CERAMIC COLOURS

Abstract

The invention relates to ceramic colors comprising effect pigments and a silicon comprising polymer for decoration of metallic, ceramic and glassy articles and to a process for the preparation of a ceramic glaze.

Claims

1. A process for the preparation of glazed articles comprising: (a) mixing at least one effect pigment comprising on a flake-form substrate and/or uncoated flake-form substrates with a refractive index R.I.>1.5, at least one silicon comprising polymer, optionally a solvent, optionally a binder, and optionally an absorptive ceramic pigment, to prepare a ceramic color, (b) printing or coating the ceramic color obtained in (a) on a ceramic or metallic body, (c) drying the ceramic or metallic body obtained in (b), (d) firing the ceramic or metallic body obtained in (c).

2. The process according to claim 1, wherein in (d) the ceramic body is fired at a temperature of 700-1300 C. or the metallic body is fired at a temperature of 450-950 C.

3. The process according to claim 1, having a proportion of effect pigment in the ceramic color of at least 0.1% by weight based on the silicon comprising polymer.

4. The process according to claim 1, wherein the effect pigments are based on flake-form substrates that are synthetic mica flakes, natural mica flakes, glass flakes, Al.sub.2O.sub.3 flakes, SiO.sub.2 flakes, Fe.sub.2O.sub.3 flakes, B.sub.4C flakes, TiO.sub.2 flakes, SiC flakes, Si.sub.xN.sub.yC.sub.z flakes with x=0.5-1.0; y=0.25-0.5; z=0.25-0.5, BN flakes, or graphite flakes.

5. The process according to claim 1, wherein the flake-form substrates of the effect pigments are covered with one or more layers of metal oxide(s), metal sulfides, rare-earth metal oxides and/or metal(s) or mixtures thereof.

6. The process according to claim 1, wherein the flake-form substrates of the effect pigments are covered on the surface with one or more layers selected from the group TiO.sub.2, Fe.sub.2O.sub.3, ZrO.sub.2, SnO.sub.2, TiO.sub.2/Fe.sub.2O.sub.3, Fe.sub.2TiO.sub.5, FeTiO.sub.3, FeOOH, Fe.sub.3O.sub.4, Cr.sub.2O.sub.3 and TiO.sub.x, where x=1.50-1.95.

7. The process according to claim 1, wherein the flake-form substrates have a particle thickness of 0.05-5.0 m.

8. The process according to claim 1, wherein the ceramic color comprises as silicon comprising polymer at least one polysilazane, at least one polysiloxane and/or at least one polysilsesquioxane.

9. The process according to claim 1, wherein ceramic color comprises a printing oil.

10. The process according to claim 1, wherein the effect pigments are: substrate flake+TiO.sub.2 substrate flake+Fe.sub.2O.sub.3 substrate flake+Fe.sub.3O.sub.4 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+FeTiO.sub.3 substrate flake+Fe.sub.2TiO.sub.5 substrate flake+ZrO.sub.2 substrate flake+ZnO substrate flake+SnO.sub.2 substrate flake+Cr.sub.2O.sub.3 substrate flake+Ce.sub.2O.sub.3 substrate flake+TiO.sub.x (reduced), where x=1.50-1.95 substrate flake+TiO.sub.2+Fe.sub.2O.sub.3 substrate flake+TiO.sub.2+Fe.sub.3O.sub.4 substrate flake+Fe.sub.2O.sub.3+TiO.sub.2 substrate flake+TiO.sub.2+SiO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2+Al.sub.2O.sub.3+TiO.sub.2 substrate flake+Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+TiO.sub.2+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+TiO.sub.2+SiO.sub.2 substrate flake+TiO.sub.2+Al.sub.2O.sub.3 substrate flake+TiO.sub.2+MgOSiO.sub.2+TiO.sub.2 substrate flake+Fe.sub.2O.sub.3+MgOSiO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+MgOSiO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+MgOSiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+MgOSiO.sub.2+TiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+TiO.sub.2+MgOSiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+SnO.sub.2+TiO.sub.2+SiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+SnO.sub.2+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3+SiO.sub.2+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3 substrate flake+Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2 substrate flake+Fe.sub.2O.sub.3+SnO.sub.2+Fe.sub.2O.sub.3 substrate flake+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3. substrate flake+Fe.sub.2TiO.sub.5+SnO.sub.2+Fe.sub.2TiO.sub.5 or substrate flake+Fe.sub.2TiO.sub.5+SiO.sub.2+Fe.sub.2TiO.sub.5.

11. The process according to claim 1, wherein the effect pigments on the substrate flake have a first low-refractive-index layer LRL comprising Al.sub.2O.sub.3, SiO.sub.2, zirconium silicate ZrSiO.sub.4, sintered mullite 3Al.sub.2O.sub.32SiO.sub.2, fused mullite 2Al.sub.2O.sub.3SiO.sub.2, alkaline-earth metal silicate MSiO.sub.3, where M=Mg.sup.2+, Ca.sup.2+, Sr.sup.2+ or Ba.sup.2+, or M.sub.2Si.sub.3O.sub.8, where M=Mg.sup.2+, Ca.sup.2+, Sr.sup.2+ or Ba.sup.2+, and are at least one of the following group of pigments: substrate flake+LRL+TiO.sub.2 substrate flake+LRL+Fe.sub.2O.sub.3 substrate flake+LRL+Fe.sub.3O.sub.4 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+FeTiO.sub.3 substrate flake+LRL+Fe.sub.2TiO.sub.5 substrate flake+LRL+ZrO.sub.2 substrate flake+LRL+ZnO substrate flake+LRL+SnO.sub.2 substrate flake+LRL+Cr.sub.2O.sub.3 substrate flake+LRL+Ce.sub.2O.sub.3 substrate flake+LRL+TiO.sub.x (reduced), where x=1.50-1.95 substrate flake+LRL+TiO.sub.2+Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+Fe.sub.3O.sub.4 substrate flake+LRL+Fe.sub.2O.sub.3+TiO.sub.2 substrate flake+LRL+TiO.sub.2+SiO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2+Al.sub.2O.sub.3+TiO.sub.2 substrate flake+LRL+Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+SiO.sub.2 substrate flake+LRL+TiO.sub.2+Al.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+MgOSiO.sub.2+TiO.sub.2 substrate flake+LRL+Fe.sub.2O.sub.3+MgOSiO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+MgOSiO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+MgOSiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+MgOSiO.sub.2+TiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+MgOSiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+SnO.sub.2+TiO.sub.2+SiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+LRL+SnO.sub.2+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+LRL+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3+SiO.sub.2+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3 substrate flake+LRL+Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2 substrate flake+LRL+Fe.sub.2O.sub.3+SnO.sub.2+Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3 substrate flake+LRL+Fe.sub.2TiO.sub.5+SnO.sub.2+Fe.sub.2TiO.sub.5 or substrate flake+LRL+Fe.sub.2TiO.sub.5+SiO.sub.2+Fe.sub.2TiO.sub.5.

12. A ceramic color comprising at least one silicon comprising polymer and at least one effect pigment based on flake-form substrates selected from the group consisting of Al.sub.2O.sub.3 flake, SiC flakes, B.sub.4C flakes, BN flakes, graphite flakes, TiO.sub.2 flakes, and Fe.sub.2O.sub.3 flakes and/or at least one uncoated flake-form substrate with a refractive index R.I.>1.5 selected from the group consisting of Al.sub.2O.sub.3 flake, SiC flakes, Si.sub.xN.sub.yC.sub.z flakes with x=0.5-1.0; y=0.25-0.5; z=0.25-0.5, B.sub.4C flakes, BN flakes, graphite flakes, TiO.sub.2 flakes, and Fe.sub.2O.sub.3 flakes.

13. The ceramic color according to claim 12, having a proportion of effect pigment in the ceramic color of at least 0.1% by weight based on the silicon comprising polymer.

14. The ceramic color according to claim 12, wherein the silicon comprising polymer is at least one polysilazane, at least one polysiloxane and/or at least one polysilsesquioxane.

15. In unfired fired bricks, unfired or fired earthenware, ceramicware, ceramic glazes, decorative tiles, porcelain glazes, metallic decoration or enamel, comprising a ceramic color, the improvement wherein the ceramic color is one according to claim 12.

16. In decorative elements on articles exhibiting an outer surface of porcelain, china, bone china, ceramic, glass or enamel, comprising a ceramic color, the improvement wherein the ceramic color is one according to claim 12.

17. The process according to claim 1, where (a) comprises firing the ceramic or metallic body obtained in (c) at a temperature of 450 C.-1300 C.

Description

EXAMPLES

[0205] For the preparation of ceramic colors, the effect pigments according to Examples 1 to 298 of Table 1 are weighed out and homogenised with the corresponding amount of a polysilsesquioxane and printing oil 221 ME by Ferro.

[0206] The polysilsesquioxane has a resulting solid content of 26% SiO.sub.2 after firing.

[0207] The pearlescent pigments used in the examples are all commercially available and have the compositions listed in Table 2 (in the Particle size column, the d.sub.10-d.sub.90 value is measured using a Malvern is indicated in each case):

[0208] The printing pastes obtained are applied to tiles by means of doctor blade and screen printing. In all cases, the printed tile is dried in a drying cabinet or fume hood at temperatures of 60-110 C. in order to evaporate the solvent present in the printing oil.

[0209] The printed and dried tiles are then fired in a firing furnace by means of a temperature profile in accordance with FIG. 1. [0210] 180 min: heating to 1100 C., [0211] 3 min: holding at 1100 C., [0212] 120 min: rapid cooling to 600 C., [0213] 300 min: slow cooling to room temperature.

BRIEF DESCRIPTION OF THE DRAWING

[0214] The temperature program as a function of time is depicted in FIG. 1.

[0215] The glazed tiles of the examples according to the invention are distinguished by the fact that the desired optical effects are stable and accessible in a reproducible manner in respective high-temperature applications 500-1300 C.

TABLE-US-00001 TABLE 1 W.sub.Pigm after Screen W.sub.Pigm in Firing in Example Pigment Pearlescent Polysilses- Printing Polymer Polysilses- No. [g] Pigment Name quioxane [g] Medium [g] [%] quioxane [%] 1 0.01 Xirallic 1 2 0.99 3.65 Crystal Silver (Merck KGaA) 2 0.15 Xirallic 0.5 2 23.08 53.17 Crystal Silver (Merck KGaA)) 3 0.3 Xirallic 0.25 2 54.55 81.96 Crystal Silver (Merck KGaA) 4 0.5 Xirallic 0.05 2 90.91 97.43 Crystal Silver (Merck KGaA) 5 0.01 Xirallic 1 3 0.99 3.65 Crystal Silver (Merck KGaA) 6 0.15 Xirallic 0.5 3 23.08 53.17 Crystal Silver (Merck KGaA) 7 0.3 Xirallic 0.25 3 54.55 81.96 Crystal Silver (Merck KGaA) 8 0.5 Xirallic 0.05 3 90.91 97.43 Crystal Silver (Merck KGaA) 9 0.01 Xirallic 2 2 0.50 1.86 Crystal Silver (Merck KGaA) 10 0.15 Xirallic 1.5 2 9.09 27.46 Crystal Silver (Merck KGaA) 11 0.3 Xirallic 1 2 23.08 53.17 Crystal Silver (Merck KGaA) 12 0.5 Xirallic 0.5 2 50.00 79.10 Crystal Silver (Merck KGaA) 13 0.01 Xirallic 0.01 2 50.00 79.10 Crystal Silver (Merck KGaA) 14 0.15 Xirallic 3 2 4.76 15.91 Crystal Silver (Merck KGaA) 15 0.3 Xirallic 1.2 2 20.00 48.62 Crystal Silver (Merck KGaA) 16 0.5 Xirallic 0.7 2 41.67 73.00 Crystal Silver (Merck KGaA) 17 4.5 Xirallic 0.5 2 90.00 97.15 Crystal Silver (Merck KGaA) 18 0.5 Xirallic 0.25 2 66.67 88.33 Crystal Silver (Merck KGaA) 19 4.9 Xirallic 0.1 2 98.00 99.46 Crystal Silver (Merck KGaA) 20 0.01 Iriodin 103 1 2 0.99 3.65 (Merck KGaA) 21 0.15 Iriodin 103 0.5 2 23.08 53.17 (Merck KGaA) 22 0.3 Iriodin 103 0.25 2 54.55 81.96 (Merck KGaA) 23 0.5 Iriodin 103 0.05 2 90.91 97.43 (Merck KGaA) 24 0.01 Iriodin 103 1 3 0.99 3.65 (Merck KGaA) 25 0.15 Iriodin 103 0.5 3 23.08 53.17 (Merck KGaA) 26 0.3 Iriodin 103 0.25 3 54.55 81.96 (Merck KGaA) 27 0.5 Iriodin 103 0.05 3 90.91 97.43 (Merck KGaA) 28 0.01 Iriodin 103 2 2 0.50 1.86 (Merck KGaA) 29 0.15 Iriodin 103 1.5 2 9.09 27.46 (Merck KGaA) 30 0.3 Iriodin 103 1 2 23.08 53.17 (Merck KGaA) 31 0.5 Iriodin 103 0.5 2 50.00 79.10 (Merck KGaA) 32 0.01 Iriodin 103 0.01 2 50.00 79.10 (Merck KGaA) 33 0.15 Iriodin 103 3 2 4.76 15.91 (Merck KGaA) 34 0.3 Iriodin 103 1.2 2 20.00 48.62 (Merck KGaA) 35 0.5 Iriodin 103 0.7 2 41.67 73.00 (Merck KGaA) 36 4.5 Iriodin 103 0.5 2 90.00 97.15 (Merck KGaA) 37 0.5 Iriodin 103 0.25 2 66.67 88.33 (Merck KGaA) 38 4.9 Iriodin 103 0.1 2 98.00 99.46 (Merck KGaA) 39 0.01 Iriodin 305 1 2 0.99 3.65 (Merck KGaA) 40 0.15 Iriodin 305 0.5 2 23.08 53.17 (Merck KGaA) 41 0.3 Iriodin 305 0.25 2 54.55 81.96 (Merck KGaA) 42 0.5 Iriodin 305 0.05 2 90.91 97.43 (Merck KGaA) 43 0.01 Iriodin 305 1 3 0.99 3.65 (Merck KGaA) 44 0.15 Iriodin 305 0.5 3 23.08 53.17 (Merck KGaA) 45 0.3 Iriodin 305 0.25 3 54.55 81.96 (Merck KGaA) 46 0.5 Iriodin 305 0.05 3 90.91 97.43 (Merck KGaA) 47 0.01 Iriodin 305 2 2 0.50 1.86 (Merck KGaA) 48 0.15 Iriodin 305 1.5 2 9.09 27.46 (Merck KGaA) 49 0.3 Iriodin 305 1 2 23.08 53.17 (Merck KGaA) 50 0.5 Iriodin 305 0.5 2 50.00 79.10 (Merck KGaA) 51 0.01 Iriodin 305 0.01 2 50.00 79.10 (Merck KGaA) 52 0.15 Iriodin 305 3 2 4.76 15.91 (Merck KGaA) 53 0.3 Iriodin 305 1.2 2 20.00 48.62 (Merck KGaA) 54 0.5 Iriodin 305 0.7 2 41.67 73.00 (Merck KGaA) 55 4.5 Iriodin 305 0.5 2 90.00 97.15 (Merck KGaA) 56 0.5 Iriodin 305 0.25 2 66.67 88.33 (Merck KGaA) 57 4.9 Iriodin 305 0.1 2 98.00 99.46 (Merck KGaA) 58 0.01 Iriodin 4504 1 2 0.99 3.65 Lava Red (Merck KGaA) 59 0.15 Iriodin 4504 0.5 2 23.08 53.17 Lava Red (Merck KGaA) 60 0.3 Iriodin 4504 0.25 2 54.55 81.96 Lava Red (Merck KGaA) 61 0.5 Iriodin 4504 0.05 2 90.91 97.43 Lava Red (Merck KGaA) 62 0.01 Iriodin 4504 1 3 0.99 3.65 Lava Red (Merck KGaA) 63 0.15 Iriodin 4504 0.5 3 23.08 53.17 Lava Red (Merck KGaA) 64 0.3 Iriodin 4504 0.25 3 54.55 81.96 Lava Red (Merck KGaA) 65 0.5 Iriodin 4504 0.05 3 90.91 97.43 Lava Red (Merck KGaA) 66 0.01 Iriodin 4504 2 2 0.50 1.86 Lava Red (Merck KGaA) 67 0.15 Iriodin 4504 1.5 2 9.09 27.46 Lava Red (Merck KGaA) 68 0.3 Iriodin 4504 1 2 23.08 53.17 Lava Red (Merck KGaA) 69 0.5 Iriodin 4504 0.5 2 50.00 79.10 Lava Red (Merck KGaA) 70 0.01 Iriodin 4504 0.01 2 50.00 79.10 Lava Red (Merck KGaA) 71 0.15 Iriodin 4504 3 2 4.76 15.91 Lava Red (Merck KGaA) 72 0.3 Iriodin 4504 1.2 2 20.00 48.62 Lava Red (Merck KGaA) 73 0.5 Iriodin 4504 0.7 2 41.67 73.00 Lava Red (Merck KGaA) 74 4.5 Iriodin 4504 0.5 2 90.00 97.15 Lava Red (Merck KGaA) 75 0.5 Iriodin 4504 0.25 2 66.67 88.33 Lava Red (Merck KGaA) 76 4.9 Iriodin 4504 0.1 2 98.00 99.46 Lava Red (Merck KGaA) 77 0.01 Iriodin 9219 1 2 0.99 3.65 (Merck KGaA) 78 0.15 Iriodin 9219 0.5 2 23.08 53.17 (Merck KGaA) 79 0.3 Iriodin 9219 0.25 2 54.55 81.96 (Merck KGaA) 80 0.5 Iriodin 9219 0.05 2 90.91 97.43 (Merck KGaA) 81 0.01 Iriodin 9219 1 3 0.99 3.65 (Merck KGaA) 82 0.15 Iriodin 9219 0.5 3 23.08 53.17 (Merck KGaA) 83 0.3 Iriodin 9219 0.25 3 54.55 81.96 (Merck KGaA) 84 0.5 Iriodin 9219 0.05 3 90.91 97.43 (Merck KGaA) 85 0.01 Iriodin 9219 2 2 0.50 1.86 (Merck KGaA) 86 0.15 Iriodin 9219 1.5 2 9.09 27.46 (Merck KGaA) 87 0.3 Iriodin 9219 1 2 23.08 53.17 (Merck KGaA) 88 0.5 Iriodin 9219 0.5 2 50.00 79.10 (Merck KGaA) 89 0.01 Iriodin 9219 0.01 2 50.00 79.10 (Merck KGaA) 90 0.15 Iriodin 9219 3 2 4.76 15.91 (Merck KGaA) 91 0.3 Iriodin 9219 1.2 2 20.00 48.62 (Merck KGaA) 92 0.5 Iriodin 9219 0.7 2 41.67 73.00 (Merck KGaA) 93 4.5 Iriodin 9219 0.5 2 90.00 97.15 (Merck KGaA) 94 0.5 Iriodin 9219 0.25 2 66.67 88.33 (Merck KGaA) 95 4.9 Iriodin 9219 0.1 2 98.00 99.46 (Merck KGaA) 96 0.01 Iriodin 9444 1 2 0.99 3.65 (Merck KGaA) 97 0.15 Iriodin 9444 0.5 2 23.08 53.17 (Merck KGaA) 98 0.3 Iriodin 9444 0.25 2 54.55 81.96 (Merck KGaA) 99 0.5 Iriodin 9444 0.05 2 90.91 97.43 (Merck KGaA) 100 0.01 Iriodin 9444 1 3 0.99 3.65 (Merck KGaA) 101 0.15 Iriodin 9444 0.5 3 23.08 53.17 (Merck KGaA) 102 0.3 Iriodin 9444 0.25 3 54.55 81.96 (Merck KGaA) 103 0.5 Iriodin 9444 0.05 3 90.91 97.43 (Merck KGaA) 104 0.01 Iriodin 9444 2 2 0.50 1.86 (Merck KGaA) 105 0.15 Iriodin 9444 1.5 2 9.09 27.46 (Merck KGaA) 106 0.3 Iriodin 9444 1 2 23.08 53.17 (Merck KGaA) 107 0.5 Iriodin 9444 0.5 2 50.00 79.10 (Merck KGaA) 108 0.01 Iriodin 9444 0.01 2 50.00 79.10 (Merck KGaA) 109 0.15 Iriodin 9444 3 2 4.76 15.91 (Merck KGaA) 110 0.3 Iriodin 9444 1.2 2 20.00 48.62 (Merck KGaA) 111 0.5 Iriodin 9444 0.7 2 41.67 73.00 (Merck KGaA) 112 4.5 Iriodin 9444 0.5 2 90.00 97.15 (Merck KGaA) 113 0.5 Iriodin 9444 0.25 2 66.67 88.33 (Merck KGaA) 114 4.9 Iriodin 9444 0.1 2 98.00 99.46 (Merck KGaA) 115 0.01 Iriodin 9504 1 2 0.99 3.65 (Merck KGaA) 116 0.15 Iriodin 9504 0.5 2 23.08 53.17 (Merck KGaA) 117 0.3 Iriodin 9504 0.25 2 54.55 81.96 (Merck KGaA) 118 0.5 Iriodin 9504 0.05 2 90.91 97.43 (Merck KGaA) 119 0.01 Iriodin 9504 1 3 0.99 3.65 (Merck KGaA) 120 0.15 Iriodin 9504 0.5 3 23.08 53.17 (Merck KGaA) 121 0.3 Iriodin 9504 0.25 3 54.55 81.96 (Merck KGaA) 122 0.5 Iriodin 9504 0.05 3 90.91 97.43 (Merck KGaA) 123 0.01 Iriodin 9504 2 2 0.50 1.86 (Merck KGaA) 124 0.15 Iriodin 9504 1.5 2 9.09 27.46 (Merck KGaA) 125 0.3 Iriodin 9504 1 2 23.08 53.17 (Merck KGaA) 126 0.5 Iriodin 9504 0.5 2 50.00 79.10 (Merck KGaA) 127 0.01 Iriodin 9504 0.01 2 50.00 79.10 (Merck KGaA) 128 0.15 Iriodin 9504 3 2 4.76 15.91 (Merck KGaA) 129 0.3 Iriodin 9504 1.2 2 20.00 48.62 (Merck KGaA) 130 0.5 Iriodin 9504 0.7 2 41.67 73.00 (Merck KGaA) 131 4.5 Iriodin 9504 0.5 2 90.00 97.17 (Merck KGaA) 132 0.5 Iriodin 9504 0.25 2 66.67 88.33 (Merck KGaA) 133 4.9 Iriodin 9504 0.1 2 98.00 99.46 (Merck KGaA) 134 0.01 Xirallic 1 2 0.99 3.65 F60-50 (Merck KGaA) 135 0.15 Xirallic 0.5 2 23.08 53.17 F60-50 (Merck KGaA) 136 0.3 Xirallic 0.25 2 54.55 81.96 F60-50 (Merck KGaA) 137 0.5 Xirallic 0.05 2 90.91 97.43 F60-50 (Merck KGaA) 138 0.01 Xirallic 1 3 0.99 3.65 F60-50 (Merck KGaA) 139 0.15 Xirallic 0.5 3 23.08 53.17 F60-50 (Merck KGaA) 140 0.3 Xirallic 0.25 3 54.55 81.96 F60-50 (Merck KGaA) 141 0.5 Xirallic 0.05 3 90.91 97.43 F60-50 (Merck KGaA) 142 0.01 Xirallic 2 2 0.50 1.86 F60-50 (Merck KGaA) 143 0.15 Xirallic 1.5 2 9.09 27.46 F60-50 (Merck KGaA) 144 0.3 Xirallic 1 2 23.08 53.17 F60-50 (Merck KGaA) 145 0.5 Xirallic 0.5 2 50.00 79.10 F60-50 (Merck KGaA) 146 0.01 Xirallic 0.01 2 50.00 79.10 F60-50 (Merck KGaA) 147 0.15 Xirallic 3 2 4.76 15.91 F60-50 (Merck KGaA) 148 0.3 Xirallic 1.2 2 20.00 48.62 F60-50 (Merck KGaA) 149 0.5 Xirallic 0.7 2 41.67 73.00 F60-50 (Merck KGaA) 150 4.5 Xirallic 0.5 2 90.00 97.15 F60-50 (Merck KGaA) 151 0.5 Xirallic 0.25 2 66.67 88.33 F60-50 (Merck KGaA) 152 4.9 Xirallic 0.1 2 98.00 99.46 F60-50 (Merck KGaA) 153 0.01 Xirallic 1 2 0.99 3.65 F60-51 (Merck KGaA) 154 0.15 Xirallic 0.5 2 23.08 53.17 F60-51 (Merck KGaA) 155 0.3 Xirallic 0.25 2 54.55 81.96 F60-51 (Merck KGaA) 156 0.5 Xirallic 0.05 2 90.91 97.43 F60-51 (Merck KGaA) 157 0.01 Xirallic 1 3 0.99 3.65 F60-51 (Merck KGaA) 158 0.15 Xirallic 0.5 3 23.08 53.17 F60-51 (Merck KGaA) 159 0.3 Xirallic 0.25 3 54.55 81.96 F60-51 (Merck KGaA) 160 0.5 Xirallic 0.05 3 90.91 97.43 F60-51 (Merck KGaA) 161 0.01 Xirallic 2 2 0.50 1.86 F60-51 (Merck KGaA) 162 0.15 Xirallic 1.5 2 9.09 27.46 F60-51 (Merck KGaA) 163 0.3 Xirallic 1 2 23.08 53.17 F60-51 (Merck KGaA) 164 0.5 Xirallic 0.5 2 50.00 79.10 F60-51 (Merck KGaA) 165 0.01 Xirallic 0.01 2 50.00 79.10 F60-51 (Merck KGaA) 166 0.15 Xirallic 3 2 4.76 15.91 F60-51 (Merck KGaA) 167 0.3 Xirallic 1.2 2 20.00 48.62 F60-51 (Merck KGaA) 168 0.5 Xirallic 0.7 2 41.67 73.00 F60-51 (Merck KGaA) 169 4.5 Xirallic 0.5 2 90.00 97.15 F60-51 (Merck KGaA) 170 0.5 Xirallic 0.25 2 66.67 88.33 F60-51 (Merck KGaA) 171 4.9 Xirallic 0.1 2 98.00 99.46 F60-51 (Merck KGaA) 172 0.01 Pyrisma 1 2 0.99 3.65 M40-58 (Merck KGaA) 173 0.15 Pyrisma 0.5 2 23.08 53.17 M40-58 (Merck KGaA) 174 0.3 Pyrisma 0.25 2 54.55 81.96 M40-58 (Merck KGaA) 175 0.5 Pyrisma 0.05 2 90.91 97.43 M40-58 (Merck KGaA) 176 0.01 Pyrisma 1 3 0.99 3.65 M40-58 (Merck KGaA) 177 0.15 Pyrisma 0.5 3 23.08 53.17 M40-58 (Merck KGaA) 178 0.3 Pyrisma 0.25 3 54.55 81.96 M40-58 (Merck KGaA) 179 0.5 Pyrisma 0.05 3 90.91 97.43 M40-58 (Merck KGaA) 180 0.01 Pyrisma 2 2 0.50 1.86 M40-58 (Merck KGaA) 181 0.15 Pyrisma 1.5 2 9.09 27.46 M40-58 (Merck KGaA) 182 0.3 Pyrisma 1 2 23.08 53.17 M40-58 (Merck KGaA) 183 0.5 Pyrisma 0.5 2 50.00 79.10 M40-58 (Merck KGaA) 184 0.01 Pyrisma 0.01 2 50.00 79.10 M40-58 (Merck KGaA) 185 0.15 Pyrisma 3 2 4.76 15.91 M40-58 (Merck KGaA) 186 0.3 Pyrisma 1.2 2 20.00 48.62 M40-58 (Merck KGaA) 187 0.5 Pyrisma 0.7 2 41.67 73.00 M40-58 (Merck KGaA) 188 4.5 Pyrisma 0.5 2 90.00 97.15 M40-58 (Merck KGaA) 189 0.5 Pyrisma 0.25 2 66.67 88.33 M40-58 (Merck KGaA) 190 4.9 Pyrisma 0.1 2 98.00 99.46 M40-58 (Merck KGaA) 191 0.5 SynCrystal 0.25 2 66.67 88.33 Silver (Eckart GmbH) 192 0.5 SYMIC B001 0.25 2 66.67 88.33 Silber (Eckart GmbH) 193 0.5 SYMIC C001 0.25 2 66.67 88.33 Silber (Eckart GmbH) 194 0.5 SYMIC C604 0.25 2 66.67 88.33 Silber (Eckart GmbH) 195 0.5 SYMIC OEM 0.25 2 66.67 88.33 X-fine Silver (Eckart GmbH) 196 0.5 SYMIC C393 0.25 2 66.67 88.33 Gold (Eckart GmbH) 197 0.5 SYMIC C522 0.25 2 66.67 88.33 Erdfarbton Kupfer (Eckart GmbH) 198 0.5 SYMIC C542 0.25 2 66.67 88.33 Erdfarbton Feuer-Rot (Eckart GmbH) 199 0.5 SYMIC OEM 0.25 2 66.67 88.33 Medium Space Gold (Eckart GmbH) 200 0.5 Magnapearl 0.25 2 66.67 88.33 1000(BASF AG) 201 0.5 Magnapearl 0.25 2 66.67 88.33 2000 (BASF AG) 202 0.5 Magnapearl 0.25 2 66.67 88.33 3100 (BASF AG) 203 0.5 Lumina Brass 0.25 2 66.67 88.33 9232D (BASF AG) 204 0.5 Lumina 0.25 2 66.67 88.33 Copper 9350D (BASF AG) 205 0.5 Lumina 0.25 2 66.67 88.33 Exterior Gold 2303D (BASF AG) 206 0.5 Lumina 0.25 2 66.67 88.33 Russet 9450D (BASF AG) 207 0.5 Lumina Royal 0.25 2 66.67 88.33 Copper (BASF AG) 208 0.5 Lumina Royal 0.25 2 66.67 88.33 Magenta (BASF AG) 209 0.5 Lumina Royal 0.25 2 66.67 88.33 Blue (BASF AG) 210 0.5 Exterior Polar 0.25 2 66.67 88.33 White KC9119- SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 211 0.5 Exterior 0.25 2 66.67 88.33 Sterling White KC9103-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 212 0.5 Exterior Fine 0.25 2 66.67 88.33 Gold Satin KC9201-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 213 0.5 Exterior 0.25 2 66.67 88.33 Platinum Pearl KC9205-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 214 0.5 Exterior Gold 0.25 2 66.67 88.3 Pearl KC9300- SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 215 0.5 Exterior Royal 0.25 2 66.67 88.33 Gold KC9303- SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 216 0.5 Exterior Royal 0.25 2 66.67 88.33 Gold Satin KC9323-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 217 0.5 Exterior Bright 0.25 2 66.67 88.33 Gold KC9307- SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 218 0.5 Exterior 0.25 2 66.67 88.33 Bronze KC9502-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 219 0.5 Exterior Wine 0.25 2 66.67 88.33 Red KC9504- SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 220 0.5 Exterior Ruby 0.25 2 66.67 88.33 KC9508-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 221 0.01 ADAMAS A- 1 2 0.99 3.65 100D (CQV Co., Ltd.) 222 0.15 ADAMAS A- 0.5 2 23.08 53.17 100D (CQV Co., Ltd.) 223 0.3 ADAMAS A- 0.25 2 54.55 81.96 100D (CQV Co., Ltd.) 224 0.5 ADAMAS A- 0.05 2 90.91 97.43 100D (CQV Co., Ltd.) 225 0.01 ADAMAS A- 1 3 0.99 3.65 100D (CQV Co., Ltd.) 226 0.15 ADAMAS A- 0.5 3 23.08 53.17 100D (CQV Co., Ltd.) 227 0.5 ADAMAS A- 0.25 2 66.67 88.33 901K Splendor White (CQV Co., Ltd.) 228 0.5 ADAMAS A- 0.25 2 66.67 88.33 901S Dazzling White (CQV Co., Ltd.) 229 0.15 ADAMAS A- 0.5 2 23.08 53.17 901S Dazzling White (CQV Co., Ltd.) 230 0.3 ADAMAS A- 0.25 2 54.55 81.96 901S Dazzling White (CQV Co., Ltd.) 231 0.5 ADAMAS A- 0.25 2 66.67 88.33 901K Splendor Gold (CQV Co., Ltd.) 232 0.15 ADAMAS A- 0.5 2 23.08 53.17 901K Splendor Gold (CQV Co., Ltd.) 233 0.3 ADAMAS A- 0.25 2 54.55 81.96 901K Splendor Gold (CQV Co., Ltd.) 234 0.5 ADAMAS A- 0.25 2 66.67 88.33 701S Dazzling Gold (CQV Co., Ltd.) 235 0.15 ADAMAS A- 0.5 2 23.08 53.17 701S Dazzling Gold (CQV Co., Ltd.) 236 0.3 ADAMAS A- 0.25 2 54.55 81.96 701S Dazzling Gold (CQV Co., Ltd.) 237 0.5 ADAMAS A- 0.25 2 66.67 88.33 741S Dazzling Red (CQV Co., Ltd.) 238 0.5 ADAMAS A- 0.25 2 66.67 88.33 781K Splendor Blue (CQV Co., Ltd.) 239 0.5 ADAMAS A- 0.25 2 66.67 88.33 781S Dazzling Blue (CQV Co., Ltd.) 240 0.5 ADAMAS A- 0.25 2 66.67 88.33 620S Dazzling Bronze (CQV Co., Ltd.) 241 0.15 ADAMAS A- 0.5 2 23.08 53.17 620S Dazzling Bronze (CQV Co., Ltd.) 242 0.3 ADAMAS A- 0.25 2 54.55 81.96 620S Dazzling Bronze (CQV Co., Ltd.) 243 0.5 ADAMAS A- 0.25 2 66.67 88.33 640K Splendor Copper (CQV Co., Ltd.) 244 0.15 ADAMAS A- 0.5 2 23.08 53.17 640K Splendor Copper (CQV Co., Ltd.) 245 0.3 ADAMAS A- 0.25 2 54.55 81.96 640K Splendor Copper (CQV Co., Ltd.) 246 0.5 ADAMAS A- 0.25 2 66.67 88.33 640S Dazzling Copper (CQV Co., Ltd.) 247 0.15 ADAMAS A- 0.5 2 23.08 53.17 640S Dazzling Copper (CQV Co., Ltd.) 248 0.3 ADAMAS A- 0.25 2 54.55 81.96 640S Dazzling Copper (CQV Co., Ltd.) 249 0.5 ADAMAS A- 0.25 2 66.67 88.33 660K Splendor Russet (CQV Co., Ltd.) 250 0.15 ADAMAS A- 0.5 2 23.08 53.17 660K Splendor Russet (CQV Co., Ltd.) 251 0.3 ADAMAS A- 0.25 2 54.55 81.96 660K Splendor Russet (CQV Co., Ltd.) 252 0.5 ADAMAS A- 0.25 2 66.67 88.33 660S Dazzling Russet (CQV Co., Ltd.) 253 0.5 CHAOS C- 0.25 2 66.67 88.33 901M Rutile Ultra Silk (CQV Co., Ltd.) 254 0.5 CHAOS C- 0.25 2 66.67 88.33 901D Rutile Fine White (CQV Co., Ltd.) 255 0.5 CHAOS C- 0.25 2 66.67 88.33 900D Fine White (CQV Co., Ltd.) 256 0.5 CHAOS C- 0.25 2 66.67 88.33 907K Skye White (CQV Co., Ltd.) 257 0.5 CHAOS C- 0.25 2 66.67 88.33 901K Splendor White (CQV Co., Ltd.) 258 0.5 CHAOS C- 0.25 2 66.67 88.33 901S Rutile Dazzling Standard (CQV Co., Ltd.) 259 0.5 CHAOS C- 0.25 2 66.67 88.33 900S Dazzling Standard (CQV Co., Ltd.) 260 0.5 CHAOS C- 0.25 2 66.67 88.33 902S Super White (CQV Co., Ltd.) 261 0.5 CHAOS C- 0.25 2 66.67 88.33 109S Super Pearl (CQV Co., Ltd.) 262 0.5 CHAOS C- 0.25 2 66.67 88.33 109B Shimmering White (CQV Co., Ltd.) 263 0.5 CHAOS C- 0.25 2 66.67 88.33 901E Glitter Pearl (CQV Co., Ltd.) 264 0.5 FERRIUS F- 0.25 2 66.67 88.33 620K Splendor Bronze (CQV Co., Ltd.) 265 0.5 FERRIUS F- 0.25 2 66.67 88.33 630K Splendor Orange (CQV Co., Ltd.) 266 0.5 FERRIUS F- 0.25 2 66.67 88.33 640K Splendor Copper (CQV Co., Ltd.) 267 0.5 FERRIUS F- 0.25 2 66.67 88.33 660K Splendor Russet (CQV Co., Ltd.) 268 0.5 FERRIUS F- 0.25 2 66.67 88.33 620P Crystal Bronze (CQV Co., Ltd.) 269 0.5 FERRIUS F- 0.25 2 66.67 88.33 630P Crystal Orange (CQV Co., Ltd.) 270 0.5 FERRIUS F- 0.25 2 66.67 88.33 640P Crystal Copper (CQV Co., Ltd.) 271 0.5 FERRIUS F- 0.25 2 66.67 88.33 660P Crystal Russet (CQV Co., Ltd.) 272 0.5 Magchrom N- 0.25 2 66.67 88.33 5001C Natural Corona Gold (CQV Co., Ltd.) 273 0.5 Magchrom N- 0.25 2 66.67 88.33 5001S Natural Dazzling Gold (CQV Co., Ltd.) 274 0.5 Magchrom S- 0.25 2 66.67 88.33 7801C Corona Blue (CQV Co., Ltd.) 275 0.5 REFLEX 0.25 2 66.67 88.33 RCN-1008S Snow White Pearl (CQV Co., Ltd.) 276 0.5 Thermaval 0.25 2 66.67 88.33 Metallic Silver (Merck KGaA) 277 0.5 Thermaval 0.25 2 66.67 88.33 Metallic Gold (Merck KGaA) 278 0.5 Thermaval 0.25 2 66.67 88.33 Metallic Red (Merck KGaA) 279 0.5 Thermaval 0.25 2 66.67 88.33 Metallic Copper (Merck KGaA) 280 0.01 Iriodin 325 1 2 0.99 21.60 (Merck KGaA) 281 0.15 Iriodin 325 0.5 2 23.08 89.21 (Merck KGaA) 282 0.3 Iriodin 325 0.25 2 54.55 97.06 (Merck KGaA) 283 0.5 Iriodin 325 0.05 2 90.91 99.64 (Merck KGaA) 284 0.01 Iriodin 325 1 3 0.99 21.60 (Merck KGaA) 285 0.15 Iriodin 325 0.5 3 23.08 89.21 (Merck KGaA) 286 0.3 Iriodin 325 0.25 3 54.55 97.06 (Merck KGaA) 287 0.5 Iriodin 325 0.05 3 90.91 99.64 (Merck KGaA) 288 0.01 Iriodin 325 2 2 0.50 12.11 (Merck KGaA) 289 0.15 Iriodin 325 1.5 2 9.09 73.37 (Merck KGaA) 290 0.3 Iriodin 325 1 2 23.08 89.21 (Merck KGaA) 291 0.5 Iriodin 325 0.5 2 50.00 96.50 (Merck KGaA) 292 0.01 Iriodin 325 0.01 2 50.00 96.50 (Merck KGaA) 293 0.15 Iriodin 325 3 2 4.76 57.94 (Merck KGaA) 294 0.3 Iriodin 325 1.2 2 20.00 87.32 (Merck KGaA) 295 0.5 Iriodin 325 0.7 2 41.67 95.16 (Merck KGaA) 296 4.5 Iriodin 325 0.5 2 90.00 99.60 (Merck KGaA) 297 0.5 Iriodin 325 0.25 2 66.67 98.22 (Merck KGaA) 298 4.9 Iriodin 325 0.1 2 98.00 99.93 (Merck KGaA) Particle size Trade name Manufacturer Substrate Coating [m] Xirallic Crystal Silver Merck KGaA Al.sub.2O.sub.3 TiO.sub.2 5-35 Iriodin 103 Merck KGaA Natural mica TiO.sub.2 10-60 Iriodin 305 Merck KGaA Natural mica Fe.sub.2O.sub.3 and 10-60 TiO.sub.2 Iriodin 4504 Lava Red Merck KGaA SiO.sub.2 Fe.sub.2O.sub.3 5-50 Iriodin 9219 Merck KGaA Natural mica TiO.sub.2 10-60 Iriodin 9444 Merck KGaA Natural mica Cr.sub.2O.sub.3 5-40 Iriodin 9504 Merck KGaA Natural mica Fe.sub.2O.sub.3 10-60 Xirallic F60-50 Merck KGaA Al.sub.2O.sub.3 Fe.sub.2O.sub.3 5-35 Xirallic F60-51 Merck KGaA Al.sub.2O.sub.3 Fe.sub.2O.sub.3 5-35 Pyrisma M40-58 Merck KGaA Natural mica Fe.sub.2O.sub.3 and 5-40 TiO.sub.2 SynCrystal Silver Eckart GmbH Synthetic TiO.sub.2 10-50 mica SYMIC B001 Silver Eckart GmbH Synthetic TiO.sub.2 5-25 mica SYMIC C001 Silver Eckart GmbH Synthetic TiO.sub.2 10-40 mica SYMIC C604 Silver Eckart GmbH Synthetic TiO.sub.2 10-40 mica SYMIC OEM Eckart GmbH Synthetic TiO.sub.2 3-15 X-fine Silver mica SYMIC C393 Gold Eckart GmbH Synthetic Fe.sub.2O.sub.3 and 10-40 mica TiO.sub.2 SYMIC C522 Copper Eckart GmbH Synthetic Fe.sub.2O.sub.3 10-40 Earth Shade mica SYMIC C542 Fire Eckart GmbH Synthetic Fe.sub.2O.sub.3 10-40 Red Earth Shade mica SYMIC OEM Medium Eckart GmbH Synthetic Fe.sub.2O.sub.3 and 12-38 Space Gold mica TiO.sub.2 Magnapearl 1000 BASF AG Natural mica TiO.sub.2 6-48 Magnapearl 2000 BASF AG Natural mica TiO.sub.2 5-25 Magnapearl 3100 BASF AG Natural mica TiO.sub.2 2-10 Lumina Brass 9232D BASF AG Natural mica Fe.sub.2O.sub.3 and 10-48 TiO.sub.2 Lumina Copper BASF AG Natural mica Fe.sub.2O.sub.3 8-48 9350D Lumina Exterior Gold BASF AG Natural mica TiO.sub.2 8-48 2303D Lumina Russet BASF AG Natural mica Fe.sub.2O.sub.3 8-48 9450D Lumina Royal Copper BASF AG Natural mica TiO.sub.2 10-34 Lumina Royal BASF AG Natural mica TiO.sub.2 10-34 Magenta Lumina Royal Blue BASF AG Natural mica TiO.sub.2 10-34 Exterior Polar White Fujian Kuncai Natural mica TiO.sub.2 5-25 KC9119-SW Fine Chemicals Co., Ltd. Exterior Sterling White Fujian Kuncai Natural mica TiO.sub.2 10-45 KC9103-SW Fine Chemicals Co., Ltd. Exterior Fine Gold Fujian Kuncai Natural mica TiO.sub.2 5-25 Satin KC9201-SW Fine Chemicals Co., Ltd. Exterior Platinum Pearl Fujian Kuncai Natural mica TiO.sub.2 10-45 KC9205-SW Fine Chemicals Co., Ltd. Exterior Royal Gold Fujian Kuncai Natural mica Fe.sub.2O.sub.3 and 10-45 KC9303-SW Fine Chemicals TiO.sub.2 Co., Ltd. Exterior Royal Gold Fujian Kuncai Natural mica Fe.sub.2O.sub.3 and 5-25 Satin KC9323-SW Fine Chemicals TiO.sub.2 Co., Ltd. Exterior Bright Gold Fujian Kuncai Natural mica Fe.sub.2O.sub.3 and 10-60 KC9307-SW Fine Chemicals TiO.sub.2 Co., Ltd. Exterior Brown Fujian Kuncai Natural mica Fe.sub.2O.sub.3 8-45 KC9502-SW Fine Chemi- cals Co., Ltd. Exterior Wine Red Fujian Kuncai Natural mica Fe.sub.2O.sub.3 8-45 KC9504-SW Fine Chemicals Co., Ltd. Exterior Ruby Fujian Kuncai Natural mica Fe.sub.2O.sub.3 8-45 KC9508-SW Fine Chemicals Co., Ltd. ADAMAS A-100D CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 3-30 ADAMAS A-901K CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 5-30 Splendor White ADAMAS A-901S CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 9-45 Dazzling White ADAMAS A-901K CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 5-30 Splendor Gold ADAMAS A-701S CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 9-45 Dazzling Gold ADAMAS A-741S CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 9-45 Dazzling Red ADAMAS A-781K CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 5-30 Splendor Blue ADAMAS A-781S CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 9-45 Dazzling Blue ADAMAS A-620S CQV Co., Ltd. Al.sub.2O.sub.3 F203 9-45 Dazzling Bronze ADAMAS A-640S CQV Co., Ltd. Al.sub.2O.sub.3 F203 9-45 Dazzling Copper ADAMAS A-660S CQV Co., Ltd. Al.sub.2O.sub.3 F203 9-45 Dazzling Russet CHAOS C-901M CQV Co., Ltd. Synthetic TiO.sub.2 3-17 Rutile Ultra Silk mica CHAOS C-901D CQV Co., Ltd. Synthetic TiO.sub.2 5-25 Rutile Fine White mica CHAOS C-900D CQV Co., Ltd. Synthetic TiO.sub.2 5-25 Fine White mica CHAOS C-907K CQV Co., Ltd. Synthetic TiO.sub.2 5-35 Sky White mica CHAOS C-901 K CQV Co., Ltd. Synthetic TiO.sub.2 5-35 Splendor White mica CHAOS C-901S CQV Co., Ltd. Synthetic TiO.sub.2 9-45 Rutile Dazzling mica Standard CHAOS C-900S CQV Co., Ltd. Synthetic TiO.sub.2 9-45 Dazzling Standard mica CHAOS C-902S CQV Co., Ltd. Synthetic TiO.sub.2 9-45 Super White mica CHAOS C-109S CQV Co., Ltd. Synthetic TiO.sub.2 9-41 Super Pearl mica CHAOS C-109B CQV Co., Ltd. Synthetic TiO.sub.2 13-60 Shimmering White mica CHAOS C-901E CQV Co., Ltd. Synthetic TiO.sub.2 17-100 Glitter Pearl mica FERRIUS F-620K CQV Co., Ltd. Synthetic Fe.sub.2O.sub.3 5-35 Splendor Bronze mica FERRIUS F-630K CQV Co., Ltd. Synthetic Fe.sub.2O.sub.3 5-35 Splendor Orange mica FERRIUS F-640K CQV Co., Ltd. Synthetic Fe.sub.2O.sub.3 5-35 Splendor Copper mica FERRIUS F-660K CQV Co., Ltd. Synthetic Fe.sub.2O.sub.3 5-35 Splendor Russet mica FERRIUS F-620P CQV Co., Ltd. Synthetic Fe.sub.2O.sub.3 25-150 Crystal Bronze mica FERRIUS F-630P CQV Co., Ltd. Synthetic Fe.sub.2O.sub.3 25-150 Crystal Orange mica FERRIUS F-640P CQV Co., Ltd. Synthetic Fe.sub.2O.sub.3 25-150 Crystal Copper mica FERRIUS F-660P CQV Co., Ltd. Synthetic Fe.sub.2O.sub.3 25-150 Crystal Russet mica Magchrom N-5001C CQV Co., Ltd. Nat. mica TiO.sub.2 7-30 Natural Corona Gold Magchrom N-5001S CQV Co., Ltd. Nat. mica TiO.sub.2 9-45 Natural Dazzling Gold Magchrom S-7801C CQV Co., Ltd. Synthetic TiO.sub.2 7-27 Corona Blue mica

[0216] The preceding examples can be repeated with similar success by substituting the generically or specifically described reactants and/or operating conditions of this invention for those used in the preceding examples.

[0217] From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of this invention and, without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.