System and method for producing plastic products from recycled mixed plastic waste and plastic product
10486352 · 2019-11-26
Assignee
Inventors
Cpc classification
B29B17/0026
PERFORMING OPERATIONS; TRANSPORTING
B29C48/9135
PERFORMING OPERATIONS; TRANSPORTING
B29C31/06
PERFORMING OPERATIONS; TRANSPORTING
B29B7/48
PERFORMING OPERATIONS; TRANSPORTING
B29K2995/0082
PERFORMING OPERATIONS; TRANSPORTING
B29C48/908
PERFORMING OPERATIONS; TRANSPORTING
B29B7/88
PERFORMING OPERATIONS; TRANSPORTING
B29C48/21
PERFORMING OPERATIONS; TRANSPORTING
Y02W30/62
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B29K2105/0032
PERFORMING OPERATIONS; TRANSPORTING
B29C48/355
PERFORMING OPERATIONS; TRANSPORTING
B29K2105/0005
PERFORMING OPERATIONS; TRANSPORTING
B29C48/625
PERFORMING OPERATIONS; TRANSPORTING
B29C48/022
PERFORMING OPERATIONS; TRANSPORTING
C08J9/0061
CHEMISTRY; METALLURGY
B29C48/0012
PERFORMING OPERATIONS; TRANSPORTING
B29B7/90
PERFORMING OPERATIONS; TRANSPORTING
B29C48/90
PERFORMING OPERATIONS; TRANSPORTING
B29B7/885
PERFORMING OPERATIONS; TRANSPORTING
B29C48/873
PERFORMING OPERATIONS; TRANSPORTING
C08J2323/16
CHEMISTRY; METALLURGY
B29B17/0042
PERFORMING OPERATIONS; TRANSPORTING
B29K2995/0058
PERFORMING OPERATIONS; TRANSPORTING
B29K2105/0044
PERFORMING OPERATIONS; TRANSPORTING
B29C48/09
PERFORMING OPERATIONS; TRANSPORTING
B29C2948/92438
PERFORMING OPERATIONS; TRANSPORTING
B29C48/875
PERFORMING OPERATIONS; TRANSPORTING
B29K2995/0016
PERFORMING OPERATIONS; TRANSPORTING
B29C48/92
PERFORMING OPERATIONS; TRANSPORTING
B29C48/0011
PERFORMING OPERATIONS; TRANSPORTING
B29C48/872
PERFORMING OPERATIONS; TRANSPORTING
B29C48/919
PERFORMING OPERATIONS; TRANSPORTING
B29C48/904
PERFORMING OPERATIONS; TRANSPORTING
International classification
B29C48/21
PERFORMING OPERATIONS; TRANSPORTING
B29C48/92
PERFORMING OPERATIONS; TRANSPORTING
B29C48/625
PERFORMING OPERATIONS; TRANSPORTING
B29C48/875
PERFORMING OPERATIONS; TRANSPORTING
B29C48/88
PERFORMING OPERATIONS; TRANSPORTING
B29B17/00
PERFORMING OPERATIONS; TRANSPORTING
B29C48/00
PERFORMING OPERATIONS; TRANSPORTING
B29C31/06
PERFORMING OPERATIONS; TRANSPORTING
B29C48/09
PERFORMING OPERATIONS; TRANSPORTING
B29B7/88
PERFORMING OPERATIONS; TRANSPORTING
C08J9/00
CHEMISTRY; METALLURGY
Abstract
Disclosed are plastic products from a recycled plastic mix of unidentified, unclean and unsorted mixed plastic waste made with a system comprising thermal and mechanical processing of the recycled plastic waste using continuous extrusion foaming, two-phase cooling, continuous metering of the pulling strength and automatic adjustment of the pulling speed and extrusion speed.
Claims
1. A plastic product made of mixed recycled plastic waste, wherein the plastic product has a top-surface structure, a bottom-surface structure, side-surface structures, a 5-20 mm thick dense surface layer, a surface, and a porous and foamed inner part; wherein the product comprises approximately 5-15% of a mixture of polystyrene (PS) and polypropylene (PP), and 70-90% of a mixture of polyethylene (PE) and prolyprolylene (PP); and wherein the product has properties of: density: 0.6-0.8 t/m.sup.3; flexural properties: 1843 N/mm.sup.2 at 50 C.; 795 N/mm.sup.2 at 22 C.; and 452 N/mm.sup.2 at 60 C.; linear expansion: 0.069 mm/m/ C. (indicates product expansion per 1 m when the temperature rises by 1 degree Celsius); flammability class: E; UV-impairment: E=1.1; water absorption: 0.17%; sound isolation: B3; resistance to with no damage from white spirits, lighter fluid, bleach or hot baking oil; non-toxic; resistant to temperature fluctuation in the range between +65 C. and 30 C.; linear expansion coefficient: 0.083-0.099 , mm/m.Math. C.; surface hardness of the product is 4H-5H; load: 166-222 N; holding strength: 1328-1776 N; and compressive force: 34.1-43.6 kN.
2. The plastic product according to claim 1, wherein the plastic product is a profile board, matchboard or terrace board.
3. The plastic product of claim 1 obtained by a method comprising steps of: a mixture of raw material is made of recycled mixed plastic waste; a first conveyor taking the mixture of raw material to a hopper, and a second conveyor taking resulting mixture from the hopper to a fine mixer with a weighing system; in the fine mixer, additives comprising recycled mixed plastic waste and/or granulated plastic waste of one type are added to the mixture; from the fine mixer, resulting mixed and grinded mixture of mixed plastic waste and additives is directed to an extruder having a multitude of temperature zones, where continuous extrusion foaming takes place in controlled temperatures according to a predetermined temperature curve, the temperature being controlled in the temperature zones of the extruder; after the extrusion foaming, obtained plastic mass is directed to a system of calibration matrices that is connected to the extruder for a two-phase cooling in the system of calibration matrices and in a water cooling bath; after cooling, obtained material is directed to a pultrusion machine that constantly measures pulling strength and pulling speed, and automatically adjusts extrusion speed, and then to an automatic cutter that cuts material obtained from the pultrusion machine to final product size.
4. The product of claim 3, wherein the product is obtained by a system comprising: a system for mixing raw materials, a first conveyor, a hopper, a second conveyor, a fine mixer with a weighing system, a control panel, an extruder, a system of calibration matrices on a calibration table, a water-cooling bath, a pultrusion machine with a converter, and an electric motor with a reducer, and an automatic cutter, wherein: the extruder comprises a motor; a gearbox; a frame; cooling ventilators; a screw that has a feeding zone, a compression zone, and a mixing zone; a barrel that includes multiple heating zones; an extrusion head; a die; and a head extension that is also used as the first cooling zone; the system of calibration matrices comprising a first calibration matrix that is connected to the extrusion head extension; a second calibration matrix, third calibration matrix, a fourth calibration matrix, each of the calibration matrices comprising a bottom, a lid and two sides and each calibration matrix being rigidly fixed to one another, thus forming an inner chamber of the matrices; and cooling channels; and the pultrusion machine constantly measuring pulling strength and pulling speed and adjusting extrusion speed automatically.
5. The plastic product of claim 4, wherein the extruder of the system has three temperature zones: a first zone, being a barrel, where temperature is kept at approximately 145 C.-180 C.; a second zone, being an extrusion head, where temperature is kept at approximately 180 C.-210 C.; and a third zone, being a head extension, where temperature is kept approximately 3 C. and 8 C.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The present invention is explained more precisely with references to figures added, where:
(2)
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DETAILED DESCRIPTION OF THE INVENTION
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(13) The invented system for producing plastic products from recycled mixed plastic waste comprises a system for mixing raw materials 3, a conveyor 5, a hopper 4 a conveyor 6, a fine mixer with a weighing system (e.g. electronic scales) 7, a control panel 8, an extruder 9, a system of calibration matrices 10 on the calibration table 11, a water-cooling bath 12, a pultrusion machine 13 with a converter 14 and an electric motor with a reducer 15, and an automatic cutter of the products 16. The alternative embodiment of the invention comprises a metal separator 1 with a conveyor 2 to the mixing system 3.
(14) According to the invented system and method in
(15) In the alternative embodiment in
(16) When the raw material is mixed, the resulting mixture comprises approximately 50%-75% raw material produced from plastic waste of low volume weight and approximately 25-50% raw material produced from plastic waste of high volume weight.
(17) After the raw material is mixed, additives are added to the mixture in the mixer 7 with an electronic scales and mixing system; for example, colouring agents, UV protection substances, antioxidants, a foaming agent (e.g. EN3), mineral additives and additives that improve the structure of the material, glass fibres, textile fibres and/or mineral additives approximately in the range of 0.2%-10%. The additive mixer 7 allows for mixing different sizes and adding powdered additives and various colourings at the same time. The mixing takes place on the basis of the volume weight. From the additive mixer, the raw material mixture is taken to the extruder 9. Raw-material bridges are prevented in the mixer and connecting tubes, because this would stop the material from moving.
(18) Foaming is used to regulate the density of plastic products in the approximate range from 0.5-0.85 t/m.sup.3. Changing the speed of the production process changes the density of the final products. At higher speeds, the processed plastic mix spends less time in the system of calibration matrices. Therefore, the foamed part of the products profile expands and the top layer of the product, through which gasses do not pass, becomes thinner. For example, by increasing the production speed by 20%, the density of the plastic products decreases by around 5%-7%. A different density also means different physical characteristics of the final product. For example, lower density incurs smaller weight and poorer flexural strength of the plastic product.
(19) The foaming substance makes the product porous on the inside, and the product is weatherproof, tolerating well temperature fluctuation (from +65 C. to 30 C.). For example, the preferred density of the material used for terrace boards is preferably 0.75-0.85 t/m.sup.3; that of non-bearing materials (e.g. partitions or faade materials) is preferably 0.5-0.6 t/m.sup.3. By adding, for example, a 0.2% foaming agent, the tonnage of the raw material saved up to 20%.
(20) The product according to the present invention can be nailed, milled and sawed well. By using 1%-4% a colouring agent that includes UV protection, the final product receives an aesthetic appearance. For example, 1%-10% glass or textile fibres added increase the flexural strength of the profile up to two times.
(21) The additives added, the continuous extrusion foaming takes place in the extruder 9 in compliance with the temperature curve in
(22) In the alternative embodiment of the invention, a co-extrusion process is used, where another extruder adds a thin layer of one type of polymer to the mixed plastic raw material. The co-extrusion process saves on colouring the whole plastic material, because only the thin top layer of a single type of polymeric material needs to be coloured. In the co-extrusion process, an additional extruder is used to melt a single type of polymeric material that is added to the molten plastic made from mixed plastic waste, immediately before it exits the extruder.
(23)
(24) The material is heated in a single-screw extruder 9 that has at least five heating zones 24-28. The screw of the extruder 9 is designed to mix the material, not to transport it, i.e. the feeding zone 21 of the screw and the compression zone 22 together do not exceed half of the screw length. The mixing zone 23 has a small volume that does not exceed one-third of the volume of the feeding zone 21.
(25) The temperature zones used in the extruder 9 are divided into three: 1) in the first zone 24-28, the barrel, the temperature is kept approximately in the range of 145 C.-180 C.; 2) in the second zone 29-30, the extrusion head, the temperature is kept approximately in the range of 180 C.-210 C.; 3) in the third zone 31, the extended head of the extruder, the temperature is kept approximately in the range of 3 C. and 8 C.
(26) The extruder to be used is chosen on the basis of the cross-section of the final profile because a highly productive extruder is not suitable for making small profiles and vice versa. For example, extruders with a screw diameter 90-120 mm are suitable for making profiles that have a cross-section of 138-140 mm30-32 mm; 138-140 mm38-40 mm; 9595 mm.
(27) The control panel of the extruder shows readings of the zone temperatures, of the ammeter, the rotational speed of the screw, pressure sensors of the extrusion head and line speed (m/min). During the process, the temperature of the extruder motor and the cooling of the gear box is kept under control (max 70 C.).
(28) The control panel is used to control the temperatures of the heating zones of the barrel in compliance with the graph shown in
(29) The temperature sensors that are controlled automatically ensure the stable functioning of the three extrusion stages, so that the polymeric mass exiting the extruder is homogenous and stable.
(30) The screw 9 of the extruder is divided into three zones: the pieces of plastic that have not yet melted are fed onto the screw in the feeding zone 21 and along the compression zone 22; in the compression zone 22, the heaters and abrasion start the melting process; and the mixing zone 23 mixes and pressurises the molten plastic and transports it into the extrusion head 29.
(31) As different types of plastic are mixed and melted, the resulting mass of molten plastic is unstable in the production process. To control it, the feeding zone 21 of the screw is as short as possible and the mixing zone is as long as possible, and the transition between the compression zone 22 and the mixing zone 23 is smooth. The feeding zone 21 and the compression zone 22 together do not exceed half of the length of the screw. The mixing zone 23 has a small volume that does not exceed one-third of the volume of the feeding zone 21.
(32) The extrusion head 29 comprises three heating zones 29.1-29.3, a die 30, a head extension 31 and an isolation plate 39 attached to the die, a flow channel 45, a guide 40 in the centre of the extrusion head 29, a pressure sensor 41 before the guide; pressure and temperature sensors 42 after the guide, the outlet 43 for the molten mass; and a system of pins 44.
(33) The die 30 of the extruder is the last part of the extrusion head 29, and it is designed to match the size and shape of the outlet and the ratio of the outlet and the inlet of the calibration matrix. The latter is preferably approximately 80% of the cross-section of the first calibration matrix 10.1. The guide 40 of the plastic flow is in the middle of the extrusion head 29 imitating the shape of the flow channel 45 of the extrusion head 29, and it is designed to guide the plastic flow to the edges of the plastic profile.
(34) The extrusion head 29 comprises two pressure sensors 41 and 42, one of them before and the other after the flow guiding zone. The sensor on the side of the calibration matrix also measures, in addition to the pressure (3-6 bar), the temperature of the molten plastic exiting the extruder, which is approximately 168-178 C.
(35) The extrusion head 29 comprises three heating zones 29.1-29.3. The head 29 is attached to the extruder in such a way that the outlet of the head 29, where the molten polymeric mass exits from, is parallel to the horizontal axis and crosswise to the vertical axis.
(36) The extrusion head 29 comprises a die 30. The die is used to regulate and guide the exiting molten plastic into the calibration matrix. The inner shape of the die imitates the profile to be produced, i.e. their cross-sections are similar. An isolation plate 39 is attached to the die to reduce heat transfer from the die 30 (up to 200 C.) to the first section of the calibration matrix 10.1, which is approximately 5 C.
(37) In the extrusion head 29, the molten plastic moves only due to the pressure generated by the screw.
(38) The flow channel 45 of the extrusion head 29 gets smaller towards the end, thus creating counter-pressure to the screw. The counter-pressure ensures control over the unstable plastic flow. The pressure inside is controlled by the pressure sensors 41 and 42 attached to the head. The trends of the pressure are monitored, i.e. if the pressure in the extrusion head 29 increases, the speed of the pultrusion machine is increased and vice versa.
(39) The outlet 43 of the die 30 has a cross-section similar to the profile to be produced. The extruder 9 ends with the head extension 31 attached to the die 30. Its temperature is below zero, and the first calibration matrix is attached to it. However, the temperature of the head 29 is up to +200 C.
(40) The outlet 43 of the die 30 has an area of approximately 80-85% of the cross-section of the profile to be produced. At the moment when the molten mass exits the head 29 and enters the calibrator, the pressure drops from 3-6 bar to 0.5-1 bar within 1-2 seconds and to 0.1 bar within the following 10 seconds. The low temperature causes the first cold shock that contributes to the control of the process. The previously known solutions do not have a sub-zero calibration matrix attached to the extrusion head 29 that is up to +200 C.
(41) After the molten mass of plastic exits the extruder 9, it is cooled down in two stages, where the first cools the calibration matrices 10 and the second, the water cooling bath 12. The cooler of the calibration matrices 10 keeps the temperature of the cooling agent at least 5 C. The cooling agent is preferably non-freezing. The couplings of the cooling hoses are quick-connect couplings for quick replacement of calibration matrices. All connection hoses are covered with thermal insulation material to avoid condensate formation and excessive energy losses.
(42) The first cooling phase takes place in the cooling system of calibration matrices 10, where the profile is given a form, and active cooling makes the form permanent. The second phase of cooling takes place when the product is going through the water cooling bath 12.
(43) After cooling, the profiles go to the pultrusion machine 13 that constantly measures pulling strength (approximately 35%-50% of the pulling capacity of the device) and pulling speed (approximately 0.3-0.5 m/min) of the product and automatically adjusts the extrusion speed. It pulls endless profiles through the calibration matrices 10 and water cooling bath 12 up to the automatic saw 16. In contrast to an ordinary pultrusion machine, the solution according to the present invention includes measurement of the pulling strength of the device. The indicator is the basis for the automatic adjustment of the pulling speed, i.e. if the pulling strength increases 1%, the pulling speed is increased by 1% and vice versa. The changes in the pulling strength of the device reflect the friction between the surface of the product and the interior of the calibration matrices. In the final stage of the reprocessing, the automatic saw 16 cuts the profiles into products of suitable length.
(44) In one embodiment of the invention, the system of calibration matrices 10 (see
(45) The system of calibration matrices 10 evenly decreases the pressure of the exiting materialeach following matrix is 0.5 mm bigger than the previous one. The calibration matrices have been designed on the basis of the last 1000 mm matrix that is the size of the profile, i.e. final product.
(46) The calibration matrices are rigidly joined (e.g. with bolts or pin systems) and preferably with an accuracy of 0.01.
(47) The multi-component system of calibration matrices makes it possible to make different profiles, using the same components.
(48) All calibration matrices are centred and level on the calibration table 11. The cooling channels of the calibration matrices are designed to allow control of cooling in the matrices by valves that adjust the volume of the cooling agent that flows through the whole system of matrices 10 or in its parts, thus making it possible to keep the first matrices in the system 10 colder than the last ones. When the pulling strength increases, the cooling is made more intensive by opening the valves in order to maintain the pulling strength of the pultrusion machine at 35%-50% of the maximum capacity, because more intensive cooling reduces friction of the product against the inner surface of the matrix.
(49) A 120 mm calibration matrix is fixed to the extrusion head 29 as an extension of the extruder. The temperature of the head 29 is +200 C. and that of the first calibration matrix 10.1 is 5 C. Other calibration matrices are on a separate calibration table 11.
(50) The table 11 is inflexible and provides adjustment opportunities in different parts. It also includes a locking system that allows for adjustment to be fixed onto the table 11. The calibration table 11 can be moved farther away from the extruder as it is on tracks.
(51) If the calibration table 11 with the calibration matrices 10 is moved against the pin system fixed to the extrusion head 29, the table can be locked in this position to avoid it moving away from the extrusion head 29 due to the pressure exerted by the molten plastic coming out of the extruder.
(52) The lids of the calibration matrices can be pressed shut and fixed at up to 12 tonnes. The possibility to open the matrices allows quick access to their inner chamber.
(53) In ordinary matrix systems, such aggressive liquid-based cooling is not used, and the insides of each following matrix are not bigger than the ones of the previous one in order to reduce the pressure and friction affecting the inner surface of the matrices.
(54) The cooling system of the water cooling bath 12 ensures effective cooling (up to +10 C.) of the cooling water required by the bath. The preferable length of the water cooling bath 12 is 8 meters, comprising a circulating water supply system. The water cooling bath 12 is designed to be used for making different profiles.
(55) The pultrusion machine 13 pulls the extruded profile through the matrices, at the same time creating counter-pressure to the extruder. The counter-pressure forms the profile in the calibration matrices. The gear reducer of the pultrusion machine 13 allows for production at very low speeds, starting from 0.002 m/min. The transmission of the electric motor and reducer system is adjusted optimal for the line speed. The pulling strength applied to the profile by the process of the pultrusion machine 13 is measured. The aim of the pultrusion machine that constantly measures pulling strength and pulling speed and automatically adjusts the extrusion speed is to pull the endless profile through the calibration matrices and water cooling bath up to the automatic saw. The task of the pultrusion machine is to pull the extruded profile through the system of calibration matrices 10, at the same time creating counter-pressure to the extruder 9. The counter-pressure forms the profile in the calibration matrices. The pulling strength applied to the profile by the process of the pultrusion machine is measured. In contrast to an ordinary pultrusion machine, the present technological process includes a measurement of the pulling strength of the machine. The indicator is the basis for the automatic adjustment of the pulling speed.
(56) The automatic saw 16 cuts the profile to a pre-set length; it can be adjusted to various lengths. It is preferable to have a cage around the saw.
(57)
(58) Depending on the statistical composition of polymers in the plastic waste of low and high density volume weight, the plastic product made according to the present invented system and method contains polymers, the composition of which in the realisation includes polystyrene and polypropylene approximately 5%-15%, PE/PP with a similar molecular formula approximately 50%-65% and unidentified types of polymers to the remaining extent. When melting into one, the molten mass of plastic with a similar molecular formula will dominate.
(59) Hence, if a mixture made of plastic waste of high volume weight is added to the composition of plastic waste of low volume weight in the mixing system 3, the molten mass of plastic of a similar molecular formula will dominate in the product according to the alternative embodiment of the present invention. Depending on the need, additional additives can be added as substances providing better control of the production process, i.e. these are used to control the behaviour of the molten mass of plastic during the reprocessing of the composition. The tests have shown that polypropylene (PP) moves in the surface layers 36 of the mass melted during the reprocessing of the composition of mixed plastic waste, and it binds the mass of polymers that have a similar molecular formula from the plastic waste of high and low volume weight. When it touches the wall of the cooling mould, it gives the product a surface 37 that does not let gases through.
(60) The tests have also shown that polystyrene (PS) moves in the middle layers 38 of the composition of mixed plastic waste. As the polystyrene (PS) cools down quicker than other plastics, and polystyrene (PS) is in the middle layers of the molten mass 38, the structure that is the result of cooling does not let the product cave in. Adequate mixing of polystyrene (PS) and other molten plastic in the molten raw material under pressure ensures homogeneity, durability and the porous insides of the product according to the present invention, its density being approximately 0.6-0.8 t/m.sup.3.
(61) When making a product according to the present invention from recycled mixed plastic waste, for example, by adding a foaming agent, the generation of gases is simulated in the molten plastic. When the mass is cooling down, the gases expand and look for a way out of the mass. Polypropylene moves in the surface layers 36 of the molten mass and binds a mass of a similar molecular formula. When it touches the cold walls of the calibration matrices, it forms a surface layer 37 that does not let the gases through. Polystyrene moves in the middle layers 38 of the molten mass. As polystyrene congeals faster than other mass and it is in the middle layers of the molten mass, the structure that is the result of cooling does not let the product cave in. At the same time, polystyrene and other mass is adequately mixed while in a molten state and under pressure. This ensures homogeneity and the porous insides of the product, its density being approximately 0.6-0.8 t/m.sup.3.
(62) To improve the quality of the product, polystyrene (PS) and/or polypropylene (PP) are/is added, in the mixing system 3, to the raw material made from a mix of mixed plastic waste that is unidentified, unclean and unsorted and has been recycled.
(63) In an alternative embodiment of the invention, the plastic products produced according to the system and method of the present invention comprise, for example, matchboards, terrace boards and profiles with various cross-sections.
(64) The characteristics of the final product made according to the system and method for producing products from raw material recycled from mixed plastic waste are as follows: density: 0.6-0.8 t/m.sup.3; dense surface layer 37 of 5-20 mm and porous and foamed insides 38; flexural properties (EN 408): 1843 N/mm.sup.2 at 50 C.; 795 N/mm.sup.2 at 22 C.; and 452 N/mm.sup.2 at 60 C.; linear expansion: 0.069 mm/m/ C. (indicates the product expansion per 1 m when the temperature raises 1 degree by Celsius); flammability class: E (ISO 13501-1); UV-impairment: E=1.1 (no damage) (the UV tests were carried out under standard conditions (ASTM G154) over a period of time correlating to approximately 10 years of natural sunlight. E indicates the change in colour-coordinates (L, a, b)) water absorption: 0.17% (ISO 62) sound isolation: B3 (EN-1793-2) resistance to with no damage from white spirits, lighter fluid, bleach or hot baking oil non-toxic resistant to a temperature fluctuation in the range between +65 C. and 30 C.; linear expansion coefficient: 0.083-0.099, mm/m.Math. C.; surface hardness (ASTM D3363): 4H-5H; load: 166-222 N; nail holding strength (EVS-EN 13446:2002): 1328-1776 N compressive force: 34.1-43.6 kN.
(65) To provide further explication to the invention, the test data of the sample product made using the system and method according to the present invention is given below.
(66) To test flexural properties and dependence on temperature, 690 mm and 810 mm long products were used. The test measured flexural strength, i.e. the bending power required to break the material at a certain temperature. Three repeat tests were used to calculate the average flexural strength (N/mm.sup.2) Flexural modulus of elasticity, i.e. the ability of the material to deform flexibly, was also tested. The bending tests were conducted on the Instron 5866 load frame. In the test, the test products were placed into a solid-CO.sub.2 cooling chamber (50 C.) for 24 hours and into a hot-air oven (60 C.) also for 24 hours; 22 C. was achieved by keeping the products at room temperature. After the required temperature was reached, the products were placed into a four-point bending setup and a load was applied. The bending test was conducted at the load speed of 5 mm/min; the test ended upon breaking of the test product.
(67) The numerical test results, average values and standard deviations for the 690-mm long product with the cross-section of 13832 mm
(68) TABLE-US-00001 Maximum Global flexural modulus of Flexural power elasticity strength N N/mm.sup.2 N/mm.sup.2 50 C. 1 2762.63 1214.32 11.34 2 3637.21 1755.92 14.93 3 5397.96 2559.40 22.16 AVG 3932.60 1843.21 16.14 STD 1342.27 676.78 5.51 22 C. 1 2468.28 703.44 10.13 2 2678.05 730.68 11.00 3 3030.06 952.69 12.44 AVG 2725.46 795.60 11.19 STD 283.88 136.72 1.17 60 C. 1 1539.32 503.18 6.32 2 1686.14 484.33 6.92 3 1612.00 368.99 6.62 AVG 1612.49 452.17 6.62 STD 73.41 72.65 0.30
(69) The numerical test results, average values and standard deviations for the 810 mm long product with the cross-section of 13838 mm
(70) TABLE-US-00002 Maximum Global flexural modulus of Flexural power elasticity strength N N/mm.sup.2 N/mm.sup.2 50 C. 1 4911.98 1489.91 17.11 2 5318.24 1804.36 18.52 3 5816.00 2002.50 20.26 AVG 5348.74 1765.59 18.63 STD 452.78 258.48 1.58 22 C. 1 2902.80 586.37 10.11 2 2893.29 583.78 10.08 3 2891.01 539.08 10.07 AVG 2895.70 569.74 10.09 STD 6.25 26.59 0.02 60 C. 1 1945.10 293.62 6.77 2 2568.48 454.08 8.95 3 2117.59 237.36 7.38 AVG 2210.39 328.35 7.70 STD 321.88 112.46 1.12
(71) The temperature-related change in the dimensions of the material was tested by measuring the linear expansion coefficient. The test was conducted at four different temperatures: 21.3 C.; 5.6 C.; 22.9 C.; 40 C.; and 60 C. The testing devices used were a Sony U30F thickness meter, a freezer (21.3 C.), a refrigerator (5.6 C.) and a hot-air oven (40 C. and 60 C.). The test products were 100 mm long. They were kept at the chosen temperatures for 24 hours and their length was measured immediately after that time.
(72) 13832 mm product. Relative length at the given temperature (mm).
(73) TABLE-US-00003 21.3 C. 5.6 C. 22.9 C. 40.0 C. 60.0 C. 1 9.601 9.845 9.993 10.143 10.261 2 9.775 9.976 10.138 10.301 10.402 3 10.846 11.069 11.24 11.43 11.528 AVG 10.074 10.297 10.457 10.625 10.730 STD 0.674 0.672 0.682 0.702 0.694
13838 mm product. Relative length at the given temperature (mm).
(74) TABLE-US-00004 21.3 C. 5.6 C. 22.9 C. 40.0 C. 60.0 C. 1 10.869 11.117 11.3 11.495 11.662 2 9.603 9.825 10.012 10.2 10.426 3 9.782 10.032 10.202 10.395 10.533 AVG 10.085 10.325 10.505 10.697 10.874 STD 0.685 0.694 0.695 0.698 0.685
Linear Expansion Coefficient
(75) TABLE-US-00005 , mm/m .Math. C. 138 32 mm 0.099 138 38 mm 0.083
(76) Surface hardness was determined using the method according to which the test result is the hardness of the pencil that does not penetrate the surface or leave a scratch on the surface. The method uses pencils of various hardnesses. Their hardness scale is as follows:
(77) TABLE-US-00006 9 H 8 H 7 H 6 H 5 H 4 H 3 H 2 H H F HB B 2 B 3 B 4 B 5 B 6 B 7 B 8 B The hardest Average The softest
(78) The surface hardness of the product is 4H-5H.
(79) To test the maximum load (N) and holding strength (N), a nail was used to find out what is the maximum power that needs to be applied to pull a nail out of the material. The nail was pushed in and pulled out using the R-5 (P-5) pulling machine with a pulling speed of 5 mm/min and pushing speed 20 mm/min. A steel construction nail of 380 mm was inserted into the whole thickness of the material, i.e. the insertion depth was 24 mm, which was the thickness of the test products. Then, the nail was pulled out of the product, and the maximum power applied during pulling was identified.
(80) TABLE-US-00007 Maximum Holding load (N) strength (N) 1 200 1600 2 202 1616 3 190 1520 4 222 1776 5 218 1744 6 202 1616 7 236 1888 8 166 1328 9 216 1728 10 208 1664 AVG 206.0 1648.0 STD 19.2 153.8
(81) The test on the maximum compressive force (kN) and the elongation (mm) upon the maximum compressive force was conducted on the Instron 8802 fatigue testing system at a compression speed of 10 mm/min Edges sawn from non-foamed parts of another profile were placed on both sides of the product for support. The test product was placed between the load cells and force was applied to it until it broke. All test products broke beginning by widening at the middle, in a tubular shape, i.e. first, the centre of the material lost resistance, and right after that the compressive strength also decreased. The characteristics and dimensions (cross-sections differing up to 2 mm) of the test products were rather varying. The foamed part was always the one that broke.
(82) TABLE-US-00008 Maximum Elongation compressive at maximum force compressive (kN) force (mm) 1 38.8 7.3 2 34.1 5.4 3 35.4 5.9 4 36.3 7.1 5 35.9 7.0 6 34.9 6.4 7 38.5 5.3 8 42.5 6.1 9 32.3 4.4 10 43.6 6.5 11 36.7 5.3 AVG 37.2 6.1 STD 3.4 0.9