facility of claim 1, further comprising a reverse osmosis system for processing water provided by said aerobic stirred reactor.
13. The facility of claim 1, further comprising a sand filter and a reverse osmosis system for processing water provided by said aerobic stirred reactor.
14. A process of treating a livestock waste water comprising i) collecting raw liquid waste in a stirred collecting tank; ii) transferring said raw liquid waste from said collecting tank to a non-stirred, flow-through channel reactor, said raw liquid waste providing a pretreated liquid waste in said channel; iii) transferring said pretreated liquid waste from said channel via a first outlet to an ASBR and to an SBR at a transfer rate of v3, and via a second outlet to a compost basin at a transfer rate of v4, where said pretreated liquid waste is mixed in said basin with a cellulose waste regularly added to said basin, wherein said v4 is at most 20% of said v3, wherein said second outlet is closer to the bottom of said basin than said first outlet, thereby obtaining a quality compost, and iv) dividing a part of said transferred pretreated liquid waste from said first outlet, via a regulated valve, so that a part of the stream is transferred to the SBR, at predetermined periods, at a transfer rate of v11 to rectify the pH in said SBR to alkaline values; v) reacting said pretreated waste water in said ASBR, allowing said waste water to settle, thereby obtaining an anaerobically treated waste water and solids, the solids being more concentrated in the lower part of ASBR (sludge) than in the upper part of ASBR; vi) optionally collecting biogas via a gas collector; vii) transferring said anaerobically treated waste water from said upper part of ASBR via a third outlet to said SBR at a transfer rate of v5, and transferring said anaerobically treated waste water from said lower part of ASBR via a fourth outlet to said channel at a transfer rate of v6, wherein said v6 is at most 15% of said v5, and wherein said fourth outlet is closer to the bottom of said ASBR than said third outlet, thereby supplying to said channel an activated sludge; and viii) reacting said anaerobically treated waste water in said SBR, allowing said waste water to settle, thereby obtaining an aerobically treated waste water, the solids being more concentrated in the lower part of SBR (sludge) than in the upper part of SBR, and transferring said aerobically treated waste water from said upper part of SBR via a fifth outlet at a transfer rate of v7 to obtain safe treated water, and transferring said aerobically treated waste water from said lower part of SBR via a sixth outlet back to said ASBR at a transfer rate of v8, wherein v8 is at most 5% of said v7, and wherein said sixth outlet is closer to the bottom of said SBR than said fifth outlet; thereby obtaining safe water for release into municipal system or for use in agriculture, and further a quality compost, and optionally biogas.
15. The process of claim 14, wherein said step iv) comprises opening the valve and allowing the flow of said pretreated liquid waste from said first outlet to the SBR when the pH in the SBR decreases to 6.9 or less, and closing the valve and stopping the flow when the pH in the SBR reaches 7.3 or more.
16. The process of claim 14, wherein said step vi) comprises utilizing the biogas to obtain energy for running the process.
17. The process of claim 14, wherein said steps of transferring comprise portions, usually from 2 to 6 batches a day.
18. The process of claim 14, wherein said step v) comprises homogenization of the reactor content which is attained by inflow and outflow of the liquids.
19. The process of claim 14, wherein said step viii) comprises homogenization of the reactor content which is attained by an intensive air influx and dispersion, and by an intensive mechanical stirring.
20. The process of claim 14, wherein the mixtures in steps v) and viii) are allowed to settle for a period of between 2 to 10 hours.
21. The process of claim 14, wherein livestock waste water comprises pigs or cattle.
22. The process of claim 14, for treating a piggery waste water, comprising passing said water through a system comprising a pretreatment, flow-through, non-stirred, settling channel at least 10 times longer than wide, an ASBR receiving pretreated water from said channel, and a SBR receiving water from said ASBR, wherein a portion of sludge from said SBR is returned to said ASBR, a portion of sludge from said ASBR is returned to said channel, and a portion of sludge from said channel is mixed with a cellulose based waste to form compost; thereby providing a safe water and a high-quality compost.
23. The process of claim 14, comprising filtering said aerobically treated water in a sand filter and in a reverse osmosis system.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The above and other characteristics and advantages of the invention will be more readily apparent through the following examples, and with reference to the appended drawings, wherein:
(2)
(3)
(4)
DETAILED DESCRIPTION
(5) It has now been found that piggery liquid waste can be cost-effectively and efficiently treated in two sequencing batch reactors connected in series, of which the first one is anaerobic sequencing batch reactor (ASBR) and the second one is aerobic sequencing batch reactor (SBR), wherein a) collected raw liquid waste is first pretreated in a non-stirred channel reactor, providing a pretreated liquid waste to be fed to said ASBR, b) a small part of sludge from said ASBR is dosed to said channel, where it combines with said raw liquid waste; c) a small part of sludge from said SBR is dosed to said ASBR, and d) a small part of said pretreated liquid waste is fed to a compost basin where it is mixed with a cellulose waste; thereby producing purified water from said SBR and compost from said basin. The term sludge in this context means that the liquid comprises more suspended materials that the average content in the reactor from which it flows, as a result of sedimentation.
(6) The facility according to the invention comprises at least elements as schematically depicted in
(7) In a preferred embodiment, the facility and the process according to the invention comprise elements as the system schematically depicted in
(8) In one aspect, the invention provides a semicontinual effective process for cleaning livestock waste water, at any scale, during which sewage is continually collected, and processed in repeated batches to purified water, compost, and biogas. When relating to
(9) In an important aspect of the invention, animal liquid waste flows through the purification system of the invention and provides safe water, for example as seen in
(10) In one preferred embodiment of the invention, the system for treating livestock waste waters, including the facility and the process according to the invention, comprises additional stages of water purification according to the external requirements and according to the desired use of the final water product; said additional stages preferably follow the aerobic treatment, for example the treatment in a SBR. Said additional stages preferably comprise filtration steps, such as sand filtration and reverse osmosis filtration (RO). In a preferred embodiment, water treated in a SBR flows to a sand filter and then to an RO system. The whole process, comprising a primary, anaerobic stage (preferably employing a pretreatment channel and an ASBR) and a secondary, aerobic stage (preferably employing a SBR), thus comprises in one embodiment a tertiary stage (sand filter) and a quaternary stage (RO). Said quaternary stage usually employs microfilter (F) followed by two carbon filters (CF1, CF2) before employing reverse osmosis process, and is usually finalized with another carbon filter (CF3). The sand filtration usually removes most of particles greater than 50 m, said microfilter most of particles greater than 5 m. The RO step advantageously lowers salinity of the waste water, for example water from piggery farms, after aerobic treatment; the RO treatment may be repeated according to the need, and after the third RO cycle, up to 90% final treated water relatively to the volume of the aerobically treated water may be obtained. In case of RO recycling, one or two holding tanks are included in the system for storing the concentrate before reprocessing.
(11)
(12) In another aspect, the present invention relates to a facility and a method for treating livestock wastes. The system of the invention, constituting the base of said facility and method, comprises: A collecting basin, to where all the waste from the animal's house (secretions, washing liquids) is collected. The collected sewage is stirred while some preliminary oxidation occurs. For example, in case of a piggery, the collected sewage may contain about 1.5% solids. A compost basin, and at least one sedimentation channel through which sewage is transferred to said compost basin, to an anaerobic tank, and intermittently to an aerobic tank; as said sewage flows through the channel, the solids sediment, and the slurry closer to the bottom with relatively more settled material arrives to the compost basin, and is stirred with wood splinters and allowed to form a high-quality compost. As a small part of said ASBR content, close to the bottom of the ASBR, is brought to the channel together with the raw sewage, the channel contains an activated sludge, containing the microorganisms from said anaerobic reactor, supporting desired biological processes in the channel, and starting the anaerobic decomposition process already in the channel. The hydraulic retention time in the channel is typically 2-4 days. The retention time in the compost basin is usually between 10 and 30 days. At least one anaerobic tank, and one aerobic tank, preferably an anaerobic sequential batch reactor (ASBR) and aerobic batch reactor (SBR), wherein in the former tank, phosphates are removed and nitrogen and COD reduced, and in the latter, remaining nitrogen is removed. The anaerobic reactor receives small amounts of the sludge from said aerobic reactor; the term sludge in this content means that the liquid comprises more suspended materials that the average content in the reactor from which it flows, as a result of sedimentation. The partially decanted slurry from said channel flows to the ASBR and to the SBR, wherein the flow is branched, so that only up to of the stream is transferred to the SBR and only at certain periods; usually, the water is allowed to flow into the SBR when the pH in SBR has decreased under the value of 6.5, and the flow is stopped when the pH reaches a predetermined value, for example at least 6.9, such as at least 7.4, for example 7.5, so that said flow to the SBR is zero or up to of the flow to the ASBR, such as or less of the flow to the ASBR; the period of the zero flow may be, for example, about 20 days, followed by a period of about ten days of non-zero flow. The sludge retention time in the reactors is typically 12-24 hours, while the solids retention time in the ASBR may be 20-35 days and in the SBR 10-20 days. Optionally a collecting dome on the ASBR to collect the released biogas. The biogas, mainly methane, may be used for heating the reactor, heating the animal's houses, and producing the electricity needed for running the farm.
(13) In one embodiment of the invention, the facility has a capacity of 25-400 m.sup.3 of raw waste water per day, for example between 50 and 200 m.sup.3 of piggery waste liquid per day.
(14) The term livestock refers herein to domesticated animals raised in an agricultural setting to produce commodities such as food, fiber and labor. Examples of such domesticated animals includes alpaca, banteng, bison, camel, cattle, deer, donkey, gayal, goat, horse, lama, pig, reindeer, sheep, water buffalo, and yak. More particularly, the term relates to pigs and cattle.
(15) The term retention time (RT), also known as residence time or (tau), refers herein to the average length of time that material (for example water suspension) remains in a containing unit (for example, reactor). RT is the volume of the containing unit divided by the influent flow rate (transfer rate). The flow rates or transfer rates are here expressed in m.sup.3 per day, m.sup.3/d, the RT is in days. The term sludge retention time, or solids retention time (SRT) relates to the average time the microorganisms are retained in the containing unit (for example, reactor). Sludge retention time is the biosolids amount in the system divided by the rate of biosolids loss from the system.
(16) The invention provides a technically non-complex system, without expensive equipment, flexible and scalable, particularly for neutralizing water from piggeries and cattle farming, comprising preliminary sedimentation, anaerobic treatment, aerobic treatment, and treatment of the sludge by composting. In one embodiment, a facility according to the invention may comprises: a blending basin; a compost basin, comprising at least one pretreatment channel and a compost tank; at least one anaerobic reactor; and at least one aerobic reactor.
(17) In another embodiment, a process according to the invention comprises: collecting the waste into the blending basin; transferring the waste to the channel, wherein the hydraulic retention time is 2-4 days; transferring the liquids from the compost basin to the anaerobic reactor, in which the hydraulic retention time is 12-24 hours, and the sludge retention time is 35-37 days; and transferring the liquids from the anaerobic reactor to the aerobic reactor;
wherein a part of the sludge of the aerobic reactor is transferred to the anaerobic reactor and a part of the sludge of the anaerobic reactor transferred to the end of the channel, and wherein a part of the stream form the channel to the anaerobic reactor is occasionally branched off to the aerobic reactor to increase the pH.
(18) The system of the invention is particularly advantageous for piggery farming, and the system can be scaled according to the need. The essence of the invention lies in A) converting the livestock waste water to a slurry enriched with an activated sludge, and B) fractionating the slurry in at least two sedimentation stages during which a more concentrated fraction is transferred to a compost basin to react with a cellulose based waste and a less concentrated fraction is transferred to further water processing. Said step A) is attained by transferring a part of settled sludge from an ASBR reactor to a flow-through channel reactor, said step B) is attained by settling the slurry in the flow-through channel and in said ASBR reactor and by taking the liquid for further processing form the upper part of the settled mixture. Without committing themselves to any particular theory, based on their experimental findings, the inventors believe that the excellent results are obtained due to a special combination of the physical and biological effects occurring in the system according to the invention, enabling efficiently processing large volumes of animal waste, while providing water of desired purity and good compost.
(19) The system can be adjusted according to the quality of the raw animal waste and also according to the required quality of final water. For example, in one embodiment, final water may be released to the municipal waste system; in other embodiment, final water may be employed in agriculture. The quality of the final water may be regulated, for example, by adjusting the retention times in the reactors; however, additional purification steps may be added to modify the quality of the final safe water according to the relevant requirements and regulations. The quality of the obtained compost may be regulated according to the needs, for example by modifying the sludge/cellulose waste ratio, or by employing various types of cellulose waste.
(20) In a first aspect, the invention is directed to a system, including a facility and a method, for treating animal liquid waste and providing safe water and compost, wherein said treating comprises at least a primary treatment stage and a secondary treatment stage employing an anaerobic reactor and an aerobic reactor, in which system said animal liquid waste and a cellulose based waste are converted to said safe water and compost, and optionally biogas. Such system is particularly useful in pig farming. In a second aspect, the invention is directed to a system, including a facility and a method, for treating animal waste comprising a liquid component and a solid component, wherein said liquid component is treated at least by a primary treatment stage and a secondary treatment stage employing an anaerobic reactor and an aerobic reactor, in which system said animal liquid waste and a cellulose based waste are converted to safe water and compost, and optionally biogas, wherein said solid component is added to said cellulose based waste or essentially forms said cellulose based waste. Such system is particularly useful in dairy farming.
(21) The invention will be further described and illustrated in the following example.
EXAMPLES
(22) The following acronyms are used herein:
(23) ASBR Anaerobic Sequencing Batch Reactor
(24) SBR Sequencing Batch Reactor
(25) COD Chemical Oxygen Demand
(26) BOD Biochemical Oxygen Demand
(27) TSS Total Suspended Solids
(28) TKN Total Kjehldahl Nitrogen
(29) NNH4 Ammonia-Nitrogen
(30) FOG Fats, Oils and Greases
(31) TP Total Phosphorous
(32) F Microfilter
(33) CF Carbon Filter
(34) RO Reverse Osmosis
Example 1
(35) A prototype facility was built in a North Israel piggery, in order to process waste collected from 4,000 pigs. The facility is a sequential, biological treatment facility for the treatment of daily throughput of 50 cubic meters of liquid waste. The treated waste contained pig urine, excrements, and washing water from a piggery. The medium-sized facility comprised a 200 m.sup.3 pretreatment channel and two reactors of 100 m.sup.3 each, serving as the anaerobic and aerobic reactors. About 50 m.sup.3 of the collected raw waste water from the collecting basin was pumped to the pretreatment channel every day. The channel was further fed with an activated sludge from the anaerobic reactor, from the lower part after settling. The lower part of the liquid in the channel, with precipitated solids, was led to the compost basin, wherein it was mixed with wood splinters, 5 m.sup.3 slurry a day and about 5 tons splinters. Two batches of 25 m.sup.3 each were daily collected from the end of the channel to the anaerobic reactor. The liquid was fed from the bottom of the container, generating a stir. During the anaerobic reaction, the COD, BOD, TSS and PT were reduced. It was estimated that burning the biogas released in the anaerobic reaction could provide at least 100 KW throughout the day. The decanted waste from the anaerobic reactor is then fed to the aerobic reactor twice a day, for final step of de-nitrification. Sludge from the aerobic reactor, after settling, was returned in an amount of 2 m.sup.3 to the anaerobic reactor. The sludge retention time was estimated at 37 days, while the hydraulic retention was about 12-24 hours.
(36) The following values were obtained for the treated water (average values from several experimental treatment cycles are followed by target values for the disposed water):
(37) TABLE-US-00001 BOD COD TSS TKN NNH4 FOG TP pH (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) (mg/l) Inlet to channel 7.5 6,500 15,000 9,200 1,800 800 400 320 Outlet from channel 6,000 12,000 6,000 1,600 280 to ASBR Outlet from ASBR 1,150 2,300 900 1,100 50 to SBR Outlet from SBR 900 1,900 800 450 19 to dispose Outlet from channel 50,000 90,000 80,000 5,500 2,000 to compost Target dispose 6-10 <500 <2,000 <1,000 <100 <100 <30 value
(38) At the end of the process, the waste was within the permitted parameter for discarding to the municipal sewage treatment system.
Example 2
(39) A small pilot system was built in a Central Israel cow shed with 300 milking cows, processing waste collected from 20 cows. Liquid waste was processed similarly as in Example 1, but about 20 times lower volumes of the pretreatment channel and two reactors were employed (about 6 m.sup.3 channel reactor and about 5 m.sup.3 each), serving as the anaerobic and aerobic reactors. About 3 m.sup.3 a day of the collected raw waste water from the collecting basin was pumped to the pretreatment channel, and the water from aerobic reactor was filtered on a sand filter, and further in a sequence of F/CF1/CF2 followed by RO device and the final CF3.
(40) TABLE-US-00002 COD NNH4 Chlorides Polyphenols Na (mg/l) (mg/l) (mg/ml) (mg/ml) (mg/ml) Outlet 1190 89 334 59 253 from SBR Saline 1350 101 366 57 256 discharge Final pure 129 37 157 <20 112 water
(41) While this invention has been described in terms of some specific examples, many modifications and variations are possible. It is therefore understood that within the scope of the appended claims, the invention may be realized otherwise than as specifically described.