CATALYST SYSTEM FOR DEHYDROGENATION

Abstract

A catalyst system for propane dehydrogenation includes a hollow fiber members packed with a Pt.sub.1Sn.sub.1/SiO.sub.2 catalyst. The hollow fiber membrane includes a separation layer coated on an interior surface of a support tube. The separation layer selectively removes H.sub.2 generated during the propane dehydrogenation reaction.

Claims

1. A catalyst system for a dehydrogenation reaction, comprising: a hollow fiber membrane comprising an outer support tube formed of a porous support material and a separation layer formed on an inner surface of the support tube such that the separation layer substantially covers the inner surface of the support tube, the separation layer comprising SiO.sub.2; and a dehydrogenation catalyst packed inside the hollow fiber membrane, the dehydrogenation catalyst comprising Pt.sub.1Sn.sub.1 arranged on a SiO.sub.2 support, wherein a ratio of a surface area to the volume of the catalyst system is about 500 m.sup.2/m.sup.3 to about 3000 m.sup.2/m.sup.3 and an amount of catalysts exposed on the membrane surface of about 300 g/m.sup.2 to about 1500 g/m.sup.2.

2. The catalyst system of claim 1, wherein the support tube comprises at least two layers, an outer layer defining an outer surface of the support tube and an inner layer disposed between the outer layer and the separation layer, wherein the outer layer has an average pore size that is larger than an average pore size of the inner layer.

3. The catalyst system of claim 2, wherein the outer layer has a thickness of about 250 micrometers to about 750 micrometers and/or the outer layer has an average pore size of about 100 nm to about 500 nm.

4. (canceled)

5. The catalyst system of claim 2, wherein the inner layer has a thickness of about 0.5 micrometers to about 20 micrometers and/or the inner layer has an average pore size of about 5 nm to about 50 nm.

6. (canceled)

7. The catalyst system of claim 1, wherein the support tube is formed of Al.sub.2O.sub.3.

8. The catalyst system of claim 1, wherein the support tube has an outer diameter of about 1.5 mm to about 6 mm and/or the support tube has a wall thickness of about 0.5 mm to about 1.5 mm.

9. (canceled)

10. The catalyst system of claim 1, wherein the separation layer has a thickness of about 20 nm to about 500 nm and/or the separation layer has an average pore size of about 2 nm to about 20 nm.

11. (canceled)

12. The catalyst system of claim 1, wherein the separation layer is a composite silica material comprising SiO.sub.2 and one or more of alumina, titania, zirconia, and zeolite materials.

13. The catalyst system of any claim 1, wherein the catalyst comprises Pt.sub.1Sn.sub.1 nanoparticles arranged on a SiO.sub.2 support.

14. A dehydrogenation process catalyzed by the catalyst system of claim 1, comprising flowing a reactant source through the catalyst system such that the propane source flows in contact with the catalyst packed within the hollow fiber membrane and upon contact with the catalyst is selectively dehydrogenated, and H.sub.2 generated during the selective dehydrogenation is selectively removed through the separation layer, wherein the process has a selectivity of at least 90%.

15. The dehydrogenation process of claim 14, comprising heating the catalyst system to a temperature of about 400? C. to about 600? C. while flowing the propane source through the catalyst system.

16. (canceled)

17. The dehydrogenation process of claim 14, wherein the process is performed with no added H.sub.2.

18. The dehydrogenation process of claim 14, further comprising flowing an inert sweeping gas over an outer surface of the tube to carry away H.sub.2 separated from the dehydrogenation reaction, optionally wherein the inert gas is Ar, He, Ne, Kr, Xe, or Rn.

19. (canceled)

20. The dehydrogenation process of claim 14, wherein the reactant source comprises propane and upon contact with the catalyst, the propane is selectively dehydrogenated to propylene.

21. A dehydrogenation process catalyzed by the catalyst system of claim 1, comprising: flowing a reactant source through the catalyst system such that the propane source flows in contact with the catalyst packed within the hollow fiber membrane and upon contact with the catalyst is selectively dehydrogenated, and H.sub.2 generated during the selective dehydrogenation is selectively removed through the separation layer; and flowing a sweeping gas comprising O.sub.2 over an outer surface of the support tube to oxidize H.sub.2 separated from the dehydrogenation reaction thereby forming water and heat, wherein the process has a selectivity of at least 90%.

22. The dehydrogenation process of claim 21, wherein the oxidization of H.sub.2 supplies heat to the catalyst system for heating the catalyst system to a temperature of about 400? C. to about 600? C. while flowing the propane source through the catalyst system.

23. (canceled)

24. The dehydrogenation process of claim 21, wherein the sweeping gas comprises about 6% to about 15% by volume O.sub.2.

25. The dehydrogenation process of claim 21, wherein the sweeping gas further comprises an inert gas, wherein the inert gas is optionally Ar, He, Ne, Kr, Xe, or Rn.

26. (canceled)

27. The dehydrogenation process of claim 21, wherein the reactant source comprises propane and upon contact with the catalyst, the propane is selectively dehydrogenated to propylene.

28. The dehydrogenation process of claim 21, wherein the process is performed with no added H.sub.2 and/or wherein the process is performed without applied heat from an external source.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0011] FIG. 1A is a schematic illustration of a catalyst system in accordance with the disclosure;

[0012] FIG. 1B is an SEM image of the inner surface of an uncoated Al.sub.2O.sub.3 hollow fiber membrane (before SiO.sub.2 deposition);

[0013] FIG. 1C is an SEM image of an outer surface of an SiO.sub.2/Al.sub.2O.sub.3 hollow fiber membrane in accordance with the disclosure showing the porous alumina substrate;

[0014] FIG. 1D is an SEM image of a cross section of an SiO.sub.2/Al.sub.2O.sub.3 hollow fiber membrane in accordance with the disclosure, showing the layered SiO.sub.2/Al.sub.2O.sub.3 structure;

[0015] FIG. 1E is an SEM image of an inner surface an SiO.sub.2/Al.sub.2O.sub.3 hollow fiber membrane in accordance with the disclosure, showing the topmost smooth SiO.sub.2layer;

[0016] FIG. 1F is a graph showing the Si 2 p photoemission spectra of an SiO.sub.2/Al.sub.2O.sub.3 hollow fiber membrane in accordance with the disclosure;

[0017] FIG. 1G is a graph showing the Al 2 p photoemission spectra of an uncoated Al.sub.2O.sub.3 hollow fiber membrane;

[0018] FIG. 2A is a graph showing H.sub.2 permeability and H.sub.2/C.sub.3H.sub.8 separation factor as a function of temperature for a hollow fiber membrane in accordance with the disclosure;

[0019] FIG. 2B is a graph showing H.sub.2 permeability and H.sub.2/C.sub.3H.sub.8 separation factor as a function of time for an equimolar mixture of H.sub.2 and C.sub.3H.sub.5 (5 cm.sup.3/min each) and an Ar sweep on the shell side (60 cm.sup.3/min);

[0020] FIG. 2C is a graph showing H.sub.2 flux and H.sub.2/C.sub.3H.sub.8 separation factor as a function of sweep:feed ratios (Ar sweep varied between 10-100 cm.sup.3/min on the shell side) at T=580? C.;

[0021] FIG. 3A is a graph showing propane conversion, propylene selectivity and propylene yield as a function of sweep:feed ratios (WHSV=1.3 hours.sup.?1) compared to reaction equilibrium limit (dashed line) calculated for the same experimental conditions;

[0022] FIG. 3B is a graph showing propane conversion, propylene selectivity, and propylene yield as a function of WHSV (sweep:feed=10) compared to reaction equilibrium limit (dashed line) calculated for the same experimental conditions;

[0023] FIG. 3C is a graph showing propylene yield as a function of dimensionless Da and Pe;

[0024] FIG. 3D is a graph showing initial reaction rate for various catalysts systems in accordance with the disclosure and PBR catalysts reported in the literature, points 40 and 41 580 and 500? C.) represent the catalyst system of the disclosure. Numbers in the figure correspond to row number in Table 2;

[0025] FIG. 3E is a graph showing conversion-selectivity plots for different PDH catalysts. Numbers in the figure correspond to row number in Table 1;

[0026] FIG. 4A is a graph showing propane conversion and propylene selectivity as a function of time for the catalyst system of the disclosure (square) compared to conventional PBR (triangle);

[0027] FIG. 4B is a graph showing H.sub.2 removal rate and the H.sub.2/C.sub.3H.sub.8 separation factor as a function of time for a catalyst system in accordance with the disclosure. Reaction temperature was 580? C., P.sub.c3H8=1, WHSV=1.3 hours.sup.?1 and sweep:feed=b 10;

[0028] FIG. 5A is a graph showing propane conversion and propylene selectivity as a function of time for a catalyst system in accordance with the disclosure (squares) as compared to convention PBR (triangles). Reaction temperature was 500? C. or 540? C., PC.sub.C3H8=1, WHSV=0.43 hours.sup.?1 and sweep:feed ratio=10;

[0029] FIG. 5B is a graph showing propane conversion and propylene selectivity as a function time for a catalysts system in accordance with the disclosure at different WHSVs. Reaction temperature was 500? C., P.sub.C3H8=1, and sweep flow rate=100 cm.sup.3/min;

[0030] FIG. 6 is a schematic illustration of a TEOS CVD setup for SiO.sub.2 deposition on Al.sub.2O.sub.3 hollow fiber membrane;

[0031] FIG. 7 is a schematic illustration of a gas permeation and reaction setup for SiO.sub.2/Al.sub.2O.sub.3 hollow fiber membrane testing;

[0032] FIG. 8 is a graph showing equilibrium propane conversion as a function of reaction temperature for a pure undiluted propane stream;

[0033] FIG. 9 is a graph showing the Gibbs free energy for propane dehydrogenation and side reactions at 580? C.;

[0034] FIG. 10 includes top-down SEM characterization images of the Al.sub.2O.sub.3 membrane confirming fiber diameter and wall thickness dimensions;

[0035] FIG. 11 is a graph showing the X-ray diffraction pattern for SiO.sub.2/Al.sub.2O.sub.3

[0036] FIG. 12 is a graph showing survey photoemissions of an SiO.sub.3 coated Al.sub.2O.sub.3 membrane;

[0037] FIG. 13 is a graph showing survey photoemissions spectral of an uncoated Al.sub.2O.sub.3 membrane;

[0038] FIG. 14 is a graph showing H.sub.2 permeability and H.sub.2/N.sub.2 separation factor (compared to the Knudsen separation limit) as a function of TEOS deposition time.

[0039] FIG. 15 is a graph showing equilibrium conversion for propane dehydrogenation as a function of temperature for different levels of H.sub.2 removal;

[0040] FIG. 16 is a graph showing permeance of a catalyst system in accordance with the disclosure;

[0041] FIG. 17 is an SEM image of a cross-section of a membrane in accordance with the disclosure;

[0042] FIG. 18 is an SEM image of a cross-section showing an about 360 nm silica layer on an asymmetric alumina support;

[0043] FIG. 19 is a schematic illustration for calculations used in assessing the catalyst system in accordance with the disclosure, where Da is a measure of whether the residence time is sufficient to reach equilibrium and Pe evaluates the effectiveness of the membrane in removing a desired product from the reaction zone;

[0044] FIG. 20A is a graph showing Da as a function of Pe for a catalyst system in accordance with the disclosure;

[0045] FIG. 20B is a graph showing WHSV as a function of permeance for a catalyst system in accordance with the disclosure;

[0046] FIGS. 21A to 21C are graphs illustrating that a tubular membrane showed an about 3% improvement at 0.68 h.sup.?1 and a sweep:feed ratio of 1:1 (higher area allowed for higher catalyst loading and operation at lower WHSV. Hollow fiber membrane in accordance with the disclosure showed an about 6% improvement at WHSV of 1.62 h.sup.?1;

[0047] FIGS. 22A and 22B are graphs illustrating that coupling of the catalyst to a membrane reactor design in the catalyst system of the disclosure allowed for an improvement to about 117% propylene yield and a 95% propylene selectivity at 580? C.;

[0048] FIGS. 23A and 23B are graphs illustrating the lower thermodynamic propensity to form coke at lower temperatures. Faster deactivation in a membrane system can be avoided by operating at lower temperature (500? C.);

[0049] FIG. 24 is a schematic illustration of a catalyst system in accordance with the disclosure and use of the catalyst system with an O.sub.2 content in the sweeping gas flow.

[0050] FIG. 25A is a graph showing propane conversion, propylene selectivity and propylene yield as a function of % O.sub.2 introduced in the sweeping gas compared to reaction equilibrium limit (bottom dashed line) and the system with no O.sub.2 (top dashed line);

[0051] FIG. 25B is a graph showing precent H.sub.2 removal as a function of % O.sub.2 in the sweeping gas;

[0052] FIG. 25C is a graph showing tube-side product distribution on a C-atom basis;

[0053] FIG. 25D is a graph showing shell side product distribution on a C-atom basis. In the graphs of FIG. 25, reaction temperature was 500? C., P.sub.C3H8=1 atm, WHSV=0.86 hours.sup.?1, and sweep:feed ratio=12;

[0054] FIG. 26A is a graph showing water formation rate calculated on the shell side of a catalyst system in accordance with the disclosure as a function of % O.sub.2 in the sweeping gas; and

[0055] FIG. 26B is a graph showing heat requirement for propane dehydrogenation and heat release from combustion of H.sub.2 and propane oxidation as a function of % O.sub.2 in the sweeping gas.

DETAILED DESCRIPTION

[0056] Catalyst systems in accordance with the disclosure include a hollow fiber membrane packed with a dehydrogenation catalyst. The dehydrogenation catalyst includes a dehydrogenation catalytic material disposed on support. The support included in dehydrogenation catalyst and the hollow fiber membrane material can both include silica. The hollow fiber membrane advantageously is H.sub.2 permeable and removes H.sub.2 generated during the dehydrogenation reaction. This multicomponent catalyst system has been observed to operate at conversions that exceeded the thermodynamic limits of the dehydrogenation reaction. The catalyst systems of the disclosure can achieve enhanced propane conversion above the equilibrium limit with complete selectivity and excellent stability. The catalysts of the disclosure can allow for expansion of the operational dehydrogenation temperature range to lower temperatures, while retaining high conversion and reaction rates. This can significantly improve overall stability of the materials under the harsh, reducing reaction conditions of the dehydrogenation reaction.

[0057] FIG. 1A is a schematic illustration of a catalyst system in accordance with the disclosure. The catalyst system has an asymmetric and porous tubular hollow fiber with a thin SiO.sub.2 separation layer on the inner side of a supporting tube. The tube can be formed by a porous Al.sub.2O.sub.3 layer or multi-layer structure. The dehydrogenation catalyst is packed inside of the fiber membrane (referenced herein as the tube side), in contact with the separation layer. An inert gas can be flowed on the other, outer side of the fiber membrane (referenced herein as the shell side).

[0058] FIG. 24 is a schematic illustration of a catalyst system in accordance with the disclosure providing for PDH and H.sub.2 oxidation. The catalyst system is similar to that of FIG. 1A, but the system is operated with an additional introduction of O.sub.2 on the shell side of the catalyst system. The O.sub.2 flow interacts with the H.sub.2 transported from the tube side where the PDH occurs in an exothermic process to produce water and release heat. As H.sub.2 is removed by the membrane and oxidized on the shell side, water is formed. It was observed that water formation rates increased as O.sub.2 levels were increased.

[0059] The catalyst can be a Pt.sub.1Sn.sub.1 dehydrogenation catalyst material disposed on a support. The support can be, for example, SiO.sub.2. This catalyst alone was observed to be a selective propane dehydrogenation catalyst that operates at the thermodynamic conversion limit with a propylene selectivity of >99% without any addition of H.sub.2. The catalyst is also suitable for ethane dehydrogenation. The catalyst includes Pt.sub.1Sn.sub.1, nanoparticles supported on silica (SiO.sub.2). The nanoparticles can be about 2 nm in diameter.

[0060] The hollow fiber membrane is an H.sub.2 permeable membrane. The membrane can include a separation layer that selectively separates H.sub.2 from during the dehydrogenation reaction. The separation layer can be, for example, SiO.sub.2. The hollow fiber membrane includes a support tube upon which the separation layer is supported. The support tube can be, for example, an alumina tube. The SiO.sub.2 separation layer can be coated on the inside of the tube. The separation layer can entirely or substantially entirely cover the inner surface of the tube.

[0061] The hollow fiber membrane can have an outer diameter of about 1.5 mm to about 6 mm, about 3 mm to about 6 mm, about 2 mm to about 4 mm, or about 1 mmm to about 5 mm. Other suitable diameters include about 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, or 6 mm and any ranges defined by such values and any values there between. The support tube wall can have a thickness of about 0.5 mm to about 1.5 mm, about 1 mm to 1.5 mm, or about 0.7 mm to about 0.9 mm. Other suitable thicknesses include about 0.5, 0.6, 0.7, 0.8, 0.9, 1, 1.1, 1.2, 1.3, 1.4, 1.5 and any ranges defined by such values and any values there between. For example, FIG. 10 shows a porous Al.sub.2O.sub.3 tube having an outer diameter of about 4.8 mm and a wall thickness of 0.9 mm.

[0062] The tube can be formed of one or more layers. For example, an Al.sub.2O.sub.3 tube can be formed two Al.sub.2O.sub.3 layers. The outer layer can have a thickness of about 250 micrometers to about 750 micrometers, about 300 micrometers to about 500 micrometers, or about 400 micrometers to about 650 micrometers. Other suitable thicknesses include about 250, 300, 350, 400, 450, 500, 550, 600, 650, 700, 750, and any ranges defined by such values and any values there between.

[0063] The outer layer can have an average pore size of about 100 nm to about 500 nm, about 250 nm to about 400 nm, about 200 nm to about 350 nm, or about 150 nm to about 500 nm. Other suitable average pore sizes include about 100, 150, 200, 250, 300, 350, 400, 450, 500 and any ranges defined by such values and any values there between.

[0064] The inner layer can have a thickness of about 0.5 micrometers to about 20 micrometers, about 0.5 micrometers to about 5 micrometers, about 10 micrometers to about 20 micrometers, about 7 micrometers to about 15 micrometers or about 1 micrometer to about 10 micrometers. Other suitable thicknesses include about 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 12, 14, 16, 18, 20, and any ranges defined by such values and any values there between.

[0065] The inner layer can have an average pore size of about 5 nm to about 50 nm, about 10 nm to about 50 nm, about 20 nm to about 40 nm, or about 15 nm to about 35 nm. Other suitable average pore sizes include about 5, 6, 7, 8, 9, 10, 12, 14, 16, 18, 20, 22, 24, 26, 28, 30, 32, 34, 36, 38, 40, 42, 44, 46, 48, 50 and any ranges defined by such values and any values there between. For example, an Al.sub.2O.sub.3 tube of the hollow fiber membrane can include an outer layer having a thickness of about 860 micrometers and an average pore size of about 200 nm, and an inner layer having a thickness of about 10 micrometers and a 20 nm average pore size.

[0066] Referring to FIGS. 1B and 1C, and SEM image of the inner surface of an Al.sub.2O.sub.3 tube formed of two layers is shown. FIG. 1B is an SEM image of the inner surface of the tube, showing a clear porous surface. FIG. 1C is an SEM of the outer surface of the tube, showing large particles of a large pore size distribution.

[0067] The separation layer can be deposited on the inner surface of the supporting tube using any known methods such as CVD. For example, a SiO.sub.2 separation layer can be deposited on an Al.sub.2O.sub.3 tube through chemical vapor deposition of tetraethyl orthosilicate (TEOS) at 600? C. The separation layer can be SiO.sub.2 or a SiO.sub.2 composite. Composite silica membranes can be formed of silica and one or more of alumina, titania, zirconia, and zeolite materials. The composite structure can be useful for stabilize the silica membranes, such as for use in humid conditions. For example, composite silica membranes can be useful when catalysis occurs with hydrothermal conditions.

[0068] The separation layer can have a thickness of about 20 nm to about 500 nm, about 50 nm to about 300 nm, about 100 nm to about 450 nm, or about 20 nm to about 75 nm. Other suitable thicknesses include about 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 100, 125, 150, 175, 200, 225, 250, 275, 300, 325, 350, 375, 400, 425, 450, 475, 500 nm and any ranges defined by such values and any values there between. The separation layer can have a porosity of about 2 nm to about 20 nm, about 10 nm to about 15 nm, about 2 nm to about 12 nm, or about 5 nm to about 18 nm. Other suitable values include about 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12 ,13, 14, 15, 16, 17, 18, 19, 20 nm and any ranges defined by such values and any values there between.

[0069] The catalyst system of the disclosure can have a ratio of the surface area to the volume of the system of about 500 m 2 /m 3 to about 3000 m.sup.2/m.sup.3, about 1000 m.sup.2/m.sup.3 to about 2500 m.sup.2/m.sup.3, or about 800 m.sup.2/m.sup.3 to about 1500 m.sup.2/m.sup.3. Other suitable ratios include about 500, 600, 700, 800, 900, 1000, 1100, 1200, 1300, 1400, 1500, 1600, 1700, 1800, 1900, 2000, 2100, 2200, 2300, 2400, 2500, 2600, 2700, 2800, 2900, 3000 m.sup.2/m.sup.3, and any ranges defined by such values and any values there between.

[0070] The catalyst system of the disclosure advantageously has a high surface area of catalyst exposed within the membrane for interaction with the reactants to be catalyzed. For example, the amount of catalyst exposed on the surface area of the membrane can be about 300 g/m.sup.2 to about 1500 g/m.sup.2, about 500 g/m.sup.2 to about 1000 g/m.sup.2 or about 700 g/m.sup.2 to about 1500 g/m.sup.2. Other suitable amounts of catalyst exposed per membrane surface area include about 300, 350, 400, 450, 500, 550, 600, 650, 700, 750, 800, 850, 900, 950, 1000, 1050, 1100, 1150, 1200, 1250, 1300, 1350, 1400, 1450, 1500 g/m.sup.2, and any ranges defined by such values and any values there between.

[0071] The catalyst system of the disclosure allows for high surface area of the H.sub.2 transporting medium without compromising the PDH catalyst surface area. Hollow fibers membranes of the disclosure can provide the needed high surface area of the transport medium with small diameters. Hollow fiber geometries in accordance with the disclosure can allow for high membrane surface areas per volume of reactor, such as up to 1000 m.sup.2/m.sup.3. This can lead to significant lowering of the overall reactor volumes for achieving desired conversion. The membrane has been observed to selectively remove H.sub.2 produced during the dehydrogenation reaction at a removal rate that effectively shifts the dehydrogenation equilibrium towards a higher conversion and yields. Catalyst systems of the disclosure have been observed to have enhancements of up to 10% in propane conversion above the equilibrium limit with improved selectivity and excellent stability.

[0072] Catalyst systems of the disclosure can be useful for dehydrogenation reactions such as, but not limited to, propane dehydrogenation and ethane dehydrogenation.

[0073] Catalyst systems of the disclosure can catalyze a reaction by flowing the reactant source (e.g., a propane or ethane source) through the catalyst system in contact with the catalyst packed within the hollow fiber membrane. Upon contact with the catalysts, the reactant within the reactant source is selectively dehydrogenated. For example, in a propane dehydrogenation reaction, the catalyst when in contact with propane from the propane source selectively dehydrogenates the propane to propylene. H.sub.2 generated during the selective dehydrogenation is selectively removed through the separation layer. The catalyst system has a selectivity of at least 90%.

[0074] The catalyst system can operate at temperatures lower than conventional systems, for example, a temperature range of about 400? C. to about 600? C.

[0075] Dehydrogenation reactions using the catalyst system of the disclosure can advantageously be performed without the need for added H.sub.2.

[0076] An inert sweeping gas can be flowed over the outer surface of the catalyst system, that is the outer side of the tube) to carry away H.sub.2 separated during the dehydrogenation reaction. Any inert gas can be used, including, one or more of Ar, He, Ne, Kr, Xe, and Rn. Additionally, the sweeping gas can include O.sub.2 to provide for oxidation of H.sub.2 on the shell side. The O.sub.2 can be present in the sweeping gas in an amount of 6% to 15% by volume based on the total volume of the sweeping gas. The sweeping gas can include an inert gas and O.sub.2.

[0077] The sweeping gas containing O.sub.2 can be flowed on the shell side during the process to oxidize the H.sub.2 released during the processes and thereby form water. The oxidation is an exothermic reaction producing heat. Heat exchange can be provided such that the heat generated by the exothermic reaction can be used in the process to heat the catalyst system to the temperature needed for the dehydrogenation reaction. The process can be performed with or without applied heat from an external source. For example, the heat generated by the exothermic oxidation of H.sub.2 can provide sufficient heat for the dehydrogenation process, such that applied heat from an external source is not needed or can be discontinued after initiation of the reaction. For example, the process can include a flowing a sweeping gas having about 10% by volume to about 15% by volume O.sub.2 and the process can be performed without applied heat.

[0078] The Damkohler (Da) and Peclet (Pe) numbers were two dimensionless numbers considered in the design of the catalyst systems of the disclosure. The Da number is described by the ratio of the reaction rate and the convective transport rate of the reactant through the reactor. It is closely related to the conversion that can be achieved in a system, with a larger Da number leading to larger conversion. The Pe number is the ratio of convective transport rate to the membrane permeation rate. A combination of high Da and low Pe numbers are desired for optimized performance, marked by a high reaction rate and a high H.sub.2 permeation rate. Tuning of the geometries of the catalysts systems of the disclosure with consideration of Da and Pe numbers can lead to further enhancements in performance.

[0079] A performance metric that is often used to quantify the performance of a catalyst is the rate of conversion per gram of the catalyst. The inherent kinetic PDH reaction rates were analyzed using an integral reactor analysis for many catalysts reported in literature and compared it to the rates measured on the Pt.sub.1Sn.sub.1/SiO.sub.2 catalyst used in the membrane system herein. The data in FIG. 3D and Table 2 show that the PDH rates on the Pt.sub.1Sn.sub.1/SiO.sub.2 catalyst are in general comparable to the best performing Pt-based PDH catalysts, and significantly higher than the rates on non-Pt based materials.

[0080] Another performance metric in PDH is the selectivity to propylene as a function of propane conversion. In general, due to downstream separation process costs, it is highly desirable that the system can achieve close to 100% selectivity at high conversions. Data in FIG. 3E and Table 1 show the initial (fresh material) selectivity/conversion performance results for different PDH systems reported in literature. The comparative literature systems for most of these catalysts were operated in packed bed reactors (PBR) (data represented with triangles in the figure), with a limited number of studies employing catalyst/membrane systems (circles in the figure).

TABLE-US-00001 TABLE 1 Feed Equilibrium Conversion/ Temp Composition conversion Conversion equilibrium Selectivity Catalyst, Membrane (? C.) (vol %) .sup.a (%) (%) .sup.b conversion (%) .sup.b Ref. 7.5 wt % Cr/Al.sub.2O.sub.3, 500 100% C.sub.3H.sub.8 18 23.8 132.2 89 (2) SiO.sub.2/Al.sub.2O.sub.3 PtSn/SiO.sub.2, 500 100% C.sub.3H.sub.8 24.7 33.7 136.4 99 Catalyst SiO.sub.2/Al.sub.2O.sub.3 system of the disclosure PtSn/SiO.sub.2, 580 100% C.sub.3H.sub.8 52 64 123.1 95 Catalysts SiO.sub.2/Al.sub.2O.sub.3 of the disclosure 1% Na.sub.2O-doped 20% 600 100% C.sub.3H.sub.8 48 75 156.3 80 (3) Cr.sub.2O.sub.3 80% Al.sub.2O.sub.3, SAPO-34 7.5 wt % Cr/Al.sub.2O.sub.3, 600 30% C.sub.3H.sub.8 64.2 48 74.8 89 (4) Pd/Al.sub.2O.sub.3 .sup.a Remainder is inert gas (either Helium or Nitrogen) .sup.b Data presented here is the best conversion and selectivity reported in each article. (2) - H. Weyten, K. Keizer, A. Kinoo, J. Luyten, R. Leysen, Dehydrogenation of propane using a packed-bed catalytic membrane reactor. AlChE Journal. 43, 1819-1827 (1997). (3) - S.- J. Kim, Y. Liu, J. S. Moore, R. S. Dixit, J. G. Pendergast, D. Sholl, C. W. Jones, S. Nair, Thin Hydrogen-Selective SAPO-34 Zeolite Membranes for Enhanced Conversion and Selectivity in Propane Dehydrogenation Membrane Reactors. Chemistry of Materials. 28, 4397-4402 (2016). (4) - S. Pati, N. Dewangan, Z. Wang, A. Jangam, S. Kawi, Nanoporous Zeolite-A Sheltered Pd-Hollow Fiber Catalytic Membrane Reactor for Propane Dehydrogenation. ACS Appl Nano Mater. 3, 6675-6683 (2020).

[0081] The catalyst system of the disclosure outperformed other systems with respect to selectivity/conversion performance metrics. For example, at 580? C., these catalyst systems reach ?123% propane conversion (relative to equilibrium conversion) with over 95% propylene selectivity. The performance can be even further improved relative to the thermodynamic equilibrium limit to over 140% conversion (relative to the eq. conversion) with 100% propylene selectivity at 500? C. As shown in FIG. 3E, the catalyst system of the disclosure had selectivity/conversion performance that was well above most other PBR catalysts and catalyst systems previously tested for propane dehydrogenation. Conventional catalysts generally suffer from poor selectivity or conversion.

[0082] The catalyst system of the disclosure also demonstrated improved stability as compared to conventional PDH catalyst. Conventional catalysts have limited stability under PDH reaction conditions. Poor stability in these conventional systems is not surprising since they operate under carbon-rich, reducing conditions which are fertile for the formation of solid carbon deposits. These harsh conditions are further exacerbated by the removal of H.sub.2. To overcome these difficulties, a large majority of previous studies of catalyst/membrane systems resorted to significant propane feed dilution and co-feeding H.sub.2, which defeats the purpose of using the catalyst/membrane systems to shift reaction equilibrium conversion. Contrary to conventional systems and the expectation in the art, the catalyst systems of the disclosure have significantly improved stability as compared to conventional catalysts, even systems that resorted to feed dilution and co-feeding H.sub.2. FIG. 4 shows propane conversion and propylene selectivity as a function of time obtained on the Pt.sub.1Sn.sub.1/SiO.sub.2 catalyst/membrane system described in the examples at 580? C., in a pure propane stream, a WHSV of 1.3 h.sup.?1 and a sweep:feed ratio of 10. The catalyst system of the disclosure deactivated slowly over time. The rate of deactivation of the catalyst system of the disclosure was compared to the measured rates of deactivation of conventional systems in Table 1. To compute the rates of deactivation, the propane conversion data, reported as a function of time for different catalysts, were analyzed assuming first-order deactivation kinetics to calculate the catalyst deactivation coefficient, k.sub.d, as is usually done for catalytic reactions on supported metal nanoparticles.

TABLE-US-00002 TABLE 2 Inverse deactivation Initial Conversion/ Catalyst, Temperature coefficient, forward rate equilibrium # Membrane (? C.) 1/k.sub.d (h) (mol/g/s) conversion Ref. 1 7.5 wt % 500 112 8.73E?7 132 (2) Cr/Al.sub.2O.sub.3, SiO.sub.2/Al.sub.2O.sub.3 2 1% Na.sub.2O- 600 8.31E?07 156.3 (3) doped 20% Cr.sub.2O.sub.3 80% Al.sub.2O.sub.3, SAPO-34 3 7.5 wt % 600 9 75 (4) Cr/Al.sub.2O.sub.3, Pd/Al.sub.2O.sub.3 4 Pt- 550 23.813 (5) based/alumino silicate, SiO.sub.2/Al.sub.2O.sub.3 5 Pt/SBA-15, 500 0.9323 (6) Pd/Al.sub.2O.sub.3 6 Pt/Al.sub.2O.sub.3, 450 0.0869 (7) Pd/Ag/Al.sub.2O.sub.3 7 PtSn/SiO.sub.2 580 262.7 4.28 ? 10.sup.?05 98.0 (1) 8 PtSn/SiO.sub.2 580 100.9 8.52 ? 10.sup.?05 99.5 (1) (diluted) 9 Pt/Al.sub.2O.sub.3 580 5.32 5.02 ? 10.sup.?06 24.8 (1) 10 PtSn/Al.sub.2O.sub.3 580 7.61 7.39 ? 10.sup.?06 34.6 (1) 11 PtSn/Al.sub.2O.sub.3 580 31.7 1.74 ? 10.sup.?05 93.2 (1) 12 PtSn/Al.sub.2O.sub.3 519 8.53 4.10 ? 10.sup.?05 92.3 (8) 13 PtSn/MgAl.sub.2O.sub.4 550 30.5 2.34 ? 10.sup.?06 52.2 (9) 14 PtGa/ 605 42.3 1.21 ? 10.sup.?05 73.6 (10) MgAl.sub.2O.sub.4 15 PtSn/SiO.sub.2 555 24.4 1.90 ? 10.sup.?05 (11) 16 PtNa/Sn- 590 83.3 1.43 ? 10.sup.?05 88.2 (12) ZSM-5 17 PtZn/NaY 555 21 6.76 ? 10.sup.?06 79 (13) 18 PtSnNa/ 590 41.3 5.61 ? 10.sup.?06 58.1 (14) Al-SBA-15 19 Pt/Mg(Ga)(Al) 600 5.1 6.16 ? 10.sup.?05 28.6 (15) O 20 Pt/Mg(In)(AI)O 600 7.28 8.30 ? 10.sup.?05 36.4 (16) 21 Meso. 580 1.9 1.86 ? 10.sup.?06 19 (17) CrO.sub.x/Al.sub.2O.sub.3 22 Cr.sub.2O.sub.3-pillared 550 4.2 2.28 ? 10.sup.?06 26.5 (18) on ZrP 23 GaCr mixed 550 2.4 3.76 ? 10.sup.?06 40.5 (19) oxide on ZrP 24 CrO.sub.x/ZrO.sub.2 550 3.8 1.76 ? 10.sup.?06 73.6 (20) 25 CrSiZr on 450 8.3 1.08 ? 10.sup.?06 83.4 (21) Xerogel 26 CrNa/Al.sub.2O.sub.3 550 14.5 5.25 ? 10.sup.?07 75.3 (22) 27 Ga.sub.2O.sub.3/SiO.sub.2 550 2.8 4.03 ? 10.sup.?07 36.9 (23) 28 BGa.sub.2O.sub.3 500 4.8 3.60 ? 10.sup.?07 51.3 (24) 29 Ga.sub.2O.sub.3 600 1.5 2.72 ? 10.sup.?07 42.7 (25) 30 Ga.sub.2O.sub.3/ZrO.sub.2 600 1.3 8.51 ? 10.sup.?07 42.0 (26) 31 Ga.sub.5Al.sub.5O.sub.15 500 5.9 7.65 ? 10.sup.?07 80.4 (27) 32 Ga.sub.5Al.sub.2O.sub.15 500 11.2 7.02 ? 10.sup.?07 77.3 (27) 33 0.35 wt % 590 146 2.27 ? 10.sup.?03 97.4 (28) PtSn/Al.sub.2O.sub.3- nanosheet 34 0.5% Pt- 590 82.6 6.81 ? 10.sup.?04 97 (29) 0.9% Sn/Al.sub.2O.sub.3 35 PtSn/CeO.sub.2 680 26.6 3.90 ? 10.sup.?05 49.5 (30) 36 K-PtSn@MFI- 600 76.7 7.70 ? 10.sup.?03 55.3 (31) 22 h 37 Pt-Sn/SiO.sub.2 500 2.38 ? 10.sup.?03 (32) 38 Pt-Sn/SiO.sub.2 500 28.8 3.02 ? 10.sup.?03 84.1 (33) 39 K-PtSn@MFI 600 83.8 4.72 ? 10.sup.?03 100 (34) 40 PtSn/SiO.sub.2, 580 57.2 2.18E?5 123 This SiO.sub.2/Al.sub.2O.sub.3 work 41 PtSn/SiO.sub.2, 500 3015 5.72E?6 136 This SiO.sub.2/Al.sub.2O.sub.3 work

[0083] Without intending to be bound by theory, it is believed that the decline in the performance of the catalyst system of the disclosure is related to a gradual deactivation of the P.sub.1Sn.sub.1 catalyst due to the formation of solid carbon on catalyst surface, which is a general feature of propene dehydrogenation processes. FIG. 4B show that the performance of the membrane was stable over time under the reaction conditions. FIG. 4B shows the measured H.sub.2 removal rate and the H.sub.2/C.sub.3H.sub.8 separation factor as a function of time for the stability experiments shown in FIG. 4A. Although the H.sub.2 removal rate slightly decreases over time (due to the decreasing propane conversion, i.e., lower H.sub.2 produced), the results show that membrane can perform selective separation (H.sub.2/C.sub.3H.sub.8 separation factor=15) for a long period of time despite the high-reducing, coke-forming environment.

[0084] The catalyst system of the disclosure further beneficially can allow for operation at lower temperatures. For example, the catalyst system can operate for a dehydrogenation process at a temperature of about 400? C. to about 600? C. For example, the temperature can be about 400, 450, 500, 550, 600? C. and any ranges defined by such values and any values there between. The carbon-induced deactivation that occurs in dehydrogenation catalysis can be significantly limited by operating at lower temperatures. Additionally, lower temperature operation reduces energy input. In conventional systems, lower temperature would be expected to result in a decline in the propane equilibrium conversion. However, this was not observed in the catalyst systems of the disclosure. Without intending to be bound by theory, it is believed that the ability to operate at lower temperatures without sacrificing performance is achieved because the catalyst system is able to bypass the equilibrium limits as illustrated in FIG. 15.

[0085] Successful lower temperature operation of the catalyst system is shown FIG. 5A, which shows the propane conversion and propylene selectivity as a function of time at 500? C. and 540? C. in a pure propane stream ((diluted by sweep gas backflow), a WHSV of 0.43 Wand a sweep: feed ratio of 10. Contrary to performance at 580? C., the system exhibited remarkable stability at these lower temperatures with >99% propylene selectivity. The operation of the catalyst system of the disclosure was compared to the performance of the same Pt.sub.1Sn.sub.1/SiO.sub.2 catalyst operated in a packed bed reactor (PBR) under the thermodynamic equilibrium limit at 500? C., without the H.sub.2 separating membrane, with the same amount of Ar as was present in the catalyst/membrane system. The data show that the catalyst system of the disclosure operates above the PBR performance by approximately 7 percent higher conversion without noticeable deactivation for more than 90 hours on stream. This improvement is equivalent to a 30? C. enhancement (temperature required to be able to operate a PBR at the same initial membrane system propane conversion).

[0086] In FIG. 5B it can be seen that the catalyst system of the disclosure exhibits very stable performance even as the flow rates are significantly increased. These increased flow rates lead to lower conversions since the utilization of the catalysts is escalated under these conditions. At 500? C., the catalyst system of the disclosure was observed to be very stable with low deactivation rates at close to 100% selectivity to propylene

EXAMPLES

[0087] A catalyst system in accordance with the disclosure included an Al.sub.2O.sub.3/Si.sub.2 hollow fiber membrane packed with a Pi.sub.1Sn.sub.1/SiO.sub.2 PDH catalyst.

[0088] H.sub.2PtCl.sub.6.6H.sub.2O (>37.5% Pt, Sigma-Aldrich), SnCl.sub.2.2H.sub.2O (reagent grade, Sigma-Aldrich), silica gel (high purity, pore size 60 ?, Sigma-Aldrich) were used for catalyst synthesis. Porous ?-Al.sub.2O.sub.3 ceramic hollow fiber (20 nm pore size) membranes on tubular supports of asymmetric structure (4.8 mm outer diameter (OD) and 3 mm inner diameter (ID)) from Coorstek have been used as supports. Tetraethyl orthosilicate (TEOS, Sigma-Aldrich, 99.9%) was used as a precursor for silica deposition. All materials were used as received without further purification.

[0089] Pt.sub.1Sn.sub.1/SiO.sub.2 catalysts were synthesized using incipient wetness impregnation. The catalyst is fabricated by mixing chloroplatinic acid (H.sub.2PtCl.sub.6) and tin (II) chloride (SnCl.sub.2) in 0.1 M hydrochloric acid solution to form a heterometallic PtSn coordination complex such that the final weight percentages of Pt and Sn were 1 and 0.6 wt % (atomic ratio was 1:1). This solution was used to impregnate the SiO.sub.2 support and obtain small PtSn nanoparticles (between 1 and 2 nm in diameter) upon the reduction. After impregnation, the catalyst was dried overnight at 80? C. Detailed synthesis procedures have been reported previously in A. H. Motagamwala, R. Almallahi, J. Wortman, V. O. Igenegbai, S. Linic, Stable and selective catalysts for propane dehydrogenation operating at thermodynamic limit. Science 373, 217 (2021). Extensive catalyst characterization was also previously performed, showing its unique features of mixing of Sn and Pt atoms in the PtSn nanoparticles, small size of the nanoparticles (1-2 nm), and the stability against the separation of Sn from Pt on the SiO.sub.2 support.

[0090] The membrane included a porous Al.sub.2O.sub.3 tube that had an outer diameter of about 4.8 mm and a thickness of about 0.9 mm. The tube consisted of two layers: an outer layer of .Math.860 micrometers (?m) with a 200 nm average pore size distribution, and an inner ?10 ?m layer with a 20 nm average pore size distribution. The tube was formed by first cutting an alumina hollow fiber was cut into smaller sections (4 cm) using a diamond saw. Next, a fiber section was connected to two non-porous alumina tubes at both ends and sealed with a combination of ceramic and glass sealants. Alumina rods were attached on the non-porous tubes as supplemental support to the fiber and alumina tubes, to prevent mechanical stresses from resulting in any breakage. The sealed fiber/tubes system was placed in a furnace and heated to 900? C. at 1? C./min in flowing air to cure the seal, and then cooled to the silica deposition temperature of 600? C. at 1? C./min. The non-porous alumina tubes used as additional support has a 12.7 mm OD.

[0091] SiO.sub.2 was deposited on the inner side of the Al.sub.2O.sub.3 tube through chemical vapor deposition (CVD) of tetraethyl orthosilicate (TEOS) at 600? C. The deposition process was conducted by placing two concentric tubes in a furnace as shown in FIG. 6. The hollow fiber connected to the non-porous alumina tubes was placed inside an outer tube formed of a quartz tube having a 17 mm inner diameter. A thin SiO.sub.2 layer was deposited by a chemical vapor deposition (CVD) method where thermal decomposition of TEOS at a high temperature results in the SiO.sub.2 layer on the Al.sub.2O.sub.3 substrate. After reaching the deposition temperature of 600? C., 40 cm.sup.3/min of argon (Ar) gas was introduced on the outer, shell side of the tube, and 100 cm.sup.3/min of nitrogen gas was passed through a bubbler filled with TEOS at room temperature and introduced to the inner tube side. The deposition time was varied until separation factors (measured using the shell side outlet gas composition obtained by the GC) at Knudsen limits were obtained (FIG. 14). The CVD process was paused at various times and the permeance of H.sub.2 and N.sub.2 were measured at different deposition times at 600? C.

[0092] After silica deposition, the reactor furnace was cooled to room temperature to pack the catalyst in the hollow fiber membrane, along its entire active length. Approximately 250 mg of the Pt.sub.1Sn.sub.1/SiO.sub.2 PDH catalyst was packed inside the hollow fiber membrane on the tube side (where propane is fed), along the entire length of the tube. On the other side of the tube (shell side), an inert Ar sweep gas was used to carry the separated H.sub.2. The SiO.sub.2/Al.sub.2O.sub.3 membrane allows for some diffusion (backflow) of Ar to the inner tube side, and this backflow-induced dilution of the reactive mixture was accounted for in the calculations of the equilibrium propane conversion.

[0093] Propane dehydrogenation experiments were conducted in a packed-bed membrane reactor. The membrane setup consisted of two concentric tubes for a typical membrane tube and shell design (FIG. 7).

[0094] In a typical test, 250 mg catalyst was used. The catalyst bed was supported by quartz wool plug on either side. Once the catalyst was loaded in the reactor, the system was purged with N.sub.2 (80 cm.sup.3/min) on the tube side and Ar (80 cm.sup.3/min) on the shell side. Following the purge, the gas composition on the tube side was changed to 20:80 H.sub.2:N.sub.2 (100 cm.sup.3/min) and the catalyst was heated at 2? C./min to 600? C. and held at 600? C. for 1 hour. Following the reduction at 600? C., the gas flow was switched to N.sub.2 (100 cm.sup.3/min) and the reactor was cooled to the reaction temperature at 2? C./min. Once the reaction temperature was achieved, the inlet composition was changed to measure catalyst performance. The feed composition was 100 vol % C.sub.3H.sub.8. An Ar sweep gas was maintained on the shell side throughout the process in membrane experiments and was varied between 12-50 cm.sup.3/min during testing experiments to measure performance at different sweep-to-feed ratios. The propane feed flow was also varied for various WHSVs (based on propane flow) between 1-5 cm.sup.3/min in the packed-membrane reactor. The effluent from the reactor (tube and shell sides) was measured using the GC. The tube side products were used to calculate propane conversion, propylene selectivity, and propylene yield. The amount of Argon backflowing into the tube side was also monitored using the GC and accounted for as a diluent in the calculations of equilibrium conversion. The shell side products were used to calculate the H.sub.2 removal rate. Both tube and shell side products were used to calculate the H.sub.2/C.sub.3H.sub.8 separation factor.

[0095] The effectiveness of the SiO.sub.2/Al.sub.2O.sub.3 hollow fiber membrane in separating H.sub.2 was evaluated through a series of gas permeation and separation characterization experiments. It is desirable to have a membrane that can reach Knudsen separation limits. A study of H.sub.2 separation from an equimolar H.sub.2/N.sub.2 mixture was performed by measuring the H.sub.2 permeance and the H.sub.2/N.sub.2 separation factors as a function of TEOS deposition time. The deposition time is proportional to the amount of SiO.sub.2 deposited and the thickness of the SiO.sub.2 separating layer (FIG. 14). In these studies, TEOS deposition was performed until the H.sub.2/N.sub.2 separation factor (eq 2) was measured to be close to the Knudsen-separation limit (3.7 for H.sub.2/N.sub.2 separation (eq 3)). It was measured that for the SiO.sub.2 layer thickness required to reach the H.sub.2/N.sub.2 Knudsen separation limits, the H.sub.2 permeability through the membrane was relatively high at >1.10.sup.?7 mol/m.sup.2 s Pa for an equimolar mixture of H.sub.2/N.sub.2 with a total flow rate of 80 cm.sup.3/min and a sweep:feed ratio of 0.5. The sweep rate was the rate at which the Ar inert gas is moved on the shell side, removing gases that permeate through the membrane.

[0096] Data in FIG. 2 show the performance of the SiO.sub.2 based membrane in the context of the H.sub.2/N.sub.2 Knudsen separation, in separating H.sub.2/C.sub.3H.sub.8 mixtures. Data in FIG. 2A show the H.sub.2 permeability and the H.sub.2/C.sub.3H.sub.8 separation factors measured at a total flow rate of 10 cm.sup.3/min of an equimolar mixture of H.sub.2 and C.sub.3H.sub.8 at a sweep:feed ratio of 6. At 580? C., where PDH is often operated, the SiO.sub.2/Al.sub.2O.sub.3 hollow fiber membrane exhibited a H.sub.2 permeability of ?2.10.sup.?7 mol/m.sup.2s Pa and a H.sub.2/C.sub.3H.sub.8 separation factor of 19. The data in FIG. 2B show the membrane performance was stable over time with no performance degradation over the duration of the study of ?20 hrs. The data in FIG. 2C show higher separation factors at higher sweep:feed ratios, even exceeding the Knudsen limit. This high separation factors can be attributed to higher sweep-induced change to the driving force to diffuse H.sub.2 through the membrane compared to the driving force to diffuse propane, i.e., the partial pressure of H.sub.2 (P.sub.H2) is lowered on the shell side by increasing the sweep gas flow rate. It was also found that increasing the sweep: feed ratio above 6 did not lead to further increases in the separation factors.

[0097] Data in FIG. 3A show the performance of the catalyst system in propane dehydrogenation at 580? C., measured at pure propane feed (diluted by Ar backflow discussed above), sweep:feed ratios between 4-10 and a constant weight hourly space velocity (WHSV) of 1.3 h.sup.?1. WHSV is defined as the mass of propane entering the reactor per unit time divided by the mass of the catalyst in the reactor. The different sweep:feed ratios were obtained by varying the Ar sweep gas flow rate on the shell side between 12-50 cm.sup.3/min to increase selective separation as described earlier. It was observed that the thermodynamic limit on propane conversion under these reaction conditions (dashed black line) was 50-52%, depending on the amount of Ar diluent present at the different sweep:feed ratios. At these conditions, the catalyst system reached propane conversions up to 10% higher than the equilibrium conversion with >95% propylene selectivity.

[0098] Another parameter that can be tuned to improve the H.sub.2 removal rate is the WHSV, since at higher gas residence times (as the WHSV is lowered), a membrane can remove higher fractions of H.sub.2 produced during the reaction. Data in FIG. 3B show the performance of the catalyst/membrane system for propane dehydrogenation at 580? C., pure propane feed (diluted by Ar backflow), a constant sweep:feed ratio of 10, and with WHSVs changing between 0.86-2.16 h.sup.?1. The different WHSVs were obtained by varying the propane flow rate on the tube side between 2-5 cm.sup.3/min for a constant catalyst loading of 250 mg. It was observed that as WHSV is decreased, propane conversion is significantly increased without sacrificing the product selectivity. The changes in the limiting, equilibrium conversion (dashed line in FIGS. 3A and B) are due to the different levels of Ar backflow at different conditions.

[0099] Data in FIG. 3C show propylene yield in the catalyst system as a function of the two dimensionless numbers, Da and Pe (calculated using eq 7-8). That data was obtained at 580? C., using a pure propane stream. The Da and Pe numbers were varied by changing the WHSV and sweep:feed ratio covering the range of WHSVs between 0.86 and 2.16 h.sup.?1 and sweep:feed ratios of 4-10. The partial H.sub.2 pressure different across the membrane was changed by changing the sweep:feed ratio, therefore affecting the Pe number, while changing WHSV impacts both the Da and Pe numbers. The data in FIG. 3C show that an improved performance is seen at higher Da and lower Pe.sup.27,29 and that at 580? C. the highest propylene yield of 65% was achieved, which is 10% above the equilibrium limit (assuming 100% selectivity to propylene) of 55%. Based on these analysis, it was concluded that for the hollow fiber catalyst/membrane tubular geometries analyzed herein, at 580? C. the enhancement factors in propylene yield and conversion of approximately 10% compared to the equilibrium conversion (from 55 to 65% conversion increase) beyond that observed in the present testing is possible.

Characterization

[0100] The deposition resulted in the formation of a thin SiO.sub.2 separation layer on the inner side of the Al.sub.2O.sub.3 tube as shown in the cross-section image in FIG. 1D. The SiO.sub.2 separation layer was formed to a thickness of about 500 nm. The deposited SiO.sub.2 covered the entire inner surface of the porous Al.sub.2O.sub.3 tube. This was confirmed by SEM imaging as shown in FIG. 1E. Referring to FIG. 1E, it can be seen that the SiO.sub.2 separation layer was a smooth layer with very small pore size distribution and no pin holes or cracks. The complete coverage of the Al.sub.2O.sub.3 inner surface with the SiO.sub.2 separation layer was also confirmed using x-ray photoelectron spectroscopy (XPS). FIGS. 1F and 1G show the XPS spectra associated with the characteristic Si 2 p and Al 2 p peaks for the SiO.sub.2 coated and uncoated Al.sub.2O.sub.3 tubes, respectively, showing that no Al peaks were detected for the SiO.sub.2 coated sample. FIG. 11 is an X-ray diffraction patter for the membrane, but only shows the spectra for the Al.sub.2O.sub.3 substrate since the topmost SiO.sub.2 layer is amorphous. FIGS. 12-13 show survey photoemission spectra of the coated and uncoated samples respectively.

[0101] X-ray diffraction (XRD) was used to confirm the Al.sub.2O.sub.3 crystalline phases in the hollow fiber membranes. XRD data was collected using Rigaku MiniFlex 600 (Cu K? source, ?=1.54059 ?) with a tube voltage of 40 kV and a current of 15 mA. A continuous scan mode was used to collect 2? data with a step size of 0.02? and speed of 2?/min.

[0102] Samples of the alumina support substrate and silica-coated membrane were characterized using a scanning electron microscope (Tescan MIRA3). The samples were prepared by mechanically breaking the membranes and sputter-coating them with gold before loading them into the microscope. Morphologies and layer thicknesses were evaluated at a 12 kV accelerating voltage. The cross-section image (FIG. 1D) was obtained using focused ion-beam milling (FIB) on a TFS Nova 200 Nanolab with an accelerating voltage of 5 kV.

[0103] X-ray photoelectron spectroscopy (XPS) was performed to determine the surface composition of SiO.sub.2-coated and uncoated Al.sub.2O.sub.3 membrane samples. XPS data was taken using a Kratos Axis Ultra XPS with a monochromated alumina K? source operating at 8 mA and 14 kV. Regional Si 2 p and Al 2 p scans were acquired using 5 sweeps with a dwell time of 60 seconds. In all experiments, the charge neutralizer was used to prevent charging of the samples, and the carbon 1s peak at 285 eV was used to detect any shifting of the spectrum.

Gas Permeation Measurements

[0104] Gas permeation measurements were conducted in the previously described setup (FIG. 7) and in the temperature range of 355-580? C., by flowing an equimolar mixture of H.sub.2 and C.sub.3H.sub.8 at atmospheric pressure in the inner tube and varying flow rates of Ar as a sweep gas on the outer shell side to carry the permeating gases. The driving force for the H.sub.2 transport through the membrane is created by using an inert (Ar) sweep gas in a co-current mode. Various flow rates and sweep-to-feed ratios were investigated. All gas flow rates were controlled using mass flow controllers (Cole-Parmer), and the effluent gases from both the tube, shell, and combined tube/shell side effluents were analyzed by a gas chromatograph (Agilent 7890B GC) equipped with a flame ionization detector and two thermal conductivity detectors. Gas permeances were calculated using the outlet gas flow rate and the concentration of the permeated gas on the shell side obtained using the GC. The total pressure on both sides of the membrane was maintained at atmospheric pressure. The membrane permeance is defined as the gas flux through the membrane per unit surface area per the partial pressure difference (Equation 1).

[00001]$\begin{array}{cc}\mathrm{Permeance}\left(\frac{\mathrm{mol}}{m^{2}s\mathrm{Pa}}\right)=\frac{y_i{F}_{shell}}{A?P_i}& \left(1\right)\end{array}$

[0105] Where y.sub.i is the molar fraction of the permeating gas, F.sub.shell is the flow rate on the shell side, A is the effective membrane area of the hollow fiber, and ?P.sub.i is the partial pressure difference.

[0106] The separation factor is calculated from the molar fractions of the two gases in the permeate and retentate streams (Equation 2) and is compared to the Knudsen separation factor (Equation 3).

[00002]$\begin{array}{cc}\mathrm{Seperation}{\mathrm{Factor}}_{A,B}=\frac{\frac{x_A}{x_B}}{\frac{y_A}{y_B}}& \left(2\right)\end{array}$

[0107] where x.sub.A and x.sub.B are the molar fractions of gases A and B in the permeate stream and y.sub.A and y.sub.B are the molar fractions of gases A and B in the retentate stream.

[00003]$\begin{array}{cc}\mathrm{Seperation}{\mathrm{Factor}}_{\mathrm{Kn},A,B}=\sqrt{\frac{M_B}{M_A}}& \left(3\right)\end{array}$

[0108] where M.sub.i is the molar mass of gas i.

Calculations Based on Reaction Testing

[0109] Propane conversion was calculated on a carbon basis:

[00004]$\begin{array}{cc}\mathrm{Propane}\mathrm{Conversion}=\frac{\begin{array}{c}1?F_{C{H}_4}+2?F_{C_2{H}_6}+2?\\ F_{C_2{H}_4}+3?F_{C_3{H}_6}\end{array}}{\begin{array}{c}1?F_{C{H}_4}+2?F_{C_2{H}_6}+2?F_{C_2{H}_4}+\\ 3?F_{C_3{H}_{?}}+3?F_{C_3{H}_8}\end{array}}& \left(4\right)\end{array}$

[0110] Propylene selectivity was also calculated on a carbon basis:

[00005]$\begin{array}{cc}\mathrm{Propylene}\mathrm{selectivity}=\frac{3?F_{C_3{H}_6}}{\begin{array}{c}1?F_{C{H}_4}+2?F_{C_2{H}_6}+2?\\ F_{C_2{H}_4}+3?F_{C_3{H}_6}\end{array}}& \left(5\right)\end{array}$

[0111] Propylene yield:

Propylene yield=propane conversion?propylene selectivity (6)

[0112] Damkohler number:

[00006]$\begin{array}{cc}Da=\frac{\mathrm{initial}\mathrm{reaction}\mathrm{rate}?M{W}_{C_3{H}_8}}{\mathrm{WHSV}}& \left(7\right)\end{array}$

[0113] Peclet number:

[00007]$\begin{array}{cc}Pe=\frac{\mathrm{WHSV}?{\mathrm{mass}}_{cat}}{M{W}_{C_3{H}_8}?\mathrm{permeance}?\mathrm{membrane}\mathrm{area}}& \left(8\right)\end{array}$

Catalyst System Operated with O.SUB.2 .Flow

[0114] A catalyst system in accordance with the disclosure was operated for PDH with a sweeping gas including 0-15% O.sub.2 in the sweeping gas flow. Referring to FIG. 25A, the performance of the system in PDH at 500? C., measured for a pure propane feed (diluted by N2 backflow discussed above), sweep:feed ratio of 12 including 0-15% O.sub.2 in the sweeping flow rate, and a constant weight hourly space velocity (WHSV) of 0.86 h?1 is shown. The total N.sub.2 sweeping flow rate on the shell side was maintained at 24 cm.sup.3/min to maintain a constant sweeping driving force even as different amounts of O.sub.2 were introduced. WHSV is defined as the mass of propane flowing per unit time divided by the catalyst mass. The thermodynamic limit on propane conversion under these reaction conditions was also shown in FIG. 25A as being 22% based on the amount of N.sub.2 backflow. A high sweep:feed ratio was used to promote higher selective H.sub.2 permeation, because the H.sub.2 partial pressure driving force is increased. By using the sweeping gas to remove permeated H.sub.2 from the reaction zone, the reaction is shifted to the product side, and therefore, propane conversion was enhanced beyond traditional equilibrium limits imposed on the PDH reaction. The data show that at these conditions, before introducing O.sub.2 in the N.sub.2 sweep, the catalyst system reached a propane conversion up to 28%, which is 6% higher than equilibrium conversion with >99% propylene selectivity. Next, 6-15 vol % of O.sub.2 was introduced in the N.sub.2 sweeping gas on the shell side. As a result of this O.sub.2 presence in the sweeping gas, higher propane conversions of 31-35% were obtained Without intending to be bound by theory, it is believed that these greater propane conversions are due to increasing H.sub.2 removal levels because of the consumption of H.sub.2 by O.sub.2 in the oxidation reaction. However, this increase in propane conversion was associated with a slight decrease in propylene selectivity because of the emergence of carbon oxide (CO.sub.x) products. Nonetheless, selectivity to propylene was still maintained above 95%. To account for this lower propylene selectivity, propylene yield was also calculated as the product of propane conversion and propylene selectivity. Propylene yield for the O.sub.2 conditions was 3-6% above the no O.sub.2 in sweep case, for a total of 8-11% above equilibrium limits.

[0115] Referring to FIG. 25B, H.sub.2 removal percentages for the catalyst system at the different amounts of O.sub.2 in the inert sweeping gas are shown. H.sub.2 removal was calculated by comparing the relative partial pressures of propylene and H.sub.2 on the tube side, since the reaction stoichiometry for PDH with no H.sub.2 removal stipulates equal amounts of both products. At 0% O.sub.2 in the inert sweeping gas, the membrane was able to remove 76% of H.sub.2 produced by the PDH reaction. To achieve this high H.sub.2 removal rate, several parameters were considered and optimized, including the sweeping flow rate, WHSV as well as the membrane reactor geometry. High sweeping flow rates of 24 cm.sup.3/min were used to maximize selective H.sub.2 removal, as the H.sub.2 diffusion driving force becomes higher. A low WHSV of 0.86 h.sup.?1 was used to closely match the dehydrogenation reaction rate to the H.sub.2 transport rate. The data show that when O.sub.2 is present in the sweeping gas, H.sub.2 removal is improved to 86-96%, with H.sub.2 being almost completely depleted from the reaction zone. Without intending to be bound by theory, it is believed that this higher H.sub.2 removal is due to an even higher driving force when O.sub.2 is present, prompted by the combustion of H.sub.2 and its subsequent consumption (H.sub.2 removed from the tube side and is now consumed on the shell side) which leads to an increase in the H.sub.2 partial pressure driving force gradient.

[0116] The product distributions on a carbon-atom basis for both the tube and shell sides are shown in FIGS. 25C and 25D. Although using O.sub.2 in the sweeping gas improved propane conversion, it decreased propylene selectivity on the tube side from 99% to 95% when 15% O.sub.2 was used. Because the membrane operates in a Knudsen separation regime, H.sub.2 removal is associated with backflow of shell side gases to the tube side. As mentioned above, N.sub.2 backflow to the tube side was monitored and accounted for in equilibrium propane conversion calculations. Similarly, when O.sub.2 was used in the sweeping gas, CO.sub.x products (CO and CO.sub.2) were monitored on both sides of the catalyst system and accounted for in product distribution calculations. For the 0% O.sub.2 case, the main reaction product was propylene (>99% selectivity) with very little propane cracking and hydrogenation side products (methane, ethane, and ethylene) on both the tube and shell sides. This high propylene selectivity, specifically in the catalyst system, is an advantage to lower temperature operation of PDH which is limited to membrane reactors, as otherwise low temperatures limit equilibrium conversion in traditional packed bed reactors. The data show that when O.sub.2 is present in the sweeping gas, CO.sub.x products start to form, especially on the shell side. Since O.sub.2 and CO.sub.2 have similar kinetic diameters and the SiO.sub.2/Al.sub.2O.sub.3 membrane used in this system performs selective separation close to the Knudsen separation limits (molecule size dependent), it is possible that either the CO.sub.x products or O.sub.2 backflowed to the tube side, where O.sub.2 reacted with propane and formed CO.sub.x. At 15% O.sub.2 in the inert sweeping gas, CO.sub.x products constituted 4% of the product distribution on the tube side and 19% on the shell side, with CO.sub.2 being the main product. The amount of C-based products diffusing from the tube to the shell side was calculated to be 9-18% for the different amounts of O.sub.2 fed in the sweeping gas.

[0117] The water formation rates at the different O.sub.2 amounts were calculated using a humidity sensor, by monitoring the relative humidity in the outlet shell side stream. FIG. 26A shows measured water formation rates at the different O.sub.2 amounts in the sweeping gas. Water formation increased as O.sub.2 levels were increased, corroborating higher H.sub.2 removal shown in FIG. 5B. Using these water formation rates, material balances and production rates, and heats of reactions for all endothermic and exothermic reactions present in the catalyst/membrane system, a heat analysis was performed to determine the feasibility of thermoneutral PDH operation (calculation details are included in the methods section). FIG. 26B shows the heat requirement mainly by PDH and heat release from oxidation reactions at 0-15% O.sub.2 in the sweeping gas. When no O.sub.2 is present in the sweep (0% O.sub.2), the main reaction is endothermic PDH, and therefore, the heat flow calculated is required by the reaction and represented by the red vertical bar. When 6% O.sub.2 is used in the sweeping gas, heat release by the exothermic oxidation reactions is close to matching the heat requirement by PDH (providing ?90% of the heat needed). This is supported by the increase in H.sub.2 removal (FIG. 5B) and the water and CO.sub.x formation rates detected and measured. At 10-15% O.sub.2 in the sweeping gas, heat release surpasses the heat requirement by PDH especially at 15% O.sub.2 (supported by the highest H.sub.2 removal levels and highest formation rates of water and CO.sub.x products). These heat calculation results confirm that thermoneutral operation of PDH in a catalyst system is possible by coupling PDH to exothermic oxidation reactions using mild oxidative conditions on the outer shell side of the catalyst system and allowing for heat exchange.

[0118] H.sub.2 removal was calculated using the remaining amounts of propylene and H.sub.2 on the tube side (Equation). The humidity level on the shell side was measured using a humidity sensor (Traceable Hygrometer) and used to calculate the water formation rates (Equation 10).

[00008]$\begin{array}{cc}{H}_2\mathrm{Removal}\left(\%\right)=\left(1-\frac{P_{H_2}}{P_{\mathrm{propylene}}}\right)?100& \mathrm{Equation}9\end{array}$$\begin{array}{cc}{H}_{2}O\mathrm{formation}\mathrm{rate}=\frac{P_{\mathrm{sat}}}{P}?\frac{\mathrm{Relative}\mathrm{Humidity}}{100}?F_{\mathrm{shell},\mathrm{out}}& \mathrm{Equation}10\end{array}$

Heat Calculation Methods

[0119] The heat requirement by, mainly, the endothermic PDH reaction and the heat release by the exothermic H.sub.2 oxidation and oxidative PDH (as per formation of CO.sub.x products) reactions were calculated. The calculation was carried out by first using compound heats of formation and heat capacities at standard conditions (obtained from the National Institute of Standards and Technology (NIST) Chemistry WebBook) as well as their stoichiometric coefficients to calculate the enthalpies of reaction at the PDH temperature. In this calculation, the standard heat capacities were assumed to be independent of temperature. Next, using the experimentally measured product formation rates (taking stoichiometry into account) and the calculated enthalpies of reaction, the heat requirement by endothermic reactions and the heat release by exothermic reactions were calculated, summed into an endothermic or exothermic category, and compared. Note that because SiO.sub.2/Al.sub.2O.sub.3 membrane operates in the Knudsen diffusion regime, some of the gases backflow between the tube and shell sides. Therefore, the tube and shell side outlet flow rates and compositions were determined separately using a bubble flow meter and the GC, respectively. The heats (required or released) were then calculated and compiled into endothermic or exothermic total terms (from both tube and shell sides). The products analyzed were assumed to form by one-step reactions included with the calculated enthalpies of reaction shown below.

TABLE-US-00003 ?H.sub.f = H.sub.f? + C.sub.p?(T ? T?) Equation 11 ?H.sub.rxn = ??i?H.sub.f, i Equation 12 C.sub.3H.sub.8 .fwdarw. C.sub.3H.sub.6 + H.sub.2 ?H.sub.rxn = 134 kJ/mol C.sub.3H.sub.8 .fwdarw. C.sub.2H.sub.4 + CH.sub.4 ?H.sub.rxn = 85 kJ/mol C.sub.2H.sub.4 + H.sub.2 .fwdarw. C.sub.2H.sub.6 ?H.sub.rxn = ?145 kJ/mol C.sub.3H.sub.8 + 3.5O.sub.2 .fwdarw. 3CO + 4H.sub.2O ?H.sub.rxn = ?506 kJ/mol C.sub.3H.sub.8 + 5O.sub.2 .fwdarw. 3CO.sub.2 + 4H.sub.2O ?H.sub.rxn = ?1965 kJ/mol H.sub.2 + O.sub.2 .fwdarw. H.sub.2O ?H.sub.rxn = ?246 kJ/mol

[0120] The foregoing description is given for clearness of understanding only, and no unnecessary limitations should be understood therefrom, as modifications within the scope of the disclosure may be apparent to those having ordinary skill in the art.

[0121] All patents, patent applications, government publications, government regulations, and literature references cited in this specification are hereby incorporated herein by reference in their entirety. In the case of conflict, the present description, including definitions, will control.

[0122] Throughout the specification, where the compounds, compositions, methods, and/or processes are described as including components, steps, or materials, it is contemplated that the compounds, compositions, methods, and/or processes can also comprise, consist essentially of, or consist of any combination of the recited components or materials, unless described otherwise. Component concentrations can be expressed in terms of weight concentrations, unless specifically indicated otherwise. Combinations of components are contemplated to include homogeneous and/or heterogeneous mixtures, as would be understood by a person of ordinary skill in the art in view of the foregoing disclosure.

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