Interference pigment

Abstract

A multilayered interference pigment containing, in succession: a metal core in the form of a flake, the metal core containing a material selected from gold, silver, palladium, rhodium, ruthenium, platinum, osmium, iridium and an alloy thereof; a first layer of transparent dielectric material; and a second discontinuous metal layer making it possible to both reflect a portion of the light beam and to transmit another portion of this beam onto the metal core.

Claims

1. A sintered multilayered interference pigment comprising in succession: a metal core comprising a material selected from the group consisting of gold, silver, palladium, rhodium, ruthenium, platinum, osmium, iridium, and alloys thereof; a first layer of transparent dielectric material; and a second discontinuous metal layer making it possible to both reflect a portion of a light beam and to transmit another portion of this beam onto the metal core, wherein the metal core is in the form of an elongated flake having an average transverse diameter D between 2 and 300 μm, an average thickness E between 20 and 1000 nm, and a form factor defined as the ratio of the average transverse diameter to the average thickness of between 5 and 1000 .

2. The pigment according to claim 1, wherein the metal core comprises a material selected from the group consisting of gold, silver, rhodium, and alloys thereof.

3. The pigment according to claim 1, further comprising a third protective layer comprising a transparent dielectric material or a transparent resin.

4. The pigment according to claim 3, wherein the dielectric material of the first layer and of the third protective layer is selected from the group consisting of TiO.sub.2, SiO.sub.2, Al.sub.2O.sub.3, MgF.sub.2, AlN, Ta.sub.2O.sub.5, Si.sub.3N.sub.4 ZnS, ZnO, ZrO.sub.2, Cr.sub.2O.sub.3, CeO.sub.2, Y.sub.2O.sub.3, HfN, HfC, HfO.sub.2, La.sub.2O.sub.3, MgO, Sb.sub.2O.sub.3, SiO, Se.sub.2O.sub.3, SnO.sub.2, and WO.sub.3.

5. The pigment according to claim 1, wherein the second discontinuous metal layer comprises a material selected from the group consisting of silver, gold, aluminium, titanium, palladium, platinum, ruthenium, rhodium, osmium, iridium, tin, chromium, iron, cobalt, nickel, copper, zinc, rhodium, and alloys thereof.

6. The pigment according to claim 1, wherein the metal core has an average transverse diameter between 5 and 100 μm, and. a form factor defined as the ratio of the average transverse diameter to the average thickness of between 10 and 500.

7. The pigment according to claim 1, wherein the first layer has a thickness between 50 and 500 nm.

8. The pigment according to claim 3, wherein each of the second discontinuous metal layer and the third protective layer have a thickness between 1 and 30 nm.

9. The pigment according to claim 3, wherein the second discontinuous metal layer is in the form of particles arranged at intervals.

10. An article, comprising interference pigments according to claim 1.

11. The article according to claim 10, comprising a coating comprising interference pigments.

12. The article according to claim 10, comprising interference pigments in the mass.

Description

BRIEF DESCRIPTION OF THE FIGURES

(1) The invention is described in the following in a more detailed manner with reference to the attached drawings, given by way of example but without restriction, in which:

(2) FIG. 1 represents schematically the different layers of the interference pigment according to the invention,

(3) FIG. 2 represents schematically the optical paths of light through the interference pigment according to the invention.

DETAILED DESCRIPTION OF THE INVENTION

(4) The present invention relates to a multilayered interference pigment comprising a core made from a pure or alloyed precious metal, such as gold, silver, platinum, palladium, ruthenium, rhodium, osmium or iridium. These metals have a degree of reflectivity that is greater than 70%, even greater than 80% or even 90% in all or part of the visible spectrum (380 nm-780 nm). The metals selected are preferably rhodium, gold, silver or an alloy thereof and, more preferably, gold, silver or an alloy thereof. Gold has an increased reflectivity for wavelengths greater than 550 nm. It is therefore preferred when warm colours (reds, yellows) are required. However, silver has increased reflectivity over a more extended range of the visible spectrum which also makes it possible to obtain blue and green colours. In the case of an alloy, the choice relates to an Ag—Pt alloy for example.

(5) The pigment 1 according to the invention represented in FIG. 1 comprises the metal core 2 coated with a first layer 3 of dielectric material which forms the interference medium, which is covered itself by a second layer 4 of metal material and possibly coated by a third protective layer 5.

(6) The metal core 2 is in the form of an elongated flake with an average transverse diameter D between 2 and 300 μm, preferably between 5 and 100 μm and more preferably between 10 and 30 μm. It has an average thickness E between 20 and 1000 nm and preferably between 300 and 500 nm. In general, the form factor of the flakes, i.e. the ratio of the average transverse diameter to the average thickness is between 5 and 1000 and preferably between 10 and 500.

(7) The first layer 3 comprises a transparent dielectric material which for example can consist of TiO.sub.2, SiO.sub.2, Al.sub.2O.sub.3, MgF.sub.2, AlN, Ta.sub.2O.sub.5, Si.sub.3N.sub.4, ZnS, ZnO, ZrO.sub.2, Cr.sub.2O.sub.3, CeO.sub.2, Y.sub.2O.sub.3, HfN, HfC, HfO.sub.2, La.sub.2O.sub.3, MgO, Sb.sub.2O.sub.3, SiO, Se.sub.2O.sub.3, SnO.sub.2, or WO.sub.3, with a preference for SiO.sub.2. This layer has a thickness between 50 and 500 nm and, preferably, between 300 and 400 nm, the thickness and the refractive index of the dielectric material being selected as a function of the desired interference colour.

(8) The second layer 4 is formed by a metal or a metal alloy designed to reflect light on the surface of the interference pigment. The metal is preferably selected from silver, gold, aluminium, titanium, palladium, platinum, ruthenium, rhodium, osmium, iridium, tin, chromium, iron, cobalt, nickel, copper, zinc, rhodium and an alloy thereof. It is more preferably selected from silver, gold, aluminium, rhodium and an alloy thereof. This layer has a thickness between 1 and 30 nm and, preferably, between 1 and 10 nm. The layer is configured to enable the transmission of a portion of the light beam incident to the metal core. It is thus preferably discontinuous, non-uniform and possibly formed by particles. In the latter case, the particles are preferably arranged at intervals with a spacing between the particles in the order of several nanometers. Of course, such a second discontinuous metal layer makes it possible both to reflect a portion of the light beam and transmit another portion of this beam onto the metal core.

(9) The third protective layer 5, which is optional, is designed to protect the second metal layer from oxidation or wear. This layer is preferably made from a transparent dielectric material such as TiO.sub.2, SiO.sub.2, Al.sub.2O.sub.3, MgF.sub.2, AlN, Ta.sub.2O.sub.5, du Si.sub.3N.sub.4, ZnS, ZnO, ZrO.sub.2, Cr.sub.2O.sub.3, CeO.sub.2, Y.sub.2O.sub.3, HfN, HfC, HfO.sub.2, La.sub.2O.sub.3, MgO, Sb.sub.2O.sub.3, SiO, Se.sub.2O.sub.3, SnO.sub.2, WO.sub.3 or a transparent resin. This layer has a thickness between 1 and 30 nm and preferably between 1 and 10 nm.

(10) The present invention does not exclude the insertion of intermediate layers between the metal core and the first layer and/or between the first and second layers in order to increase the adhesion between the different constituent layers of the interference pigment.

(11) As illustrated in FIG. 2, a portion of the incidental light is reflected on the outer metal layer 4 whilst another portion is transmitted and reflected on the metal core 2. The difference in the trajectory of the reflected beams creates a colour due to the effect of interference which has nuances depending on the angle of observation.

(12) According to the invention, the metal core can be made from a leaf, for example gold or silver leaf, with outer layers deposited by CVD, PVD, electrochemically or by a non-electrolytic process, the whole being subsequently crushed. The multilayered pigment can also be made from flakes obtained chemically by wet or dry methods, or even by atomisation, possibly crushed before being coated.

(13) The pigment powder obtained in this way can be dispersed in an appropriate medium according to the application. It can thus be used in formulations for paint, ink, cosmetic products and as well as generally in coating formulations.

(14) It is also possible to use the pigment powder as it is. In this configuration, the previously deposited powder is compacted onto a substrate then sintered in a uniform or selective manner from the effect of a local application of heat for example by laser. This results in a dense coating covering all or part of the substrate. It is also possible to form solid articles by compacting and thickening the pigment powder. It is also possible to produce solid particles by means of additive manufacturing.

(15) By way of example, in the field of horology, the pigments can be used after dispersion in an appropriate medium or as such for coating or decorating a trim piece (dial, bezel, caseband, base, clasp, . . . ) or for forming a solid trim piece (dial, hand, pointer, pushbutton, etc.).

(16) Finally, it should be noted that the pigment with a core made of pure gold and its different layers is titratable at 18 carats. Thus for a pigment comprising in succession: a gold core with a thickness of 400 nm for a transverse diameter of 30 μm, a first coating layer of SiO.sub.2 with a thickness of 330 nm, a second metal coating layer of Ag with a thickness of 5 nm, a third protective layer of SiO.sub.2 with a thickness of 10 nm,
the percentage by weight of gold is 79.01%, i.e. greater than the 75% required for 18 carat gold.

(17) The metal core can also be made from other precious alloys in order to achieve legal standards such as for example Pd500 or Pt900.

KEY TO THE FIGURES

(18) (1) interference pigment (2) metal core (3) first layer, also referred to as dielectric layer (4) second layer, also referred to as metal layer (5) third layer, also referred to as protective layer D: Transverse diameter of the metal core forming a flake E: Thickness of metal core forming a flake