SEMICONDUCTOR STRUCTURE AND MANUFACTURING METHOD FOR SAME
20190378910 ยท 2019-12-12
Inventors
Cpc classification
H01L29/161
ELECTRICITY
H01L29/16
ELECTRICITY
H01L29/66545
ELECTRICITY
H01L29/66628
ELECTRICITY
H01L29/66772
ELECTRICITY
H01L29/78618
ELECTRICITY
H01L29/7838
ELECTRICITY
H01L21/0217
ELECTRICITY
H01L29/6653
ELECTRICITY
H01L29/6656
ELECTRICITY
International classification
H01L29/49
ELECTRICITY
H01L29/06
ELECTRICITY
H01L21/02
ELECTRICITY
H01L29/16
ELECTRICITY
H01L21/762
ELECTRICITY
H01L21/311
ELECTRICITY
H01L29/161
ELECTRICITY
Abstract
The present disclosure provides a semiconductor structure and a manufacturing method for the semiconductor structure. The semiconductor structure manufactured according to the manufacturing method provided in the present disclosure comprises a substrate and a gate formed on the substrate, and a silicon epitaxial layer is formed on the substrate at two sides of the gate; and a side surface of the gate is provided with a first side wall, with a gap being provided between the first side wall and the silicon epitaxial layer, and a surface of the first side wall further comprises a second side wall, with the second side wall covering the gap, so that there is an air gap between the first side wall and the silicon epitaxial layer.
Claims
1. A semiconductor structure, comprising: a substrate and a gate formed on the substrate, wherein a silicon epitaxial layer is formed on the substrate at two sides of the gate; and each side surface of the gate is provided with a first side wall, with a gap being provided between the first side wall and the silicon epitaxial layer, and a surface of the first side wall further comprises a second side wall, with the second side wall covering the gap, so that there is an air gap between the first side wall and the silicon epitaxial layer.
2. The semiconductor structure of claim 1, wherein the first side wall further comprises an extending part located on a surface of the substrate, the silicon epitaxial layer adjoins the extending part, and the width of the extending part is equal to the width of the air gap.
3. The semiconductor structure of claim 2, wherein the extending part has a width ranging from 4 to 8 nanometres.
4. The semiconductor structure of claim 1, wherein the first side wall has a thickness ranging from 3 to 6 nanometres, and the second side wall has a thickness ranging from 20 to 30 nanometres.
5. The semiconductor structure of claim 1, wherein the silicon epitaxial layer has a thickness ranging from 15 to 30 nanometres, and the height of the air gap is associated with the thickness of the silicon epitaxial layer.
6. The semiconductor structure of claim 1, wherein the material of the second side wall is TEOS or PETEOS.
7. The semiconductor structure of claim 1, wherein the substrate is a composite substrate, comprising a silicon base layer, a buried oxide layer and a silicon surface layer, wherein the buried oxide layer is located between the silicon base layer and the silicon surface layer, and the gate is formed on the silicon surface layer.
8. The semiconductor structure of claim 1, wherein for an N-type device, the silicon epitaxial layer is made of a silicon material, and for a P-type device, the silicon epitaxial layer is made of a silicon-germanium material.
9. A manufacturing method for a semiconductor structure, comprising: providing a substrate; forming a gate on the substrate; forming a first side wall on each side surface of the gate; epitaxially growing a silicon epitaxial layer on a surface of the substrate at two sides of the gate, with a gap being provided between the silicon epitaxial layer and the first side wall; and forming a second side wall on a side surface of the first side wall, with the second side wall covering the gap, so that an air gap is formed between the first side wall and the silicon epitaxial layer.
10. The manufacturing method of claim 9, further comprising: after the step of forming the first side wall, forming a dummy side wall on the side surface of the first side wall, wherein the silicon epitaxial layer epitaxially grows on a surface of the substrate adjacent to the dummy side wall; and removing the dummy side wall, so as to form the gap between the silicon epitaxial layer and the first side wall.
11. The manufacturing method of claim 10, wherein the steps of forming the first side wall and the dummy side wall further comprise: forming a side wall layer covering the gate and the surface of the substrate; forming a sacrificial layer covering the surface of the side wall layer; and etching the side wall layer and the sacrificial layer to retain the side wall layer and the sacrificial layer at the two sides of the gate, so as to form the first side wall and the dummy side wall, wherein the first side wall comprises an extending part located on the surface of the substrate, and the width of the extending part is equal to the thickness of the dummy side wall.
12. The manufacturing method of claim 10, wherein the first side wall has a thickness ranging from 3 to 6 nanometres, and the dummy side wall has a thickness ranging from 4 to 8 nanometres.
13. The manufacturing method of claim 10, wherein the first side wall is formed by means of atomic layer deposition; and the dummy side wall is formed by means of hollow cathode discharge deposition.
14. The manufacturing method of claim 10, characterized by after the step of depositing the first side wall, further comprising: performing a surface oxidation treatment on the first side wall.
15. The manufacturing method of claim 9, wherein the step of forming a second side wall further comprises: depositing an oxide on the surfaces of the first side wall and the silicon epitaxial layer, with the oxide covering the gap, so that an air gap is formed between the first side wall and the silicon epitaxial layer; and etching back the oxide, so as to form a second side wall.
16. The manufacturing method of claim 15, wherein the oxide is deposited by means of chemical vapor deposition or plasma-enhanced chemical vapor deposition.
17. The manufacturing method of claim 15, wherein the material of the oxide is TEOS or PETEOS.
18. The manufacturing method of claim 15, wherein the step of etching back the oxide further comprises: etching back the oxide by means of dry etching, so as to form the second side wall having a thickness ranging from 20 to 30 nanometres.
19. The manufacturing method of claim 9, wherein the provided substrate is a composite substrate, comprising a silicon base layer, a buried oxide layer and a silicon surface layer, wherein the buried oxide layer is located between the silicon base layer and the silicon surface layer, and the gate is formed on the silicon surface layer.
20. The manufacturing method of claim 9, further comprising epitaxially growing the silicon epitaxial layer that has a thickness ranging from 15 to 30 nanometres, wherein for an N-type device, the silicon epitaxial layer is made of a silicon material, and for a P-type device, the silicon epitaxial layer is made of a silicon-germanium material.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0035]
[0036]
[0037]
REFERENCE SIGNS
[0038] Substrate 100, 200 [0039] Silicon base layer 101, 201 [0040] Buried oxide layer 102, 202 [0041] Silicon surface layer 103, 203 [0042] Gate 110, 210 [0043] Interlayer insulation layer 111 [0044] High-K dielectric layer 112 [0045] Capping layer 113 [0046] Polycrystalline silicon gate 114 [0047] Hard mask layer 115, 116 [0048] First side wall 120, 220 [0049] Side wall oxide layer 121, 221 [0050] Sacrificial layer 130, 230 [0051] Silicon epitaxial layer 140, 141, 142, 240 [0052] Air gap 150, 250 [0053] Second side wall 160, 260 [0054] Oxide 161, 261
DETAILED DESCRIPTION OF THE DISCLOSURE
[0055] The present disclosure is described below in detail in conjunction with the accompanying drawings and particular embodiments. It is noted that the embodiments described in conjunction with the accompanying drawings and particular embodiments are merely exemplary, and should not be construed as any limitation on the scope of protection of the present disclosure.
[0056] The present disclosure relates to a semiconductor process and device. More specifically, the embodiments of the present disclosure provide a semiconductor device. The semiconductor device comprises a substrate and a gate on the substrate, and silicon epitaxial layers are formed at two sides of the gate, a side surface of the gate is provided with a first side wall, with a gap being provided between the first side wall and the silicon epitaxial layer, and a surface of the first side wall is further provided with a second side wall for covering the gap, so that there is an air gap between the first side wall and the silicon epitaxial layer. By forming the air gap between the side wall and the silicon epitaxial layer, the dielectric values K of the materials of the side walls are reduced, and the parasitic capacitance value is effectively reduced. The present disclosure also provides other embodiments.
[0057] The reader is cautioned as to all files and documents which are filed at the same time as this specification and which are open for the public to consult, and the contents of all such files and documents are incorporated herein by reference. Unless directly stated otherwise, all features disclosed in this specification (including any appended claims, the abstract, and the accompanying drawings) may be replaced by other features serving the same, equivalent, or similar purpose. Therefore, unless expressly stated otherwise, each feature disclosed is only one example of a group of equivalent or similar features.
[0058] Note that when used, the flags left, right, front, back, top, bottom, front, back, clockwise, and counterclockwise are used for convenience purposes only and do not imply any specific fixed direction. In fact, they are used to reflect the relative position and/or direction between various parts of an object.
[0059] As used herein, the terms over . . . , under . . . , between . . . and . . . , and on . . . means the relative position of that layer relative to another layer. Likewise, for example, a layer that is deposited or placed over or under another layer may be in direct contact with another layer or there may be one or more intervening layers. In addition, a layer that is deposited or placed between layers may be in direct contact with the layers or there may be one or more intervening layers. In contrast, a first layer on a second layer is in contact with the second layer. In addition, a relative position of a layer relative to another layer is provided (assuming that film operations of deposition, modification, and removal are performed in relative to a starting substrate, without considering the absolute orientation of the substrate).
[0060] As state above, in a 28 nanometres and below node manufacturing process, the process for a gate side wall is particularly important, because it defines the position of a gate source/drain region relative to a gate, and decides the magnitude of the parasitic capacitance between a contact hole (CT) and the gate with regard to the following process for the contact hole. In terms of reducing the parasitic capacitance, because of process limitations, it is difficult to reduce the parasitic capacitance value by means of geometry changes at present.
[0061] Therefore, the present disclosure provides a semiconductor structure and a manufacturing method for the semiconductor structure, which can effectively reduce the parasitic capacitance of a circuit, so as to improve the performance of a semiconductor device.
[0062]
[0063] As shown in
[0064] Specifically, in one embodiment, as shown in
[0065] A person skilled in the art should know that the above-mentioned structure regarding the gate 110 is merely exemplary, and the semiconductor structure and the gate structure 110 formed by means of the manufacturing process for same, and the manufacturing process for the gate 110 can use the existing or future techniques as needed, but not limited to the above-mentioned examples.
[0066]
[0067] After the step of forming the first side wall 120, a surface oxidation treatment is performed on the formed first side wall 120.
[0068]
[0069]
[0070]
[0071] In the above-mentioned embodiment, before an epitaxial process, removing a natural oxidation layer from the surface of the silicon surface layer 103 is further comprised. Specifically, dilute hydrofluoric (DHF) with a concentration of 200:1 can be used as a remover for the natural oxidation layer.
[0072] In the above-mentioned embodiment, for an N-type semiconductor device, the silicon epitaxial layer 140 is made of a silicon material. For a P-type semiconductor device, the silicon epitaxial layer 140 is made of a silicon-germanium material, so as to better improve the electrical property of the silicon epitaxial layer 140. Moreover, as stated above, the silicon epitaxial layer 140 grows on the surface of the silicon substrate 100 with the first side wall 120 and the sacrificial layer 130 removed, and therefore, the silicon epitaxial layer 140 adjoins the first side wall 120 and the sacrificial layer 130 retained on the side surface of the gate 110.
[0073]
[0074]
[0075] In the above-mentioned embodiment, an oxide with a poor fillibility is used for deposition, and the deposition can be performed by means of chemical vapor deposition or plasma-enhanced chemical vapor deposition. Specifically, the oxide with a poor fillibility includes but is not limited to Tetraethoxysilane (TEOS, Si(OC2H5)4) or plasma enhanced Tetraethoxysilane (PETEOS). For example, by taking TEOS as a raw material, where chemical vapor deposition or plasma-enhanced chemical vapor deposition is used to form the oxide, Si(OC2H5)4--->SiO2+by-products, the two deposition methods have a relatively simple process, but have a poor coverage rate in a small-sized region because of rapid deposition rate, such that the air gap 150 is formed between the gate and the source/drain region.
[0076]
[0077] Subsequent operations should be performed so as to form a usable transistor device after the second side wall 160 is formed. The subsequent steps at least comprise: doping source/drain regions of various devices by means of photo-etching and doping steps; growing NiSi in the source/drain regions of the devices; and etching a contact hole, depositing a stop layer and depositing an intermediate medium layer, etc., which will not be described herein.
[0078] By means of the above-mentioned steps, in the semiconductor structure provided in the present disclosure, between the gate and the source/drain, dielectric values K of the materials of the side walls are changed via an air gap formed between the first side wall and the silicon epitaxial layer and covered by the second side wall, thereby achieving the effect of effectively reducing the parasitic capacitance between a contact hole and the gate as a result of a lower K value of the air gap, so as to further improve the electrical properties of the semiconductor device.
[0079]
[0080]
[0081] After the surface oxidation treatment is performed on the first side wall 220, in this embodiment, a process of etching the first side wall 220 is further comprised.
[0082]
[0083] As shown in
[0084]
[0085]
[0086] By means of the above-mentioned steps, in the semiconductor structure provided in the present disclosure, between the gate and the source/drain, dielectric values K of the materials of the side walls are changed via an air gap formed between the first side wall and the silicon epitaxial layer and covered by the second side wall, thereby achieving the effect of effectively reducing the parasitic capacitance between a contact hole and the gate as a result of a lower K value of the air gap, so as to further improve the electrical properties of the semiconductor device. Since the height of the air gap is larger in the above-mentioned embodiment, the dielectric K value of the material of the side wall is more preferably reduced.
[0087] Therefore, the embodiments of the method for manufacturing a side wall with a semiconductor structure having a gap and the structure thereof have been described. Although the present disclosure has been described with respect to certain exemplary embodiments, it will be apparent that various modifications and changes may be made to these embodiments without departing from the more general spirit and scope of the disclosure. Accordingly, the specification and the accompanying drawings are to be regarded in an illustrative rather than a restrictive sense.
[0088] It is to be understood that this description is not intended to explain or limit the scope or meaning of the claims. In addition, in the detailed description above, it can be seen that various features are combined together in a single embodiment for the purpose of simplifying the disclosure. The method of the present disclosure should not be interpreted as reflecting the intention that the claimed embodiments require more features than those expressly listed in each claim. Rather, as reflected by the appended claims, an inventive subject matter lies in being less than all features of a single disclosed embodiment. Therefore, the appended claims are hereby incorporated into the detailed description, with each claim standing on its own as a separate embodiment.
[0089] One embodiment or embodiments mentioned in this description is/are intended to be, combined with a particular feature, structure, or characteristic described in the embodiment, included in at least one embodiment of a circuit or method. The appearances of phrases in various places in the specification are not necessarily all referring to a same embodiment.