ELASTOMERIC LAYER FABRICATION FOR LIGHT EMITTING DIODES
20190333903 ยท 2019-10-31
Inventors
Cpc classification
G03F7/039
PHYSICS
H01L2924/00012
ELECTRICITY
H01L2924/00014
ELECTRICITY
H01L2224/81203
ELECTRICITY
H01L24/75
ELECTRICITY
H01L2224/97
ELECTRICITY
H01L24/97
ELECTRICITY
H01L33/0095
ELECTRICITY
H01S5/343
ELECTRICITY
H01L2224/7565
ELECTRICITY
H01L21/67144
ELECTRICITY
H01L33/06
ELECTRICITY
H01L2924/00014
ELECTRICITY
G03F7/038
PHYSICS
H01L25/167
ELECTRICITY
H01L2224/7565
ELECTRICITY
H01L2924/00012
ELECTRICITY
H01S5/0201
ELECTRICITY
H01L2221/68368
ELECTRICITY
H01S5/02325
ELECTRICITY
G03F7/162
PHYSICS
H01L33/20
ELECTRICITY
H01L2224/97
ELECTRICITY
H01L33/30
ELECTRICITY
H01L2224/81203
ELECTRICITY
International classification
H01L25/16
ELECTRICITY
H01L33/00
ELECTRICITY
G03F7/038
PHYSICS
H01L21/67
ELECTRICITY
G03F7/039
PHYSICS
H01S5/02
ELECTRICITY
H01L25/075
ELECTRICITY
Abstract
An elastomeric interface layer (elayer) is formed over multiple light emitting diode (LED) dies by depositing photoresist materials across multiple LED dies, and using the LED dies as a photolithography mask to facilitate formation of the elayer on each LED die. The elayer facilitates adhesive attachment of each LED die with a pick and place head (PPH), allowing the LED dies to be picked up and placed onto a display substrate including control circuits for sub-pixels of an electronic display. In some embodiments, the LED dies are micro-LED (LED) dies.
Claims
1. A method, comprising: depositing a removable material between light emitting diode (LED) dies on a carrier substrate; depositing an elastomeric material on at least some of the LED dies, the removable material providing a mold for the elastomeric material; and removing the removable material after depositing the elastomeric material, the elastomeric material forming elastomeric interface layers on the at least some of the LED dies.
2. The method of claim 1, wherein the removable material includes a photoresist material.
3. The method of claim 3, further comprising exposing the removable material to light to render the removable material insoluble, and wherein removing the removable material includes using a photoresist stripping material.
4. The method of claim 3, wherein exposing the removable material to light comprises applying light through the carrier substrate toward the removable material.
5. The method of claim 1, further comprising subsequent to removing the removable material, transferring at least one LED die from the substrate to another substrate.
6. The method of claim 5, further comprising subsequent to transferring the at least one LED die from the substrate to the other substrate, bonding the at least one LED die to the other substrate.
7. The method of claim 1, further comprising curing the elastomeric material prior to removing the removable material.
8. The method of claim 1, wherein removing the removable material includes: exposing the removable material to light to render the removable material soluble; and dissolving the removable material with a solvent.
9. A method, comprising: depositing a removable material at side surfaces of a light emitting diode (LED) die on a carrier substrate; depositing an elastomeric material on the LED die, the removable material providing a mold for the elastomeric material; and removing the removable material after depositing the elastomeric material, the elastomeric material forming an elastomeric interface layer on the LED die.
10. The method of claim 9, wherein the removable material includes a photoresist material.
11. The method of claim 10, further comprising exposing the removable material to light to render the removable material insoluble, and wherein removing the removable material includes using a photoresist stripping material.
12. The method of claim 11, wherein exposing the removable material to light comprises applying light through the carrier substrate toward the removable material.
13. The method of claim 9, further comprising subsequent to removing the removable material, transferring the LED die from the substrate to another substrate.
14. The method of claim 13, further comprising subsequent to transferring the LED die from the substrate to the other substrate, bonding the LED die to the other substrate.
15. The method of claim 9, further comprising curing the elastomeric material prior to removing the removable material.
16. The method of claim 9, wherein removing the removable material includes: exposing the removable material to light to render the removable material soluble; and dissolving the removable material with a solvent.
17. An electronic display panel fabricated by a method, comprising: depositing a removable material between light emitting diode (LED) dies on a carrier substrate; depositing an elastomeric material on at least some of the LED dies, the removable material providing a mold for the elastomeric material; and removing the removable material after depositing the elastomeric material, the elastomeric material forming elastomeric interface layers on the at least some of the LED dies.
18. The electronic display panel of claim 17, wherein the method further comprises: subsequent to removing the removable material, transferring at least one LED die from the substrate to another substrate; and subsequent to transferring the at least one LED die from the substrate to the other substrate, bonding the LED die to the other substrate.
19. The electronic display panel of claim 17, wherein: the removable material is photoresist material; the method further includes, prior to removing the removable material, exposing at least a portion of the removable material to light to render the at least a portion of the removable material insoluble; and removing the removable material includes using a photoresist stripping material.
19. The electronic display panel of claim 19, wherein exposing the removable material to light comprises applying light through the carrier substrate toward the removable material.
20. The method of claim 15, wherein the LED dies are micro-LEDs and include one of Gallium nitride (GaN), gallium arsenide (GaAs), or gallium phosphide (GaP).
Description
BRIEF DESCRIPTION OF DRAWINGS
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[0027] The figures depict various embodiments of the present disclosure for purposes of illustration only. One skilled in the art will readily recognize from the following discussion that alternative embodiments of the structures and methods illustrated herein may be employed without departing from the principles of the disclosure described herein.
DETAILED DESCRIPTION
[0028] In the following description of embodiments, numerous specific details are set forth in order to provide more thorough understanding. However, note that the embodiments may be practiced without one or more of these specific details. In other instances, well-known features have not been described in detail to avoid unnecessarily complicating the description.
[0029] Embodiments are described herein with reference to the figures, where like reference numbers indicate identical or functionally similar elements. Also in the figures, the left most digits of each reference number corresponds to the figure in which the reference number is first used.
[0030] Embodiments relate to depositing an elastomeric interface layer (elayer) over multiple light emitting diode (LED) dies by using photoresist materials rather than physical molds or processes that may damage the elayer or the LED dies. The deposited elayer allows each LED to be picked up by a pick-up head (or pick and place head (PPH)), and placed onto a display substrate including control circuits for sub-pixels of an electronic display. In some embodiments, the LED dies are micro-LED (mLED) dies.
[0031]
[0032] The elayer 110 is formed on the light emitting side 112 of each LED die 102. The elayer 110 is a conformable layer that allows each of the LED dies 102 to be attached to and picked up by a pick and place head (PPH) (e.g., as discussed in greater detail with reference to
[0033] The side of each LED die 102 facing the carrier substrate 104 includes contact pads 114. Each of the LED dies 102 emit light out of the light emitting side 112 if an electric potential is applied between electrical contact pads 114. The electrical contact pads 114 connect with control circuits in a display substrate (e.g., as shown in
[0034] As discussed in greater detail below in connection with
[0035] The carrier substrate 104 has a flat surface mounted with LED dies 102 that supports the LED dies 102 during the process of forming the elayer 110 over each LED die 102. The carrier substrate 104 is transparent to, at least some, wavelengths of light. For example, the carrier substrate 104 may include a glass or sapphire substrate that is transparent to light that changes photoresist material state and is absorbed by the LED dies 102. This allows light to be applied through the carrier substrate 104 to the bottom sides of the LED dies 102 and the regions between the LED dies 102, resulting in photoresist material over LED dies 102 to be blocked from the light and exposing photoresist material between the LED dies 102 to the light. The carrier substrate 104 may have any number of LED dies 102 attached, such as one or more arrays of LED dies. The carrier substrate 104 may have a hard flat surface, rigid enough to support the LED dies 102 as the carrier substrate 104 is moved. In some embodiments, the LED dies 102 are released from the carrier substrate 104 by removing the adhesive 108 (e.g., with a solvent, wet or dry etching, etc.), or weakening the adhesive 108. In other embodiments, the adhesive 108 is weak enough that the LED dies 102 may be removed with force (e.g., by a PPH 1302) without damaging the LED dies 102.
[0036]
[0037] A negative photoresist material is deposited 402 in the regions between the LED dies 102 on the carrier substrate 104 and over the LED dies 102. With reference to
[0038] The carrier substrate 104 may be an intermediate substrate to facilitate LED die 102 transfer between a native substrate and the display substrate 1402. The space between the LED dies 102 may be a result of the singulation process (in which a single group of LED dies 102 are separated into individual LED dies 102) or another process that creates the open regions between the LED dies 102.
[0039] For example, the open regions between the LED dies 102 may be formed by the use of an expanding carrier film. The carrier film is attached to a first side of the LED dies 102 on a native substrate. The LED dies 102 may be singulated before or after the carrier film is attached to the LED dies 102. After the LED dies 102 are detached from the native substrate, the LED dies 102 are separated by expanding the carrier film to widen the open regions between the LED dies 102. The carrier substrate 104 is applied to a second side of the LED dies 102. The LED dies 102 are attached to the adhesive 108 layer of the carrier substrate 104 with the open regions being defined between the LED dies 102. The carrier film is separated from the first side of the LED dies 102 to expose the first die of the LED dies 102 for formation of the elayer 110.
[0040] After depositing the negative photoresist material 402, light is applied 204 through the carrier substrate 104 towards the LED dies 102 and the deposited negative photoresist material 402. With reference to
[0041] Light 502 incident on the LED dies is absorbed 206 to retain soluble first portions of the negative photoresist material 402 on the LED dies 102. With reference to
[0042] Portions of the negative photoresist material 402 between the LED dies 102 are exposed 208 to light 502 to render the second portions of the negative photoresist material 402 between the LED dies 102 insoluble. With reference to
[0043] After applying the light 502, first portions of the negative photoresist material 402 over the LED dies 102 are removed 210. With reference to
[0044] Elastomeric material 802 is deposited 212 on each LED die 102 and between the second portions of insoluble photoresist material 604, after removing the first portions of soluble photoresist material 602. With reference to
[0045] After depositing the elastomeric material 802, the second portions of the photoresist material (the insoluble photoresist material 604) are removed 214, resulting in the elastomeric material 802 forming an elayer 110 on each of LED dies 102. With reference to
[0046]
[0047] Positive photoresist material is deposited 902 in the regions between the LED dies 102 on the carrier substrate 104 and over the LED dies 102. The LED dies 102 on the carrier substrate 104 may be evenly spaced apart and mounted to the substrate 106 by a layer of adhesive 108 (e.g., as shown in
[0048] The positive photoresist material 1002 eventually forms an elayer 110 over the LED dies 102. In some embodiments, the positive photoresist material 1002 includes materials to increase adhesion to the pick-up surfaces 1304. For example, the positive photoresist material 1002 is mixed with a functional group material which is able to bind (e.g., covalently) to the non-conformable pick-up surface 1304. In some embodiments, the elastomeric material is cured in connection with baking the positive photoresist material 1002. In other embodiments, a separate curing process is used to cure the elastomeric material.
[0049] After depositing the positive photoresist material 1002, light is applied 904 through the carrier substrate 104 towards the LED dies 102 and the positive photoresist material 1002. With reference to
[0050] Portions of the light 502 incident on the LED dies 102 are absorbed 906 to retain insoluble first portions of the positive photoresist material 1002 on the LED dies 102. With reference to
[0051] Second portions of the photoresist material between the LED dies 102 are exposed 908 to another portion of light 502 to render the second portions soluble. The light 502 renders the portions of the positive photoresist material 1002 soluble, forming the soluble photoresist material 1204 between the LED dies 102.
[0052] The second portions of the photoresist material (the soluble photoresist material 1204) are removed 910, to form an elayer 110 on each of the LED dies 102, from the first portions of the insoluble photoresist material 1202. The soluble photoresist material 1204 can be removed with a solvent. The solvent may be a photoresist developer that dissolves soluble photoresist material 1204, but is benign to insoluble photoresist material 1202. The remaining insoluble photoresist material 1202 forms the elayers 110 on the LED dies 102. The elayer 110 is conformable layer that allows each of the LED dies 102 to be attached to and picked up by a pick-up surface 1304 of a pick and place head (PPH) 1302. In some embodiments, the insoluble photoresist material 1202is cured after removal of the soluble photoresist material 1204 to form the elayers 110.
[0053]
[0054] The micromanipulator 1306 is connected to the PPH 1302 and controls movement of the PPH 1302. The micromanipulator 1306 aligns the PPH 1302 with the carrier substrate 104 to allow the PPH 1302 to pick up one or more LED dies 102. In some embodiments, the micromanipulator 1306 may be a multiple degree of freedom micromanipulator, such as a four degree of freedom micromanipulator configured to move the PPH 1302 up and down, left and right, forward and back, or rotate the PPH 1302 (e.g., along the rotational axis 1308). In some embodiments, the system 1300 includes multiple micromanipulators 1306 and/or PPHs 1302 to perform pick and place tasks in parallel to increase throughput of the system.
[0055] The PPH 1302 has a polygon shaped cross section. The edges of the polygon shape cross section define multiple pick-up surfaces 1304 of the PPH 1302. The elayer 110 of each LED dies 102 are configured to mount to the pick-up surfaces 1304 (e.g., due to adhesion forces) to facilitate transfer of the LED dies 102 from the carrier substrate 104 to a display substrate 1402. The PPH 1302 may be rotated along the rotational axis 1308 to pick up arrays of LED dies 102 at one or more pick-up surfaces 1304. Although the PPH 1302 has an octagonal cross section and eight pick-up surfaces 1304, a PPH 1302 may have different shaped cross sections (e.g., triangular, square, hexagon, etc.) and different numbers of pick-up surfaces in various embodiments. Although the pick and place tool discussed herein is a PPH 1302, other types of pick-up heads using adhesive attachment with elayers 110 may be used.
[0056] The pick-up surfaces 1304 may be non-conformable pick-up heads that allow the LED dies 102 with elayers 110 to attach to the PPH 1302. For example, the pick-up surfaces 1304 may be glass or fused silica. The pick-up surfaces 1304 interface with the elayer 110 of the LED dies 102 using adhesion forces, such as Van der Waals. The adhesive 108 may be removed from the carrier substrate 104 before the pick-up surfaces 1304 attach to the elayer 110 of each LED die 102. Although the elayers 110 discussed herein are particularly adapted for non-conformable pick-up heads, in some embodiments, the pick-up surfaces 1304 are conformable, such as with an elastomeric coating.
[0057] Subsequent to the PPH 1302 picking up the one or more first LED dies 102a with the first pick-up surface 1304a, the PPH 1302 is rotated about axis 1308 to pick up one or more second LED dies 102b with a second pick-up surface 1304b of the PPH 1302. The second pick-up surface 1304b may be adjacent to the first pick-up surface 1304a, as shown in
[0058]
[0059] After the PPH 1302 has been populated with LED dies 102, the PPH 1302 is moved away from the carrier substrate 104 and aligned with the display substrate 1402. For example, the PPH 1302 may be lifted away from the carrier substrate 104 by the micromanipulator 1306 for subsequent placement of the LED dies 102 on the display substrate 1402. The micromanipulator 1306 places the LED dies 102 on the display substrate 1402 by aligning the PPH 1302 with the display substrate 1402 and rolling the PPH 1302 across the display substrate 1402. The display substrate 1402 may be part of an electronic display with the LED dies 102 placed at sub-pixel locations to connect with the control circuits in the display substrate 1402 that drive the LED dies 102. For example, the display substrate 1402 may be a printed circuit board including gate lines and data lines for a control circuit at each sub-pixel that drive the LED dies 102 according to signals on the gate and data lines. After placement, the LED dies 102 may be bonded to the display substrate 1402, such as using thermocompression (TC) bonding.
[0060]
[0061] If the semiconductor structure of the mLED 1500 is grown on a growth substrate, such as a non-transparent substrate, the growth substrate may be removed to reveal the light emitting side 112 as shown in
[0062] The mesa 1512 may include various shapes, such as a parabolic shape with a truncated top, to form a reflective enclosure for light 1516 generated within the mLED 1500. In other embodiments, the mesa 1512 may include a cylindrical shape with a truncated top, or a conic shape with a truncated top. The arrows show how the light 1516 emitted from the MQW 1504 is reflected off the p-contact 1508 and internal walls of the mesa 1512 toward the light emitting side 112 at an angle sufficient for the light to escape the mLED device 1500 (i.e., within a critical angle of total internal reflection). The p-contact 1508 and the n-contact 1510 connect the mLED 1500, such as to the display substrate including a control circuit for the mLED 1500. The n-contact 1510 is formed at the base 1514 on a side opposite the light emitting side 112.
[0063] The mLED 1500 may include an active light emitting area defined by the MQW 1504. The mLED 1500 directs the light 1516 from the MQW 1504 and increases the brightness level of the light output. In particular, the mesa 1512 and p-contact 1508 cause reflection of the light 1516 from the MWQ 1504 to form a collimated or quasi-collimated light beam emerging from the light emitting side 112.
[0064] The foregoing description of the embodiments has been presented for the purpose of illustration; it is not intended to be exhaustive or to limit the patent rights to the precise forms disclosed. For example, the deposited layer may be made of other materials, and the same method can be applied to micro-electric devices other than LEDs. Persons skilled in the relevant art can appreciate that many modifications and variations are possible in light of the above disclosure.
[0065] The language used in the specification has been principally selected for readability and instructional purposes, and it may not have been selected to delineate or circumscribe the inventive subject matter. It is therefore intended that the scope of the patent rights be limited not by this detailed description, but rather by any claims that issue on an application based hereon. Accordingly, the disclosure of the embodiments is intended to be illustrative, but not limiting, of the scope of the patent rights, which is set forth in the following claims.