Oxidizing composition for the treatment of keratin fibers comprising at least one cationic polymer, at least one fatty amide and at least one anti-oxygen agent

Abstract

Provided is a composition for the treatment of keratin fibers, for example human keratin fibers such as the hair, comprising, in a cosmetically acceptable medium, at least one cationic polymer; at least one fatty amide; at least one anti-oxygen agent; and at least one oxidizing agent; wherein the pH of the composition ranges from 1.5 to 4.5. Also provided is a composition for the treatment of keratin fibers, comprising, in a cosmetically acceptable medium, at least one cationic polymer; at least one fatty amide; at least one anti-oxygen agent; and at least one oxidizing agent; wherein the pH of the composition is alkaline. Also provided is a method for treating keratin fibers, comprising applying, to the keratin fibers, at least one oxidizing composition described herein.

Claims

1. A composition for treating keratin fibers comprising: at least two cationic polymers comprising Polyquaternium-6 and hexadimethrine chloride; at least one fatty amide; at least one anti-oxygen agent; at least one non-silicone oil selected from mineral, vegetable, animal, or synthetic oils; at least one oxidizing agent comprising hydrogen peroxide; and a solvent comprising water and optionally at least one non-aqueous solvent; wherein the pH of the composition ranges from 1.5 to 4.5; wherein the at least one non-silicone oil is present in an amount of at least 20% by weight, relative to the total weight of the composition; wherein the composition does not include a hair dye; and wherein the composition is an oxidizing composition.

2. A composition for treating keratin fibers comprising: at least two cationic polymers comprising Polyquaternium-6 and hexadimethrine chloride; at least one fatty amide; at least one anti-oxygen agent selected from vitamin E, ethers thereof, or esters thereof; at least one non-silicone oil selected from mineral, vegetable, animal, or synthetic oils; at least one oxidizing agent comprising hydrogen peroxide; and a solvent comprising water and optionally at least one non-aqueous solvent; wherein the pH of the composition is alkaline, wherein the at least one non-silicone oil is present in an amount of at least 20% by weight, relative to the total weight of the composition; wherein the composition does not include a hair dye; and wherein the composition is an oxidizing composition.

3. The composition according to claim 1, wherein the at least one fatty amide is selected from those of formula (I): ##STR00003## wherein: R is a saturated or unsaturated, linear or branched C.sub.8-C.sub.30 alkyl radical, optionally substituted with at least one radical selected from an OR.sub.5 radical, a NR.sub.6R.sub.7 radical, a carboxyl radical, a sulphonic radical, a carboxamido radical CONR.sub.6R.sub.7, a sulphonamido radical SO.sub.2NR.sub.6R.sub.7, a heteroaryl, and an aryl radical optionally substituted with at least one entity selected from (C.sub.1-C.sub.4)alkyl, hydroxy, C.sub.1-C.sub.2 alkoxy, amino, and (di)alkyl(C.sub.1-C.sub.2)amino groups; R.sub.5, R.sub.6 and R.sub.7, which may be identical or different, represent: a hydrogen atom; a linear or branched C.sub.1-C.sub.4 alkyl radical, optionally substituted with at least one radical selected from a hydroxy, a C.sub.1-C.sub.2 alkoxy, a carboxamido CONR.sub.8R.sub.9, a sulphonyl SO.sub.2R.sub.8, and an aryl radical optionally substituted with a (C.sub.1-C.sub.4)alkyl, hydroxy, C.sub.1-C.sub.2 alkoxy, amino, or (di)alkyl(C.sub.1-C.sub.2)amino radical; or an aryl radical optionally substituted with a (C.sub.1-C.sub.4)alkyl, hydroxy, C.sub.1-C.sub.2 alkoxy, amino, or (di)alkyl(C.sub.1-C.sub.2)amino radical; R.sub.6 and R.sub.7, which may be identical or different, can also represent a carboxamido radical CONR.sub.8R.sub.9 or a sulphonyl radical SO.sub.2R.sub.8, R.sub.8 and R.sub.9, which may be identical or different, represent a hydrogen atom or a linear or branched C.sub.1-C.sub.4 alkyl radical optionally substituted with at least one hydroxyl or C.sub.1-C.sub.2 alkoxy radical; and n, m and p, which may be identical or different, are integers ranging from 0 to 10, wherein m+p≥1.

4. The composition according to claim 3, wherein R is selected from a C.sub.10-C.sub.18 alkyl radical, n is an integer ranging from 0 to 5, m is an integer ranging from 0 to 1, and p is an integer ranging from 1 to 5.

5. The composition according to claim 3, wherein n is 0.

6. The composition according to claim 1, wherein the at least one fatty amide comprises an ethoxylated amide of colza acids.

7. The composition according to claim 1, wherein the at least one anti-oxygen agent is selected from vitamin E and the ethers and esters thereof.

8. The composition according to claim 1, wherein the composition further comprises at least one hydrogen peroxide stabilizer present in an amount ranging from about 0.0001% to about 5% by weight, relative to the total weight of the composition.

9. The composition of claim 8, wherein the at least one hydrogen peroxide stabilizer comprises a combination of at least one pyrophosphate and at least one stannate.

10. The composition of claim 1, wherein in the composition: the at least one fatty amide is selected from PEG-4 rapeseedamide; the at least one anti-oxygen agent is selected from vitamin E, ethers thereof, or esters thereof; the at least one non-silicone oil is selected from mineral oil; and the composition further comprises at least one hydrogen peroxide stabilizer chosen from pyrophosphates.

11. A composition comprising: at least two cationic polymers comprising Polyquaternium-6 and hexadimethrine chloride; at least one fatty amide; at least one anti-oxygen agent; at least one non-silicone oil selected from mineral, vegetable, animal, or synthetic oils; at least one oxidizing agent comprising hydrogen peroxide; at least one hydrogen peroxide stabilizer in an amount ranging from about 0.0001% to about 5% by weight, relative to the total weight of the composition; and a solvent comprising water and optionally at least one non-aqueous solvent; wherein the pH of the composition ranges from 1.5 to 4.5; wherein the at least one non-silicone oil is present in an amount of at least 20% by weight, relative to the total weight of the composition; wherein the composition does not include a hair dye; and wherein the composition is an oxidizing composition.

12. The composition according to claim 8, wherein the at least one hydrogen peroxide stabilizer comprises at least one pyrophosphate or at least one stannate.

13. The composition according to claim 1, wherein the at least one fatty amide is present in an amount ranging from 0.5% to 5% by weight, relative to the total weight of the composition.

14. The composition according to claim 2, wherein the composition further comprises at least one hydrogen peroxide stabilizer comprising pyrophosphates and/or stannates.

15. The composition according to claim 2, wherein the at least one fatty amide is present in an amount ranging from 0.5% to 5% by weight, relative to the total weight of the composition.

16. A composition for treating keratin fibers comprising: from 0.01% to 0.75% of at least two cationic polymers comprising Polyquaternium-6 and hexadimethrine chloride; from 0.1% to 1.3% of at least one fatty amide comprising PEG-4 rapeseedamide; at least one anti-oxygen agent comprising Vitamin E; from 20% to 50% of at least one non-silicone oil comprising mineral oil; from 1% to 12% of hydrogen peroxide; and a solvent comprising water and optionally at least one non-aqueous solvent; wherein all of the percentages are based on the total weight of the composition; wherein the pH of the composition ranges from 1.5 to 4.5; wherein the composition does not include a hair dye; and wherein the composition is an oxidizing composition.

Description

EXAMPLES

(1) The following compositions were prepared:

(2) TABLE-US-00001 Composition A B C Diethylenetriamine pentaacetic acid, 0.15 g 0.15 g 0.15 g pentasodium salt in 40% aqueous solution Hydrogen peroxide in solution 12 g 24 g 12 g at 50% (hydrogen peroxide 200 volumes) Sodium stannate 0.04 g 0.04 g 0.04 g Tetrasodium pyrophosphate, 10H.sub.2O 0.03 g 0.03 g 0.03 g Tetramethyl hexamethylenediamine/ 0.25 g 0.25 g 0.25 g dichloro-1,3-propylene polycondensate in aqueous solution sold under the name MEXOMERE PO by the company Chimex Poly-dimethyl-diallyl ammonium 0.50 g 0.50 g 0.50 g chloride in water at 40%, unstabilized, sold under the name MERQUAT 100 by the company Nalco Deionized water 75.73 g 75.73 g 75.73 g Vaseline oil — — 25 g Glycerol 0.50 g 0.50 g 0.50 g Stearyl alcohol 30/70 8 g 8 g 8 g Ceteareth-33 1.40 g 1.40 g 3 g Ethoxylated amide of colza acids (4 1.30 g 1.30 g 1.30 g EO) protected PEG-4 rapeseedamide Vitamin E 0.10 g 0.10 g 0.10 g Phosphoric acid q.s. pH 2 pH 2 pH 2

(3) Compositions A, B, and C were stable, even after 2 months stored at 45° C.

(4) Similar results were obtained when the 0.25 g of MEXOMERE PO and the 0.5 g of MERQUAT 100 were replaced with 0.75 g of MERQUAT 100 and of MEXOMERE PO.