SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE

Abstract

The present invention addresses to a system that aims at reproducing situations close to those found in oil wells, in relation to the thermodynamic conditions (pressure and temperature), and the fluids present (by means of the chemical species involved), aiming at representing in a more realistic way the production scenarios to be faced. The main scope is to represent on a laboratory scale the phenomenon of depressurization with the release of carbon dioxide inducing the precipitation of calcite (calcium carbonate), the growth and agglomeration of inorganic crystals, and the phenomena of adhesion and scale on common metallic surfaces of elements of completion of oil wells.

Claims

1. A SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE, characterized in that it comprises a reactor/pressurized cell (1) coupled to a core-holder (2) and a screened core-holder (3), an optical microscope, cold water buffer tank (4), heater (5), cooler (6), booster (7), safety valves (8), control valves (9), control panel (10), solids collection filter (11), impeller with coupon basket, gas vent/relief system (12), dynamic display (13), pressurized pipette (14), circulation pump (15), gas flowmeter (16), pneumatic lifter (17), nitrogen pressurized buffer tank (18), various sensors, sample collector (19), hydrocyclone (20), in-process reagent addition funnel (21), safety vent/gas exhauster (22), distilled water system (23), and pH meter (coupled to the reactor).

2. THE SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE according to claim 1, characterized in that the reactor/pressurized cell (1) is able to operate at pressures of up to 100 bar (10 MPa) and temperatures between 2° C. and 100° C., assisted by the subsystems of cooling (6) with a cold water buffer tank (4), heating (5) and pressurization booster (7) with a nitrogen pressurized hot water buffer tank (18), controlled by valves (9) and (12), sensors, transducers, pH meter, flowmeter (16), control panel (10), with the process safety guaranteed by safety valves (8) (check, PSV, PRV and PCV), by the gas vent line (22) and by the hydrocyclone (20), and with the auxiliary features of operating distilled water (23) and lifting the reactor cover by the pneumatic lifter (17).

3. THE SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE according to claim 1, characterized in that the core-holder (2) allows investigating the phenomenon of inorganic precipitation in porous specimens, which aim at representing not only a gravel-pack-type sand containment system, but also a near-well condition.

4. THE SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE according to claim 1, characterized in that the screened core-holder (3) is designed to support screen coupons that represent screen-type sand containment systems, such as wire-wrapped and premium.

5. THE SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE according to claim 1, characterized in that the optical photomicroscopy system is capable of capturing particles with an equivalent diameter of 2.0 micrometers, at a pressure of 100 bar (10 MPa) directly inside the reactor (1) or the dynamic display (13), allowing the incorporation of features that capture particles with an equivalent diameter of 0.5 micrometers for lower pressures.

6. THE SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE according to claim 1, characterized in that the solids collection filter (11) associated with the recirculation pump (15) is able to remove solid particles from the solution, allowing supersaturation tests to be performed.

7. THE SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE according to claim 1, characterized in that the metallic coupon cage operates inside the pressurized reactor (1) comprising: magnetic coupling of the motor (24), upper support (25), set of 8 coupons (26), lower support (27), and impeller type stirrer for bubbling CO.sub.2 (28).

8. THE SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE according to claim 7, characterized in that the coupon cage installed inside the reactor (1) is able to evaluate the dynamic fouling in different materials, metallic or not, with different finishings and with different types of coating.

9. THE SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE according to claim 1, characterized in that the dynamic display (13) can be used to visualize particles in flow, by displacing the microscope to its viewing windows.

10. THE SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE according to claim 9, characterized in that the dynamic display (13) is provided with on-off valves, being possible to store an aliquot of the contents of the reactor (1) at the test pressure, detach the display from the set, and transport the same for analysis on other equipment outside the laboratory.

11. THE SYSTEM FOR EVALUATION OF THE PRECIPITATION, ADHESION AND INORGANIC SCALE according to claim 1, characterized in that the pressurized pipette (14) is able to inject reagents during the tests with the reactor (1) already pressurized and heated.

Description

BRIEF DESCRIPTION OF DRAWINGS

[0018] The present invention will be described in more detail below, with reference to the attached figures which, in a schematic form and not limiting the inventive scope, represent examples of its embodiment. In the drawings, there are:

[0019] FIG. 1, which illustrates the descriptive flowchart of the system of the present invention;

[0020] FIG. 2, which illustrates a set with premium screen coupon and sintered element that allows simulating the packing of proppant or coupling with the porous medium, which may be used inside the core-holder (3) of FIG. 1;

[0021] FIG. 3, which illustrates the porous specimens that may be used within the core-holders (2) and (3) of FIG. 1, which allow simulating the rocky environment;

[0022] FIG. 4, which illustrates a schematic drawing of the metallic coupon cage that will operate inside the pressurized reactor (1) of FIG. 1. There are represented in there: magnetic coupling of the motor (24), upper support (25), set of 8 coupons (26), lower support (27), impeller-type stirrer for bubbling CO.sub.2 (28);

[0023] FIG. 5, which illustrates the coupling of lenses of the photomicroscopy system for the non-invasive investigation of phenomena associated with fouling, which will operate in front of the viewing windows of the reactor (1) or the dynamic display (13) of FIG. 1. There are represented: 10×objective lens (29), LED ring light (30), 4.7× ultrazoom (31), 3.3× zoom adapter (32), high resolution digital camera (33);

[0024] FIG. 6, which illustrates the formation of CaCO.sub.3 crystals in a test performed in beaker, obtained with the photomicroscopy system of FIG. 5;

[0025] FIG. 7, which illustrates a graph of the validation of the photomicroscopy technique (which is non-invasive and can be applied in in situ conditions) against the technique of granulometry by laser beam diffraction (which is invasive and can only be applied in atmospheric conditions), for samples of the same CaCO.sub.3 solution prepared in a beaker.

[0026] FIG. 8, which illustrates an experimental core-holder without the presence of gas and without the possibility of operating at temperatures higher than the ambient one. There are represented: water tank (34), pump (35), transfer cell—fluid 1 (cylinder-piston system) (36), transfer cell—fluid 2 (cylinder-piston system) (37), pressure transducers (38), core-holder (39), rock sample (porous medium) (40), balance (41);

[0027] FIG. 9, which illustrates a graph of the pressure evolution in the core-holder of FIG. 8 as a function of BaSO.sub.4 precipitation;

[0028] FIG. 10, which illustrates the experimental setup for study on a screen at low pressure and at room temperature. There are represented: positive displacement helical pump (42), pressure accumulators (43), mechanical coupling (screen holder) (44), screens (45), pressure transducers (46), flowmeter (47), reservoir of fluid (20 liters) (48), bypass (49);

[0029] FIG. 11, which illustrates the carbonate fouling in a screen coupon for a test performed on the apparatus of FIG. 10;

[0030] FIG. 12, which illustrates the pressure curve as a function of the restriction caused by the accumulation of CaCO.sub.3 on the surface of the screen coupon for a test performed on the apparatus of FIG. 10.

DETAILED DESCRIPTION OF THE INVENTION

[0031] The experimental system of the present invention aims at reproducing situations close to those found in oil wells, not only at thermodynamic ones (pressure and temperature), but also in relation to fluids (by means of the chemical species involved), aiming at representing in a more realistic way the scenarios of completion to be faced. The main scope is to represent on a laboratory scale the phenomenon of depressurization with the release of carbon gas, inducing the precipitation of calcite (calcium carbonate), the growth and agglomeration of inorganic crystals, and the phenomena of adhesion and scale on metallic surfaces and in porous media.

[0032] The system for evaluating precipitation, adhesion and inorganic fouling, object of this invention, is illustrated in FIG. 1 comprising the following components: a reactor or pressurized cell (1) coupled to a core-holder (2) and a screened core-holder (3), an optical microscope (mobile accessory—not shown), a cold water buffer tank (4), a heater (reboiler) (5), a cooler (6), a booster (pressure increase) (7), safety valves (8) (check, PSV, PRV and PCV), control valves (9), a control panel (10), a solids collection filter (11), an impeller with coupon basket (element internal to the reactor—shown in FIG. 4), gas vent relief valve and line (12), a dynamic display (13), pressurized pipette (14), a circulation pump (15), a gas flowmeter (16), a pneumatic lifter (17), a nitrogen pressurized hot water buffer tank (18), several sensors (not identified in the figure), a sample collector (19), a hydrocyclone (20), a funnel of addition of in-process reagents (21), a safety vent/gas exhauster (22), a distilled water system (23), a pH meter (represented in the figure coupled to the reactor—unidentified).

[0033] The reactor/pressurized cell (1) is capable of operating at pressures of up to 100 bar (10 MPa) and temperatures between 2° C. and 100° C., assisted by the subsystems of cooling (6) with cold water buffer tank (4), heating (5) and pressurization booster (7) with nitrogen pressurized hot water buffer tank (18), controlled by valves (9) and (12), sensors, transducers, pH meter, flowmeter (16), control panel (10), with the process safety guaranteed by safety valves (8) (check, PSV, PRV and PCV), by the gas vent line (22) and by the hydrocyclone (20), and with the auxiliary resources of distilled water operation (23) and lifting of the reactor cover by the pneumatic lifter (17).

[0034] As can be seen in the flowchart of FIG. 1, the process begins with the addition of dissolved chemical species (such as NaHCO.sub.3) in the reactor (1). Next, the pressurization of the system begins by injecting CO.sub.2 and/or N.sub.2. Through the previously pressurized pipette (14), the second solution (CaCl.sub.2) is introduced into the system. Once the system is homogenized, the temperature is adjusted by the heating system (5). Once the desired thermodynamic conditions have been reached, pH measurements are carried out in order to monitor the process during depressurization, which occurs by opening the relief valve (12). Concomitantly, the behavior of the precipitation of calcite crystals is monitored through the microscope of FIG. 5 positioned in the viewing window.

[0035] The reactor (1) has the option of connecting to auxiliary equipment (core-holders (2 and 3)), in which the depressurization will occur when passing through a completion element. This element can be a screen coupon (FIG. 2), representing a containment screen, or a porous medium (FIG. 3), representing a gravel-pack, or even a near well region. In this type of experiment, the effect of precipitation/fouling on the head loss associated with flow in the completion element can be evaluated. The system in question still allows the combination of the two systems, resulting in a coupon arrangement of screen and porous media simultaneously. It should be highlighted that the operation of these modules requires a pressure and temperature control system independent of the reactor system.

[0036] Another auxiliary equipment of the reactor (1) is the dynamic display (13). The reactor contents can be unloaded by passing through the display, where the particles can be visualized in flow, by displacing the microscope in FIG. 5 to the viewing windows of the dynamic display. In addition, the dynamic display (13) is provided with on-off valves, which allows confining a sample of the solution inside the same; that is, it allows to store an aliquot of the contents of the reactor (1) at the test pressure, being possible to detach the display from the set and transport the same for analysis in other equipment outside the laboratory.

[0037] The optical photomicroscopy system is capable of capturing particles with an equivalent diameter of 2.0 micrometers, at a pressure of 100 bar (10 MPa) directly inside the reactor (1) or the dynamic display (13), admitting the incorporation of features that capture particles with an equivalent diameter of 0.5 micrometer for lower pressures.

[0038] The solids collection filter (11) associated with the recirculation pump (15) is capable of removing solid particles from the solution, allowing supersaturation tests to be performed.

[0039] The hose system for selecting the type of auxiliary equipment to be used also allows the coupling of any other equipment that may be developed and that is intended to be tested under the presence of a pressurized, heated fluid containing precipitated material and in the presence of gases, like, for example, the prototype of an intelligent valve.

[0040] With the system operating with the metallic coupon basket, as shown in FIG. 4, it is possible to evaluate the deposition of CaCO.sub.3 on different metallic surfaces, when subjected to the same depressurization process. In this way, it is possible to evaluate not only the effect of the material, but also the type of finishing (polished, burnished, ground), or even surfaces that have a polymeric coating layer. That is, the coupon cage installed inside the reactor (1) is capable of evaluating dynamic fouling in different metallic or non-metallic materials, with different finishings and with different types of coating.

[0041] The coupling of the pressurized reactor (1) to two core-holders, that is, the core-holder (2) and the screened core-holder (3), will allow to evaluate the phenomenon of fouling in systems that represent the reservoir (porous medium), the well-reservoir coupling region, or constituent parts of completion elements (screens and gravel-pack).

[0042] With the conventional core-holder (2), it is possible to investigate the phenomenon of inorganic precipitation in porous specimens, which aim at representing not only a gravel-pack-type sand containment system, but also a near well condition. The second core-holder (3) is designed to support screen coupons that represent screen-type sand containment systems, such as wire-wrapped and premium, further allowing configurations with screen and porous medium, or even with porous medium, screen and porous medium, which makes it possible to evaluate the interface between porous medium and screen, and also between screen and proppant material of the gravel-pack.

[0043] The system has a multipurpose bias, allowing the study to be extended to related systems, such as inorganic scale around barium sulfate, and organic scale from methane hydrates or calcium and sodium naphthenates (organic soaps that are strongly dependent on the thermodynamics of CO.sub.2, such as calcium carbonate).

[0044] Another aspect is the versatility of the system, which also allows temperature variation (up to 100° C.) and the insertion of other chemical species, aiming at evaluating the effect of salinity in the precipitation, adhesion and scaling processes.

[0045] It is worth to highlight that the system of the present invention has viewing windows that aim at monitoring the process in a non-intrusive way by means of photomicroscopy techniques. This strategy allows monitoring the dynamic behavior of crystals formed in the process (growth and agglomeration) under in situ conditions. Changing the thermodynamic conditions used with intrusive techniques has the potential to change the variables investigated.

[0046] Some experimental tests were carried out to evaluate the phenomena involved, in order to assist in the design and dimensioning of the system of the present invention.

[0047] Under laboratory conditions (ambient temperature and pressure), the technique of monitoring the dynamic behavior of calcite crystals was studied. The main objective was the validation of the microscopy technique against the established technique of granulometry by laser beam diffraction.

[0048] The result obtained by the analysis of microscope images (represented in FIG. 5), as shown in FIG. 6, in a non-intrusive condition, showed good agreement, as represented in FIG. 7.

[0049] Regarding precipitation in porous elements (gravel-pack), preliminary experimental tests were conducted on an apparatus to investigate the experimental conditions for precipitation in pressurized porous media (FIG. 8).

[0050] Through the formation of BaSO.sub.4 crystals in the system, it was possible to evaluate the pressure growth over time, as shown qualitatively in FIG. 9.

[0051] In a similar way, to evaluate the fouling in screen coupons, experiments were carried out under laboratory conditions of pressure and temperature (FIG. 10).

[0052] The change in the pressure curve as a function of the restriction caused by the accumulation of CaCO.sub.3 on the surface of the screen coupon (FIG. 11) can be seen in FIG. 12.

[0053] In the system of the present invention, an evaluation of the fouling potential in screen coupons is provided; however, in a lower flow rate condition, below the erosion velocity of the sand containment systems.

[0054] It should be noted that, although the present invention has been described in relation to the attached drawings, it may undergo modifications and adaptations by technicians skilled on the subject, depending on the specific situation, but provided that it is within the inventive scope defined herein.