METHOD OF FORMING A SOLDERABLE SOLDER DEPOSIT ON A CONTACT PAD

Abstract

A method of forming a solderable solder deposit on a contact pad, comprising the steps of providing an organic, non-conductive substrate which exposes said contact pad under an opening of a first non-conductive resist layer, depositing a conductive layer inside and outside the opening such that an activated surface results, thereby forming an activated opening, electrolytically depositing nickel or nickel alloy into the activated opening such that nickel/nickel alloy is deposited onto the activated surface, electrolytically depositing tin or tin alloy onto the nickel/nickel alloy, with the proviso that the electrolytic deposition of later steps results in an entirely filled activated opening, wherein the entirely filled activated opening is completely filled with said nickel/nickel alloy, or in the entirely filled activated opening the total volume of nickel/nickel alloy is higher than the total volume of tin and tin alloy, based on the total volume of the entirely filled activated opening.

Claims

1. A method of forming a solderable solder deposit on a contact pad (B), comprising the steps of (i) providing or manufacturing an organic, non-conductive substrate (A) which exposes said contact pad under an opening (F) of a first non-conductive resist layer (C), (ii) depositing a conductive layer (G) inside (G) and outside (G) the opening such that an activated surface results, thereby forming an activated opening (F), (iii) electrolytically depositing nickel (D) or a nickel alloy (D) into the activated opening such that nickel/nickel alloy is deposited onto the activated surface, (iv) electrolytically depositing tin (E) or a tin alloy (E) onto the nickel/nickel alloy deposited in step (iii), with the proviso that the electrolytic deposition of steps (iii) or (iv) results in an entirely filled activated opening, wherein the entirely filled activated opening is completely filled with said nickel/nickel alloy, or in the entirely filled activated opening the total volume of nickel/nickel alloy is higher than the total volume of tin and tin alloy, based on the total volume of the entirely filled activated opening.

2. The method of claim 1, wherein the organic, non-conductive substrate is a circuit board.

3. The method of claim 1, wherein the first non-conductive resist layer exhibiting the opening has a layer thickness of 200 m or less.

4. The method of claim 1, wherein the maximum width of the opening in step (i) is 1000 m or less.

5. The method of claim 1, wherein the conductive layer has a layer thickness in the range of 200 nm to 2500 nm.

6. The method of claim 1, wherein in step (iii) nickel/nickel alloy is non-conformally deposited into the activated opening such that non-conformal nickel/nickel alloy is deposited onto the activated surface.

7. The method of claim 1, wherein the nickel/nickel alloy in step (iii) is deposited through a nickel plating bath comprising nickel ions in a total amount from 1 g/L to 160 g/L, based on the total volume of the nickel plating bath.

8. The method of claim 7, wherein the nickel plating bath further comprises one or more than one leveler compound.

9. The method of claim 1, wherein step (iv) is carried out directly after step (iii).

10. The method of claim 1, wherein in step (iv) the tin and tin alloy, respectively, is conformally deposited onto the nickel/nickel alloy deposited in step (iii).

11. The method of claim 1, wherein the tin and tin alloy is electrolytically deposited through a deposition bath not containing a leveling compound.

12. The method of claim 1 of forming a solderable solder deposit on a contact pad, comprising the steps of (i) providing or manufacturing an organic, non-conductive substrate which exposes said contact pad under an opening of a permanent first non-conductive resist layer, (ii) depositing a conductive layer inside and outside the opening such that an activated surface results, thereby forming an activated opening, (iia) forming outside the activated opening a second non-conductive resist layer, which is patterned, onto the activated surface such that an extended activated opening results, (iii) electrolytically, non-conformally depositing nickel or a nickel alloy into the extended activated opening such that non-conformal nickel/nickel alloy is deposited onto the activated surface, (iv) electrolytically, conformally depositing tin or a tin alloy onto the non-conformal nickel/nickel alloy deposited in step (iii), with the proviso that the electrolytic deposition of step (iii) results in an entirely filled activated opening being completely filled with said nickel/nickel alloy, and said nickel/nickel alloy is additionally deposited onto the activated surface outside the activated opening.

13. The method of claim 1, wherein after step (iv) no gold is deposited onto the tin or tin alloy.

14. A printed circuit board exposing on an activated contact pad a solderable solder deposit, the deposit being partly embedded within a permanent solder mask and having a consecutive sequence of layers starting from the activated copper pad (a) a nickel or nickel alloy layer, (b) a tin or tin alloy layer onto the nickel/nickel alloy layer, wherein in the portion of the solder deposit, which is embedded in the permanent solder mask, the total volume of nickel/nickel alloy is higher than the total volume of tin and tin alloy.

15. The printed circuit board of claim 14, wherein the nickel/nickel alloy in the nickel/nickel alloy layer is non-conformal nickel/nickel alloy.

16. The method of claim 7, wherein the nickel plating bath further comprises one or more than one leveler compound, selected from the group of leveler compounds consisting of compounds of Formulae (I) and (II) ##STR00004## wherein R.sup.1 independently is hydrogen, substituted or unsubstituted alkyl, or substituted or unsubstituted alkenyl, R.sup.2 independently is (CH.sub.2).sub.nSO.sub.3.sup., wherein n is 1, 2, 3, 4, 5, or 6, or (CH.sub.2).sub.nSO.sub.3.sup., wherein n is 1, 2, 3, 4, 5, or 6, and one or more than one hydrogen atom in (CH.sub.2).sub.nSO.sub.3.sup. is substituted by a substituent.

17. The method of claim 7, wherein the nickel plating bath further comprises one or more than one leveler compound, selected from the group of leveler compounds consisting of compounds of Formulae (Ia) and (IIa) ##STR00005## wherein R.sup.1 independently is in Formula (Ia) methyl, ethyl, linear or branched propyl, or linear or branched butyl, in Formula (IIa) (CH.sub.2).sub.mCHCH.sub.2, wherein m is 0, 1, 2, 3, or 4, and R.sup.2 independently is (CH.sub.2).sub.nSO.sub.3.sup., wherein n is 1, 2, 3, or 4.

18. The method of claim 7, wherein the nickel plating bath further comprises one or more than one leveler compound selected from the group of leveler compounds consisting of compounds of Formulae (Ib) and (IIb) ##STR00006##

Description

EXAMPLE

[0197] In a first step an organic, non-conductive substrate exposing several copper pads under respective circular openings of a permanent solder mask (permanent first non-conductive resist layer) was provided (as exemplarily shown in FIG. 1a). Each opening had a maximum opening diameter of approximately 40 m. The solder mask layer thickness was approximately 20 m.

[0198] In a second step a conductive copper layer with a layer thickness of approximately 500 nm (Printoganth TP1, Atotech) was electrolessly deposited onto the entire organic, non-conductive substrate such that inside and outside the openings a solder mask with an activated surface resulted. This included that the conductive copper layer was also deposited on each copper pad under the openings (as exemplarily shown in FIG. 1b). As a result, activated openings resulted, exhibiting electrical connectivity for subsequent electrolytic nickel deposition.

[0199] In a third step a temporary photo-imageable resist layer as second non-conductive resist layer (typically supplied by Hitachi or Dow) with a layer thickness of approximately 25 m was formed onto the activated surface of the solder mask and was subsequently patterned such that extended activated openings resulted (as exemplarily shown in FIG. 1c).

[0200] In a fourth step the surface of the no-conductive substrate obtained after the third step was cleaned in a 35 C., acidic cleaning solution (Cupra Pro S8, Atotech) for 5 minutes.

[0201] In a fifth step pure nickel was electrolytically deposited into the extended activated openings such that nickel was deposited onto the activated surface inside and outside the activated openings (as exemplarily shown in FIG. 1d). Nickel deposition was carried out in an aqueous nickel plating bath for 20 minutes at a temperature of approximately 20 C. utilizing direct current with a current density of 3 A/dm.sup.2. The nickel plating bath (base plating bath: Spherolyte, Atotech) contained nickel ions in a total amount of 30 g/L to 60 g/L, boric acid, and at least one leveler compound selected from the group of compounds of Formulae (Ia) and (IIa) in a total amount in the range of 10 mg/L to 1000 mg/L. The activated openings were completely filled with nickel and nickel was also significantly deposited onto the conductive layer outside the activated opening, wherein the thickness of deposited nickel onto the conductive layer outside the activated opening is less than the thickness of deposited nickel inside the activated opening. Eventually, an even and leveled surface of the nickel deposit was obtained, which means that nickel was non-conformally deposited.

[0202] In a sixth step pure tin was electrolytically deposited onto the electrolytically deposited nickel utilizing a tin deposition bath comprising approximately 25 g/L tin ions and 100 to 140 g/L of an organic acid (as exemplarily shown in FIG. 1e). Tin deposition was carried out for 20 minutes at a temperature of approximately 25 C. utilizing direct current with a current density of 2 A/dm.sup.2.

[0203] In a seventh step the temporary, patterned photo-imageable resist layer was removed (stripped) by utilizing a first stripping solution (ResistStrip IC, Atotech; as exemplarily shown in FIG. 1f).

[0204] In an eighth step copper of the copper conductive layer exposed after stripping the temporary, patterned photo-imageable resist layer was also removed (stripped) by utilizing a second stripping solution (EcoFlash, Atotech; also exemplarily shown in also FIG. 1f).

[0205] Thus, a printed circuit board with solderable solder deposits in openings exhibiting a maximum diameter of approximately 40 m was obtained, wherein the portion of the solder deposit, which is embedded in the permanent solder mask, is completely nickel.

[0206] In a subsequent test, the solderable solder deposits were melted at 245 C. According to this test the total amount of copper in the melted solder deposit was below 0.1 weight percent, despite a layer thickness of the conductive layer of approximately 500 nm.

[0207] Additionally, upon forming interconnections with test chips, dimensional stability was increased also compared to comparative examples based on WO 2010/046235 A1. An increased dimensional stability was already observed after the melting at 245 C. Upon melting, the solder deposit maintained its shape and dimensions more than melting solder deposits obtained according to WO'235.

[0208] Furthermore, internal stiffness was significantly higher compared to comparative examples based on WO 2010/046235 A1.