Laminated glazing with a switchable liquid crystal layer

Abstract

A switchable laminated glazing comprising two stacks of components with different lamination parameters, a first stack of components which provides the mechanical protection of the glazing, and a second stack of components with variable light transmission.

Claims

1. A switchable laminated glazing, comprising: a first stack of components having: an exterior glass layer having inner and outer surfaces; an intermediate glass layer having inner and outer surfaces; and at least one plastic bonding layer located between inner surfaces of said exterior and intermediate glass layers; and a second stack of components having: an interior glass layer having inner and outer surfaces; a first cured liquid optically clear adhesive; and a liquid crystal layer; wherein the second stack of components is disposed on and bonded to the first stack of components by said first cured liquid optically clear adhesive, such that the liquid crystal layer is sandwiched between the outer surface of the intermediate glass layer and the inner surface of the interior glass layers with the first cured liquid optically clear adhesive; wherein the first cured liquid optically clear adhesive and the liquid crystal layer are located within a sealed space, said sealed space defined by and sealed exclusively by the intermediate glass layer, the interior glass layer, and a perimeter seal, and wherein the perimeter seal is located between and directly contacts the intermediate and interior glass layers; wherein the liquid crystal layer comprises liquid crystals, two confronting polymeric substrates to encapsulate said liquid crystal layer, an edge seal and spacers; wherein the laminated glazing is a vehicle roof or vehicle side window; and wherein the switchable laminate glazing is curved.

2. The switchable laminated glazing of claim 1, wherein the edge seal and spacers of the liquid crystal layers are distributed along the surface substrates to maintain a gap between thereof.

3. The switchable laminated glazing of claim 1, wherein the gap between substrates of the liquid crystal layer ranges from about 6 μm to about 15 μm.

4. The switchable laminated glazing of claim 1, wherein said at least one plastic bonding layer is selected from the group consisting of polyvinyl butyral, ethylene vinyl acetate, and thermoplastic polyurethane.

5. The switchable laminated glazing of claim 1, wherein at least one of the plastic bonding layer is selected from the group consisting of a plastic bonding layer with high UV absorption, a plastic bonding layer with high IR absorption, and a plastic bonding layer with high UV and IR absorption.

6. The switchable laminate glazing of claim 1, wherein the first liquid optically clear adhesive is cured using a combination of UV light and another mechanism selected from the group consisting of temperature, moisture and chemical reaction.

7. The switchable laminated glazing of claim 1, wherein the first liquid optically clear adhesive is a liquid optically clear adhesive with high UV absorption.

8. The switchable laminated glazing of claim 1 further comprising a second optically clear adhesive layer disposed between the liquid crystal layer and either the outer surface of the intermediate glass layer or the inner surface of the interior glass layer.

9. The switchable laminated glazing of claim 1, wherein the first stack further comprises a performance layer.

10. The switchable laminated glazing of claim 9, wherein the performance layer is selected from the group consisting of UV reflective film, IR reflective film, and UV and IR reflective film.

11. The switchable laminated glazing of claim 9, wherein the performance layer is a low emissivity coating disposed on the inner surface of the exterior glass layer.

12. A method of producing a switchable laminated glazing comprising the steps of: providing an exterior, intermediate and interior glass layers having each of them inner and outer surfaces; providing at least one plastic bonding layer; providing a liquid crystal layer; placing said at least one plastic bonding layer between the inner surfaces of the exterior and intermediate glass layers such that a first stack of components is assembled; laminating said first stack of components using an autoclave lamination cycle; placing a first liquid optically clear adhesive onto the inner surface of the interior glass layer; disposing the outer surface of the intermediate glass layer against the inner surface of the interior glass layers such that the liquid crystal layer is sandwiched between them; disposing a perimeter seal between and in direct contact with the intermediate glass layer and the interior glass layer; and curing the first liquid optically clear adhesive such that said first stack is permanently bonded to the interior glass layer and the components disposed in between such that a second stack of components is assembled; wherein the first liquid optically clear adhesive once cured and the liquid crystal layer are located within a sealed space, said sealed space defined by and sealed exclusively by the intermediate glass layer, the interior glass layer, and the perimeter seal, wherein the liquid crystal layer comprises liquid crystals, two confronting polymeric substrates to encapsulate said liquid crystal layer, an edge seal and spacers; wherein the laminated glazing is a vehicle roof or vehicle side window; and wherein the switchable laminate glazing is curved.

13. The method of producing a switchable laminated glazing of claim 12, wherein after the step of placing the first liquid optically clear adhesive onto the inner surface of the interior glass layer, the liquid crystal layer is embedded into said first liquid optically clear adhesive.

14. The method of producing a switchable laminated glazing of claim 12, wherein after the step of laminating the first stack of components, the liquid crystal layer is fixed to the outer surface of the intermediate glass layer by means of a second liquid optically clear adhesive.

15. The method of producing a switchable laminated glazing of claim 12, wherein said at least one plastic bonding layer is selected from the group consisting of polyvinyl butyral, ethylene vinyl acetate, and thermoplastic polyurethane.

16. The method of producing a switchable laminated glazing of claim 12, wherein at least one of the plastic bonding layer is selected from the group consisting of a plastic bonding layer with high UV absorption, a plastic bonding layer with high IR absorption, and a plastic bonding layer with high UV and IR absorption.

17. The method of producing a switchable laminated glazing of claim 12, wherein the first liquid optically clear adhesive is selected from the group consisting of UV curable resin, polymer, silicone, acrylic, urethane, sulfide based and combinations thereof.

18. The method of producing a switchable laminated glazing of claim 12, wherein the first liquid optically clear adhesive presents high UV absorption.

19. The method of producing a switchable laminated glazing of claim 14, wherein the second liquid optically clear adhesive is selected from the group consisting of UV curable resin, polymer, silicone, acrylic, urethane, sulfide based and combinations thereof.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) These features and advantages of the present invention will become apparent from the detailed description of the following embodiments in conjunction with the accompanying drawings, wherein:

(2) FIG. 1 shows an isometric view of a laminated glazing according to an embodiment of the present invention.

(3) FIG. 2 shows an exploded view of the laminated glazing of FIG. 1.

(4) FIG. 3 shows a cross sectional view A-A′ of the laminated glazing of FIG. 1.

(5) FIG. 4 shows a cross sectional view A-A′ of the laminated glazing of FIG. 1 according to an alternative embodiment.

(6) FIG. 5 shows a cross sectional view of a liquid crystal film according to an embodiment of the present invention.

(7) FIG. 6 shows a cross sectional view of a laminated glazing with a performance film according to an embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

(8) Referring now to the drawings, there are shown preferred embodiments of the laminated glazing with a switchable liquid crystal layer according to the present invention.

(9) FIGS. 1, 2 and 3 show a roof window 1 with a switchable liquid crystal layer having a first stack of components 10 and a second stack of components 20. The first stack of components 10 comprises exterior 201 and intermediate 202 glass layers bonded to each other by a plastic bonding layer 4 (interlayer), which is located between inner surfaces 102, 103 of said glass layers 201, 202. In this embodiment, the plastic bonding layer 4 is polyvinyl butyral (PVB), which has excellent adhesion to glass and is optically clear once laminated. The assembled stack 8 is loaded into a vacuum bag, and then placed in an autoclave for lamination.

(10) In other embodiments, the plastic bonding layer can be ethylene vinyl acetate (EVA), thermoplastic polyurethane (TPU) or another standard lamination bonding layer. Additionally, interlayers are available with enhanced capabilities beyond bonding glass layers together. Some embodiments include plastic bonding layers having solar attenuating properties such as high UV absorption, high IR absorption or both high UV and IR absorption.

(11) Again, in FIGS. 1, 2, 3, the second stack of components 20 comprises an interior glass layer 203 having inner 105 and outer 106 surfaces, a first optically clear adhesive 12, and a liquid crystal layer 16. According to this embodiment, the liquid crystal layer 16 is embedded in a suitable liquid optically clear adhesive 12 curable to the solid state, and sandwiched between the outer surface 104 of the intermediate glass layer 202 and the inner surface 105 of the interior glass layers 203, such that after curing the liquid optically clear adhesive, the second stack of components 20 is bonded to the first stack of components 10 by said liquid adhesive 12.

(12) In an alternative embodiment, shown in FIG. 4, the second stack of components 20 is bonded to the first stack in other ways. The liquid crystal layer 16 is fixed before the application of the first optically clear adhesive 12, to the outer surface 104 of the intermediate glass layer 202 with a second optically clear adhesive 14, that may or may not be curable, to hold the liquid crystal layer 16 in place. Then, the first optically clear adhesive 12 is incorporated into the second stack of components 20, such that the latter is bonded to the first stack of components 10 by said first optically clear adhesive 12. It is understood that in this alternative embodiment, the liquid crystal layer 16 may be fixed to the inner surface 105 of the interior glass layer 203 instead.

(13) In several embodiments, each of the first and second optically clear adhesives 12, 14 are selected from the group consisting of a liquid optically clear adhesive which is cured by exposing it to ultraviolet (UV) light, temperature, moisture, by a chemical reaction, or other curing methods, a UV curable resin, polymer, silicone, acrylic, urethane, sulfide based, or combinations thereof.

(14) An obscuration 6 is disposed on inner surface 102 of exterior glass layer 201 and outer surface 106 of interior glass layer 203.

(15) FIG. 5 shows a cross sectional view of a liquid crystal layer 16 having liquid crystals 24 encapsulated between two confronting polymeric substrates 301, 302. An edge seal 26 is used to cover the edge of substrates 301, 302, such that the liquid crystals 24 get trapped between said substrates. Additionally, spacers 28 are distributed along surface substrates 301, 302 to maintain a gap ranging from 6 to 15 μm depending on the liquid crystal's formulation.

(16) FIG. 6 shows a cross sectional view of a vehicle glazing 2 having a first stack of components 30 and a second stack of components 40. In the first stack of components 30, a performance layer 18 is sandwiched between an exterior glass layer 201 and an intermediate glass layer 202. Two plastic bonding layers 4 are used on each side of the performance layer 18 to bond said performance layer 18 to glass layers 201, 202. Obscuration 6 is applied on the inner surface 102 of the exterior glass layer 201. The first stack of components 30 is then laminated.

(17) One of the big advantages of a laminated glazing over a tempered monolithic glazing is that a laminate can make use of performance coatings and films. A wide variety of films or coatings are available that can be incorporated into a laminate. The uses for these films or coatings include but are not limited to: solar control, variable light transmission, increased stiffness, increased structural integrity, improved penetration resistance, improved occupant retention, providing a barrier, tint, providing a sunshade, and color correction, among others. In some embodiments the performance layer is selected from the group consisting of UV reflective film, IR reflective film, and UV and IR reflective film. In alternative embodiments, a performance layer is a low emissivity coating disposed on the inner surface of the exterior glass layer.

(18) Again in FIG. 6, the second stack of components 40 has the same configuration as that of the embodiment depicted in FIGS. 1, 2, 3, 4, with the exception that additionally comprises a perimeter seal 22 to keep a gap between the intermediate glass layer 202 and the interior glass layer 203.

(19) In some embodiments, including those mentioned above, the exterior glass layer 201 is either a soda-lime glass or a borosilicate glass, and both intermediate 202 and interior 203 glass layers are either soda-lime, borosilicate, or aluminosilicate glass. In several embodiments, glass layers 201, 202, 203 are at least 0.5 mm thick, preferably the exterior glass layer 201 is at least 1.5 mm thick, more preferably the exterior glass layer 201 is at least 2 mm thick. Furthermore, in several embodiments, the laminated glazing is a curved glazing, wherein the exterior glass layer is formed using gravity bending, press bending, cold bending or any other conventional means known in the art. Likewise, in several embodiments, intermediate and interior glass layers are cold bent glass. Additionally, in some embodiments, the switchable laminated glazing is a side window.

(20) It must be understood that this invention is not limited to the embodiments described and illustrated above. A person skilled in the art will understand that numerous variations and/or modifications can be carried out that do not depart from the spirit of the invention, which is only defined by the following claims.