SYNTHETIC STONE

Abstract

A synthetic stone for decorative purposes, countertops, flooring, and the like comprises, as a major component, magnesium compounds, and includes diamond or quartz sand. It is formed via a vibro-compression process that is conducted under vacuum and at ambient temperature. The synthetic stone slab is very hard, waterproof, mildew-proof, insect-proof, environmentally friendly, and low cost.

Claims

1. A composition for forming a synthetic stone slab, wherein the composition, as specified in weight percentages of the total composition, consists essentially of: an amount of magnesium oxide in a range of about 40 to about 50 percent; an amount of magnesium sulfate in a range of about 15 to about 25 percent; an amount of diamond or quartz sand in a range of about 8 to about 12 percent; an amount of fiber in a range of about 3 to about 5 percent; an amount of a hardening agent in a range of about 2 to about 4 weight percent; an amount of pigment in a range of about 4 to about 6 weight percent; an amount of a chemical additive in a range of about 2 to about 4 percent; and water for the balance of the composition.

2. The composition of claim 1 wherein the hardening agent is a solvent and isocyanate-free formulation.

3. The composition of claim 1 wherein the pigments are selected from the group consisting of chromic oxide chloride and ferric chloride.

4. The composition of claim 1 wherein the chemical additives are selected from the group consisting of citric acid and calcium carbonate.

5. A synthetic stone slab comprising, as major ingredients collectively representing more than 50 weight percent of the synthetic stone slab, magnesium compounds, excluding magnesium chloride, and, as a minor ingredient representing less than 15 weight percent of the synthetic stone slab, diamond sand or quartz sand.

6. The synthetic stone slab of claim 5, further comprising, as a minor ingredient representing less than 6 weight percent of the synthetic stone slab, fiber.

7. The synthetic stone slab of claim 5 excluding fiber.

8. A process for fabricating a synthetic stone slab, the process comprising: pouring a starting composition into a mold, the starting composition including magnesium compounds accounting for over 50 weight percent of the starting composition and diamond sand or quartz sand in an amount within a range of about 8 to about 12 weight percent of the starting composition; forming the synthetic stone slab by vibrating and compressing the starting composition, while under vacuum and at ambient temperature; and drying the formed synthetic stone slab for at least two days at ambient temperature.

9. The process of claim 8 wherein the starting composition is compressed at a pressure of about 40 to about 50 pounds per square inch.

Description

BRIEF DESCRIPTION OF THE DRAWING

[0023] The FIGURE depicts a block flow diagram of a process for manufacturing synthetic stone slabs in accordance with the illustrative embodiment of the present invention.

DETAILED DESCRIPTION

[0024] As used herein, the terms approximately, about, substantially, and similar terms are intended to have a broad meaning consistent with the common and accepted usage by those of ordinary skill in the art to which the subject matter of this disclosure pertains. It will be understood by those of skill in the art that these terms are intended to allow a description of certain features described and claimed without restricting the scope of these features to the precise numerical ranges provided. Accordingly, these terms should be interpreted as indicating that insubstantial or inconsequential modifications or alterations of the subject matter described and claimed are considered to be within the scope of the invention as recited in the appended claims. In the absence of any common and accepted usage, the above referenced terms mean +/15% of the stated FIGURE.

[0025] The FIGURE depicts method 100 for manufacturing the synthetic stone slabs described herein. The process can be automated to a greater or lesser degree, as desired. Although method 100 is similar to that of conventional stone-fabrication methods and uses much of the same equipment, it differs in that in accordance with the illustrative embodiment of the method, heat is not applied during the forming operation.

[0026] In operation 101, the ingredients for the synthetic stone slab are selected and weighed to ensure that the starting mixture contains the appropriate amounts of each ingredient. All ingredients are readily commercially available from a variety of suppliers. In some embodiments, the ingredients are fed to hopper and combined.

[0027] A synthetic stone slab in accordance with the invention is formulated from the following ingredients, which are present in the starting mixture in the following amounts: [0028] magnesium oxide: about 40 to about 50 weight percent; [0029] magnesium sulfate: about 15 to about 25 weight percent; [0030] diamond or quartz sand: about 8 to about 12 weight percent; [0031] fiber: about 3 to about 5 weight percent; [0032] hardening agent: 2 to about 4 weight percent; [0033] pigments: about 4 to about 6 weight percent; [0034] chemical additives: about 2 to about 4 percent; and [0035] water: balance of the composition.
In some other embodiments, fiber is not present in the starting mixture (and, of course, the synthesized slab). In such embodiments, the weight ranges for all other starting materials are proportionally increased.

[0036] Magnesium oxide, MgO, is physically and chemically stable at high temperatures. Magnesium sulfate, MgSO.sub.4(H.sub.2O).sub.x, where 0x7, is an inorganic salt. The diamond or quartz sand provides hardness and scratch resistance to the finished engineered stone. The fiber may be, without limitation, glass woven fabric, which is typically cut into strips (e.g., length in the range of about 20 to about 25 millimeters, etc.). Alternatively, fiber bundles (unwoven bundled strands of fiber) may suitably be used. In some embodiments, carbon fiber is used.

[0037] Any of a variety of conventional hardening agents, as typically used for the production of construction board to increase toughness and moisture resistance, may suitable be used in the starting formulation. For example, in some embodiments, the hardening agent is a solvent and isocyanate-free formulation based on cyclocarbonated soybean oil and diamines and functional silica or ZnO fillers.

[0038] The pigments are used to provide a desired color to the finished synthetic stone material. For example, in some embodiments, both chromic oxide chloride and ferric chloride are used, such as in a weight ratio (chromic oxide chloride:ferric chloride) in a range of about 1:0.2 to about 1:2. By using these pigments in different ratios, in the range specified, thousands of colors can be created.

[0039] Chemical additives (and water) are used to convert at least some portion of the starting magnesium compounds to other magnesium compounds in the synthetic stone slab. The chemical additives include, without limitation, citric acid and calcium carbonate, such as in a weight ratio (citric acid:calcium carbonate) in a range of about 1:0.2 to about 1:2.

[0040] Per operation S102, The ingredients are added to a low-speed mixer and thoroughly mixed (i.e., for about 10 to about 60 minutes) at a rate of about 10 to 60 rpm. The mixing step is used in conventional synthetic stone fabrication processes; those skilled in the art will know how to specify an appropriate mixer and use it to mix the ingredients. In some embodiments, only some, not all, of the ingredients are mixed at the same time. In other words, in some embodiments, there are separate mixing steps.

[0041] In operation S103, the mixture is poured into a (female) mold of appropriate size and shape for casting the synthetic stone slab. The mold, which can be PVC and typically has a rectangular shape, is filled with an appropriate amount of the starting mixture, as a function of the desired thickness of the final slab. The molds can made to any size, such as 4 ft8 ft, etc.

[0042] In forming operation S104, the mixture is exposed to vibration, compaction force, and vacuum. These operations are performed by a vibro-compaction machine, into which the mold is introduced. The vibro-compaction machine is similar to those used for conventional engineered-stone fabrication processes. A vibro-compaction machine is an apparatus that can simultaneously apply sufficient vibration, pressure, and vacuum to the synthetic stone mixture to force the diamond/quartz sand, fiber, etc., into a tightly packed relationship to ensure that there are substantially no voids in the mixture. In some embodiments, the vibro-compaction machine applies about 100 to about 120 tons of pressure to the mixture in the mold (i.e., about 40-50 psi of mold surface). The operation is performed under vacuum to ensure that no air remains in the mixture, thereby minimizing the porosity of the final product. In some embodiments, the vacuum is about 0.98 kPa. Although the compression, vibration, and vacuum operations are conventional for fabricating engineered stone, in accordance with the present invention and unlike the prior art, the mixture is not heated during forming operation S104.

[0043] After forming, the material, while still in the mold, is moved to a storage rack for drying in operation S105. In some embodiments, the mold is dried for 2 to 4 days at room temperature (about 25 C. to as high as about 39 C.).

[0044] In operation S106, the hardened material is removed from the mold. In operation S107, the material is trimmed, cut to size, and polished using conventional stone cutting and polishing equipment.

[0045] It is to be understood, and will be appreciated by those skilled in the art, that some of the operations of the method can be performed in an order different than implied by the discussion above.

EXAMPLES

[0046] Engineered stone in accordance with the present teachings was fabricated via method 100. Compositions of the starting material are weight percent.

TABLE-US-00001 Starting Composition I II III IV* Ingredient Magnesium Oxide 40 50 45 41.2 Magnesium Sulfate 25 15 20 20.6 Fiber 3 5 4 Hardening agent.sup.A 4 2 4 4.1 Chemical Additives.sup.B 2 4 3 4.1 Pigments.sup.C 6 4 5 6.2 Diamond/Quartz Sand 8 12 10 12.4 Water 12 8 9 11.4 Conditions Molding Pressure, psi 110 110 110 Vacuum level, kPa 0.98 0.98 0.98 Mixing time, minutes 60 30 45 Drying time, days 4 2 3 Hardness, Mohs 6 6 6 *Prophetic example. .sup.AFor Compositions I, II, and III, the hardening agent comprised cyclocarbonated soybean oil, diamines, and functional silica or ZnO fillers. .sup.BFor Compositions I, II, and III, the chemical additives were citric acid and calcium carbonate, in a ratio within the weight range of about 1:0.2 to 1:2. .sup.CFor Compositions I, II, and III, the pigments were chromic oxide chloride and ferric chloride, in a ratio within the weight range of about 1:0.2 to 1:2.

[0047] It is to be understood that the disclosure describes a few embodiments and that many variations of the invention can easily be devised by those skilled in the art after reading this disclosure and that the scope of the present invention is to be determined by the following claims.