ORGANIC COMPOUND, AND ELECTRONIC ELEMENT AND ELECTRONIC DEVICE USING SAME

Abstract

The present disclosure relates to an organic compound. The structure of the organic compound consists of a structure represented by formula (I) and a structure represented by formula (II); the structure represented by formula (I) is fused with the structure represented by formula (II); and * represents a connection point, in formula (I), capable of being fused with formula (II). When being used to the organic light-emitting layer of an organic electroluminescent device, the organic compound of the present application can effectively improve the device efficiency of the device and prolong the service life of the organic electroluminescent device.

##STR00001##

Claims

1. An organic compound, having a structure consisting of a structure represented by a formula I and a structure represented by a formula II: ##STR00506## wherein the structure represented by the formula I is fused with at least one structure represented by the formula II; * represents a site where the formula I is fused with the formula II; a ring A is selected from a benzene ring or a fused aromatic ring with 10 to 14 ring-forming carbon atoms; n.sub.1 represents the number of R.sub.1, n.sub.2 represents the number of R.sub.2, and n.sub.3 represents the number of R.sub.3; R.sub.1, R.sub.2 and R.sub.3 are represented by R.sub.k, n.sub.1 to n.sub.3 are represented by n.sub.k, and k is a variable and represents 1, 2 or 3; in response to determining that k is 1, n.sub.k is selected from 0, 1, 2, 3 or 4; in response to determining that k is 2, n.sub.k is selected from 0, 1 or 2; in response to determining that k is 3, n.sub.k is selected from 0, 1, 2, 3, 4, 5, 6, 7 or 8; and in response to determining that n.sub.k is greater than 1, any two n.sub.k are the same or different; and optionally, any two adjacent R.sub.k are connected to each other to form a ring, and the formed ring is optionally substituted with R′; R.sub.1, R.sub.2, R.sub.3, and R′ are the same or different, and are each independently selected from an alkyl with 1 to 5 carbon atoms or a structure represented by a formula III:
—(L).sub.m—Ar m represents the number of L, and m is selected from 0, 1, 2 or 3; and in response to determining that m is 2 or 3, any two L are the same or different; Ar is selected from a substituted or unsubstituted aryl with 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl with 3 to 30 carbon atoms; L is selected from a single bond, a substituted or unsubstituted arylene with 6 to 30 carbon atoms, or a substituted or unsubstituted heteroarylene with 3 to 30 carbon atoms; substituents in L and Ar are one or more, wherein the substituents in L and Ar are each independently selected from deuterium, a halogen group, cyano, a heteroaryl with 3 to 12 carbon atoms, an aryl with 6 to 12 carbon atoms, an alkyl with 1 to 5 carbon atoms, or trimethylsilyl; and X and Y are the same or different, and are each independently selected from a single bond, O, S, C(R.sub.4R.sub.5), and Si(R.sub.6R.sub.7), and X and Y are not simultaneously a single bond; wherein R.sub.4 to R.sub.7 are the same or different, and are each independently selected from an alkyl with 1 to 5 carbon atoms, an unsubstituted aryl with 6 to 20 carbon atoms, or an unsubstituted heteroaryl with 3 to 20 carbon atoms; optionally, R.sub.4 and R.sub.5 are connected to each other to form a 3- to 15-membered saturated or unsaturated ring together with the atoms to which they are commonly connected; and optionally, R.sub.6 and R.sub.7 are connected to each other to form a 3- to 15-membered saturated or unsaturated ring together with the atoms to which they are commonly connected.

2. The organic compound according to claim 1, wherein the organic compound has a structure shown in any one of formulae 1-1 to 1-17: ##STR00507## ##STR00508## ##STR00509## ##STR00510## wherein n′.sub.1 is selected from 0, 1 or 2; and n′.sub.2 is selected from 0, 1 or 2.

3. The organic compound according to claim 1, wherein the organic compound has a structure shown in any one of 2-1 to 2-41: ##STR00511## ##STR00512## ##STR00513## ##STR00514## ##STR00515## ##STR00516## ##STR00517## ##STR00518## ##STR00519## wherein n′.sub.2 is selected from 0, 1 or 2.

4. The organic compound according to claim 1, wherein the formula II has a structure shown in any one of formulae II-1 to II-11: ##STR00520## ##STR00521##

5. The organic compound according to claim 1, wherein the ring A is selected from a benzene ring, a naphthalene ring, an anthracene ring, or a phenanthrene ring.

6. (canceled)

7. The organic compound according to claim 1, wherein L is selected from a single bond, a substituted or unsubstituted arylene with 6 to 15 carbon atoms, or a substituted or unsubstituted heteroarylene with 3 to 20 carbon atoms.

8. The organic compound according to claim 1, wherein L is selected from a single bond or a substituted or unsubstituted group T.sub.1, wherein the unsubstituted group T.sub.1 is selected from the group consisting of: ##STR00522## ##STR00523## ##STR00524## ##STR00525## ##STR00526## the substituted group T.sub.1 has one or two or more substituents, and the substituents in substituted group T.sub.1 are independently selected from deuterium, fluorine, cyano, trimethylsilyl, triphenylsilyl, methyl, ethyl, isopropyl, tent-butyl, phenyl, biphenyl, pyridyl, naphthyl, carbazolyl, dibenzofuranyl or dibenzothienyl.

9. The organic compound according to claim 1, wherein L is selected from a single bond or the group consisting of: ##STR00527## ##STR00528## ##STR00529## ##STR00530## ##STR00531## ##STR00532## ##STR00533## ##STR00534## ##STR00535## ##STR00536## ##STR00537## ##STR00538##

10. (canceled)

11. The organic compound according to claim 1, wherein Ar is selected from a substituted or unsubstituted aryl with 6 to 25 carbon atoms or a substituted or unsubstituted heteroaryl with 3 to 20 carbon atoms.

12. The organic compound according to claim 1, wherein Ar is selected from a substituted or unsubstituted group T.sub.2, wherein the unsubstituted group T.sub.2 is selected from the group consisting of: ##STR00539## ##STR00540## ##STR00541## the substituted group T.sub.2 has one or two or more sub stituents, and the sub stituents in the substituted group T.sub.2 are independently selected from deuterium, fluorine, cyano, methyl, ethyl, isopropyl, tert-butyl, phenyl, biphenyl, pyridyl, naphthyl, carbazolyl, cyclohexyl, dibenzofuranyl or dibenzothienyl.

13. The organic compound according to claim 1, wherein Ar is selected from the following groups: ##STR00542## ##STR00543## ##STR00544## ##STR00545## ##STR00546## ##STR00547##

14. (canceled)

15. (canceled)

16. The organic compound according to claim 1, wherein the organic compound is selected from the group consisting of the following compounds: ##STR00548## ##STR00549## ##STR00550## ##STR00551## ##STR00552## ##STR00553## ##STR00554## ##STR00555## ##STR00556## ##STR00557## ##STR00558## ##STR00559## ##STR00560## ##STR00561## ##STR00562## ##STR00563## ##STR00564## ##STR00565## ##STR00566## ##STR00567## ##STR00568## ##STR00569## ##STR00570## ##STR00571## ##STR00572## ##STR00573## ##STR00574## ##STR00575## ##STR00576## ##STR00577## ##STR00578## ##STR00579## ##STR00580## ##STR00581## ##STR00582## ##STR00583## ##STR00584## ##STR00585## ##STR00586## ##STR00587## ##STR00588## ##STR00589## ##STR00590## ##STR00591## ##STR00592## ##STR00593## ##STR00594## ##STR00595## ##STR00596## ##STR00597## ##STR00598## ##STR00599## ##STR00600## ##STR00601## ##STR00602## ##STR00603## ##STR00604## ##STR00605## ##STR00606## ##STR00607## ##STR00608## ##STR00609## ##STR00610## ##STR00611## ##STR00612## ##STR00613## ##STR00614## ##STR00615## ##STR00616## ##STR00617## ##STR00618## ##STR00619## ##STR00620## ##STR00621## ##STR00622## ##STR00623## ##STR00624## ##STR00625## ##STR00626##

17. An electronic element, comprising an anode and a cathode which are oppositely disposed, and a functional layer disposed between the anode and the cathode; and the functional layer comprises the organic compound according to claim 1.

18. The electronic element according to claim 17, wherein the functional layer comprises an organic light-emitting layer, and the organic light-emitting layer comprises the organic compound.

19. The electronic element according to claim 17, wherein the electronic element is an organic electroluminescent device.

20. An electronic device, comprising the electronic element according to claim 17.

21. The electronic element according to claim 19, wherein the organic electroluminescent device is a green device or a red device

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0023] The accompanying drawings are used to provide a further understanding of the present disclosure, and constitute a part of this description, and together with the following specific examples, are used to explain the present disclosure, but do not constitute a limitation to the present disclosure.

[0024] FIG. 1 is a structural schematic diagram of an organic electroluminescent device according to one example of the present disclosure.

[0025] FIG. 2 is a structural schematic diagram of an electronic device according to one example of the present disclosure.

DESCRIPTION OF REFERENCE SIGNS

[0026] 100, anode; 200, cathode; 300, functional layer; 310, hole injection layer; 320, hole transport layer; 321, first hole transport layer; 322, second hole transport layer; 330, organic light-emitting layer; 340, electron transport layer; 350, electron injection layer; and 400, electronic device.

DETAILED DESCRIPTION

[0027] Specific examples of the present disclosure will be described in detail below. It should be understood that the specific examples described here are only used to illustrate and explain the present disclosure, but are not intended to limit the present disclosure.

[0028] In a first aspect, the present disclosure provides an organic compound, having a structure consisting of a structure represented by a formula I and a structure represented by a formula II:

##STR00005##

[0029] where the structure represented by the formula I is fused with at least one structure represented by the formula II;

[0030] * represents a site where the formula I is fused with the formula II;

[0031] a ring A is selected from a benzene ring or a fused aromatic ring with 10 to 14 ring-forming carbon atoms;

[0032] n.sub.1 represents the number of R.sub.1, n.sub.2 represents the number of R.sub.2, and n.sub.3 represents the number of R.sub.3;

[0033] R.sub.1, R.sub.2 and R.sub.3 are represented by R.sub.k, n.sub.1 to n.sub.3 are represented by n.sub.k, and k is a variable and represents 1, 2 or 3; when k is 1, n.sub.k is selected from 0, 1, 2, 3 or 4; when k is 2, n.sub.k is selected from 0, 1 or 2; when k is 3, n.sub.k is selected from 0, 1, 2, 3, 4, 5, 6, 7 or 8; and when n.sub.k is greater than 1, any two n.sub.k are the same or different; and optionally, any two adjacent R.sub.k are connected to each other to form a ring, and the formed ring is optionally substituted with R′;

[0034] R.sub.1, R.sub.2, R.sub.3, and R′ are the same or different, and are each independently selected from an alkyl with 1 to 5 carbon atoms or a structure represented by a formula III:

##STR00006##

##STR00007##

[0035] represents a chemical bond;

[0036] m represents the number of L, and m is selected from 1, 2 or 3; and when m is 2 or 3, any two L are the same or different;

[0037] Ar is selected from a substituted or unsubstituted aryl with 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl with 3 to 30 carbon atoms, a triarylsilyl with 18 to 30 carbon atoms, a triarylphosphinyloxy with 12 to 20 carbon atoms, or a cycloalkyl with 3 to 10 carbon atoms;

[0038] L is selected from a single bond, a substituted or unsubstituted arylene with 6 to 30 carbon atoms, or a substituted or unsubstituted heteroarylene with 3 to 30 carbon atoms;

[0039] sub stituents in L and Ar are one or more (when L and Ar include substituents), and the substituents in L and Ar are each independently selected from deuterium, a halogen group, cyano, a heteroaryl with 3 to 12 carbon atoms, an aryl with 6 to 12 carbon atoms, an alkyl with 1 to 5 carbon atoms, a cycloalkyl with 3 to 10 carbon atoms, trimethylsilyl, or triphenylsilyl; and

[0040] X and Y are the same or different, and are each independently selected from a single bond, O, S, C(R.sub.4R.sub.5), and Si(R.sub.6R.sub.7), and X and Y are not simultaneously a single bond; R.sub.4 to R.sub.7 are the same or different, and are each independently selected from an alkyl with 1 to 5 carbon atoms, an aryl with 6 to 30 carbon atoms, or a heteroaryl with 2 to 30 carbon atoms; optionally, R.sub.4 and R.sub.5 are connected to each other to form a 3- to 15-membered saturated or unsaturated ring together with the atoms to which they are commonly connected; and optionally, R.sub.6 and R.sub.7 are connected to each other to form a 3- to 15-membered saturated or unsaturated ring together with the atoms to which they are commonly connected.

[0041] In the present disclosure, R.sub.1, R.sub.2, R.sub.3, and R′ may also each independently be selected from deuterium, a halogen group, and cyano.

[0042] In the present disclosure “* represents a site where the formula I is fused with the formula II”, which means that the formula II is connected to any two adjacent fused positions of eight fused sites of the formula I.

[0043] Optionally, the structure represented by the formula I is fused with one structure represented by the formula II.

[0044] Optionally, the structure represented by the formula I is fused with two structures represented by the formula II.

[0045] Optionally, the structure represented by the formula I is fused with three structures represented by the formula II.

[0046] In the present disclosure, “

##STR00008##

” means that m L are linked together in sequence, and are linked to Ar, specifically, when m is 1,

##STR00009##

represents

##STR00010##

when m is 2,

##STR00011##

represents

##STR00012##

; when m is 3,

##STR00013##

represents

##STR00014##

and when m is 2 or 3, each L may be the same or different.

[0047] In the present disclosure, the terms “optional” and “optionally” mean that the subsequently described event or circumstance can but need not occur, and that the description includes occasions where the event or circumstance occurs or does not occur. For example, “optionally, two adjacent substituents xx form a ring”, which means that the two substituents can, but need not, form a ring, including a scenario in which two adjacent substituents form a ring and a scenario in which two adjacent substituents do not form a ring. For another example, “optionally, R.sub.4 and R.sub.5 are connected to each other to form a 3- to 15-membered saturated or unsaturated ring together with the atoms to which they are commonly connected”, which means that R.sub.4 and R.sub.5 may be connected to each other to form a 3- to 15-membered saturated or unsaturated ring together with the atoms to which they are commonly connected, or R.sub.4 and R.sub.5 may also each independently be present.

[0048] In the present disclosure, if a group is not specifically indicated to be substituted, it indicates that the group is unsubstituted.

[0049] In the present disclosure, the used descriptions modes “each . . . is independently”, “ . . . is respectively and independently” and “ . . . is independently selected from” can be interchanged, which should be understood in a broad sense, and may mean that specific options expressed by a same symbol in different groups do not influence each other, or may also mean that specific options expressed by a same symbol in a same group do not influence each other. For example, the meaning of “

##STR00015##

where each q is independently 0, 1, 2 or 3 and each R″ is independently selected from hydrogen, deuterium, fluorine, and chlorine” is as follows: a formula Q-1 represents that a benzene ring has q substituents R″, each R″ can be the same or different, and options of each R″ do not influence each other; and a formula Q-2 represents that each benzene ring of biphenyl has q substituents R″, the number q of the sub stituents R″ on the two benzene rings can be the same or different, each R″ can be the same or different, and options of each R″ do not influence each other.

[0050] In the present disclosure, the term “substituted or unsubstituted” means that a functional group described behind the term may or may not have substituents (the substituents are collectively referred to as Rc below for ease of description). For example, “substituted or unsubstituted aryl” refers to aryl with a substituent Rc or unsubstituted aryl. The above substituent, i.e. Rc, can be, for example, deuterium, a halogen group, cyano, heteroaryl, aryl, trimethylsilyl, triphenylsilyl, alkyl or cycloalkyl.

[0051] In the present disclosure, in the expression that “any two adjacent substituents form a ring”, “any adjacent” can include the condition that there are two substituents on a same atom and can also include the condition that two adjacent atoms each have one substituent; when there are two sub stituents on the same atom, the two sub stituents may form a saturated or unsaturated ring (e.g., a 3- to 18-membered saturated or unsaturated ring) with the atom to which they are commonly connected; when two adjacent atoms each have one substituent, the two substituents may be fused to form a ring, e.g., a naphthalene ring, a phenanthrene ring, or an anthracene ring. For example, “any two adjacent R.sub.1 form a ring”, which includes the condition that any two adjacent R.sub.1 are connected to each other to form a ring with the atoms to which they are commonly connected, or the condition that any two adjacent R.sub.2 are connected to each other to form a ring with the atoms to which they are commonly connected, or the condition that any two adjacent R.sub.3 are connected to each other to form a ring with the atoms to which they are commonly connected. For example: any two adjacent R.sub.1 may form a ring having 6 to 15 carbon atoms, or a ring having 6 to 10 carbon atoms; the ring may be saturated (e.g., a five-membered ring

##STR00016##

a six-membered ring

##STR00017##

etc.) or unsaturated, (for example, an aromatic ring, and specific examples of the aromatic ring include a benzene ring

##STR00018##

a naphthalene ring

##STR00019##

a phenanthrene ring

##STR00020##

etc.).

[0052] In the present disclosure, the number of carbon atoms of a substituted or unsubstituted functional group refers to the number of all carbon atoms. For example, if Ar is a substituted aryl with 12 carbon atoms, then the number of all carbon atoms of the aryl and substituents on the aryl is 12.

[0053] In the present disclosure, aryl refers to an optional functional group or substituent derived from an aromatic carbocyclic ring. The aryl can be monocyclic aryl (e.g., phenyl) or polycyclic aryl, in other words, the aryl can be monocyclic aryl, fused aryl, two or more monocyclic aryl conjugatedly linked by carbon-carbon bonds, monocyclic aryl and fused aryl which are conjugatedly linked by a carbon-carbon bond, and two or more fused aryl conjugatedly linked by carbon-carbon bonds. That is, unless specified otherwise, two or more aromatic groups conjugatedly linked by carbon-carbon bonds can also be regarded as aryl of the present disclosure. The fused aryl may, for example, include bicyclic fused aryl (e.g., naphthyl), tricyclic fused aryl (e.g., phenanthryl, fluorenyl, and anthryl), and the like. The aryl does not contain heteroatoms such as B, N, O, S, P, Se, and Si. For example, in the present disclosure, biphenyl, terphenyl, and the like are aryl. Examples of the aryl can include, but are not limited to, phenyl, naphthyl, fluorenyl, anthryl, phenanthryl, biphenyl, terphenyl, quaterphenyl, quinquephenyl, benzo[9,10]phenanthryl, pyrenyl, benzofluoranthenyl, chrysenyl, and the like. In the present disclosure, involved arylene refers to a divalent group formed by further loss of one hydrogen atom of the aryl.

[0054] In the present disclosure, substituted aryl can be that one or two or more hydrogen atoms in the aryl are substituted with groups such as a deuterium atom, a halogen group, —CN, aryl, heteroaryl, trialkylsilyl, alkyl, cycloalkyl, and the like. Specific examples of heteroaryl-substituted aryl include, but are not limited to, dibenzofuranyl-substituted phenyl, dibenzothiophenyl-substituted phenyl, pyridinyl-substituted phenyl, and the like. It should be understood that the number of carbon atoms of the substituted aryl refers to the total number of carbon atoms of the aryl and substituents on the aryl, for example, substituted aryl with 18 carbon atoms means that the total number of carbon atoms of the aryl and substituents is 18.

[0055] In the present disclosure, examples of aryl as a substituent include, but are not limited to, phenyl, biphenyl, naphthyl, 9,9-dimethylfluorenyl, anthryl, phenanthryl, and chrysenyl.

[0056] In the present disclosure, heteroaryl refers to a monovalent aromatic ring containing at least one heteroatom in the ring or its derivative, and the heteroatom can be at least one of B, O, N, P, Si, Se, and S. The heteroaryl may be monocyclic heteroaryl or polycyclic heteroaryl, in other words, the heteroaryl may be a single aromatic ring system or a plurality of aromatic ring systems conjugatedly connected via carbon-carbon bonds, and any one aromatic ring system is one aromatic monocyclic ring or one aromatic fused ring. For example, the heteroaryl may include thienyl, furyl, pyrrolyl, imidazolyl, thiazolyl, oxazolyl, oxadiazolyl, triazolyl, pyridyl, bipyridyl, pyrimidinyl, triazinyl, acridinyl, pyridazinyl, pyrazinyl, quinolyl, quinazolinyl, quinoxalinyl, phenoxazinyl, phthalazinyl, pyridopyrimidinyl, pyridopyrazinyl, pyrazinopyrazinyl, isoquinolyl, indolyl, carbazolyl, benzoxazolyl, benzimidazolyl, benzothiazolyl, benzocarbazolyl, benzothienyl, dibenzothienyl, thienothienyl, benzofuranyl, phenanthrolinyl, isoxazolyl, thiadiazolyl, benzothiazolyl, phenothiazinyl, silafluorenyl, dibenzofuranyl, as well as N-phenylcarbazolyl, N-pyridylcarbazolyl, N-methylcarbazolyl and the like, but is not limited to this. Thienyl, furyl, phenanthrolinyl, etc. are heteroaryl of the single aromatic ring system, and N-arylcarbazolyl, and N-heteroarylcarbazolyl are heteroaryl of the plurality of aromatic ring systems conjugatedly connected via carbon-carbon bonds. In the present disclosure, involved heteroarylene refers to a divalent group formed by further loss of one hydrogen atom of the heteroaryl.

[0057] In the present disclosure, substituted heteroaryl can be that one or two or more hydrogen atoms in the heteroaryl are substituted with groups such as a deuterium atom, a halogen group, —CN, aryl, heteroaryl, trialkylsilyl, alkyl, cycloalkyl, and the like. Specific examples of aryl-substituted heteroaryl include, but are not limited to, phenyl-substituted dibenzofuranyl, phenyl-substituted dibenzothienyl, phenyl-substituted pyridyl, and the like. It should be understood that the number of carbon atoms of the substituted heteroaryl refers to the total number of carbon atoms of the heteroaryl and substituents on the heteroaryl.

[0058] In the present disclosure, heteroaryl as a substituent includes, for example, but is not limited to, pyridyl, pyrimidinyl, carbazolyl, dibenzofuranyl, dibenzothienyl, quinolyl, quinazolinyl, quinoxalinyl, and isoquinolyl.

[0059] In the present disclosure, an unpositioned connecting bond refers to a single bond “

##STR00021##

” extending from a ring system, which indicates that one end of the connecting bond can be connected to any position in the ring system through which the bond penetrates, and the other end of the connecting bond is connected to the remaining part of a compound molecule.

[0060] For example, as shown in a formula (f) below, naphthyl represented by the formula (f) is connected to other positions of a molecule by two unpositioned connecting bonds penetrating a bicyclic ring, and its meaning includes any one possible connection mode represented by formulae (f-1) to (f-10).

##STR00022## ##STR00023##

[0061] For another example, as shown in a formula (X′) below, phenanthryl represented by the formula (X′) is connected to other positions of a molecule via one unpositioned connecting bond extending from the middle of a benzene ring on one side, and its meaning includes any one possible connection mode represented by formulae (X′-1) to (X′-4).

##STR00024##

[0062] An unpositioned substituent in the present disclosure refers to a substituent connected through a single bond extending from the center of a ring system, which means that the substituent can be connected to any possible position in the ring system. For example, as shown in a formula (Y) below, a substituent R′ as shown in the formula (Y) is connected to a quinoline ring via one unpositioned connecting bond, and its meaning includes any one possible connection mode represented by formulae (Y-1) to (Y-7).

##STR00025##

[0063] In the present disclosure, the number of carbon atoms of alkyl may be 1 to 5, and the alkyl may include linear alkyl with 1 to 5 carbon atoms and branched alkyl with 3 to 5 carbon atoms. The number of carbon atoms may be any integer of 1, 2, 3, 4, or 5; and specific examples of the alkyl can include, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentyl, isopentyl, neopentyl, and the like.

[0064] In the present disclosure, the number of carbon atoms of cycloalkyl can be, for example, 3, 5, 6, 7, 8, 9 or 10. Specific examples of the cycloalkyl include, but are not limited to, cyclopentyl, cyclohexyl, and adamantyl.

[0065] In the present disclosure, the halogen group can be, for example, fluorine, chlorine, bromine or iodine.

[0066] In the present disclosure, specific examples of trialkylsilyl include, but are not limited to, trimethylsilyl, triethylsilyl, and the like.

[0067] In the present disclosure, specific examples of triarylsilyl include, but are not limited to, triphenylsilyl and the like.

[0068] In the present disclosure, in the above two groups of groups R.sub.4 and R.sub.5, as well as R.sub.6 and R.sub.7, two groups in each group are connected to each other to form a 3- to 15-membered saturated or unsaturated ring together with the atoms to which they are commonly connected. For example, in the formula II

##STR00026##

when Y is a single bond, n.sub.3 is 0, and X is C(R.sub.4R.sub.5), and when R.sub.4 and R.sub.5 are connected to each other to form a 5-membered ring together with the atoms to which they are commonly connected, the formula II is

##STR00027##

likewise, the formula II may also represent

##STR00028##

that is, R.sub.4 and R.sub.5 are connected to each other to form a 6-membered ring together with the atoms to which they are commonly connected; likewise, the formula II may also represent

##STR00029##

that is, R.sub.4 and R.sub.5 are connected to each other to form a partially unsaturated 13-membered ring together with the atoms to which they are commonly connected; and likewise, the formula II may also represent

##STR00030##

that is, R.sub.4 and R.sub.5 are connected to each other to form a 10-membered ring together with the atoms to which they are commonly connected.

[0069] In one example of the present disclosure, the organic compound has a structure shown in any one of formulae 1-1 to 1-17:

##STR00031## ##STR00032## ##STR00033## ##STR00034##

[0070] where n′.sub.1 is selected from 0, 1 or 2; and n′.sub.2 is selected from 0, 1 or 2. X and Y may be the same or different.

[0071] In one example of the present disclosure, the organic compound has a structure shown in any one of 2-1 to 2-41:

##STR00035## ##STR00036## ##STR00037## ##STR00038## ##STR00039## ##STR00040## ##STR00041## ##STR00042## ##STR00043## ##STR00044##

[0072] where n′.sub.2 is selected from 0, 1 or 2.

[0073] In one example of the present disclosure, the formula II has a structure shown in any one of formulae II-1 to II-11:

##STR00045##

[0074] Optionally, n.sub.1, n.sub.2, and n.sub.3 are not simultaneously 0, and at least one R.sub.k, if present, has the structure represented by the formula III. For example, n.sub.1=1, and R.sub.1 has the structure represented by the formula III; or n.sub.2=1, and R.sub.2 has the structure represented by the formula III; or n.sub.3=1, and R.sub.3 has the structure represented by the formula III.

[0075] In the present disclosure, a ring A refers to

##STR00046##

where the ring A is a benzene ring or a fused aromatic ring with 10 to 14 ring-forming carbon atoms. The fused aromatic ring may be, for example, a naphthalene ring, an anthracene ring, or a phenanthrene ring. Where

##STR00047##

represents a chemical bond. For example, in a compound

##STR00048##

the ring A is a benzene ring, the number of a substituent R.sub.3 on the ring A is 0 (i.e., n.sub.3=0), X represents C(R.sub.4R.sub.5), R.sub.4 and R.sub.5 are each methyl, Y is a single bond, and the number of a substituent R.sub.1 and the number of a substituent R.sub.2 are also 0 (i.e., n.sub.1 and n.sub.2 are both 0).

[0076] In one example of the present disclosure, n.sub.1, n.sub.2 and n.sub.3 may each independently be selected from 0, 1 or 2.

[0077] In the present disclosure, when R.sub.1, R.sub.2, and R.sub.3 respectively have the structure represented by the formula III, Ar in R.sub.1, R.sub.2, and R.sub.3 may each be the same or different, and L may each also be the same or different.

[0078] In some examples, L is selected from a single bond or the group consisting of groups represented by formulae j-1 to j-15:

##STR00049## ##STR00050##

[0079] where M.sub.2 is selected from a single bond or

##STR00051##

and

##STR00052##

represents a chemical bond;

[0080] Q.sub.1 to Q.sub.5 and Q′.sub.1 to Q′.sub.4 are each independently selected from N, C or C(J.sub.1), and at least one of Q.sub.1 to Q.sub.5 is selected from N; when two or more of Q.sub.1 to Q.sub.5 are selected from C(J.sub.1), any two J.sub.1 are the same or different; and when two or more of Q′.sub.1 to Q′.sub.4 are selected from C(J.sub.1), any two J.sub.1 are the same or different;

[0081] Q.sub.6 to Q.sub.13 are each independently selected from N, C or C(J.sub.2), and at least one of Q.sub.6 to Q.sub.13 is selected from N; and when two or more of Q.sub.6 to Q.sub.13 are selected from C(J.sub.2), any two J.sub.2 are the same or different;

[0082] Q.sub.14 to Q.sub.23 are each independently selected from N, C or C(J.sub.3), and at least one of Q.sub.14 to Q.sub.23 is selected from N; and when two or more of Q.sub.14 to Q.sub.23 are selected from C(J.sub.3), any two J.sub.3 are the same or different;

[0083] Q.sub.24 to Q.sub.25 are each independently selected from N, C or C(J.sub.4);

[0084] Q.sub.26 and Q.sub.27 are each independently selected from N, C or C(J.sub.5), and at least one of Q.sub.26 to Q.sub.27 is selected from N; and when Q.sub.26 and Q.sub.27 are both selected from C(J.sub.5), both J.sub.5 are the same or different;

[0085] E.sub.1 to E.sub.14, and J.sub.1 to J.sub.5 are each independently selected from hydrogen, deuterium, fluorine, chlorine, bromine, cyano, a heteroaryl with 3 to 10 carbon atoms, an aryl with 6 to 12 carbon atoms, trimethylsilyl, triphenylsilyl, an alkyl with 1 to 5 carbon atoms, or a cycloalkyl with 3 to 10 carbon atoms;

[0086] e.sub.1 to e.sub.14 are represented by e.sub.r, E.sub.1 to E.sub.14 are represented by E.sub.r, r is a variable, and represents any integer from 1 to 14, and e.sub.r represents the number of a sub stituent E.sub.r; when r is selected from 1, 2, 3, 4, 5, 6, 9, 13 or 14, e.sub.r is selected from 1, 2, 3 or 4; when r is selected from 7 or 11, e.sub.r is selected from 1, 2, 3, 4, 5 or 6; when r is 12, e.sub.r is selected from 1, 2, 3, 4, 5, 6, or 7; when r is selected from 8 or 10, e.sub.r is selected from 1, 2, 3, 4, 5, 6, 7 or 8; and when e.sub.r is greater than 1, any two E.sub.r are the same or different, and optionally, any two adjacent E.sub.r are connected to each other to form a ring;

[0087] K.sub.1 is selected from O, S, Se, N(E.sub.15), C(E.sub.16E.sub.17) or Si(E.sub.18E.sub.19); where E.sub.15, E.sub.16, E.sub.17, E.sub.18 and E.sub.19 are each independently selected from an aryl with 6 to 20 carbon atoms, a heteroaryl with 3 to 20 carbon atoms, an alkyl with 1 to 5 carbon atoms, or a cycloalkyl with 3 to 10 carbon atoms, or E.sub.16 and E.sub.17 are connected to each other to form a saturated or unsaturated ring having 3 to 15 carbon atoms together with the atoms to which they are commonly connected, or E.sub.18 and E.sub.19 are connected to each other to form a saturated or unsaturated ring having 3 to 15 carbon atoms together with the atoms to which they are commonly connected; and

[0088] K.sub.2 is selected from a single bond, O, S, Se, N(E.sub.20), C(E.sub.21E.sub.22) or Si(E.sub.23E.sub.24); where E.sub.20 to E.sub.24 are each independently selected from an aryl with 6 to 20 carbon atoms, a heteroaryl with 3 to 20 carbon atoms, an alkyl with 1 to 5 carbon atoms, or a cycloalkyl with 3 to 10 carbon atoms, or E.sub.21 and E.sub.22 are connected to each other to form a saturated or unsaturated ring having 3 to 15 carbon atoms together with the atoms to which they are commonly connected, or E.sub.23 and E.sub.24 are connected to each other to form a saturated or unsaturated ring having 3 to 15 carbon atoms together with the atoms to which they are commonly connected.

[0089] In the present disclosure, in the four groups of groups E.sub.16 and E.sub.17, E.sub.18 and E.sub.19, E.sub.21 and E.sub.22, as well as E.sub.23 and E.sub.24, a ring formed by connecting two groups in each group to each other can be a saturated or unsaturated ring having 3 to 15 carbon atoms. For example, in the formula j-8

##STR00053##

when both K.sub.4 and M.sub.1 are a single bond, Q′.sub.1, Q′.sub.2, Q′.sub.3, Q′.sub.4, and E.sub.11 are hydrogen, and K.sub.1 is C(E.sub.16E.sub.17), and when E.sub.16 and E.sub.17 are connected to each other to form a 5-membered ring together with the atoms to which they are commonly connected, the formula j-8 is

##STR00054##

likewise, the formula j-8 may also represent

##STR00055##

that is, E.sub.16 and E.sub.17 are connected to each other to form a partially unsaturated 13-membered ring together with the atoms to which they are commonly connected.

[0090] In the present disclosure, in the formulae j-10 to j-12, J.sub.1 to J.sub.3 may be represented by J.sub.j, where j is a variable and represents 1, 2, or 3. For example, when j is 2, J.sub.j refers to J.sub.2. It should be understood that J.sub.j in C(J.sub.j) is not present when an unpositioned connecting bond is connected to C(J.sub.j). For example, in the chemical formula i-11, when “

##STR00056##

” is connected to Q.sub.12, Q.sub.12 can only represent a C atom, i.e. the structure of the formula i-11 is specifically:

##STR00057##

[0091] Optionally, L is selected from a single bond, substituted or unsubstituted arylene with 6 to 25 carbon atoms, and substituted or unsubstituted heteroarylene with 3 to 25 carbon atoms. For example, L can be selected from a single bond, substituted or unsubstituted arylene with 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, or 25 carbon atoms, and substituted or unsubstituted heteroarylene with 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, or 25 carbon atoms.

[0092] Optionally, L is selected from a single bond, a substituted or unsubstituted arylene with 6 to 15 carbon atoms, or a substituted or unsubstituted heteroarylene with 3 to 20 carbon atoms.

[0093] Optionally, L is selected from a single bond or a substituted or unsubstituted group T.sub.1, and the unsubstituted group T.sub.1 is selected from the group consisting of:

##STR00058## ##STR00059## ##STR00060## ##STR00061## ##STR00062## ##STR00063##

[0094] the substituted group T.sub.1 has one or two or more substituents, and the substituents in substituted group T.sub.1 are independently selected from deuterium, fluorine, cyano, trimethylsilyl, triphenylsilyl, methyl, ethyl, isopropyl, tert-butyl, phenyl, biphenyl, pyridyl, naphthyl, carbazolyl, dibenzofuranyl or dibenzothienyl.

[0095] Further optionally, L is selected from a single bond or the group consisting of:

##STR00064## ##STR00065## ##STR00066## ##STR00067## ##STR00068## ##STR00069## ##STR00070## ##STR00071## ##STR00072## ##STR00073## ##STR00074## ##STR00075## ##STR00076## ##STR00077##

[0096] Optionally, L is selected from a single bond, or substituted or unsubstituted phenylene, substituted or unsubstituted naphthylene, substituted or unsubstituted anthrylene, substituted or unsubstituted dibenzofuranylene, substituted or unsubstituted dibenzothienylene, substituted or unsubstituted benzothiazolylene, substituted or unsubstituted benzoxazolylene, substituted or unsubstituted biphenylene, substituted or unsubstituted quinolylene, substituted or unsubstituted quinazolinylene, substituted or unsubstituted benzo[f]quinoxalinylene, substituted or unsubstituted benzo[f]quinazolinylene, substituted or unsubstituted benzo[h]quinazolinylene, substituted or unsubstituted fluorenylene, substituted or unsubstituted benzimidazolylene, substituted or unsubstituted phenanthro[9,10-d]imidazolylene, substituted or unsubstituted pyridylene, substituted or unsubstituted carbazolylene, substituted or unsubstituted triazinylene, substituted or unsubstituted quinoxalinylene, substituted or unsubstituted phenanthrylene, substituted or unsubstituted pyrimidylene, substituted or unsubstituted benzothienopyrimidinylene, substituted or unsubstituted benzofuropyrimidinylene, and substituted or unsubstituted dibenzo[f,h]quinoxalinylene; or is a group formed by connecting two or three of the above groups by a single bond; and substituents in the above groups are the same or different, and are each independently selected from deuterium, fluorine, cyano, methyl, ethyl, isopropyl, tert-butyl, phenyl, phenyl substituted with methyl, ethyl, isopropyl, and tert-butyl, naphthyl, dimethylfluorenyl, biphenyl, biphenyl substituted with phenyl, dibenzofuranyl, dibenzothienyl, carbazolyl, quinolyl, and pyridyl.

[0097] In some examples, Ar is selected from the group consisting of groups represented by any one of formulae i-1 to i-15:

##STR00078## ##STR00079##

[0098] where M.sub.1 is selected from a single bond or

##STR00080##

[0099] G.sub.1 to G.sub.5 and G′.sub.1 to G′.sub.4 are each independently selected from N, C, or C(J.sub.6), and at least one of G.sub.1 to G.sub.5 is selected from N; when two or more of G.sub.1 to G.sub.5 are selected from C(J.sub.6), any two J.sub.6 are the same or different; and when two or more of G′.sub.1 to G′.sub.4 are selected from C(J.sub.6), any two J.sub.6 are the same or different;

[0100] G.sub.6 to G.sub.13 are each independently selected from N, C or C(J.sub.7), and at least one of G.sub.6 to G.sub.13 is selected from N; and when two or more of G.sub.6 to G.sub.13 are selected from C(J.sub.7), any two J.sub.7 are the same or different;

[0101] G.sub.14 to G.sub.23 are each independently selected from N, C or C(J.sub.8), and at least one of G.sub.14 to G.sub.23 is selected from N; and when two or more of G.sub.14 to G.sub.23 are selected from C(J.sub.8), any two J.sub.8 are the same or different;

[0102] G.sub.24 is selected from O, S, N(J.sub.9) or C(J.sub.10);

[0103] Z.sub.1 is selected from hydrogen, deuterium, a halogen group, cyano, trimethylsilyl, an alkyl with 1 to 5 carbon atoms, a cycloalkyl with 3 to 10 carbon atoms, or triphenylsilyl;

[0104] Z.sub.2 to Z.sub.9, and Z.sub.22 are each independently selected from hydrogen, deuterium, a halogen group, cyano, trimethylsilyl, an alkyl with 1 to 5 carbon atoms, a cycloalkyl with 3 to 10 carbon atoms, a heteroaryl with 3 to 18 carbon atoms, or triphenylsilyl;

[0105] Z.sub.10 to Z.sub.21, and J.sub.1 to J.sub.10 are each independently selected from hydrogen, deuterium, a halogen group, cyano, trimethylsilyl, an alkyl with 1 to 5 carbon atoms, a cycloalkyl with 3 to 10 carbon atoms, an aryl with 6 to 18 carbon atoms, a heteroaryl with 3 to 18 carbon atoms, or triphenylsilyl;

[0106] h.sub.1 to h.sub.22 are represented by h.sub.k, Z.sub.1 to Z.sub.22 are represented by Z.sub.k, k is a variable and represents any integer from 1 to 22, and h.sub.k represents the number of a substituent Z.sub.k; when k is selected from 5 or 17, h.sub.k is selected from 1, 2 or 3; when k is selected from 2, 7, 8, 12, 15, 16, 18, 21 or 22, h.sub.k is selected from 1, 2, 3 or 4; when k is selected from 1, 3, 4, 6, 9 or 14, h.sub.k is selected from 1, 2, 3, 4 or 5; when k is 13, h.sub.k is selected from 1, 2, 3, 4, 5, or 6; when k is selected from 10 or 19, h.sub.k is selected from 1, 2, 3, 4, 5, 6 or 7; when k is 20, h.sub.k is selected from 1, 2, 3, 4, 5, 6, 7, or 8; when k is 11, h.sub.k is selected from 1, 2, 3, 4, 5, 6, 7, 8 or 9; and when h.sub.k is greater than 1, any two Z.sub.k are the same or different;

[0107] K.sub.1 is selected from O, S, N(Z.sub.23), C(Z.sub.24Z.sub.25), and Si(Z.sub.26Z.sub.27); where Z.sub.23, Z.sub.24, Z.sub.25, Z.sub.26, and Z.sub.27 are each independently selected from an aryl with 6 to 18 carbon atoms, a heteroaryl with 3 to 18 carbon atoms, an alkyl with 1 to 5 carbon atoms, or cycloalkyl with 3 to 10 carbon atoms, or Z.sub.24 and Z.sub.25 are connected to each other to form a saturated or unsaturated ring having 3 to 15 carbon atoms together with the atoms to which they are commonly connected, or Z.sub.26 and Z.sub.27 are connected to each other to form a saturated or unsaturated ring having 3 to 15 carbon atoms together with the atoms to which they are commonly connected; and

[0108] K.sub.2 is selected from a single bond, O, S, N(Z.sub.28), C(Z.sub.29Z.sub.30), and Si(Z.sub.31Z.sub.32); where Z.sub.28, Z.sub.29, Z.sub.30, Z.sub.31, and Z.sub.32 are each independently selected from an aryl with 6 to 18 carbon atoms, a heteroaryl with 3 to 18 carbon atoms, an alkyl with 1 to 5 carbon atoms, or cycloalkyl with 3 to 10 carbon atoms, or Z.sub.29 and Z.sub.30 are connected to each other to form a saturated or unsaturated ring having 3 to 15 carbon atoms together with the atoms to which they are commonly connected, or Z.sub.31 and Z.sub.32 are connected to each other to form a saturated or unsaturated ring having 3 to 15 carbon atoms together with the atoms to which they are commonly connected.

[0109] Optionally, Ar is selected from a substituted or unsubstituted aryl with 6 to 25 carbon atoms or a substituted or unsubstituted heteroaryl with 3 to 20 carbon atoms. For example, Ar may be selected from substituted or unsubstituted aryl with 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, or 25 carbon atoms, and substituted or unsubstituted heteroaryl with 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, or 20 carbon atoms.

[0110] Optionally, Ar is selected from a substituted or unsubstituted group T.sub.2, and the unsubstituted group T.sub.2 is selected from the group consisting of:

##STR00081## ##STR00082##

[0111] the substituted group T.sub.2 has one or two or more substituents, and the substituents in the substituted group T.sub.2 are independently selected from deuterium, fluorine, cyano, methyl, ethyl, isopropyl, tert-butyl, phenyl, biphenyl, pyridyl, naphthyl, carbazolyl, cyclohexyl, dibenzofuranyl or dibenzothienyl.

[0112] Further optionally, Ar is selected from the group consisting of:

##STR00083## ##STR00084## ##STR00085## ##STR00086## ##STR00087## ##STR00088## ##STR00089##

[0113] In one example, Ar is selected from substituted or unsubstituted phenyl, substituted or unsubstituted pyridyl, substituted or unsubstituted pyrimidinyl, substituted or unsubstituted triazinyl, substituted or unsubstituted naphthyl, substituted or unsubstituted anthryl, substituted or unsubstituted benzothiazolyl, substituted or unsubstituted benzoxazolyl, substituted or unsubstituted phenanthryl, substituted or unsubstituted biphenyl, substituted or unsubstituted quinolyl, substituted or unsubstituted 1,10-phenanthrolinyl, substituted or unsubstituted 9,9-dimethylfluorenyl, substituted or unsubstituted dibenzofuranyl, substituted or unsubstituted dibenzothienyl, substituted or unsubstituted 9,10-benzophenanthryl, substituted or unsubstituted N-phenylcarbazolyl, substituted or unsubstituted terphenyl, substituted or unsubstituted carbazolyl, substituted or unsubstituted pyrenyl, substituted or unsubstituted fluoranthenyl, 1-phenyl-1H-benzimidazolyl, substituted or unsubstituted 9,9-spirobifluorenyl, substituted or unsubstituted 9,9-diphenylfluorenyl, substituted or unsubstituted 4,5-diaza-9,9′-spirodifluorenyl, substituted or unsubstituted silafluorenyl, and substituted or unsubstituted benzofuropyrimidinyl, and substituents in the above groups are the same or different, and are each independently selected from deuterium, cyano, fluorine, trimethylsilyl, methyl, ethyl, isopropyl, tert-butyl, phenyl, biphenyl, pyridyl, carbazolyl, and naphthyl.

[0114] Optionally, R.sub.4 to R.sub.7 are each independently selected from an alkyl with 1 to 5 carbon atoms, an aryl with 6 to 20 carbon atoms, or a heteroaryl with 3 to 20 carbon atoms.

[0115] Further optionally, R.sub.4 to R.sub.7 are each independently selected from methyl, ethyl, isopropyl, tert-butyl, phenyl, naphthyl, biphenyl, pyridyl, and quinolyl.

[0116] Optionally, the organic compound is selected from the group consisting of the following compounds:

##STR00090## ##STR00091## ##STR00092## ##STR00093## ##STR00094## ##STR00095## ##STR00096## ##STR00097## ##STR00098## ##STR00099## ##STR00100## ##STR00101## ##STR00102## ##STR00103## ##STR00104## ##STR00105## ##STR00106## ##STR00107## ##STR00108## ##STR00109## ##STR00110## ##STR00111## ##STR00112## ##STR00113## ##STR00114## ##STR00115## ##STR00116## ##STR00117## ##STR00118## ##STR00119## ##STR00120## ##STR00121## ##STR00122## ##STR00123## ##STR00124## ##STR00125##

##STR00126## ##STR00127## ##STR00128## ##STR00129## ##STR00130## ##STR00131## ##STR00132## ##STR00133## ##STR00134## ##STR00135## ##STR00136## ##STR00137## ##STR00138## ##STR00139## ##STR00140## ##STR00141## ##STR00142## ##STR00143## ##STR00144## ##STR00145## ##STR00146## ##STR00147## ##STR00148## ##STR00149## ##STR00150## ##STR00151## ##STR00152## ##STR00153## ##STR00154## ##STR00155## ##STR00156## ##STR00157## ##STR00158## ##STR00159## ##STR00160## ##STR00161## ##STR00162## ##STR00163## ##STR00164## ##STR00165## ##STR00166## ##STR00167## ##STR00168## ##STR00169## ##STR00170## ##STR00171## ##STR00172## ##STR00173## ##STR00174## ##STR00175## ##STR00176## ##STR00177##

[0117] A synthetic method of the organic compound provided is not particularly limited in the present disclosure, and those skilled in the art can determine a suitable synthetic method according to the organic compound of the present disclosure in combination with synthetic methods provided in Synthesis examples. In other words, the Synthesis examples of the present disclosure exemplarily provide methods for the preparation of the organic compounds, and the used raw materials may be commercially obtained or obtained by a method well known in the art. All organic compounds provided by the present disclosure can be obtained according to these exemplary synthetic methods by those skilled in the art, and all specific synthetic methods for preparing such organic compounds are not described in detail here, which should not be understood by those skilled in the art as limiting the present disclosure.

[0118] In a second aspect, the present disclosure provides an electronic element, including an anode and a cathode which are oppositely disposed, and a functional layer disposed between the anode and the cathode; and the functional layer includes the organic compound described above.

[0119] The organic compound provided by the present disclosure can be used to form at least one organic film layer in the functional layer to improve the efficiency and service life characteristics of the electronic element.

[0120] In one example of the present disclosure, the functional layer includes an organic light-emitting layer including the organic compound. The organic light-emitting layer may be composed of the organic compound provided by the present disclosure or may be composed of the organic compound provided by the present disclosure together with other materials.

[0121] Optionally, the electronic element is an organic electroluminescent device.

[0122] According to one example of the present disclosure, the organic electroluminescent device can be a green device or a red device. As shown in FIG. 1, the organic electroluminescent device may include an anode 100, a first hole transport layer 321, a second hole transport layer 322, an organic light-emitting layer 330 as an energy conversion layer, an electron transport layer 340, and a cathode 200 which are sequentially stacked.

[0123] Optionally, the anode 100 includes the following anode materials, which are preferably materials having a large work function that facilitate hole injection into the functional layer. Specific examples of the anode materials include metals such as nickel, platinum, vanadium, chromium, copper, zinc, and gold or their alloys; metal oxides such as zinc oxide, indium oxide, indium tin oxide (ITO), and indium zinc oxide (IZO); combined metals and oxides such as ZnO:Al or SnO.sub.2:Sb; or conducting polymers such as poly(3-methylthiophene), poly[3,4-(ethylene-1,2-dioxy)thiophene] (PEDT), polypyrrole, and polyaniline, but are not limited to this. A transparent electrode containing indium tin oxide (ITO) as the anode is preferably included.

[0124] Optionally, the hole transport layer 320 includes a first hole transport layer 321 and a second hole transport layer 322 which are sequentially stacked, and the first hole transport layer 321 is closer to the anode 100 than the second hole transport layer 322.

[0125] Optionally, the first hole transport layer 321 and the second hole transport layer 322 each include one or more hole transport materials, and the hole transport materials may be selected from a carbazole polymer, carbazole-linked triarylamine compounds, or other types of compounds, which are not particularly limited in the present disclosure. For example, the first hole transport layer 321 may be composed of a compound NPB, HT-01 or HT-03; and the second hole transport layer 322 may be composed of a compound HT-02 or HT-04. The structures of HT-01 to HT-04 are shown below.

[0126] Optionally, the organic light-emitting layer 330 may be composed of a single light-emitting material, and may also include a host material and a guest material. The host material and/or the guest material of the organic light-emitting layer may contain the organic compound of the present disclosure. Further optionally, the organic light-emitting layer 330 is composed of the host material and the guest material, and holes injected into the organic light-emitting layer 330 and electrons injected into the organic light-emitting layer 330 may be recombined in the organic light-emitting layer 330 to form excitons, the excitons transfer energy to the host material, and the host material transfers energy to the guest material, thus enabling the guest material to emit light. In one example of the present disclosure, the host material of the organic light-emitting layer contains the organic compound of the present disclosure.

[0127] The guest material of the organic light-emitting layer 330 may be a compound having a condensed aryl ring or its derivative, a compound having a heteroaryl ring or its derivative, an aromatic amine derivative, or other materials, which is not specially limited in the present disclosure.

[0128] The electron transport layer 340 may be of a single-layer structure or a multi-layer structure, and may include one or more electron transport materials, and the electron transport materials may be selected from, but are not limited to, a benzimidazole derivative, an oxadiazole derivative, a quinoxaline derivative, or other electron transport materials. In one example of the present disclosure, the electron transport layer 340 may be composed of TPBi and LiQ or ET-01 (with a structure shown below) and LiQ.

[0129] In the present disclosure, the cathode 200 may include a cathode material, which is a material having a small work function that facilitates electron injection into the functional layer. Specific examples of the cathode material include, but are not limited to, metals such as magnesium, calcium, sodium, potassium, titanium, indium, yttrium, lithium, gadolinium, aluminum, silver, tin, and lead or their alloys; or multilayer materials such as LiF/Al, Liq/Al, LiO.sub.2/Al, LiF/Ca, LiF/Al, and BaF.sub.2/Ca. A metal electrode containing magnesium and silver as the cathode is preferably included.

[0130] Optionally, as shown in FIG. 1, a hole injection layer 310 may also be arranged between the anode 100 and the first hole transport layer 321 to enhance the ability to inject holes into the first hole transport layer 321. The hole injection layer 310 can be made of a benzidine derivative, a starburst arylamine compound, a phthalocyanine derivative or other materials, which is not specially limited in the present disclosure. For example, the hole injection layer 310 may be composed of HAT-CN or F4-TCNQ.

[0131] Optionally, as shown in FIG. 1, an electron injection layer 350 may also be arranged between the cathode 200 and the electron transport layer 340 to enhance the ability to inject electrons into the electron transport layer 340. The electron injection layer 350 may include an inorganic material such as an alkali metal sulfide and an alkali metal halide, or may include a complex of an alkali metal and an organic substance. For example, the electron injection layer 350 may include LiQ or Yb.

[0132] In a third aspect, the present disclosure provides an electronic device, including the electronic element according to the second aspect of the present disclosure.

[0133] According to one example, as shown in FIG. 2, the electronic device is an electronic device 400 including the organic electroluminescent device described above. The electronic device 400 may be, for example, a display device, a lighting device, an optical communication device, or other types of electronic devices, and may include, for example, but is not limited to, a computer screen, a mobile phone screen, a television, electronic paper, an emergency lighting lamp, an optical module, and the like.

[0134] Compounds of which synthetic methods are not mentioned in the present disclosure are all raw material products obtained by commercial routes.

[0135] The synthetic methods of the organic compounds of the present disclosure are specifically described below in conjunction with synthesis examples.

SYNTHESIS EXAMPLES

[0136] 1. Preparation of Intermediate IM a-1

##STR00178##

[0137] 2-Bromo-4-chloro-1-iodobenzene (50.0 g, 157.5 mmol), dibenzofuran-3-boronic acid (30.4 g, 157.5 mmol), tetrakis(triphenylphosphine)palladium (3.6 g, 3.1 mmol), potassium carbonate (54.3 g, 393.8 mmol), and tetrabutylammonium bromide (10.1 g, 31.5 mmol) were added to a flask, and a mixed solvent of toluene (440 mL), ethanol (200 mL) and water (100 mL) was added, and the mixture was heated to 80° C. under nitrogen protection, and stirred for 24 h while maintaining the temperature, after cooling to room temperature, stirring was stopped, the reaction solution was washed with water, the obtained organic phase was separated, and dried by anhydrous magnesium sulfate, and a solvent was removed under reduced pressure to give a crude product; and the crude product was purified by silica gel column chromatography using dichloromethane/n-heptane as a mobile phase to obtain a white solid intermediate IM a-1 (33.8 g, yield: 60%).

[0138] Intermediates IM x-1 listed in Table 1 were synthesized by the same method as that for synthesis of the intermediate IM a-1 except that a reactant A was used instead of 2-bromo-4-chloro-l-iodobenzene and a reactant B was used instead of dibenzofuran-3-boronic acid. The used main reactants, the synthesized intermediates and their yields are shown in Table 1.

TABLE-US-00001 TABLE 1 Yield/ Reactant A Reactant B Intermediate IM x-1 % [00179] [00180] [00181] 60 [00182] [00183] [00184] 58 [00185] [00186] [00187] 61 [00188] [00189] [00190] 63 [00191] [00192] [00193] 57 [00194] [00195] [00196] 59 [00197] [00198] [00199] 60 [00200] [00201] [00202] 64 [00203] [00204] [00205] 56 [00206] [00207] [00208] 67 [00209] [00210] [00211] 62 [00212] [00213] [00214] 64 [00215] [00216] [00217] 66 [00218] [00219] [00220] 63 [00221] [00222] [00223] 62 [00224] [00225] [00226] 61 [00227] [00228] [00229] 60 [00230] [00231] [00232] 59 [00233] [00234] [00235] 64 [00236] [00237] [00238] 65 [00239] [00240] [00241] 63 [00242] [00243] [00244] 58 [00245] [00246] [00247] 58 [00248] [00249] [00250] 59 [00251] [00252] [00253] 61

[0139] 2. Preparation of Intermediate IM a-2

##STR00254##

[0140] The intermediate IM a-1 (33.8 g, 94.5 mmol) and tetrahydrofuran (280 mL) were added to a flask, and cooled to −78° C. under nitrogen protection, a solution (2.5 M) of n-butyllithium (57 mL, 141.75 mmol) in tetrahydrofuran was added dropwise under stirring, after the dropwise addition was complete, stirring was performed for 1 h while heat preservation, a solution of adamantanone (11.3 g, 75.6 mmol) in tetrahydrofuran (56 mL) was added dropwise while maintaining at −78° C., after the addition was complete, heat preservation was performed for 1 h, then the system was heated to room temperature, stirring was performed for 24 h, hydrochloric acid (12M) (17.7 mL, 212.59 mmol) (100 mL) was added to the reaction solution, stirring was performed for 1 h, liquid separation was performed, the obtained organic phase was washed with water to be neutral, and dried by anhydrous magnesium sulfate, and a solvent was removed under reduced pressure to obtain a crude product, and the crude product was purified by silica gel column chromatography using a dichloromethane/n-heptane system to obtain a white solid intermediate IM a-2 (20.3 g, yield: 50%).

[0141] Intermediates IM x-2 listed in Table 2 were synthesized by the same method as that for synthesis of the intermediate IM a-2 except that a reactant C was used instead of the intermediate IM a-1. The used main reactants, the synthesized intermediates and their yields are shown in Table 2.

TABLE-US-00002 TABLE 2 Reactant C Intermediate IM x-2 Yield/% [00255] [00256] 56 [00257] [00258] 54 [00259] [00260] 53 [00261] [00262] 52 [00263] [00264] 51 [00265] [00266] 57 [00267] [00268] 50 [00269] [00270] 59 [00271] [00272] 57 [00273] [00274] 55 [00275] [00276] 54 [00277] [00278] 52 [00279] [00280] 54 [00281] [00282] 56 [00283] [00284] 53 [00285] [00286] 52 [00287] [00288] 53 [00289] [00290] 59 [00291] [00292] 58 [00293] [00294] 60 [00295] [00296] 63 [00297] [00298] 59 [00299] [00300] 61 [00301] [00302] 59 [00303] [00304] 58

[0142] 3. Preparation of Intermediate IM a-3

##STR00305##

[0143] The intermediate IM a-2 (20.3 g, 47.3 mmol) and glacial acetic acid (200 mL) were added into a flask, a solution of concentrated sulfuric acid (98%) (0.9 mL, 9.5 mmol) in acetic acid (20 mL) was slowly added dropwise under stirring at room temperature under nitrogen protection, and after the dropwise addition was complete, the mixture was heated to 60° C., and stirred for 2 h; the resulting reaction solution was cooled to room temperature, the precipitated solid was filtered, and a filter cake was rinsed with water and ethanol, and oven-dried to obtain a crude product; and the crude product was purified by silica gel column chromatography using a dichloromethane/n-heptane system to obtain a white solid intermediate IM a-3 (15.5 g, yield: 80%).

[0144] Intermediates IM x-3 listed in Table 3 were synthesized by the same method as that for synthesis of the intermediate IM a-3 except that the reactant D was used instead of the intermediate IM a-2. The used main reactants, the synthesized intermediates and their yields are shown in Table 3.

TABLE-US-00003 TABLE 3 Reactant D Intermediate x-3 Yield/% [00306] [00307] 76 [00308] [00309] 77 [00310] [00311] 73 [00312] [00313] 72 [00314] [00315] 79 [00316] [00317] 80 [00318] [00319] 75 [00320] [00321] 73 [00322] [00323] 75 [00324] [00325] 72 [00326] [00327] 69 [00328] [00329] 68 [00330] [00331] 79 [00332] [00333] 76 [00334] [00335] 73 [00336] [00337] 71 [00338] [00339] 70 [00340] [00341] 79 [00342] [00343] 80 [00344] [00345] 81 [00346] [00347] 77 [00348] [00349] 78 [00350] [00351] 74 [00352] [00353] 73 [00354] [00355] 72

[0145] 4. Preparation of Intermediate IM a-4

##STR00356##

[0146] The intermediate IM a-3 (15.5 g, 37.7 mmol), bis(pinacolato)diboron (11.5 g, 45.3 mmol), tris(dibenzylideneacetone)dipalladium (0.35 g, 0.38 mmol), 2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl (0.35 g, 0.75 mmol), potassium acetate (11.1 g, 113.1 mmol) and 1,4-dioxane (150 mL) were added to a flask, and stirred under reflux at 100° C. for 12 h under nitrogen protection; the resulting reaction solution was cooled to room temperature, dichloromethane and water were added to the reaction solution, liquid separation was performed, the obtained organic phase was washed with water and dried by anhydrous magnesium sulfate, and a solvent was removed under reduced pressure to obtain a crude product; and the crude product was purified by silica gel column chromatography using a dichloromethane/n-heptane system to obtain a white solid intermediate IM a-4 (10.0 g, yield: 53%).

[0147] Intermediates IM x-4 listed in Table 4 were synthesized by the same method as that for synthesis of the intermediate IM a-4 except that a reactant E was used instead of the intermediate IM a-3. The used main reactants, the synthesized intermediates and their yields are shown in Table 4.

TABLE-US-00004 TABLE 4 Reactant E Intermediate IM x-4 Yield/% [00357] [00358] 53 [00359] [00360] 52 [00361] [00362] 50 [00363] [00364] 56 [00365] [00366] 57 [00367] [00368] 58 [00369] [00370] 55 [00371] [00372] 59 [00373] [00374] 58 [00375] [00376] 58 [00377] [00378] 56 [00379] [00380] 54 [00381] [00382] 60 [00383] [00384] 59 [00385] [00386] 56 [00387] [00388] 55 [00389] [00390] 57 [00391] [00392] 58 [00393] [00394] 57 [00395] [00396] 55 [00397] [00398] 54 [00399] [00400] 57 [00401] [00402] 52 [00403] [00404] 59 [00405] [00406] 58

[0148] 5. Preparation of Compounds

##STR00407##

[0149] The intermediate TM a-4 (10 g, 19.9 mmol), 2-(4-biphenyl)-4-chloro-6-phenyl-1,3,5-triazine (6.2 g, 18.1 mmol), tetrakis(triphenylphosphine)palladium (0.41 g, 0.36 mmol), potassium carbonate (6.2 g, 45.2 mmol), and tetrabutylammonium bromide (1.1 g, 3.6 mmol) were added to a flask, and a mixed solvent of toluene (80 mL), ethanol (20 mL) and water (20 mL) was added, and the mixture was heated to 80° C. under nitrogen protection, and stirred for 8 h while maintaining the temperature; then cooling to room temperature, stirring was stopped, the reaction solution was washed with water, the obtained organic phase was separated, and dried by anhydrous magnesium sulfate, and a solvent was removed under reduced pressure to obtain a crude product; and the crude product was purified by silica gel column chromatography using a dichloromethane/n-heptane mixed solvent as a mobile phase to obtain a white solid compound 2 (8.6 g, yield: 70%).

[0150] Compounds listed in Table 5 were synthesized by the same synthesis method as that for the synthesis of the compound 2 except that a reactant F was used instead of the intermediate IM a-4, and a reactant G was used instead of 2-(4-biphenyl)-4-chloro-6-phenyl-1,3,5-triazine. The used main reactants, the synthesized compounds and their yields are shown in Table 5.

TABLE-US-00005 TABLE 5 Yield/ Reactant F Reactant G Compound % [00408] [00409] [00410] 69 [00411] [00412] [00413] 60 [00414] [00415] [00416] 63 [00417] [00418] [00419] 60 [00420] [00421] [00422] 68 [00423] [00424] [00425] 64 [00426] [00427] [00428] 71 [00429] [00430] [00431] 72 [00432] [00433] [00434] 59 [00435] [00436] [00437] 60 [00438] [00439] [00440] 67 [00441] [00442] [00443] 54 [00444] [00445] [00446] 68 [00447] [00448] [00449] 59 [00450] [00451] [00452] 68 [00453] [00454] [00455] 68 [00456] [00457] [00458] 62 [00459] [00460] [00461] 56 [00462] [00463] [00464] 66 [00465] [00466] [00467] 55 [00468] [00469] [00470] 70 [00471] [00472] [00473] 64 [00474] [00475] [00476] 57 [00477] [00478] [00479] 63 [00480] [00481] [00482] 66 [00483] [00484] [00485] 68 [00486] [00487] [00488] 66 [00489] [00490] [00491] 64

[0151] Preparation of Compound 374:

[0152] (1) Synthesis of Intermediate IM A

##STR00492##

[0153] 8-Bromonaphtho[1,2-B]benzofuran (50 g, 168.2 mmol) and tetrahydrofuran (400 ml) were added to a flask, and cooled to −78° C. under nitrogen protection, a solution (2.5 M) of n-butyllithium (72.4 mL, 181.1 mmol) in tetrahydrofuran was added dropwise under stirring, after the dropwise addition was complete, stirring was performed for 1 h while heat preservation, a solution of trimethyl borate (17.5 g, 168.2 mmol) in tetrahydrofuran (70 mL) was added dropwise while maintaining at −78° C., after the dropwise addition was complete, heat preservation was performed for 1 h, the system was heated to room temperature, stirring was performed for 24 h, a solution of hydrochloric acid (12M) (22.6 mL, 271.6 mmol) in water (113.2 mL) was added into the reaction solution, stirring was performed for 1 h, liquid separation was performed, the obtained organic phase was washed with water to be neutral, and dried by anhydrous magnesium sulfate, and a solvent was removed under reduced pressure to give a crude product, and the crude product was purified by silica gel column chromatography using a dichloromethane/n-heptane system to obtain a white solid intermediate IM A (24.7 g, yield: 56%).

[0154] (2) Synthesis of Intermediate IM B

##STR00493##

[0155] 1-Bromo-2-iodonaphthalene (29.9 g, 89.8 mmol), the intermediate IM A (24.7 g, 94.2 mmol), tetrakis(triphenylphosphine)palladium (2.1 g, 1.8 mmol), potassium carbonate (27.3 g, 197.5 mmol), and tetrabutylammonium bromide (5.8 g, 17.9 mmol) was added to a flask, and a mixed solvent of toluene (240 mL), ethanol (120 mL) and water (60 mL) was added, and the mixture was heated to 80° C. under nitrogen protection, and stirred for 24 h while maintaining the temperature, after cooling to room temperature, stirring was stopped, the reaction solution was washed with water, the obtained organic phase was separated, and dried by anhydrous magnesium sulfate, and a solvent removed under reduced pressure to give a crude product; and the crude product was purified by silica gel column chromatography using dichloromethane/n-heptane as a mobile phase to obtain a white solid intermediate IM B (28.5 g, yield: 75%).

[0156] (3) Synthesis of Intermediate IM C

##STR00494##

[0157] The intermediate IM B (28.5 g, 67.3 mmol) and tetrahydrofuran (230 mL) were added to a flask, and cooled to −78° C. under nitrogen protection, a solution (2.5 M) of n-butyllithium (32.3 mL, 80.8 mmol) in tetrahydrofuran was added dropwise under stirring, after the dropwise addition was complete, stirring was performed for 1 h while heat preservation, a solution of adamantanone (11.1 g, 74.0 mmol) in tetrahydrofuran (44 mL) was added dropwise while maintaining at -78° C., after the dropwise addition was complete, heat preservation was performed for 1 h, the system was heated to room temperature, stirring was performed for 24 h, 50 mL of hydrochloric acid (12M) (10.1 mL, 121.2 mmol) was added to the reaction solution, stirring was performed for 1 h, liquid separation was performed, the obtained organic phase was washed with water to be neutral, and dried by anhydrous magnesium sulfate, and a solvent was removed under reduced pressure to give a crude product, and the crude product was purified by silica gel column chromatography using a dichloromethane/n-heptane system to obtain a white solid intermediate IM C (18.3 g, yield: 55%).

[0158] (4) Synthesis of Intermediate IM D

##STR00495##

[0159] The intermediate IM C (18.3 g, 37.0 mmol) and glacial acetic acid (146 mL) were added into a flask, and a solution of concentrated sulfuric acid (98%) (0.8 mL, 7.4 mmol) in acetic acid (15 mL) was slowly added dropwise under stirring at room temperature under nitrogen protection, after the dropwise addition was completed, the mixture was heated to 60° C., and stirred for 2 h; the resulting reaction solution was cooled to room temperature, the precipitated solid was filtered, and a filter cake was rinsed with water and ethanol and oven-dried to give a crude product; and the crude product was purified by silica gel column chromatography using a dichloromethane/n-heptane system to obtain a white solid intermediate IM D (13.6 g, yield: 77%).

[0160] (5) Synthesis of Intermediate IM E

##STR00496##

[0161] The intermediate IM D (13.6 g, 28.5 mmol) and a solvent DMF (N,N-dimethylformamide) (110 mL) were added to a flask, and stirred at room temperature under nitrogen protection for 10 min, N-bromosuccinimide (NBS) (7.6 g, 42.8 mmol) was added, and the mixture was heated to 80° C., and stirred for 4 h while heat preservation; after the reaction was completed, the resulting reaction solution was cooled to room temperature, the reaction solution was extracted with dichloromethane and water, the obtained organic phase was taken and dried by anhydrous magnesium sulfate, and a solvent was removed under reduced pressure to give a crude product; and the crude product was purified by silica gel column chromatography using a dichloromethane/n-heptane system as a mobile phase to obtain a white solid intermediate IM E (11.9 g, yield: 75%).

[0162] (6) Synthesis of Intermediate IM F

##STR00497##

[0163] The intermediate IM E (11.9 g, 21.4 mmol), bis(pinacolato)diboron (6.5 g, 25.7 mmol), tris(dibenzylideneacetone)dipalladium (0.2 g, 0.2 mmol), 2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl (0.4, 0.2 mmol), potassium acetate (4.6 g, 47.1 mmol) and 1,4-dioxane (150 mL) were added to a flask, and stirred under reflux at 100° C. for 12 h under nitrogen protection; the resulting reaction solution was cooled to room temperature, dichloromethane and water were added to the reaction solution, liquid separation was performed, the obtained organic phase was washed with water, and dried by anhydrous magnesium sulfate, and a solvent was removed under reduced pressure to give a crude product; and the crude product was purified by silica gel column chromatography using a dichloromethane/n-heptane system to obtain a white solid intermediate IM F (7.74 g, yield: 60%).

[0164] (7) Synthesis of Compound 374

##STR00498##

[0165] The intermediate IM F (7.7 g, 12.8 mmol), 2-(4-biphenyl)-4-chloro-6-phenyl-1,3,5-triazine (3.3 g, 12.2 mmol), tetrakis(triphenylphosphine)palladium (0.28 g, 0.24 mmol), potassium carbonate (3.7 g, 26.9 mmol), and tetrabutylammonium bromide (0.8 g, 2.4 mmol) were added to a flask, and a mixed solvent of toluene (60 mL), ethanol (30 mL) and water (15 mL) was added, and the mixture was heated to 80° C. under nitrogen protection, and stirred for 8 h while maintaining the temperature; then cooling to room temperature, stirring was stopped, the reaction solution was washed with water, the obtained organic phase was separated, and dried by anhydrous magnesium sulfate, and a solvent was removed under reduced pressure to obtain a crude product; and the crude product was purified by silica gel column chromatography using a dichloromethane/n-heptane mixed solvent as a mobile phase to obtain a white solid compound 374 (5.6 g, yield: 65%).

[0166] The above synthesized compounds were subjected to mass spectrometry and the results are shown in Table 6:

TABLE-US-00006 TABLE 6 Mass spectrometric data for compounds Compound 2  m/z = 684.3 Compound 98  m/z = 800.2 Compound 4  m/z = 608.3 [M + H].sup.+ [M + H].sup.+ [M + H].sup.+ Compound 7  m/z = 698.3 Compound 116 m/z = 713.3 Compound 125 m/z = 710.3 [M + H].sup.+ [M + H].sup.+ [M + H].sup.+ Compound 13 m/z = 636.3 Compound 135 m/z = 724.3 Compound 144 m/z = 750.4 [M + H].sup.+ [M + H].sup.+ [M + H].sup.+ Compound 23 m/z = 605.3 Compound 28  m/z = 734.3 Compound 154 m/z = 595.3 [M + H].sup.+ [M + H].sup.+ [M + H].sup.+ Compound 44 m/z = 734.3 Compound 159 m/z = 786.4 Compound 167 m/z = 709.4 [M + H].sup.+ [M + H].sup.+ [M + H].sup.+ Compound 48 m/z = 684.3 Compound 58  m/z = 728.3 Compound 209 m/z = 756.3 [M + H].sup.+ [M + H].sup.+ [M + H].sup.+ Compound 59 m/z = 730.2 Compound 237 m/z = 652.3 Compound 60  m/z = 804.3 [M + H].sup.+ [M + H].sup.+ [M + H].sup.+ Compound 64 m/z = 623.2 Compound 322 m/z = 569.3 Compound 261 m/z = 658.3 [M + H].sup.+ [M + H].sup.+ [M + H].sup.+ Compound 67 m/z = 597.2 Compound 323 m/z = 585.3 Compound 90  m/z = 724.3 [M + H].sup.+ [M + H].sup.+ [M + H].sup.+ Compound 78 m/z = 700.3 Compound 324 m/z = 579.3 Compound 374 m/z = 708.3 [M + H].sup.+ [M + H].sup.+ [M + H].sup.+

[0167] NMR data for compounds are as follows:

[0168] Compound 2:

[0169] .sup.1H-NMR (CD.sub.2Cl.sub.2, 400 MHz): 8.81 (d, 2H), 8.20-8.17 (m, 3H), 8.04-7.97 (m, 3H), 7.86 (d, 2H), 7.66-7.56 (m, 4H), 7.54-7.39 (m, 8H), 7.31 (t, 1H), 2.83 (d, 2H), 2.71 (d, 2H), 2.14 (s, 1H), 2.06 (s, 1H), 1.89 (s, 2H), 1.73 (t, 4H), 1.46 (s, 2H).

[0170] Compound 23:

[0171] .sup.1H-NMIR (CD.sub.2Cl.sub.2, 400 MHz): 8.14 (d, 2H), 8.08-8.06 (m, 2H), 7.86 (t, 2H), 7.78 (d, 1H), 7.70 (s, 1H), 7.63 (d, 4H), 7.52 (t, 4H), 7.47-7.33 (m, 5H), 7.27 (t, 1H), 2.80 (d, 2H), 2.73 (d, 2H), 2.14 (s, 1H), 2.07 (s, 1H), 1.88 (s, 2H), 1.72 (t, 4H), 1.38 (s, 2H).

[0172] Compound 78:

[0173] .sup.1H-NMR (CD.sub.2Cl.sub.2, 400 MHz): 8.79 (d, 2H), 8.34 (s, 1H), 8.29 (d, 1H), 8.20-8.16 (m, 3H), 8.07 (s, 1H), 8.01 (d, 2H), 7.86 (d, 2H), 7.75 (d, 1H), 7.66-7.51 (m, 8H), 7.43-7.38 (m, 1H), 7.30-7.26 (m, 1H), 2.84 (d, 2H), 2.75 (d, 2H), 2.12 (s, 1H), 2.06 (s, 1H), 1.86 (s, 2H), 1.70 (t, 4H), 1.36 (s, 2H).

Example 1: Green Organic Electroluminescent Device

[0174] A green organic electroluminescent device was manufactured by using the following method:

[0175] an anode was prepared by the following process: an ITO substrate with an ITO thickness of 1500 Å was cut into a dimension of 40 mm (length)×40 mm (width)×0.7 mm (thickness) to be prepared into an experimental substrate with a cathode, an anode and an insulating layer pattern by adopting a photoetching process, and surface treatment was performed by ultraviolet ozone and O.sub.2:N.sub.2 plasma to increase the work function of the anode, and the surface of the ITO substrate may be cleaned with an organic solvent to clean impurities and gungo on the surface of the ITO substrate.

[0176] F4-TCNQ was vacuum evaporated on the experimental substrate (the anode) to form a hole injection layer (HIL) having a thickness of 100 Å, and HT-01 was evaporated on the hole injection layer to form a first hole transport layer with a thickness of 850 Å.

[0177] HT-02 was vacuum evaporated on the first hole transport layer to form a second hole transport layer with a thickness of 350 Å.

[0178] A compound 23, GHn1 and Ir(ppy)3 were co-evaporated at a ratio of 50%:45%:5% (an evaporation rate) on the second hole transport layer to form a green light-emitting layer (EML) with a thickness of 400 Å.

[0179] ET-01 and LiQ were mixed at a weight ratio of 1:1 and evaporated to form an electron transport layer (ETL) having a thickness of 300 Å, LiQ was evaporated on the electron transport layer to form an electron injection layer (EIL) having a thickness of 10 Å, and then magnesium (Mg) and silver (Ag) were mixed and vacuum evaporated at an evaporation rate of 1:9 on the electron injection layer to form a cathode with a thickness of 110 Å.

[0180] In addition, CP-01 with a thickness of 650 Å was evaporated on the cathode to form an organic capping layer (CPL), thus completing the manufacture of the entire organic light-emitting device.

Examples 2-10

[0181] The organic electroluminescent devices were manufactured by the same methodas as that in Example 1, except that a mixed component shown in Table 7 below was used instead of the mixed component in Example 1 when the organic light-emitting layer was formed.

Comparative Examples 1-3

[0182] The organic electroluminescent devices were manufactured by the same methodas as that in Example 1, except that a mixed component shown in Table 7 below was used instead of the mixed component in Example 1 when the organic light-emitting layer was formed.

[0183] The structures of main materials used in Examples 1-10 and Comparative examples 1-3 are shown below:

##STR00499## ##STR00500## ##STR00501## ##STR00502##

[0184] The organic electroluminescent devices manufactured in Examples 1-10 and Comparative examples 1-3 were subjected to performance tests under a condition of 20 mA/cm.sup.2, and the test results are shown in Table 7 below.

TABLE-US-00007 TABLE 7 Performance test results of organic electroluminescent device External Light-emitting quantum T95 layer Driving Current Power Chromaticity efficiency service three materials = voltage efficiency efficiency coordinate EQE life Example No. 50%:45%:5% (V) (Cd/A) (lm/W) CIEx, CIEy (%) (h) Example 1 Compound 3.78 80.5 66.9 0.22, 0.73 18.2 216 23:GHn1:Ir(ppy).sub.3 Example 2 Compound 3.76 82.3 68.7 0.22, 0.73 18.8 219 323:GHn1:Ir(ppy).sub.3 Example 3 Compound 3.80 82.8 68.4 0.22, 0.73 19.2 221 324:GHn1:Ir(ppy).sub.3 Example 4 GHp1:Compound 3.77 83.2 69.3 0.22, 0.73 19.3 227 64:Ir(ppy).sub.3 Example 5 GHp1:Compound 3.70 84.5 71.7 0.22, 0.73 18.2 226 67:Ir(ppy).sub.3 Example 6 GHp1:Compound 3.70 87.3 74.1 0.22, 0.73 18.4 232 2:Ir(ppy).sub.3 Example 7 GHp1:Compound 3.69 86.8 73.9 0.22, 0.73 19.1 236 4:Ir(ppy).sub.3 Example 8 GHp1:Compound 3.66 89.8 77.0 0.22, 0.73 19.4 240 7:Ir(ppy).sub.3 Example 9 GHp1:Compound 3.62 88.3 76.6 0.22, 0.73 18.8 237 13:Ir(ppy).sub.3 Example 10 GHp1:Compound 3.70 89.1 75.6 0.22, 0.73 18.6 241 28:Ir(ppy).sub.3 Comparative Compound 3.71 68.2 57.7 0.22, 0.73 16.4 154 example 1 A:GHn1:Ir(ppy).sub.3 Comparative Compound 3.80 73.2 60.5 0.22, 0.73 17.6 152 example 2 B:GHn1:Ir(ppy).sub.3 Comparative GHp1:Compound 3.69 66.9 56.9 0.22, 0.73 16.4 176 example 3 C:Ir(ppy).sub.3

[0185] From the data shown in Table 7, it can be seen that the organic electroluminescent devices manufactured in Examples 1-10 have the advantages that the driving voltages were substantially similar, the luminous efficiency was improved by at least 10%, and the service life of the devices were prolonged by at least 23% compared with the organic electroluminescent devices manufactured in Comparative examples 1-3. It can be seen that when the organic compound of the present disclosure is used as an organic light-emitting layer material of the organic electroluminescent device, in particular a host material, the efficiency performance and the service life of the organic electroluminescent device can be effectively improved.

Example 11: Red Organic Electroluminescent Device

[0186] An anode was prepared by the following process: an ITO substrate with an ITO thickness of 1500 Å was cut into a dimension of 40 mm (length)×40 mm (width)×0.7 mm (thickness) to be prepared into an experimental substrate with a cathode, an anode and an insulating layer pattern by adopting a photoetching process, and surface treatment was performed by ultraviolet ozone and O.sub.2:N.sub.2 plasma to increase the work function of the anode, and the surface of the ITO substrate may be cleaned with an organic solvent to clean impurities and gungo on the surface of the ITO substrate.

[0187] F4-TCNQ was vacuum evaporated on the experimental substrate (the anode) to form a hole injection layer (HIL) with a thickness of 100 Å, and HT-03 was evaporated on the hole injection layer to form a first hole transport layer with a thickness of 850 Å.

[0188] HT-04 was vacuum evaporated on the first hole transport layer to form a second hole transport layer with a thickness of 800 Å.

[0189] A compound 44 and Ir(piq).sub.2(acac) were co-evaporated at a ratio of 95%:5% (an evaporation rate) on the second hole transport layer to form a red light-emitting layer (EML) with a thickness of 350 Å.

[0190] ET-01 and LiQ were mixed at a weight ratio of 1:1 and evaporated to form an electron transport layer (ETL) having a thickness of 300 Å, LiQ was evaporated on the electron transport layer to form an electron injection layer (EIL) with a thickness of 10 Å, and then magnesium (Mg) and silver (Ag) were mixed and vacuum evaporated at an evaporation rate of 1:9 on the electron injection layer to form a cathode with a thickness of 105 Å.

[0191] In addition, CP-01 with a thickness of 650 Å was evaporated on the cathode to form an organic capping layer (CPL), thus completing the manufacture of an organic light-emitting device.

Examples 12-18

[0192] The organic electroluminescent devices were manufactured by the same methodas as that in Example 11, except that a mixed component shown in Table 8 below was used instead of the mixed component in Example 11 when the light-emitting layer was formed.

Comparative Examples 4-5

[0193] The organic electroluminescent devices were manufactured by the same methodas as that in Example 11, except that a mixed component shown in Table 8 below was used instead of the mixed component in Example 11 when the light-emitting layer was formed.

[0194] The structures of main materials used in Examples 11-18 and Comparative examples 4-5 are shown below:

##STR00503## ##STR00504## ##STR00505##

[0195] The organic electroluminescent devices manufactured in Examples 11-18 and Comparative examples 4-5 were subjected to performance tests under a condition of 20 mA/cm.sup.2, and the test results are shown in Table 8 below.

TABLE-US-00008 TABLE 8 Performance test results of organic electroluminescent device External quantum T95 Driving Current Power Chromaticity efficiency service Compound:Ir(piq).sub.2 voltage efficiency efficiency coordinate EQE life Example No. (acac) = 95%:5% (V) (Cd/A) (lm/W) CIEx, CIEy (%) (h) Example 11 Compound 44 3.78 39.0 32.4 0.68, 0.32 27.4 430 Example 12 Compound 48 3.74 39.2 32.9 0.68, 0.32 27.3 428 Example 13 Compound 58 3.73 41.5 34.9 0.68, 0.32 28.4 401 Example 14 Compound 59 3.76 38.6 32.2 0.68, 0.32 26.0 458 Example 15 Compound 60 3.71 41.6 35.2 0.68, 0.32 27.9 387 Example 16 Compound 78 3.70 40.8 34.6 0.68, 0.32 27.6 412 Example 17 Compound 90 3.72 38.9 32.8 0.68, 0.32 26.5 452 Example 18 Compound 374 3.73 39.4 33.2 0.68, 0.32 26.8 445 Comparative Compound D 4.05 27.7 21.4 0.68, 0.32 20.2 270 example 4 Comparative Compound E 3.78 28.5 23.6 0.68, 0.32 19.4 270 example 5

[0196] From the data shown in Table 8, it can be seen that the organic electroluminescent devices manufactured in Examples 11-18 have the advantages that the driving voltages are similar, the luminous efficiency of the devices were improved by at least 35%, and the service life was prolonged by at least 43% compared with the organic electroluminescent devices manufactured in Comparative example 5. The organic electroluminescent devices manufactured in Examples 11-18 have the advantages that the driving voltage was reduced by at least 7%, the luminous efficiency was improved by at least 39%, and the service life was prolonged by at least 43% compared with Comparative example 4. It can be seen that when the compounds of the present disclosure are used as an organic light-emitting layer material of the organic electroluminescent device, in particular a host material, the efficiency performance and the service life performance of the organic electroluminescent device can be improved.

[0197] In the compounds of the present disclosure, spiro[adamantane-fused fluorenyl] as a part of a core is a large planar conjugated structure, which has a strong rigidity and thus the compounds of the present disclosure have a high first triplet energy level, conjugated connection with a fused heteroaromatic ring in the compounds has a better hole transport ability, adamantyl is spiro-bonded to fluorenyl, so that the electron cloud density of the large planar conjugate structure can be greatly increased by a hyperconjugation effect, enhancing the hole mobility of the compounds, helping to promote the transport balance of holes and electrons in the light-emitting layer, and improving the efficiency performance of the organic electroluminescent device, and thus the compounds of the present disclosure are suitable as the host material of the organic light-emitting layer in the organic electroluminescent device. Not only that, the improvement of the hole transport performance of the compounds can improve the recombination rate of electrons and holes in the organic light-emitting layer, and reduce or avoid the transport of electrons to the hole transport layer through the organic light-emitting layer, and then, the hole transport layer material may be effectively protected from the impact of electrons, improving the service life of the organic electroluminescent device. Moreover, adamantyl spiro-bonded to fluorenyl has a large space volume and strong rigidity, thus, it is possible to reduce the interaction force between large planar conjugated structures, reduce intermolecular π-π stacking, and adjust the degree of intermolecular stacking, thus enabling the compounds to have a more stable amorphous form during film formation, and improving the film-forming properties of the compounds, and thus further improving the service life of the organic electroluminescent device.

[0198] Preferred examples of the present disclosure have been described in detail above, but the present disclosure is not limited to specific details in the above-described examples, and many simple modifications may be made to the technical solutions of the present disclosure within the technical idea of the present disclosure, and these simple modifications are all within the scope of protection of the present disclosure. In addition, it should be noted that various specific technical features described in the above specific examples may be combined in any suitable manner without contradiction. In order to avoid unnecessary repetition, the present disclosure does not further describe the various possible combinations.