SEMI-PROCESSED PRODUCTS FOR EXTEMPORANEOUSLY PRODUCING COVERING FLUID PRODUCTS WHICH ARE OBTAINED BY IDENTIFYING AND RECOMBINING THE COMPONENTS OF A WHITE COVERING FLUID PRODUCT
20190367763 ยท 2019-12-05
Inventors
- Edoardo ROSSETTI (Calderara di Reno (BO), IT)
- Marco ROSSETTI (Calderara di Reno (BO), IT)
- Francesco LUNGHINI (Calderara di Reno (BO), IT)
- Leopoldo MAZZALVERI (Calderara di Reno (BO), IT)
- Chasmine CAIANI (Calderara di Reno (BO), IT)
Cpc classification
B01F2101/30
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
A kit of products for extemporaneously preparing covering fluid products, such as varnishes, paints, enamels and other similar decorative products, including a non-pigmented main semi-processed product with one or more binder substances and one or more filler substances which are dispersed in a fluid diluent. The kit also includes at least one pigmented subordinate semi-processed product which contains at least one particulate of titanium dioxide which is dispersed in the fluid diluent. The kit also includes at least one non-pigmented subordinate semi-processed product which contains at least one or more filler substance(s) and one or more binder substance(s) which are dispersed in the fluid diluent.
Claims
1. A kit of products for extemporaneously preparing covering fluid products, such as varnishes, paints, enamels and other similar decorative products, comprising: a non-pigmented main semi-processed product comprising one or more binder substances and one or more filler substances which are dispersed in a fluid diluent; at least one pigmented subordinate semi-processed product which contains at least one particulate of titanium dioxide which is dispersed in the fluid diluent and at least one non-pigmented subordinate semi-processed product which contains at least one or more filler substance(s) and one or more binder substance(s) which are dispersed in the fluid diluent.
2. A kit of products according to claim 1, wherein the one or more binder substances in the at least one non-pigmented subordinate semi-processed product constitute on the whole a proportion thereof not greater than 50% by weight.
3. A kit of products according to claim 1, comprising at least two non-pigmented subordinate semi-processed products which are mutually different as a result of the type and/or quantity of the one or more filler substance(s) and/or as a result of the type and/or quantity of the one or more binder substance(s) which are mutually different as a result of the respective characteristics of brilliance.
4. A kit of products according to claim 1, comprising at least two pigmented subordinate semi-processed products which are mutually different as a result of the respective characteristics of brilliance.
5. A kit of products according to claim 1, wherein: the binder substances are selected from the group comprising synthetic resins, such as polyurethane, acrylic, alkyd, phenolic, styrenic, vinyl and copolymer resins; and the filler substances are selected from the group comprising calcium carbonate, barium sulphate, barium sulphate and other functionally similar substances.
6. A kit of products according to claim 1, wherein the at least one non-pigmented subordinate semi-processed product contains one or more filler substances which are suitable for the production of paint of a high quality, for example, a barium sulphate.
7. A kit of products according to claim 1, further comprising at least one thickening product or thixotropic product, for example, an acrylic product.
8. A kit of products according to claim 1, further comprising a group of concentrated colourants.
9. A kit of products according to claim 1, wherein the non-pigmented main semi-processed product is provided in a state packed in a container which contains a quantity thereof (fill level) less than a predefined maximum quantity (fill level 100%) of covering fluid product produced by adding at least one of the subordinate semi-processed products to the container, the lesser quantity (fill level<100%) being determined by the quantity of titanium dioxide in the pigmented subordinate semi-processed product which is necessary in order to reproduce a covering fluid product of a white colour.
10. A dispensing machine for use with the kit of products according to claim 1, which is suitable for extemporaneously preparing covering fluid products, such as varnishes, paints, enamels and other similar decorative products, comprising a plurality of tanks and dispensing circuits for concentrated colourants, and at least four tanks having larger dimensions with relevant dedicated dispensing circuits for at least two pigmented subordinate semi-processed products, respectively, and for at least two non-pigmented semi-processed products.
11. A dispensing machine according to claim 10, further comprising at least one tank and a corresponding dispensing circuit for a thickening or thixotropic product.
12. A process for formulating a kit of products according to claim 1, comprising the steps of: selecting a reference white covering fluid product having a predetermined quality and an optimized formulation for production in batches in a factory (ready mix); providing a reference list of the components and the relative proportional quantities thereof in the reference white covering fluid product, the reference list comprising among the other components at least one proportional quantity of titanium dioxide and at least one proportional quantity of fluid diluent; obtaining a main list from the reference list by subtracting the listed proportional quantity of titanium dioxide and a proportional quantity of diluent which is suitable for optimally diluting the proportional quantity of titanium dioxide, obtaining a main list; formulating a non-pigmented main semi-processed product which is intended to be included in the kit of products having components and relative proportional quantities which are equal to those listed in the main list; formulating at least one pigmented subordinate semi-processed product which is intended to be included in the kit of products, comprising titanium dioxide which is dispersed in the at least one diluent included in the reference list; formulating at least one non-pigmented subordinate semi-processed product which is intended to be included in the kit of products, containing one or more filler substances and one or more binder substances which are dispersed in the at least one diluent which is included in the reference list.
13. A process according to claim 12, wherein the one or more binder substances in the at least one non-pigmented subordinate semi-processed product generally constitute a proportion thereof not greater than 50% by weight.
14. A process according to claim 12, wherein the one or more filler substance(s) and the one or more binder substance(s) in the at least one non-pigmented subordinate product are equal to or compatible with the components on the reference list of the components of the reference white covering fluid product.
15. A process according to claim 12, wherein there are formulated at least two non-pigmented subordinate semi-processed products which are intended to be included in the kit of products and which are mutually different as a result of the type and/or quantity of the one or more filler substance(s) and/or as a result of the type and/or quantity of the one or more binder substance(s).
16. A process according to claim 12, wherein there are formulated at least two pigmented subordinate semi-processed products which are mutually different as a result of the respective characteristics of brilliance.
17. A process for extemporaneously preparing covering fluid products, such as varnishes, paints, enamels and other similar decorative products, by mixing fluid products which are contained in a kit of products according to claim 1, comprising the following steps: providing the non-pigmented main semi-processed product of the kit of products in a container which contains a quantity (fill level) thereof less than a predefined maximum quantity (fill level 100%) of the final covering fluid product; providing a plurality of concentrated colourants; opening the container of non-pigmented main semi-processed product; introducing into the container of non-pigmented main semi-processed product selected quantities of the at least one of the subordinate semi-processed products and selected quantities of the at least one of the concentrated colourants, on the basis of formulations produced for obtaining a finished covering fluid product having a predetermined brilliance (gloss) which is constant for any colouration in a range of shades which can generally be obtained.
18. A process according to claim 17, wherein there is provision for introducing into the container of non-pigmented main semi-processed product selected quantities of at least two pigmented subordinate semi-processed products which are mutually different and/or selected quantities of at least two non-pigmented semi-processed products which are mutually different, on the basis of formulations produced for obtaining a finished covering fluid product having a predetermined brilliance (gloss) which is constant for any colouration in a range of shades which can generally be obtained.
19. A process according to claim 17, further comprising the step of providing an acrylic thickening or thixotropic fluid product to be introduced into the container of main semi-processed product on the basis of formulations produced for obtaining a finished covering fluid product having a viscosity which is predetermined and constant for any colouration in a range of shades which can generally be obtained or for producing thixotropic paints.
Description
EXAMPLE 1
[0051] For producing a kit of semi-processed products, a process is carried out starting, for example, from 100 g of a reference white paint. There is provided a reference list of the components and the relative quantities thereof. The reference list comprises among the other components a quantity of titanium dioxide TiO.sub.2 and a quantity of fluid diluent, in this case water. The reference list obtained is as follows:
TABLE-US-00001 Water 25 g Filler 10 g TiO.sub.2 20 g Additives 4.5 g Thickening agents 0.5 g Binders 40 g
[0052] There is obtained from the reference list a main list by subtracting the listed quantity of titanium dioxide and a proportional quantity of water which is adapted to the optimum dispersion thereof. In this case, in order to optimally disperse 20 g of titanium dioxide, there is required 9 g of water. The main list, which is reproportioned with respect to 100 g of product, is as follows:
TABLE-US-00002 Water 23 g Filler 15.3 g Additives 5 g Thickening agents 0.7 g Binders 56 g
[0053] There is formulated with the main list a non-pigmented main semi-processed product which has components and relative proportional quantities which are equal to those listed in the main list, less the quantities of titanium dioxide and water which are eliminated from the reference list.
[0054] There is also formulated at least one pigmented subordinate semi-processed product which comprises titanium dioxide which is dispersed in water. The titanium dioxide does not necessarily have to be the same as the reference list but may be different. This pigmented subordinate semi-processed product has a white colour which is imparted by the titanium dioxide which in 100 g is present at 70% by weight and is dispersed in 30 g of water.
[0055] The combination of the two non-pigmented main and pigmented subordinate semi-processed products at sufficient proportions is capable of reproducing the reference white paint with the same quality.
EXAMPLE 2
[0056] A non-pigmented main semi-processed product which therefore does not contain titanium dioxide has been produced by mixing the following components:
TABLE-US-00003 Main semi-processed product Quantity in 1 kg Raw material (% w/w) Quantity in 100 cm.sup.3 WATER 229.44 26.647 SODIUM 3.22 0.151 HEXAMETAPHOSPHATE MECELLOSE 7.42 0.490 REOTAN L 10.36 0.926 COMILEC W14B 3.64 0.406 FLUXAIR C83 1.40 0.163 CAUSTIC SODA 1.12 0.130 OMYACARB 1AV 152.60 6.564 SEPISOL 224 28.00 3.423 POLICRIL 547 560.00 60.784 ACTICIDE ICB5 2.80 0.316 Total 1000.00 100.00
[0057] A non-pigmented subordinate semi-processed product which is opaque has been produced by mixing the following components:
TABLE-US-00004 Non-pigmented subordinate semi-processed product, opaque Raw material Quantity in 1 kg Quantity in 100 cm.sup.3 DEMI WATER 199.8 28.330 PEG200 40 5.047 THYLOSE HX6000 2 0.189 BENTONE LT 2 0.164 BENTONE 27 2 0.158 DYNAWEED 200 12 1.702 OROTAN N4045 15 1.636 OMYACARB C120 420 22.057 TEGO AIREX 902 4 0.567 POLICRIL 547 300 39.755 ACTICIDE MBS 1.8 0.248 ACTICIDE F 1.4 0.148 Total 1000.00 100.00
[0058] A non-pigmented subordinate semi-processed product which is clear has been produced by mixing the following components:
TABLE-US-00005 Non-pigmented subordinate semi-processed product, clear Raw material Quantity in 1 kg Quantity in 100 cm.sup.3 DEMI WATER 199.8 31.071 PEG200 40 5.535 THYLOSE HX6000 2 0.207 BENTONE LT 2 0.180 BENTONE 27 2 0.173 DYNAWEED 200 12 1.867 OROTAN N4045 15 1.794 BARIUM SULPHATE 420 14.514 TEGO AIREX 902 4 0.622 POLICRIL 547 300 43.602 ACTICIDE MBS 1.8 0.272 ACTICIDE F 1.4 0.162 Total 1000.00 100.00
[0059] The commercial names of the above-indicated products are respective manufacturers.
[0060] There have further been provided two pigmented subordinate semi-processed products which are titanium slurry in which the titanium dioxide is concentrated to 70% by weight. One of the two titanium slurries contains titanium dioxide which has the commercial name Tioxide TR88 and which is produced by Huntsman. The other titanium slurry contains titanium dioxide which has the commercial name Ti-Pure R-942 and which is produced by DuPont.
[0061] Using the above semi-processed products, there have been produced various finished paints using the following colourants:
TABLE-US-00006 Colour Colourant Name Description index Red Chromaflo 807-0755 REE ES Organic Red PR 254 Blue Chromaflo 807-7055 EXE ES Blue PB 15:3 Yellow Chromaflo 807-1811 CNE Yellow Iron Oxide PY 42 Black Chromaflo 807-9957 BXE HS Lamp Black PBk 7
[0062] The gloss according to the norm UNI 9389 (ISO 2813-78) of the finished paints was measured using a glossmeter from Elcometer which is capable of measuring the gloss at angles of 20, 60 and 85. The results obtained are set out in the following table.
TABLE-US-00007 Main semi- processed product fill Clear Opaque Clear Opaque Gloss Gloss level TiO.sub.2 TiO.sub.2 filler filler Colourant 60 85 COLOUR (% v/v) (% v/v) (% v/v) (% v/v) (% v/v) (% v/v) (GU) (GU) WHITE 84 4 12 0 0 0 11 32 RED 84 4.6 9.3 1.2 0.7 0.2 11.5 33 BLUE 84 2 5.5 3 2.5 3 11 31 YELLOW 84 0 0 0 7.7 8.3 12.5 32.5 BLACK 84 0 0 7 4 5 9 32
[0063] The minimum differences encountered with respect to the gloss are practically indistinguishable with the naked eye.
[0064] Naturally, the principle of the invention remaining the same, the forms of embodiment and details of construction may be varied widely with respect to those described and illustrated, without thereby departing from the scope of the present invention.