Liquid crystal display panel wherein a thickness direction retardation of at least one of a first, second, third, and fourth phase difference plate has a negative value
10437106 ยท 2019-10-08
Assignee
Inventors
- Akira Sakai (Sakai, JP)
- Kohzoh Nakamura (Sakai, JP)
- Masahiro Hasegawa (Sakai, JP)
- Takako Koide (Sakai, JP)
- Kiyoshi Minoura (Sakai, JP)
Cpc classification
G02F1/133634
PHYSICS
G02F1/134363
PHYSICS
G02F1/1337
PHYSICS
G02F1/133638
PHYSICS
International classification
G02F1/1337
PHYSICS
Abstract
A liquid crystal display panel (100A) includes a first polarizing plate (22) and a first phase difference plate (32a) disposed on an observer side, and a second polarizing plate (24) and a second phase difference plate (34a) disposed on a back surface side. nd of a liquid crystal layer having a homogeneous alignment when no electrical field is applied is 360 nm or greater and 490 nm or less, and an in-plane retardation R1 of the first phase difference plate is 100 nm or greater and 160 nm or less. A thickness direction retardation of at least one of the first and second phase difference plates has a negative value. The slow axes of the first and second phase difference plates are substantially parallel to each other and substantially orthogonal to an azimuthal direction of the liquid crystal director.
Claims
1. A liquid crystal display panel comprising: a liquid crystal cell including a bottom-side substrate, a top-side substrate, a liquid crystal layer, and an electrode pair, the top-side substrate being disposed on an observer side of the bottom-side substrate, the liquid crystal layer being provided between the bottom-side substrate and the top-side substrate, and the electrode pair being formed on one of the bottom-side substrate and the top-side substrate and generating a transverse electrical field in the liquid crystal layer; a first polarizing plate disposed on an observer side of the liquid crystal cell; a first phase difference plate disposed between the liquid crystal layer and the first polarizing plate and having an in-plane retardation R1; a second polarizing plate disposed on a back surface side of the liquid crystal cell; a second phase difference plate disposed between the second polarizing plate and the liquid crystal layer and having an in-plane retardation R2; a third phase difference plate disposed between the liquid crystal layer and the first polarizing plate; and a fourth phase difference plate disposed between the second polarizing plate and the liquid crystal layer, wherein the liquid crystal layer includes a nematic liquid crystal and has a homogeneous alignment when no electrical field is applied, and nd is greater than or equal to 360 nm and less than or equal to 490 nm, where n represents a birefringence of the nematic liquid crystal and d represents a thickness of the liquid crystal layer, the in-plane retardation R1 of the first phase difference plate is greater than or equal to 100 nm and less than or equal to 160 nm, a thickness direction retardation of at least one of the first phase difference plate, the second phase difference plate, the third phase difference plate, and the fourth phase difference plate has a negative value, and a slow axis of the first phase difference plate and a slow axis of the second phase difference plate are substantially parallel to each other and substantially orthogonal to an azimuthal direction of a director of the nematic liquid crystal in the homogeneous alignment, wherein the third phase difference plate is disposed between the first phase difference plate and the first polarizing plate.
2. The liquid crystal display panel according to claim 1, wherein the third phase difference plate is disposed between the first phase difference plate and the liquid crystal layer.
3. The liquid crystal display panel according to claim 1, wherein the fourth phase difference plate is disposed between the second phase difference plate and the second polarizing plate.
4. The liquid crystal display panel according to claim 1, wherein the fourth phase difference plate is disposed between the second phase difference plate and the liquid crystal layer.
5. The liquid crystal display panel according to claim 1, wherein the thickness direction retardation of the third phase difference plate and the thickness direction retardation of the fourth phase difference plate are substantially equal.
6. The liquid crystal display panel according to claim 3, wherein a sum of Rth1+Rth2+Rth3+Rth4 is smaller than the nd of the liquid crystal layer, where Rth1 represents a thickness direction retardation of the first phase difference plate, Rth2 represents a thickness direction retardation of the second phase difference plate, Rth3 represents a thickness direction retardation of the third phase difference plate, and Rth4 represents a thickness direction retardation of the fourth phase difference plate.
7. The liquid crystal display panel according to claim 1, wherein a sum of Rth1+Rth2+Rth3+Rth4 is substantially zero, where Rth1 represents a thickness direction retardation of the first phase difference plate, Rth2 represents a thickness direction retardation of the second phase difference plate, Rth3 represents a thickness direction retardation of the third phase difference plate, and Rth4 represents a thickness direction retardation of the fourth phase difference plate.
8. The liquid crystal display panel according to claim 1, wherein at least one of the first phase difference plate, the second phase difference plate, the third phase difference plate, and the fourth phase difference plate is a phase difference plate having a negative thickness direction retardation and having a dual-axis refractive index ellipsoid.
9. The liquid crystal display panel according to claim 1, wherein the third phase difference plate has an in-plane retardation R3, the fourth phase difference plate has an in-plane retardation R4, the in-plane retardation R3 of the third phase difference plate and the in-plane retardation R4 of the fourth phase difference plate are substantially equal to one another, and a slow axis of the third phase difference plate and a slow axis of the fourth phase difference plate are substantially orthogonal to each other.
10. The liquid crystal display panel according to claim 1, wherein an absorption axis of the first polarizing plate and the slow axis of the third phase difference plate are substantially parallel to each other, and an absorption axis of the second polarizing plate and a slow axis of the fourth phase difference plate are substantially parallel to each other.
11. The liquid crystal display panel according to claim 1, wherein at least one of the third phase difference plate and the fourth phase difference plate is a positive C plate.
12. The liquid crystal display panel according to claim 1, wherein the in-plane retardation R3 of the third phase difference plate and the in-plane retardation R4 of the fourth phase difference plate are substantially zero.
13. A liquid crystal display panel comprising: a liquid crystal cell including a bottom-side substrate, a top-side substrate, a liquid crystal layer, and an electrode pair, the top-side substrate being disposed on an observer side of the bottom-side substrate, the liquid crystal layer being provided between the bottom-side substrate and the top-side substrate, and the electrode pair being formed on one of the bottom-side substrate and the top-side substrate and generating a transverse electrical field in the liquid crystal layer; a first polarizing plate disposed on an observer side of the liquid crystal cell; a first phase difference plate disposed between the liquid crystal layer and the first polarizing plate and having an in-plane retardation R1; a second polarizing plate disposed on a back surface side of the liquid crystal cell; a second phase difference plate disposed between the second polarizing plate and the liquid crystal layer and having an in-plane retardation R2; a third phase difference plate disposed between the liquid crystal layer and the first polarizing plate; and a fourth phase difference plate disposed between the second polarizing plate and the liquid crystal layer, wherein the liquid crystal layer includes a nematic liquid crystal and has a homogeneous alignment when no electrical field is applied, and nd is greater than or equal to 360 nm and less than or equal to 490 nm, where n represents a birefringence of the nematic liquid crystal and d represents a thickness of the liquid crystal layer, the in-plane retardation R1 of the first phase difference plate is greater than or equal to 100 nm and less than or equal to 160 nm, a thickness direction retardation of at least one of the first phase difference plate, the second phase difference plate, the third phase difference plate, and the fourth phase difference plate has a negative value, and a slow axis of the first phase difference plate and a slow axis of the second phase difference plate are substantially parallel to each other and substantially orthogonal to an azimuthal direction of a director of the nematic liquid crystal in the homogeneous alignment, wherein the fourth phase difference plate is disposed between the second phase difference plate and the liquid crystal layer.
14. The liquid crystal display panel according to claim 13, wherein the third phase difference plate is disposed between the first phase difference plate and the first polarizing plate.
15. The liquid crystal display panel according to claim 13, wherein the third phase difference plate is disposed between the first phase difference plate and the liquid crystal layer.
16. The liquid crystal display panel according to claim 13, wherein the fourth phase difference plate is disposed between the second phase difference plate and the second polarizing plate.
17. The liquid crystal display panel according to claim 13, wherein the thickness direction retardation of the third phase difference plate and the thickness direction retardation of the fourth phase difference plate are substantially equal.
18. The liquid crystal display panel according to claim 13, wherein a sum of Rth1+Rth2+Rth3+Rth4 is smaller than the nd of the liquid crystal layer, where Rth1 represents a thickness direction retardation of the first phase difference plate, Rth2 represents a thickness direction retardation of the second phase difference plate, Rth3 represents a thickness direction retardation of the third phase difference plate, and Rth4 represents a thickness direction retardation of the fourth phase difference plate.
19. The liquid crystal display panel according to claim 13, wherein a sum of Rth1+Rth2+Rth3+Rth4 is substantially zero, where Rth1 represents a thickness direction retardation of the first phase difference plate, Rth2 represents a thickness direction retardation of the second phase difference plate, Rth3 represents a thickness direction retardation of the third phase difference plate, and Rth4 represents a thickness direction retardation of the fourth phase difference plate.
20. The liquid crystal display panel according to claim 13, wherein at least one of the first phase difference plate, the second phase difference plate, the third phase difference plate, and the fourth phase difference plate is a phase difference plate having a negative thickness direction retardation and having a dual-axis refractive index ellipsoid.
21. The liquid crystal display panel according to claim 13, wherein the third phase difference plate has an in-plane retardation R3, the fourth phase difference plate has an in-plane retardation R4, the in-plane retardation R3 of the third phase difference plate and the in-plane retardation R4 of the fourth phase difference plate are substantially equal to one another, and a slow axis of the third phase difference plate and a slow axis of the fourth phase difference plate are substantially orthogonal to each other.
22. The liquid crystal display panel according to claim 13, wherein an absorption axis of the first polarizing plate and the slow axis of the third phase difference plate are substantially parallel to each other, and an absorption axis of the second polarizing plate and a slow axis of the fourth phase difference plate are substantially parallel to each other.
23. The liquid crystal display panel according to claim 13, wherein at least one of the third phase difference plate and the fourth phase difference plate is a positive C plate.
24. The liquid crystal display panel according to claim 13, wherein the in-plane retardation R3 of the third phase difference plate and the in-plane retardation R4 of the fourth phase difference plate are substantially zero.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DESCRIPTION OF EMBODIMENT
(92) A liquid crystal display panel according to embodiments (including first and second embodiments) of the present invention includes: a liquid crystal cell, the liquid crystal cell including a bottom-side substrate (a back surface-side substrate disposed on a backlight-side substrate, such as a TFT substrate), a top-side substrate (an observer-side substrate, such as a color filter substrate), a liquid crystal layer provided between the bottom-side substrate and the top-side substrate, and an electrode pair formed on one of the bottom-side substrate and the top-side substrate and generating a transverse electrical field in the liquid crystal layer; a first polarizing plate disposed on the observer side of the liquid crystal cell; a first phase difference plate disposed between the liquid crystal layer and the first polarizing plate; a second polarizing plate disposed on the back surface side of the liquid crystal cell; and a second phase difference plate disposed between the second polarizing plate and the liquid crystal layer. The following will describe a liquid crystal display panel according to embodiments of the present invention using a liquid crystal display panel in which the bottom-side substrate is a TFT substrate and the bottom-side substrate includes the electrode pair that generates a transverse electrical field in the liquid crystal layer as an example. However, the top-side substrate may be a TFT substrate and the top-side substrate may include the electrode pair that generates a transverse electrical field in the liquid crystal layer. The liquid crystal display panel according to embodiments of the present invention is a liquid crystal display panel having a transverse electrical field mode, such as an in-plane switching mode or a fringe field switching mode.
(93) The liquid crystal layer includes nematic liquid crystals, and has a homogeneous alignment when no electrical field is applied. Here, homogeneous alignment includes an alignment in which pretilt directions, defined by an alignment film of the bottom-side substrate and an alignment film of the top-side substrate provided in contact with the liquid crystal layer, are parallel to each other, and an alignment in which the pretilt directions are antiparallel to each other. The liquid crystal layer may include nematic liquid crystals having negative dielectric anisotropy, or nematic liquid crystals having positive dielectric anisotropy.
(94) In a case where n represents a birefringence of the nematic liquid crystals and d represents a thickness of the liquid crystal layer, nd is greater than or equal to 360 nm and less than or equal to 490 nm. An in-plane retardation R1 of the first phase difference plate is greater than or equal to 100 nm and less than or equal to 160 nm. A slow axis of the first phase difference plate and a slow axis of the second phase difference plate are substantially parallel to each other and substantially orthogonal to an azimuthal direction of a director of the nematic liquid crystals in the homogeneous alignment.
(95) Typically, the first phase difference plate is a quarter wave plate (/4 plate). Note that 550 nm is used for the wavelength . This is because 550 nm, which has the highest visibility, is typically used for the wavelength for design purposes.
(96) In the liquid crystal display panel according to the first embodiment, an in-plane retardation R2 of the second phase difference plate is greater than or equal to 200 nm and less than or equal to 360 nm. Typically, the second phase difference plate is a half wave plate (/2 plate). A half wave plate rotates the polarization direction of linear polarized light having a polarization direction that forms an angle with the slow axis of the slow axis thereof by 2. As disclosed in PTL 1, when a quarter wave plate (/4 plate) is used as the second phase difference plate, reflection of the light from the backlight incident on the liquid crystal panel is suppressed, and thus the reflected light cannot be reused by causing the light reflected toward the backlight to be reflected back toward the liquid crystal display panel. However, when a half wave plate (/2 plate) is used as the second phase difference plate, and is disposed such that, for example, the polarization direction of linear polarized light passing through the second polarizing plate is 45 relative to the slow axis of the half wave plate, the polarization direction of the linear polarized light (polarization plane) simply rotates by 90, and thus the reflected light can be reused.
(97) The in-plane retardation nd of the liquid crystal layer is typically a 3/4 wave (3/4=412.5 nm), and is equal to a sum of R1+R2 of the in-plane retardation R1 of the first phase difference plate (typically, /4=137.5 nm) and the in-plane retardation R2 of the second phase difference plate (typically, /2=275.0 nm). The first phase difference plate and the second phase difference plate are disposed such that the slow axes thereof are substantially parallel to each other and substantially orthogonal to an azimuthal direction of a director of the nematic liquid crystals (this corresponds to the slow axis of the liquid crystal layer) in the homogeneous alignment. Such a configuration enables a good black display when no voltage is applied (NB mode). The slow axes of the first phase difference plate and the second phase difference plate are substantially orthogonal to the slow axis of the liquid crystal layer when no voltage is applied, and thus the retardations thereof cancel out. Thus, in a case where nd and R1+R2 are equal, nd and R1+R2 cancel each other out in a state where no voltage is applied to the liquid crystal layer, and the in-plane retardation becomes substantially zero. In other words, a good black display when observed from a forward viewing angle can be achieved.
(98) In-plane retardation (in-plane phase difference) refers to a retardation (phase difference) with respect to two linear polarized lights orthogonal to each other and incident orthogonally on phase difference layer (here, the liquid crystal layer or a phase difference plate). In a case where d is the thickness of the phase difference layer, ns and ny are each an in-plane principle refractive index, and nz is a principle refractive index in the normal direction, the in-plane retardation is defined as the absolute value of (nxny)d(|(nxny)d|). ( indicates multiplication in the present specification.) Using ns and nf, the in-plane retardation can also be defined as (nsnf)d. Here, ns is the greater of the in-plane principle refractive indices nx and ny, and nf is the smaller of the in-plane principle refractive indices nx and ny. As opposed to this, the thickness direction retardation is defined as ((nx+ny)/2nz)d. The thickness direction retardations of the liquid crystal layer and the phase difference plates will be discussed mainly in the second embodiment.
(99) Note that in the present specification, the slow axis of a phase difference layer (here, the liquid crystal layer or a phase difference plate) is an in-plane slow axis unless otherwise specified.
(100) As indicated by the results of simulations according to the first embodiment, described later, reflection of light incident on the liquid crystal display panel from the observer side can be suppressed and a display having a high contrast ratio can be achieved even without the above-described typical configuration, as long as the nd of the liquid crystal layer is greater than or equal to 360 nm and less than or equal to 490 nm, the in-plane retardation R1 of the first phase difference plate is greater than or equal to 100 nm and less than or equal to 160 nm, and the in-plane retardation R2 of the second phase difference plate is greater than or equal to 200 nm and less than or equal to 360 nm.
(101) Furthermore, the pixel structure in the liquid crystal display panel according to the first embodiment of the present invention may have a region in which the director azimuthal direction, the azimuthal direction of the transverse electrical field, and the azimuthal directions of the slow axes of the first and second phase difference plates satisfy a condition (1) or (2) below. Note that pixel structure refers to the structure of the liquid crystal display panel defined by the outer edges of the pixels when the pixels are viewed from the normal direction of the display surface of the liquid crystal display panel.
(102) Condition (1): the direction in which the nematic liquid crystal director is rotated by the transverse electrical field at or near the bottom-side substrate is leftward, and the light passing through the first phase difference plate from the observer side is leftward circular polarized light or leftward elliptical polarized light.
(103) Condition (2): the direction in which the nematic liquid crystal director is rotated by the transverse electrical field at or near the bottom-side substrate is rightward, and the light passing through the first phase difference plate from the observer side is rightward circular polarized light or rightward elliptical polarized light.
(104) As indicated by the results of simulations according to the first embodiment, described later, when the director azimuthal direction, the azimuthal direction of the transverse electrical field, and the azimuthal directions of the slow axes of the first and second phase difference plates are set to satisfy the condition (1) or (2), the viewing angle dependence of properties (the relationship between the input gray scale and the output gray scale) can be improved. This effect was not anticipated by the inventors, and was first discovered through simulations.
(105) Although the effects of a liquid crystal display panel in which the overall pixel openings satisfy the condition (1) or (2) will be described later with reference to examples, the effect of improving the viewing angle dependence of the properties can be achieved even in a case where the overall pixel openings do not satisfy the condition (1) or (2). When the dielectric anisotropy of nematic liquid crystals is negative, it is preferable that the surface area ratio of the region satisfying the condition (1) or (2) that occupies the pixel openings be greater than or equal to 38%, for example. On the other hand, when the dielectric anisotropy of nematic liquid crystals is positive, it is preferable that the surface area ratio of the stated region that occupies the pixel openings be greater than or equal to 45%, for example. In the present specification, a part in a pixel through which light contributing to the display is transmitted in particular is referred to as a pixel opening. For example, in a case where the edge portions of pixel electrodes are shielded by a black matrix, the openings in the black matrix define the pixel openings.
(106) A transverse electrical field mode liquid crystal display panel having two or more liquid crystal domains of different alignment directions in a single pixel (a so-called multi-domain structure) is known. In such a pixel, the viewing angle dependence of the properties can be improved even in a case where only a region corresponding to some of the liquid crystal domains satisfies the condition (1) or (2).
(107) A phase difference plate having regions where the azimuthal direction of the slow axis is different (also referred to as a patterned phase difference plate) is known as well. When a patterned phase difference plate is used, the viewing angle dependence of the properties can be improved even in a case where only some regions of the pixel openings satisfy the condition (1) or (2). Furthermore, a configuration in which regions of some or all of the pixel openings satisfy the condition (1) or (2) can also be realized by combining a patterned phase difference plate and pixels having a multi-domain structure. Note that the patterned phase difference plate is sometimes formed within the liquid crystal cell.
(108) In the liquid crystal display panel according to the second embodiment, the thickness direction retardation of at least one of the first phase difference plate and the second phase difference plate has a negative value. When the thickness direction retardation of at least one of the first phase difference plate and the second phase difference plate has a negative value, the sum of the thickness direction retardations of the first phase difference plate, the second phase difference plate, and the liquid crystal layer decreases. When the absolute value of the sum of the thickness direction retardations is low, a good black display when no voltage is applied can be achieved when observed from oblique viewing angles. This effect was not anticipated by the inventors, and was first discovered through simulations.
(109) The liquid crystal display panel according to the second embodiment may include a third phase difference plate disposed between the first phase difference plate and the first polarizing plate, and a fourth phase difference plate disposed between the second phase difference plate and the second polarizing plate. In this case, the thickness direction retardation of at least one of the first phase difference plate, the second phase difference plate, the third phase difference plate, and the fourth phase difference plate has a negative value. When the thickness direction retardation of at least one of the first to fourth phase difference plates has a negative value, the sum of the thickness direction retardations of the first to fourth phase difference plates and the liquid crystal layer decreases. As described above, when the absolute value of the sum of the thickness direction retardations is low, a good black display when no voltage is applied can be achieved when observed from oblique viewing angles.
(110) The structure and features of a liquid crystal display panel according to embodiments of the present invention will be described below with reference to the drawings. Note that the embodiments of the present invention are not limited to this example of the liquid crystal display panel.
First Embodiment
(111) A configuration of a liquid crystal display panel 100 according to the first embodiment of the present invention will be described with reference to
(112) As illustrated in
(113) As illustrated in
(114) In the liquid crystal display panel 100, first, the viewing angle dependence of the properties can be improved by employing a configuration in which (1) the direction in which a nematic liquid crystal director is rotated by the transverse electrical field at or near the first substrate 10Sa is leftward, and the light passing through the first phase difference plate from the observer side is leftward circular polarized light or leftward elliptical polarized light, or (2) the direction in which the nematic liquid crystal director is rotated by the transverse electrical field at or near the first substrate 10Sa is rightward, and the light passing through the first phase difference plate from the observer side is rightward circular polarized light or rightward elliptical polarized light. This will be described first.
(115) Here, rightward circular polarized light and leftward circular polarized light are defined as follows. Circular polarized light in which the rotation direction of an electric vector of the circular polarized light rotates clockwise as viewed along the travel direction is referred to as rightward circular polarized light (or right handed circularly-polarized light), and in which the stated rotation direction rotates counter-clockwise as viewed along the travel direction is referred to as leftward circular polarized light (or left handed circularly-polarized light),
(116) The direction in which a nematic liquid crystal director is rotated by the transverse electrical field at or near the first substrate 10Sa is defined as the rotation direction, viewed from the observer side, in which the liquid crystal director is rotated by the transverse electrical field.
(117) The in-plane retardations of the liquid crystal layer 18, the first phase difference plate 32, and the second phase difference plate 34 are all assumed to be typical values. That is, in a case where the nd of the liquid crystal layer 18 is 3/4=412.5 nm, the in-plane retardation R1 of the first phase difference plate 32 is /4=137.5 nm, and the in-plane retardation R2 of the second phase difference plate 34 is/2=275.0 nm, nd=R1+R2 is satisfied. The birefringence n of the nematic liquid crystal material was 0.111, and the thickness d of the liquid crystal layer 18 was 3.716 m.
(118) Here, nematic liquid crystals having a negative dielectric anisotropy were used. The dielectric constant of the nematic liquid crystals was 3.2. Using nematic liquid crystals having a negative dielectric anisotropy has the following advantages. When a voltage is applied to the electrode pair for generating a transverse electrical field in the liquid crystal layer, vertical electrical field components are produced (e.g., at or near the edges of the electrode pair) in addition to the transverse electrical field (an electrical field in the horizontal direction, an electrical field parallel to the liquid crystal layer surface) in the liquid crystal layer. The molecules of nematic liquid crystals having positive dielectric anisotropy align in such a manner that the long axes of the molecules (parallel to the director) are parallel to the electrical field, and thus in regions of strong vertical electrical field components, the liquid crystal molecules stand up, and the retardation in the liquid crystal layer plane drops or becomes uneven. In contrast, the molecules of nematic liquid crystals having negative dielectric anisotropy align such that the long axes of the molecules are orthogonal to the electrical field, and thus the liquid crystal molecules stand up little even in regions of strong vertical electrical field components, maintaining an alignment parallel to the liquid crystal layer plane. Accordingly, using nematic liquid crystals having negative dielectric anisotropy improves the transmittance and the display quality.
(119) A width S of the openings 16a in the pixel electrodes 16 was set to 3.3 m, and a distance L between the openings 16a and the edges of the pixel electrodes 16 was set to 2.7 m. In other words, a slitted structure in which L+S is 6.0 m, and L/S is 2.7 m/3.3 m, i.e. 45/55, was used. The thickness of the dielectric layer 15 was set to 100 nm, and the relative dielectric constant was set to 6.
(120) Graphs of the viewing angle dependence of 7 properties were found, for various azimuth angles, through simulations of the configurations illustrated in Table 1 below (Examples 1-1 and 1-2, Comparative Examples 1-1 and 1-2). An LCDMaster 2-D (Shintech, Inc.) was used in the simulations. Table 1 also illustrates quality determinations for viewing angle dependences based on the results of the simulations. The viewing angle dependence was determined to be high (x) in a case where, at an input level of 0.5, an output level at a polar angle of 30 varied by greater than 10% relative to an output level at a polar angle of 0.
(121) TABLE-US-00001 TABLE 1 Example Example Comparative Comparative 1-1 1-2 Example 1-1 Example 1-2 Rotation direction Left Right Right Left of observer side circular polarized light Rotation direction Left Right Left Right of LC director when voltage is applied Viewing angle x x dependence of properties
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(123) The director of nematic liquid crystals having negative dielectric anisotropy (NnLC) (parallel to the long axes of the oval-shaped liquid crystal molecules) is aligned to form an angle of 5 with respect to a direction of the transverse electrical field (azimuth angle 0) when no voltage is applied, as indicated in
(124) The slow axis of the first phase difference plate 32 and the slow axis of the second phase difference plate 34 (azimuth angle 95) are arranged to be orthogonal to the liquid crystal director (azimuth angle 5), as illustrated in
(125) The absorption axis of the first polarizing plate 22 (azimuth angle 50) is arranged to form an angle of 45 with respect to the liquid crystal director (azimuth angle 5), as illustrated in
(126) The above-described angles depend on, for example, the precision of lamination carried out in the process of assembling the liquid crystal display panel, and may therefore vary from the design values. Error of approximately 10 is allowed for each of the angles. Thus, for example, two directions described as being substantially orthogonal in the present specification allows for error of 1 in each of the two directions, and thus means that the two directions form an angle of greater than or equal to 88 and less than or equal to 92. Error is also allowed for retardation (including in-plane retardations and thickness direction retardations). For example, the thickness of the liquid crystal layer, the retardations of the phase difference plates, and the like may have manufacturing variations. The error in in-plane retardation is approximately 3 nm. Accordingly, error of 3 nm from the design values is allowed for nd, R1, and R2. The error of the thickness direction retardations of the liquid crystal layer and the phase difference plates is approximately 10 nm. Accordingly, error of 10 nm from the design values of the thickness direction retardations of the liquid crystal layer and the phase difference plates is allowed. The same applies hereinafter.
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(128) The director of nematic liquid crystals having negative dielectric anisotropy (NnLC) is aligned to form an angle of 5 with respect to the direction of the transverse electrical field (azimuth angle 0) when no voltage is applied, as indicated in
(129) The slow axis of the first phase difference plate 32 and the slow axis of the second phase difference plate 34 (azimuth angle 85) are arranged orthogonal to the liquid crystal director (azimuth angle 5), as illustrated in
(130) The absorption axis of the first polarizing plate 22 (azimuth angle 50) is arranged to form an angle of 45 with respect to the liquid crystal director (azimuth angle 5), as illustrated in
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(132) The director of nematic liquid crystals having negative dielectric anisotropy (NnLC) is aligned to form an angle of 5 with respect to the direction of the transverse electrical field (azimuth angle 0) when no voltage is applied, as indicated in
(133) The slow axis of the first phase difference plate 32 and the slow axis of the second phase difference plate 34 (azimuth angle 95) are arranged orthogonal to the liquid crystal director (azimuth angle 5), as illustrated in
(134) The absorption axis of the first polarizing plate 22 (azimuth angle 40) is arranged to form an angle of 45 with respect to the liquid crystal director (azimuth angle 5), as illustrated in
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(136) The director of nematic liquid crystals having negative dielectric anisotropy (NnLC) is aligned to form an angle of 5 with respect to the direction of the transverse electrical field (azimuth angle 0) when no voltage is applied, as indicated in
(137) The slow axis of the first phase difference plate 32 and the slow axis of the second phase difference plate 34 (azimuth angle 85) are arranged orthogonal to the liquid crystal director (azimuth angle 5), as illustrated in
(138) The absorption axis of the first polarizing plate 22 (azimuth angle 40) is arranged to form an angle of 45 with respect to the liquid crystal director (azimuth angle 5), as illustrated in
(139)
(140) Looking at
(141) In contrast, looking at the viewing angle dependence of the properties of the liquid crystal display panel according to Comparative Example 1-1, illustrated in
(142) Next,
(143) Looking at
(144) In contrast, looking at the viewing angle dependence of the properties of the liquid crystal display panel according to Comparative Example 1-2, illustrated in
(145) Thus, it can be seen that using nematic liquid crystals having negative dielectric anisotropy makes it possible to obtain a liquid crystal display panel in which, depending on the combination of the rotation direction of circular polarized light and the rotation of the liquid crystal director (left-left or right-right), the viewing angle dependence of the properties is low at all azimuthal directions, as indicated by Example 1-1 and Example 1-2 in Table 1.
(146) Although the liquid crystal display panels according to Example 1-1 and Example 1-2 have overall pixel openings satisfying the condition (1) or (2), the effect of improving the viewing angle dependence of the properties can be achieved even the overall pixel openings do not satisfy the condition (1) or (2).
(147) For example,
(148) As can be seen from
(149) The effects of a simulation in which nematic liquid crystals having positive dielectric anisotropy (NpLC) are used will be described next. The basic configuration of the liquid crystal display panel is the same as in the above-described examples. The n of the nematic liquid crystals having positive dielectric anisotropy was 0.106, and the thickness d of the liquid crystal layer was 3.892 m. The dielectric constant of the nematic liquid crystals was +7.0.
(150) In a similar manner as described above, graphs of the viewing angle dependence of properties were found, for various azimuth angles, through simulations of the configurations illustrated in Table 2 below (Examples 2-1 and 2-2, Comparative Examples 2-1 and 2-2). Table 2 also illustrates quality determinations for viewing angle dependences based on the results of the simulations. The viewing angle dependence was determined to be high (x) in a case where, at an input level of 0.5, an output level at a polar angle of 30 varied by greater than 10% relative to an output level at a polar angle of 0.
(151) TABLE-US-00002 TABLE 2 Example Example Comparative Comparative 2-1 2-2 Example 2-1 Example 2-2 Rotation direction Right Left Left Right of observer side circular polarized light Rotation direction Right Left Right Left of LC director when voltage is applied Viewing angle x x dependence of properties
(152)
(153) The director of nematic liquid crystals having positive dielectric anisotropy (NpLC) (parallel to the long axes of the oval-shaped liquid crystal molecules) is aligned to form an angle of 85 with respect to the direction of the transverse electrical field (azimuth angle 0) when no voltage is applied, as indicated in
(154) The slow axis of the first phase difference plate 32 and the slow axis of the second phase difference plate 34 (azimuth angle 5) are arranged orthogonal to the liquid crystal director (azimuth angle 85), as illustrated in
(155) The absorption axis of the first polarizing plate 22 (azimuth angle 40) is arranged to form an angle of 45 with respect to the liquid crystal director (azimuth angle 85), as illustrated in
(156)
(157) The director of nematic liquid crystals having positive dielectric anisotropy (NpLC) is aligned to form an angle of 85 with respect to the direction of the transverse electrical field (azimuth angle 0) when no voltage is applied, as indicated in
(158) The slow axis of the first phase difference plate 32 and the slow axis of the second phase difference plate 34 (azimuth angle 5) are arranged orthogonal to the liquid crystal director (azimuth angle 85), as illustrated in
(159) The absorption axis of the first polarizing plate 22 (azimuth angle 40) is arranged to form an angle of 45 with respect to the liquid crystal director (azimuth angle 85), as illustrated in
(160)
(161) The director of nematic liquid crystals having positive dielectric anisotropy (NpLC) is aligned to form an angle of 85 with respect to the direction of the transverse electrical field (azimuth angle 0) when no voltage is applied, as indicated in
(162) The slow axis of the first phase difference plate 32 and the slow axis of the second phase difference plate 34 (azimuth angle 5) are arranged orthogonal to the liquid crystal director (azimuth angle 85), as illustrated in
(163) The absorption axis of the first polarizing plate 22 (azimuth angle 50=130) is arranged to form an angle of 45 with respect to the liquid crystal director (azimuth angle 85), as illustrated in
(164)
(165) The director of nematic liquid crystals having positive dielectric anisotropy (NpLC) is aligned to form an angle of 85 with respect to the direction of the transverse electrical field (azimuth angle 0) when no voltage is applied, as indicated in
(166) The slow axis of the first phase difference plate 32 and the slow axis of the second phase difference plate 34 (azimuth angle 5) are arranged orthogonal to the liquid crystal director (azimuth angle 85), as illustrated in
(167) The absorption axis of the first polarizing plate 22 (azimuth angle 50=130) is arranged to form an angle of 45 with respect to the liquid crystal director (azimuth angle 85), as illustrated in
(168)
(169) Looking at
(170) In contrast, looking at the viewing angle dependence of the properties of the liquid crystal display panel according to Comparative Example 2-1, illustrated in
(171) Next,
(172) Looking at
(173) In contrast, looking at the viewing angle dependence of the properties of the liquid crystal display panel according to Comparative Example 2-2, illustrated in
(174) Thus, it can be seen that using nematic liquid crystals having positive dielectric anisotropy, too, makes it possible to obtain a liquid crystal display panel in which, depending on the combination of the rotation direction of circular polarized light and the rotation of the liquid crystal director (left-left or right-right), the viewing angle dependence of the properties is low at all azimuthal directions, as indicated by Example 2-1 and Example 2-2 in Table 1.
(175) Although the liquid crystal display panels according to Example 2-1 and Example 2-2 have overall pixel openings satisfying the condition (1) or (2), the effect of improving the viewing angle dependence of the properties can be achieved even in a case where the overall pixel openings do not satisfy the condition (1) or (2).
(176) For example,
(177) As can be seen from
(178) Results of investigating an allowable range for the nd of the liquid crystal layer 18 in a case where nematic liquid crystals having negative dielectric anisotropy are used will be described next with reference to
(179) Additionally, simulations were carried out for liquid crystal display panels having different L+S for the slitted structure of the pixel electrodes 16. Table 3 below illustrates the L+S and the L/S of the slitted structures used in the simulations.
(180) Simulations were also carried out for Comparative Examples 3-1 to 3-3 and 3-5, which are liquid crystal display panels having similar structures as those of Examples 3-1 to 3-3 and 3-5 but use past fringe field switching modes with the first and second phase difference plates omitted.
(181) TABLE-US-00003 TABLE 3 Example 3-1 Example 3-2 Example 3-3 Example 3-4 Example 3-5 First phase 137.5 nm 137.5 nm 137.5 nm 137.5 nm 137.5 nm difference plate R1 Liquid crystal 370 nm to 380 nm to 390 nm to 400 nm to 410 nm to layer nd 450 nm 460 nm 470 nm 480 nm 490 nm Second phase nd-R1 nd-R1 nd-R1 nd-R1 nd-R1 difference plate R2 L + S 4 m 5 m 6 m 7 m 8 m L/S 1.8 m/2.2 m 2.2 m/2.8 m 2.7 m/3.3 m 3.1 m/3.9 m 3.6 m/4.4 m 45/55 44/56 45/55 44/56 45/55
(182)
(183) By comparing
(184) From
(185) As will be described later, this result does not substantially depend on the L/S, the n, and an elastic constant of the liquid crystal material.
(186) Results of investigating an allowable range for the nd of the liquid crystal layer 18 in a case where nematic liquid crystals having positive dielectric anisotropy are used will be described next with reference to
(187) TABLE-US-00004 TABLE 4 Example 4-1 Example 4-2 Example 4-3 Example 4-4 Example 4-5 First phase 137.5 nm 137.5 nm 137.5 nm 137.5 nm 137.5 nm difference plate R1 Liquid crystal layer 360 nm to 370 nm to 370 nm to 380 nm to 400 nm to nd 440 nm 440 nm 450 nm 440 nm 440 nm Second phase nd-R1 nd-R1 nd-R1 nd-R1 nd-R1 difference plate R2 L + S 4 m 5 m 6 m 7 m 8 m L/S 1.8 m/2.2 m 2.2 m/2.8 m 2.7 m/3.3 m 3.1 m/3.9 m 3.6 m/4.4 m 45/55 44/56 45/55 44/56 45/55
(188)
(189) In comparing
(190) From
(191) Results of investigating an allowable range for the in-plane retardation R1 of the first phase difference plate 32 will be described next with reference to
(192) An antireflective effect is highest when the in-plane retardation R1 of the first phase difference plate 32 is 137.5 nm (/4). On the other hand, the transmittance rises when R1 deviates from these conditions. As can be seen from
(193) Results of investigating an allowable range for the in-plane retardation R2 of the second phase difference plate 34 will be described next with reference to
(194) Next,
(195) TABLE-US-00005 TABLE 5 Example 3-3 Example 3-3a Example 3-3b Example 3-3c Liquid 412.5 nm 412.5 nm 412.5 nm 412.5 nm crystal layer nd L + S 6 m 6 m 6 m 6 m L/S 2.7 m/ 3.3 m/2.7 m 3.0 m/3.0 m 2.5 m/3.5 m 3.3 m 55/45 50/50 42/58 45/55
(196) As can be seen from
(197) Next,
(198) TABLE-US-00006 TABLE 6 Example 4-3 Example 4-3a Example 4-3b Example 4-3c Liquid 412.5 nm 412.5 nm 412.5 nm 412.5 nm crystal layer nd L + S 6 m 6 m 6 m 6 m L/S 2.7 m/ 3.3 m/2.7 m 3.0 m/3.0 m 2.5 m/3.5 m 3.3 m 55/45 50/50 42/58 45/55
(199) As can be seen from
(200) Next, results of investigating the influence of the n of the liquid crystal material will be described with reference to
(201) As can be seen from
(202)
(203) A liquid crystal display panel according to embodiments of the present invention, using a liquid crystal display panel in which the bottom-side substrate is a TFT substrate and the bottom-side substrate includes the electrode pair that generates a transverse electrical field in the liquid crystal layer as an example, has been described in the foregoing embodiment. However, the top-side substrate may be a TFT substrate and the top-side substrate may include the electrode pair that generates a transverse electrical field in the liquid crystal layer. In the liquid crystal display panel according to embodiments of the present invention, the first phase difference plate and the first polarizing plate basically function as a circular polarizing plate, and thus light reflected by wires or the like in the TFT substrate is reduced. Accordingly, the display quality will not drop, even when a TFT substrate is used as the top-side substrate.
Second Embodiment
(204) A structure of a liquid crystal display panel according to a second embodiment of the present invention will be described below with reference to
(205) As illustrated schematically in
(206) In the liquid crystal display panel 100A according to the second embodiment, the thickness direction retardation of at least one of the first phase difference plate 32a and the second phase difference plate 34a has a negative value. When the thickness direction retardation of at least one of the first phase difference plate 32a and the second phase difference plate 34a has a negative value, the sum of the thickness direction retardations of the first phase difference plate 32a, the second phase difference plate 34a, and the liquid crystal layer 18 decreases. It was found that when the absolute value of the sum of the thickness direction retardations was low, a good black display when no voltage was applied can be achieved when observed from oblique viewing angles. The inventors of the present invention first confirmed this effect after carrying out many simulations.
(207) The liquid crystal display panel according to the present embodiment is not limited to the liquid crystal display panel 100A illustrated as an example in
(208) As illustrated schematically in
(209) When the thickness direction retardation of at least one of the first phase difference plate 32a, the second phase difference plate 34a, the third phase difference plate 32b, and the fourth phase difference plate 34b has a negative value, the sum of the thickness direction retardations of the first to fourth phase difference plates 32a, 34a, 32b, and 34b and the liquid crystal layer 18 decreases. When the absolute value of the sum of the thickness direction retardations is low, a good black display when no voltage is applied can be achieved when observed from oblique viewing angles.
(210) The first and second phase difference plates 32a and 34a have in-plane retardations. The third phase difference plate 32b and the fourth phase difference plate 34b may each independently have in-plane retardations, or may not have in-plane retardations. In the present specification, a phase difference layer (a liquid crystal layer or a phase difference plate, for example) having an in-plane retardation means that the in-plane retardation of the phase difference layer is greater than 3 nm.
(211) In the liquid crystal display panel 100B, the third phase difference plate 32b is disposed between the first phase difference plate 32a and the first polarizing plate 22, and the fourth phase difference plate 34b is disposed between the second phase difference plate 34a and the second polarizing plate 24. The arrangement relationship of the first phase difference plate 32a and the third phase difference plate 32b, and the arrangement relationship of the second phase difference plate 34a and the fourth phase difference plate 34b, are not limited to the configurations described here. For example, as illustrated in
(212) The third phase difference plate 32b may be disposed between the first phase difference plate 32a and the liquid crystal cell 10, as in the liquid crystal display panels 100B1 and 100B3 schematically illustrated in
(213) As illustrated in
(214) As schematically illustrated in
(215) In the liquid crystal display panel 100C1, the thickness direction retardation of at least one of the first phase difference plate 32a, the second phase difference plate 34a, and the third phase difference plate 32b has a negative value. When the thickness direction retardation of at least one of the first phase difference plate 32a, the second phase difference plate 34a, and the third phase difference plate 32b has a negative value, the sum of the thickness direction retardations of the first to third phase difference plates 32a, 34a, and 32b and the liquid crystal layer 18 decreases. When the absolute value of the sum of the thickness direction retardations is low, a good black display when no voltage is applied can be achieved when observed from oblique viewing angles.
(216) As schematically illustrated in
(217) In the liquid crystal display panel 100C2, the thickness direction retardation of at least one of the first phase difference plate 32a, the second phase difference plate 34a, and the fourth phase difference plate 34b has a negative value. When the thickness direction retardation of at least one of the first phase difference plate 32a, the second phase difference plate 34a, and the fourth phase difference plate has a negative value, the sum of the thickness direction retardations of the first, second, and fourth phase difference plates 32a, 34a, and 34b and the liquid crystal layer 18 decreases. When the absolute value of the sum of the thickness direction retardations is low, a good black display when no voltage is applied can be achieved when observed from oblique viewing angles.
(218) Although not illustrated for the sake of simplicity, the arrangement relationship of the first phase difference plate 32a and the third phase difference plate 32b, and the arrangement relationship of the second phase difference plate 34a and the fourth phase difference plate 34b, may be reversed in the liquid crystal display panels 100C1 and 100C2 as well.
(219) In the liquid crystal display panels 100A, 100B, 100B1, 100B2, 100B3, 100C1, and 100C2 according to the present embodiment, the first to fourth phase difference plates 32a, 34a, 32b, and 34b are, for example, phase difference plates including drawn polymer films, phase difference plates in which a liquid crystalline material has a fixed alignment, thin plates formed from an inorganic material, or the like.
(220) The materials, manufacturing methods, and the like of the first and second polarizing plates 22 and 24 and the first to fourth phase difference plates 32a, 34a, 32b, and 34b are not particularly limited. For example, a plate obtained by adsorbing and aligning an anisotropic material such as an iodine complex having dichroism in a polyvinyl alcohol (PVA) film can be suitably used as the polarizing plate.
(221) In the liquid crystal display panel 100A according to the present embodiment, the first polarizing plate 22 and the first phase difference plate 32a generally function as a circular polarizing plate or an elliptical polarizing plate. The first polarizing plate 22 and the first phase difference plate 32a are affixed to each other with an adhesion layer (an adhesive layer) interposed therebetween, in some cases. The first phase difference plate 32a may include a plurality of phase difference layers. A support layer (protection layer) may additionally be affixed, as appropriate. The support layer (protection layer) improves, for example, the mechanical strength and resistance to moisture and heat of the polarizing plate and the phase difference plate. The support layer (protection layer) is a triacetyl cellulose (TAC) film or an acrylic resin-based film, for example. The in-plane retardation of the adhesion layer (adhesive layer) is less than or equal to approximately 3 nm, and the absolute value of the thickness direction retardation is less than or equal to approximately 10 nm. The in-plane retardation of the support layer (protection layer) is less than or equal to approximately 3 nm, and the absolute value of the thickness direction retardation is less than or equal to approximately 50 nm. The absolute value of the thickness direction retardation of a support layer (protection layer) in which the absolute value of the phase difference has been actively reduced (also referred to as a zero-phase difference support layer (protection layer) or a zero-phase difference film) is less than or equal to approximately 10 nm. Accordingly, the in-plane retardations and thickness direction retardations of the adhesion layer (adhesive layer) and the zero-phase difference support layer (protection layer) can be substantially ignored. It is difficult to ignore the thickness direction retardation of a support layer (protection layer) that is not a zero-phase difference support layer (protection layer), i.e. a support layer (protection layer) in which the absolute value of the thickness direction retardation is greater than approximately 10 nm, and thus such a layer may be handled as a phase difference plate or a phase difference layer in a phase difference plate. For example, the first phase difference plate 32a having a plurality of phase difference layers may include a support layer (protection layer) that is not a zero-phase difference support layer (protection layer) as one of the phase difference layers. Alternatively, the first phase difference plate 32a may be a support layer (protection layer) that is not a zero-phase difference support layer (protection layer).
(222) The second polarizing plate 24 and the second phase difference plate 34a may have a similar configuration. The second polarizing plate 24 and the second phase difference plate 34a can function as a linear polarizing plate or an elliptical polarizing plate.
(223) Likewise, in the liquid crystal display panels 100B, 100B1 to 100B3, 100C1, and 100C2 according to the present embodiment, the first polarizing plate 22, the first phase difference plate 32a, and the third phase difference plate 32b are sometimes affixed to each other with adhesion layers (adhesive layers) therebetween. The first phase difference plate 32a and the third phase difference plate 32b may each include a plurality of phase difference layers. A support layer (protection layer) may additionally be affixed, as appropriate. A similar configuration may apply to the second polarizing plate 24, the second phase difference plate 34a, and the fourth phase difference plate 34b.
(224) Phase difference plates (or phase difference layers) are given names according to various methods based on the optical anisotropy thereof. For example, a phase difference plate having a uniaxial refractive index ellipsoid may be divided into the following four types depending on the shape of the refractive index ellipsoid. In a case where nx and ny are principle refractive indices in a plane of a phase difference plate and nz is a principle refractive index in the normal direction, a phase difference plate satisfying the relationship of nx>ny=nz is referred to as a positive A plate, a phase difference plate satisfying the relationship of nx<ny=nz is referred to as a negative A plate, a phase difference plate satisfying the relationship of nx=ny<nz is referred to as a positive C plate, and a phase difference plate satisfying the relationship of nx=ny>nz is referred to as a negative C plate. These names and classifications are well-known to those of ordinary skill in the art. In these classifications, xyz axes are read instead as ABC axes, and a phase difference plate in which the optical axis is in-plane (i.e. an A axis direction or a B axis direction) is referred to as an A plate, whereas a phase difference plate in which the optical axis is in the normal direction (i.e. a C axis direction) is referred to as a C plate. Then, either positive or negative is categorized depending on the sign of the result of the refractive index anisotropy=extraordinary refractive indexordinary refractive index. In other words, positive denotes a case where the extraordinary refractive index is higher than the ordinary refractive index, and negative denotes a case where the extraordinary refractive index is smaller than the ordinary refractive index.
(225) For example, a phase difference film including rod-shaped liquid crystals having a horizontal alignment and a uniaxially-stretched resin material having positive intrinsic birefringence (polycarbonate or cycloolefin polymer, for example) can be given as examples of a phase difference plate (or phase difference layer) classified as a positive A plate. A phase difference film including disk-shaped liquid crystals having a horizontal alignment and a uniaxially-stretched resin material having negative intrinsic birefringence (polystyrene, for example) can be given as examples of a phase difference plate (or phase difference layer) classified as a negative A plate. A phase difference film including disk-shaped liquid crystals having a vertical alignment and a biaxially-stretched resin material having positive intrinsic birefringence (polycarbonate or cycloolefin polymer, for example) can be given as examples of a phase difference plate (or phase difference layer) classified as negative C plate. A phase difference film including rod-shaped liquid crystals having a vertical alignment and a biaxially-stretched resin material having negative intrinsic birefringence (polystyrene, for example) can be given as examples of a phase difference plate (or phase difference layer) classified as a positive C plate.
(226) The plates are not limited to the specific examples described above, and it is also possible to achieve spontaneous alignment in the film transport direction or the normal direction, and thereby achieve a phase difference, at the point in time when a film is formed in a typical method such as solvent casting or melt extrusion, without actively applying an alignment treatment or a stretching treatment. For example, in many cases, a triacetyl cellulose (TAC) film used as a protective film for a polarizing plate becomes a negative C plate at the point in time when the film is formed through solvent casting.
(227) As described earlier, the in-plane retardation is defined as the absolute value of (nxny)d, and the thickness direction retardation is defined as ((nx+ny)/2nz)d. According to these definitions, of the above-described four types of uniaxial phase difference plates, the negative A plate and the positive C plate have negative thickness direction retardations. The positive C plate does not have an in-plane retardation. Accordingly, in the liquid crystal display panel 100A according to the present embodiment, at least one of the first phase difference plate 32a and the second phase difference plate 34a having an in-plane retardation may be a negative A plate. Results of simulations of liquid crystal display panels according to Examples 7-1 to 7-3 will be described later, for example.
(228) In the liquid crystal display panels 100B and 100B1 to 100B3 according to the present embodiment, for example, at least one of the third phase difference plate 32b and the fourth phase difference plate 34b may be a negative A plate or a positive C plate. At least one of the first phase difference plate 32a and the second phase difference plate 34a having an in-plane retardation may be a negative A plate. Results of simulations of liquid crystal display panels according to Examples 7-4 to 7-8, 7-9A to 7-9C, and 7-9F to 7-9N will be described later, for example.
(229) Likewise, in the liquid crystal display panels 100C1 and 100C2 according to the present embodiment, for example, the third phase difference plate 32b or the fourth phase difference plate 34b may be a negative A plate or a positive C plate. At least one of the first phase difference plate 32a and the second phase difference plate 34a having an in-plane retardation may be a negative A plate. Results of simulations of liquid crystal display panels according to Examples 7-9D and 7-9E will be described later, for example.
(230) A phase difference plate having a negative thickness direction retardation is not limited to a uniaxial refractive index ellipsoid. A phase difference plate having a biaxial refractive index ellipsoid and having a negative thickness direction retardation can be used. A phase difference plate having a biaxial refractive index ellipsoid generally has an in-plane retardation, and thus at least one of the first phase difference plate 32a, the second phase difference plate 34a, the third phase difference plate 32b, and the fourth phase difference plate 34b may be a phase difference plate having a biaxial refractive index ellipsoid and a negative thickness direction retardation. Results of simulations of liquid crystal display panels according to Examples 7-10 to 7-29 will be described later, for example.
(231) NZ, which is defined as (nsnz)/(nsnf), is used as a parameter characterizing a biaxial phase difference plate. Here, ns represents a greater one of the in-plane principle refractive indices nx and ny (i.e., a refractive index with respect to an electrical field component oscillating in a direction parallel to an in-plane slow axis), whereas nf represents a smaller one of the in-plane principle refractive indices nx and ny (i.e., a refractive index with respect to an electrical field component oscillating in a direction parallel to an in-plane fast axis). NZ can be used for a uniaxial phase difference plate. For example, NZ of a positive A plate is 1, and NZ of a negative A plate is 0. For a C plate, in which the in-plane retardation is zero, the denominator of NZ is zero, and thus NZ is undefined. However, NZ of a positive C plate may be defined as , and NZ of a negative C plate as +, for the sake of convenience. There are cases where using NZ makes it possible to grasp the properties of a uniaxial phase difference plate and a biaxial phase difference plate in a unified way, which is convenient.
(232) With a uniaxial phase difference plate, error is allowed for the above-described relational expressions (equalities, in particular) of the principle refractive indices nx, ny, and nz. The allowable range for a uniaxial phase difference plate can be expressed using NZ. For example, a phase difference plate in which NZ is in a range from approximately 0.5 to 2.0 can be regarded as a positive A plate. A phase difference plate in which NZ is in a range from approximately 0.5 to 1.0 can be regarded as a negative A plate. A phase difference plate in which NZ is greater than approximately 5.0 can be regarded as a negative C plate. A phase difference plate in which NZ is less than approximately 4.0 can be regarded as a positive C plate.
(233) The liquid crystal layers 18 in the liquid crystal display panels 100A, 100B, 100B1 to 100B3, 100C1, and 100C2 according to the present embodiment include nematic liquid crystals, and have a homogeneous alignment when no electrical field is applied. In a case where n is birefringence of the nematic liquid crystals and d is a thickness of the liquid crystal layer, the in-plane retardation nd of the liquid crystal layer 18 is greater than or equal to 360 nm and less than or equal to 490 nm, and is typically 412.5 nm (3/4). The first phase difference plate 32a and the second phase difference plate 34a have in-plane retardations. The in-plane retardation R1 of the first phase difference plate 32a is greater than or equal to 100 nm and less than or equal to 160 nm, and is typically 137.5 nm (/4). The slow axis of the first phase difference plate 32a and the slow axis of the second phase difference plate 34a are substantially parallel to each other, and the azimuthal directions of the nematic liquid crystal directors in the homogeneous alignment are substantially orthogonal to each other. A preferred configuration for the in-plane retardations of the liquid crystal layer 18 and the first and second phase difference plates 32a and 34a in the liquid crystal display panel according to the present embodiment may be the same as in the liquid crystal display panel according to the first embodiment.
(234) Simulation results for the examples and reference examples will be described hereinafter.
(235) Only the black display state, i.e. the transmittance when no voltage is applied, was examined in the simulations of the liquid crystal display panels according to the present embodiment. No voltage is applied during a black display, and thus the black display performance depends neither on whether a negative-working or positive-working liquid crystal material is used, nor on the direction in which the liquid crystal molecules rotate due to the transverse electrical field. However, employing the preferred conditions according to the first embodiment for the sign of the dielectric anisotropy of the nematic liquid crystals and the direction in which the liquid crystal molecules rotate due to the transverse electrical field makes it possible to achieve not only a good black display but also a display with a low viewing angle dependence of the properties.
(236) The black display performance does not depend on the direction in which the slits of the pixel electrodes extend. Although an example in which the slits in the pixel electrodes extend parallel to the vertical direction of the drawing surface in the cross-sectional view is given here (see
(237) As described in the first embodiment, the azimuth angle corresponds to 0 in the direction of three o'clock on the face of a clock (x axis), and the counter-clockwise direction is defined as positive. The x axis direction is orthogonal to the direction in which the pixel electrodes extend.
(238) Unless otherwise specified, the phase differences of the liquid crystal layer and the phase difference plates indicate values at a wavelength of 550 nm.
(239) First, the results of simulations for the liquid crystal display panels according to Examples 7-1 to 7-3 and Reference Example 7-1 will be described. The liquid crystal display panels according to Examples 7-1 to 7-3 have the same configuration as the liquid crystal display panel 100A illustrated in
(240) Table 7 illustrates design values of the liquid crystal display panels according to Reference Example 7-1 and Examples 7-1 to 7-3 (values used in the simulations) and transmittances calculated at a wavelength of 550 nm.
(241) TABLE-US-00007 TABLE 7 Reference Example Example Example Example 7-1 7-1 7-2 7-3 First polarizing plate Absorption axis 40.0 40.0 40.0 40.0 (deg) Third phase difference Slow axis (deg) plate R3 (nm) Rth3 (nm) NZ First phase difference Slow axis (deg) 5.0 5.0 5.0 5.0 plate R1 (nm) 137.5 137.5 137.5 137.5 Rth1 (nm) 68.75 68.75 68.75 68.75 NZ 1.00 0.00 1.00 0.00 Liquid crystal layer nd (nm) 412.5 412.5 412.5 412.5 RthLC (nm) 206.3 206.3 206.3 206.3 Alignment 85.0 85.0 85.0 85.0 (deg) Second phase Slow axis (deg) 5.0 5.0 5.0 5.0 difference plate R2 (nm) 275.0 275.0 275.0 275.0 Rth2 (nm) 137.50 137.50 137.50 137.50 NZ 1.00 0.00 0.00 1.00 Fourth phase Slow axis (deg) difference plate R4 (nm) Rth4 (nm) NZ Second polarizing Absorption axis 130.0 130.0 130.0 130.0 plate (deg) Sum of thickness RthS (nm) 412.5 0.0 137.5 275.0 direction retardations Black display Maximum 0.257 0.016 0.065 0.159 transmittance Average 0.130 0.008 0.029 0.090 (Polar angle 60)
(242) In the liquid crystal display panel according to Example 7-1, both the first phase difference plate 32a and the second phase difference plate 34a serve as negative A plates. In the liquid crystal display panel according to Example 7-2, the first phase difference plate 32a is a positive A plate and the second phase difference plate 34a serves as a negative A plate. In the liquid crystal display panel according to Example 7-3, the first phase difference plate 32a is a negative A plate and the second phase difference plate 34a serves as a positive A plate.
(243)
(244) Table 7 illustrates, for the black display transmittances of the liquid crystal display panels, both a maximum value of the values at a polar angle of 60 and an average value of the values at a polar angle of 60. As these values decrease, a better black display, having little light leakage when viewed from an oblique viewing angle, can be achieved.
(245) A liquid crystal simulator (LCD master, manufactured by Shintech) was used in the simulations. The orthogonal transmittance of the polarizing layers used in the simulations was 0.0015%, and the parallel transmittance was 39.04%. The calculated values are obtained when a wavelength is 550 nm.
(246) As illustrated in Table 7, the design values of the liquid crystal display panels according to Reference Example 7-1 and Examples 7-1 to 7-3 are the same as for the liquid crystal display panel according to the above-described Example 2-1 of the first embodiment, except for the thickness direction retardations of the liquid crystal layer 18, the first phase difference plate 32a, and the second phase difference plate 34a. That is, in a case where an in-plane retardation nd of the liquid crystal layer 18 is 3/4=412.5 nm, an in-plane retardation R1 of the first phase difference plate 32a is /4=137.5 nm, and an in-plane retardation R2 of the second phase difference plate 34a is /2=275.0 nm, nd=R1+R2 is satisfied. The nematic liquid crystal director is aligned to form an azimuth angle of 85. The slow axis of the first phase difference plate 32a and the slow axis of the second phase difference plate 34a (azimuth angle 5) are arranged orthogonal to the liquid crystal director (azimuth angle 85). nd and R1+R2 cancel each other out, and the in-plane retardation becomes substantially zero, and thus when observed from a forward viewing angle, a good black display is achieved when no voltage is applied.
(247) The absorption axis of the first polarizing plate 22 (azimuth angle 40) is arranged to form an angle of 45 with respect to the liquid crystal director (azimuth angle 85). The absorption axis of the second polarizing plate 24 (azimuth angle 130) is arranged to form an angle of 45 with respect to the liquid crystal director (azimuth angle 85). The absorption axis of the first polarizing plate 22 and the absorption axis of the second polarizing plate 24 are orthogonal to each other (a cross Nicol arrangement).
(248) In the simulations, the birefringence n of the nematic liquid crystal material was 0.111, and the thickness d of the liquid crystal layer 18 was 3.716 m. A width S of the openings 16a in the pixel electrodes 16 was 3.3 m, and a distance L between the openings 16a and the edges of the pixel electrodes 16 was 2.7 m. The thickness of the dielectric layer 15 was set to 100 nm, and the relative dielectric constant was set to 6. In Examples 7-4 to 7-29 described below, a similar configuration will be used.
(249) The in-plane retardations of the liquid crystal layer 18 and the first and second phase difference plates 32a and 34a preferably satisfy the relationship n=R1+R2, as with the liquid crystal display panels according to Examples 7-1 to 7-3. In this case, a good black display is achieved and the contrast of bright areas is improved when observed from a forward viewing angle. Additionally, as described in the first embodiment, in a case where the in-plane retardation R1 of the first phase difference plate 32a is greater than or equal to 100 nm and less than or equal to 160 nm, and the in-plane retardation R2 of the second phase difference plate 34a is greater than or equal to 200 nm and less than or equal to 360 nm, the reflection of light incident on the liquid crystal display panel from the observer side can be suppressed, and a display having a high contrast ratio when viewed from a forward viewing angle can be achieved.
(250) An angle formed by the absorption axis of the first polarizing plate 22 and the slow axis of the first phase difference plate 32a is typically substantially 45 or substantially 135, as in the liquid crystal display panels according to Examples 7-1 to 7-3. However, the present embodiment is not limited thereto. The ellipticity of an elliptical polarizing plate is generally determined by the angle formed by the absorption axis of the polarizing plate and the slow axis of the phase difference plate constituting the elliptical polarizing plate, and by the in-plane retardation of the phase difference plate. There are normally multiple combinations of angles formed by the absorption axis of the polarizing plate and the slow axis of the phase difference plate, and in-plane retardations of the phase difference plate, that give the same ellipticity. Accordingly, the angle formed by the absorption axis of the first polarizing plate 22 and the slow axis of the first phase difference plate 32a, and the in-plane retardation R1 of the first phase difference plate 32a, may be adjusted as appropriate to obtain the desired ellipticity.
(251) An angle formed by the absorption axis of the second polarizing plate 24 and the slow axis of the second phase difference plate 34a is typically substantially 450 or substantially 135, as in the liquid crystal display panels according to Examples 7-1 to 7-3. However, like the first polarizing plate 22 and the first phase difference plate 32a, the present embodiment is not limited thereto.
(252) Table 7 also illustrates a sum RthS of the thickness direction retardations. The sum RthS of the thickness direction retardations is the total value including a thickness direction retardation RthLC of the liquid crystal layer 18, a thickness direction retardation Rth1 of the first phase difference plate 32, and a thickness direction retardation Rth2 of the second phase difference plate 34 (RthS=RthLC+Rth1+Rth2).
(253) For an A plate, a relationship in which the absolute value of the thickness direction retardation is of the in-plane retardation is satisfied. A liquid crystal layer having a homogeneous alignment is also classified as an A plate. The thickness direction retardation is not normally considered for a liquid crystal layer having a homogeneous alignment, but can be calculated, based on the definition of the thickness direction retardation. In the liquid crystal display panel according to Reference Example 7-1, the values of the thickness direction retardations Rth1 and Rth2 of the first and second phase difference plates 32a and 34a are both positive, and thus in combination with the relationship nd=R1+R2, the sum RthS of the thickness direction retardations is equal to the nd of the liquid crystal layer 18. In contrast, in the liquid crystal display panels according to Examples 7-1 to 7-3, at least one of the values of the thickness direction retardations Rth1 and Rth2 of the first and second phase difference plates 32a and 34a is negative, and thus the sum RthS of the thickness direction retardations is smaller than the nd of the liquid crystal layer 18.
(254) As can be seen from
(255) Considering the simulation results for Examples 7-4 to 7-29, described later, along with Examples 7-1 to 7-3, it was found that a better black display was achieved as the absolute value of the sum of the thickness direction retardations decreases. The method for reducing the absolute value of the sum of the thickness direction retardations is not limited to providing a negative A plate as a phase difference plate.
(256) The simulation results for Examples 7-4 to 7-29 will be described next. The liquid crystal display panels according to Examples 7-4 to 7-8, 7-9A to 7-9C, and 7-10 to 7-29 have the same configuration as the liquid crystal display panel 100B illustrated in
(257) The design values of the liquid crystal display panels according to Examples 7-4 to 7-29 are the same as the design values of the liquid crystal display panel according to Reference Example 7-1, except for the third phase difference plate 32b and the fourth phase difference plate 34b. In the liquid crystal display panels according to Examples 7-4 to 7-29, the first phase difference plate 32a and the second phase difference plate 34a are positive A plates. In other words, the thickness direction retardations Rth1 and Rth2 of the first phase difference plate 32a and the second phase difference plate 34a are both positive values. In the liquid crystal display panels according to Examples 7-4 to 7-29 (except for Examples 7-9D and 7-9E), thickness direction retardations Rth3 and Rth4 of the third phase difference plate 32b and the fourth phase difference plate 34b both have negative values. In the liquid crystal display panels according to Examples 7-9D and 7-9E, the thickness direction retardation Rth3 of the third phase difference plate 32b or the thickness direction retardation Rth4 of the fourth phase difference plate 34b has a negative value. Of course, the liquid crystal display panel according to the present embodiment is not limited to the examples described here. In a liquid crystal display panel having the first to fourth phase difference plates 32a, 34a, 32b, and 34b, it is sufficient for the thickness direction retardation of at least one of the phase difference plates to have a negative value. In a liquid crystal display panel having the first phase difference plate 32a, the second phase difference plate 34a, and the third phase difference plate 32b or the fourth phase difference plate 34b, it is sufficient for the thickness direction retardation of at least one of the phase difference plates to have a negative value.
(258) The design values and black display transmittances of the liquid crystal display panels according to Examples 7-4 to 7-8 will be described next with reference to Table 8 and
(259) Like Table 7, Table 8 illustrates design values of the liquid crystal display panels according to Examples 7-4 to 7-8 (values used in the simulations) and black display transmittances (when no voltage is applied) calculated at a wavelength of 550 nm.
(260) TABLE-US-00008 TABLE 8 Example Example Example Example Example 7-4 7-5 7-6 7-7 7-8 First polarizing Absorption 40.0 40.0 40.0 40.0 40.0 plate axis (deg) Third phase Slow axis difference plate (deg) R3 (nm) 0.0 0.0 0.0 0.0 0.0 Rth3 (nm) 50.00 100.00 150.00 200.00 250.00 NZ First phase Slow axis 5.0 5.0 5.0 5.0 5.0 difference plate (deg) R1 (nm) 137.5 137.5 137.5 137.5 137.5 Rth1 (nm) 68.75 68.75 68.75 68.75 68.75 NZ 1.00 1.00 1.00 1.00 1.00 Liquid crystal nd (nm) 412.5 412.5 412.5 412.5 412.5 layer RthLC (nm) 206.3 206.3 206.3 206.3 206.3 Alignment 85.0 85.0 85.0 85.0 85.0 (deg) Second phase Slow axis 5.0 5.0 5.0 5.0 5.0 difference plate (deg) R2 (nm) 275.0 275.0 275.0 275.0 275.0 Rth2 (nm) 137.50 137.50 137.50 137.50 137.50 NZ 1.00 1.00 1.00 1.00 1.00 Fourth phase Slow axis difference plate (deg) R4 (nm) 0.0 0.0 0.0 0.0 0.0 Rth4 (nm) 50.00 100.00 150.00 200.00 250.00 NZ Second polarizing Absorption 130.0 130.0 130.0 130.0 130.0 plate axis (deg) Sum of thickness RthS (nm) 312.5 212.5 112.5 12.5 87.5 direction retardations Black display Maximum 0.181 0.109 0.056 0.040 0.049 transmittance Average 0.086 0.049 0.023 0.014 0.021 (Polar angle 60)
(261) The liquid crystal display panels according to Examples 7-4 to 7-8 have positive C plates as the third phase difference plate 32b and the fourth phase difference plate 34b. A C plate does not have in-plane retardation, and thus the slow axis and NZ are undefined.
(262) As illustrated in Table 8, in the liquid crystal display panels according to Examples 7-4 to 7-8, the thickness direction retardation Rth3 of the third phase difference plate 32b and the thickness direction retardation Rth4 of the fourth phase difference plate 34b have different values. Table 8 also illustrates the sum RthS of the thickness direction retardations. The sum RthS of the thickness direction retardations is the total value including the thickness direction retardation RthLC of the liquid crystal layer 18, the thickness direction retardation Rth1 of the first phase difference plate 32a, the thickness direction retardation Rth2 of the second phase difference plate 34s, the thickness direction retardation Rth3 of the third phase difference plate 32b, and the thickness direction retardation Rth4 of the fourth phase difference plate 34b (RthS=RthLC+Rth1+Rth2+Rth3+Rth4).
(263) As can be seen from Table 8 and
(264) The in-plane retardations of the liquid crystal display panels according to Examples 7-4 to 7-8 will be discussed next. The slow axis of the first phase difference plate 32a and the slow axis of the second phase difference plate 34a (azimuth angle 5) are arranged orthogonal to the liquid crystal director (azimuth angle 85). nd=R1+R2 is satisfied, and thus nd and R1+R2 cancel each other out. The third phase difference plate 32b and the fourth phase difference plate 34b are C plates having no in-plane retardations. Accordingly, the in-plane retardations of the liquid crystal display panels according to Examples 7-4 to 7-8 become substantially zero, and thus when observed from a forward viewing angle too, a good black display is achieved when no voltage is applied.
(265) The design values and black display transmittances of liquid crystal display panels according to Examples 7-9A to 7-9N will be described next with reference to Tables 9 to 12 and
(266) Like Table 8, Tables 9 to 12 illustrate design values of the liquid crystal display panels according to Examples 7-9A to 7-9N (values used in the simulations) and black display transmittances (when no voltage is applied) calculated at a wavelength of 550 nm.
(267) TABLE-US-00009 TABLE 9 Example Example Example Example Example 7-9A 7-9B 7-9C 7-9D 7-9E First polarizing Absorption 40.0 40.0 40.0 40.0 40.0 plate axis (deg) Third phase Slow axis difference plate (deg) R3 (nm) 0.0 0.0 0.0 0.0 Rth3 (nm) 206.25 137.50 275.00 412.50 NZ First phase Slow axis 5.0 5.0 5.0 5.0 5.0 difference plate (deg) R1 (nm) 137.5 137.5 137.5 137.5 137.5 Rth1 (nm) 68.75 68.75 68.75 68.75 68.75 NZ 1.00 1.00 1.00 1.00 1.00 Liquid crystal nd (nm) 412.5 412.5 412.5 412.5 412.5 layer RthLC (nm) 206.3 206.3 206.3 206.3 206.3 Alignment 85.0 85.0 85.0 85.0 85.0 (deg) Second phase Slow axis 5.0 5.0 5.0 5.0 5.0 difference plate (deg) R2 (nm) 275.0 275.0 275.0 275.0 275.0 Rth2 (nm) 137.50 137.50 137.50 137.50 137.50 NZ 1.00 1.00 1.00 1.00 1.00 Fourth phase Slow axis difference plate (deg) R4 (nm) 0.0 0.0 0.0 0.0 Rth4 (nm) 206.25 275.00 137.50 412.50 NZ Second polarizing Absorption 130.0 130.0 130.0 130.0 130.0 plate axis (deg) Sum of thickness RthS (nm) 0.0 0.0 0.0 0.0 0.0 direction retardations Black display Maximum 0.040 0.058 0.037 0.099 0.087 transmittance Average 0.014 0.017 0.015 0.026 0.031 (Polar angle 60)
(268) TABLE-US-00010 TABLE 10 Example Example Example 7-9F 7-9G 7-9H First polarizing plate Absorption axis (deg) 40.0 40.0 40.0 First phase difference plate Slow axis (deg) 5.0 5.0 5.0 R1 (nm) 137.5 137.5 137.5 Rth1 (nm) 68.75 68.75 68.75 NZ 1.00 1.00 1.00 Third phase difference plate Slow axis (deg) R3 (nm) 0.0 0.0 0.0 Rth3 (nm) 206.25 137.50 275.00 NZ Liquid crystal layer nd (nm) 412.5 412.5 412.5 RthLC (nm) 206.3 206.3 206.3 Alignment (deg) 85.0 85.0 85.0 Fourth phase difference Slow axis (deg) plate R4 (nm) 0.0 0.0 0.0 Rth4(nm) 206.25 275.00 137.50 NZ Second phase difference Slow axis (deg) 5.0 5.0 5.0 plate R2 (nm) 275.0 275.0 275.0 Rth2 (nm) 137.50 137.50 137.50 NZ 1.00 1.00 1.00 Second polarizing plate Absorption axis (deg) 130.0 130.0 130.0 Sum of thickness direction RthS (nm) 0.0 0.0 0.0 retardations Black display transmittance Maximum 0.135 0.073 0.202 (Polar angle 60) Average 0.066 0.039 0.096
(269) TABLE-US-00011 TABLE 11 Example Example Example 7-9I 7-9J 7-9K First polarizing plate Absorption axis (deg) 40.0 40.0 40.0 Third phase difference plate Slow axis (deg) R3 (nm) 0.0 0.0 0.0 Rth3 (nm) 206.25 137.50 275.00 NZ First phase difference plate Slow axis (deg) 5.0 5.0 5.0 R1 (nm) 137.5 137.5 137.5 Rth1 (nm) 68.75 68.75 68.75 NZ 1.00 1.00 1.00 Liquid crystal layer nd (nm) 412.5 412.5 412.5 RthLC (nm) 206.3 206.3 206.3 Alignment (deg) 85.0 85.0 85.0 Fourth phase difference Slow axis (deg) plate R4 (nm) 0.0 0.0 0.0 Rth4 (nm) 206.25 275.00 137.50 NZ Second phase difference Slow axis (deg) 5.0 5.0 5.0 plate R2 (nm) 275.0 275.0 275.0 Rth2 (nm) 137.50 137.50 137.50 NZ 1.00 1.00 1.00 Second polarizing plate Absorption axis (deg) 130.0 130.0 130.0 Sum of thickness direction RthS (nm) 0.0 0.0 0.0 retardations Black display transmittance Maximum 0.038 0.037 0.044 (Polar angle 60) Average 0.017 0.017 0.017
(270) TABLE-US-00012 TABLE 12 Example Example Example 7-9L 7-9M 7-9N first polarizing plate Absorption axis (deg) 40.0 40.0 40.0 first phase difference plate Slow axis (deg) 5.0 5.0 5.0 R1 (nm) 137.5 137.5 137.5 Rth1 (nm) 68.75 68.75 68.75 NZ 1.00 1.00 1.00 Third phase difference plate Slow axis (deg) R3 (nm) 0.0 0.0 0.0 Rth3 (nm) 206.25 137.50 275.00 NZ Liquid crystal layer nd (nm) 412.5 412.5 412.5 RthLC (nm) 206.3 206.3 206.3 Alignment (deg) 85.0 85.0 85.0 Second phase difference Slow axis (deg) 5.0 5.0 5.0 plate R2 (nm) 275.0 275.0 275.0 Rth2 (nm) 137.50 137.50 137.50 NZ 1.00 1.00 1.00 Fourth phase difference Slow axis (deg) plate R4 (nm) 0.0 0.0 0.0 Rth4 (nm) 206.25 275.00 137.50 NZ Second polarizing plate Absorption axis (deg) 130.0 130.0 130.0 Sum of thickness direction RthS (nm) 0.0 0.0 0.0 retardations Black display transmittance Maximum 0.171 0.138 0.210 (Polar angle 60) Average 0.073 0.050 0.100
(271) The liquid crystal display panels according to Examples 7-9A to 7-9N have positive C plates as the third phase difference plate 32b and/or the fourth phase difference plate 34b. A C plate does not have in-plane retardation, and thus the slow axis and NZ are undefined. In the liquid crystal display panels according to Examples 7-9A to 7-9N, the values of the thickness direction retardations of the third phase difference plate 32b and the fourth phase difference plate 34b are set such that the sum RthS of the thickness direction retardations is zero.
(272) As illustrated in Table 9, the liquid crystal display panels according to Examples 7-9A to 7-9C have the same configuration as the liquid crystal display panel 100B illustrated in
(273) As illustrated in Table 9, the liquid crystal display panel according to Example 7-9D has the same configuration as the liquid crystal display panel 100C1 illustrated in
(274) In each of the liquid crystal display panels according to Examples 7-9A to 7-9E, the sum RthS of the thickness direction retardation is zero, and thus a good black display when viewing from oblique viewing angles can be achieved. In comparing the results of Examples 7-9A to 7-9E, it can be seen that a structure in which both the third and fourth phase difference plates 32b and 34b are provided, as in the liquid crystal display panels according to Examples 7-9A to 7-9C, achieves a better black display when observed from oblique viewing angles than a structure in which only the third phase difference plate 32b or the fourth phase difference plate 34b is provided, as in the liquid crystal display panels according to Example 7-9D or Example 7-9E. In comparing the results of Examples 7-9A to 7-9C, it can be seen that when priority is given to reducing the black display transmittance at a polar angle of 60 by the average value rather than the maximum value, it tends to be preferable that the thickness direction retardation Rth3 of the third phase difference plate 32b and the thickness direction retardation Rth4 of the fourth phase difference plate 34b be equal to each other, as in the liquid crystal display panel according to Example 7-9A.
(275) The liquid crystal display panels according to Examples 7-9F to 7-9H illustrated in Table 10, the liquid crystal display panels according to Examples 7-9I to 7-9K illustrated in Table 11, and the liquid crystal display panels according to Examples 7-9L to 7-9N illustrated in Table 12 are the same as the liquid crystal display panels according to Examples 7-9A to 7-9C illustrated in Table 9 in terms of the values of the thickness direction retardation Rth3 of the third phase difference plate 32b and the thickness direction retardation Rth4 of the fourth phase difference plate 34b.
(276) As illustrated in Table 10, the liquid crystal display panels according to Examples 7-9F to 7-9H have the same configuration as the liquid crystal display panel 100B1 illustrated in
(277) As illustrated in Table 11, the liquid crystal display panels according to Examples 7-9I to 7-9K have the same configuration as the liquid crystal display panel 100B2 illustrated in
(278) As illustrated in Table 12, the liquid crystal display panels according to Examples 7-9L to 7-9N have the same configuration as the liquid crystal display panel 100B3 illustrated in
(279) A preferred arrangement relationship of the first phase difference plate 32a and the third phase difference plate 32b, and a preferred arrangement relationship of the second phase difference plate 34a and the fourth phase difference plate 34b, were investigated by comparing the results illustrated in Tables 9 to 12. In comparing the results of Examples 7-9A to 7-9N, it can be seen that an excellent black display when observed from oblique viewing angles is achieved by the liquid crystal display panels according to Examples 7-9A to 7-9C and the liquid crystal display panels according to Examples 7-9I to 7-9K. The liquid crystal display panels according to Examples 7-9A to 7-9C in particular have excellent black displays when observed from oblique viewing angles. It tends to be preferable that the third phase difference plate 32b be disposed between the first phase difference plate 32a and the first polarizing plate 22, as long as the sum of the thickness direction retardations is the same. Additionally, it is further preferable that the fourth phase difference plate 34b be disposed between the second phase difference plate 34a and the second polarizing plate 24.
(280) The in-plane retardations of the liquid crystal display panels according to Examples 7-9A to 7-9N will be discussed next. The slow axis of the first phase difference plate 32a and the slow axis of the second phase difference plate 34a (azimuth angle 5) are arranged orthogonal to the liquid crystal director (azimuth angle 85). nd=R1+R2 is satisfied, and thus nd and R1+R2 cancel each other out. The third phase difference plate 32b and the fourth phase difference plate 34b are C plates having no in-plane retardations. Accordingly, the in-plane retardations of the liquid crystal display panels according to Examples 7-9A to 7-9N become substantially zero, and thus when observed from a forward viewing angle too, a good black display is achieved when no voltage is applied.
(281) The design values and black display transmittances of the liquid crystal display panels according to Examples 7-10 to 7-17 will be described next with reference to Table 13 and
(282) TABLE-US-00013 TABLE 13 Example Example Example Example Example Example Example Example 7-10 7-11 7-12 7-13 7-14 7-15 7-16 7-17 First polarizing plate Absorption 40.0 40.0 40.0 40.0 40.0 40.0 40.0 40.0 axis (deg) Third phase Slow axis 40.0 130.0 40.0 130.0 40.0 130.0 40.0 130.0 difference plate (deg) R3 (nm) 33.3 33.3 66.6 66.6 99.9 99.9 133.2 133.2 Rth3 (nm) 49.95 49.95 99.9 99.9 149.9 149.9 199.8 199.8 NZ 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 First phase difference Slow axis 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 plate (deg) R1 (nm) 137.5 137.5 137.5 137.5 137.5 137.5 137.5 137.5 Rth1 (nm) 68.75 68.75 68.75 68.75 68.75 68.75 68.75 68.75 NZ 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Liquid crystal layer nd (nm) 412.5 412.5 412.5 412.5 412.5 412.5 412.5 412.5 RthLC (nm) 206.3 206.3 206.3 206.3 206.3 206.3 206.3 206.3 Alignment 85.0 85.0 85.0 85.0 85.0 85.0 85.0 85.0 (deg) Second phase Slow axis 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 difference plate (deg) R2 (nm) 275.0 275.0 275.0 275.0 275.0 275.0 275.0 275.0 Rth2 (nm) 137.50 137.50 137.50 137.50 137.50 137.50 137.50 137.50 NZ 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Fourth phase Slow axis 130.0 40.0 130.0 40.0 130.0 40.0 130.0 40.0 difference plate (deg) R4 (nm) 33.3 33.3 66.6 66.6 99.9 99.9 133.2 133.2 Rth4 (nm) 49.95 49.95 99.9 99.9 149.9 149.9 199.8 199.8 NZ 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Second polarizing Absorption 130.0 130.0 130.0 130.0 130.0 130.0 130.0 130.0 plate axis (deg) Sum of thickness RthS (nm) 312.6 312.6 212.7 212.7 112.8 112.8 12.9 12.9 direction retardations Black display Maximum 0.154 0.210 0.067 0.179 0.061 0.173 0.123 0.196 transmittance Average 0.072 0.103 0.031 0.084 0.025 0.081 0.055 0.093 (Polar angle 60)
(283) In the liquid crystal display panels according to Examples 7-10 to 7-17, biaxial phase difference plates having negative thickness direction retardations are used as the third phase difference plate 32b and the fourth phase difference plate 34b. In Examples 7-10 to 7-17, the NZs of the biaxial phase difference plates used are all 1. In the liquid crystal display panels according to Examples 7-10, 7-12, and 7-14, the thickness direction retardations Rth3 and Rth4 of the third and fourth phase difference plates 32b and 34b have mutually-different values. In the liquid crystal display panels according to Examples 7-10, 7-12, and 7-14, the in-plane retardations R3 and R4 of the third and fourth phase difference plates 32b and 34b also have mutually-different values. In comparing these results, is can be seen that as the absolute value of the sum RthS of the thickness direction retardation decreases, a better black display when observed from oblique viewing angles tends to be achieved. However, in Example 7-16, although the sum RthS of the thickness direction retardations is smaller than in Examples 7-10, 7-12, and 1-14, the black display transmittance at a polar angle of 60 is greater than in Examples 7-12 and 7-14. In the liquid crystal display panel according to Example 7-16, the in-plane retardation R3 of the third phase difference plate 32b and the in-plane retardation R4 of the fourth phase difference plate 34b are each 133.2 nm. When the in-plane retardation R3 of the third phase difference plate 32b and the in-plane retardation R4 of the fourth phase difference plate 34b are high (greater than 100 nm, for example), the sum RthS of the thickness direction retardations decrease, and there are thus cases where it is difficult to reduce the black display transmittance at a polar angle of 60. Preferably, the in-plane retardation R3 of the third phase difference plate 32b and the in-plane retardation R4 of the fourth phase difference plate 34b are both less than 100 nm, for example.
(284) In the liquid crystal display panels according to Examples 7-10 and 7-11, the thickness direction retardations Rth3 and Rth4 of the third and fourth phase difference plates 32b and 34b are the same, but the angle formed by the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b, and the angle formed by the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b, are different from each other. In the liquid crystal display panel according to Example 7-10, the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b are parallel to each other, and the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b are parallel to each other. However, in the liquid crystal display panel according to Example 7-11, the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b are orthogonal to each other, and the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b are orthogonal to each other. The same relationship applies in the liquid crystal display panels according to Examples 7-12 and 7-13, 7-14 and 7-15, and 7-16 and 7-17, respectively.
(285) In comparing the results of the liquid crystal display panels according to Examples 7-10 and 7-11, the liquid crystal display panel according to Example 7-10 has a lower black display transmittance, and achieves a better black display when observed from oblique viewing angles, despite the sums of the thickness direction retardations being the same. It can be seen that compared to a case where the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b are orthogonal and the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b are orthogonal to each other, it is preferable that the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b be parallel to each other and the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b be parallel to each other. To rephrase, it can be seen that preferably, the polarization axis (transmission axis) of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b be orthogonal to each other, and the polarization axis (transmission axis) of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b be orthogonal to each other. The same results are obtained by the liquid crystal display panels according to Examples 7-12 and 7-13, 7-14 and 7-15, and 7-16 and 7-17, respectively.
(286) In a case where the angle formed by the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b is the same as the angle formed by the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b, a better black display when observed from oblique viewing angles tends to be achieved as the absolute value of the sum RthS of the thickness direction retardations decreases. However, such a configuration may not be the case when the sizes of these angles differ. For example, in comparing the liquid crystal display panel according to Example 7-12 with the liquid crystal display panel according to Example 7-15, the absolute value of the sum RthS of the thickness direction retardations is higher than in the liquid crystal display panel according to Example 7-15, but the black display transmittance at a polar angle of 60 is smaller than in the liquid crystal display panel according to Example 7-15. In other words, a good black display can be achieved by appropriately adjusting not only the sum RthS of the thickness direction retardations, but also the angle formed by the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b, and the angle formed by the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b.
(287) The angle formed by the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b is typically substantially 0 or substantially 90, as in the liquid crystal display panels according to Examples 7-10 to 7-17. However, the present embodiment is not limited thereto. Likewise, the angle formed by the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b is typically substantially 0 or substantially 90, as in the liquid crystal display panels according to Examples 7-10 to 7-17. However, the present embodiment is not limited thereto.
(288) The in-plane retardations of the liquid crystal display panels according to Examples 7-10 to 7-17 will be discussed next. The slow axis of the first phase difference plate 32a and the slow axis of the second phase difference plate 34a (azimuth angle 5) are arranged orthogonal to the liquid crystal director (azimuth angle 85). nd=R1+R2 is satisfied, and thus nd and R1+R2 cancel each other out. The in-plane retardation R3 of the third phase difference plate 32b and the in-plane retardation R4 of the fourth phase difference plate 34b are equal. The slow axis of the third phase difference plate 32b (azimuth angle 40 in Examples 7-10, 7-12, 7-14, and 7-16; azimuth angle 130 in Examples 7-11, 7-13, 7-15, and 7-17) and the slow axis of the fourth phase difference plate 34b (azimuth angle 130 in Examples 7-10, 7-12, 7-14, and 7-16; azimuth angle 40 in Examples 7-11, 7-13, 7-15, and 7-17) are orthogonal to each other. Accordingly, the in-plane retardation R3 of the third phase difference plate 32b and the in-plane retardation R4 of the fourth phase difference plate 34b cancel each other out. Thus, the in-plane retardations of the liquid crystal display panels according to Examples 7-10 to 7-17 become substantially zero, and thus when observed from a forward viewing angle too, a good black display is achieved when no voltage is applied.
(289) The design values and black display transmittances of the liquid crystal display panels according to Examples 7-18 to 7-29 will be described next with reference to Tables 14 and 15 and
(290) TABLE-US-00014 TABLE 14 Example Example Example Example Example Example Example Example 7-18 7-19 7-20 7-21 7-22 7-23 7-24 7-25 First polarizing Absorption axis 40.0 40.0 40.0 40.0 50.0 40.0 40.0 40.0 plate (deg) Third phase Slow axis (deg) 40.0 130.0 40.0 130.0 40.0 130.0 40.0 130.0 difference plate R3 (nm) 20.0 20.0 40.0 40.0 14.3 14.3 28.60 28.60 Rth3 (nm) 50.00 50.00 100.0 100.0 50.05 50.05 100.10 100.10 NZ 2.00 2.00 2.00 2.00 3.00 3.00 3.00 3.00 First phase Slow axis (deg) 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 difference plate R1 (nm) 137.5 137.5 137.5 137.5 137.5 137.5 137.5 137.5 Rth1 (nm) 68.75 68.75 68.75 68.75 68.75 68.75 68.75 68.75 NX 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Liquid crystal nd (nm) 412.5 412.5 412.5 412.5 412.5 412.5 412.5 412.5 layer RthLC (nm) 206.3 206.3 206.3 206.3 206.3 206.3 206.3 206.3 Alignment (deg) 85.0 85.0 85.0 85.0 85.0 85.0 85.0 85.0 Second phase Slow axis (deg) 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 difference plate R2 (nm) 275.0 275.0 275.0 275.0 275.0 275.0 275.0 275.0 Rth2 (nm) 137.50 137.50 137.50 137.50 137.50 137.50 137.50 137.50 NZ 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Fourth phase Slow axis (deg) 130.0 40.0 130.0 40.0 130.0 40.0 130.0 40.0 difference plate R4 (nm) 20.0 20.0 40.0 40.0 14.3 14.3 28.60 28.60 Rth4 (nm) 50.00 50.00 100.0 100.0 50.05 50.05 100.10 100.10 NZ 2.00 2.00 2.00 2.00 3.00 3.00 3.00 3.00 Second Absorption axis 130.0 130.0 130.0 130.0 130.0 130.0 130.0 130.0 polarizing plate (deg) Sum of thickness RthS (nm) 312.5 312.5 212.5 212.5 312.4 312.4 212.3 212.3 direction retardations Black display Maximum 0.164 0.199 0.076 0.151 0.169 0.194 0.084 0.139 Transmittance Average 0.077 0.096 0.034 0.070 0.080 0.093 0.037 0.063 (Polar angle 60)
(291) TABLE-US-00015 TABLE 5 Example Example Example Example 7-26 7-27 7-28 7-29 First polarizing Absorption axis 40.0 40.0 40.0 40.0 plate (deg) Third phase Slow axis (deg) 40.0 130.0 40.0 130.0 difference plate R3 (nm) 11.1 11.1 22.2 22.2 Rth3 (nm) 49.95 49.95 99.9 99.9 NZ 4.00 4.00 4.00 4.00 First phase Slow axis (deg) 5.0 5.0 5.0 5.0 difference plate R1 (nm) 137.5 137.5 137.5 137.5 Rth1 (nm) 68.75 68.75 68.75 68.75 NZ 1.00 1.00 1.00 1.00 Liquid crystal layer nd (nm) 412.5 412.5 412.5 412.5 RthLC (nm) 206.3 206.3 206.3 206.3 Alignment (deg) 85.0 85.0 85.0 85.0 Second phase Slow axis (deg) 5.0 5.0 5.0 5.0 difference plate R2 (nm) 275.0 275.0 275.0 275.0 Rth2 (nm) 137.50 137.50 137.50 137.50 NZ 1.00 1.00 1.00 1.00 Fourth phase Slow axis (deg) 130.0 40.0 130.0 40.0 difference plate R4 (nm) 11.1 11.1 22.2 22.2 Rth4 (nm) 49.95 49.95 99.9 99.9 NZ 4.00 4.00 4.00 4.00 Second polarizing Absorption axis 130.0 130.0 130.0 130.0 plate (deg) Sum of thickness RthS (nm) 312.6 312.6 212.7 212.7 direction retardations Black display Maximum 0.172 0.191 0.089 0.132 transmittance Average 0.081 0.092 0.040 0.060 (Polar angle 60)
(292) In the liquid crystal display panels according to Examples 7-18 to 7-29, biaxial phase difference plates having negative thickness direction retardations are used as the third phase difference plate 32b and the fourth phase difference plate 34b. In the liquid crystal display panels according to Examples 7-18 to 7-21, the NZ of the third phase difference plate 32b and the fourth phase difference plate 34b are 2. In the liquid crystal display panels according to Examples 7-22 to 7-25, the NZ of the third phase difference plate 32b and the fourth phase difference plate 34b are 3. In the liquid crystal display panels according to Examples 7-26 to 7-29, the NZ of the third phase difference plate 32b and the fourth phase difference plate 34b are 4.
(293) In the liquid crystal display panels according to Examples 7-18 and 7-20, the values of the thickness direction retardations Rth3 and Rth4, and the values of the in-plane retardations R3 and R4, of the third and fourth phase difference plates 32b and 34b are different. Likewise, in the liquid crystal display panels according to Examples 7-19 and 7-21, the values of the thickness direction retardations Rth3 and Rth4, and the values of the in-plane retardations R3 and R4, of the third and fourth phase difference plates 32b and 34b are different. In comparing these results, as the absolute value of the sum RthS of the thickness direction retardation decreases, a better black display when observed from oblique viewing angles is achieved.
(294) In the liquid crystal display panels according to Examples 7-18 and 7-19, the angle formed by the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b, and the angle formed by the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b, are different from each other. In the liquid crystal display panel according to Example 7-18, the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b are parallel to each other, and the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b are parallel to each other. However, in the liquid crystal display panel according to Example 7-19, the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b are orthogonal to each other, and the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b are orthogonal to each other. The liquid crystal display panels according to Examples 7-20 and 7-21 have the same relationship as the liquid crystal display panels according to Examples 7-18 and 7-19.
(295) In comparing the results of the liquid crystal display panels according to Examples 7-18 and 7-19, the liquid crystal display panel according to Example 7-18 has a lower black display transmittance, and achieves a better black display when observed from oblique viewing angles, despite the sums of the thickness direction retardations being the same. The liquid crystal display panels according to Examples 7-20 and 7-21 also have similar results. It can be seen that compared to a case where the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b are orthogonal and the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b are orthogonal to each other, it is preferable that the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b be parallel to each other and the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b be parallel to each other. To rephrase, it can be seen that preferably, the polarization axis (transmission axis) of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b be orthogonal to each other, and the polarization axis (transmission axis) of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b be orthogonal to each other.
(296) The liquid crystal display panels according to Examples 7-22 to 7-25 and 7-26 to 7-29 have the same relationship as the liquid crystal display panels according to Examples 7-18 to 7-21.
(297) Examples 7-10 to 7-13 (where the NZ of the third and fourth phase difference plates 32b and 34b is 1), Examples 7-18 to 7-21 (where the NZ of the third and fourth phase difference plates 32b and 34b is 2), Examples 7-22 to 7-25 (where the NZ of the third and fourth phase difference plates 32b and 34b is 3), and Examples 7-26 to 7-29 (where the NZ of the third and fourth phase difference plates 32b and 34b is 4), will be compared. In comparing Examples 7-4 to 7-8 (where the third and fourth phase difference plates 32b and 34b are positive C plates and the NZ is ) as well, it can be seen that a biaxial phase difference plate approaches a positive C plate as the absolute value of the NZ of the biaxial phase difference plate increases. For example, in comparing Examples 7-12, 7-20, 7-24, 7-28, and 7-5, in which the thickness direction retardations Rth3 and Rth4 of the third and fourth phase difference plates 32b and 34b are all 100 nm, the black display transmittance increases as the absolute value of the NZ increases, and approaches the value of the black display transmittance in the positive C plate (Example 7-5). Furthermore, with respect to the angle formed by the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b, and the angle formed by the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b, in comparing Examples 7-13, 7-21, 7-25, 7-29, and 7-5, the black display transmittance decreases as the absolute value of the NZ increases, and approaches the value of the black display transmittance of a positive C plate (Example 7-5). As the absolute value of the NZ of a biaxial phase difference plate increases, the change (dependence) of the black display transmittance with respect to the angle formed by the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b, and the angle formed by the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b, decreases; from this too, it can be seen that the biaxial phase difference plate approaches a positive C plate. For example, it can be seen that a biaxial phase difference plate in which the NZ is less than 4 can substantially be considered to be a positive C plate.
(298) An angle formed by the absorption axis of the first polarizing plate 22 and the slow axis of the third phase difference plate 32b is typically substantially 0 or substantially 90, as in the liquid crystal display panels according to Examples 7-18 to 7-29. However, the present embodiment is not limited thereto. Likewise, the angle formed by the absorption axis of the second polarizing plate 24 and the slow axis of the fourth phase difference plate 34b is typically substantially 0 or substantially 90, as in the liquid crystal display panels according to Examples 7-18 to 7-29. However, the present embodiment is not limited thereto.
(299) The in-plane retardations of the liquid crystal display panels according to Examples 7-18 to 7-29 will be discussed next. The slow axis of the first phase difference plate 32a and the slow axis of the second phase difference plate 34a (azimuth angle 5) are arranged orthogonal to the liquid crystal director (azimuth angle 85). nd=R1+R2 is satisfied, and thus nd and R1+R2 cancel each other out. The in-plane retardation R3 of the third phase difference plate 32b and the in-plane retardation R4 of the fourth phase difference plate 34b are equal. The slow axis of the third phase difference plate 32b (azimuth angle 40 in Examples 7-18, 7-20, 7-22, 7-24, 7-26, and 7-28; azimuth angle 130 in Examples 7-19, 7-21, 7-23, 7-25, 7-27, and 7-29) and the slow axis of the fourth phase difference plate 34b (azimuth angle 130 in Examples 7-18, 7-20, 7-22, 7-24, 7-26, and 7-28; azimuth angle 40 in Examples 7-19, 7-21, 7-23, 7-25, 7-27, and 7-29) are orthogonal to each other. Accordingly, the in-plane retardation R3 of the third phase difference plate 32b and the in-plane retardation R4 of the fourth phase difference plate 34b cancel each other out. Thus, the in-plane retardations of the liquid crystal display panels according to Examples 7-18 to 7-29 become substantially zero, and thus when observed from a forward viewing angle too, a good black display is achieved when no voltage is applied.
(300) As indicated by Examples 7-4 to 7-29, the angle formed by the absorption axis of the first polarizing plate 22 and the slow axis of the first phase difference plate 32a is typically substantially 45 or substantially 135 in the liquid crystal display panels 100B, 100B1 to 100B3, 100C1, and 100C2 according to the present embodiment. An angle formed by the absorption axis of the second polarizing plate 24 and the slow axis of the second phase difference plate 34a is typically substantially 45 or substantially 135. However, the present embodiment is not limited thereto, and can be adjusted as appropriate.
(301) The liquid crystal display panels according to embodiments of the present invention (including the first and second embodiments) can be produced using a known production method for a transverse electrical field mode liquid crystal cell. Processes for attaching the polarizing plates and the phase difference plates to the liquid crystal cell in a predetermined direction also can of course be carried out using a known method.
(302) The liquid crystal cell 10 of the liquid crystal display panels 100, 100A, 100B, 100B1, 100B2, 100B3, 100C1, and 100C2 can be produced as follows, for example.
(303) The bottom-side substrate 10 is prepared through a known method. For example, circuit elements such as TFTs, gate bus lines, source bus lines, and common wiring are formed on the glass substrate 32a. The common electrode 14, the dielectric layer 15, and the pixel electrodes 16 are then formed. An alignment film is formed on the liquid crystal layer 18-side surface of the bottom-side substrate 10Sa. The alignment film is then subjected to a rubbing treatment, for example, so that the liquid crystal molecules near the bottom-side substrate 10 are aligned in a predetermined direction.
(304) The top-side substrate 10 produced through a known method is then prepared. The top-side substrate 10 has, for example, a black matrix and a color filter layer upon the glass substrate 12b, and has an alignment film on the liquid crystal layer 18 side. The alignment film is then subjected to a rubbing treatment, for example, so that the liquid crystal molecules near the top-side substrate 10Sb are aligned in a predetermined direction.
(305) Controlling the thickness of the liquid crystal layer 18 using spacers formed on the bottom-side substrate 10Sa or the top-side substrate 10Sb, the liquid crystal layer 18 is formed through one drop filling, for example, and the bottom-side substrate 10Sa and the top-side substrate 10Sb are then affixed to each other to prepare the liquid crystal cell 10.
(306) Note that the alignment treatment of the alignment film is not limited to a rubbing treatment, and an optical alignment treatment may be carried out using an optical alignment film. A rubbing treatment and an optical alignment treatment may be combined as well.
(307) The TFT of the liquid crystal display panels 100, 100A, 100B, 100B1, 100B2, 100B3, 100C 1, and 100C2 according to embodiments of the present invention may be a known TFT such as an amorphous silicon TFT (a-Si TFT), a polysilicon TFT (p-Si TFT), or a microcrystalline silicon TFT (C-Si TFT), but it is preferable to use a TFT having an oxide semiconductor layer (an oxide TFT). Using an oxide TFT makes it possible to reduce the surface area of the TFT, and thus the pixel aperture ratio can be increased.
(308) The oxide semiconductor included in the oxide semiconductor layer may be an amorphous oxide semiconductor or a crystalline oxide semiconductor having a crystalline part. A polycrystalline oxide semiconductor, a microcrystalline oxide semiconductor, and a crystalline oxide semiconductor in which the c-axis is oriented substantially orthogonal to the layer surface can be given as examples of the crystalline oxide semiconductor.
(309) The oxide semiconductor layer may have a layered structure including two or more layers. In a case where the oxide semiconductor layer has a layered structure, the oxide semiconductor layer may include an amorphous oxide semiconductor layer and a crystalline oxide semiconductor layer. Alternatively, a plurality of crystalline oxide semiconductor layers having different crystal structures may be included. In addition, a plurality of amorphous oxide semiconductor layers may be included. In a case where the oxide semiconductor layer has a two-layer structure including an upper layer and a lower layer, the energy gap of the oxide semiconductor included in the upper layer is preferably greater than the energy gap of the oxide semiconductor included in the lower layer. However, in a case where the difference in energy gap between these layers is comparatively small, the energy gap of the lower-layer oxide semiconductor may be greater than the energy gap of the upper-layer oxide semiconductor.
(310) A material, a structure, and a film formation method of the amorphous oxide semiconductor and each of the above-described crystalline oxide semiconductors, a configuration of an oxide semiconductor layer having a layered structure, and the like are described in, for example, JP 2014-007399 A. The entire contents of JP 2014-007399 A are incorporated into the present specification by reference.
(311) The oxide semiconductor layer may include at least one metal element selected from In, Ga, and Zn, for example. The oxide semiconductor layer includes, for example, an InGaZnO semiconductor (indium-gallium-zinc oxide, for example). Here, the InGaZnO semiconductor is a ternary oxide of In (indium), Ga (gallium), and Zn (zinc); the ratio of In, Ga, and Zn (the composition ratio) is not particularly limited, and includes, for example, In:Ga:Zn=2:2:1, In:Ga:Zn=1:1:1, In:Ga:Zn=1:1:2, and the like. Such an oxide semiconductor layer can be formed from an oxide semiconductor film including an InGaZnO semiconductor. Note that a channel-etched TFT having an active layer including an oxide semiconductor such as an InGaZnO semiconductor may be referred to as a CE-OS-TFT.
(312) The InGaZnO semiconductor may be amorphous or crystalline. For a crystalline InGaZnO semiconductor, a crystalline InGaZnO semiconductor in which the c-axis is oriented generally perpendicular to the layer surface is preferable.
(313) Note that JP 2014-007399 A, JP 2012-134475 A, and JP 2014-209727 A, for example, disclose crystal structures of crystalline InGaZnO semiconductors. The entire contents of JP 2012-134475 A and JP 2014-209727 A are incorporated into the present specification by reference. A TFT having an InGaZnO semiconductor layer has a high mobility (greater than 20 times that of an a-Si TFT) and a low leak current (less than 1/100th that of an a-Si TFT), and thus can be used favorably as a driving TFT (for example, a TFT included in a drive circuit provided on the same substrate as a display region including a plurality of pixels, in the periphery of the display region) and a pixel TFT (a TFT provided in a pixel).
(314) The oxide semiconductor layer may include another oxide semiconductor, instead of an InGaZnO semiconductor. For example, the oxide semiconductor layer may include an InSnZnO semiconductor (In.sub.2O.sub.3SnO.sub.2ZnO or InSnZnO, for example). The InSnZnO semiconductor is a ternary oxide of in (indium), Sn (tin), and Zn (zinc). Alternatively, the oxide semiconductor layer may include an InAlZnO semiconductor, an InAlSnZnO semiconductor, a ZnO semiconductor, an InZnO semiconductor, a ZnTiO semiconductor, a CdGeO semiconductor, a CdPbO semiconductor, CdO (cadmium oxide), a MgZnO semiconductor, an InGaSnO semiconductor, an InGaO semiconductor, a ZrInZnO semiconductor, an HfInZnO semiconductor, an AlGaZnO semiconductor, a GaZnO semiconductor, or the like.
INDUSTRIAL APPLICABILITY
(315) The present invention is broadly applicable to liquid crystal display panels in transverse electrical field modes. The present invention is particularly suited to use in transverse electrical field mode liquid crystal display panels to be used outdoors.
REFERENCE SIGNS LIST
(316) 10 Liquid crystal cell 10Sa Bottom-side substrate (first substrate) 10Sb Top-side substrate (second substrate) 12a, 12b Transparent substrate (glass substrate) 14 Common electrode 15 Dielectric layer 16 Pixel electrode 16a Opening in pixel electrode (slit) 22 First polarizing plate 24 Second polarizing plate 32, 32a First phase difference plate 34, 34a Second phase difference plate 32b Third phase difference plate 34b Fourth phase difference plate 100, 100A, 100B, 100B1, 100B2, 100B3, 100C1, 100C2 Liquid crystal display panel