Magnetocaloric thermal generator and method of cooling same
10502462 ยท 2019-12-10
Assignee
Inventors
Cpc classification
F25B21/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02B30/00
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F25B2321/0022
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25B2321/0021
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A magnetocaloric thermal generator having a primary circuit fluidically connecting first and second stages of magnetocaloric elements using a heat transfer primary fluid flowing alternately back and forth. The stages being subjected to variable magnetic field of a magnetic system. The primary system includes a cold side and a hot side to which the magnetocaloric elements of the stages are fluidically connected. At least the cold side of the primary circuit has an outlet point connected to another point of the primary circuit, referred to as the injection point, on the hot side by a bypass pipe allowing the primary fluid to be displaced only from the outlet point towards the injection point. The magnetocaloric thermal generator is used in a method for cooling the secondary fluid.
Claims
1. A magnetocaloric thermal generator (10, 20, 30, 40, 50, 60, 70, 80) comprising: at least one primary circuit (P10, P20, P30, P40, P50, P60, P70) fluidically connecting magnetocaloric elements (M11, M12, M21, M22, M111, M112, M113, M114, M221, M222, M223, M224) by a heat transfer primary fluid flowing alternately back and forth, the magnetocaloric elements (M11, M12, M21, M22, M111, M112, M113, M114, M221, M222, M223, M224) being subjected to a variable magnetic field of a magnetic system (2) that alternately creates, in each of the magnetocaloric elements (M11, M12, M21, M22, M111, M112, M113, M114, M221, M222, M223, M224), a magnetic heating phase and a magnetic cooling phase generator, the primary circuit comprises a cold side (F) and a hot side (C) at which the magnetocaloric elements (M11, M12; M111, M112 et M21, M22, M223, M224) are fluidically connected with each other, wherein at least one of the hot (C) and the cold (F) sides of the primary circuit comprises at least one outlet point (S1, S2, S3, S4, S5, S6) connected to an injection point (I1, I2, I3, I4, I5, I6, I7, I8, I9, I10, I11) provided at the other one of the cold (F) and the hot (C) side of the primary circuit by at least one bypass pipe (D1, D2, D3, D4, D5, D6, D7, D8, D9, D10, D11) allowing the primary fluid to be displaced only from the outlet point (S1, S2,S3, S4, S5, S6) towards the injection point (I1, I2, I3, I4, I5, I6, I7, I8, I9, I10, I11).
2. The thermal generator according to claim 1, wherein the magnetocaloric elements (M11, M12, M21, M22, M111, M112, M113, M114, M221, M222, M223, M224) are distributed in at least first and second stages (E1, E2, E10, E20), and the magnetocaloric elements (M11, M12; M111,M112) of the first stage (E1, E10) are connected fluidically with each other on the cold side (F), and the magnetocaloric elements (M21, M22, M223, M224) of the second stage (E2, E20) are connected fluidically with each other on the hot side (C).
3. The thermal generator according to claim 1, wherein the bypass pipe (D1, D2, D3, D4, D5, D6, D7, D8, D9, D10, D11) is thermally connected to a secondary circuit (6) by at least one heat exchange zone (ZF1, ZF2, ZF3, ZF4, ZF5, ZF6, ZF7, ZF8, ZF9, ZF10, ZF11).
4. The thermal generator according to claim 3, wherein the heat exchange zone (ZF1, ZF2, ZF3, ZF4, ZF5, ZF6, ZF7, ZF8, ZF9, ZF10, ZF11) is designed to achieve a counter-current displacement between the primary fluid and a secondary fluid of the secondary circuit (6).
5. The thermal generator according to claim 3, wherein the heat exchange zone (ZF1, ZF2, ZF3, ZF4, ZF5, ZF6, ZF7, ZF8, ZF9, ZF10) is designed to achieve a co-current displacement between the primary fluid and a secondary fluid of the secondary circuit (6).
6. The thermal generator according to claim 3, wherein the heat exchange zone (ZF1, ZF2, ZF3, ZF4, ZF5, ZF6, ZF7, ZF8, ZF9, ZF10) is designed to achieve a cross-current displacement between the primary fluid and a secondary fluid of the secondary circuit (6).
7. The thermal generator according to claim 1, wherein the bypass pipe (D1, D2, D3, D4, D5, D6, D7, D8, D9, D10, D11) comprises a device (5) for adjusting a flow rate of the primary fluid that circulates therein.
8. The thermal generator according to claim 1, wherein the at least one outlet point (S1, S2, S3, S4, S5, S6) is boated in the cold side (F) of the primary circuit.
9. The thermal generator according to claim 1, wherein the at least one outlet point is located in the hot side (C) of the primary circuit.
10. The thermal generator according to claim 8, wherein the injection point (I1, I2, I3, I4, I5) is located in the hot side (C) of the primary circuit.
11. The thermal generator according to claim 9, wherein the injection point is located in the cold side (F) of the primary circuit.
12. The thermal generator according to claim 1, wherein the injection point (I6, I7, I10, I11, I12, I13) is located between first and second stages (E1, E2; E10, E20) of the magnetocaloric elements (M11, M12, M21, M22, M111, M112, M113, M114, M221, M222, M223, M224).
13. The thermal generator according to claim 1, wherein the injection point (I8, I9) is located between consecutive magnetocaloric elements (M111, M112, M113, M114, M221, M222, M223, M224) of each stage (E13, E20).
14. A method of cooling a secondary fluid by a magnetocaloric thermal generator (10, 20, 30, 40, 50, 60, 70, 80) that has at least one primary circuit (P10, P20, P30, P40, P50, P60, P70) fluidically connecting magnetocaloric elements (M11, M12, M21, M22, M111, M112, M113, M114, M221, M222, M223, M224) by a heat transfer primary fluid flowing alternately back and forth, the magnetocaloric elements (M11, M12, M21, M22, M111, M112, M113, M114, M221, M222, M223, M224) being subjected to a variable magnetic field of a magnetic system (2) that alternately creates, in each of the magnetocaloric elements (M11, M12, M21, M22, M111, M112, M113, M114, M221, M222, M223, M224), a magnetic heating phase and a magnetic cooling phase generator, the primary circuit comprises a cold side (F) and a hot side (C) at which the magnetocaloric elements (M11, M12; M111, M112 et M21, M22, M223, M224) are fluidically connected with one another, at least one of the hot (C) and the cold (F) sides of the primary circuit includes at least one outlet point (S1, S2, S3, S4, S5, S6) connected to an injection point (I1, I2, I3, I4, I5, I6, I7, I8, I9, I10, I11) provided at the other one of the cold (F) the hot (C) side of the primary circuit by at least one bypass pipe (D1, D2, D3, D4, D5, D6, D7, D8, D9, D10, D11) allowing the primary fluid to be displaced only from the outlet point (S1, S2, S3, S4, S5, S6) towards the injection point (I1, I2, I3, I4, I5, I6, I7, I8, I9, I10, I11), the method comprising: thermally connecting the secondary circuit (6) in which the secondary fluid circulates by at least one heat exchange zone (ZF1, ZF2, ZF3, ZF4, ZF5, ZF6, ZF7, ZF8, ZF9, ZF10, ZF11) to the at least one bypass pipe (D1, D2, D3, D4, D5, D6, D7, D8, D9, D10, D11) of the magnetocaloric thermal generator, and continuously circulating the secondary fluid in the secondary circuit.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The present invention and its advantages will be better revealed in the following description of the embodiments given as non limiting examples, in reference to the drawings in appendix, in which:
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ILLUSTRATION OF THE INVENTION
(14) In the illustrated embodiment examples, the identical elements or parts have the same numerical references.
(15) The invention relates to a magnetocaloric thermal generator 10, 20, 30, 40, 50, 60, 70, 80, 90, 100, 110 comprising magnetocaloric elements M.sub.11, M.sub.12, M.sub.21, M.sub.22, M.sub.111, M.sub.112, M.sub.113, M.sub.114, M.sub.221, M.sub.222, M.sub.223, M.sub.224. In the illustrated embodiment variants, these magnetocaloric elements M.sub.11, M.sub.12, M.sub.21, M.sub.22, M.sub.111, M.sub.112, M.sub.113, M.sub.114, M.sub.221, M.sub.222, M.sub.223, M.sub.224 are distributed in at least two thermal stages. A heat transfer fluid called primary fluid is displaced in an alternating movement in at least one primary circuit passing through said magnetocaloric elements M.sub.11, M.sub.12, M.sub.21, M.sub.22, M.sub.111, M.sub.112, M.sub.113, M.sub.114, M.sub.221, M.sub.222, M.sub.223, M.sub.224. The function of this primary fluid is, on the one hand, to establish and maintain a thermal gradient in the magnetocaloric elements of said thermal stages between two ends of thermal generator 10, 20, 30, 40, 50, 60, 70, 80, that is to say a cold side F and a hot side C and, on the other hand, to allow exchanging or restituting the thermal energy produced in said generator with at least one external application, that is to say not belonging to thermal generator 10, 20, 30, 40, 50, 60, 70, 80, 90, 100, 110. This exchange or this restitution occurs by means of an exchange zone that can be materialized by a heat exchanger. This exchange zone allows achieving a heat exchange between the primary fluid and a secondary fluid of a secondary circuit that belongs to the external application.
(16) Even though this is not illustrated, the invention also provides to have only one stage of magnetocaloric elements.
(17) The primary fluid and the secondary fluid are preferably liquids. The secondary fluid is preferably displaced continuously by a pump or any similar device for cooling, heating or tempering an external application. The primary fluid intended to be in contact with the magnetocaloric elements can be made of water, water with an antifreeze product such as glycol for example, a liquid gas, pressurized or not, or a brine.
(18) Each magnetocaloric element M.sub.11, M.sub.12, M.sub.21, M.sub.22, M.sub.111, M.sub.112, M.sub.113, M.sub.114, M.sub.221, M.sub.222, M.sub.223, M.sub.224 can be made of one or several magnetocaloric materials through which the primary fluid can flow. For the purpose of this invention, a magnetocaloric element must be understood as a physical element comprising magnetocaloric material. A magnetocaloric element can in particular comprise several types of magnetocaloric materials. To that purpose, said magnetocaloric elements can be porous so that their pores form through fluid passages. They can also have the form of one or several solid blocks in which mini or micro channels are machined, molded or injected. They can also be made of an assembly of superposed, possibly grooved plates, between which the heat transfer fluid can flow. They can finally have the form of powder or particles, so that the gaps form fluid passages. Any other embodiment, allowing the primary fluid to achieve heat exchange with the material making up a magnetocaloric element M.sub.11, M.sub.12, M.sub.21, M.sub.22, M.sub.111, M.sub.112, M.sub.113, M.sub.114, M.sub.221, M.sub.222, M.sub.223, M.sub.224 can of course be suitable. The magnetocaloric materials making up magnetocaloric elements M.sub.11, M.sub.12, M.sub.21, M.sub.22, M.sub.111, M.sub.112, M.sub.113, M.sub.114, M.sub.221, M.sub.222, M.sub.223, M.sub.224 have preferably different Curie temperatures, going from the lowest towards the highest from cold side F towards hot side C.
(19) In the represented embodiment variants, the magnetic system that subjects magnetocaloric elements M.sub.11, M.sub.12, M.sub.21, M.sub.22, M.sub.111, M.sub.112, M.sub.113, M.sub.114, M.sub.221, M.sub.222, M.sub.223, M.sub.224 to a magnetic field variation comprises permanent magnets 2 or similar (
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(21) Moreover, magnetocaloric elements M.sub.11, M.sub.12 of stage E.sub.1 are connected on cold side F of primary circuit P.sub.10 and magnetocaloric elements M.sub.21, M.sub.22 of stage E.sub.2 are connected on hot side C of primary circuit P.sub.10. According to the invention, cold side F of primary circuit P.sub.10 comprises an outlet point S.sub.1 fiuidically connected by a bypass pipe D.sub.1 to an injection point I.sub.1 In hot side C of said primary circuit P.sub.10. This bypass pipe D.sub.1 comprises a device that only allows the fluid to pass from outlet point S.sub.1 towards injection point I.sub.1. Such device controlling the direction of circulation of the primary fluid can be for example a cheek valve 4. This bypass pipe D.sub.1 passes through a cold exchange zone Z.sub.F1 where the primary fluid performs a heat, exchange with a secondary fluid of a secondary circuit 6.
(22) So, the fact of forcing the direction of circulation of the fluid in bypass pipe D.sub.1 allows making sure that, only the fluid exiting cold side F of a magnetocaloric element in a demagnetization phase can be directed towards this bypass pipe D.sub.1, From this results that the cooling capacity of the secondary circuit is optimized.
(23) The primary fluid coming from bypass pipe D.sub.1 has heated up after having passed through cold exchange zone Z.sub.F1. It is however reinjected in hot side C of primary circuit P.sub.10, so that this heating has a limited impact on the temperature of cold side F of primary circuit P.sub.10, which is particularly advantageous in the case of refrigeration. This moreover allows achieving a substantial exchange in cold exchange zone Z.sub.F1.
(24) This embodiment, variant is also transposable to an embodiment with, one single stage, in which the bypass pipe can connect an outlet point of the cold side to an injection point of the hot side of the primary circuit.
(25) Primary circuit P.sub.10 comprises two consecutive hot exchange zones Z.sub.C1, Z.sub.C2 on its hot side C, and injection point I.sub.1 is located between these two exchange zones Z.sub.C1, Z.sub.C2. This is very advantageous as this allows injecting the primary fluid coming from bypass pipe D.sub.1 in the portion of primary circuit P.sub.10 that passes through a magnetocaloric element in cooling phase. Thus the primary fluid is reinjected towards magnetocaloric element M.sub.22, which is cooling down in the phase illustrated in
(26) The hot exchange zones Z.sub.C1, Z.sub.C2 allow either evacuating the heat produced by thermal generator 10, or heating up another external application, for example by means of a heat exchange with a second secondary fluid circuit 7.
(27) According to the invention, bypass line D.sub.1 can advantageously comprise a flow rate adjusting device 5 for the primary fluid that circulates in it. This adjusting device 5 allows determining the heat exchange capacity between primary circuit P.sub.10 and secondary circuit 6 in cold exchange zone Z.sub.F1 and adjusting the head losses between primary circuit P.sub.10 and bypass pipe D.sub.1. This characteristic can be transposed to all embodiment variants represented.
(28) Moreover, in all illustrated examples, the outlet points are located in cold side F of the primary circuit and therefore illustrate magnetocaloric thermal generator configurations optimized for optimal use of their cold output. The invention also provides to position these outlet points in the hot side and to perform a classical exchange in cold side F. Such arrangement allows exploiting the heat produced by the thermal generator while limiting the impact due to this heat exchange on the temperature of hot side C of the primary circuit, which is particularly advantageous in the case of heating. This therefore allows achieving a significant exchange in the exchange zone connected to the bypass pipe whose outlet point is located in the hot side of the primary circuit. In other words, the whole of the illustrated examples can be transposed by inverting hot side C and cold side F in order to obtain a higher capacity to heat or to increase the temperature of a secondary fluid of an external application.
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(31) Conversely, in the opposite magnetization state illustrated in
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(34) In addition, implanting more magnetocaloric elements in thermal generator 50 allows increasing its thermal output and/or its thermal gradient.
(35) The magnetocaloric thermal generator 60 represented in
(36) The magnetocaloric thermal generator 70 represented in
(37) The magnetocaloric thermal generator 80 represented in
(38) The magnetocaloric thermal generator 90 represented in
(39) The first bypass pipe D.sub.12 connects outlet point S.sub.7 on cold end F of thermal generator 90 to injection point I.sub.12 located in primary circuit P.sub.90, on the hot end of stage E.sub.1, between actuator 3 and the hot end of magnetocaloric element M.sub.11. The second bypass pipe D.sub.13 connects outlet point S.sub.7 on cold end F of thermal generator 90 to the other point of the primary circuit located on the hot side of first stage E.sub.1, located between an actuator 3 and the hot end of magnetocaloric element M.sub.12. Bypass pipes D.sub.12 and D.sub.13 comprise a common pipe portion D.sub.12, in which a cold exchange zone Z.sub.F11 intended for achieving the heat exchange between the primary fluid and a secondary fluid of secondary circuit 61 is integrated. Moreover, bypass pipes D.sub.12 and D.sub.13 comprise each a device that controls the direction of circulation of the primary fluid.
(40) So, the common bypass pipe portion D.sub.12 that comprises a heat exchanger able to perform a heat exchange with the secondary heat transfer fluid of secondary circuit 61 receives the primary fluid exiting the cold side of magnetocaloric elements M.sub.11 and M.sub.12 of stage E.sub.1 located on cold side F when they are in a demagnetization phase. This way, the primary fluid always passes through this common bypass pipe portion D.sub.12 when it has reached the coldest temperature of the cycle. From this results that the heat exchange in exchange zone Z.sub.F11 is optimized. Moreover, the primary fluid that has undergone a raise of its temperature due to the heat exchange with the secondary circuit to be cooled is then reinjected in the primary circuit, between thermal stages E.sub.1 and E.sub.2, at a point I.sub.12, I.sub.13 of the primary circuit where the temperature is not the lowest. The possibility to adjust the fluid How rate that can circulate towards bypass pipes D.sub.12 and D.sub.13 in order to regulate the thermal power that can be exchanged between the primary circuit and the secondary circuit in exchange zone Z.sub.F11 is particularly advantageous. So, the higher the volume flow of the primary fluid passing through this exchange zone Z.sub.F11 will be, the more important the exchange will be, Advantageously, thanks to the positioning of exchange zone Z.sub.F11 in a bypass pipe, the raise of the temperature of the primary fluid due to the heat exchange in exchange zone Z.sub.F11 has very little, or even no impact on the operation of thermal generator 90, in particular on its ability to maintain a thermal gradient with a high efficiency. This is made possible by the reinjection of the primary fluid heated after a heat exchange in a zone of primary circuit P.sub.90 where the temperature of the primary fluid is not the lowest.
(41) The thermal generator 90 represented in
(42) The magnetocaloric thermal generator 100 represented in
(43) The magnetocaloric thermal generator 110 represented in
(44) Of course, the magnetocaloric thermal generator 10, 20, 30, 40, 50, 60, 70, 80, 90, 100, 110 according to the invention can comprise several primary circuits. Moreover, these primary circuits can comprise a number of magnetocaloric elements different from what is represented in the attached figures.
(45) Moreover, the shape of magnetocaloric elements M.sub.11, M.sub.12, M.sub.21, M.sub.22, M.sub.111, M.sub.112, M.sub.113, M.sub.114, M.sub.221, M.sub.222, M.sub.223 and M.sub.224 is not restricted to a rectangular part. Another shape can be considered. In addition, every magnetocaloric element can be made of several parts attached or fiuidically connected in series to each other.
POSSIBILITIES FOR INDUSTRIAL APPLICATION
(46) This description shows clearly that the invention allows reaching the goals defined, that is to say allow achieving an important heat exchange either on cold side F or on hot side C of magnetocaloric thermal generator 10, 20, 30, 40, 50, 60, 70, 80, 90, 100, 110 without disturbing the operation of the latter while optimizing its efficiency.
(47) The thermal generator, as well as the method according to the invention, can find an application in all thermal areas, such as for example the area of heating, air conditioning, tempering, cooling or others, however without being restricted to these, at competitive costs and with reduced space requirements.
(48) The present invention is not restricted to the examples of embodiment described, but extends to any modification and variant which is obvious to a person skilled in the art while remaining within the scope of the protection defined in the attached claims.