Multi-layer body and method for the production thereof

Abstract

The invention relates to a multilayer body with a volume hologram layer and a partial opaque layer, arranged on a surface of the volume hologram layer, which is present in a first area and is not present in a second area. The invention furthermore relates to a method for the production of such a multilayer body, as well as a security element and security document with such a multilayer body.

Claims

1. A multilayer body with a volume hologram layer and a partial opaque layer, arranged on a surface of the volume hologram layer, wherein the partial opaque layer comprises an opaque varnish with transparent openings, the opaque varnish being present in a first area and is not present in a second area, and the transparent openings being present in the second area and not being present in the first area, and wherein the multilayer body further comprises a decorative ply, wherein the partial opaque layer is arranged between the volume hologram layer and the decorative ply, and wherein the opaque varnish has a luminance L* in the CIELAB color space of from 0 to 50.

2. The multilayer body according to claim 1, wherein the first area of the opaque layer covers 1% to 99% of the volume hologram layer.

3. The multilayer body according to claim 1, wherein the opaque layer comprises at least one dye, pigment or effect pigment.

4. The multilayer body according to claim 1, wherein the opaque layer comprises a thermoplastic varnish.

5. The multilayer body according to claim 1, wherein the opaque layer has a layer thickness of from 1 m to 5 m.

6. The multilayer body according to claim 1, wherein the first and/or second area forms at least a graphic element.

7. The multilayer body according to claim 6, wherein the graphic element comprises an endless motif and/or an individual image motif.

8. The multilayer body according to claim 6, wherein the graphic element is arranged registered relative to a graphic element of the volume hologram layer.

9. The multilayer body according to claim 1, wherein the volume hologram layer is formed from a UV-curing photopolymer.

10. The multilayer body according to claim 1, wherein the volume hologram layer has a layer thickness of from 5 m to 100 m.

11. The multilayer body according to claim 1, wherein a sealing wax layer is arranged between the volume hologram layer and the partial opaque layer.

12. The multilayer body according to claim 11, wherein the sealing wax layer is formed from a UV-curing varnish the refractive index of which deviates from a refractive index of the volume hologram layer by at most 0.2.

13. The multilayer body according to claim 1, wherein the decorative ply comprises a transparent color varnish layer.

14. The multilayer body according to claim 13, wherein the color varnish layer comprises at least one dye, pigment, effect pigment, thin-film system, and/or cholesteric liquid crystal system.

15. The multilayer body according to claim 1, wherein the color varnish layer and/or the opaque layer is dyed in a complementary color to a base color of the volume hologram layer.

16. The multilayer body according to claim 1, wherein the decorative ply is or comprises a replication layer made of a thermoplastic or UV-curing varnish, with a surface relief.

17. The multilayer body according to claim 16, wherein the surface relief comprises one or more relief structures selected from the group diffractive grating, hologram, blazed grating, linear grating, cross grating, hexagonal grating, asymmetrical or symmetrical grating structure, retroreflective structure, microlens, microprism, zero-order diffraction structure, moth-eye structure or anisotropic or isotropic mat structure, or a superimposition or combination of two or more of the above-named relief structures.

18. The multilayer body according to claim 16, wherein a layer thickness of the replication layer is 1 m to 5 m.

19. The multilayer body according to claim 1, wherein the decorative ply comprises a reflective layer.

20. The multilayer body according to claim 19, wherein the reflective layer is formed as a metal layer made of Cu, Ag, Au or an alloy thereof.

21. The multilayer body according to claim 19, wherein the reflective layer is formed as an HRI (high refractive index) layer made of ZnS, TiO.sub.2 or ZrO.sub.2.

22. The multilayer body according to claim 19, wherein a layer thickness of the reflective layer is from 5 nm to 100 nm.

23. The multilayer body according to claim 1, wherein the multilayer body has an adhesive layer which forms an outer surface of the multilayer body.

24. The multilayer body according to claim 23, wherein a layer thickness of the adhesive layer is from 0.5 m to 15 m.

25. The multilayer body according to claim 1, wherein the multilayer body comprises a substrate, to which the volume hologram layer is applied.

26. The multilayer body according to claim 25, wherein the substrate comprises a carrier ply made of PET, PEN or BOPP, which is arranged on the side of the substrate facing away from the volume hologram layer.

27. The multilayer body according to claim 26, wherein a layer thickness of the carrier ply is from 6 m to 50 m.

28. The multilayer body according to claim 26, wherein the substrate comprises a protective layer made of a UV-curing varnish, PVC, polyester or an acrylate, which is arranged between the carrier ply and the volume hologram layer.

29. The multilayer body according to claim 28, wherein a layer thickness of the protective layer is from 0.5 m to 10 m.

30. The multilayer body according to claim 28, wherein the substrate comprises a detachment layer made of an acrylate, which is arranged between the carrier ply and the protective layer.

31. The multilayer body according to claim 30, wherein a layer thickness of the detachment layer is from 100 nm to 2 m.

32. The multilayer body according to claim 26, wherein the substrate comprises an adhesion-promoter layer made of a mixture of UV-crosslinking monomers, which is arranged between the volume hologram layer and the protective layer.

33. The multilayer body according to claim 32, wherein a layer thickness of the adhesion-promoter layer is from 0.1 m to 3 m.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The invention is now explained in more detail with reference to embodiment examples. There are shown in:

(2) FIG. 1 a schematic sectional representation through an embodiment example of a multilayer body;

(3) FIG. 2 a schematic representation of a design of an embodiment example of a multilayer body;

(4) FIG. 3 a schematic representation of a design of a further embodiment example of a multilayer body;

(5) FIG. 4 a schematic representation of a design of a further embodiment example of a multilayer body;

(6) FIG. 5 a schematic representation of a design of a further embodiment example of a multilayer body;

(7) FIG. 6 a schematic representation of a design of a further embodiment example of a multilayer body;

(8) FIG. 7 a schematic representation of a design of a further embodiment example of a multilayer body.

DETAILED DESCRIPTION OF THE INVENTION

(9) A multilayer body labeled 1 as a whole, for use as a security element, is shown in cross section in FIG. 1 and comprises a substrate 11, to which a protective varnish layer 12 is applied. The substrate 11 is itself constructed multilayered and comprises a carrier ply 111 and a detachment layer 112.

(10) An adhesion-promoter layer 13, on which a volume hologram layer 14 is in turn arranged, is constructed on the protective varnish layer 12. This volume hologram layer is provided with a sealing wax layer 15 on its side facing away from the substrate 11. A partial opaque varnish layer 16, which has transparent openings 161, is applied to the sealing wax 15. A decorative ply 17, which in the embodiment example shown in FIG. 1 comprises a transparent varnish layer 171, a replication varnish layer 172 and a reflective layer 173, adjoins the side of the opaque varnish layer 16 away from the substrate.

(11) Finally, another adhesive layer 18, by means of which the multilayer body 1 can be applied to an object, for example a security document, is applied to the surface of the decorative ply 17 facing away from the substrate 11.

(12) The carrier ply 111 of the multilayer body is preferably formed as a film made of PET and is preferably between 6 m and 50 m thick. The film is expediently transparent to laser radiation, which is used to imprint the volume hologram into the volume hologram layer 14.

(13) The detachment layer 112 is optional and consists, for example, of wax components. A detachment layer 112 is used if the carrier ply 111 is to be removed from the multilayer body 1 after application to an object. This is the case, for example, when the multilayer body 1 is formed as a hot-embossing film. In the case of multilayer bodies 1 formed as laminating films, the carrier ply remains on the multilayer body, with the result that a detachment layer can be dispensed with.

(14) The protective layer 12 can also achieve a separating effect with respect to the carrier ply 111 and can make a separate detachment layer superfluous. The protective layer can in this case, for example, consist of a UV-curing or thermoplastic varnish. Suitable protective varnishes are, for example, formulated on the basis of PVC, polyester or acrylates and are preferably 1 m to 10 m thick. After detachment of the carrier ply 111 the protective layer 12 protects the multilayer body from environmental influences, scratching and the like.

(15) The protective layer can also be designed multilayered. For example, the protective layer has three layers of acrylate, wherein the first partial layer is a high-molecular-weight thermoplastic acrylate, the second partial layer is an acrylate crosslinking with isocyanate (NCO) and the third layer is a high-molecular-weight thermoplastic acrylate.

(16) The adhesion-promoter layer 13 improves the adhesion between the protective layer 12 and the volume hologram layer 14. It is preferably constructed from a mixture of UV-crosslinking monomers and has a layer thickness of from 0.1 m to 3 m, preferably from 0.5 m to 2 m.

(17) The volume hologram layer 14 is constructed from a photopolymer, which is, for example, the Omni DEX 706 photopolymer from Dupont. Further, the use of photopolymers which are present as a liquid substance and are polymerized, and thereby cured, for example by the action of UV light is also possible. It can also be provided to cast the photopolymer as a layer and to precure it by the action of weak UV light or by heat treatment.

(18) The application of the volume hologram layer preferably takes place by means of a printing process, preferably by means of a smearing process. The photopolymer here is preferably in a layer thickness of from 5 to 100 m, further preferably in a layer thickness of approximately 20 m.

(19) The illumination of the volume hologram preferably takes place with the aid of a surface master. Further, it is also possible for a volume hologram to be used as volume hologram master instead of a master provided with a surface relief and for the recording of the volume hologram in the volume hologram layer to take place using a usual, holographic copying process to form a transmission or reflection hologram in the volume hologram layer 14.

(20) The volume hologram layer 14 is UV-curing, with the result that the protective layer 12 is preferably also designed to be UV-curing, in order to achieve a particularly good adhesion. If the protective layer is thermoplastic, the adhesion-promoter layer 13 arranged between protective layer 12 and volume hologram 14 is advantageous in particular.

(21) The volume hologram layer 14 is covered by a sealing wax layer 15 on its side facing away from the substrate 11. This sealing wax is, like the volume hologram layer, UV-curing and seals the molded surface structures of the surface master in the volume hologram layer 14. The sealing wax has a largely identical refractive index to the volume hologram or deviates from it by not more than 0.2.

(22) The opaque varnish layer 16 consists of a pigmented varnish which is as opaque as possible and is preferably thermoplastic. It is applied using gravure printing or screen printing and is 1 m to 5 m thick.

(23) It is preferred if the opaque layer has a luminance L* in the CIELAB color space of from 0 to 50, preferably from 0 to 30.

(24) The luminance L* of the opaque layer is 16 determined in particular by means of the CIELAB Datacolor SF 600 measuring system, which is based on a spectrophotometer. In the colorimetric determination of color differences in body colors according to the CIELAB formula L*a*b*, the value L* represents the light/dark axis, the value a* represents the red/green axis and the value b* represents the yellow/blue axis. The L*a*b* color space is thus described as a three-dimensional coordinate system, wherein the L* axis describes the lightness and can adopt a value between 0 and 100.

(25) The measurement of the lightness L* preferably takes place under the following conditions: Measurement geometry: diffuse/8 according to DIN 5033 and ISO 2496 Diameter of measurement opening: 9 mm Spectral range: 360 nm-700 nm according to DIN 6174 Standard illuminant: D65

(26) The openings 161 in the opaque layer 16 form a graphic element, in particular a motif, an image, a symbol, a logo and/or an alphanumeric character.

(27) This graphic element contributes to the overall design of the multilayer body 1 and thus increases the protection against forgery. Depending on the relative arrangement and formation of the layers, this element can be visible together with the volume hologram or can be dependent on the angle of observation independently of this.

(28) The graphic element preferably comprises an endless motif and/or an individual image motif.

(29) The graphic element can be arranged registered relative to a graphic element of the volume hologram layer.

(30) The openings 161 in the opaque layer 16 are either a continuous endless pattern or an individual image decoration or a combination thereof. The openings can (but need not) be arranged registered relative to the motif of the volume hologram.

(31) The volume hologram can, for its part, likewise have either a continuous endless pattern or an individual image decoration or a combination thereof.

(32) Optionally another translucent color varnish layer 171 can be applied to the opaque layer 16 in order to dye the subsequent layers with their optical effect.

(33) In order to realize further optically variable diffractive or refractive structures, the decorative ply 17 comprises a replication varnish layer 172 with a surface relief. This is thermoplastic or UV-curing and 1 m to 5 m thick. The material of the replication varnish layer 172 is preferably highly transparent.

(34) The surface relief preferably comprises one or more relief structures selected from the group diffractive grating, hologram, blazed grating, linear grating, cross grating, hexagonal grating, asymmetrical or symmetrical grating structure, retroreflective structure, microlens, microprism, zero-order diffraction structure, moth-eye structure or anisotropic or isotropic mat structure, or a superimposition of two or more of the above-named relief structures.

(35) A reflective layer 173 made of metal, preferably of Al, Cu, Ag, Au or of alloys of the above-named metals, which serves to make the diffractive structures of the replication varnish layer 172 visible, is vapor-deposited directly onto the replication varnish layer 172. Alternatively an HRI (high refractive index) layer, in particular made of ZnS, TiO.sub.2 or ZrO2, is also possible. Alternatively a varnish layer with metallic pigments can also be provided.

(36) The layer thickness of the reflective layer is expediently from 5 nm to 100 nm, preferably from 10 nm to 50 nm.

(37) A single- or multilayer adhesive layer 18, which can be formed thermoplastic, UV-curing or thermally curing, is applied to the reflective layer 17. Different partial layers of the adhesive layer can fulfill different functions, for example to promote adhesion to neighboring layers or to the object to which the multilayer body is to be applied. A function as a barrier layer against the diffusion of substances from and/or into neighboring layers is also possible.

(38) Exemplary designs of multilayer bodies of this type are shown in top view in FIGS. 2 to 7.

(39) FIG. 2 shows a multilayer body 1 with two out-of-register, continuous endless decorations which are not matched to each other, but are superimposed randomly. In this embodiment example the flowers 2 are realized in the volume hologram. The volume hologram can show either only the outlines or also a two-dimensional flower, or also both. The leaves 3 in the decoration are realized through the openings 161 in the opaque layer 16. Here too, the opening can represent either the outline or also the entire leaf surface area.

(40) As FIG. 3 shows, an individual image, here the flower 2, in the volume hologram can also be combined with an endless decoration, here the leaves 3, in the opaque layer 16. The individual image is designed registered relative to the substrate, the endless decoration is designed out-of-register relative to the substrate and also to the individual image.

(41) A registered arrangement of the decorations is also possible, as FIG. 4 shows. The relative position of the two decorations is aligned relative to each other such that the two decorations together form an overall decoration. In other words, in practice, the flowers 2 in each case are to be arranged in gaps between the leaves 3. Here too, the flowers 2 of the decoration are formed by the volume hologram layer 14, while the openings 161 in the opaque layer 16 form the leaves 3.

(42) The opaque layer 16, alone or in combination with the decorative ply 17, can also form more complex structures. In the embodiment example according to FIG. 5 the opaque layer 16 has a decoration consisting of several dark colors (represented dotted), which can interact with the two other decorations or with them can form an overall decoration. Here a leaf motif 3, which is combined with openings 161 which are likewise formed in the shape of leaves 3, is thus provided on the dark layer.

(43) The decoration of the multilayer body 1 can furthermore vary in sections, as represented in FIG. 6. Here the design of the opaque layer 16 and the decorative ply 17 varies in the three partial areas 4, 5, 6 of the multilayer body 1.

(44) It is also possible to omit the decorative ply 17 and also the opaque layer 16 completely in a section, in order to design the volume hologram 14 transparent in this section. For example, the volume hologram 14 in this section then lies on a light background made of white paper or plastic of the substrate 11, which is covered in the other sections by the opaque layer 16 and the decorative ply 17. Specific optical effects can thereby be produced by the volume hologram 14 being present with a lower brilliance of the optical effects in the omitted section than in the neighboring sections, where the volume hologram 14 is present a higher brilliance brought about by the opaque layer 16 and the decorative ply 17. In particular due to design elements of the volume hologram 14 overlapping both sections, these design elements can be altered locally in terms of their brilliance due to the different background. For example, a continuous line of the volume hologram 14 can have a low brilliance in one section and a high brilliance in the neighboring section, wherein both line sections are arranged totally positionally accurate relative to each other.

(45) It is also possible for the decorative ply 17 in a section to be omitted in the second areas 161 of the opaque layer 16 in which the opaque layer is not present, in order to leave the substrate 11 visible in these areas. In other words, the substrate 11 forms the background for the volume hologram 14. If, for example, the substrate 11 is light, in particular white, paper or plastic, the brilliance of the volume hologram 14 is accordingly lowered or reduced.

(46) However, the substrate 11 can also already have color layers or other decorative layers, which are then at least partially visible through the second areas 161 of the opaque layer 16 and through the transparent volume hologram 14 and likewise form a background for the volume hologram 14. Due to the substrate 11 shining through the second areas 161 of the opaque layer 16, optical effects that are distinctive and at the same time difficult to forge can in turn be produced.

(47) In FIG. 7 a further embodiment example is shown in which, for the sake of clarity, only the decoration of the opaque layer 16 is shown and the likewise present decorations of the volume hologram layer 14 and the openings 161 in the opaque layer 16 are not represented.

(48) The decoration of the opaque layer 16 (represented with continuous lines) can interact or be combined with a further decoration on the object to which the multilayer body 1 is applied (further decoration represented dotted). The horizontal lines show the outer edges of a strip of film formed by the multilayer body 1.

(49) For example, the opaque layer 16 can end transparently towards the edge of the strip of film and gradually expose a printed motif located underneath and/or next to the strip of film.

(50) In this example, the opaque layer 16 has a motif of leaves 3, which increases in transparency towards the edge of the multilayer body 1. The object to which the multilayer body 1 is to be applied likewise has a leaf motif, and the two leaf motifs form an overall representation.

LIST OF REFERENCE NUMBERS

(51) 1 multilayer body 11 substrate 111 carrier ply 112 detachment layer 12 protective layer 13 adhesion-promoter layer 14 volume hologram layer 15 sealing wax layer 16 opaque layer 161 openings 17 decorative ply 171 color varnish layer 172 replication varnish layer 173 reflective layer 18 adhesive layer 2 flowers 3 leaves 4,5,6 areas