LIGHT GUIDES WITH LOW REFRACTIVE COATING TO BE USED IN WATER

Abstract

The invention provides a light guide element (1300) comprising a light guide (300) and a layer element (30), wherein the light guide (300) comprises a light guide face (301) and wherein the layer element (30) comprises an optical layer (310), wherein said optical layer (310) is in contact with at least part of the light guide face (301), wherein the optical layer (310) has a first index of refraction (n1) smaller than 1.36 at 280 nm, wherein the light guide (300) comprises a UV radiation transmissive light guide material (305).

Claims

1. A light guide element comprising a light guide and a layer element, wherein the light guide comprises a light guide face and wherein the layer element comprises an optical layer, wherein said optical layer is in contact with at least part of the light guide face, wherein the optical layer has a first index of refraction (n1) smaller than 1.36 at 280 nm, wherein the light guide comprises a UV radiation transmissive light guide material.

2. The light guide element according to claim 1, wherein the optical layer is a patterned optical layer with one or more first regions comprising an optical layer material with a first layer thickness (h1) and one or more second regions comprising said optical layer material with a second layer thickness (h2) in the range of 0h2<h1, and wherein the optical layer comprises a UV radiation transmissive optical layer material.

3. The light guide element according to claim 1, wherein the first index of refraction (n1) is equal to or smaller than 1.30 at 280 nm, wherein the optical layer is a porous optical layer having a porosity in the range of 5-70%.

4. The light guide element according to claim 1, wherein the optical layer material comprises a sol-gel material.

5. The light guide element according to claim 1, wherein the layer element comprises a layer stack comprising said optical layer and further comprising a second layer in contact with at least part of said optical layer, and wherein the second layer comprises a UV radiation transmissive optical layer material.

6. The light guide element according to claim 1, comprising a second light guide face, wherein a distance (h3) between the first light guide face and the second light guide face defines a thickness of the light guide, wherein the light guide element further comprises a third layer in contact with at least part of the second light guide face.

7. The light guide element according to claim 5, wherein the second layer comprises one or more of (a) a silicone and (b) a fluoropolymer, wherein the second layer is configured to impede ingress of UV-light absorbing organic molecules into the light guide, and wherein the third layer has one or more functionalities selected from the group consisting of (a) reflective for UV radiation, (b) adhesive for adhering the light guide to an object, (c) reinforcing the light guide element, and (d) protective for the light guide.

8. The light guide element according to claim 1, wherein the light guide comprises a closed cavity filled with a UV radiation transmissive liquid, wherein the light guide comprises a first material comprising silicone, wherein the first material defines the cavity, and wherein the UV radiation transmissive liquid comprises water.

9. An anti-biofouling system comprising the light guide element according to claim 1 and a light source, wherein the anti-biofouling system comprises a radiation exit window comprising said light guide face, wherein the light source is configured to provide said UV radiation into the light guide, and wherein the radiation exit window is configured to transmit at least part of said UV radiation.

10. The anti-biofouling system according to claim 9, wherein the light source comprises a light emitting face, wherein the light emitting face is configured within the light guide.

11. The anti-biofouling system according to claim 9, wherein the light guide further comprises optical structures configured to provide an even distribution of the UV radiation downstream from said radiation exit window.

12. The anti-biofouling system according to claim 9, wherein the light guide comprises a closed cavity filled with a UV radiation transmissive liquid, wherein the light guide comprises a first material comprising silicone, wherein the first material defines the cavity, wherein the UV radiation transmissive liquid comprises water, and wherein the first index of refraction (n1) is equal to or smaller than 1.30 at 280 nm.

13. An object that during use is at least partly submerged in water, the object comprising the anti-biofouling system according to claim 9, wherein the anti-biofouling system is configured to irradiate with UV radiation during an irradiation stage one or more of (i) a part of an external surface of said object and (ii) water adjacent to said part of said external surface.

14. A method of providing an anti-biofouling system as defined in claim 9 to an object, that during use is at least temporarily exposed to water, the method comprising providing the anti-biofouling system to the object with the anti-biofouling system configured to provide said UV radiation to one or more of a part of an external surface of the object and water adjacent to said part.

15. A method of preventing and/or reducing biofouling at an external surface of an object, the external surface during use of the object being at least temporarily exposed to water, the method comprising generating UV radiation by an anti-biofouling system and providing said UV radiation to the external surface of the object and water adjacent to the external surface, wherein the anti-biofouling system comprises a light guide element according to claim 1.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0133] Embodiments of the invention will now be described, by way of example only, with reference to the accompanying schematic drawings in which corresponding reference symbols indicate corresponding parts, and in which:

[0134] FIGS. 1a-1h schematically depict some general aspects;

[0135] FIGS. 2a-2f schematically depict some embodiments; and

[0136] FIG. 3 schematically depicts some variants which may be applied, optionally in combination.

[0137] The drawings are not necessarily to scale.

DETAILED DESCRIPTION OF THE EMBODIMENTS

[0138] FIG. 1a schematically depicts an embodiment of an anti-biofouling system 200 which comprises an UV-emitting element 210. The UV-emitting element 210 comprises a UV radiation exit window 230. The UV-emitting element 210 at least partly encloses a light source 220 configured to provide UV radiation 221 (anti-fouling light). Here, by way of example three light sources 220 are depicted. Here, the UV-emitting element 210 is configured as waveguide or light guide, with elements embedded therein. Hence, the light sources 220 arein this schematically depicted embodimentembedded in the waveguide. The UV radiation exit window 230 is configured to transmit at least part of the UV radiation 221 of the light source 220. The UV radiation exit window 230 comprises an upstream window side 231, here directed to the light source(s) and a downstream window side 232. In FIG. 1a, a light guide element 1300 comprising a light guide 300 or optical medium and a layer element 30 is schematically depicted. The light guide 300 comprises a light guide face 301, which comprises the radiation exit window 230. The light guide 300 may especially be a plate with the light guide face 301 and a face opposite thereof, indicated with second light guide face 302. The distance between those faces may define a thickness or height of the light guide 300, indicated with reference h3 (the length and width (see also FIG. 2e, may be much larger than the height). The second face 302 may include a reflective layer.

[0139] The layer element 30 comprises an optical layer 310. The optical layer 310 is in contact with at least part of the light guide face 301. The optical layer is in physical contact with at least part of the light guide face. Especially, the optical layer 310 has a first index of refraction n1 smaller than 1.36 at 280 nm. Further, the light guide 300 comprises a UV radiation transmissive light guide material 305 (such as a silicone). The optical layer 310 comprises an optical layer material 315. This optical layer material 315 is especially transmissive for UV radiation but has an index of refraction smaller than water. In this way, the layer reduces outcoupling from the UV radiation when the light guide element 1300 is applied in aquatic environments, and may enhance outcoupling of radiation at other parts of the light guide face. The optical layer 310 is configured on the downstream window side 232. Here, by way of example the light guide 300 comprises optical structures 7. These may be within the guide or at the faces of the light guide 300. The optical structures 7 may be configured to provide an even distribution of the UV radiation 221 escaping from the UV emitting element 210. Here, the light sources 220 are depicted as being comprised by the light guide element 1300; however, this is not necessarily the case (see also FIG. 2c.

[0140] The light guide element 1300 in combination with the light source(s) 220 can e.g. be used as lighting module for anti-fouling of a (protected) surface. Such module may comprise (thus) at least one light source for generating an anti-fouling light, an optical medium for distributing at least part of the anti-fouling light through the optical medium, the optical medium comprising an emission surface for emitting the distributed anti-fouling light in a direction away from the protected surface when the lighting module is arranged in, on and/or near the protected surface. The the emission surface may be a substantially planar surface. The emission surface is the UV radiation exit window 230 including the layer element 30/is the light guide face 301 including the layer element 30.

[0141] FIGS. 1b-1d schematically depict embodiments of an object 10 that during use is at least partly submerged in water 2, see the water line 13. The object 10, such as a vessel or a sluice, see also below, further comprises an anti-biofouling system 200 comprising an UV-emitting element 210, especially for application of UV radiation 221 to a part 111 of an external surface 11 of the object 10, such as a hull or part or a hull. Here, two embodiments are shown wherein the anti-biofouling system 200, or more especially the UV-emitting element 210 is part of an outer surface, and thereby forms in fact part of the outer surface (FIG. 1a) or wherein the UV-emitting element 210 is configured to irradiate the outer surface and does not necessarily form part of an outer surface, such as a hull of a ship (FIG. 1c). For instance, the object 10 is selected from the group consisting of a vessel 1 and an infrastructural object 15 (see also below). Reference 400 in amongst others FIG. 1b refers to a control system, which may in embodiments control the light source(s) 220 of the anti-biofouling system 200.

[0142] The UV-emitting element 210 comprises one or more light sources 220 and may thus especially be configured to irradiate with said UV radiation 221 during an irradiation stage one or more of (i) said part 111 of said external surface 11 and (ii) water adjacent to said part 111 of said external surface 11. The former variant applies especially the embodiment of FIG. 1c, and the latter embodiment especially applies to both embodiments of FIGS. 1b-1c. Note however that when an external surface of the UV-emitting element 210 is configured as external surface of the object 10, of course the part 111 is irradiated per se with the UV radiation 21.

[0143] Hence, the UV-emitting element 210 comprises a UV radiation exit window 230 and the UV-emitting element 210 is configured to provide said UV radiation 221 downstream from said UV radiation exit window 230 of said UV-emitting element 210.

[0144] As indicated above, the term vessel, indicated with reference 1, may e.g. refer to e.g. a boat or a ship (ref. 10a in FIG. 1d), etc., such as a sail boat, a tanker, a cruise ship, a yacht, a ferry, a submarine (ref. 10d in FIG. 1d), etc. etc., like schematically indicated in FIG. 1d. The term infrastructural object, indicated with reference 15, may especially refer to aquatic applications that are in general arranged substantially stationary, such as a dam/sluice (references 10e/10f in FIG. 1d), a pontoon (ref. 10c in FIG. 1d), an oilrig (ref. 10b in FIG. 1d), etc. etc.

[0145] FIG. 1e schematically depicts in more detail an embodiment of the anti-biofouling system 200, here by way of example including an integrated control system 300 and an integrated sensor 310.

[0146] FIG. 1f schematically depicts an external surface 11 of an object 10, such as a vessel wall or a wall of an infrastructural object, with by way of example a plurality UV-emitting elements 210 (here associated to a hull 21 of a vessel 1). Alternatively or additionally, a plurality of functionally coupled or independently functioning anti-biofouling systems 200 may be applied.

[0147] FIG. 1f also schematically depicts the embodiment wherein the anti-biofouling system 200 comprises a plurality of UV-emitting elements 210 (with a plurality of light sources), a plurality of radiation exit windows 230, and a plurality of said parts 111, wherein the plurality of light sources 220 are configured to provide said UV radiation 221 via said plurality of radiation exit windows 23 to said plurality of parts 111, and wherein said plurality of parts 111 are configured at different heights of the object 10, and wherein the control system 300 is configured to control the light sources 220 individually as function of said input information. For instance, in an embodiment the control system 300 may be configured to control the light sources 220 individually as function of the positions of the parts 111 of the external surface 11 relative to the water.

[0148] FIG. 1g schematically depicts an embodiment wherein a vessel 1, as embodiment of the object 10, comprises a plurality of anti-biofouling systems 200 and/or a one or more of such anti-biofouling systems 200 comprising a plurality of UV-emitting elements 210. Dependent upon the height of the specific such anti-biofouling system 200 and/or the height of the UV-emitting elements 210, such as relative to a water (line), the respective UV-emitting elements 210 may be switched on.

[0149] FIG. 1h shows a chicken-wire embodiment where light sources 210, such as UV LEDs, are arranged in a grid and connected in a series of parallel connections. The LEDs can be mounted at the nodes either through soldering, glueing or any other known electrical connection technique for connecting the LEDs to the chicken wires. One or more LEDs can be placed at each node. DC or AC driving can be implemented. If AC is used, then a couple of LEDs in anti parallel configuration may be used. The person skilled in the art knows that at each node more than one couple of LEDs in anti parallel configuration can be used. The actual size of the chicken-wire grid and the distance between UV LEDs in the grid can be adjusted by stretching the harmonica structure. The chicken-wire grid may be embedded in an optical medium. Above, especially active prevention applications are described, wherein the anti-biofouling system 200 switches off, or switches specific UV-emitting elements 210 or specific light sources 220 off, dependent upon contact with the water, a signal of a sensor, etc. etc. However, alternatively or additionally, also warning signals or messages may be used to warn a person of danger.

[0150] FIG. 2a schematically depicts an embodiment wherein the optical layer 310 is a patterned optical layer 310. One or more first regions 311 may comprising said optical layer material 315 with a first layer thickness h1. One or more second regions 312 may comprising said optical layer material 315 with a second layer thickness h2 in the range of 0h2<h1. Here, h20. Note that the different regions may comprise different optical layer materials 315 or the same optical layer materials. Especially when the entire light guide face is in physical contact with the optical layer 310, the optical layer 310 comprises UV radiation transmissive optical layer material 315. The thickness of the layer (h1, or h1 and h2) may depend upon the distance to the closest light source; especially closer to a light source h10 and further away from the light source in embodiments h2=0. The transmission of the UV radiation through the optical layer (i.e. through height h1 (and/or h2) is especially at least 10%, such as even more especially at least 20%, such as at least 40%, like in the range of 40-95%, or even higher (i.e. for UV radiation that is not directed back into the light guide 300). This especially applied to UV radiation propagating in a direction substantially perpendicular to the light guide face 301 (in a direction away from the light guide and thus through the optical layer with the indicated layer height h1 (or h2; if any)).

[0151] Further, here by way of example a first region and a second region are indicated. Also more than two different regions may be applied

[0152] FIG. 2b schematically depicts a combination of embodiments. Amongst others, this drawing schematically depicts a porous optical layer 310. The optical layer includes pores or cavities, indicated with reference 313. These may be filled with a gas, such as a noble gas or air. Further, the layer element 30 comprises a layer stack 3 comprising said optical layer 310 and further comprising a second layer 320 in contact with at least part of said optical layer 310. In embodiments, the second layer 320 is water impermeable. Especially when the second layer covers substantially the entire light guide face, the second layer 320 comprises a UV radiation transmissive optical layer material 325. As indicated above, the optical layer may be configured over the entire light guide face, such as in FIG. 2b, but may in other embodiments also be available on only part of the light guide face, such as in FIG. 1a.

[0153] FIG. 2c schematically depicts variants wherein the light source 220 is configured external from the light guide 300 (left) and configured at least partly within the light guide 300. The light source 220 comprises a light emitting face 227. In the latter variant, the light emitting face 227 is configured within the light guide 300.

[0154] FIG. 2d schematically depicts an embodiment wherein the light guide 300 comprises a closed cavity 350 filled with a UV radiation transmissive liquid 305a. The light guide 300 may in this embodiment comprises a first material 305b, especially comprising silicone. The first material 305b may define the cavity 350. Here, in fact the optical layer 310 may define the cavity 350. The UV radiation transmissive liquid 305a may e.g. comprise demineralized water. Would such light guide element 1300 be used in the anti-biofouling system, the system may include a pump for moving, such as circulating, the liquid 305a. Such pump may be controlled by the herein mentioned control system.

[0155] FIGS. 2e and 2f very schematically depicts two variants of the light guide 300, with an elongated plate, such as a silicone plate (which may effectively be a coating on an object), or a channel like system. The diameter of the latter is defined as d1. The dimension of the diameter may be substantially the same as those defined herein for the height h3 of the light guide 300. With respect to the former variant, the light guide may have a height substantially smaller than a length or a width, such as at least 5 times smaller. In FIG. 2e, the length of the plate is indicated with reference l1 and the width is indicated with reference w1. Especially, w1/h35 and l1/h35.The top face, here the light guide face 301 (optical layer not indicated) may be used as outcoupling face. The face opposite of the light guide face 301 is indicated with reference 302, and is here the bottom face. This face may include a reflector. The edge(s) 303 may be used to couple light UV radiation into the light guide 300, assuming light sources external from the light guide 300. Edges not used, and/or in embodiments wherein the light sources have light emitting faces within the light guide 300, the edge(s) 303 may include reflective material. The length of the light guide 300 in FIG. 2f is perpendicular to the diameter and along an axis of elongation of the light guide. Hence, the light guide may in embodiments be a fiber.

[0156] FIG. 3 schematically depicts a further embodiment of the light guide element 1300 and the anti-biofouling system 200, wherein a plurality of variants are included, which may independently be used or which may be applied in combination.

[0157] For instance, in this schematically depicted embodiment the light source 220 are at least partially, here essentially entirely, embedded in the light guide 300. Hence, the light source(s) comprise a light emitting face 227, wherein the light emitting face 227 is configured within the light guide 300. Especially, the light emitting face is the die of a solid state light source (220).

[0158] Further, the light guide element 1300 comprises a first stack 30, comprising at least a layer, here by way of example two layers, wherein a first layer is the optical layer 310, and wherein a second layer 320 may e.g. be used as protective layer. The optical layer 310 is in contact with the first light guide surface 301. The optical layer material 315 and the second layer material, indicated with reference 325, is especially transmissive for UV radiation.

[0159] Alternatively or additionally, a second stack 130, comprising a least a layer, here by way of example a single layer, indicated as third layer 330, is available. The layer stack, here the third layer 130, is in contact with the second light guide surface 301. The third layer may comprise third layer material 335, which may in embodiments be identical to the optical layer material 315, but which in other embodiments may be essentially reflective, and/or which may in other embodiments be adhesive. For instance, the third layer 330 may be applied to arrange the light guide element 1300, more precisely the light guide layer 300 to an external surface 11 of an object.

[0160] The light guide 300 has a first light guide surface 301. When the first layer element 30 is available, the external surface of the light guide element 1300 is now effectively a surface of an external layer, herein indicated as 1301. Hence, reference 1301 indicates an outer layer of the light guide element 1300. The radiation exit window can be considered the layer (stack) between first light guide surface 301 and the outer layer 1301.

[0161] Hence, there may be a top layer or top foil and/or there may be a bottom layer or top foil. The former may be indicated more general as optical layer, or may be more general be comprised by a layer stack. The latter may be indicated more general as third layer, or may be more general comprise by a second layer stack.

[0162] The top foil/layer may especially be applied to protect the light carrier against mechanical damage. Further, it may be to be sufficiently transparent for UVC.

[0163] The optical layer, or the (first) layer stack may provide protection against chemical intrusion of unwanted molecules which may destroy the transparency of the light carrier.

[0164] The second layer may especially have a good resistance against tear. The second layer may have a lower refraction index compared to silicone to propagate the UVC light further through the silicone before it is emitted to the surface. This becomes more important if the silicone layer is very thin (2 mm) or if the silicone is highly transparent. This effect may also be obtained by adding a sol-gel layer, as embodiment of the optical layer, in between the light carrier and the top foil (see also above).

[0165] The bottom foil may especially be applied to reflect light back to the surface, into the light guide. The third layer may be a chemical interface enabling us to attach other layers to it at the bottom side, such as lead frames carrying wires and electronics.

[0166] Also the third layer may have a lower refraction index compared to silicone to propagate the UVC light further through the silicone before it is emitted to the surface. This effect may also be obtained by adding a sol-gel layer (see also above), as embodiment of the optical layer, in between the light carrier and the third layer.

[0167] Suitable materials for the second layer or for the third layer or for both the second layer and the third layer may be selected from the group of PET (Polyethylene terephthalate) and FEP (Fluorinated ethylene propylene). Other materials may also be possible, such as one or more of fluorinated ethylene, fluorinated propylene, fluorinated ethylene propylene, and fluorinated propylene acetate. Alternatively or additionally, suitable materials for the second layer or for the third layer or for both the second layer and the third layer may be selected from silicone materials (but different from the light guide material in embodiments wherein the light guide material would also comprise a silicone). The materials of the second layer and third layer may be different.

[0168] Hence, amongst others, the invention provides a light guide element 1300 as defined herein, comprising a second light guide face 302, wherein a distance h3 between the first light guide face 301 and the second light guide face 302 defines a thickness of the light guide 300. Especially, the light guide element 1300 may further comprise a third layer 330 in contact with at least part of the second light guide face 302. Alternatively or additionally, the light guide element 1300 as defined herein, may include the second layer 320, wherein the second layer 320 comprises in embodiments one or more of (a) a silicone and (b) a fluoropolymer. Especially, the second layer 320 is configured to impede ingress of UV-light absorbing organic molecules into the light guide 300. The optional third layer 330 may in embodiments have one or more functionalities selected from the group consisting of a reflective for UV radiation, b adhesive for adhering the light guide 300 to an object, c reinforcing the light guide element 1300, and d protective for the light guide 300.

[0169] The term plurality especially refers to two or more.

[0170] The term substantially herein, such as in substantially all light or in substantially consists, will be understood by the person skilled in the art. The term substantially may also include embodiments with entirely, completely, all, etc. Hence, in embodiments the adjective substantially may also be removed. Where applicable, the term substantially may also relate to 90% or higher, such as 95% or higher, especially 99% or higher, even more especially 99.5% or higher, including 100%. The term comprise includes also embodiments wherein the term comprises means consists of. The term and/or especially relates to one or more of the items mentioned before and after and/or. For instance, a phrase item 1 and/or item 2 and similar phrases may relate to one or more of item 1 and item 2. The term comprising may in an embodiment refer to consisting of but may in another embodiment also refer to containing at least the defined species and optionally one or more other species.

[0171] Furthermore, the terms first, second, third and the like in the description and in the claims, are used for distinguishing between similar elements and not necessarily for describing a sequential or chronological order. It is to be understood that the terms so used are interchangeable under appropriate circumstances and that the embodiments of the invention described herein are capable of operation in other sequences than described or illustrated herein.

[0172] The devices herein are amongst others described during operation. As will be clear to the person skilled in the art, the invention is not limited to methods of operation or devices in operation.

[0173] It should be noted that the above-mentioned embodiments illustrate rather than limit the invention, and that those skilled in the art will be able to design many alternative embodiments without departing from the scope of the appended claims. In the claims, any reference signs placed between parentheses shall not be construed as limiting the claim. Use of the verb to comprise and its conjugations does not exclude the presence of elements or steps other than those stated in a claim. The article a or an preceding an element does not exclude the presence of a plurality of such elements. The invention may be implemented by means of hardware comprising several distinct elements, and by means of a suitably programmed computer. In the device claim enumerating several means, several of these means may be embodied by one and the same item of hardware. The mere fact that certain measures are recited in mutually different dependent claims does not indicate that a combination of these measures cannot be used to advantage.

[0174] The invention further applies to a device comprising one or more of the characterizing features described in the description and/or shown in the attached drawings. The invention further pertains to a method or process comprising one or more of the characterizing features described in the description and/or shown in the attached drawings.

[0175] The various aspects discussed in this patent can be combined in order to provide additional advantages. Furthermore, some of the features can form the basis for one or more divisional applications.