SUPERCRITICAL-STATE CLEANING SYSTEM AND METHODS

Abstract

Disclosed is a supercritical-state cleaning system, comprising a cleaning chamber, a gas booster apparatus, a first heating apparatus, and a carbon dioxide supply apparatus. The cleaning chamber is separately connected to the first heating apparatus and the carbon dioxide supply apparatus. A vacuum pump set is connected to the cleaning chamber. Compared with the prior art, in the Invention, air introduced when a workpiece enters a cleaning chamber is completely removed, so as to prevent mixing of CO.sub.2 and air, thereby improving a cleaning effect.

Claims

1. A cleaning method using a supercritical-state cleaning system, comprising the following steps: S1. starting a vacuum pump set to vacuumize a cleaning chamber in which a target workpiece is placed; S2. after a vacuum degree in the cleaning chamber satisfies a set requirement, turning off the vacuum pump set; S3. making carbon dioxide in a storage tank pass through a buffer tank to enter the cleaning chamber, and starting a gas booster apparatus; S4. when a pressure in the cleaning chamber reaches a set pressure, stopping the carbon dioxide from entering the cleaning chamber, turning off a pipe between the cleaning chamber and the outside, and starting a first heating apparatus to reach a set temperature in the cleaning chamber, so that the carbon dioxide enters a supercritical state; and S5. cleaning the target workpiece by using the carbon dioxide in a supercritical state.

2. A method for recycling carbon dioxide using the supercritical-state cleaning system, comprising: making carbon dioxide in a cleaning chamber pass through a buffer tank to enter a storage tank, wherein a gas booster apparatus keeps the carbon dioxide in the buffer tank in a gaseous state.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0030] The sole FIGURE is a schematic structural diagram of a cleaning system according to an embodiment of the Invention.

REFERENCE NUMERALS

[0031] 1 is a vacuum pump set; 2 is a first pipe; 3 is a first pressure measurement apparatus; 4 is a cleaning chamber; 5 is a first heating apparatus; 6 is a target workpiece; 7 is a second pipe; 8 is a third pipe; 9 is a fourth pipe; 10 is a fifth pipe; 11 is a gas booster apparatus; 12 is a sixth valve; 13 is a seventh valve; 14 is a second pressure measurement apparatus; 15 is a buffer tank; 16 is a third pressure measurement apparatus; 17 is a storage tank; and 18 is a second heating apparatus.

DETAILED DESCRIPTION OF THE INVENTION

[0032] The Invention is described in detail below with reference to the accompanying drawings and specific embodiments. The embodiments are implemented based on the technical solutions of the Invention, and detailed implementations and specific operating processes are given, but the protection scope of the Invention is not limited to the following embodiments.

Embodiment

[0033] A supercritical-state cleaning system is provided. In the system, a heat treatment workpiece is cleaned by means of carbon dioxide in a supercritical state that can dissolve non-polar organic matter or organic matter having relatively low polarity. Inexpensive carbon dioxide (dry ice) is used as a cleaning medium, and the temperature and pressure are adjusted to switch the carbon dioxide among a liquid state, a gaseous state, and a supercritical state, so as to satisfy a cleaning requirement of the heat treatment workpiece.

[0034] CO.sub.2 is in a supercritical state when the temperature is higher than 31.1 C. and the pressure is greater than 73 bar. The density of a supercritical fluid is greater than the density of a gas by hundreds of times, and has a value close to that of the density of a liquid. The viscosity of the supercritical fluid is less than that of a liquid by two orders of magnitude, and has a value close to that of the viscosity of gas. The diffusion coefficient of the supercritical fluid ranges between diffusion coefficients of a gas and a liquid, and is 1/100 as large as that of a gas but is greater than that of a liquid by hundreds of times. As can be seen here, the supercritical fluid has a density close to that of a liquid and therefore has a characteristic of dissolving a solute like a liquid. Moreover, the supercritical fluid has a characteristic of easy diffusion like a gas. The low viscosity and high diffuseness of the supercritical fluid facilitate the diffusion of a substance dissolved in the supercritical fluid and the permeation of the substance to a solid matrix. When a substance is in a supercritical state, the density of the substance changes significantly provided that the pressure and temperature change slightly, and the solubility of the substance changes accordingly. These characteristics are utilized in this patent to achieve the objective of this patent.

[0035] In this patent, CO.sub.2 is switched from one state to another to achieve the objective of cleaning a workpiece. CO.sub.2 is selected as a cleaning medium as CO.sub.2 exists in nature and is safe, not flammable and explosive, non-toxic, and non-corrosive, and it is easy to implement a supercritical state of CO.sub.2.

[0036] A vacuumization system requires to be mounted on cleaning equipment to completely remove air introduced when a workpiece enters the cleaning equipment, so as to prevent mixing of CO.sub.2 and air to mitigate a cleaning effect. After vacuumization, carbon dioxide is added to a cleaning chamber, and a booster system is used to increase the pressure in the cleaning chamber to 73 bar or above. CO.sub.2 in the cleaning chamber is then heated to keep the temperature above 31.1 C. In this case, CO.sub.2 is in a supercritical state. CO.sub.2 in a supercritical state can dissolve non-polar organic matter or organic matter having relatively low polarity, and therefore can dissolve quenching oil attached on the surface of the workpiece.

[0037] After cleaning ends, CO.sub.2 in the cleaning chamber is discharged to a specific buffer tank. The pressure in the buffer tank is controlled to keep CO.sub.2 in a gaseous state. In this way, quenching oil dissolved when CO.sub.2 is in a supercritical state can be released. Eventually, gaseous CO.sub.2 is transferred to a storage tank through the booster system for a next cycle of work.

[0038] No other gas or liquid is mixed in the entire cleaning process, so that perfect recycling and reuse are implemented, energy resources are saved, and an optimal cleaning effect can be achieved, thereby bringing economic benefits to users.

[0039] As shown in the sole FIGURE, the system comprises a cleaning chamber 4, a gas booster apparatus 11, a first heating apparatus 5, and a carbon dioxide supply apparatus. The cleaning chamber 4 is separately connected to the first heating apparatus 5 and the carbon dioxide supply apparatus. A vacuum pump set 1 is connected to the cleaning chamber 4. The vacuum pump set 1 and the cleaning chamber 4 are connected through a first pipe 2. A first valve 21 is disposed on the first pipe 2.

[0040] The carbon dioxide supply apparatus comprises a storage tank 17 and a buffer tank 15 connected to each other. The gas booster apparatus 11 is disposed on a pipe between the buffer tank 15 and the cleaning chamber 4. Carbon dioxide flows to the buffer tank 15 from the storage tank 17, is boosted by the gas booster apparatus 11, and then enters the cleaning chamber 4.

[0041] Pipes in the system comprise: a fifth pipe 10 with two ends respectively connected to the storage tank 17 and the buffer tank 15, a third pipe 8 with two ends respectively connected to the buffer tank 15 and the cleaning chamber 4, a second pipe 7 with two ends respectively connected to the cleaning chamber 4 and the buffer tank 15, and a fourth pipe 9 with two ends respectively connected to the buffer tank 15 and the storage tank 17. The gas booster apparatus 11 is connected to the third pipe 8 and the fourth pipe 9. The gas booster apparatus 11 is disposed at the middle part of the buffer tank 15, so as to ensure that no waste liquid impurity is contained in the third pipe 8 and the fourth pipe 9. A valve is disposed on each of the second pipe 7, the third pipe 8, the fourth pipe 9, and the fifth pipe 10.

[0042] Before cleaning, the carbon dioxide is output from the storage tank 17 and sequentially passes through the fifth pipe 10, the buffer tank 15, and the third pipe 8 to enter the cleaning chamber 4. After cleaning, the carbon dioxide is output from the cleaning chamber 4 and sequentially passes through the second pipe 7, the buffer tank 15, and the fourth pipe 9 to enter the storage tank 17.

[0043] A first pressure measurement apparatus 3 is connected to the cleaning chamber 4. A second pressure measurement apparatus 14 is connected to the buffer tank 14. A second heating apparatus 18 and a third pressure measurement apparatus 16 are connected to the storage tank 17.

[0044] A dry ice addition port 13 is disposed above the buffer tank 15, and a waste liquid recycle port 12 is disposed at the bottom of the buffer tank 15.

[0045] A cleaning method using the cleaning system in this embodiment comprises the following steps:

S1. starting the vacuum pump set 1 to vacuumize the cleaning chamber 4 in which a target workpiece 6 is placed;
S2. when a vacuum degree in the cleaning chamber 4 satisfies a set requirement, turning off the vacuum pump set 1;
S3. making carbon dioxide in the storage tank 17 pass through the buffer tank 15 to enter the cleaning chamber 4, and starting the gas booster apparatus 11;
S4. when a pressure in the cleaning chamber 4 reaches a set pressure, stopping the carbon dioxide from entering the cleaning chamber 4, turning off the pipe between the cleaning chamber 4 and the outside, and starting the first heating apparatus 5 to reach a set temperature in the cleaning chamber 4, so that the carbon dioxide enters a supercritical state; and
S5. cleaning the target workpiece 6 by using the carbon dioxide in a supercritical state.

[0046] A method for recycling carbon dioxide using the supercritical-state cleaning system comprises: making the carbon dioxide in the cleaning chamber 4 pass through the buffer tank 15 to enter the storage tank 17, wherein the gas booster apparatus 11 keeps the carbon dioxide in the buffer tank 15 in a gaseous state.

[0047] The vacuum pump set 1 is connected to the cleaning chamber 4 through the first valve 2.

[0048] A specific operation process is as follows:

[0049] First, the target workpiece 6 is placed in the cleaning chamber 4. The valve on the first pipe 2 and the vacuum pump set 1 are then started. Vacuumization processing is performed on the cleaning chamber 4 to eliminate air introduced by the target workpiece 6, to prevent CO.sub.2 added in a next step from being polluted and ensure the cleanliness of CO.sub.2 in the entire cleaning system.

[0050] When the first pressure measurement apparatus 3 detects that a vacuum degree in the cleaning chamber 4 satisfies a set requirement, the valve on the first pipe 2 and the vacuum pump set 1 are turned off. The valve on the fifth pipe 10, the valve on the third pipe 8, and the gas booster apparatus 11 are then turned on to transfer CO.sub.2 in the storage tank 17 to the cleaning chamber 4 via the buffer tank 15, to clean the target workpiece 6.

[0051] When the first pressure measurement apparatus 3 detects that the pressure in the cleaning chamber 4 reaches a set pressure (greater than 73 bar), transfer of CO.sub.2 is stopped. The first heating apparatus 5 is then started to control the temperature in the cleaning chamber 4 to reach a set temperature (greater than 31.1 C.). In this case, it is ensured that CO.sub.2 in the cleaning chamber 4 is in a supercritical state, thereby satisfying a requirement of cleaning the target workpiece 6.

[0052] After cleaning is completed, the valve on the second pipe 7, the valve on the fourth pipe 9, and the gas booster apparatus 11 are turned on. CO.sub.2 in the cleaning chamber 4 is transferred to the storage tank 17 via the buffer tank 15, to complete the cleaning process.

[0053] To save space, the second heating apparatus 18 and the third pressure measurement apparatus 16 are controlled to keep CO.sub.2 in a liquid state in the storage tank 17.

[0054] The second pressure measurement apparatus 14 is used to control CO.sub.2 in the buffer tank 15 to be in a gaseous state. In this way, CO.sub.2 switches from a supercritical state in the cleaning chamber 4 to a gaseous state in the buffer tank 15. Quenching oil that is dissolved when CO.sub.2 is in a supercritical state is released to the buffer tank 15, and the sixth valve 12 is regularly opened to recycle the quenching oil. After the equipment operates a long time, to compensate for loss of CO.sub.2 during use, the seventh valve 13 may be used to complete a supplement.