Multipurpose drill system
11959381 ยท 2024-04-16
Assignee
Inventors
- Jeff William BRANSON (Head, AU)
- Warren Barry FAIR (Kalamunda, AU)
- Steven John PAYNE (Wooroloo, AU)
- James Daniel CHOMLEY (Meadow Springs, AU)
- John Edward KENNEDY (Jane Brook, AU)
- David Bruce CARNEGIE-SMITH (Walliston, AU)
Cpc classification
E21B7/022
FIXED CONSTRUCTIONS
International classification
Abstract
The present invention relates to a multipurpose drill system, the multipurpose drill system comprising: a drilling rig adapted to drive a drilling assembly; and two or more power sources, wherein at least one of the two or more power sources is a high pressure power source, wherein the drilling assembly is adapted to be in communication with either or both of the two or more power sources.
Claims
1. A multipurpose drill system, the multipurpose drill system comprising: a drilling rig adapted to drive a drilling assembly; two or more power sources in selective communication with the drilling assembly, the two or more power sources configured to deliver a fluid stream to the drilling assembly to flush drill cuttings generated by the drilling assembly, wherein at least one of the two or more power sources is a high pressure power source and at least one of the two or more power sources is a low pressure power source or a second high pressure power source, wherein the drilling rig is adapted to interchangeably receive at least rotary drilling assemblies and down the hole hammer drilling assemblies and where the drilling assembly is a down the hole hammer drilling assembly, the fluid stream further actuates a hammer assembly of the down the hole hammer drilling assembly.
2. A multipurpose drill system according to claim 1, where the fluid stream is a gas, each of the two or more power sources will be compressor apparatus.
3. A multipurpose drill system according to claim 2, wherein the one or more high pressure power sources are each capable of providing a supply of compressed air with a pressure of at least 10 Bar.
4. A multipurpose drill system according to claim 1, wherein the low pressure power source is capable of providing a supply of compressed air with a volume of at least 15 m.sup.3/min at a maximum pressure of 10 bar.
5. A multipurpose drill system according to claim 1, wherein the multipurpose drill system further comprises at least one engine to power the two or more power sources.
6. A multipurpose drill system according to claim 1, wherein the drilling rig is further adapted to interchangeably receive percussion assisted rotary drilling assemblies and where the fluid stream further actuates a hammer assembly of the percussion assisted rotary drilling assembly.
7. A multipurpose drill system according to claim 1, wherein the two or more power sources operate independently.
8. A multipurpose drill system according to claim 1, wherein the drilling assembly is adapted to be selectively switched between communication with each power source independently or two or more power sources simultaneously.
9. A multipurpose drill system according to claim 1, wherein at least one engine independently powers each power source.
10. A multipurpose drill system according to claim 1, wherein the multipurpose drill system is mounted on a mobile rig platform.
11. A method of drilling, the method comprising the use of the multipurpose drill system of claim 1.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Further features of the present invention are more fully described in the following description of several non-limiting embodiments thereof. This description is included solely for the purposes of exemplifying the present invention. It should not be understood as a restriction on the broad summary, disclosure or description of the invention as set out above. The description will be made with reference to the accompanying drawings in which:
(2)
(3)
(4)
(5)
DESCRIPTION OF EMBODIMENTS
(6) In
(7) In the embodiment shown in
(8) The drilling rig 12 includes a drill mast 22 which is hinged to the rig platform 16, such that the drill mast 22 is able to tilt relative to the rig platform 16. In the arrangement shown in
(9) The drilling rig 12 further comprises an operator cab 36 which houses the operating controls for the drilling operation, along with monitoring instruments. Whilst the embodiment shown in
(10) The drilling rig 12 comprises a drill head 38 supported within or on the drill mast 22. The drill head 38 is guided for longitudinal movement along the drill mast 22. Movement of the drill head 38 is controlled by a hoist (not shown). Hydraulic head actuators (not shown) control the movement of the drill head 38 and the hoist. Whilst a drill head 38 shown in the Figures is adapted move along the drill mast 22, it is envisaged that other rotation drive mechanisms may be employed, such as for example a Table Drive. As would be understood by a person skilled in the art, where a Table Drive is utilised, it does not move along the drill mast 22.
(11) The multipurpose drill system 10 further comprises a hydraulic pump mechanism 44 adapted to supply hydraulic fluid for hydraulic operations. The Hydraulic actuators 24 for tilting the drill mast 22, the drill head 38, the hoist and various other components of the drilling rig 12, are operated by the hydraulic fluid supplied by the hydraulic pump mechanism 44. The hydraulic pump mechanism 44 is operated by a diesel engine 46 mounted on the rig platform 16.
(12) With reference to
(13) Typical RD assemblies employ a rotational drill bit at the end of the drill pipe 48 to cut or crushing/grinding into the formation. Both rotational forces and downward pressure must be exerted on the drill bit to drive it through the formation. The rotation and pressure is exerted on the drill bit by the drill head 38. As the drilling continues, a fluid stream such as compressed air or a liquid is sent down the drill pipe 48 to flush and clear the cuttings from within the borehole.
(14) Typical DTHH drilling assemblies operate by providing a hammer assembly at the end of the drill pipe 48 to chip away rock and produce a hole. The hammer assembly comprises a pneumatic or hydraulic percussion mechanism, commonly called the hammer, which is located directly behind a drill bit. The pneumatic or other fluid (hydraulic) percussion mechanism strikes the impact surface of the bit directly to drive the drill bit into the rock. Compressed air or another fluid is provided down the drill pipe 48 to actuate the pneumatic hammer and to flush out the cutting. The drill pipe 48 transmits the necessary feed force and rotation to hammer and bit.
(15) Typical PARD drilling assemblies use both rotary and low(er) percussive action in order to chip away rock during the RD application and produce a hole. The combination of rotation and percussion helps the drill achieve a cutting/crushing and grinding (rotary) action at the same time as a chipping (percussive) action. Usually these motions are hydraulically or pneumatically driven. A hole is formed when the power source is transmitted through the drill pipe 48 to the drill bit.
(16) In
(17) As would be appreciated by a person skilled in the art, a compressor is a mechanical device that increases the pressure of a gas by reducing its volume. Air compressors typically operate by forcing air into a storage tank, thereby increasing the pressure of that air. The compressed air is held in the tank for use. There are many different types of compressors that are available to the skilled addressee and these include piston-type compressors, reciprocating compressors, compound compressors, rotary-screw compressors, rotary vane compressors, scroll compressors and turbo compressors.
(18) As would be understood by a person skilled in the art, each drilling assembly 14 has different power source requirements. DTHH drill assemblies require high pressure fluid, but do not require as high volumes of fluid as rotary or PARD drilling techniques for the same drill hole diameter. Conversely, RD drilling assemblies require a high volume of low pressure fluid to clear the cutting, but the required pressure is not as high as for DTHH drilling. The inventors have determined that the requirements for each drilling assembly 14 can be provided independently by either a high pressure power source, for example the high pressure compressor 52 or a low pressure power source, for example the low pressure compressor 54. As separate engines 56; 58 are used to power each power source, it is envisaged that the specification of the each engine can be matched to the requirements of the power source.
(19) The inventors have determined that the use of parallel low pressure and high pressure compressors 52; 54 on a single drilling rig 12 is particularly advantageous for the drilling of large diameter holes in formations that contain rock of varying hardness. As would be appreciated by a person skilled in the art, rotary drilling assemblies generally have a high penetration rate and are more economic for drilling in soft rocks. As such, rotary drilling assemblies are typically used for the drilling of large diameter holes into rock with a hardness of less than 200 MPa. However, the use of rotary drilling assemblies for the drilling of large diameter holes in hard rock requires a drilling rig 12 with high pull down and rotation capacity to drive the RD bit through the rock. This presents a significant capital expenditure for the high capacity drill rig itself, along with higher operating costs to power the compressor. Furthermore, the rotary drill bits may wear at a quicker rate, requiring ongoing replacement costs. These factors together contribute to a higher cost impediment to such operations. Unlike RD, DTHH drilling assemblies are generally more suited and more economic for drilling of hard rock material. Whilst DTHH drilling for such large diameter (up to and greater than 229 mm) hole drilling operations may be preferred, these assemblies require a significantly higher air pressure than RD assemblies and as such, is outside the capacity of conventional low pressure only RD rigs. To increase utility of some large capacity conventional low pressure only drill rigs, some PARD assemblies are used to provide percussive assistance to drill bits used in RD applications. Through this assistance drill penetration rates may be increased in hard rock thereby improved. Unlike conventional drilling systems, the multipurpose drill system 10 of the present invention provides the ability to support multiple large diameter drilling assemblies (up to and >than 229 mm) from a single drilling system. It is envisaged that such a system will allow for the ability to switch between RD, PARD, and DTHH drilling when material of different hardness is encountered.
(20) In the embodiment shown in the figures, separate engines power each of the hydraulic pump mechanism 44, the high pressure compressor 52 and the low pressure compressor 54. It is envisaged that by having three separate engines, the overall operating cost may be reduced and drill rig output optimised to match the rock hardness for the required drill hole diameter. As discussed above, the compressed air requirements of each of the RD and DTHH drilling assemblies are significantly different. Accordingly, the loads experienced by engines operating compressors running to each of these specifications are also different. Whilst it is envisaged that a single engine may operate all of the hydraulic pump mechanism 44 and both the high pressure and low pressure compressors 52; 54, the inventors have determined that it is less efficient to run such an over specified engine. It is envisaged that the use of individual engines for each of the hydraulic pump mechanism 44 the high pressure compressor 52 and the low pressure compressor 54 will allow for the efficient energy use. Whilst the engine operating the hydraulic pump mechanism 44 would need to remain running to power the drill hydraulics, the first and second engines would not need to be running in tandem. They would only be called upon when their function is necessary.
(21) The hydraulic pump mechanism 44 is powered by an engine of specific horsepower to function and operate the hydraulic requirements, for example a 570 kw @ 1850 rpm diesel engine. The preferred hydraulic pump mechanism 44 will provide an open circuit flow rate of approximately 3?425 I/min, a closed circuit flow rate of 2?125 I/min and max pressure of 320 bar.
(22) In a highly preferred embodiment of the present invention, the high pressure compressor 52 is a double stage compressor that produces approximately 40 m.sup.3/min. of compressed air at a pressure of ?35 bar. Those skilled in the art would be able to determine the appropriate engine to power the selected high pressure compressor 52, for example one suitable engine to power the high pressure compressor 52 is a ?570 kw @ 2100 rpm diesel engine.
(23) In a highly preferred embodiment of the present invention, the low pressure compressor 54 is a single stage compressor that produces approximately 100 m.sup.3/min. of compressed air at a pressure of ?7 bar. Those skilled in the art would be able to determine the appropriate engine to power the selected low pressure compressor 54, for example one suitable engine to power the low pressure compressor 54 is a ?780 kw @ 1850 rpm diesel engine.
(24) In order to drive the RD assembly for drill hole diameters >200 mm in rock formation with a hardness of above ?200 MPa, the drill rig typically requires a pulldown capacity of at least 200 kN. The rotary head requires a minimum 10,000 nm rotation torque.
(25) In use, it envisaged that the multipurpose drill system 10 will enable the operation of each of RD, DTHH drilling and PARD from a single drill rig. In operation, the rig will be positioned adjacent to the site where the hole is to be drilled. The support jacks 20 may be extended and the drill mast 22 will be moved to required hole angle positon. In typical drilling operations, the hardness of the rock at the surface is relatively softer than unweathered or stronger rock formations which may be present at greater depths and so a RD assembly will be fixed to the drill rig. During RD, the engine for the hydraulic pump mechanism 44 will be operated and the engine for the low pressure compressor 54 will be operated. The drilling will commence, with the drill head 38 driving the RD assembly through the rock with the cuttings being flushed out by the compressed air. As the drilling continues additional dill pipe sections may be added until the desired drill hole depth is reached, or the encountered rock hardness becomes uneconomic to drill using RD assemblies due to slow penetration rates or high drill bit wear/consumption.
(26) When portion of rock formations with a greater hardness (?200 MPa) are encountered, the RD drilling ceases and the RD assembly is lifted from drill hole/drill pipe/rod. Once removed from the drill hole, the RD assembly is removed from the drilling rig 12 and is replaced by a DTHH assembly. It is envisaged that the removed assembly may be safely stored on the rig platform 16, thereby allowing it to be easily accessed when again required. The engine for the high pressure compressor 52 is operated and the compressed air is sent down the drill pipe 48 to the DTHH drilling assembly 14. Drilling may continue through the rock of greater hardness using the DTHH drilling assembly 14, with the compressed air from the high pressure compressor 52 being used to actuate the DTHH and flush out the cuttings or in application where large volumes of hard rock material are encountered over the entire designed drill hole length or drill hole array program.
(27) Once the hard portion of the rock formation has been penetrated, the DTHH drilling assembly 14 may lifted from the hole and the RD assembly can once again be attached. RD through the soft rock may then continue, with the compressed air being supplied by the low pressure compressor 54. It is envisaged that hard rock formations could alternatively be encountered first, in which case the DTHH assembly will be attached first and replaced with the RD assembly when soft rock formations are encountered.
(28) As would be appreciated by a person skilled in the art, blast hole drilling requires an array of holes to be drilled to a predetermined depth, for example 10-20 m. Across the array of holes, the hardness of the rock may vary. It is envisaged that the drilling assembly 10 of the present invention allows for the use of RD drilling techniques for portions where the rock hardness is less than about 200 MPa and DTHH drilling techniques for portions where the rock hardness is more than about 200 MPa.
(29) In
(30) The multipurpose drill system 100 is adapted to interchangeably receive different drilling assemblies, such as a rotary drilling (RD) assembly, a percussion assisted rotary drilling (PARD) assembly or a down the hole hammer (DTHH) drilling assembly.
(31) The multipurpose drill system 100 comprises two high pressure power sources, for example two high pressure compressors 102, mounted on the drilling rig 12. Each of the compressors 102 is adapted to provide compressed air to the drilling rig 12 and down the drill pipe 48. In the embodiment shown in the figures, each high pressure compressor 102 is powered by separate engines 104. The separate engines 104 allow the independent operation of each of the high pressure compressors 102.
(32) As discussed above, each drilling assembly 14 has different power source requirements. The inventors have determined that the requirements for each drilling assembly 14 can be provided by one or each of the high pressure compressors 102. Unlike the first embodiment of the present invention, no low pressure power source is provided on the drilling rig 12 to provide a volume of compressed air to the drilling rig 12 and down the drill pipe 48 that is sufficient to operate a RD drilling assembly. In this embodiment, the inventors have determined that both high pressure compressors 102 can be arranged to be in communication with the drilling assembly and can be operated simultaneously to provide the required volume of air. It is envisaged that the pressure of the compressed air provided by each high pressure compressor 102 may need to be regulated so as to match the specifications of the RD drilling assembly.
(33) Similar to the first embodiment, the inventors have determined that the use of parallel high pressure compressors 102 on a single drilling rig 12 is particularly advantageous for the drilling of large diameter holes in formations that contain rock of varying hardness. As would be appreciated by a person skilled in the art, rotary drilling assemblies generally have a high penetration rate and are more economic for drilling in soft rocks. As such, rotary drilling assemblies are typically used for the drilling of large diameter holes into rock with a hardness of less than 200 MPa. However, the use of rotary drilling assemblies for the drilling of large diameter holes in hard rock requires a drilling rig 12 with high pull down and rotation capacity to drive the bit through the rock. This presents a significant capital expenditure for the high capacity drill rig itself, along with higher operating costs to power the compressor. Furthermore, the rotary drill bits may wear at a quicker rate, requiring ongoing replacement costs. These factors together contribute to a much higher cost impediment to such operations. Unlike RD, DTHH drilling assemblies are generally more suited and more economic for drilling of hard rock material. Whilst DTHH drilling for such large diameter hole drilling operations may be preferred, these assemblies require a significantly higher air pressure than RD assemblies and as such, is outside the capacity of conventional low pressure only RD rigs. To increase utility of some large capacity conventional low pressure only drill rigs, some PARD assemblies are used to provide percussive assistance to drill bits used in RD applications. Through this assistance drill penetration rates may be increased in hard rock thereby improved. Unlike conventional drilling systems, the multipurpose drill system 100 of the present invention provides the ability to support multiple large diameter drilling assemblies from a single drilling system. It is envisaged that such a system will allow for the ability to switch between RD, PARD, and DTHH drilling when material of different hardness is encountered.
(34) In the embodiment shown in
(35) The hydraulic pump mechanism 44 is powered by an engine of specific horsepower to function and operate the hydraulic requirements, for example a 570 kw @ 1850 rpm diesel engine. The preferred hydraulic pump mechanism 44 will provide an open circuit flow rate of approximately 3?425 I/min, a closed circuit flow rate of 2?125 I/min and max pressure of 320 bar.
(36) In a highly preferred embodiment of the present invention, each of the high pressure compressors 102 are each a double stage compressor that produces approximately 40 m.sup.3/min. of compressed air at a pressure of ?35 bar. Those skilled in the art would be able to determine the appropriate engine to power the selected high pressure compressor 52, for example a suitable engine to power the high pressure compressor 52 is a ?570 kw @ 2100 rpm diesel engine.
(37) In order to drive the RD assembly for drill hole diameters >200 mm and >200 mPa hard rock, the drill rig requires a pulldown capacity of at least 200 kN. The rotary head requires a minimum 10,000 nm rotation torque.
(38) In use, it envisaged that the multipurpose drill system 100 will enable the operation of each of RD, DTHH drilling and PARD from a single drill rig. In operation, the rig will be positioned adjacent to the site where the hole is to be drilled. The support jacks 20 may be extended and the drill mast 22 will be moved to required hole angle positon. In typical drilling operations, the hardness of the rock at the surface is relatively softer than unweathered or stronger rock formations which may be present at greater depths and so a RD assembly will be fixed to the drill rig. The drill pipe will be arranged to be in communication with both of the high pressure compressors 102. During RD, the engine for the hydraulic pump mechanism 44 will be operated and the engines 104 for each of the high pressure compressors 102 will be operated to operate both high pressure compressors 102 simultaneously. The drilling will commence, with the drill head 38 driving the RD assembly through the rock with the cuttings being flushed out by the compressed air. As the drilling continues additional dill pipe sections may be added until the desired drill hole depth is reached, or the encountered rock hardness becomes uneconomic to drill using RD assemblies due to slow penetration rates or high drill bit wear/consumption.
(39) When portion of rock formations with a greater hardness (?200 MPa) are encountered, the RD drilling ceases and the RD assembly is lifted from drill hole/drill pipe/rod. Once removed from the drill hole, the RD assembly is removed from the drilling rig 12 and is replaced by a DTHH assembly. It is envisaged that the removed assembly may be safely stored on the rig platform 16, thereby allowing it to be easily accessed when again required. The drill pipe will be arranged to be in communication with only one high pressure compressor 102. The engine for the high pressure compressor 102 is operated and the compressed air is sent down the drill pipe 48 to the DTHH drilling assembly 14. Drilling may continue through the rock of greater hardness using the DTHH drilling assembly 14, with the compressed air from the high pressure compressor 102 being used to actuate the DTHH and flush out the cuttings or in application where large volumes of hard rock material are encountered over the entire designed drill hole length.
(40) Once the hard portion of rock has been penetrated, the DTHH drilling assembly 14 may lifted from the hole and the RD assembly can once again be attached. RD through the soft rock may then continue, with the compressed air being supplied by both high pressure compressors 102 simultaneously.
(41) As would be appreciated by a person skilled in the art, blast hole drilling requires an array of holes to be drilled to a predetermined depth, for example 12-15 m. Across the array of holes, the hardness of the rock may vary. It is envisaged that the drilling assembly 10 of the present invention allows for the use of RD drilling techniques for portions where the rock hardness is less than about 200 MPa and DTHH drilling techniques for portions where the rock hardness is more than about 200 MPa.
(42) The present invention will now be described with reference to the following non-limiting examples.
COMPARATIVE EXAMPLE 1
(43) A comparison of the specifications of a RD rig of the prior art (Atlas Copco PV351) and a drilling rig in accordance with a first embodiment of the present invention is shown in the Table 1.
(44) In this embodiment, the drilling rig is provided with the following power sources:
(45) A high pressure power source in the form of a double stage compressor that produces approximately 40 m.sup.3/min of compressed air at a pressure of ?35 bar. It is powered by a ?570 kw @ 2100 rpm diesel engine
(46) A low pressure power source in the form of a single stage compressor that produces approximately 100 m.sup.3/min of compressed air at a pressure of ?7 bar. It is powered by a ?780 kw @ 1850 rpm diesel engine.
(47) TABLE-US-00001 TABLE 1 Prior Art Comparison Specifications Existing Art Example 1 Comment Pull Down Up to 120,000 Up to 120-140,000 Extra 20,000 lbf (534 kN) lbf (534-623 kN) lbf (89 kN) pulldown Low pressure air rotary up to 3,800 cfm @ up to 3,800 cfm @ Equivalent drilling 110 psi 110 psi (108 m{circumflex over ()}3/min @ (108 m{circumflex over ()}3/min @ 7.6Bar) 7.6Bar) High pressure air hammer N/A 1,500 cfm @ 500 Example 1 enables drilling psi (42 m{circumflex over ()}3/min @ down hole hammer 34Bar) drilling of +200 MPa rock if required at diameters greater than 200 mm Drill Hole Diameters 200-450 mm by 200-450 mm by Existing Art does not RD or PARD RD, PARD & DTHH provide High Pressure compressed air to enable DTHH drilling of large diameter drill holes.
(48) As will be noted in Table 1, both systems provide low pressure air rotary drilling, but the drilling system in accordance with the first embodiment of the present invention further provides the ability to use DTHH drilling when the rock strength increases to +200 MPa at diameters above 200 mm.
COMPARATIVE EXAMPLE 2
(49) A comparison of the specifications of a RD rig of the prior art (Atlas Copco PV351) and a drilling rig in accordance with the second embodiment of the present invention is shown in the Table 2.
(50) In this embodiment, the drilling rig is provided with the following power sources.
(51) A first high pressure power source in the form of a double stage compressor that produces approximately 40 m.sup.3/min of compressed air at a pressure of ?35 bar. It is powered by a ?570kw @ 2100 rpm diesel engine.
(52) A second high pressure power source in the form of a double stage compressor that produces approximately 40 m.sup.3/min of compressed air at a pressure of ?35 bar. It is powered by a ?570kw @ 2100 rpm diesel engine.
(53) TABLE-US-00002 TABLE 2 Prior Art Comparison Specifications Existing Art Example 2 Comment Pull Down Up to ~120,000 Up to 140,000 Extra 20,000 lbf (534 kN) lbf (534-623 kN) lbf (89 kN) pulldown Low pressure air rotary up to 3,800 cfm @ up to 3,800 cfm @ Equivalent drilling 110 psi 110 psi (108 m{circumflex over ()}3/min @ (108 m{circumflex over ()}3/min @ 7.6Bar) 7.6Bar) High pressure air hammer N/A Two ? ~1,500 cfm @ Enables efficient drilling 500 psi down hole hammer (42 m{circumflex over ()}3/min @ drilling of large ~34Bar) diameter holes (>200 mm) in +200 MPa rock if required Increased capacity of additional 1,500 cfm at ~35 bar Drill Hole Diameters 200-406 mm by 200-406 mm by Existing Art does not RD or PARD RD, PARD & DTHH provide high pressure compressed air to enable DTHH drilling of large diameter drill holes.
(54) As will be noted in Table 2, both systems provide low pressure air rotary drilling, but the drilling system in accordance with this embodiment further provides the ability to use DTHH drilling when the rock strength increases to +200 mpa at diameters above 200 mm. Unlike the first embodiment of the present invention, the drilling rig of the second embodiment has additional volume of high pressure capacity when operating a DTHH drill. The inventors envisage that this will deliver the volume of compressed air to enable DTHH performance at pressures higher than that which is conventionally available on DTHH rigs. This may be used to support DTHH assemblies that operate at pressures up to or above 35 bar and or consumption greater than 1500 cfm/42 m.sup.3/min
(55) Computer modelling of the use of the system of the present invention has calculated a reduced number of individual drilling systems when completing drilling of large diameter blastholes in harder/higher rock strengths >200 pma. This is achieved through the capability of the multipurpose drill rig to enable a simple change of drilling method from RD to DTHH for large diameter holes (>200 mm) on the same drill rig platform. The current art of sufficient pull-down capacity to complete RD large diameter drill holes does not currently have the high pressure power source capacity to perform DTHH drilling of large diameter holes (>200 mm) economically, or at all. Consequently, through the reduction in the number of drill rigs able to drill the same drill hole diameter in hard rock using DTHH as is currently drilled in softer/less hard rock formations the user is able to achieve an overall reduced capital expenditure on drill rigs plus savings in overall operating expenditure.
(56) Those skilled in the art will appreciate that the invention described herein is susceptible to variations and modifications other than those specifically described. The invention includes all such variation and modifications. The invention also includes all of the steps, features, formulations and compounds referred to or indicated in the specification, individually or collectively and any and all combinations or any two or more of the steps or features.