Masking substrates for application of protective coatings
10449568 · 2019-10-22
Assignee
Inventors
- David James Astle (Park City, UT, US)
- Tyler Christensen Child (South Jordan, UT, US)
- Vimal Kumar Kasagani (Taylorsville, UT, US)
- Cameron LaMar Loose (Roy, UT, US)
- Blake LeRoy Stevens (Morristown, NJ, US)
- Max Ernest Sorenson (Cottonwood Heights, UT, US)
Cpc classification
H05K2201/0145
ELECTRICITY
H01L2924/0002
ELECTRICITY
H05K3/0073
ELECTRICITY
C09J9/00
CHEMISTRY; METALLURGY
H01L2924/00
ELECTRICITY
H05K3/0079
ELECTRICITY
H01L2924/0002
ELECTRICITY
C09J2301/304
CHEMISTRY; METALLURGY
H01L2924/00
ELECTRICITY
H01L21/6715
ELECTRICITY
International classification
H01L21/00
ELECTRICITY
H05K1/18
ELECTRICITY
C09J9/00
CHEMISTRY; METALLURGY
B05D1/32
PERFORMING OPERATIONS; TRANSPORTING
H01L21/67
ELECTRICITY
H05K3/00
ELECTRICITY
Abstract
A method for applying a protective coating to selected portions of a substrate is disclosed. The method includes applying a mask to or forming a mask on at least one portion of the substrate that is not to be covered with the protective coating. The mask may be selectively formed by applying a flowable material to the substrate. Alternatively, the mask may be formed from a preformed film. With the mask in place, the protective coating may be applied to the substrate and the mask. A portion of the protective coating that overlies the mask may be delineated from other portions of the protective coating; for example, by cutting, weakening or removing material from the protective coating at locations at or adjacent to the perimeter of the mask. The portion of the protective coating that overlies the mask, and the mask, may then be removed from the substrate.
Claims
1. A method for protectively coating a substrate, comprising: introducing a flowable mask material into at least one selected communication port of a substrate to define a mask in the at least one selected communication port, the flowable mask material substantially conforming a shape of a surface of the at least one selected communication port under natural force; applying a mechanical force to the flowable mask material to conform the flowable mask material to the shape of the surface of the at least one selected communication port after the flowable mask material has been introduced into the at least one selected communication port, wherein the mechanical force is applied by an instrument that does not form a part of a finished device including the substrate, wherein the mask bonds to the substrate; applying a protective coating over the substrate and over the mask, such that the protective coating adheres to the substrate and the mask; cutting the protective coating at locations outside an outer perimeter of the mask, wherein cuts from the cutting the protective coating does not extend completely through the protective coating; and removing the mask and at least a portion of the protective coating over the mask.
2. The method of claim 1, wherein introducing the flowable mask material comprises introducing the flowable mask material into a connector of an electronic assembly and wherein the mechanical force applied by the instrument is different than an applicator instrument that applies the liquid masking material.
3. The method of claim 1, wherein introducing the flowable mask material comprises introducing a hot melt adhesive into the at least one selected communication port.
4. The method of claim 1, wherein removing the mask and at least the portion of the protective coating over the mask comprises removing locations of the protective coating over or adjacent to a perimeter of the mask material.
5. The method of claim 4, further comprising: pulling at least the portion of the protective coating from the mask material or from the substrate.
6. The method of claim 5, further comprising: pulling the mask material from the substrate, with a portion of the protective coating remaining on protected areas of the substrate.
7. The method of claim 1, further comprising: inserting a plug into the at least one selected communication port in the substrate before introducing the flowable mask material.
8. The method of claim 7, wherein introducing the flowable mask material comprises applying a seal around the plug to create a seal between the plug and the substrate at an opening of the at least one selected port.
9. A method for applying a protective coating to a substrate, comprising: applying a liquid mask material to at least one selected location of an electronic device assembly, the at least one selected location being a location to be exposed through a protective coating, including introducing the liquid masking material into at least one communication port of the electronic device assembly, the liquid mask material flowing to substantially conform to a shape of a surface of the at least one selected location of the electronic device assembly upon being applied to the at least one selected location of the electronic device assembly; applying a mechanical force to the liquid mask material to conform the liquid mask material to the shape of the surface of the at least one selected location after the liquid mask material has been applied to the at least one selected location, wherein the mechanical force is applied by an instrument that does not form a part of a finished device including the substrate; allowing the liquid mask material to substantially harden and bond to the substrate, by cooling to an ambient temperature, to define a mask; after the mask is hardened, applying the protective coating over the mask and the electronic device assembly, such that the protective coating adheres to the mask and the electronic device assembly; cutting the protective coating at locations outside an outer perimeter of the mask; and removing the mask and at least a portion of the protective coating over the mask.
10. The method of claim 9, wherein applying the protective coating over the mask comprises applying a coating comprising poly(p-xylylene) and wherein the mechanical force applied by the instrument is different than an applicator instrument that applies the liquid masking material.
11. The method of claim 9, wherein applying the protective coating over the mask comprises applying a coating comprising aluminum oxide.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) In the drawings:
(2)
(3)
(4)
(5)
(6)
(7)
(8)
DETAILED DESCRIPTION
(9)
(10) As used herein, the terms component and feature are used broadly to encompass a variety of elements of a substrate 100, such as an electronic device. Certain components or features 102a-c may benefit from being covered or shielded by a protective coating (e.g., to prevent their exposure to moisture, contamination, etc.). However, a protective coating may adversely affect the operation or performance of other components or features 102a-c. Accordingly, it may be desirable to ultimately leave some components or features 102a-c uncoated.
(11)
(12) A component or feature 102c of the substrate 100, or any other area of the substrate 100 (which area may include at least part of one or more components), that is to be covered by the mask material 106 may be referred to herein as a selected area or as a masked component.
(13) In one embodiment, a mask may be formed as a mask material 106 is selectively applied to the substrate 100. Various embodiments of mask materials 106 that may be dispensed or sprayed onto a substrate 100 include adhesive materials (e.g., cements, epoxies, hot-melt adhesives, etc.), greases, gels, liquid masking materials and the like. Such a mask material 106 may solidify once it has been applied to the substrate, and bond to the substrate 100 in such a way that the resulting mask may be subsequently peeled away or otherwise removed from the substrate 100. The mask material 106 may leave little to no residue (e.g., fugitive adhesive, etc.) on the substrate 100 when it is removed from the substrate 100.
(14) In a specific embodiment, the mask material 106 may comprise a low temperature hot glue. In embodiments where the substrate 100 or its components or features 102c that are to be masked are delicate or sensitive to heat (e.g., when the substrate 100 is an electronic device, a subassembly of an electronic device, or the like), the use of a low temperature hot glue may prevent damage to the component or feature 102c when the mask material 106 is applied. Without limitation, a low temperature hot glue that has a softening point of about 97 C. to about 197 C. may be used as a mask material 106 for an electronic device. The mask material 106 may also be selected to be removable with relatively little force such that the mask formed from the adhesive can be removed from the substrate 100 or a component or feature 102c thereof without damaging the substrate 100, its component or feature 102c or the carrier 104. It may also be desirable to select a mask material 106 that does not react chemically with the portion(s) of the substrate that are being masked. A specific embodiment of such a mask material 106 is the hot melt adhesive available as TECHNOMELT TACK 003A from Henkel AG & Company, KGaA of Dusseldorf, Germany, or the hot melt adhesive sold as GIA 1057 Permanent EVA by Glue Machinery Corporation of Baltimore, Md. The mask material 106 may be applied to small components or features 102c on the substrate 100.
(15) In another embodiment, the mask material 106 may comprise a film, which is also referred to herein as a wrapper. As used herein, the term wrapper refers to a thin layer of material. The wrapper may be a thin, continuous sheet of material that is applied to components or features 102c of the substrate 100; in other embodiments, the wrapper may comprise a film that is formed on substrate 100 as a mask material 106 is applied to the substrate 100.
(16) In embodiments where the mask material 106 is a wrapper, the wrapper may have a thickness of about 2 mils (i.e., 0.002 inch or about 0.05 mm) to about 10 mils (i.e., 0.010 inch or about 0.254 mm). The wrapper may have a high elongation-to-break value, or ultimate elongation, which represents the strain on a sample of the wrapper when it breaks. In a specific embodiment, the wrapper may have an elongation value of 130% or greater. One side of the wrapper may be coated with an adhesive material (e.g., a high tack acrylic, a silicone adhesive, etc.) to facilitate adhesion of the wrapper to a substrate 100. Such an adhesive material may have a tackiness of high to very high. In some embodiments, the wrapper may include a backing (e.g., a co-extruded multi-polymer backing, etc.), which may facilitate its positioning onto a substrate 100. The wrapper may be configured to bond securely to a substrate 100, while still being removable without tearing or slivering. In one embodiment, the wrapper may comprise a polyethylene film; for example, the Polyethylene Protective Tape 2E97C available from 3M of St. Paul, Minn. In another embodiment, the wrapper may comprise a polyvinyl chloride film, such as those marketed by Orafol Europe GmbH of Oranienburg, Germany as ORAGUARD films (e.g., ORAGRUARD 210, etc.).
(17) In another embodiment, the mask material 106 may include a combination of a sealant (e.g., a dispensable or sprayable material, etc.) and a wrapper; for example, the mask material 106 may have a wrapper element covering a component or feature 102c of a substrate 100 and a glue located around the perimeter of the component or feature 102c. The sealant may form a seal between the substrate 100 and the periphery of the wrapper that secures the wrapper in place over the component or feature 102c
(18)
(19) In a more specific embodiment, where the mask material 106 comprise a hot melt adhesive, the hot melt adhesive may be heated to its softening point and, while remaining at a temperature at or above its softening point, applied to a substrate 100. The hot melt adhesive may then flow and conform to the shape of the portion of the substrate 100 to which it is applied (e.g., the component or feature 102c, etc.), or the hot melt adhesive may be molded to the shape of the component 102c while the hot melt adhesive is still soft.
(20) In another specific embodiment, where the mask material 106 comprises a wrapper, the wrapper may be stretched and heated prior to its application to a substrate 100. The wrapper may then be subjected to pressure that causes it to substantially conform to the topography of the portion of the substrate 100 (e.g., the component or feature 102c, etc.) to which it is applied.
(21) In the ensuing disclosure, reference numeral 106 may refer to the mask(s) formed from a mask material, rather than to the mask material itself.
(22) With one or more masks 106 in place on the substrate 100, a protective coating may be applied to the substrate 100.
(23) The protective coating 202 may be applied by a suitable coating element. In a specific embodiment, the coating element of an assembly system may comprise an apparatus that forms reactive monomers, which monomers may then be deposited onto and form polymers on one or more surfaces that are to be made moisture-resistant (e.g., water-resistant, waterproof, etc.). In specific embodiments, the coating element may be configured to deposit a protective coating 202 of a poly(p-xylylene) (i.e., parylene), including unsubstituted and/or substituted units, onto one or more surfaces that are to be rendered moisture-resistant. Examples of protective coatings 202 that function in this manner are described by U.S. patent application Ser. Nos. 12/104,080, 12/104,152 and 12/988,103, the entire disclosure of each of which is hereby incorporated herein. U.S. patent application Ser. Nos. 12/446,999, 12/669,074 and 12/740,119, the entire disclosures of all of which are, by this reference, incorporated herein, also disclose embodiments of equipment and/or processes that may be employed by a coating element of an assembly system to form protective coatings 202.
(24) Other materials that may be applied by a coating element to form the protective coating 202 include, but are not limited to, thermoplastic materials and/or curable materials (e.g., radiation-curable materials, two-part materials, thermoset materials, room-temperature curable materials, etc.). A protective coating 202 may also be formed from an inorganic material, such as a glass or a ceramic material. A CVD or an ALD process may, in specific embodiments, be used for depositing a protective coating 202 comprising aluminum oxide (Al.sub.2O.sub.3) or a protective coating 202 consisting substantially of aluminum oxide.
(25) Some techniques for applying a protective coating 202 are non-directional; that is, the protective coating 202 is applied non-selectively and adheres to all areas of a substrate that are exposed to the coating material(s). For example, using CVD processes, material that deposits on components 102a and 102b will also cover component 102c.
(26) In the context of an entire assembly system, a plurality of different coating elements, and even different types of coating elements, may be used and, optionally, incorporated into the organization of the assembly system to provide desired types of protective coatings 202 on different types of features. Without limitation, one coating element may be configured to provide protective coating 202 in small spaces between different components or features 102a-c of a substrate, such as an electronic device under assembly (e.g., between surface mount technology (SMT) components and a circuit board, etc.), while another coating element may be configured to provide a conformal, blanketed protective coating 202 on surfaces that are exposed during the coating process, and another coating element may selectively apply a second protective coating 202 to certain other components or features 102a-c.
(27) The protective coating 202 may provide moisture-resistance to the substrates 100, or at least to selected components or features 102a-c thereof, once the protective coating 202 is applied, as seen in
(28) Any of a variety of metrics may be used to quantify the moisture-resistance of each protective coating 202. For example, the ability of a protective coating 202 to physically inhibit water or other moisture from contacting a coated feature may be considered to impart the protective coating 202 with moisture-resistance.
(29) As another example, the water-resistance or, more broadly, the moisture-resistance of a protective coating 202 may be based on more quantifiable data, such as the rate at which water permeates through the protective coating 202, or its water vapor transfer rate, which may be measured using known techniques in units of g/m.sup.2/day or in units of g/100 in.sup.2/day (e.g., less than 2 g/100 in.sup.2/day, about 1.5 g/100 in.sup.2/day or less, about 1 g/100 in.sup.2/day or less, about 0.5 g/100 in.sup.2/day or less, about 0.25 g/100 in.sup.2/day or less, about 0.15 g/100 in.sup.2/day or less, etc., through a film having a minimum thickness or an average thickness of about 1 mil (i.e., about 25.4 m), at a temperature of 37 C. and at a relative humidity of 90%).
(30) Another way in which the moisture-resistance of a protective coating 202 may be determined is by the water contact angle of a droplet of water that has been applied to a surface of the protective coating 202 by an acceptable technique (e.g., the static sessile drop method, the dynamic sessile drop method, etc.). The hydrophobicity of the surface may be measured by determining the angle the base of the water droplet makes with the surface, from beneath a base of the water droplet; for example, using the Young equation, i.e.:
(31)
where .sub.A is the highest, or advancing, contact angle; .sub.R is the lowest, or receding, contact angle;
(32)
If the surface is hydrophilic, the water will spread somewhat, resulting in a water contact angle of less than 90 with the surface. In contrast, a hydrophobic surface, which, for purposes of this disclosure, may be considered to be water-resistant or, more broadly, moisture-resistant, will prevent the water from spreading, resulting in a water contact angle of 90 or greater. The more the water beads on a surface, the greater the water contact angle. When water droplets bead on a surface such that the water contact angle with the surface is about 120 or more, the surface is considered to be highly hydrophobic. When the angle at which water contacts a surface exceeds 150 (i.e., a water droplet on the surface is nearly spherical), the surface is said to be superhydrophobic.
(33) Of course, other measures of water-resistance or other types of moisture-resistance may also be employed. While the coating element(s) of an assembly system may be configured to apply a protective coating 202 to exterior surfaces of one or more components or features 102a-c of a substrate 100, such as an electronic device under assembly, when the substrate 100 is incorporated into a fully assembled device (e.g., an electronic device, etc.), one or more surfaces on which a protective coating 202 resides may be located within an interior of the substrate. Thus, an assembly system may be configured to assemble an electronic device that includes a protective coating 202 on internal surfaces, or an internally confined protective coating 202.
(34) Turning now to
(35) The cut 204 may be formed in a variety of ways, including, but not limited to, those disclosed by the U.S. Provisional Patent Application No. 61/750,257, filed on Jan. 8, 2013 and titled METHODS FOR REMOVING PROTECTIVE COATING FROM AREAS OF AN ELECTRONIC DEVICE, by U.S. Provisional Patent Application No. 61/750,254, filed on Jan. 8, 2013 and titled METHODS FOR MASKING ELECTRONIC DEVICES FOR APPLICATION OF PROTECTIVE COATINGS AND MASKED ELECTRONIC DEVICES, and by PCT international patent application no. PCT/US2014/010510, filed on Jan. 7, 2014 and titled REMOVAL OF SELECTED PORTIONS OF PROTECTIVE COATINGS FROM SUBSTRATES, the entire disclosures of which are hereby incorporated herein.
(36) As seen in
(37) Removal of portions of the protective coating 202 and the mask 106 from the substrate 100 may be effected manually or as part of an automated process. In one embodiment, a pick-and-place apparatus (e.g., a vacuum head, etc.) may be moved over the protective coating 202 after one or more cuts 204 are formed to selectively remove (e.g., pull, etc.) each cut portion of the protective coating 202 and the underlying mask 106 from the substrate 100, leaving desired areas (e.g., the component or feature 102c, etc.) exposed, as shown in
(38)
(39) In the illustrated embodiment, the subassembly 302 includes a display 310 carried by a support 304. A subassembly 302 may, of course, additionally or alternatively include other components, such as lenses, buttons, switches, ports, speakers, receivers or the like. The subassembly 302 may be oriented with the display 310 being readily accessible for masking. In certain embodiments, it may be desirable to apply the mask 106 to the display 310, including its outer periphery 308, to prevent the protective coating 202 from adhering to the display 310 and its outer periphery 308.
(40) With the subassembly 302 in position, a mask material 106 may be applied to locations that are not to be covered by a subsequently formed protective coating 202. In the illustrated embodiment, the mask material 106 may comprise a wrapper, such as a polyethylene tape or a PVC tape. A retainer 320 may hold the mask material 106 in position above the support 304 in a manner that prepares the mask material 106 for application to the subassembly 302. For example, the retainer 320 may stretch or enable stretching of the mask material 106 in one or more directions.
(41) As shown in
(42)
(43)
(44) As an alternative to the use of a vacuum 306 to cause the mask material 106 to conform to the shape of the subassembly 302, other approaches may be used. In some embodiments, force may be applied mechanically to the mask material 106 (e.g., using a press, a mold, etc.). In other embodiments, fluid (e.g., air, gas, a liquid, etc.) under positive pressure (i.e., pressure exceeding ambient pressure) may be applied onto a side of the mask material 106 opposite from the subassembly 302 in order to press the mask material 106 against the subassembly 302.
(45) When the mask material 106 conforms to the shape of the subassembly 302, it may be secured to the subassembly 302. Without limitation, the mask material 106 may adhere to the subassembly 302 upon conformation or subsequent treatment. In more specific embodiments, a mask material 106 that shrinks under elevated temperature (e.g., a so-called shrink wrap material, etc.) may be heated after it has been applied to the subassembly 302 to tighten the mask material 106, which may shape it to better fit the subassembly 302 and at least partially mechanically secure the mask 106 to the subassembly 302.
(46) Any excess material (e.g., loose portions around the periphery of the mask 106, etc.) may then be cut, and the subassembly 302, with mask 106 in place, may be removed from the support 304. The subassembly 302 may then be ready for the coating 202 to be applied. The mask material 106 may prevent the coating 202 from being formed on the display 310 and the outer periphery 308, and may also protect the display 310 and the outer periphery 308 from scratches or other damage during application of the coating 202.
(47)
(48) As shown in
(49) The mask 106 may also include an adhesive 512. The adhesive 512 may be applied before or after the wrapper 510 is applied to the subassembly 302. The adhesive 512 may be applied adjacent to or around a peripheral edge 506 of the wrapper 510 to secure the outer periphery of the wrapper 510 to the subassembly 302, and to prevent material of a protective coating 202 from creeping between the wrapper 510 and the subassembly 302.
(50) Once the protective coating 202 is applied to the interior 502 of the subassembly 302, the mask 106 and portions of the protective coating 202 thereover may be removed. Without limitation, the protective coating 202, at the peripheral edge 506 of the subassembly 302 (e.g., along line 508, etc.), may be removed, cut or weakened. By removing, cutting or weakening the protective coating 202 at locations outside the outer perimeter of the mask 106, the entire mask 106 may be removed from the subassembly 302.
(51) In another embodiment, the entire peripheral edge 506 of the subassembly 302 may be subjected to a material removal process to remove portions of the protective coating 202, any adhesive 512 and any portion of the wrapper 510 on or over the edge 506. Any remaining portion of the wrapper 510 and the adhesive 512 may then, along with overlying portions of the protective coating 202, be removed from the subassembly 302, including its display 310. Other portions of the protective coating 202 will remain over components or features 102 in the interior 502 of the subassembly 302.
(52) The mask 106 may protect the display 310 or other features of the subassembly 302 during the assembly process, and even during subsequent storage and shipment. The mask 106, in such an embodiment, may include a tab or other protrusion that allows a user to easily remove it from the display 310 or from another component or feature of the subassembly 302; e.g., by a consumer.
(53) In certain embodiments, other masking elements may be used to prevent undesired application of a protective coating 202 (see, e.g.,
(54)
(55) Although the foregoing disclosure provides many specifics, these should not be construed as limiting the scope of any of the ensuing claims. Other embodiments may be devised which do not depart from the scopes of the claims. Features from different embodiments may be employed in combination. The scope of each claim is, therefore, indicated and limited only by its plain language and the full scope of available legal equivalents to its elements.