One-piece part including a magnetocaloric material including an alloy including iron and silicon and at least one lanthanide, and method for manufacturing said one-piece part
10451319 ยท 2019-10-22
Assignee
Inventors
Cpc classification
Y10T428/12389
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F25B2500/09
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B29K2995/0012
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/2457
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B29C48/12
PERFORMING OPERATIONS; TRANSPORTING
F25B21/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28F3/048
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02B30/00
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F25B2500/01
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25B2321/002
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F25B21/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B29C48/12
PERFORMING OPERATIONS; TRANSPORTING
B29C48/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A one-piece part based on magnetocaloric material comprising an alloy comprising iron and silicon and a lanthanide, comprises a base in a first plane defined by a first and second direction and N unitary blades secured to the base; the blades having a first and second dimension in the first and second direction, respectively, and a third dimension in a third direction at right angles to the first and second dimensions; an ith blade being separated from an (i+1)th blade by an ith distance; the ratio between the second dimension and first dimension being at least 10; the ratio between the third dimension and first dimension being at least 6; the first dimension being the same order of magnitude as the distance separating an ith blade from an (i+1)th blade. The magnetocaloric material can be rare-earth alloy or a composite material based on polymer binder and rare-earth alloy.
Claims
1. A one-piece part comprising at least one magnetocaloric material comprising an alloy including iron, silicon, at least one lanthanide, and an organic binder, the one-piece part being configured to transfer heat when subjected to a magnetic field, the one-piece part comprising: a base situated in a first plane defined by a first direction and a second direction; and a set of blades secured to said base, wherein: said set of blades have a first dimension in the first direction, a second dimension in the second direction, and a third dimension in a third direction at right angles to the first and second dimensions, an ith blade of said set of blades is separated from an (i+1)th blade of said set of blades by an ith distance (d.sub.i), a ratio between the second dimension and the first dimension is greater than or equal to 10, a ratio between the third dimension and the first dimension being greater than or equal to 6, and the first dimension being of the same order of magnitude as said ith distance (d.sub.i).
2. The one-piece part of claim 1, wherein the first dimension is between approximately 0.1 mm and 0.8 mm.
3. The one-piece part of claim 1, wherein the second dimension is between approximately 10 mm and 100 mm.
4. The one-piece part of claim 1, wherein the third dimension is between approximately 6 mm and 25 mm.
5. The one-piece part of claim 1, wherein the ith distance (d.sub.i) is between approximately 0.1 mm and 1 mm.
6. The one-piece part of claim 1, wherein the set of blades comprise convex upper surfaces.
7. The one-piece part of claim 1, wherein said base comprises hollowed-out surfaces between the ith blade and the (i+1)th blade.
8. The one-piece part of claim 7, wherein said base comprises concave surfaces between the ith blade and the (i+1)th blade.
9. The one-piece part of claim 1, wherein the set of blades comprise at least one blade of a third dimension different from that of other blades of the set of blades constituting a marking and/or positioning element.
10. The one-piece part of claim 1, wherein said base comprises at least one surface between the ith blade and the (i+1)th blade hollowed out differently from other hollowed out surfaces constituting a marking and/or positioning element.
11. The one-piece part of claim 1, wherein at least one subset of the set of blades has at least one protruberance extending along the second direction, said protruberance being situated between the base and an end of the blade opposite said base to gauge a space between two adjacent blades.
12. The one-piece part of claim 1, wherein a ratio between a dimension of the base in the third direction and a dimension of the base in the second direction is between approximately ? and 1/30, a ratio between the dimension of the base in the third direction and the third dimension of the set of blades is of the order of 1/20, and the first dimension of the set of blades is substantially equal to the dimension of the base in the third direction.
13. The one-piece part of claim 1, wherein the base is made of a base material, the set of blades are made of the at least one magnetocaloric material, the base material and the at least one magnetocaloric material being different.
14. The one-piece part of claim 1, further comprising at least two series of the set of blades made of at least two different magnetocaloric materials.
15. The one-piece part of claim 1, wherein at least one subset of the set of blades comprises regions distributed in the second direction comprising different magnetocaloric materials.
16. The one-piece part of claim 1, wherein at least one subset of the set of blades comprises regions distributed in the third direction comprising different magnetocaloric materials.
17. The one-piece part of claim 1, wherein blades of the set of blades have integrated channels at a base level.
18. The one-piece part of claim 1, wherein the base comprises at least one channel in said first plane configured to receive a flow of a fluid.
19. The one-piece part of claim 1, wherein the base comprises peripheral parts.
20. The one-piece part of claim 1, wherein at least one of a first blade and a last blade of the set of blades situated at a periphery of the base is offset relative to an end of said base in said first plane.
21. The one-piece part of claim 1, wherein the one-piece part has a configuration at least partially folded along said second direction.
22. A one-piece part comprising at least one magnetocaloric material comprising an alloy including iron and silicon and at least one lanthanide, the one-piece part being configured to transfer heat when subjected to a magnetic field, the one-piece part comprising: a base situated in a first plane defined by a first direction and a second direction; and a set of blades secured to said base, wherein: said set of blades have a first dimension in the first direction, a second dimension in the second direction, and a third dimension in a third direction at right angles to the first and second dimensions, an ith blade of said set of blades is separated from an (i+1)th blade of said set of blades by an ith distance (d.sub.i), a ratio between the second dimension and the first dimension is greater than or equal to 10, a ratio between the third dimension and the first dimension being greater than or equal to 6, and the first dimension being of the same order of magnitude as said ith distance (d.sub.i), and wherein the magnetocaloric material includes at least one powder of iron, silicone, and lanthanum, and an organic binder, a ratio of the organic binder by volume of the powder being between 50% and 90%.
23. The one-piece part of claim 22, wherein the powder comprises (LaCe)(FeCoMn)H, and the organic binder comprises polypropylene, polycarbonate, or polyethylene.
24. A complex part comprising two one-piece parts as claimed in claim 1, said two parts (P.sub.1,P.sub.2) being embedded head-to-tail, making it possible to reduce the free space between blades of the set of blades.
25. The complex part comprising two one-piece parts as claimed in claim 24, in which: a first part comprises a subset of the set of blades comprising at least one blade of third dimension greater than that of other blades the set of blades; a second part comprises a base comprising as many surfaces hollowed out to greater depths as there are blades of third dimension greater than that of the other blades, and said at least one blade of third dimension greater than the first part being of a form complementing one of the surfaces hollowed out to a greater depth of the second part.
26. A method for manufacturing a one-piece part as claimed in claim 1, further comprising the following steps: the continuous introduction into at least one extruder body (Ex) comprising at least one heating sheath (Fi), at least one powder of magnetocaloric material or a mixture of at least one magnetocaloric powder with an organic binder; the mixing, the homogenization and the melting of said powder of magnetocaloric material and, if appropriate, of the organic binder, by at least one extrusion screw (Vi) situated in the extruder body or bodies; the shaping of said mixture comprising said magnetocaloric material through at least one extrusion die (fill), equipped with at least one imprint, making it possible to shape a one-piece part according to claim 1; and said at least one die defining the structure of said one-piece part.
27. The method for manufacturing a one-piece part as claimed in claim 26, further comprising a step of gradual cooling in the space, at the output of said at least one die, using dedicated means.
28. The method for manufacturing a one-piece part as claimed in claim 27, wherein the dedicated means comprise a die, comprising at least one section equipped with at least one channel (Ca) in which a cooling/tempering fluid can circulate.
29. The method for manufacturing a one-piece part as claimed in claim 28, the die comprising a plurality of sections (T.sub.1, T.sub.2, T.sub.3, T.sub.4), at least two sections being separated by a thermal insulation plate (Is).
30. The method for manufacturing a one-piece part as claimed in claim 26, the extruder body or bodies each comprising two co-rotating screws.
31. The method for manufacturing a one-piece part as claimed in claim 26, further comprising: the continuous production of a set consisting of strips of magnetocaloric material, secured to a base; and an operation of cutting said set so as to define individual one-piece parts.
32. The method for manufacturing a one-piece part as claimed in claim 26, further comprising the introduction of different materials through different feed means distributed along the extruder body or bodies.
33. The method for manufacturing a one-piece part as claimed in claim 32, further comprising the introduction through a feed means of an organic binder so as to produce a composite material comprising at least one powder of magnetocaloric material.
34. The method for manufacturing a one-piece part as claimed in claim 32, in which: said one-piece part being made up spatially of different materials; the method comprising the sequenced introduction of the different magnetocaloric materials so as to produce a set of continuous strips exhibiting sequences of different magnetocaloric materials, secured to a base; and the cutting of unitary one-piece parts from said set of strips.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The invention will be better understood and other advantages will become apparent on reading the following description given as a nonlimiting example, and through the attached figures in which:
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DETAILED DESCRIPTION
(18) Generally, the one-piece part of the present invention comprises a structure incorporated in magnetocaloric material(s) in which holed regions are provided in a gauged manner and exhibiting geometrical parameters optimized for the passage of a heat transfer fluid.
(19) According to a variant of the invention, the one-piece part can comprise a comb-shaped structure. A first example of this particularly advantageous variant is illustrated in
(20) More specifically, the one-piece part comprises, in this configuration, a comb-shaped structure with a base E and a set of blades L.sub.a,1, . . . , L.sub.a,i, . . . , L.sub.a,N secured to said base. The dimensions of these blades are, according to the directions represented Dx, Dy and Dz respectively: D.sub.Lai,x, D.sub.Lai,y and D.sub.Lai,z.
(21) Two blades L.sub.a,i and L.sub.a,i+i are, moreover, spaced apart by a distance d.sub.i intended to correspond to a fluid blade circulating between said blades, except in a case of assembly where the distance will not be the same (two fluid blades and one material blade).
(22) The one-piece part can be made of a single magnetocaloric material. It can be a composite material based on powder from the well-known family LaFeSi, for example (LaCe)(FeCoMn)Si, in which, in variable proportions as chosen by the manufacturer, Ce is introduced in place of La and Co and/or Mn in place of Fe, with a composition and metallurgical structure that remain compatible with the methods implemented described below. The composite material comprising an organic binder, for example a polymer that can be polypropylene, and in which is dispersed a powder of magnetocaloric material that can be, for example, (LaCe)(FeCoMn)SiH in which H is introduced by insertion into the material thus comprising hydrogen atoms, as is conventionally known from the prior art. Typically, the powder charge ratio by volume can be of the order of 50% to 90%.
(23) For the targeted magnetic cold technology applications, in which the aim is to optimize the interaction between a heat transfer fluid that can be water-based and the part made of magnetocaloric material subjected to magnetic alternations, the aim is to control and optimize the following main characteristics involved in the heat exchange processes.
(24) The main determining characteristics are listed according to the following criteria:
(25) criterion 1: the heat exchange coefficient: h (W/m.sup.2K);
(26) criterion 2: the thickness of the blade of heat transfer liquid;
(27) criterion 3: the height of the blade of heat transfer liquid;
(28) criterion 4: the thickness of the blade of magnetocaloric material(s);
(29) criterion 5: the height of the blade of magnetocaloric material(s);
(30) criterion 6: the length of the blade of magnetocaloric material(s);
(31) criterion 7: the number of blades of magnetocaloric material(s).
(32) The criteria 2 to 7 thus define the geometry of the block of magnetocaloric material. These criteria combined with criterion 1 make it possible to define the heat exchange capacity of the block of magnetocaloric material.
(33) This is reflected in a magnetocaloric material block geometry including thin grooves in which the heat transfer liquid circulates. These thin blades of material thus delimit, between them, blades of liquid.
(34) If the blades of material are too thick, the liquid will not be able to extract the energy originating from the magnetocaloric effect of the blade sufficiently rapidly before the next cycle (the thermal conductivity of the material limits the heat transfer flux).
(35) If the blade of water is not high enough, the exchange surface area existing on the two faces of the blades of magnetocaloric material will not be sufficient to extract sufficient power as a function of the coefficient h.
(36) The heat exchange coefficient h is greatly dependent on the thickness of the blade of water. It increases when the thickness of the blade of water decreases.
(37) This is why, typically, the dimensions of the blades and of the spaces between blades can advantageously be as follows: 0.1 mm?D.sub.Lai,x?0.8 mm; 10 mm?D.sub.Lai,y?100 mm; 5 mm?D.sub.Lai,z?25 mm and preferably D.sub.Lai,z can be of the order of 12 mm; 0.1?d.sub.i?1 mm and preferably d.sub.i: can be of the order of 0.2 mm.
(38) According to the example illustrated in
(39) Out of all the blades secured to the base, it may be advantageous to produce a differentiating element that makes it possible, during mass production, to recognize, for example, one one-piece part from another, in terms of thermal properties in conjunction with the material or materials of which they are made. For this, a base surface can be provided between two consecutive blades that is more concave than the others or a blade height greater than that of the other blades can be provided. The concave surface between the blades L.sub.a,1 and L.sub.a,2 is more hollowed out.
(40) According to a second example of this variant of the invention, illustrated in
(41) According to a third example of this variant of the invention, illustrated in
(42) According to a fourth example which is not illustrated of this variant of the invention, said integrated channels CLi.sub.a,i in said blades L.sub.a,i can comprise a magnetocaloric or non-magnetocaloric material exhibiting a magnetic permeability greater than that of the material forming said blades L.sub.a,i, integration of such a material makes it possible to increase the intensity of the magnetic induction when the one-piece part is subjected to a magnetic field.
(43) According to a fifth example of this variant of the invention, illustrated in
(44) According to another variant of the invention that is not illustrated, the one-piece part can also comprise a solid magnetocaloric material comprising holed regions intended for the flow of a heat transfer fluid, said regions being holed in a second direction Dy, at right angles to a first direction Dx and to a third dimension Dz.
(45) The dimensions of these holed regions in the direction Dx, and dR.sub.ai,z in the direction Dz are of an order of magnitude less than the dimension dR.sub.ai,y in the second dimension.
(46) The distances between holed regions can typically be of the order of a few tens of millimeters.
(47) In this type of configuration, the holed regions can be organized in a structure of honeycomb type with hexagonal holed regions.
(48) Advantageously, thermal generators can incorporate complex parts in which two one-piece parts of the invention, P.sub.1 and P.sub.2, are embedded head-to-tail as illustrated in
(49) In this case, it is advantageous to provide at least one positioning element, which can also be an element for marking blades made of materials of different characteristics from a first block, said positioning element consisting of at least one blade of third dimension greater than that/those of the other blades positioned facing a surface of the second block hollowed out in the base, said hollowing out being dimensioned to complement the end of the at least one blade of said first block. A configuration of this type is illustrated in the figure by the second blade starting from the right and the second hollow starting from the left of the bottom block of
(50) According to a variant of the invention, illustrated in
(51) According to another variant of the invention, illustrated in
(52) According to the present invention, it is proposed to use an extrusion method to produce the geometry of the one-piece part, this method making it possible to achieve the dimensions required with an excellent reproducibility and a particularly advantageous production cost.
(53) In effect, producing parts having very small dimensions between the blades of magnetocaloric material corresponding to very thin blades of fluid currently entails firstly producing a solid block of magnetocaloric material and then secondly machining this block. The block can be produced by powder sintering at approximately 1200? C.; producing the channels by spark erosion can be tried, but the sintering generates mechanical stresses and tensions in the blocks. This can lead to the breaking of the blocks or of the blades already produced. Moreover, the spark erosion wire diameter making it possible to achieve dimensions smaller than a few tens of millimeters becomes a real problem, because the wire has to have a very small diameter, which makes it very fragile.
(54) Generally, extrusion is a method for continuously transforming a malleable material homogenized and melted by stirring and heating (mechanical and thermal). In a sheath (cylinder), the material compressed and stirred by one or more screws is pushed toward a die, to be shaped.
(55) The use of a method for extruding magnetocaloric materials has already been described, in the patent application WO 2006/074790. Nevertheless, this method entails manufacturing a paste whose viscosity is set by the nature of the mixture itself and adjusted by the addition of water or of solvent. It is a cold transformation method and comprises a drying step.
(56) The method proposed in the present invention is a hot forming method, using at least one heating sheath and not involving the production of a paste likely to generate problems of oxidation of the metallic materials employed, because of the presence of water.
(57) According to the present invention more specifically, the extruder comprises an extruding body equipped with at least one heating cylindrical sheath (thermoregulated) inside which one (or two) motorized screws rotate, the body of the extruder is fed through apertures in said sheath by dosing apparatuses that have hoppers supplying pellets or powder.
(58) The extrusion screw continuously stirs, compresses, cuts, heats and transports the fluidized and homogenized material toward the die. The latter confers the desired shape on the fluidized mass by pushing the material through the die.
(59) In the present invention, an extrusion machine can be used like the one schematically represented in
(60) Such a machine notably comprises: an extrusion body Ex, itself comprising a set of individual sheath modules Fi, controlled by at least one heating system; the extrusion body which advantageously comprises two co-rotating extrusion screws together referenced Vi, rotating in the same direction and thereby making it possible to achieve output pressures of the order of 150 bar. Said extrusion screws can comprise different stirring, decompression, acceleration and other such modules. Thus, the raw materials introduced into the body of the extruder are transferred from one screw module to the other which cooperate to increase the mixing capacity, the compression and the transportation of the raw materials introduced; if necessary, a compression chamber CP which receives the fluidized and stirred material m.sub.fl, and propels it toward one or more dies; a die f.sub.il replicates the shape of the one-piece part of composite material based on magnetocaloric material powder and binder m.sub.pl.
(61) For example, the extrusion screw can have a length of between 1 and 4 meters, preferably 2 meters, its length can correspond to its diameter multiplied by a coefficient of between 10 and 24.
(62) The rotation speed is between 80 and 400 rpm, the maximum pressure being able to be approximately 200 bar, bearing in mind that it is possible to provide a gate valve opening and discharging the material when the pressure is too great (typically greater than 200 bar).
(63) The temperature of the material can be between 150? C. (corresponding to the temperature of the extrusion screw and of the sheath) and 240? C. For its part, the temperature of the die can be greater by a few degrees than the temperature of the material in order to reduce the adhesion of the material to the die.
(64) The extrusion screw can comprise a number of different screw elements or modules, with different and/or inverted screw pitches, and also with stirring elements (that can be stacked on the axes of the extrusion screws).
(65) By virtue of the method of the invention, it is possible to sequentially supply the extruder body so as to successively form sections of strips of different materials in the direction Dy.
(66) Thus, according to another variant of the invention illustrated in
and so on, so as to produce interfaces of high quality in the cutting operation, by virtue of the fact that the cutting takes place in one and the same material and not at the interface between two different materials.
(67) It is also particularly advantageous and suitable to use a co-extrusion method to produce a one-piece part made of different materials in planes parallel to the plane defined by the directions Dx, Dy.
(68) To do this, a number of extruder bodies are used in parallel, all emerging into a single compression chamber CP as schematically represented in
(69) It is thus possible to notably form the one-piece part illustrated in
(70) According to another variant illustrated in
(71) Generally, in the extrusion or co-extrusion production method, a means for cooling said one-piece part can be provided, to ensure that it keeps its shape after it is removed from said die f.sub.il. The benefit of this cooling means is to avoid having the one-piece part become deformed when it leaves the die f.sub.il. The aim of this cooling is to bring the one-piece part very quickly from a temperature of approximately 200? C. to a temperature close to ambient temperature. This cooling means can come in a number of variants.
(72) A first variant which is not represented consists in using external cooling means and thus in cooling the one-piece part on leaving the die with a blade of air at low temperature (approximately 5? C. for example) and at low speed (suitable speed to avoid deforming the one-piece part).
(73) A second variant represented in
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(75) The invention is not limited to such a number of sections, it is possible for example to envisage incorporating two sections: one section comprising a cooling channel and another section without cooling channel.
(76) The one-piece parts described previously can advantageously be incorporated in a thermal module. For that, according to an advantageous variant, the one-piece part can have a V-shaped geometry, the set of blades on their base being curved in the second direction Dy, as illustrated in