CERAMIC COLOURS

Abstract

The invention relates to ceramic colours comprising effect pigments and a sol-gel based glassy matrix for decoration of metallic, ceramic and glassy articles and to a process for the preparation of a ceramic glaze.

Claims

1. A process for the preparation of glazed articles comprising: (a) preparing a ceramic colour by mixing at least one effect pigment based on flake-form substrates and/or uncoated flake-form substrates with a refractive index R.I.>1.5, at least one sol-gel component, optionally a solvent, optionally a binder, optionally an absorptive ceramic pigment and optionally at least one additive, (b) printing or coating the ceramic colour obtained in step (a) on a ceramic or metallic body, (c) drying the ceramic or metallic body obtained in step (b), (d) firing the ceramic or metallic body obtained in step (c) at a temperature in the range of 450 C.-1300 C.

2. A process according to claim 1, wherein in step (d) the ceramic body is fired at a temperature in the range of 700-1300 C. or the metallic body is fired at a temperature in the range of 450-950 C.

3. A process according to claim 1, wherein the proportion of effect pigment in the ceramic colour is at least 0.1% by weight based on the weight of the sol-gel component in the ceramic color.

4. A process according to claim 1, wherein the effect pigments are pearlescent pigments based on flake-form substrates selected from the group consisting of synthetic mica flakes, natural mica flakes, glass flakes, Al.sub.2O.sub.3 flakes, SiO.sub.2 flakes, Fe.sub.2O.sub.3 flakes, B.sub.4C flakes, TiO.sub.2 flakes, SiC flakes, Si.sub.xN.sub.yC.sub.z flakes with x=0.5-1.0; y=0.25-0.5; z=0.25-0.5, BN flakes, and graphite flakes.

5. A process according to claim 1, wherein the flake-form substrates of the effect pigments are covered with one or more layers of metal oxide(s), metal sulfides, rare-earth metal oxides and/or metal(s) or mixtures thereof.

6. A process according to claim 1, wherein the flake-form substrates of the effect pigments are covered on the surface with one or more layers selected from the group TiO.sub.2, MnO, CuO, CuCr.sub.2O.sub.4 Fe.sub.2O.sub.3, ZrO.sub.2, SnO.sub.2, TiO.sub.2/Fe.sub.2O.sub.3, Fe.sub.2TiO.sub.5, FeTiO.sub.3, FeOOH, Fe.sub.3O.sub.4, Cr.sub.2O.sub.3 and TiO.sub.x, where x=1.50-1.95.

7. A process according to claim 1, wherein the flake-form substrates have a particle thickness of 0.05-5.0 m.

8. A process according to claim 1, wherein the ceramic colour comprises at least one sol-gel component selected from pre-hydrolysed pure or organo-functionalized alkoxysilanes.

9. A process according to claim 1, wherein the ceramic colour comprises at least one additional metal-organic metal-oxide precursor selected from the group of pure or organo-functionalized alkoxymetallates.

10. A process according to claim 1, wherein the ceramic colour comprises at least one metal-halogenide, which is CaCl.sub.2, SnCl.sub.4 or CeCl.sub.3.

11. A process according to claim 1, wherein the ceramic colour comprises a printing oil.

12. A process according to claim 1, wherein the effect pigments are selected from the following group of pigments: substrate flake+TiO.sub.2 substrate flake+Fe.sub.2O.sub.3 substrate flake+Fe.sub.3O.sub.4 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+FeTiO.sub.3 substrate flake+Fe.sub.2TiO.sub.5 substrate flake+ZrO.sub.2 substrate flake+ZnO substrate flake+SnO.sub.2 substrate flake+Cr.sub.2O.sub.3 substrate flake+Ce.sub.2O.sub.3 substrate flake+TiO.sub.x (reduced), where x=1.50-1.95 substrate flake+TiO.sub.2+Fe.sub.2O.sub.3 substrate flake+TiO.sub.2+Fe.sub.3O.sub.4 substrate flake+Fe.sub.2O.sub.3+TiO.sub.2 substrate flake+TiO.sub.2+SiO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2+Al.sub.2O.sub.3+TiO.sub.2 substrate flake+Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+TiO.sub.2+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+TiO.sub.2+SiO.sub.2 substrate flake+TiO.sub.2+Al.sub.2O.sub.3 substrate flake+TiO.sub.2+MgO x SiO.sub.2+TiO.sub.2 substrate flake+Fe.sub.2O.sub.3+MgO x SiO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+MgO x SiO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+MgO x SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+MgO x SiO.sub.2+TiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+TiO.sub.2+MgO x SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+SnO.sub.2+TiO.sub.2+SiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+SnO.sub.2+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3+SiO.sub.2+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3 substrate flake+Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2 substrate flake+Fe.sub.2O.sub.3+SnO.sub.2+Fe.sub.2O.sub.3 substrate flake+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2 substrate flake+TiO.sub.2/Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3. substrate flake+Fe.sub.2TiO.sub.5+SnO.sub.2+Fe.sub.2TiO.sub.5 and substrate flake+Fe.sub.2TiO.sub.5+SiO.sub.2+Fe.sub.2TiO.sub.5.

13. A process according to claim 1, wherein the effect pigments on the substrate flake have a first low-refractive-index layer (=LRL) comprising Al.sub.2O.sub.3, SiO.sub.2, zirconium silicate ZrSiO.sub.4, mullite 3Al.sub.2O.sub.3 x 2SiO.sub.2 or 2Al.sub.2O.sub.3 x SiO.sub.2 (sintered or fused mullite) or alkaline-earth metal silicate (MSiO.sub.3, where M=Mg.sup.2+, Ca.sup.2+, Sr.sup.2+ or Ba.sup.2+, or M.sub.2Si.sub.3O.sub.8, where M=Mg.sup.2, Ca.sup.2+, Sr.sup.2+ or Ba.sup.2+) and are selected from the following group of pigments: substrate flake+LRL+TiO.sub.2 substrate flake+LRL+Fe.sub.2O.sub.3 substrate flake+LRL+Fe.sub.3O.sub.4 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+FeTiO.sub.3 substrate flake+LRL+Fe.sub.2TiO.sub.5 substrate flake+LRL+ZrO.sub.2 substrate flake+LRL+ZnO substrate flake+LRL+SnO.sub.2 substrate flake+LRL+Cr.sub.2O.sub.3 substrate flake+LRL+Ce.sub.2O.sub.3 substrate flake+LRL+TiO.sub.x (reduced), where x=1.50-1.95 substrate flake+LRL+TiO.sub.2+Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+Fe.sub.3O.sub.4 substrate flake+LRL+Fe.sub.2O.sub.3+TiO.sub.2 substrate flake+LRL+TiO.sub.2+SiO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2+Al.sub.2O.sub.3+TiO.sub.2 substrate flake+LRL+Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+SiO.sub.2+TiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+SiO.sub.2 substrate flake+LRL+TiO.sub.2+Al.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+MgO x SiO.sub.2+TiO.sub.2 substrate flake+LRL+Fe.sub.2O.sub.3+MgO x SiO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+MgO x SiO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+MgO x SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+MgO x SiO.sub.2+TiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+MgO x SiO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+SnO.sub.2+TiO.sub.2+SiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+LRL+SnO.sub.2+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+LRL+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3+SiO.sub.2+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3 substrate flake+LRL+Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2 substrate flake+LRL+Fe.sub.2O.sub.3+SnO.sub.2+Fe.sub.2O.sub.3 substrate flake+LRL+TiO.sub.2+SnO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2 substrate flake+LRL+TiO.sub.2/Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2/Fe.sub.2O.sub.3 substrate flake+LRL+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3+SnO.sub.2+TiO.sub.2+Fe.sub.2O.sub.3 substrate flake+LRL+Fe.sub.2TiO.sub.5+SnO.sub.2+Fe.sub.2TiO.sub.5 and substrate flake+LRL+Fe.sub.2TiO.sub.5+SiO.sub.2+Fe.sub.2TiO.sub.5.

14. A ceramic colour comprising at least one sol-gel component and at least one effect pigment based on flake-form substrates selected from the group consisting of mica flakes, natural mica flakes, glass flakes, Al.sub.2O.sub.3 flakes, SiO.sub.2 flakes, Fe.sub.2O.sub.3 flakes, B.sub.4C flakes, TiO.sub.2 flakes, SiC flakes, Si.sub.xN.sub.yC.sub.z flakes with x=0.5-1.0; y=0.25-0.5; z=0.25-0.5, BN flakes and graphite flakes and/or at least one uncoated flake-form substrate with R.I.>1.5 selected from the group consisting of Al.sub.2O.sub.3 flake, SiC flakes, Si.sub.xN.sub.yC.sub.z flakes; B.sub.4C flakes, BN flakes, graphite flakes, TiO.sub.2 flakes, and Fe.sub.2O.sub.3 flakes.

15. A ceramic colour according to claim 14, wherein the proportion of effect pigment and/or uncoated flake-form substrate in the ceramic colour is at least 0.1% by weight based on the pre-ceramic sol-gel component.

16. A ceramic colour according to claim 14, wherein the at least one sol-gel component comprises pre-hydrolysed pure or organo-functionalized alkoxysilane.

17. A method which comprises including the ceramic colour according to claim 14 in unfired bricks, fired bricks, unfired earthenware or fired earthenware, ceramicware, ceramic glazes, decorative tiles, porcelain glazes or enamel metallic decoration.

18. A formulation comprising the ceramic colour according to claim 14.

19. A method for the manufacture of decorative elements on articles exhibiting an outer surface of porcelain, china, bone china, ceramic, glass or enamel which comprises incorporating a ceramic colour according to claim 14 in said outer surface of porcelain, china, bone china, ceramic, glass or enamel.

20. A process according to claim 1, wherein the ceramic colour comprises tetra-methoxy-silane, 3-Aminopropyltriethoxysilane.

21. A ceramic colour according to claim 14, which comprises tetra-methoxy-silane, 3-Aminopropyltriethoxysilane

22. A process according to claim 1, wherein the ceramic colour comprises at least one additional metal-organic metal-oxide precursor selected from the group Tetra-ethoxy-titanate; Titanium(IV) i-propoxide; Germanium(IV) ethoxide; Lanthanum(III) i-propoxide; Tin(IV) t-butoxide; Vanadium (V) tri-i-propoxide; and Zirconium(IV) ethoxide.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0187] FIG. 1 is a graph.

[0188] The following examples are intended to explain the invention, but without limiting it.

EXAMPLES

[0189] For the preparation of ceramic colours, the effect pigments according to Examples 1 to 298 are weighed out and homogenised with the corresponding amount of sol-gel component having at solid content of 3.6% SiO.sub.2 and printing oil (221-ME Ferro). The so-gel-component is received by hydrolysis of TEOS.

[0190] The pearlescent pigments used in the examples are all commercially available and have the compositions listed in Table 2 (in the Particle size column, the d.sub.10-d.sub.90 value is measured using a Malvern is indicated in each case):

[0191] The printing paste obtained is applied to tiles by means of doctor blade and screen printing. In all cases, the printed tile is dried in a drying cabinet or fume hood at temperatures of 60-110 C. in order to evaporate the solvent present in the printing oil.

[0192] The printed and dried tiles are then fired in a firing furnace by means of a temperature profile in accordance with FIG. 1.

[0193] 180 min: heating to 1100 C.,

[0194] 3 min: holding at 1100 C.,

[0195] 120 min: rapid cooling to 600 C.,

[0196] 300 min: slow cooling to room temperature.

[0197] The temperature programme as a function of time is depicted in FIG. 1.

[0198] The glazed tiles of the examples according to the invention are distinguished by the fact that the desired optical effects are stable and accessible in a reproducible manner in respective high-temperature applications 500-1300 C.

TABLE-US-00001 TABLE 1 Screen W.sub.Pigm W.sub.Pigm Preceramic Printing in Sol-Gel- in Film Example Pigment Pearlescent Sol-Gel Medium Matrix after Firing No. [g] Pigment Name [g] [g] [%] [%] 1 0.01 Xirallic 1 2 0.99 21.60 Crystal Silver (Merck KGaA) 2 0.15 Xirallic 0.5 2 23.08 89.21 Crystal Silver (Merck KGaA) 3 0.3 Xirallic 0.25 2 54.55 97.06 Crystal Silver (Merck KGaA) 4 0.5 Xirallic 0.05 2 90.91 99.64 Crystal Silver (Merck KGaA) 5 0.01 Xirallic 1 3 0.99 21.60 Crystal Silver (Merck KGaA) 6 0.15 Xirallic 0.5 3 23.08 89.21 Crystal Silver (Merck KGaA) 7 0.3 Xirallic 0.25 3 54.55 97.06 Crystal Silver (Merck KGaA) 8 0.5 Xirallic 0.05 3 90.91 99.64 Crystal Silver (Merck KGaA) 9 0.01 Xirallic 2 2 0.50 12.11 Crystal Silver (Merck KGaA) 10 0.15 Xirallic 1.5 2 9.09 73.37 Crystal Silver (Merck KGaA) 11 0.3 Xirallic 1 2 23.08 89.21 Crystal Silver (Merck KGaA) 12 0.5 Xirallic 0.5 2 50.00 96.50 Crystal Silver (Merck KGaA) 13 0.01 Xirallic 0.01 2 50.00 96.50 Crystal Silver (Merck KGaA) 14 0.15 Xirallic 3 2 4.76 57.94 Crystal Silver (Merck KGaA) 15 0.3 Xirallic 1.2 2 20.00 87.32 Crystal Silver (Merck KGaA) 16 0.5 Xirallic 0.7 2 41.67 95.16 Crystal Silver (Merck KGaA) 17 4.5 Xirallic 0.5 2 90.00 99.60 Crystal Silver (Merck KGaA) 18 0.5 Xirallic 0.25 2 66.67 98.22 Crystal Silver (Merck KGaA) 19 4.9 Xirallic 0.1 2 98.00 99.93 Crystal Silver (Merck KGaA) 20 0.01 Iriodin 103 1 2 0.99 21.60 (Merck KGaA) 21 0.15 Iriodin 103 0.5 2 23.08 89.21 (Merck KGaA) 22 0.3 Iriodin 103 0.25 2 54.55 97.06 (Merck KGaA) 23 0.5 Iriodin 103 0.05 2 90.91 99.64 (Merck KGaA) 24 0.01 Iriodin 103 1 3 0.99 21.60 (Merck KGaA) 25 0.15 Iriodin 103 0.5 3 23.08 89.21 (Merck KGaA) 26 0.3 Iriodin 103 0.25 3 54.55 97.06 (Merck KGaA) 27 0.5 Iriodin 103 0.05 3 90.91 99.64 (Merck KGaA) 28 0.01 Iriodin 103 2 2 0.50 12.11 (Merck KGaA) 29 0.15 Iriodin 103 1.5 2 9.09 73.37 (Merck KGaA) 30 0.3 Iriodin 103 1 2 23.08 89.21 (Merck KGaA) 31 0.5 Iriodin 103 0.5 2 50.00 96.50 (Merck KGaA) 32 0.01 Iriodin 103 0.01 2 50.00 96.50 (Merck KGaA) 33 0.15 Iriodin 103 3 2 4.76 57.94 (Merck KGaA) 34 0.3 Iriodin 103 1.2 2 20.00 87.32 (Merck KGaA) 35 0.5 Iriodin 103 0.7 2 41.67 95.16 (Merck KGaA) 36 4.5 Iriodin 103 0.5 2 90.00 99.60 (Merck KGaA) 37 0.5 Iriodin 103 0.25 2 66.67 98.22 (Merck KGaA) 38 4.9 Iriodin 103 0.1 2 98.00 99.93 (Merck KGaA) 39 0.01 Iriodin 305 1 2 0.99 21.60 (Merck KGaA) 40 0.15 Iriodin 305 0.5 2 23.08 89.21 (Merck KGaA) 41 0.3 Iriodin 305 0.25 2 54.55 97.06 (Merck KGaA) 42 0.5 Iriodin 305 0.05 2 90.91 99.64 (Merck KGaA) 43 0.01 Iriodin 305 1 3 0.99 21.60 (Merck KGaA) 44 0.15 Iriodin 305 0.5 3 23.08 89.21 (Merck KGaA) 45 0.3 Iriodin 305 0.25 3 54.55 97.06 (Merck KGaA) 46 0.5 Iriodin 305 0.05 3 90.91 99.64 (Merck KGaA) 47 0.01 Iriodin 305 2 2 0.50 12.11 (Merck KGaA) 48 0.15 Iriodin 305 1.5 2 9.09 73.37 (Merck KGaA) 49 0.3 Iriodin 305 1 2 23.08 89.21 (Merck KGaA) 50 0.5 Iriodin 305 0.5 2 50.00 96.50 (Merck KGaA) 51 0.01 Iriodin 305 0.01 2 50.00 96.50 (Merck KGaA) 52 0.15 Iriodin 305 3 2 4.76 57.94 (Merck KGaA) 53 0.3 Iriodin 305 1.2 2 20.00 87.32 (Merck KGaA) 54 0.5 Iriodin 305 0.7 2 41.67 95.16 (Merck KGaA) 55 4.5 Iriodin 305 0.5 2 90.00 99.60 (Merck KGaA) 56 0.5 Iriodin 305 0.25 2 66.67 98.22 (Merck KGaA) 57 4.9 Iriodin 305 0.1 2 98.00 99.93 (Merck KGaA) 58 0.01 Iriodin 4504 1 2 0.99 21.60 Lava Red (Merck KGaA) 59 0.15 Iriodin 4504 0.5 2 23.08 89.21 Lava Red (Merck KGaA) 60 0.3 Iriodin 4504 0.25 2 54.55 97.06 Lava Red (Merck KGaA) 61 0.5 Iriodin 4504 0.05 2 90.91 99.64 Lava Red (Merck KGaA) 62 0.01 Iriodin 4504 1 3 0.99 21.60 Lava Red (Merck KGaA) 63 0.15 Iriodin 4504 0.5 3 23.08 89.21 Lava Red (Merck KGaA) 64 0.3 Iriodin 4504 0.25 3 54.55 97.06 Lava Red (Merck KGaA) 65 0.5 Iriodin 4504 0.05 3 90.91 99.64 Lava Red (Merck KGaA) 66 0.01 Iriodin 4504 2 2 0.50 12.11 Lava Red (Merck KGaA) 67 0.15 Iriodin 4504 1.5 2 9.09 73.37 Lava Red (Merck KGaA) 68 0.3 Iriodin 4504 1 2 23.08 89.21 Lava Red (Merck KGaA) 69 0.5 Iriodin 4504 0.5 2 50.00 96.50 Lava Red (Merck KGaA) 70 0.01 Iriodin 4504 0.01 2 50.00 96.50 Lava Red (Merck KGaA) 71 0.15 Iriodin 4504 3 2 4.76 57.94 Lava Red (Merck KGaA) 72 0.3 Iriodin 4504 1.2 2 20.00 87.32 Lava Red (Merck KGaA) 73 0.5 Iriodin 4504 0.7 2 41.67 95.16 Lava Red (Merck KGaA) 74 4.5 Iriodin 4504 0.5 2 90.00 99.60 Lava Red (Merck KGaA) 75 0.5 Iriodin 4504 0.25 2 66.67 98.22 Lava Red (Merck KGaA) 76 4.9 Iriodin 4504 0.1 2 98.00 99.93 Lava Red (Merck KGaA) 77 0.01 Iriodin 9219 1 2 0.99 21.60 (Merck KGaA) 78 0.15 Iriodin 9219 0.5 2 23.08 89.21 (Merck KGaA) 79 0.3 Iriodin 9219 0.25 2 54.55 97.06 (Merck KGaA) 80 0.5 Iriodin 9219 0.05 2 90.91 99.64 (Merck KGaA) 81 0.01 Iriodin 9219 1 3 0.99 21.60 (Merck KGaA) 82 0.15 Iriodin 9219 0.5 3 23.08 89.21 (Merck KGaA) 83 0.3 Iriodin 9219 0.25 3 54.55 97.06 (Merck KGaA) 84 0.5 Iriodin 9219 0.05 3 90.91 99.64 (Merck KGaA) 85 0.01 Iriodin 9219 2 2 0.50 12.11 (Merck KGaA) 86 0.15 Iriodin 9219 1.5 2 9.09 73.37 (Merck KGaA) 87 0.3 Iriodin 9219 1 2 23.08 89.21 (Merck KGaA) 88 0.5 Iriodin 9219 0.5 2 50.00 96.50 (Merck KGaA) 89 0.01 Iriodin 9219 0.01 2 50.00 96.50 (Merck KGaA) 90 0.15 Iriodin 9219 3 2 4.76 57.94 (Merck KGaA) 91 0.3 Iriodin 9219 1.2 2 20.00 87.32 (Merck KGaA) 92 0.5 Iriodin 9219 0.7 2 41.67 95.16 (Merck KGaA) 93 4.5 Iriodin 9219 0.5 2 90.00 99.60 (Merck KGaA) 94 0.5 Iriodin 9219 0.25 2 66.67 98.22 (Merck KGaA) 95 4.9 Iriodin 9219 0.1 2 98.00 99.93 (Merck KGaA) 96 0.01 Iriodin 9444 1 2 0.99 21.60 (Merck KGaA) 97 0.15 Iriodin 9444 0.5 2 23.08 89.21 (Merck KGaA) 98 0.3 Iriodin 9444 0.25 2 54.55 97.06 (Merck KGaA) 99 0.5 Iriodin 9444 0.05 2 90.91 99.64 (Merck KGaA) 100 0.01 Iriodin 9444 1 3 0.99 21.60 (Merck KGaA) 101 0.15 Iriodin 9444 0.5 3 23.08 89.21 (Merck KGaA) 102 0.3 Iriodin 9444 0.25 3 54.55 97.06 (Merck KGaA) 103 0.5 Iriodin 9444 0.05 3 90.91 99.64 (Merck KGaA) 104 0.01 Iriodin 9444 2 2 0.50 12.11 (Merck KGaA) 105 0.15 Iriodin 9444 1.5 2 9.09 73.37 (Merck KGaA) 106 0.3 Iriodin 9444 1 2 23.08 89.21 (Merck KGaA) 107 0.5 Iriodin 9444 0.5 2 50.00 96.50 (Merck KGaA) 108 0.01 Iriodin 9444 0.01 2 50.00 96.50 (Merck KGaA) 109 0.15 Iriodin 9444 3 2 4.76 57.94 (Merck KGaA) 110 0.3 Iriodin 9444 1.2 2 20.00 87.32 (Merck KGaA) 111 0.5 Iriodin 9444 0.7 2 41.67 95.16 (Merck KGaA) 112 4.5 Iriodin 9444 0.5 2 90.00 99.60 (Merck KGaA) 113 0.5 Iriodin 9444 0.25 2 66.67 98.22 (Merck KGaA) 114 4.9 Iriodin 9444 0.1 2 98.00 99.93 (Merck KGaA) 115 0.01 Iriodin 9504 1 2 0.99 21.60 (Merck KGaA) 116 0.15 Iriodin 9504 0.5 2 23.08 89.21 (Merck KGaA) 117 0.3 Iriodin 9504 0.25 2 54.55 97.06 (Merck KGaA) 118 0.5 Iriodin 9504 0.05 2 90.91 99.64 (Merck KGaA) 119 0.01 Iriodin 9504 1 3 0.99 21.60 (Merck KGaA) 120 0.15 Iriodin 9504 0.5 3 23.08 89.21 (Merck KGaA) 121 0.3 Iriodin 9504 0.25 3 54.55 97.06 (Merck KGaA) 122 0.5 Iriodin 9504 0.05 3 90.91 99.64 (Merck KGaA) 123 0.01 Iriodin 9504 2 2 0.50 12.11 (Merck KGaA) 124 0.15 Iriodin 9504 1.5 2 9.09 73.37 (Merck KGaA) 125 0.3 Iriodin 9504 1 2 23.08 89.21 (Merck KGaA) 126 0.5 Iriodin 9504 0.5 2 50.00 96.50 (Merck KGaA) 127 0.01 Iriodin 9504 0.01 2 50.00 96.50 (Merck KGaA) 128 0.15 Iriodin 9504 3 2 4.76 57.94 (Merck KGaA) 129 0.3 Iriodin 9504 1.2 2 20.00 87.32 (Merck KGaA) 130 0.5 Iriodin 9504 0.7 2 41.67 95.16 (Merck KGaA) 131 4.5 Iriodin 9504 0.5 2 90.00 99.60 (Merck KGaA) 132 0.5 Iriodin 9504 0.25 2 66.67 98.22 (Merck KGaA) 133 4.9 Iriodin 9504 0.1 2 98.00 99.93 (Merck KGaA) 134 0.01 Xirallic F60-50 1 2 0.99 21.60 (Merck KGaA) 135 0.15 Xirallic F60-50 0.5 2 23.08 89.21 (Merck KGaA) 136 0.3 Xirallic F60-50 0.25 2 54.55 97.06 (Merck KGaA) 137 0.5 Xirallic F60-50 0.05 2 90.91 99.64 (Merck KGaA) 138 0.01 Xirallic F60-50 1 3 0.99 21.60 (Merck KGaA) 139 0.15 Xirallic F60-50 0.5 3 23.08 89.21 (Merck KGaA) 140 0.3 Xirallic F60-50 0.25 3 54.55 97.06 (Merck KGaA) 141 0.5 Xirallic F60-50 0.05 3 90.91 99.64 (Merck KGaA) 142 0.01 Xirallic F60-50 2 2 0.50 12.11 (Merck KGaA) 143 0.15 Xirallic F60-50 1.5 2 9.09 73.37 (Merck KGaA) 144 0.3 Xirallic F60-50 1 2 23.08 89.21 (Merck KGaA) 145 0.5 Xirallic F60-50 0.5 2 50.00 96.50 (Merck KGaA) 146 0.01 Xirallic F60-50 0.01 2 50.00 96.50 (Merck KGaA) 147 0.15 Xirallic F60-50 3 2 4.76 57.94 (Merck KGaA) 148 0.3 Xirallic F60-50 1.2 2 20.00 87.32 (Merck KGaA) 149 0.5 Xirallic F60-50 0.7 2 41.67 95.16 (Merck KGaA) 150 4.5 Xirallic F60-50 0.5 2 90.00 99.60 (Merck KGaA) 151 0.5 Xirallic F60-50 0.25 2 66.67 98.22 (Merck KGaA) 152 4.9 Xirallic F60-50 0.1 2 98.00 99.93 (Merck KGaA) 153 0.01 Xirallic F60-51 1 2 0.99 21.60 (Merck KGaA) 154 0.15 Xirallic F60-51 0.5 2 23.08 89.21 (Merck KGaA) 155 0.3 Xirallic F60-51 0.25 2 54.55 97.06 (Merck KGaA) 156 0.5 Xirallic F60-51 0.05 2 90.91 99.64 (Merck KGaA) 157 0.01 Xirallic F60-51 1 3 0.99 21.60 (Merck KGaA) 158 0.15 Xirallic F60-51 0.5 3 23.08 89.21 (Merck KGaA) 159 0.3 Xirallic F60-51 0.25 3 54.55 97.06 (Merck KGaA) 160 0.5 Xirallic F60-51 0.05 3 90.91 99.64 (Merck KGaA) 161 0.01 Xirallic F60-51 2 2 0.50 12.11 (Merck KGaA) 162 0.15 Xirallic F60-51 1.5 2 9.09 73.37 (Merck KGaA) 163 0.3 Xirallic F60-51 1 2 23.08 89.21 (Merck KGaA) 164 0.5 Xirallic F60-51 0.5 2 50.00 96.50 (Merck KGaA) 165 0.01 Xirallic F60-51 0.01 2 50.00 96.50 (Merck KGaA) 166 0.15 Xirallic F60-51 3 2 4.76 57.94 (Merck KGaA) 167 0.3 Xirallic F60-51 1.2 2 20.00 87.32 (Merck KGaA) 168 0.5 Xirallic F60-51 0.7 2 41.67 95.16 (Merck KGaA) 169 4.5 Xirallic F60-51 0.5 2 90.00 99.60 (Merck KGaA) 170 0.5 Xirallic F60-51 0.25 2 66.67 98.22 (Merck KGaA) 171 4.9 Xirallic F60-51 0.1 2 98.00 99.93 (Merck KGaA) 172 0.01 Pyrisma M40-58 1 2 0.99 21.60 (Merck KGaA) 173 0.15 Pyrisma M40-58 0.5 2 23.08 89.21 (Merck KGaA) 174 0.3 Pyrisma M40-58 0.25 2 54.55 97.06 (Merck KGaA) 175 0.5 Pyrisma M40-58 0.05 2 90.91 99.64 (Merck KGaA) 176 0.01 Pyrisma M40-58 1 3 0.99 21.60 (Merck KGaA) 177 0.15 Pyrisma M40-58 0.5 3 23.08 89.21 (Merck KGaA) 178 0.3 Pyrisma M40-58 0.25 3 54.55 97.06 (Merck KGaA) 179 0.5 Pyrisma M40-58 0.05 3 90.91 99.64 (Merck KGaA) 180 0.01 Pyrisma M40-58 2 2 0.50 12.11 (Merck KGaA) 181 0.15 Pyrisma M40-58 1.5 2 9.09 73.37 (Merck KGaA) 182 0.3 Pyrisma M40-58 1 2 23.08 89.21 (Merck KGaA) 183 0.5 Pyrisma M40-58 0.5 2 50.00 96.50 (Merck KGaA) 184 0.01 Pyrisma M40-58 0.01 2 50.00 96.50 (Merck KGaA) 185 0.15 Pyrisma M40-58 3 2 4.76 57.94 (Merck KGaA) 186 0.3 Pyrisma M40-58 1.2 2 20.00 87.32 (Merck KGaA) 187 0.5 Pyrisma M40-58 0.7 2 41.67 95.16 (Merck KGaA) 188 4.5 Pyrisma M40-58 0.5 2 90.00 99.60 (Merck KGaA) 189 0.5 Pyrisma M40-58 0.25 2 66.67 98.22 (Merck KGaA) 190 4.9 Pyrisma M40-58 0.1 2 98.00 99.93 (Merck KGaA) 191 0.5 SynCrystal 0.25 2 66.67 98.22 Silver (Eckart GmbH) 192 0.5 SYMIC B001 0.25 2 66.67 98.22 Silber (Eckart GmbH) 193 0.5 SYMIC C001 0.25 2 66.67 98.22 Silber (Eckart GmbH) 194 0.5 SYMIC C604 0.25 2 66.67 98.22 Silber (Eckart GmbH) 195 0.5 SYMIC OEM 0.25 2 66.67 98.22 X-fine Silver (Eckart GmbH) 196 0.5 SYMIC C393 0.25 2 66.67 98.22 Gold (Eckart GmbH) 197 0.5 SYMIC C522 0.25 2 66.67 98.22 Erdfarbton Kupfer (Eckart GmbH) 198 0.5 SYMIC C542 0.25 2 66.67 98.22 Erdfarbton Feuer-Rot (Eckart GmbH) 199 0.5 SYMIC OEM 0.25 2 66.67 98.22 Medium Space Gold (Eckart GmbH) 200 0.5 Mag napearl 0.25 2 66.67 98.22 1000 (BASF AG) 201 0.5 Mag napearl 0.25 2 66.67 98.22 2000 (BASF AG) 202 0.5 Mag napearl 0.25 2 66.67 98.22 3100 (BASF AG) 203 0.5 Lumina Brass 0.25 2 66.67 98.22 9232D (BASF AG) 204 0.5 Lumina Copper 0.25 2 66.67 98.22 9350D (BASF AG) 205 0.5 Lumina 0.25 2 66.67 98.22 Exterior Gold 2303D (BASF AG) 206 0.5 Lumina Russet 0.25 2 66.67 98.22 9450D (BASF AG) 207 0.5 Lumina Royal 0.25 2 66.67 98.22 Copper (BASF AG) 208 0.5 Lumina Royal 0.25 2 66.67 98.22 Magenta (BASF AG) 209 0.5 Lumina Royal 0.25 2 66.67 98.22 Blue (BASF AG) 210 0.5 Exterior Polar 0.25 2 66.67 98.22 White KC9119-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 211 0.5 Exterior Sterling 0.25 2 66.67 98.22 White KC9103-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 212 0.5 Exterior Fine 0.25 2 66.67 98.22 Gold Satin KC9201-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 213 0.5 Exterior Platinum 0.25 2 66.67 98.22 Pearl KC9205-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 214 0.5 Exterior Gold 0.25 2 66.67 98.22 Pearl KC9300-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 215 0.5 Exterior Royal 0.25 2 66.67 98.22 Gold KC9303-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 216 0.5 Exterior Royal 0.25 2 66.67 98.22 Gold Satin KC9323-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 217 0.5 Exterior Bright 0.25 2 66.67 98.22 Gold KC9307-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 218 0.5 Exterior Bronze 0.25 2 66.67 98.22 KC9502-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 219 0.5 Exterior Wine 0.25 2 66.67 98.22 Red KC9504-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 220 0.5 Exterior Ruby 0.25 2 66.67 98.22 KC9508-SW (Fujian Kuncai Fine Chemicals Co., Ltd.) 221 0.01 ADAMAS A-100D 1 2 0.99 21.60 (CQV Co., Ltd.) 222 0.15 ADAMAS A-100D 0.5 2 23.08 89.21 (CQV Co., Ltd.) 223 0.3 ADAMAS A-100D 0.25 2 54.55 97.06 (CQV Co., Ltd.) 224 0.5 ADAMAS A-100D 0.05 2 90.91 99.64 (CQV Co., Ltd.) 225 0.01 ADAMAS A-100D 1 3 0.99 21.60 (CQV Co., Ltd.) 226 0.15 ADAMAS A-100D 0.5 3 23.08 89.21 (CQV Co., Ltd.) 227 0.5 ADAMAS A-901K 0.25 2 66.67 98.22 Splendor White (CQV Co., Ltd.) 228 0.5 ADAMAS A-901S 0.25 2 66.67 98.22 Dazzling White (CQV Co., Ltd.) 229 0.15 ADAMAS A-901S 0.5 2 23.08 89.21 Dazzling White (CQV Co., Ltd.) 230 0.3 ADAMAS A-901S 0.25 2 54.55 97.06 Dazzling White (CQV Co., Ltd.) 231 0.5 ADAMAS A-901K 0.25 2 66.67 98.22 Splendor Gold (CQV Co., Ltd.) 232 0.15 ADAMAS A-901K 0.5 2 23.08 89.21 Splendor Gold (CQV Co., Ltd.) 233 0.3 ADAMAS A-901K 0.25 2 54.55 97.06 Splendor Gold (CQV Co., Ltd.) 234 0.5 ADAMAS A-701S 0.25 2 66.67 98.22 Dazzling Gold (CQV Co., Ltd.) 235 0.15 ADAMAS A-701S 0.5 2 23.08 89.21 Dazzling Gold (CQV Co., Ltd.) 236 0.3 ADAMAS A-701S 0.25 2 54.55 97.06 Dazzling Gold (CQV Co., Ltd.) 237 0.5 ADAMAS A-741S 0.25 2 66.67 98.22 Dazzling Red (CQV Co., Ltd.) 238 0.5 ADAMAS A-781K 0.25 2 66.67 98.22 Splendor Blue (CQV Co., Ltd.) 239 0.5 ADAMAS A-781S 0.25 2 66.67 98.22 Dazzling Blue (CQV Co., Ltd.) 240 0.5 ADAMAS A-620S 0.25 2 66.67 98.22 Dazzling Bronze (CQV Co., Ltd.) 241 0.15 ADAMAS A-620S 0.5 2 23.08 89.21 Dazzling Bronze (CQV Co., Ltd.) 242 0.3 ADAMAS A-620S 0.25 2 54.55 97.06 Dazzling Bronze (CQV Co., Ltd.) 243 0.5 ADAMAS A-640K 0.25 2 66.67 98.22 Splendor Copper (CQV Co., Ltd.) 244 0.15 ADAMAS A-640K 0.5 2 23.08 89.21 Splendor Copper (CQV Co., Ltd.) 245 0.3 ADAMAS A-640K 0.25 2 54.55 97.06 Splendor Copper (CQV Co., Ltd.) 246 0.5 ADAMAS A-640S 0.25 2 66.67 98.22 Dazzling Copper (CQV Co., Ltd.) 247 0.15 ADAMAS A-640S 0.5 2 23.08 89.21 Dazzling Copper (CQV Co., Ltd.) 248 0.3 ADAMAS A-640S 0.25 2 54.55 97.06 Dazzling Copper (CQV Co., Ltd.) 249 0.5 ADAMAS A-660K 0.25 2 66.67 98.22 Splendor Russet (CQV Co., Ltd.) 250 0.15 ADAMAS A-660K 0.5 2 23.08 89.21 Splendor Russet (CQV Co., Ltd.) 251 0.3 ADAMAS A-660K 0.25 2 54.55 97.06 Splendor Russet (CQV Co., Ltd.) 252 0.5 ADAMAS A-660S 0.25 2 66.67 98.22 Dazzling Russet (CQV Co., Ltd.) 253 0.5 CHAOS C-901M 0.25 2 66.67 98.22 Rutile Ultra Silk (CQV Co., Ltd.) 254 0.5 CHAOS C-901D 0.25 2 66.67 98.22 Rutile Fine White (CQV Co., Ltd.) 255 0.5 CHAOS C-900D 0.25 2 66.67 98.22 Fine White (CQV Co., Ltd.) 256 0.5 CHAOS C-907K 0.25 2 66.67 98.22 Skye White (CQV Co., Ltd.) 257 0.5 CHAOS C-901K 0.25 2 66.67 98.22 Splendor White (CQV Co., Ltd.) 258 0.5 CHAOS C-901S 0.25 2 66.67 98.22 Rutile Dazzling Standard (CQV Co., Ltd.) 259 0.5 CHAOS C-900S 0.25 2 66.67 98.22 Dazzling Standard (CQV Co., Ltd.) 260 0.5 CHAOS C-902S 0.25 2 66.67 98.22 Super White (CQV Co., Ltd.) 261 0.5 CHAOS C-109S 0.25 2 66.67 98.22 Super Pearl (CQV Co., Ltd.) 262 0.5 CHAOS C-109B 0.25 2 66.67 98.22 Shimmering White (CQV Co., Ltd.) 263 0.5 CHAOS C-901E 0.25 2 66.67 98.22 Glitter Pearl (CQV Co., Ltd.) 264 0.5 FERRIUS F-620K 0.25 2 66.67 98.22 Splendor Bronze (CQV Co., Ltd.) 265 0.5 FERRIUS F-630K 0.25 2 66.67 98.22 Splendor Orange (CQV Co., Ltd.) 266 0.5 FERRIUS F-640K 0.25 2 66.67 98.22 Splendor Copper (CQV Co., Ltd.) 267 0.5 FERRIUS F-660K 0.25 2 66.67 98.22 Splendor Russet (CQV Co., Ltd.) 268 0.5 FERRIUS F-620P 0.25 2 66.67 98.22 Crystal Bronze (CQV Co., Ltd.) 269 0.5 FERRIUS F-630P 0.25 2 66.67 98.22 Crystal Orange (CQV Co., Ltd.) 270 0.5 FERRIUS F-640P 0.25 2 66.67 98.22 Crystal Copper (CQV Co., Ltd.) 271 0.5 FERRIUS F-660P 0.25 2 66.67 98.22 Crystal Russet (CQV Co., Ltd.) 272 0.5 Magchrom N-5001C 0.25 2 66.67 98.22 Natural Corona Gold (CQV Co., Ltd.) 273 0.5 Magchrom N-5001S 0.25 2 66.67 98.22 Natural Dazzling Gold (CQV Co., Ltd.) 274 0.5 Magchrom S-7801C 0.25 2 66.67 98.22 Corona Blue (CQV Co., Ltd.) 275 0.5 REFLEX RCN-1008S 0.25 2 66.67 98.22 Snow White Pearl (CQV Co., Ltd.) 276 0.5 Thermaval 0.25 2 66.67 88.33 Metallic Silver (Merck KGaA) 277 0.5 Thermaval 0.25 2 66.67 88.33 Metallic Gold (Merck KGaA) 278 0.5 Thermaval 0.25 2 66.67 88.33 Metallic Red (Merck KGaA) 279 0.5 Thermaval 0.25 2 66.67 88.33 Metallic Copper (Merck KGaA) 280 0.01 Iriodin 325 1 2 0.99 21.60 (Merck KGaA) 281 0.15 Iriodin 325 0.5 2 23.08 89.21 (Merck KGaA) 282 0.3 Iriodin 325 0.25 2 54.55 97.06 (Merck KGaA) 283 0.5 Iriodin 325 0.05 2 90.91 99.64 (Merck KGaA) 284 0.01 Iriodin 325 1 3 0.99 21.60 (Merck KGaA) 285 0.15 Iriodin 325 0.5 3 23.08 89.21 (Merck KGaA) 286 0.3 Iriodin 325 0.25 3 54.55 97.06 (Merck KGaA) 287 0.5 Iriodin 325 0.05 3 90.91 99.64 (Merck KGaA) 288 0.01 Iriodin 325 2 2 0.50 12.11 (Merck KGaA) 289 0.15 Iriodin 325 1.5 2 9.09 73.37 (Merck KGaA) 290 0.3 Iriodin 325 1 2 23.08 89.21 (Merck KGaA) 291 0.5 Iriodin 325 0.5 2 50.00 96.50 (Merck KGaA) 292 0.01 Iriodin 325 0.01 2 50.00 96.50 (Merck KGaA) 293 0.15 Iriodin 325 3 2 4.76 57.94 (Merck KGaA) 294 0.3 Iriodin 325 1.2 2 20.00 87.32 (Merck KGaA) 295 0.5 Iriodin 325 0.7 2 41.67 95.16 (Merck KGaA) 296 4.5 Iriodin 325 0.5 2 90.00 99.60 (Merck KGaA) 297 0.5 Iriodin 325 0.25 2 66.67 98.22 (Merck KGaA) 298 4.9 Iriodin 325 0.1 2 98.00 99.93 (Merck KGaA)

TABLE-US-00002 TABLE 2 Particle size Trade name Manufacturer Substrate Coating [m] Xirallic Crystal Silver Merck KGaA Al.sub.2O.sub.3 TiO.sub.2 5-35 Iriodin 103 Merck KGaA Natural mica TiO.sub.2 10-60 Iriodin 305 Merck KGaA Natural mica Fe.sub.2O.sub.3 and 10-60 TiO.sub.2 Iriodin 4504 Lava Red Merck KGaA SiO.sub.2 Fe.sub.2O.sub.3 5-50 Iriodin 9219 Merck KGaA Natural mica TiO.sub.2 10-60 Iriodin 9444 Merck KGaA Natural mica Cr.sub.2O.sub.3 5-40 Iriodin 9504 Merck KGaA Natural mica Fe.sub.2O.sub.3 10-60 Xirallic F60-50 Merck KGaA Al.sub.2O.sub.3 Fe.sub.2O.sub.3 5-35 Xirallic F60-51 Merck KGaA Al.sub.2O.sub.3 Fe.sub.2O.sub.3 5-35 Pyrisma M40-58 Merck KGaA Natural mica Fe.sub.2O.sub.3 and 5-40 TiO.sub.2 SynCrystal Silver Eckart GmbH Synthetic mica TiO.sub.2 10-50 SYMIC B001 Silver Eckart GmbH Synthetic mica TiO.sub.2 5-25 SYMIC C001 Silver Eckart GmbH Synthetic mica TiO.sub.2 10-40 SYMIC C604 Silver Eckart GmbH Synthetic mica TiO.sub.2 10-40 SYMIC OEM X-fine Eckart GmbH Synthetic mica TiO.sub.2 3-15 Silver SYMIC C393 Gold Eckart GmbH Synthetic mica Fe.sub.2O.sub.3 and 10-40 TiO.sub.2 SYMIC C522 Copper Eckart GmbH Synthetic mica Fe.sub.2O.sub.3 10-40 Earth Shade SYMIC C542 Fire Eckart GmbH Synthetic mica Fe.sub.2O.sub.3 10-40 Red Earth Shade SYMIC OEM Medium Eckart GmbH Synthetic mica Fe.sub.2O.sub.3 and 12-38 Space Gold TiO.sub.2 Magnapearl 1000 BASF AG Natural mica TiO.sub.2 6-48 Magnapearl 2000 BASF AG Natural mica TiO.sub.2 5-25 Magnapearl 3100 BASF AG Natural mica TiO.sub.2 2-10 Lumina Brass 9232D BASF AG Natural mica Fe.sub.2O.sub.3 and 10-48 TiO.sub.2 Lumina Copper 9350D BASF AG Natural mica Fe.sub.2O.sub.3 8-48 Lumina Exterior BASF AG Natural mica TiO.sub.2 8-48 Gold 2303D Lumina Russet 9450D BASF AG Natural mica Fe.sub.2O.sub.3 8-48 Lumina Royal Copper BASF AG Natural mica TiO.sub.2 10-34 Lumina Royal Magenta BASF AG Natural mica TiO.sub.2 10-34 Lumina Royal Blue BASF AG Natural mica TiO.sub.2 10-34 Exterior Polar White Fujian Kuncai Natural mica TiO.sub.2 5-25 KC9119-SW Fine Chemi- cals Co., Ltd. Exterior Sterling White Fujian Kuncai Natural mica TiO.sub.2 10-45 KC9103-SW Fine Chemicals Co., Ltd. Exterior Fine Gold Fujian Kuncai Natural mica TiO.sub.2 5-25 Satin KC9201-SW Fine Chemicals Co., Ltd. Exterior Platinum Pearl Fujian Kuncai Natural mica TiO.sub.2 10-45 KC9205-SW Fine Chemicals Co., Ltd. Exterior Royal Gold Fujian Kuncai Natural mica Fe.sub.2O.sub.3 and 10-45 KC9303-SW Fine Chemicals TiO.sub.2 Co., Ltd. Exterior Royal Gold Fujian Kuncai Natural mica Fe.sub.2O.sub.3 and 5-25 Satin KC9323-SW Fine Chemicals TiO.sub.2 Co., Ltd. Exterior Bright Gold Fujian Kuncai Natural mica Fe.sub.2O.sub.3 and 10-60 KC9307-SW Fine Chemicals TiO.sub.2 Co., Ltd. Exterior Brown Fujian Kuncai Natural mica Fe.sub.2O.sub.3 8-45 KC9502-SW Fine Chemicals Co., Ltd. Exterior Wine Red Fujian Kuncai Natural mica Fe.sub.2O.sub.3 8-45 KC9504-SW Fine Chemicals Co., Ltd. Exterior Ruby Fujian Kuncai Natural mica Fe.sub.2O.sub.3 8-45 KC9508-SW Fine Chemicals Co., Ltd. ADAMAS A-100D CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 3-30 ADAMAS A-901K CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 5-30 Splendor White ADAMAS A-901S CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 9-45 Dazzling White ADAMAS A-901K CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 5-30 Splendor Gold ADAMAS A-701S CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 9-45 Dazzling Gold ADAMAS A-741S CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 9-45 Dazzling Red ADAMAS A-781K CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 5-30 Splendor Blue ADAMAS A-781S CQV Co., Ltd. Al.sub.2O.sub.3 TiO.sub.2 9-45 Dazzling Blue ADAMAS A-620S CQV Co., Ltd. Al.sub.2O.sub.3 Fe.sub.2O.sub.3 9-45 Dazzling Bronze ADAMAS A-640S CQV Co., Ltd. Al.sub.2O.sub.3 Fe.sub.2O.sub.3 9-45 Dazzling Copper ADAMAS A-660S CQV Co., Ltd. Al.sub.2O.sub.3 Fe.sub.2O.sub.3 9-45 Dazzling Russet CHAOS C-901M CQV Co., Ltd. Synthetic mica TiO.sub.2 3-17 Rutile Ultra Silk CHAOS C-901D CQV Co., Ltd. Synthetic mica TiO.sub.2 5-25 Rutile Fine White CHAOS C-900D CQV Co., Ltd. Synthetic mica TiO.sub.2 5-25 Fine White CHAOS C-907K CQV Co., Ltd. Synthetic mica TiO.sub.2 5-35 Sky White CHAOS C-901K CQV Co., Ltd. Synthetic mica TiO.sub.2 5-35 Splendor White CHAOS C-901S CQV Co., Ltd. Synthetic mica TiO.sub.2 9-45 Rutile Dazzling Standard CHAOS C-900S CQV Co., Ltd. Synthetic mica TiO.sub.2 9-45 Dazzling Standard CHAOS C-902S CQV Co., Ltd. Synthetic mica TiO.sub.2 9-45 Super White CHAOS C-109S CQV Co., Ltd. Synthetic mica TiO.sub.2 9-41 Super Pearl CHAOS C-109B CQV Co., Ltd. Synthetic mica TiO.sub.2 13-60 Shimmering White CHAOS C-901E CQV Co., Ltd. Synthetic mica TiO.sub.2 17-100 Glitter Pearl FERRIUS F-620K CQV Co., Ltd. Synthetic mica Fe.sub.2O.sub.3 5-35 Splendor Bronze FERRIUS F-630K CQV Co., Ltd. Synthetic mica Fe.sub.2O.sub.3 5-35 Splendor Orange FERRIUS F-640K CQV Co., Ltd. Synthetic mica Fe.sub.2O.sub.3 5-35 Splendor Copper FERRIUS F-660K CQV Co., Ltd. Synthetic mica Fe.sub.2O.sub.3 5-35 Splendor Russet FERRIUS F-620P CQV Co., Ltd. Synthetic mica Fe.sub.2O.sub.3 25-150 Crystal Bronze FERRIUS F-630P CQV Co., Ltd. Synthetic mica Fe.sub.2O.sub.3 25-150 Crystal Orange FERRIUS F-640P CQV Co., Ltd. Synthetic mica Fe.sub.2O.sub.3 25-150 Crystal Copper FERRIUS F-660P CQV Co., Ltd. Synthetic mica Fe.sub.2O.sub.3 25-150 Crystal Russet Magchrom N-5001C CQV Co., Ltd. Nat. mica TiO.sub.2 7-30 Natural Corona Gold Magchrom N-5001S CQV Co., Ltd. Nat. mica TiO.sub.2 9-45 Natural Dazzling Gold Magchrom S-7801C CQV Co., Ltd. Synthetic mica TiO.sub.2 7-27 Corona Blue

[0199] Without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invention to its fullest extent. The preceding preferred specific embodiments are, therefore, to be construed as merely illustrative, and not limitative of the remainder of the disclosure in any way whatsoever.

[0200] In the foregoing and in the examples, all temperatures are set forth uncorrected in degrees Celsius and, all parts and percentages are by weight, unless otherwise indicated.

[0201] The entire disclosures of all applications, patents and publications, cited herein and of corresponding Singapore application No. 10201803807.X, filed May 4, 2018, are incorporated by reference herein.

[0202] The preceding examples can be repeated with similar success by substituting the generically or specifically described reactants and/or operating conditions of this invention for those used in the preceding examples.

[0203] From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of this invention and, without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.