SYNAPSE DEVICE, MANUFACTURING METHOD THEREOF, AND NEUROMORPHIC DEVICE INCLUDING SYNAPSE DEVICE
20240136445 ยท 2024-04-25
Inventors
Cpc classification
H01L29/792
ELECTRICITY
H01L29/42348
ELECTRICITY
H01L29/40117
ELECTRICITY
H01L29/66833
ELECTRICITY
H01L29/513
ELECTRICITY
G11C16/0466
PHYSICS
International classification
H01L29/792
ELECTRICITY
H01L29/423
ELECTRICITY
H01L21/28
ELECTRICITY
Abstract
A synapse device, a manufacturing method thereof, and a neuromorphic device including the synapse device are disclosed. The synapse device may include a channel member, a tunnel insulating layer disposed on the channel member, a charge trap layer disposed on the tunnel insulating layer, a blocking insulating layer disposed on the charge trap layer, a gate electrode disposed on the blocking insulating layer, a first terminal and a second terminal respectively connected to first and second regions of the channel member, and first and second conductors respectively bonded to the first and second terminals The charge trap layer may have a multilayer structure including a first trap layer disposed adjacent to the channel member and a second trap layer disposed adjacent to the gate electrode. The first trap layer may have a trap of a shallower level than that of the second trap layer.
Claims
1. A synapse device comprising: a channel member; a tunnel insulating layer disposed on the channel member; a charge trap layer disposed on the tunnel insulating layer; a blocking insulating layer disposed on the charge trap layer; a gate electrode disposed on the blocking insulating layer; a first terminal and a second terminal respectively connected to first and second regions of the channel member; and first and second conductors respectively bonded to the first and second terminals, wherein the charge trap layer has a multilayer structure including a first trap layer disposed adjacent to the channel member and a second trap layer disposed adjacent to the gate electrode, and wherein the first trap layer has a trap of a shallower level than that of the second trap layer.
2. The synapse device of claim 1, wherein the first trap layer is a first silicon nitride layer, and the second trap layer is a second silicon nitride layer different from the first silicon nitride layer.
3. The synapse device of claim 2, wherein the first silicon nitride layer is a silicon (Si)-rich silicon nitride layer, and the second silicon nitride layer is a silicon nitride layer having a higher nitrogen (N) content than the first silicon nitride layer.
4. The synapse device of claim 3, wherein the second silicon nitride layer includes silicon nitride having a stoichiometric composition, or N-rich silicon nitride, or both.
5. The synapse device of claim 3, wherein the first silicon nitride layer has a silicon (Si) content in a range from about 43 at % to about 86 at %.
6. The synapse device of claim 3, wherein the second silicon nitride layer has a silicon (Si) content in a range from about 14 at % to about 43 at %.
7. The synapse device of claim 1, wherein the first trap layer has a smaller energy bandgap than that of the second trap layer.
8. The synapse device of claim 1, wherein the first terminal is a source and the second terminal is a drain, and wherein the source and the first conductor form a Schottky junction, and the drain and the second conductor form a Schottky junction.
9. The synapse device of claim 8, wherein each of the source and the drain has a doping concentration of 1?10.sup.16 to 2?10.sup.18 atoms/cm.sup.3.
10. A neuromorphic device comprising the synapse device according to claim 1.
11. The neuromorphic device of claim 10, further comprising a CMOS peripheral circuit connected to the synapse device.
12. A method for manufacturing a synapse device, the method comprising: forming a stacked structure by sequentially stacking a tunnel insulating layer, a charge trap layer, a blocking insulating layer, and a gate electrode on a channel member; forming a first terminal and a second terminal respectively connected to first and second regions of the channel member; and forming first and second conductors respectively bonded to the first and second terminals, wherein the charge trap layer is formed to have a multilayer structure including a first trap layer disposed adjacent to the channel member and a second trap layer disposed adjacent to the gate electrode, and wherein the first trap layer has a trap of a shallower level than that of the second trap layer.
13. The method of claim 12, wherein the first trap layer is a first silicon nitride layer, and the second trap layer is a second silicon nitride layer different from the first silicon nitride layer.
14. The method of claim 13, wherein the first silicon nitride layer is a silicon (Si)-rich silicon nitride layer, and the second silicon nitride layer is a silicon nitride layer having a higher nitrogen (N) content than the first silicon nitride layer.
15. The method of claim 14, wherein the second silicon nitride layer includes silicon nitride having a stoichiometric composition, or N-rich silicon nitride, or both.
16. The method of claim 14, wherein the first silicon nitride layer has a silicon (Si) content in a range from about 43 at % to about 86 at %.
17. The synapse device of claim 14, wherein the second silicon nitride layer has a silicon (Si) content in a range from about 14 at % to about 43 at %.
18. The method of claim 12, wherein the first trap layer has a smaller energy bandgap than that of the second trap layer.
19. The method of claim 12, wherein the first terminal is a source and the second terminal is a drain, and wherein the source and the first conductor form a Schottky junction, and the drain and the second conductor form a Schottky junction.
20. The method of claim 19, wherein each of the source and the drain has a doping concentration of 1?10.sup.16 to 2?10.sup.18 atoms/cm.sup.3.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0029]
[0030]
[0031]
[0032]
[0033]
[0034]
[0035]
[0036]
[0037]
[0038]
DETAILED DESCRIPTION
[0039] Hereinafter, the embodiments of the present disclosure will be described in detail with reference to the accompanying drawings.
[0040] The embodiments of the present disclosure to be described below are provided to more clearly explain various embodiments of the present disclosure to those skilled in the art, and the scope of embodiments of the present disclosure is not limited by the following embodiments, and the embodiments may be modified in many different forms.
[0041] The terms used in this specification are used to describe specific embodiments and are not intended to limit embodiments of the present disclosure. The terms indicating a singular form used herein may include plural forms unless the context clearly indicates otherwise. Also, as used herein, the terms, comprise and/or comprising specify the presence of the stated shape, step, number, operation, member, element, and/or group thereof and do not exclude the presence or addition of one or more other shapes, steps, numbers, operations, elements, elements and/or groups thereof. In addition, the term, connection used in this specification indicates not only a direct connection of certain members, but also an indirect connection in which one or more other members are interposed between the connected members.
[0042] In addition, in the present specification, when a member is said to be located on another member, this arrangement includes not only a case in which a member is in contact with another member, but also a case where another member exists between the two members. As used herein, the term, and/or includes any one and all combinations of one or more of the listed items. In addition, the terms of degree such as about and substantially used in the present specification are used as a range of values or degrees, or as a meaning close thereto, taking into account inherent manufacturing and material tolerances, and exact or absolute figures provided to aid in the understanding of this application are used to prevent the infringers from unfairly exploiting the stated disclosure.
[0043] Hereinafter, embodiments of the present disclosure will be described in detail with reference to the accompanying drawings. A size or a thickness of areas or parts shown in the accompanying drawings may be slightly exaggerated for clarity of the specification and convenience of description. The same reference numbers indicate the same configuring elements throughout the detailed description.
[0044]
[0045] Referring to
[0046] The substrate 10 may be, for example, a semiconductor substrate such as a silicon substrate. The silicon substrate may be a single crystal substrate. In this case, the channel member 12 may be, for example, a region (e.g., silicon region) doped with a first type of dopant (e.g., P-type dopant). Meanwhile, the source 14a and the drain 14b may be regions (silicon regions) doped with a second type of dopant (e.g., N-type dopant). However, the material of the substrate 10 is not limited to silicon and may be changed according to circumstances. For example, the substrate 10 may be any one of various substrates such as a silicon substrate, a germanium substrate, a silicon-germanium substrate, and a silicon carbide substrate.
[0047] The tunnel insulating layer 20 may be formed of an insulating material such as, for example, silicon oxide (e.g., SiO.sub.2) However, the material of the tunnel insulating layer 20 is not limited to silicon oxide and may be varied in some cases.
[0048] The blocking insulating layer 40 may be formed of an insulating material such as, for example, silicon oxide (e.g., SiO.sub.2) However, the material of the blocking insulating layer 40 is not limited to silicon oxide, and may be varied in some cases.
[0049] The gate electrode 50 may include, for example, silicon. In this case, the gate electrode 50 may include highly doped polycrystalline silicon. However, the material of the gate electrode 50 is not limited thereto and may be variously changed depending on the case.
[0050] The charge trap layer 30 may have a multilayer structure. The charge trap layer 30 may have a multilayer structure including a first trap layer 31 disposed adjacent to the channel member 12 and a second trap layer 32 disposed adjacent to the gate electrode 50. The multilayer structure may be, for example, a double-layer structure. The first trap layer 31 may be disposed to contact the tunnel insulating layer 20. The first trap layer 31 may be disposed between the tunnel insulating layer 20 and the second trap layer 32. The second trap layer 32 may be disposed to be in contact with the blocking insulating layer 40. The second trap layer 32 may be disposed between the first trap layer 31 and the blocking insulating layer 40.
[0051] The first trap layer 31 may have a trap of a shallower level than that of the second trap layer 32, that is, the second trap layer 32 may have a trap of a deeper level than that of the first trap layer 31. In other words, the first trap layer 31 may have a shallower trap level than the second trap layer 32, that is, the second trap layer 32 may have a deeper trap level than the first trap layer 31. Also, the first trap layer 31 may have a smaller energy bandgap than that of the second trap layer 32.
[0052] When the charge trap layer 30 includes the first trap layer 31 and the second trap layer 32 as described above, as the charges (electrons) trapped in shallow traps of the first trap layer 31 may escape to the channel member 12 at a relatively high speed when a potentiation voltage (e.g., erase voltage) is applied, the synaptic operation speed may be improved. Specifically, since charges trapped in the first trap layer 31 may be discharged to the channel member 12 at a relatively high speed, an operation speed of a synapse device including the first and second trap layers 31 and 32 may be higher than that of a conventional synapse device having a single charge trap layer. In other words, the update speed of the weight of the synapse device may be increased. When the first trap layer 31 has a smaller energy bandgap than that of the second trap layer 32, the operation speed improvement effect may be further improved. Meanwhile, since the second trap layer 32 has a deep trap, charge retention characteristics of the charge trap layer 30 may be improved (secured) due to the second trap layer 32. During the potentiation operation by applying the potentiation voltage, the charges (electrons) trapped in the deep trap of the second trap layer 32 may move to the shallow trap of the first trap layer 31, and then, may exit to the channel member 12.
[0053] The first trap layer 31 and the second trap layer 32 may have different material configurations (compositions). The first trap layer 31 may be a first silicon nitride layer, and the second trap layer 32 may be a second silicon nitride layer different from the first silicon nitride layer. The first silicon nitride layer may be a Si-rich silicon nitride layer. When the first silicon nitride layer is referred to as Si.sub.xN.sub.y, x and y may satisfy the conditional expression x/y>?. The content of Si (silicon) in the first silicon nitride layer may be greater than 300/7 at %, and may be less than 600/7 at %. In other words, the Si content in the first silicon nitride layer may be greater than about 43 (e.g., 42.857) at %, and less than about 86 (e.g., 85.714) at %. When the Si content in the first silicon nitride layer is greater than about 43 at %, and less than about 86 at %, the operation speed of a synapse device including the first silicon nitride layer is significantly and unexpectedly increased compared to when the Si content in the first silicon nitride layer lies outside the range.
[0054] The second silicon nitride layer may be a silicon nitride layer having a higher nitrogen (N) content than the first silicon nitride layer. For example, the second silicon nitride layer may include silicon nitride having a stoichiometric composition, or N-rich silicon nitride, or both. When the second silicon nitride layer is referred to as Si.sub.xN.sub.y, x and y may satisfy the conditional expression x/y??. The content of Si in the second silicon nitride layer may be equal to or less than 300/7 at %, and may be greater than 100/7 at %. In other words, the Si content in the second silicon nitride layer may be greater than about 14 (e.g., 14.285) at % and equal to or less than about 43 (e.g., 42.857) at %. When the Si content in the second silicon nitride layer is greater than about 14 at % and less than about 43 at %, the charge retention characteristics of the charge trap layer 30 is significantly and unexpectedly improved compared to when the Si content in the second silicon nitride layer lies outside the range.
[0055] When the first trap layer 31 is composed of the first silicon nitride layer and the second trap layer 32 is composed of the second silicon nitride layer, the first trap layer 31 may have trap of a shallower level than that of the second trap layer 32, That is, the second trap layer 32 may have trap of a deeper level than that of the first trap layer 31. Also, the first trap layer 31 may have a smaller energy bandgap than that of the second trap layer 32.
[0056] Meanwhile, a thickness of the first trap layer 31 may be substantially the same as or different from a thickness of the second trap layer 32. As a non-limiting example, the thickness of the first trap layer 31 may be about 2 to 5 nm. The thickness of the second trap layer 32, as a non-limiting example, may be about 2 to 5 nm. When these thickness conditions are satisfied, it may be advantageous to secure excellent charge trap characteristics and synaptic operation speed improvement characteristics.
[0057] Also, according to an embodiment of the present invention, the source 14a and the first conductor 70a may form a Schottky junction, and the drain 14b and the second conductor 70b may form a Schottky junction. In other words, a Schottky contact may be formed between the source 14a and the first conductor 70a, and similarly, a Schottky contact may be formed between the drain 14b and the second conductor 70b.
[0058] The first and the second conductors 70a and 70b may be made of a predetermined metal or metallic material. As the material of the first and the second conductors 70a and 70b, any metal contact material of a general electronic device may be applied. Each of the source 14a and the drain 14b may have a doping level corresponding to the N? level. For example, each of the source 14a and the drain 14b may have a doping concentration of about 1?10.sup.16 to 2?10.sup.18 atoms/cm.sup.3. Under these conditions, the source 14a may form a Schottky junction with the first conductor 70a, and the drain 14b may form a Schottky junction with the second conductor 70b.
[0059] As such, when a Schottky junction is formed between the source 14a/drain 14b and the first conductor 70a/second conductor 70b, unlike a typical charge trap-based device, a current section due to a tunneling (TU) mechanism may be generated between a current section due to a thermionic emission (TE) mechanism and a current section due to a drift mechanism, and linearity of weight control (update) of the synapse device may be easily secured by using the current section due to the tunneling (TU) mechanism. For example, the weight of a synapse device according to an embodiment of the present disclosure characterized by conductance of device may substantially linearly vary with the number of pulses applied to the device in the current section due to the tunneling (TU) mechanism, thereby improving linearity of the device compared to a conventional charge trap-based memory device without having the current section due to the tunneling (TU) mechanism.
[0060] Although not shown in
[0061]
[0062] Referring to
[0063] In
[0064]
[0065] Referring to
[0066] The first trap layer 31 may have a trap of a shallower level than that of the second trap layer 32, that is, the second trap layer 32 may have a trap of a deeper level than that of the first trap layer 31. In other words, the first trap layer 31 may have a shallower trap level than the second trap layer 32, that is, the second trap layer 32 may have a deeper trap level than the first trap layer 31.
[0067] In a case that the charge trap layer 30 includes the first trap layer 31 and the second trap layer 32, since the charges (electrons) trapped in shallow traps of the first trap layer 31 may escape to the channel member 12 at a relatively high speed when a potentiation voltage (e.g., an erase voltage) is applied, the synaptic operation speed may be improved. In other words, the update speed of the weight of the synapse device may be increased. Meanwhile, since the second trap layer 32 has a deep trap, charge retention characteristics of the charge trap layer 30 may be improved (secured) by the second trap layer 32. During the potentiation operation by applying the potentiation voltage, the charges (electrons) trapped in the deep trap of the second trap layer 32 may move to the shallow trap of the first trap layer 31, and then may exit towards the channel member 12.
[0068]
[0069] Referring to
[0070] When a Schottky junction is formed between the source 14a/drain 14b and the first conductor 70a/second conductor 70b, unlike a typical charge trap-based device, a current section due to a tunneling (TU) mechanism may be generated between a current section due to a thermionic emission (TE) mechanism and a current section due to a drift mechanism, and linearity of weight control (update) of the synapse device may be secured by using the current section due to the tunneling (TU) mechanism.
[0071]
[0072] Referring to
[0073] In the case of a charge trap memory with a general SONOS (silicon/oxide/nitride/oxide/silicon) structure, I.sub.D-V.sub.G curve may include only a current section by thermionic emission (TE) mechanism and a current section by drift mechanism. However, as in the embodiment of the present disclosure, when a Schottky junction is formed between the source 14a/drain 14b and the first conductor 70a/second conductor 70b, a current section by the tunneling (TU) mechanism may be generated between the current section by the thermionic emission (TE) mechanism and the current section by the drift mechanism. In the current section by the tunneling (TU) mechanism, it is possible to easily secure a linear change characteristic of current. The current section by the tunneling (TU) mechanism may have a relatively smooth slope.
[0074]
[0075] Referring to
[0076]
[0077] Referring to
[0078] When a synapse which is a connection between a pre-neuron and a post-neuron is configured as a circuit, the synapse device according to an embodiment of the present disclosure may be applied. A pre-neuron may input a pre-spike signal into a synapse, the synapse may transmit a synaptic signal to a post-neuron, and a post-neuron may generate a post-spike signal. Similar to a method in which a synapse connects a pre-neuron and a post-neuron, the synapse device may connect a pre-synaptic neuron circuit and a post-synaptic neuron circuit. A circuit diagram of this configuration may be shown as
[0079]
[0080] Referring to
[0081]
[0082] Referring to
[0083] A pre-spike signal may be applied from the pre-synaptic neuron circuit N10 to the gate electrode of the synapse device S10 through the first wiring W10. A post-synaptic current may flow to the post-synaptic neuron circuit N20 through the source of the synapse device S10. A post-spike signal may be generated from the post-synaptic neuron circuit N20.
[0084] According to an embodiment of the present disclosure, it is possible to configure a neuromorphic device and system to which one or more synapse devices according to the above embodiment are applied. The neuromorphic device may include a CMOS peripheral circuit connected to the synapse devices. The CMOS peripheral circuit may include a pre-synaptic neuron circuit and a post-synaptic neuron circuit, etc. The plurality of synapse devices according to an embodiment of the present disclosure, for example, may have an array structure as described in
[0085]
[0086] Referring to
[0087] Referring to
[0088] The charge trap layer 300 may be formed to have a multilayer structure including a first trap layer 310 adjacent to the substrate 100 and a second trap layer 320 adjacent to the gate electrode 500. The first trap layer 310 may have a trap of a shallower level than that of the second trap layer 320, that is, the second trap layer 320 may have a trap of a deeper level than that of the first trap layer 310. For example, the first trap layer 310 may be a first silicon nitride layer, and the second trap layer 320 may be a second silicon nitride layer different from the first silicon nitride layer. The first silicon nitride layer may be a Si-rich silicon nitride layer, and the second silicon nitride layer may be a silicon nitride layer having a higher nitrogen (N) content than the first silicon nitride layer. The second silicon nitride layer may include silicon nitride having a stoichiometric composition, or N-rich silicon nitride, or both. The first trap layer 310 may have a smaller energy bandgap than that of the second trap layer 320. The material, the characteristics, and the thickness of each of the first trap layer 310 and the second trap layer 320 may correspond to the material, the characteristics, and the thickness of each of the first trap layer 31 and the second trap layer 32 described with reference to
[0089] Referring to
[0090] Referring to
[0091] According to an embodiment, the source 140a and the first conductor 700a may form a Schottky junction, and similarly, the drain 140b and the second conductor 700b also form a Schottky junction. In this regard, each of the source 140a and the drain 140b may have a doping level corresponding to the N? level. For example, each of the source 140a and the drain 140b may have a doping concentration of about 1?10.sup.16 to 2?10.sup.18 atoms/cm.sup.3. Under these conditions, the source 140a may form a Schottky junction with the first conductor 700a, and the drain 140b may form a Schottky junction with the second conductor 700b.
[0092] Although not shown in
[0093] The synapse device manufactured by the method of
[0094] Additionally, although
[0095] According to the embodiments of the present disclosure described above, it is possible to implement a synapse device capable of increasing the speed of an operation related to synaptic weight update. In addition, according to embodiments of the present disclosure, it is possible to implement a synapse device capable of securing or improving linearity when adjusting synaptic weights. In addition, according to embodiments of the present disclosure, it is possible to implement a synapse device having excellent process compatibility with CMOS technology. For example, a synapse device according to embodiments may be substantially completely compatible with conventional CMOS technology. Therefore, the synapse device according to these embodiments may be used as an artificial synapse which may replace a biological synapse, and may be usefully used for a neuromorphic device (neuromorphic system) and a neural network.
[0096] In this specification, the preferred embodiments of the present disclosure have been disclosed, and although specific terms have been used, they are only used in a general sense to easily explain the technological content of the present disclosure and to help understanding embodiments of the present disclosure, and they are not used to limit the scope of embodiments of the present disclosure. It is obvious to those having ordinary skill in the related art to which the present disclosure belong that other modifications based on the technological idea of the present disclosure may be implemented in addition to the embodiments disclosed herein. It will be understood to those having ordinary skill in the related art that in connection with a synapse device, a manufacturing method thereof, and a neuromorphic device including the synapse device according to the embodiments described with reference to
EXPLANATION OF SYMBOLS
[0097]
TABLE-US-00001 * Explanation of symbols for the main parts of the drawing * 10: substrate 12: channel member 14a: source 14b: drain 20: tunnel insulating layer 30: charge trap layer 31: first trap layer 32: second trap layer 40: blocking insulating layer 50: gate electrode 70a: first conductor 70b: second conductor N1: pre-synaptic neuron circuit N2: post-synaptic neuron circuit N10: pre-synaptic neuron circuit N20: post-synaptic neuron circuit S10: synapse device W10: first wiring W20: second wiring