Gas turbine cycle equipment, equipment for recovering CO2 from flue gas, and method for recovering exhaust heat from combustion flue gas
10480406 ยท 2019-11-19
Assignee
Inventors
Cpc classification
F05D2220/32
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C3/305
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28C1/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05D2220/60
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C7/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C6/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C7/1435
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C3/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05D2260/211
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C7/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05D2220/76
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02C20/40
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F22B1/1815
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E20/32
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F28C2001/006
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05D2260/213
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05D2240/35
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05D2220/75
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E20/16
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F01K21/047
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28C1/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05D2260/61
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F05D2260/212
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C3/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F02C3/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C7/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01K21/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C6/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C7/143
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C3/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28C1/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F22B1/18
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28C1/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F02C7/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
By using a combustion flue gas (18) from a power turbine (16), a high-pressure secondary compressed air (12C) is subjected to heat exchange in a first heat exchange unit (19A) of an exhaust heat recovery device (19), and by using resultant heat-exchanged flue gas (18A), a low-pressure primary compressed air (12A) is subjected to heat recovery in a second heat exchange unit (19B) of a saturator (31). Then, a primary compressed air (12B) that has been subjected to heat recovery in the second heat exchange unit (19B) is introduced into a secondary air compressor (22) to increase the pressure of the air, and then the high-pressure air is subjected to heat recovery in the first heat exchange unit (19A), producing a secondary compressed air (12D). The secondary compressed air (12D) is introduced into a combustor (14) and combusted using fuel.
Claims
1. A method for recovering exhaust heat from combustion flue gas produced by a system, the system comprising a gas turbine having a combustor configured to combust fuel with compressed air, a power turbine configured to be driven by combustion flue gas from the combustor, and an exhaust heat recovery device configured to receive the combustion flue gas from the power turbine and recover heat energy from the combustion flue gas, wherein the gas turbine comprises a primary air compressor and a secondary air compressor, the primary air compressor being configured to compress air to produce primary compressed air, the secondary air compressor being configured to compress the primary compressed air to produce secondary compressed air, wherein the compressed air includes the primary compressed air and the secondary compressed air, wherein the exhaust heat recovery device includes a heat exchanger configured to perform indirect heat exchange between the combustion flue gas and the secondary compressed air, and a saturator provided downstream, with respect to a flow of the combustion flue gas through the exhaust heat recovery device, from the heat exchanger and configured to perform indirect heat exchange between the combustion flue gas and the primary compressed air and supply water, the saturator being configured to permit steam to be entrained in the primary compressed air, wherein the saturator includes a supply water header configured to introduce the supply water into the saturator, a plurality of heat exchange tubes configured to communicate with the supply water header at a first end of the saturator and which are arranged within the saturator, a storage header configured to communicate with the plurality of heat exchange tubes at a second end of the saturator, the storage header having an introducing part configured to introduce the primary compressed air into a space in the storage header for storing the supply water, the saturator further including a supply water circulation line by which the supply water is circulated through the saturator, wherein the saturator is configured to pass the primary compressed air through spaces within the plurality of the heat exchange tubes through which the supply water circulates in the shape of a wet wall along inner wall surfaces of the plurality of heat exchange tubes, the saturator is further configured to perform heat exchange with the combustion flue gas flowing against outer peripheries of the plurality of heat exchange tubes to generate steam from the supply water, and the saturator being configured to permit the generated steam to be entrained in the primary compressed air flowing through the saturator, wherein the system is configured to first introduce the primary compressed air to the saturator in which the steam is entrained by the primary compressed air and compress the primary compressed air to produce the secondary compressed air in the secondary air compressor, then heat the secondary compressed air in the heat exchanger, and then introduce the heated secondary compressed air into the combustor, the method comprising: subjecting the combustion flue gas from the gas turbine to heat exchange with the secondary compressed air in the heat exchanger of the exhaust heat recovery device; recovering heat from the combustion flue gas via heat exchange between the combustion flue gas and the primary compressed air in the saturator after subjecting the combustion flue gas to heat exchange with the secondary compressed air in the heat exchanger; introducing the primary compressed air from the saturator into the secondary air compressor, thereby producing the secondary compressed air, then recovering heat from the combustion flue gas via heat exchange with the secondary compressed air in the heat exchanger, thereby heating the secondary compressed air; and introducing the heated secondary compressed air into the combustor to combust fuel.
2. A system comprising: a gas turbine having a combustor configured to combust fuel with compressed air and a power turbine configured to be driven by combustion flue gas from the combustor; and an exhaust heat recovery device configured to receive the combustion flue gas from the power turbine and recover heat energy from the combustion flue gas, wherein the gas turbine comprises a primary air compressor and a secondary air compressor, the primary air compressor configured to compress air to produce primary compressed air, the secondary air compressor configured to compress the primary compressed air to produce secondary compressed air, wherein the compressed air includes the primary compressed air and the secondary compressed air, wherein the exhaust heat recovery device includes: a heat exchanger configured to perform indirect heat exchange between the combustion flue gas and the secondary compressed air, and a saturator provided downstream, with respect to a flow of the combustion flue gas through the exhaust heat recovery device, from the heat exchanger and configured to perform indirect heat exchange between the combustion flue gas and the primary compressed air and supply water, the saturator being configured to permit steam to be entrained in the primary compressed air, wherein the saturator includes: a supply water header configured to introduce the supply water into the saturator, a plurality of heat exchange tubes configured to communicate with the supply water header at a first end of the saturator, the plurality of heat exchange tubes being arranged within the saturator, a storage header configured to communicate with the plurality of heat exchange tubes at a second end of the saturator, the storage header having an introducing part configured to introduce the primary compressed air into a space in the storage header for storing the supply water, and a supply water circulation line via which the supply water is circulated through the saturator, wherein the saturator is configured to pass the primary compressed air through spaces within the plurality of the heat exchange tubes through which the supply water circulates in the shape of a wet wall along inner wall surfaces of the plurality of heat exchange tubes, is configured to perform heat exchange with the combustion flue gas flowing against outer peripheries of the plurality of heat exchange tubes to generate steam from the supply water, and is configured to permit the generated steam to be entrained in the primary compressed air flowing through the saturator; and wherein the system is configured to first introduce the primary compressed air to the saturator in which the steam is entrained by the primary compressed air and compress the primary compressed air to produce the secondary compressed air in the secondary air compressor, then heat the secondary compressed air in the heat exchanger, and then introduce the heated secondary compressed air into the combustor.
3. The system according to claim 2, further comprising: a cooling tower configured to cool the combustion flue gas discharged from the exhaust heat recovery device; and a supply water supply line configured to supply condensed water as the supply water to the supply water circulation line.
4. The system according to claim 3, wherein the heat exchanger is a first heat exchanger and wherein the exhaust heat recovery device further includes an additional heat exchanger downstream, with respect to the flow of combustion flue gas through the exhaust heat recovery device, from the first heat exchanger and the saturator, the additional heat exchanger configured to perform indirect heat exchange between the combustion flue gas and the supply water in the supply water supply line.
5. The system according to claim 3, comprising: a CO.sub.2 recovery apparatus that recovers CO.sub.2 in the combustion flue gas from the cooling tower.
6. The system according to claim 5, wherein the CO.sub.2 recovery apparatus includes a CO.sub.2 absorption tower configured to absorb CO.sub.2 from the combustion flue gas with an absorbing liquid, and an absorbing liquid regeneration tower configured to regenerate the absorbing liquid which has absorbed CO.sub.2, wherein the absorbing liquid is circulated and reused.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DESCRIPTION OF EMBODIMENTS
(10) Preferable examples of the invention will be described below in detail with reference to the accompanying drawings. In addition, the invention is not limited by the examples and includes those configured by combining respective examples in a case where there are a plurality of examples.
Example 1
(11)
(12) As illustrated in
(13) In the present example, a third heat exchange unit 19C that performs heat exchange of the supply water 30, using the combustion flue gas 18B after being subjected to heat exchange in the second heat exchange unit 19B, is further provided on a downstream side of the second heat exchange unit 19B of the exhaust heat recovery device 19.
(14) Additionally, in the present example, a cooling line L.sub.10 including a cooling tower 41 that cools the flue gas 40 after heat exchange discharged from the exhaust heat recovery device 19, and a cooler 42 that circulates the cooling tower 41 with a pump P1, and a supply water supply line L.sub.11 along which condensed water 44 condensed within the cooling tower 41 is supplied as the supply water 30 to the saturator 31.
(15) In addition, in
(16) The gas turbine 17 includes the primary and secondary air compressors 21 and 22, the combustor 14, and the power turbine 16. The air 12a introduced from the outside is compressed in the primary and secondary air compressors 21 and 22, and the compressed air 12 made to have high temperature/high pressure is guided to the combustor 14 side. In the combustor 14, the high-temperature/high-pressure compressed air 12, and the fuel 13 are injected and combusted, and a high-temperature (for example, 1500 C.) combustion gas 15 is generated. The combustion gas 15 is injected into the power turbine 16, and the heat energy of the high-temperature high-pressure combustion gas 15 is converted into rotational energy in the power turbine 16. The coaxial primary/secondary air compressors 21 and 22 are driven with this rotational energy, and the power generator G is driven with the rotational energy remaining after being used to drive this compressor, and generates power.
(17) Next, the combustion flue gas 18 that has driven the power turbine 16 is guided to the exhaust heat recovery device 19 in order to recover the heat energy thereof.
(18) This exhaust heat recovery device 19 includes the first heat exchange unit 19A and the second heat exchange unit 19B. In the first heat exchange unit 19A, as illustrated in
(19)
(20) As illustrated in
(21)
(22) Referring to
(23) Referring to
(24) Then, as illustrated in
(25) Then, for example, as illustrated in
(26) Then, the wet wall-like water screen 30a that flows through the inside of the heat exchange tube 33 is indirectly heated by the heat of the combustion flue gas 18A from the outside, and the supply water 30 becomes the steam 38 by heat exchange, is entrained in the primary compressed air 12A, and becomes the primary compressed air (water steam) 12B. The second heat exchange unit 19B performs heat exchange using the combustion flue gas 18A that has contributed to the heat exchange in the first heat exchange unit 19A.
(27) Here, the primary compressed air (a pressure of 6 ata (0.6 MPa)) 12A introduced into the space 35 within the storage header 37 of the saturator 31 is cooled by the supply water 30 to be introduced, and the temperature thereof falls from 224 C. to 84 C. within the space 35.
(28) The primary compressed air 12A made to have this low temperature (84 C.) is indirectly subjected to heat exchange with the combustion flue gas 18A after the first heat exchange, in the saturator 31 of the second heat exchange unit 19B, and becomes the primary compressed air (water steam) 12B of which the temperature reaches 107 C. (a pressure of 6 ata).
(29) Next, the primary compressed air (water steam) 12B is introduced into the secondary air compressor 22, is subjected to second compression, and becomes the high-pressure (a pressure of 21 ata (2.1 MPa)) secondary compressed air (low temperature: 275 C.) 12C.
(30) The secondary compressed air 12C is low (275 C.) in temperature, is capable of being subjected to heat exchange with the high-temperature (for example, 617 C.) combustion flue gas 18 in the first heat exchange unit 19A of the exhaust heat recovery device 19, and becomes the high-pressure secondary compressed air (a high temperature of 565 C.) 12D.
(31) In the related art, in a case where one compressor is installed to perform compressing, the primary compressed air (a temperature of 224 C.) compressed by the primary air compressor is introduced into the same secondary air compressor as it is, and is introduced into the combustor as high-pressure (21 ata)/high-temperature (400 C.) compressed air.
(32) In contrast, in the present invention, a total amount of the low-pressure (a pressure of 6 ata) primary compressed air 12A, which has passed through the primary air compressor 21 is introduced into the second heat exchange unit 19B of the exhaust heat recovery device 19, is subjected to heat exchange with the combustion flue gas 18A after being subjected to heat exchange in the first heat exchange unit 19A, in the saturator 31.
(33) In this case, in the saturator 31, the supply water is introduced so as to lower (275 C..fwdarw.84 C.) the temperature of the low-pressure (a pressure of 6 ata) primary compressed air 12A, is subjected to heat exchange with the exhaust heat of the combustion flue gas (a temperature of 336 C.) 18A after being subjected to heat exchange in the first heat exchange unit 19A, and becomes the low-pressure primary compressed air (water steam) 12B of which the temperature has been raised (107 C.). The primary compressed air (water steam) (107 C.) 12B is further compressed by the secondary air compressor 22 next, and becomes the high-pressure (a pressure of 21 ata) secondary compressed air (low temperature: 275 C.) 12C. In the case of this secondary compression, the capacity of the compressor can be made small because the temperature falls unlike a case where compression is continuous as in the related art.
(34) Moreover, the high-pressure secondary compressed air (low temperature: 275 C.) 12C is introduced into the first heat exchange unit 19A of the exhaust heat recovery device 19, becomes the high-pressure secondary compressed air (high temperature: 565 C.) 12D, and is introduced into the combustor 14.
(35) In the present example, since the amount of the steam 38 to be entrained is small in the case of the heat exchange of the primary compressed air 12A in the second heat exchange unit 19B, it is possible to raise combustion temperature in the combustor 14 to a high temperature of, for example, 1500 C.
(36) Additionally, in the present example, the third heat exchange unit 19C is installed, and performs heat exchange so as to further improve the exhaust heat recovery efficiency of the combustion flue gas 18 when condensed water that has condensed moisture in the combustion flue gas 18C in the cooling tower 41 is supplied to the saturator 31 as the supply water 30. That is, since the temperature of the supply water 30 that is cooled and condensed in the cooling tower 41 is about 40 C., the supply water 30 at 40 C. is passed through the third heat exchange unit 19C, is subjected to heat exchange with the combustion flue gas (120 C.) 18B, and is supplied to the storage header 37 side as the supply water 30 at a temperature of 88 C.
(37) In this way, when exhaust heat is recovered by performing heat exchange of the combustion flue gas 18, in the exhaust heat recovery device 19 of the present example, efficient heat exchange is performed in the first heat exchange unit 19A, the second heat exchange unit 19B, and the third heat exchange unit 19C, respectively. Thus, the heat of the high-temperature (617 C.) combustion flue gas 18 is recovered to a low temperature (95 C.), and the heat recovery efficiency improves.
(38) Additionally, since the amount of the steam 38 entrained in the primary compressed air (water steam) 12B is small, exhaust loss becomes little.
(39)
(40) As illustrated in
(41) In contrast, the supply water 30 rises from 40 C. to 88 C. in the third heat exchange unit 19C, and rises from 84 C. to 107 C. because the temperature of the primary compressed air 12A falls in the saturator 31. Next, the secondary compressed air 12C rises from 275 C. to 565 C. in the first heat exchange unit 19A.
(42) Additionally, as shown in Table 1, gas turbine cycle efficiency reaches 66.76% (LHV base) depending on a relationship between input heat and exhaust loss. This made it possible to achieve a significant improvement of about 6.7% or more greater than 60% that is the gas turbine cycle efficiency of a related-art 1500 C. class.
(43) TABLE-US-00001 TABLE 1 1. Input of Heat Air: 2.158T/Hx(1500 565 C.) 0.285 = 575.05 10.sup.6 kcal/H Water: 378.0T/Hx(1500 565 C.) 0.556 = 196.51 10.sup.6 kcal/H Fuel:
(44) As described above, in a gas turbine combined cycle (GTCC) power generation plant including the related-art exhaust heat recovery steam generator using a high-pressure/medium-pressure/low-pressure boiler, the efficiency (LHV) thereof that is about 60% can be markedly raised.
(45) In the present example, when exhaust heat is recovered by performing heat exchange of the combustion flue gas 18, in the exhaust heat recovery device 19 of the present example, efficient heat exchange is performed in the first heat exchange unit 19A, the second heat exchange unit 19B, and the third heat exchange unit 19C, respectively. However, the third heat exchange unit 19C may be omitted as illustrated in the gas turbine cycle equipment 10B illustrated in
(46) In this case, heat of the high-temperature (617 C.) combustion flue gas 18 is recovered to a low temperature (120 C.). As a result, the heat recovery efficiency becomes slightly lower than that of the gas turbine cycle equipment 10A of
Example 2
(47) Next, equipment for recovering CO.sub.2 from flue gas related to Example 2 of the present invention will be described with reference to
(48) Generally, in a case where an amine-based absorbing liquid, for example, is used as the absorbing liquid 52, the CO.sub.2 recovery unit 51 makes the amine absorbing liquid to absorb and remove CO.sub.2 contained in the flue gas 40 within the CO.sub.2 absorption tower 53, and discharges the removed CO.sub.2 as a treated flue gas 55 from a top side of the CO.sub.2 absorption tower 53. Additionally, the absorbing liquid 52 that has absorbed CO.sub.2 is regenerated by steam stripping using a reboiler 59, in the absorbing liquid regeneration tower 54, and forms closed-system circulation lines L.sub.21 and L.sub.22 to be again reused in the CO.sub.2 absorption tower 53. In addition, within the CO.sub.2 absorption tower 53, the amine-based absorbing liquid is, for example, brought into opposed contact with the flue gas 40 so as to take CO.sub.2 into the amine absorbing liquid. Here, on the absorbing liquid regeneration tower 54 side, the gas 56 containing CO.sub.2 removed by the steam stripping is discharged, moisture is removed by a gas-liquid separator, and CO.sub.2 is recovered as gas.
(49) In the related art, in a case where CO.sub.2 in flue gas is recovered, a cooling tower is separately provided on a preceding stage side of the CO.sub.2 recovery unit so as to cool the flue gas. However, in Example 1, the flue gas 40 is cooled by the cooling tower 41 for obtaining the supply water 30. Thus, it becomes unnecessary to separately install cooling equipment in the equipment 50 for recovering CO.sub.2 from flue gas in the present example. Additionally, in ordinary gas turbines, CO.sub.2 concentration in flue gas is as low as 3.5 to 4.0 Vol. %. However, in the present gas turbine cycle, CO.sub.2 concentration in flue gas rises as high as 5 to 7 Vol. %. As a result, the amount of the flue gas can be reduced, and the CO.sub.2 recovery unit can be made compact.
(50) In addition, in the present example, a case including the CO.sub.2 absorption tower 53 that absorbs CO.sub.2 in the flue gas 40 with the absorbing liquid 52, and the absorbing liquid regeneration tower 54 that regenerates the absorbing liquid 52 that has absorbed CO.sub.2 has been described as the CO.sub.2 recovery unit 51. However, the present invention is not limited to this. Arbitrary equipment may be used as long as the equipment can recover CO.sub.2 in flue gas.
REFERENCE SIGNS LIST
(51) 10A, 10B: GAS TURBINE CYCLE EQUIPMENT 12a: AIR 12: COMPRESSED AIR 12A: PRIMARY COMPRESSED AIR 12B: PRIMARY COMPRESSED AIR (WATER STEAM) 12C: SECONDARY COMPRESSED AIR (LOW TEMPERATURE) 12D: SECONDARY COMPRESSED AIR (HIGH TEMPERATURE) 13: FUEL 14: COMBUSTOR 15: COMBUSTION GAS 16: POWER TURBINE 17: GAS TURBINE 18, 18A to 18C: COMBUSTION FLUE GAS 19: EXHAUST HEAT RECOVERY DEVICE 19A: FIRST HEAT EXCHANGE UNIT 19B: SECOND HEAT EXCHANGE UNIT 19C: THIRD HEAT EXCHANGE UNIT 21: PRIMARY AIR COMPRESSOR 22: SECONDARY AIR COMPRESSOR 31: SATURATOR 32: SUPPLY WATER HEADER 33: HEAT EXCHANGE TUBE 34: STORAGE PART 35: SPACE 37: STORAGE HEADER 38: STEAM 40: FLUE GAS 50: EQUIPMENT FOR RECOVERING CO.sub.2 FROM FLUE GAS 51: CO.sub.2 RECOVERY UNIT