PAINT COMPOSITION FOR VEHICLE INTERMEDIATE COATING WITH IMPROVED CHIPPING RESISTANCE

Abstract

A paint composition for vehicle intermediate coating including a polyester resin, a melamine resin, a color pigment, an extender pigment, cellulose nanofibers (CNFs), a dispersant, a surface conditioner, an antisagging agent, and a solvent. The extender pigment may include calcium carbonate (CaCO.sub.3). The paint composition can impart improved chipping resistance to a paint film.

Claims

1. A paint composition comprising: a polyester resin; a melamine resin; a color pigment; an extender pigment; cellulose nanofibers (CNFs); a dispersant; a surface conditioner; an antisagging agent; and a solvent.

2. The paint composition of claim 1, wherein, based on a total weight of the paint composition, the paint composition comprises: 15 wt % to 20 wt % of the polyester resin; 7 wt % to 13 wt % of the melamine resin; 15.1 wt % to 20.3 wt % of the color pigment; 8 wt % to 15 wt % of the extender pigment; 3 wt % to 4 wt % of the cellulose nanofibers; 0.5 wt % to 1 wt % of the dispersant; 0.5 wt % to 1.5 wt % of the surface conditioner; 4 wt % to 6 wt % of the antisagging agent; and 30 wt % to 43 wt % of the solvent.

3. The paint composition of claim 1, wherein the color pigment comprises titanium dioxide (TiO.sub.2) and carbon black, wherein, based on a total weight of the paint composition, the paint composition comprises: 15 wt % to 20 wt % of the titanium dioxide (TiO.sub.2), and 0.1 wt % to 0.3 wt % of the carbon black.

4. The paint composition of claim 1, wherein the extender pigment comprises calcium carbonate (CaCO.sub.3).

5. The paint composition of claim 1, wherein the cellulose nanofibers (CNFs) have a width of 10 to 100 nm, and a length of 1 to 5 ?m.

6. The paint composition of claim 1, wherein the dispersant comprises a silicone-free polyester polymer.

7. The paint composition of claim 1, wherein the surface conditioner comprises a silicone-modified acrylic resin.

8. The paint composition of claim 1, wherein the antisagging agent comprises at least one selected from the group consisting of acrylic derivatives and modified urethane.

9. The paint composition of claim 1, wherein the solvent comprises distilled water, an alcohol-based solvent, and a glycol-based solvent, wherein, based on a total weight of the paint composition, the paint composition comprises: 25 wt % to 35 wt % of the distilled water; 4 wt % to 6 wt % a content of the alcohol-based solvent; and 1 wt % to 2 wt % a content of the glycol-based solvent.

10. A paint film manufactured using the paint composition of claim 1, wherein the paint film has a chipping resistance evaluation grade of Grade 2 or less as evaluated at an air pressure of 5 kgf/cm.sup.2 and a temperature of ?20? C. using as a gravelometer.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0020] The above and other features of the present disclosure will now be described in detail with reference to certain exemplary embodiments thereof illustrated in the accompanying drawing which is given hereinbelow by way of illustration only, and thus is not limitative of the present disclosure, and wherein:

[0021] FIGURE is a diagram showing chipping resistance determination criteria in chipping resistance grade evaluation.

[0022] It should be understood that the appended drawing is not necessarily to scale, presenting a somewhat simplified representation of various preferred features illustrative of the basic principles of the disclosure. The specific design features of the present disclosure as disclosed herein, including, for example, specific dimensions, orientations, locations, and shapes, will be determined in part by the particular intended application and use environment.

[0023] In the FIGURES, reference numbers refer to the same or equivalent parts of the present disclosure throughout the several FIGURES of the drawings.

DETAILED DESCRIPTION

[0024] The above-described objects, other objects, advantages and features of the present disclosure will become apparent from the descriptions of embodiments given hereinbelow with reference to the accompanying drawings. However, the present disclosure is not limited to the embodiments disclosed herein and may be implemented in various different forms. The embodiments are provided to make the description of the present disclosure thorough and to fully convey the scope of the present disclosure to those skilled in the art.

[0025] In the following description of the embodiments, terms, such as including, comprising and having, are to be interpreted as indicating the presence of characteristics, numbers, steps, operations, elements or parts stated in the description or combinations thereof, and do not exclude the presence of one or more other characteristics, numbers, steps, operations, elements, parts or combinations thereof, or possibility of adding the same.

[0026] All numbers, values and/or expressions representing amounts of components, reaction conditions, polymer compositions and blends used in the description are approximations in which various uncertainties in measurement generated when these values are acquired from essentially different things are reflected and thus it will be understood that they are modified by the term about, unless stated otherwise. In addition, it will be understood that, if a numerical range is disclosed in the description, such a range includes all continuous values from a minimum value to a maximum value of the range, unless stated otherwise. Further, if such a range refers to integers, the range includes all integers from a minimum integer to a maximum integer, unless stated otherwise.

[0027] A paint composition according to the present disclosure includes a polyester resin, a melamine resin, a color pigment, an extender pigment, cellulose nanofibers (CNFs), a dispersant, a surface conditioner, an antisagging agent and a solvent.

[0028] Hereinafter, the respective components of the paint composition according to the present disclosure will be described in more detail.

[0029] (A) Polyester Resin

[0030] In the present disclosure, the polyester resin may be used as a base resin so as to provide to adhesiveness and main properties to the paint composition. The polyester resin serves to form the appearance characteristics and properties of a paint film manufactured using the paint composition including the polyester resin.

[0031] The content of the polyester resin may be 15 to 20 wt %, based on the total weight of the paint composition. When the content of the polyester resin is less than 15 wt %, the adhesive properties and main properties of the paint composition are reduced. On the other hand, when the content of the polyester resin exceeds 20 wt %, workability is reduced by use of the excessive amount of the polyester resin.

[0032] (B) Melamine Resin

[0033] In the present disclosure, the melamine resin may be used as a base resin so as to provide to hardenability and the main properties to the paint composition. The melamine resin serves to form the appearance characteristics and properties of the paint film manufactured using the paint composition including the melamine resin.

[0034] The melamine resin may include at least one selected from the group consisting of a butoxy and methoxy mixed melamine resin and a methylated melamine resin. For example, the melamine resin may include the butoxy and methoxy mixed melamine resin and the methylated melamine resin.

[0035] The content of the melamine resin may be 7 to 13 wt %, based on the total weight of the paint composition. When the content of the melamine resin is less than 7 wt %, the hardness of the paint film is reduced. On the other hand, when the content of the melamine resin exceeds 13 wt %, the paint film is excessively hardened and thus sanding workability is reduced.

[0036] (C) Color Pigment

[0037] The color pigment is colored powder, which is insoluble in water, oil and solvents, and endures sunlight, and is dispersed in resin varnish and used to allow the paint composition to have a designated color.

[0038] The content of the color pigment may be 15.1 to 20.3 wt %, based on the total weight of the paint composition. When the content of the color pigment is less than 15.1 wt % or exceeds 20.3 wt %, it is difficult to implement the designated color, and thus, the paint composition may include the color pigment which is within the above content range.

[0039] Concretely, the color pigment may include titanium dioxide (TiO.sub.2) and carbon black. More concretely, the color pigment may include 15 to 20 wt % of titanium dioxide (TiO.sub.2) and 0.1 to 0.3 wt % of carbon black, based on the total weight of the paint composition.

[0040] (D) Extender Pigment

[0041] The extender pigment may be a transparent white pigment with low coverage, which has a white color in the air, has a low refractive index, and thus becomes transparent when mixed with a vehicle.

[0042] In the present disclosure, the extender pigment may be used to improve workability.

[0043] The content of the extender pigment may be 8 to 15 wt %, based on the total weight of the paint composition. When the content of the color pigment is less than 8 wt %, coverage is reduced. On the other hand, when the content of the color pigment exceeds 15 wt %, the properties, including the adhesive properties, of the paint composition are reduced by use of the excessive amount of the extender pigment.

[0044] Concretely, the extender pigment may include calcium carbonate (CaCO.sub.3).

[0045] (E) Cellulose Nanofibers (CNFs)

[0046] In the present disclosure, the cellulose nanofibers (CNFs) may be used to improve chipping resistance.

[0047] In the cellulose nanofibers (CNFs), wooden biomass or non-wooden biomass, which is a raw material of nanocellulose, forms a hard configuration through binding of cellulose with materials, such as hemicellulose and lignin, and generally has a fiber diameter of 1 to 100 nm.

[0048] The content of the cellulose nanofibers (CNFs) may be 3 to 4 wt %, based on the total weight of the paint composition. When the content of the cellulose nanofibers (CNFs) is less than 3 wt %, chipping resistance improvement effect is insignificant. On the other hand, when the content of the cellulose nanofibers (CNFs) exceeds 4 wt %, use of the excessive amount of the cellulose nanofibers (CNFs) has a negative influence on the adhesive properties of the paint composition.

[0049] The cellulose nanofibers (CNFs) may have a width of 10 to 100 nm, and a length of 1 to 5 ?m. When the length of the cellulose nanofibers (CNFs) is less than 1 ?m, the cellulose nanofibers (CNFs) do not exhibit the chipping resistance improvement effect, and, when the length of the cellulose nanofibers (CNFs) exceeds 5 ?m, the cellulose nanofibers (CNFs) are tangled, and may thus clog a filter of a painting machine when a vehicle is coated with the paint composition.

[0050] (F) Dispersant

[0051] In the present disclosure, the dispersant may be used to uniformly disperse the cellulose nanofibers (CNFs).

[0052] The content of the dispersant may be 0.5 to 1 wt %, based on the total weight of the paint composition. When the content of the dispersant is less than 0.5 wt %, dispersion of the cellulose nanofibers (CNFs) is reduced and thus the cellulose nanofibers (CNFs) may be aggregated. On the other hand, when the content of the dispersant exceeds 1 wt %, use of the excessive amount of the dispersant may reduce interlayer adhesion of the paint film.

[0053] Concretely, the dispersant may use a silicone-free polyester polymer.

[0054] (G) Surface Conditioner

[0055] In the present disclosure, the surface conditioner may be used to improve leveling of the paint composition.

[0056] The content of the surface conditioner may be 0.5 to 1.5 wt %, based on the total weight of the paint composition. When the content of the surface conditioner is less than 0.5 wt %, leveling of the paint composition is reduced. On the other hand, when the content of the surface conditioner exceeds 1.5 wt %, use of the excessive amount of the surface conditioner may reduce workability.

[0057] Concretely, the surface conditioner may use a silicone-modified acrylic resin.

[0058] (H) Antisagging Agent

[0059] In the present disclosure, the antisagging agent may be used to provide thixotropy to the paint composition.

[0060] The content of the antisagging agent may be 4 to 6 wt %, based on the total weight of the paint composition. When the content of the antisagging agent is less than 4 wt %, sagging performance of the paint composition is reduced. On the other hand, when the content of the antisagging agent exceeds 6 wt %, leveling of the paint composition is reduced.

[0061] Concretely, the antisagging agent may use at least one elected from the group consisting of acrylic derivatives, modified urethane and combinations thereof.

[0062] (I) Solvent

[0063] In the present disclosure, the solvent may be used to provide painting workability of the paint composition. The solvent serves to adjust viscosity of the paint composition so as to improve workability of the paint composition.

[0064] The content of the solvent may be 30 to 43 wt %, based on the total weight of the paint composition. When the content of the solvent is less than 30 wt %, the viscosity of the paint composition is raised, and thus, workability of the paint composition is reduced during spray painting. On the other hand, when the content of the solvent exceeds 43 wt %, the viscosity of the paint composition is reduced, and thus, workability of the paint composition is reduced during spray painting.

[0065] Concretely, the solvent may include distilled water, an alcohol-based solvent and a glycol-based solvent. More concretely, the solvent may include 25 to 35 wt % of the distilled water, 4 to 6 wt % of the alcohol-based solvent, and 1 to 2 wt % of the glycol-based solvent, based on the total weight of the paint composition.

[0066] When chipping resistance of a paint film manufactured using the paint composition according to the present disclosure is evaluated at an air pressure of 5 kgf/cm.sup.2 and a temperature of ?20? C. using as a chipping testing apparatus called a gravelometer, the chipping resistance evaluation grade of the hardened paint film may be Grade 2 or less.

[0067] Particularly, the paint composition according to the present disclosure is not limited to a specific field of application, and may be applied as a paint for vehicle intermediate coating. Thereby, toughness of a paint film for intermediate coating is improved, and thus, damage to the paint film due to chipping by stones encountered during driving of a vehicle may be minimized.

[0068] Further, the paint composition according to the present disclosure may be applied to various fields including painting for plastics other than vehicle body painting.

[0069] Hereinafter, the present disclosure will be described in more detail through the following examples. The following examples serve merely to exemplarily describe the present disclosure, and are not intended to limit the scope of the invention.

Example

[0070] Paint compositions were prepared using components in contents set forth in Table 1 below by a general method.

TABLE-US-00001 TABLE 1 Component (wt %) Example 1 Comp. example 1 Comp. example 2 Comp. example 3 Comp. example 4 Resin (A) Polyester resin 16.5 16.5 16.5 17.2 16.9 (B) Melamine resin 11.0 11.0 11.0 11.8 11.3 Pigment (C-1) Color pigment 1 17.0 17.0 17.0 17.0 17.0 (C-2) Color pigment 2 0.3 0.3 0.3 0.3 0.3 (D) Extender pigment 11.7 12.3 11.0 12.1 12.0 Additives (E) CNFs 3.9 5.0 2.0 3.5 (F) Dispersant 0.7 0.5 0.7 0.1 (G) Surface conditioner 0.9 0.9 0.9 0.9 0.9 (H) Antisagging agent 4.3 4.3 4.3 4.3 4.3 Solvent (I-1) DIW (distilled water) 28.1 30.3 28.1 28.1 28.1 (I-2) Alcohol-based solvent 4.1 5.5 4.1 4.1 4.1 (I-3) Glycol-based solvent 1.5 1.9 1.5 1.5 1.5 Sum total 100.0 100.0 100.0 100.0 100.0 Color pigment 1: White pigment (TiO.sub.2) Color pigment 2: Black pigment (Carbon black) Extender pigment: CaCO.sub.3 Cellulose nanofibers (CNFs): CNFs having a width of 10 to 100 nm and a length of 1 to 5 ?m Dispersant: silicone-free polymer Surface conditioner: silicone-modified acrylic resin Antisagging agent: acrylic derivative

Test Example

[0071] Thereafter, chipping resistances of the paint compositions according to Example 1 and Comparative Examples 1 to 4 were measured by the following method, and measurement results are set forth in Table 2 below.

[0072] [Evaluation Method]

[0073] (1) Chipping Resistance: Paint Films manufactured using the respective paint compositions were evaluated under the following conditions using a gravelometer (i.e., a chipping test apparatus). [0074] Air pressure: 5 kgf/cm.sup.2, Temperature: ?20? C., Use of 50 g of crushed stone JIS7

[0075] FIGURE is a diagram showing chipping resistance determination criteria in chipping resistance grade evaluation. Concretely, the chipping resistance determination criteria shown in the FIGURE were applied, and indicates that the lower the grade, the better the chipping resistance. In the present disclosure, it was determined that the chipping resistance of a paint film is excellent when the chipping resistance of the paint film satisfies Grade 2 or less.

TABLE-US-00002 TABLE 2 Evaluation result Evaluation Comp. Comp. Comp. Comp. item Example 1 example 1 example 2 example 3 example 4 Chipping Grade 2.0 Grade 3.0 Grade 2.5 Grade 3.0 Grade 2.5 resistance

[0076] Referring to Table 2, it may be confirmed that the paint composition according to Comparative Example 1, in which the CNFs and any dispersant were not used, did exhibit little chipping resistance improvement effect, compared to the paint composition according to Example 1 of the present disclosure.

[0077] Further, it may be confirmed that the paint composition according to Comparative Example 2, in which the content of the CNFs exceeded 4 wt %, and the paint composition according to Comparative Example 3, in which the content of the CNFs was less than 3 wt %, exhibited little chipping resistance improvement effect, compared to the paint composition according to Example 1 of the present disclosure.

[0078] In addition, it may be confirmed that, in the paint composition according to Comparative Example 4, in which a proper CNF content was used but the content of the dispersant was less than 0.5 wt %, the CNFs were not sufficiently dispersed in the paint film, and thus, the paint composition according to Comparative Example 4 exhibited less chipping resistance improvement effect.

[0079] On the contrary, the paint composition according to Example 1 of the present disclosure was prepared by mixing the polyester resin, the melamine resin, the color pigment, the extender pigment, the cellulose nanofibers (CNFs), the dispersant, the surface conditioner, the antisagging agent, and the solvent in specific contents, and may thus improve chipping resistance of the paint film for intermediate coating, compared to the conventional paint compositions.

[0080] As is apparent from the above description, a paint composition according to the present disclosure is prepared by mixing a polyester resin, a melamine resin, a color pigment, an extender pigment, cellulose nanofibers (CNFs), a dispersant, a surface conditioner, an antisagging agent and a solvent in specific contents, thereby being capable of improving chipping resistance of a paint film for intermediate coating, compared to the conventional paint compositions.

[0081] Further, a paint film manufactured using the paint composition according to the present disclosure has excellent toughness, and may thus be applied to various fields, such as vehicle body painting and painting for plastics.

[0082] The disclosure has been described in detail with reference to preferred embodiments thereof. However, it will be appreciated by those skilled in the art that changes may be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.