Glass panel comprising a liquid crystal film

Abstract

A laminated automotive glazing including a PDLC film powered electrically by an AC current or a frequency lower than 100 Hz. The voltage varies non-sinusoidally, and a maximum of an effective voltage does not exceed 80 Vrms.

Claims

1. A laminated automotive glazing comprising: a PDLC film powered electrically by an AC current having a frequency of from 20 Hz to less than 50 Hz, a voltage varying non-sinusoidally, a maximum of an effective voltage not exceeding 55 Vrms, wherein a residual scattering in an actuated state is no higher than 5% for a temperature not exceeding 50 C., and wherein power required to obtain the actuated state is no higher than 10 W/m.sup.2 of PDLC film.

2. The glazing according to claim 1, wherein the maximum of the effective voltage does not exceed 50 Vrms and a minimum effective voltage is 30 Vrms.

3. The glazing according to claim 1, wherein a voltage variation has a trapezoidal profile.

4. The glazing according to claim 3, wherein the voltage does not exceed 50 Vrms.

5. The glazing according to claim 3, wherein the voltage variation has a trapezoidal shape with a rise time of 0.5 to 2 ms.

6. The glazing as claimed in claim 1, wherein the frequency is no lower than 25 Hz.

7. The glazing according to claim 1, wherein the residual scattering in the actuated state is no higher than 3% for a temperature not exceeding 60 C.

8. The glazing according to claim 1, wherein a direct light transmission in the unactuated state is no higher than 1%.

9. The glazing according to claim 1, wherein a direct light transmission in the unactuated state is no higher than 0.5%.

10. The glazing according to claim 1, wherein power required to obtain the actuated state is no higher than 5 W/m.sup.2 of PDLC film.

11. The glazing according to claim 1, wherein a voltage variation has a square profile.

12. The glazing according to claim 1, wherein the maximum of the effective voltage does not exceed 50 Vrms.

13. The glazing according to claim 1, wherein the PDLC film is powered electrically by an AC current having a frequency of 30 Hz or lower.

14. The glazing according to claim 13, wherein the PDLC film is powered by a current that does not exceed 200 mA.

15. An automotive roof comprising: two glass sheets; a first interlayer sheet; and a PDLC film powered electrically by an AC current having a frequency of from 20 Hz to less than 50 Hz, a voltage varying non-sinusoidally, and a maximum of an effective voltage not exceeding 50 Vrms, wherein a residual scattering in an actuated state is no higher than 5% for a temperature not exceeding 50 C., and wherein power required to obtain the actuated state is no higher than 10 W/m.sup.2 of PDLC film.

16. The glazing according to claim 15, wherein a voltage variation has a trapezoidal profile.

17. The glazing according to claim 15, further comprising second and third interlayer sheets, wherein the second interlayer sheet defines a housing for the PDLC film.

18. The glazing according to claim 15, wherein the minimum effective voltage is 30 Vims.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The invention is described below with reference to the figures in which:

(2) FIG. 1 shows a schematic exploded view of a glazing comprising a PDLC film;

(3) FIG. 2 shows a cross-sectional schematic of the glazing in FIG. 1 but assembled;

(4) FIG. 3 is a graph illustrating the variation in the proportion of diffuse light (haze) to the total, i.e. direct and diffuse, transmission, such as defined in standard ASTM 1003, as a function of temperature in the unactuated state;

(5) FIG. 4 is analogous to FIG. 3, the film being actuated;

(6) FIG. 5 shows, for three separate samples, the variation in the direct transmission TL in the unactuated state as a function of temperature;

(7) FIG. 6 illustrates a conventional voltage signal mode and a mode according to the invention;

(8) FIG. 7 shows by comparison the residual scattering in actuated mode under conventional conditions and under conditions according to the invention;

(9) FIG. 8 just like FIG. 7 shows by comparison the total transmission for the actuated mode;

(10) FIG. 9 shows the effect of various effective voltages on the residual scattering for trapezoidal signals.

(11) The glazing shown in FIGS. 1 and 2 is intended to be a constituent of an automotive roof. In this chosen application, a low light transmission is required in all circumstances, whether or not the PDLC film is actuated. For this reason the assembly formed of the glass sheets and the interlayers very substantially decrease transmission.

(12) In the chosen example, the glazing comprises two glass sheets 1 and 2. Sheet 1 is made of clear glass to minimize its absorption of solar infrared. It is coated on its face that is turned toward the interlayers with a set of layers that selectively reflect the infrared, which set of layers is referenced 6 in FIG. 2. In the chosen example, it is a set comprising three layers of silver with dielectric layers separating these metal layers. The system of layers is of the type described in publication WO 2005/00348.

(13) The proportion of incident energy that is transmitted through the system of layers is thus limited to about half. The combination of the clear glass sheet and the reflective layers limits the heating of the glazing, and therefore of the PDLC film, when it is exposed to solar radiation.

(14) Under the glass sheet 1 coated with the reflective layers, a first interlayer sheet 3 of gray PVB makes contact with the PDLC film 4. The film itself is inserted into a frame 5 that is formed of a PVB sheet in which the housing for receiving the film 4 is produced. Another PVB sheet 3 makes contact with the second face of the film 4.

(15) The interlayer sheets and the film 4 each have a thickness of 0.38 mm.

(16) The second glass sheet is made of highly absorbent gray glass. Each glass sheet has a thickness of 2.1 mm.

(17) The glass sheets and interlayers (in the absence of the PDLC film) together have a light transmission of 7-8%. The presence of the PDLC film allows this light transmission in scattered or transmitted form to be modified as indicated below.

(18) In the reported trials the PDLC film was supplied by the company Innoptec. This film, as most of the films of this type originating from other suppliers, was formed of a polymer matrix containing liquid crystals. This matrix was coated on each of its faces with electrodes formed of sheets of PET (polyethylene terephthalate) coated with a layer of conductive oxide (ITO).

(19) Manufacturers firstly require that glazings including a PDLC film meet their requirements in respect of optical properties. To do this, in the unactuated state the glazing must scatter practically all the visible light that passes through the glazing. The scattering is that measured according to standard ASTMD 1003. It is done with an integrating sphere and comprises the light actually scattered as well as any light that is practically not deviated at all (less than 2 with respect to the incidence), which light is designated as transmitted light.

(20) In the reported trials, the chosen illuminant was illuminant C.

(21) The trialed film was firstly subjected to a sinusoidal AC current with a maximum voltage of 70 Vrms (i.e. a maximum of 100 V) and a frequency of 50 Hz.

(22) In a first trial, the results of which are shown in FIG. 3, the variation in the ratio of the scattering to the total transmission (referenced haze) and the value of the total transmission of the glazing as a function of the temperature of the glazing were measured. It may be seen that practically complete scattering is obtained in the unactuated state at room temperature. The percentage of total transmitted light is lower than 10%. Under these conditions, the glazing was translucent and played its role as a screen masking the objects located on the other side of the glazing with respect to the observer.

(23) These characteristics remained little modified when the temperature of the glazing was increased to about 50 C. Beyond, the scattering character rapidly attenuated.

(24) The same glazing was tested under actuated conditions. The results are shown in FIG. 4. This time the scattering was very much less. The preceding ratio remained below 4% for temperatures below 55 C. It then increased because of a decrease in the effect of the electric field on the liquid-crystal particles.

(25) The total transmission in the 2 of angle remained little changed at about 6%.

(26) FIG. 5 illustrates the ratio of the direct TL to the total amount of transmitted light (direct TL+scattered light) in unactuated mode for three separate samples (a, b, c). This ratio shows how effective the film is at creating a private mode.

(27) To improve the characteristics of the supply of the PDLC film, the voltage used is such as shown in FIG. 6. This figure includes the conventional type with a supply the voltage (70 Vrms) of which varies sinusoidally at a frequency of 50 Hz. FIG. 6 also shows a supply according to the invention. According to the invention, the frequency is decreased to 30 Hz, and the voltage signal is of trapezoidal shape with an effective voltage of 48 Vrms. The voltage rise time is 1 ms and leads to a current that does not exceed 200 mA. It will be noted that the same frequency and the same voltage, but with a square signal, led to an initial current peak of about 2 A.

(28) In the configuration according to the invention, it was first verified that the optical properties of the glazing had not been adversely affected. In the unactuated mode it goes without saying that nothing changed. For the actuated mode, the curves corresponding to the glazing according to the invention (d) and to the comparative glazing (e) in FIGS. 7 and 8 show that an almost perfect concordance was obtained in the residual scattering (FIG. 7) and the total transmission (FIG. 8). The supply mode according to the invention therefore perfectly preserves the properties of the PDLC film used under prior-art conditions.

(29) FIG. 9 shows the variation in the residual scattering as a function of temperature for a frequency of 30 Hz and for various values of the effective voltage of a trapezoidal voltage signal. It will be noted that a minimum voltage is necessary to obtain a residual scattering of acceptable order of magnitude. At 20 Vrms the scattering is excessive. It decreases rapidly when the effective voltage reaches 30 V and practically stabilizes for the values of 40 and 48 Vrms, showing that an additional increase would be pointless. By way of indication, the prior-art mode is also noted in the figure (value 70 Vrms).

(30) The power required under the various conditions was compared. The following table collates the recorded results. This table shows the shapes and frequencies applied, the effective voltage, and the power consumed per square meter of PDLC film. The measurements were carried out at a temperature of 60 C.

(31) TABLE-US-00001 Voltage Frequency Power Shape Vrms Hz W/m.sup.2 Sinusoidal 70 50 17 Trapezoidal 48 30 6.8 Trapezoidal 40 30 5.7 Trapezoidal 30 30 4.2 Trapezoidal 25 30 3.5

(32) The first row corresponds to the reference serving as the basis for comparison. It will be noted that whatever the trial, under the conditions of the invention the consumed power was substantially less than for the comparative example. It will also be noted that for a given frequency (30 Hz) with a given signal shape, the power consumed decreases significantly with the applied effective voltage, the latter, if chosen with a little care, allowing a low residual scattering to be maintained, as indicated with regard to FIG. 9.