Multi-chamber compressor of mechanical vapor re-compression and water treatment methods
11691895 · 2023-07-04
Inventors
Cpc classification
B01D1/2887
PERFORMING OPERATIONS; TRANSPORTING
B01D1/2881
PERFORMING OPERATIONS; TRANSPORTING
F04C2/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01C9/002
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F04C21/002
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02A20/124
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F01C1/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01D3/065
PERFORMING OPERATIONS; TRANSPORTING
F04C9/002
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01D1/289
PERFORMING OPERATIONS; TRANSPORTING
F04C18/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
Multi-chamber Compressor (6, 206, 506) of Mechanical Vapor re-Compression (MVC) and water treatment methods, the compressor bearing independent compression chambers of positive displacement, for heat-pumps, of two main variants: a) reciprocating-rotary motion (6, 206) wherein the compression chambers (7V) are radially arranged cylindrical sectors based on concentric circular sectors of the same angle, with, pistons of radially arranged vanes (20, 220) of respective surface and with the plane of the vanes passing through the axis of the common rotor (14) and the shaft (16) and b) reciprocating-linear motion (506) wherein the compression chambers (52v) are in series arranged cylinders with pistons/vanes (50v) of corresponding circular surfaces and with the plane of the vanes perpendicular to the common shaft (51). In both cases, the shaft (16, 51) and the motor are common to all the vanes (20v, 50v), which follow identical strokes. The surfaces of the vanes (20v, 50v), as well as of the compression chambers (7V, 52v), differ from each other, since each compression chamber (7V, 52v) has its own and independent pair of evaporation (ev, dv, Lv, by) and heat-exchanger chambers/areas (Cv/eCv, 32v/33v, 132v, 54v/53v), said compression chamber exclusively sucks from, compresses and discharges to, and the fluids/vapors being dispensed, are under different thermodynamic state conditions. The stages are independent from each other, the medium-vapor providing the energy of evaporation is produced in the stage itself, and flow rate and compression ratio CR are independently controlled and adjusted in each stage.
Claims
1. A method for treating water, the method comprising: (a) providing: (a)(i) a plurality of evaporation chambers (e.sub.ν, d.sub.ν, L.sub.ν, b.sub.ν); (a)(ii) a plurality of heat-exchangers or heat-exchanger chambers (C.sub.ν, 32.sub.ν, 132.sub.ν, 54.sub.ν), each corresponding a respective one of the plurality of evaporation chambers; (a)(iii) a compressor (6, 206, 306, 406), comprising a plurality of independent compression chambers (7.sub.ν) and respective vanes (20.sub.ν, 220.sub.ν, 320.sub.ν, 50.sub.ν), each vane configured to move within an active compression area of a respective one of the compression chambers, the active compression area extending between a pair of partitions (9.sub.ν); wherein multiple effects are provided, each effect being formed by an evaporation chamber and the respective one of the heat-exchanger or the heat-exchanger chamber; wherein each compression chamber is associated with a respective one of the effects, such that pressure ratio, temperature lift, vacuum height, and flow rate required are different for the different effects; wherein volumes of the compression chambers and the surfaces of the respective vanes differ between the compression chambers; wherein the compression chambers are adjacent sections of a cylinder and are separated by spacers (3) extending along different radii of the cylinder, such that each compression chamber (7.sub.ν) is adjacent to two compression chambers and separated from a compression chamber of a preceding effect via a first spacer and from a compression chamber of a subsequent effect via a second spacer, each compression chamber (7.sub.ν) comprising: a first collection chamber (8.sub.ν) extending between the first spacer and the first partition (9.sub.ν) and a second collection chamber (8.sub.ν) extending between the second spacer and the second partition, such that the active compression area is located between the first collection chamber and the second collection chamber; wherein each collection chamber (8.sub.ν) comprises: a suction sub-chamber (11.sub.ν) in fluid communication with the evaporation chamber of the same effect; and a compression sub-chamber (12.sub.ν) separated from the suction sub-chamber (11.sub.ν) via a horizontal partition (10.sub.ν), each compression sub-chamber being is fluid communication with the heat-exchanger or the heat-exchanger chamber of the effect associated with compression chamber; wherein at least one first valve is located on a portion of the partition which separates the active compression area of the compression chamber from the suction sub-chamber and at least one second valve is located on a portion of the partition which separates the active compression area from the compression sub-chamber; (a)(iv) a common rotor (14) located on a center of the cylinder, the rotor being joined to the plurality of vanes. (b) driving feed-water into an external heat-exchanger, to generate heated feed-water; (c) driving the heated feed-water into the evaporation chamber of the first effect; (d) evaporating the heated feed-water to create vapor and brine in the evaporation chamber of the first effect, and directing the brine to the evaporation chamber of the next effect; (e) at each effect, evaporating the brine in the evaporation chamber, to create further vapor and further brine, and directing each further brine to the evaporation chamber of a following effect; (f) at each compression chamber moving the vane circumferentially inside the active compression area away from the first partition, to lower pressure in a portion of the active compression area located between the vane and the first partition, causing the at least one first valve on the first partition to open, to suck the vapor from the evaporation chamber of the effect associated with the compression chamber into a first one of the suction sub-chambers and into a portion of the active compression area; (g) at each compression chamber moving the vane circumferentially inside the active compression area toward the first partition, to compress the vapor in the portion of the active compression area located between the vane and the first partition and thereby generate the super-heated vapor, and causing closing of the at least one first valve on the first partition and opening of the at least one second valve of the compression sub-chamber on the first partition, to direct the super-heated vapor to the compression sub-chamber; (h) at each effect, discharging the super-heated vapor from the compression sub-chamber associated with the effect into the heat-exchanger or the heat-exchanger chamber of the effect via a duct, such that the super-heated vapor in the heat-exchanger or the heat-exchanger chamber exchanges heat with the feed-water and condensates into treated water; wherein brine temperature at each effect is lower than brine temperature at a preceding effect.
2. The method of claim 1, wherein the evaporation chambers (b.sub.ν) are linearly arranged.
3. The method of claim 1, wherein the evaporation chambers (d.sub.ν, e.sub.ν) are sectors of a cylinder separated from each other via spacers (3) extending along different radii of the cylinder.
4. The method of claim 1, wherein the evaporation chambers are of parallelepiped shape (L.sub.ν), or cylindrical shape (b.sub.ν).
5. The method of claim 1, wherein step (a) comprises: providing a plurality of suction pre-chambers (246.sub.ν, 346.sub.ν), each being in fluid communications with a respective evaporation chamber (e.sub.ν, d.sub.ν,) and a respective pair of suction sub-chambers of the same effect.
6. The method of claim 1, wherein step (a) comprises: providing a sleeve-cylinder (2) in the middle of and concentric with the cylinder, wherein the common rotor is located in the sleeve cylinder.
7. The method of claim 1, wherein the vanes (20.sub.ν) slide into radially arranged slots in the interior of the rotor (16), and are supported by springs (20.sub.a).
8. The method of claim 1, wherein the vanes are mounted to the rotor via arms (121.sub.ν) shorter than the vanes.
9. The method of claim 1, wherein step (a) comprises: providing a drive mechanism for moving the vanes, the drive mechanism comprising a rotary motor (26) a crankshaft (27), a connecting rod (28), a rack (29) and a pinion.
10. The method of claim 1, wherein radii of the vanes (20.sub.ν) and of the compression chambers (7.sub.ν) are equal to each other, while heights and volumes of the compression chambers differ to each other and stepwise increase as the temperature of the corresponding effects decreases.
11. The method of claim 1, wherein step (a) comprises: wherein the heights of the vanes (20.sub.ν) and of the compression chambers (7.sub.ν) are kept constant while their radii are stepwise increased towards the effects of the lowest temperature.
Description
DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
(16)
(17) The unit is enclosed by two coaxial cylindrical shells, an outer shell 1 and an of smaller diameter inner sleeve-cylinder 2, between of which the four radially arranged evaporation chambers e.sub.ν (e1, e2, e3, e4) of the respective stages are developed, which are laterally separated from each other by the four crosswise arranged vertical spacers 3.sub.ν (3.sub.1-3.sub.4).
(18) The roofs of the evaporation chambers of the four stages-segments are covered by a common and uniform, preferably horizontal, airtight roof cover 4.sub.ν (4.sub.1-4.sub.4) below of which are developed the respective droplet separators 5.sub.ν (5.sub.1-5.sub.4) for holding the droplets of brine.
(19) The bottoms 31.sub.ν (31.sub.1-31.sub.4) as well as the roof covers 4.sub.ν of the evaporation chambers of all stages are preferably for all stages a common and uniform circular horizontal plane divided into four circular sectors.
(20) On to the roofs covers 4.sub.ν of the evaporation chambers is located the compressor 6 with the four compression chambers 7.sub.ν which are radially arranged above the evaporation chambers e.sub.ν corresponding one by one to them.
(21) Similarly to the evaporation chambers e.sub.ν, the compression chambers 7.sub.ν are separated by the same vertical spacers 3.sub.ν extending upwards.
(22) Inside the compression chambers 7.sub.ν, at both ends of them and in contact with the vertical spacers 3.sub.ν, are developed two for each compression chamber identical, narrow, opposite facing, collection chambers 8.sub.ν (8.sub.1-8.sub.4) which are restricted laterally, internally by two also radially arranged vertical spacers 9.sub.ν (9.sub.1-9.sub.4) which extend over the entire height of the compression chamber 7.sub.ν, and externally by the radial vertical crosswise arranged spacers 3.sub.ν of the respective stage.
(23) All collection chambers 8.sub.ν are cylindrical sectors extending at the same, for all the stages, area corresponding to the central angle β° and are restricted circumferentially and internally by the inner sleeve-cylinder 2 of smaller diameter. The two inward facing vertical spacers 9.sub.ν are extending, in the present application of the four-stage version, at a central angle α°=90°−2*β° and restrict the active area of the compression chambers 7.sub.ν and respectively the range/stroke of the reciprocating-rotational motion of the vanes 20.sub.ν (20.sub.1-20.sub.4). The compression chambers are cylindrical sectors based on circular sectors of the same central angle 90° (=α°+2*β°).
(24) The collection chambers 8.sub.ν are also divided by intermediate horizontal flat partitions 10.sub.ν (10.sub.1-10.sub.4) into two smaller chambers: the lower or suction sub-chambers 11.sub.ν (11.sub.1-11.sub.4) and the upper or compression sub-chambers 12.sub.ν (12.sub.1-12.sub.4).
(25) Roofs/covers 13.sub.ν (13.sub.1-13.sub.4) of the compression chambers 7.sub.ν (as well as of the corresponding collection chambers 8.sub.ν) show preferably a gradual and stepwise increase in the height, with the roof 13.sub.1 of the first stage being lower than the corresponding 13.sub.2 of the second and the second lower than the third, etc.
(26) The compression chambers 7.sub.ν are encircled externally by a preferably, common for all stages, cylindrical housing 18 the height of which varies gradually stepwise and follows the height of the roofs 13.sub.ν of the respective compression chambers 7.sub.ν.
(27) The roofs 13.sub.ν also form the upper cover of the compact four-stage unit. Inside the four compression chambers 7.sub.ν, move the radially arranged flat vanes 20.sub.ν (20.sub.1-20.sub.4) of the rotor 14 of the compressor 6, projecting through the permanently open openings 122.sub.ν of the sleeve-cylinder 2 as will be described below.
(28) The two opposite facing suction sub-chambers 11.sub.ν of the two collection chambers of each stage, communicate with the underlying evaporation chamber e.sub.ν of the respective stage through their bottom which is identical to the roof 4.sub.ν of the evaporation chamber of the respective stage and which remains permanently open above the droplet separators 5.sub.ν.
(29) Both suction sub-chambers 11.sub.ν and compression sub-chamber 12.sub.ν, communicate with the respective compression chambers 7.sub.ν of the compressor 6 of their stage, through suction and compression check-valves 22.sub.ν (22.sub.1-22.sub.4) and 21.sub.ν (21.sub.1-21.sub.4) respectively. The valves operate automatically and preferably by varying of the pressures in the respective compression chambers.
(30) Evaporation chambers are empty spaces and do not contain any heat-exchangers. Just below the evaporation chambers e.sub.ν, and with almost the same circular-sector plan-view, are developed the respective four condensation chambers C.sub.ν (C.sub.1-C.sub.4) with the water-vapor heat-exchangers eC.sub.ν (eC.sub.1-eC.sub.4), which are preferably comprised of vertical tubes 30.sub.ν (30.sub.1-30.sub.4) and are connected to the compression chambers 7.sub.ν of the above lying compressor of the stage through the vertical ducts 19.sub.ν of the superheated vapor. The heat-exchangers eC.sub.ν pre-heat the feed-water 40 before it enters the system.
(31) In
(32) The surfaces of the four vanes 20.sub.ν (20.sub.1-20.sub.4) preferably differ from one another as they progressively increase corresponding to the cross-sections of the four compression chambers 7.sub.ν within of which they are rotated. The rotor 14 terminates on a vertical shaft 16 that exits the main body of the stages and the sleeve-cylinder 2 and terminates on a toothed wheel (pinion) 17 which connects it to the reciprocating-rotary drive transmission systems.
(33)
(34) It concerns an embodiment of sealing the rotation of the rotor between the adjacent compression chambers 7.sub.ν by sealing the openings 122.sub.ν within of which the vanes 20.sub.ν move/stroke. the openings 122.sub.ν within of which the vanes 20.sub.ν move/stroke. The sealing is a series of concentric closed frames of horizontal and vertical bars 23 projecting slightly around the openings 122.sub.ν on the inner cylindrical surface of the sleeve-cylinder 2 creating between them the peripheral channels and the labyrinth conditions of trapping the vapor.
(35) Correspondingly, there are also the parallel rows of rolled bars 23a circumferentially and sequentially arranged below and above the openings 122.sub.ν. The bars 23a also cooperate with respective equal number of parallel rows of rolled bars 23b deployed on the opposed convex portion of the rotor 14 and are interposed one by one between the bars 23a, creating a double labyrinth seal (the latter is e.g. applicable to compression chambers' version of
(36) At the top of the inner sleeve-cylinder 2, around the upper-end and right before the top bearing of the shaft 16, there is also an auxiliary water-vapor heat-exchanger for the additional pre-heating of a portion of the feed-water 40 on the walls of which the vapor, which escapes from the labyrinth bars, condenses and flows, collected as desalinated water at the bottom of the sleeve-cylinder 2. The heat-exchanger is not designed.
(37)
(38)
(39) In
(40) At the center of the vane 120.sub.ν, the adjustable (sliding) aperture 123.sub.ν (by-pass) exists to adjust the discharge of the compression chamber by by-passing of a portion of the vapor from the high-pressure side in the low-pressure side of the vane, that are continuously alternating.
(41) There might be other mounting and sealing systems of vanes as well as dividing in parts, prefabrication and assembling of the compressor chambers, etc.
(42)
(43) The main factors of each stage (i.e. compression 7.sub.ν, evaporation e.sub.ν, condensation C.sub.ν, and heat-exchangers eC.sub.ν chambers) correspond and are located one directly above the other, in such a way that the four stages can be prefabricated as four independent cylindrical sectors (modules) and assembled during installation creating the cylindrical body of the unit. Correspondingly, the vanes and obviously the chambers could be, in particular in the variant of
(44) What will remain to complete the installation of the unit, is the external connections of the ducts 19.sub.ν with the condensation chambers C.sub.ν, and the in-series external hydraulic connections of (a) the heat-exchangers' eC.sub.ν, (b) the brine and (c) the desalinated water, that will be removed.
(45) The rotary-radial compressor 6, due to its shape and motion, is characterized as a “fan” type.
(46) The reciprocating-rotary motion of the rotor 14 functions as a multi-compressor of four independent compression chambers. Creates a lower pressure at the inlet of the multi-compressor, sucking the vapors from the evaporation chambers e.sub.ν, and transferring them to the compression chambers 7.sub.ν where it compresses and superheats them before leading them to the condensation chambers C.sub.ν. Similar operation with the “supercharger” system of internal combustion engines, hence the significant thermodynamic and technological improvement that the present multi-compressor offers, among other things, in thermal desalination, etc.
The Operation of the Compressor 106 at the MVC-MSF System of FIGS. 1-4
(47) The feed-water 40 is pumped and passed through the multi-stream external heat-exchangers (not designed) where it is pre-heated in the multi-stream heat-exchangers of the desalinated water 44.sub.ν and the brine 36.sub.ν which are removed. The pre-heated feed-water 40 enters under pressure from the fourth and coldest stage through the bundle of vertical tubes 30.sub.ν of the water-vapor heat-exchangers eC.sub.ν, runs all the stages where it is gradually pre-heated, by the superheated vapors which correspondingly condense, and finally the feed-water enters the evaporation chamber e.sub.1 of the first stage. The condensed, desalinated water is collected in the bottom of the condensation chambers C.sub.ν and is removed.
(48) Upon entry of the feed-water 40 into the evaporation chamber e.sub.1 of the first stage, part of it is subjected to flash evaporation and the vapor produced, in saturation state, is intensively sucked, entering through the permanent openings of the roof cover 4.sub.1 and passes to the two suction sub-chambers 11.sub.1 of the double collecting chamber 8.sub.1 of the first stage after passing through the droplet separators 5.sub.1.
(49) Whenever the vane 20.sub.1 of the first stage begins the reciprocating stroke from one of its two terminal positions, which are identical to the two opposed vertical spacers 9.sub.1, lower pressure is created in the suction sub-chamber 11.sub.1 of the collecting chamber 8.sub.1 behind the vane.
(50) The lower pressure opens the suction check-valves 21.sub.1 and the vapor enters at high speed into the compression chamber 7.sub.1 of the first stage of the compressor, following the vane's 20.sub.1 motion. The intense suction reduces the vapor pressure in the evaporation chamber e.sub.1 and causes more intensive evaporation.
(51) After the stroke of the vane 20.sub.1 and the suction phase have been completed, the vane 20.sub.1 moves in the opposite direction. Part of the compression chamber 7.sub.1, which was previously under lower pressure conditions, is now at higher pressure conditions, the suction check-valves 21.sub.1 close behind it, while at a certain point on the new stroke and when the required high pressure has been reached, the compression check-valves 20.sub.1 open-up at the opposite (in the vane movement) compression sub-chamber 12.sub.1. Due to the dual-action of the vane, vapors are sucked and compressed continuously.
(52) With the compression, the vapor temperature rises and superheated and under considerable higher pressure is guided through the permanent opening of the compression sub-chamber 12.sub.1 in the peripheral channel 15.sub.1 and from there through the common vertical duct 19.sub.1, of the first stage, descends into the condensation chamber C.sub.1 and the water-vapor pre-heating exchangers eC.sub.1 of the feed-water 40.
(53) The superheated vapor transfers its sensible and latent heat to pre-heat the feed-water 40 and condenses on the outer surfaces of the tubes 30.sub.1 of the heat-exchanger, while the condensate 44.sub.1 descends to the circumferential channel 42.sub.1 at the bottom of the chamber C.sub.1 of the first stage.
(54) The brine portion 36.sub.1 which is not evaporated in the first stage, has lost temperature and from the bottom of the evaporation chamber e.sub.1 is fed to the next evaporation chamber e.sub.2 of the second stage. Herein the same flash evaporation process and compression of the vapors is followed, with the exception that since the brine 36.sub.2 is colder and the vapor pressure lower, the vacuum at this stage is higher.
(55) Furthermore, because the specific enthalpy (kJ/kg) is reduced while the specific volume (m.sup.3/kg) of the saturated vapor is greater, the circulation of a larger volume is required in order to have the same production as the first stage.
(56) For this reason the surface of the vane 20.sub.2 is larger. Therefore, the suction volume, the compression ratio (CR) and the rise in the vapor temperature, have different values compared to the first stage.
(57) The process is repeated in the third and fourth (last) stage with the surface of the vanes 20.sub.ν being gradually increased, the brine 36.sub.ν circulating and becoming colder and more saline and the temperature of the compressed vapors also gradually decreasing.
(58) The feed-water 40, following a reverse course in regards to the brine, is pre-heated gradually in the heat-exchangers eC.sub.ν which are connected in-series, so that the temperature t.sub.a (corresponding to the boiling temperature of the brine 36.sub.1 of the first stage) is finally reached before entering the first stage.
(59) The desalinated water, by following the reverse direction relative to the feed-water, is collected and removed after it has passed through the multi-stream external water-water heat-exchanger of the initial pre-heating of the feed-water 40.
(60) In order for the flow of the brine and the desalinated water to be moved preferably by gravity, the levels of the bottoms 31.sub.ν of the evaporation chambers may be gradually stepped. Also, the volumes of the evaporation chamber e.sub.ν, of the condensation chambers C.sub.ν, as well as the surfaces of the water-vapor heat-exchangers eC.sub.ν, may not be the same, but they change gradually from stage to stage.
(61)
(62) This application of the four-stage unit resembles that of
(63) They have the same rotary-radial compressor 206 with the vanes 220.sub.ν, the rotor 214, the collection chambers 208.sub.ν, the vertical spacers 203.sub.ν and 209.sub.ν, the horizontal flat partitions 210.sub.ν in the sub-chambers 211.sub.ν and 212.sub.ν with the respective suction and compression check-valves 221.sub.ν and 222.sub.ν and the circumferential channel 215.sub.ν. Finally, the compression chambers 207.sub.ν, with the flat roofs 213.sub.ν of gradually and stepwise increased heights and the cylindrical housing 218, complement the compressor 206.
(64) The unit has the same radial arrangement of the evaporation chambers d.sub.ν with the common roof cover 204.sub.ν, the peripheral cylindrical shell 201, the inner sleeve-cylinder 202, with the bases of the chambers d.sub.ν occupying the four circular bottom segments 231.
(65) With regard to the differences with the aforementioned variation MVC-MSF of
(66) Regarding the evaporation chambers d.sub.ν (d.sub.1-d.sub.4), between the peripheral cylindrical shell 201 and the narrow inner sleeve-cylinder 202, is interposed a larger coaxial cylindrical shell 236.sub.ν. Between the latter cylindrical shell 236.sub.ν and the sleeve-cylinder 202, an intermediate vertical duct riser 46.sub.ν is formed, terminating at the top of the roofs 204.sub.ν.
(67) The evaporation chambers d.sub.ν contain heat-exchangers 32.sub.ν, preferably water-vapor, consisting of vertical tube bundles 33.sub.ν of falling brine film. They are developed within the chambers d.sub.ν and are covered from top and bottom by horizontal flat frontal plates (tube sheets) 34.sub.ν and 35.sub.ν respectively and internally peripherally from the large cylindrical shell 236.sub.ν.
(68) The flat frontal plates (tube sheets) 34.sub.ν and 35.sub.ν and the cylindrical shell 236.sub.ν isolate the spaces of the saturated vapor, from the spaces of the superheated one. Externally and peripherally, the heat-exchangers 32.sub.ν are open in order for the superheated vapor, descending from the compression chambers 207.sub.ν, to access the spaces of the heat-exchangers 32.sub.ν.
(69) The superheated vapors, from the peripheral channel 215.sub.ν of the compressor and through the vertical ducts 37.sub.ν, end up in the troughs 41.sub.ν which develop at the periphery of the evaporation chambers d.sub.ν and from there in the space of the heat-exchangers 32.sub.ν.
(70) Regarding the compressor, between the roofs 204.sub.ν of the evaporation chambers d.sub.ν and the compression chambers 207.sub.ν are developed four suction pre-chambers 246.sub.ν (246.sub.1-246.sub.4) which are located below their respective compression chambers 207.sub.ν (and bellow their collection chambers 208.sub.ν). The suction pre-chambers correspond exactly to the compression chambers and are also an integral part of the compressor's housing, occupying the entire circular surface under it and are peripherally enclosed by the common cylindrical housing 218.
(71) At the upper-end of the vertical duct 46.sub.ν, inside the evaporation chamber and before the suction pre-chambers 246.sub.ν, brine droplets separators 205.sub.ν are developed.
(72) Within the differences are included the pumping system 36.sub.ν of the brine which pumps the brine from the bottom of the evaporation chambers d.sub.ν by the pumps 38.sub.ν and sprays it through the spray/nozzle systems 39.sub.ν onto the flat frontal plates (tube sheets) 35.sub.ν in the upper portion of the evaporation chambers and above the bundle of the vertical tubes 33.sub.ν of the water-vapor heat-exchangers 32.sub.ν. The surfaces of the heat-exchangers are gradually changed from stage to stage.
(73) The
The Operation of the Compressor 206 and of the System MVC-MEE/MED
(74) The feed-water 40 is pumped at ambient temperature, is pre-heated at the specific temperature t.sub.o in the multi-stream external heat-exchanger (not designed) from the removed brine 36.sub.ν and the desalinated water 44.sub.ν and is fed to the evaporation chamber d.sub.1 of the first stage.
(75) The inlet temperature t.sub.o is slightly lower than the temperature t.sub.1 of the boiling point of the brine which corresponds to the specific vacuum prevailing in the evaporation chamber d.sub.1 of the first stage.
(76) From the bottom of the chamber d.sub.1, the brine 36.sub.1 is sucked by pump 38.sub.1 and sprayed through the spray system 39.sub.1 at the inner surfaces of the falling film tubes 33.sub.1 of the water-vapor heat-exchanger 32.sub.1, wherein a portion of the brine is evaporated by the sensible and latent heat transferred by the superheated vapor S.sub.1 flowing onto the outer surfaces of the tubes 33.sub.1. In particular:
(77) Whenever the vane 220.sub.1 of the first stage of the compressor 206 begins the reciprocating stroke from one of the two of its terminal positions, as per known, lower pressure is created in the suction sub-chamber 211.sub.1 of the collection chamber 208.sub.1 which happens to be behind the vane.
(78) The lower pressure opens the suction check-valve 221.sub.1 and the saturated vapor produced in the evaporation chamber d.sub.1 is strongly sucked following the stroke of the vane, enters the suction sub-chamber 211.sub.1 of the collection chamber 208.sub.1 of the first stage, after having ascended through the vertical duct 46.sub.1, having dismissed the brine droplets at the separator 205 and having entered in the suction pre-chamber 246.sub.1 of the compressor.
(79) After the vane's stroke 220.sub.1 and the suction phase have been completed, the vane 220.sub.1 moves in the reverse direction, as per known from the previous embodiment of the
(80) The compression ratio CR.sub.1 corresponds to the required temperature rise of the superheated vapor of the first stage. The saturated vapor is compressed, superheated and its temperature is raised from t.sub.1 to t.sub.1+Δt.sub.1, wherein the portion Δt.sub.1 covers:
(81) a) the rise α.sub.1 of the boiling point of the brine of the first stage due to increased salinity and
(82) b) the temperature difference D.sub.1 which will increase the enthalpy of the superheated vapor S.sub.1 to cause a relatively quick evaporation of the brine.
(83) For the overall required temperature rise of the vapor at the first stage, the relationship holds: Δt.sub.1=α.sub.1+D.sub.1, or in general for the stages that follow: Δt.sub.ν=α.sub.ν+D.sub.ν.
(84) The superheated vapor S.sub.1, after the heat transfer in the heat-exchanger, is cooled-down and condensed. The condensate and desalinated water 44.sub.1, descends to the bottom of the peripheral channel 41.sub.1, from where it is pumped along with the corresponding condensates of the other stages and is directed to the multi-stream external water-water heat-exchanger of the pre-heating of the feed-water 40 and from there to the storage space.
(85) The brine, which has not been evaporated in the first stage and is colder, is passed to the next evaporation chamber d.sub.2 of the second stage. There it follows the same evaporation and compression process. In order to achieve the same production of desalinated water 44.sub.ν at each and every stage, the surface of the vane 220.sub.2 and of the corresponding compression chamber are larger, compared to the first stage (or, in generally, to the previous stage).
(86) The compression ratio CR.sub.2 also varies in order to achieve the required temperature rise Δt.sub.2 of the superheated vapor S.sub.2. The saturated vapor having the temperature t.sub.2 of the brine of the second stage, is sucked into the compression chamber 207.sub.2 of the stage, is compressed, superheated and is guided through the corresponding peripheral channel 215.sub.2 and the vertical duct 37.sub.2 in the second stage heat-exchanger at a lower temperature t.sub.2+Δt.sub.2, compared to the corresponding one of the first stage t.sub.1+Δt.sub.1 (the relationship holds: t.sub.ν+Δt.sub.ν< . . . <t.sub.2+Δt.sub.2<t.sub.1+Δt.sub.1).
(87) The process is repeated in the third and the fourth (last stage), with the brine circulating from stage to stage becoming colder and saltier and the temperature of the superheated vapor S.sub.ν becoming also gradually lower.
(88) The unit instead of an electric motor can use an internal combustion engine, so there will simultaneously be a permanent supplementary and auxiliary heat supply, significantly improving the start-up and the efficiency of both drivetrain and desalination.
(89)
(90) They have the same rotary-radial compressor 306, with the four chambers and the vanes 320.sub.ν, the collection chambers 308.sub.ν, the vertical spacers 303.sub.ν and 309.sub.ν, the horizontal flat partitions 310.sub.ν, the two sub-chambers 311.sub.ν and 312.sub.ν, the suction check-valves 321.sub.ν and compression check-valves 322.sub.ν and the suction pre-chambers 346.sub.ν (346.sub.1-346.sub.4).
(91) Collection chambers 308.sub.ν and compression chambers 307.sub.ν, have as their bottom the partition plane 345.sub.ν under which the four suction pre-chambers 346.sub.ν are developed. The suction sub-chambers 311.sub.ν are connected directly, via their permanently open bottoms, with their corresponding pre-chambers 346.sub.ν.
(92) The compressor is also covered by flat roofs 313.sub.ν of gradually and stepwise increased heights, enclosed by a cylindrical housing 318, while the bottom 347.sub.ν forms its lower outer cover and at the same time the bottom of the suction pre-chambers 346.sub.ν. The surfaces of the vanes 320.sub.ν are gradually and stepwise increased as are the cross-sections of the compression chambers 307.sub.ν.
(93) This is therefore the same system compared to that of
(94) The four evaporation chambers L.sub.ν, with the inside incorporated heat-exchangers, are longitudinal and of parallelepiped shape, arranged in pairs and in two parallel rows. The two rows are located adjacent to each other forming a common parallelepiped consisting of the four parallelepipeds, all of which having a common junction point.
(95) The four chambers are mounted with their largest surface on an elevated frame below which there are pipelines, pumps and all the auxiliary machinery and devices. Not designed.
(96) The outer coverings 101.sub.ν of the evaporation chambers L.sub.ν are slightly convex in order to increase stiffness due to vacuum conditions prevailing within. Inside the evaporation chambers L.sub.ν, vapor-water heat-exchangers 132.sub.ν are developed, consisting of a bundle of horizontal preferably flattened tubes 133.sub.ν which terminate in two narrow vertical collector-chambers, the inlet collector-chambers 110.sub.ν of the superheated vapor, and the outlet collector-chambers 111.sub.ν of the condensates 44.sub.ν, with the corresponding vertical and flat frontal plates (tube sheets) 134.sub.ν and 135.sub.ν respectively. The inlet collector-chambers 110.sub.ν, are restricted by the frontal plates (tube sheets) 134.sub.ν and by their external side walls 112.sub.ν.
(97) Above the heat-exchangers, there are the brine spray systems 139.sub.ν, while in the lower part, the brine basins 131.sub.ν are developed.
(98) Between the external side walls 112.sub.ν of the inlet collector-chambers 110.sub.ν and the outer coverings 101.sub.ν with which the stages are in contact in pairs frontally to each other, develop narrow, flattened vertical duct-chambers 114.sub.ν. They extend over the entire width and height of the evaporation chamber L.sub.ν, in parallel to the inlet collector-chambers 110.sub.ν connecting the upper part of the basins 131.sub.ν with the suction pre-chamber 346.sub.ν of the compressor 306 corresponding to the stage.
(99) The duct-chambers 114.sub.ν correspond to the vertical ducts 46.sub.ν, rising upwards, of the saturated vapors of the corresponding variant of
(100) From the center of the unit, namely from the four-stages' common junction, passes the already known narrow sleeve-cylinder 102 with the rotation shaft 316 and the rotor at its center and the compressor 306 at the top.
(101) The double compression sub-chambers 312.sub.ν are connected to the inlet collector-chambers 110.sub.ν of the heat-exchangers 132.sub.ν through the double ducts 337.sub.ν which terminate on the two opposite sides of the inlet collector-chambers 110.sub.ν directing alternately, due to the dual-action, the superheated vapors from two different and opposite points of the collector-chambers, increasing the heat transfer coefficient and the overall efficiency of the heat-exchanger. See also
(102) In another variation there may be only a single vapor duct 337.sub.ν from each sub-chamber 312.sub.ν to the corresponding inlet collector-chamber 110.sub.ν.
The Operation of the Compressor 306 and the MVC-MEE/MED System of FIGS. 8a, 8b, 9, 10, 11, 12
(103) The similarities of the operation of the compressor 306 and the MVC-MEE/MED of
(104) The feed-water 40 is pre-heated at the known specific temperature by both the rejected brine 136.sub.4 of the fourth stage and the desalinated water 44.sub.ν and is supplied to the evaporation chamber L.sub.1 of the first stage.
(105) The brine 136.sub.1 is pumped from the bottom of the evaporation chamber L.sub.1 and is sprayed through the overlying spray nozzle system 139.sub.1 externally onto the bundle of horizontal tubes 133.sub.1 of the water-vapor heat-exchangers 132.sub.1 in the interior of which flows the superheated vapor of the first stage, which descends through the ducts 337.sub.1 and is distributed to the tubes 133.sub.1 via the inlet collector-chamber 110.sub.1.
(106) The saturated vapor produced, descends along with the sprayed brine in the basin 131.sub.1, where, due to the lower pressure created at the compressor's suction side, is sucked up vigorously and rises through the vertical duct-chamber 114.sub.1 in the suction pre-chamber 346.sub.1 to be compressed.
(107) The superheated vapor condenses and as a condensate and desalinated water 44.sub.1, flows along the length of the horizontal tubes 133.sub.1 and descends to the bottom of the opposite terminal collector-chamber 111.sub.1 of the condensates. The process is repeated in the other stages, as per known.
(108) In another variation, the evaporation chambers d.sub.ν and L.sub.ν, as already developed in the two previous embodiments of MVC-MEE/MED, with the heat-exchangers incorporated in their interior, the intermediate vertical duct 46.sub.ν/114.sub.ν and the compressor with the suction pre-chambers 246.sub.ν/346.sub.ν, could also be used for MVC-MSF applications.
(109) As such, the water-vapor heat-exchangers eC.sub.ν of the pre-heating feed-water 40 of MVC-MSF, will take the place of the vapor-water heat-exchangers 32.sub.ν/132.sub.ν inside the evaporation chambers d.sub.ν and L.sub.ν and no particular condensation chamber C.sub.ν will be required.
(110) The condensate (desalinated water) is collected, as in the case of MVC-MEE/MED, from the bottom of their heat-exchangers' eC.sub.ν in the peripheral channels 41.sub.ν/111.sub.ν. Obviously the pumping and sprayer system of the brine is not needed in the MVC-MSF application and will be removed.
(111)
(112) The vanes are parallel to each other and are mounted to a common horizontal shaft 51, perpendicular to their surface, which moves reciprocally and linearly by a drive mechanism.
(113) The operation of the new embodiment is absolutely analogous to that already described in
(114) The compression chambers 52.sub.ν are developed in the upper part of the unit and preferably outside the evaporation chambers b.sub.ν (b.sub.1-b.sub.3). Under the evaporation chambers b.sub.ν are located the condensation chambers of the water-vapor heat-exchangers 54.sub.ν (54.sub.1-54.sub.3) corresponding to the stages, while in the present variation the heat-exchangers are a bundle of straight horizontal long tubes 53 into which feed-water 40 circulates and is gradually pre-heated.
(115) There are also here the relevant vapor suction and compression both, check-valves 524.sub.ν and 525.sub.ν, as well as ducts 543a and 543b respectively, communicating with the evaporation chambers b.sub.ν (b.sub.1-b.sub.3) and the respective condensation chambers of the heat-exchangers 54.sub.ν (54.sub.1-54.sub.3).
(116) The feed-water 40, after being pre-heated, enters initially the collector 555, is distributed to the long tubes 53, is pre-heated gradually to the known specific temperature t.sub.a (corresponding to the boiling temperature of the brine of the first stage) and through the terminal collector 556, the pipe 47 and the control-valve 548, enters the evaporation chamber b.sub.1 of the first stage, where the known flash evaporation and condensation process follows, as described in
(117) The compression ratio (CR) as well as the temperatures rise, are also here independently regulated parameters.
(118) In another variation the compressor 506 and the compression chambers are located between heat-exchanger chambers 54.sub.ν (54.sub.1-54.sub.3) and evaporation chambers b.sub.ν (b.sub.1-b.sub.3), whereby the lengths of the ducts 543a and 543b will be significantly shorter. Not designed.
(119) In another variation, the chambers of the heat-exchangers 54.sub.ν are located in the same plane and adjacent to the evaporation chambers b.sub.ν of the respective stages. Not designed.
(120) In another variation the evaporation chambers b.sub.ν are cylindrical, the compressor 506 and the cylindrical compression chambers are located within the respective evaporation chambers b.sub.ν, and the heat-exchangers 54.sub.ν with the horizontal long tubes of the bundle of feed-water are developed on a peripheral cylindrical sector-sleeve coaxially around the evaporation chambers b.sub.ν covering them along the entire length. Not designed.
(121) In another variation the heat-exchangers 54.sub.ν are located within the evaporation chambers b.sub.ν. Not designed.
(122) In another general variation the heat-exchangers instead of being tubular are plate-like.
(123) There will also be variants of Multi-Stage Desalination units MVC-MEE/MED where the compressor is of cylindrical type 506.
(124) The complete independence of the stages allows them to be divided in smaller, standard and prefabricated modules, in order large plants/units to be easily transported in containers.
(125) In another variation, the vanes' surfaces of the rotary-radial compressors are trapezoidal or of another shape, whereby the roof of the compressor is of a correspondingly shaped surface.
(126) In another variation of the rotary-radial compressors, instead of gradually and stepwise increasing the height of the compression chambers, by keeping constant the length of the radius of their vanes, the radius is stepwise increased by keeping constant the height of the compression chambers. Also the evaporation chambers may be of different types e.g. of dynamic type with moving-rotating parts, etc.
(127) A common feature of all the variants of MVC-MEE/MED and MVC-MSF of the present invention is that the multi-stage desalination, resembles and consists essentially of an array of co-operating independent single-effect desalination units arranged and connected in series, with simple common connections and synergies with each other, such as:
(128) a) the brine 36.sub.ν circulating from stage to stage, b) the desalinated water 44.sub.ν circulating from stage to stage, c) the pre-heating of the feed-water in the common multi-stream external heat-exchanger, d) the pre-heating of the feed-water from the last to the first stage through a common water-vapor heat-exchanger.
(129) The last synergy/feature d) is the main one for the variants MVC-MSF, but it could also exist as complementary to MVC-MEE/MED variants.
(130) Additionally, the three main elements of each stage (e.g. compression chambers, evaporation and heat-exchanger chambers) of the variants of
(131) The same thing happens in the case of parallelepiped evaporation chambers of linear arrangement.
Benefits in General
(132) Increased production for the same vapor suction volume, since both independent suction of the saturated vapor of each stage and compression/condensation of the superheated vapor within the same stage, occurs. Meaning that vapors of clearly higher temperatures and therefore of lower specific volume (containing a greater mass of water vapor) are sucked in comparison to the prior art which sucks saturated vapor by a single compressor, only from the last and colder stage, whose vapor has the largest specific volume of the unit and contains therefore the smallest mass of water vapor.
(133) Increased production due to augmented suction volume as the suction is more intense due to lower pressure created at the inlet of each suction sub-chamber of the compression chambers.
(134) Reduced heat-exchangers' surface, due to increased overall heat transfer coefficient (caused by the increased velocity and forced movement of superheated vapors in the condenser/heat-exchanger areas).
(135) Reduced energy cost per unit produced (m.sup.3 of desalinated water) due to reduction of entropy, because of independent and partial compression in very small steps (smaller CRs and smaller temperature differences Δt.sub.ν between the stages).
(136) More precise control of the state's conditions and the smallest permissible temperature differences (Δt.sub.ν) because of independent control, adjustment and operation of the stages {a smaller overall temperature difference ΔT.sub.max (since ΔT.sub.max=ΣΔt.sub.ν) and a reduction of the specific energy consumption, is achieved}.
(137) Increased number of stages for the same overall maximum temperature difference ΔT.sub.max (=ΣΔt.sub.ν) of the unit (higher efficiency) due to easier and more effective control of very small temperature differences (Δt.sub.ν).
(138) Faster startup of process, as suction and compression are performed simultaneously from multiple chambers and smaller CRs.
(139) Reduce volume of the unit and ability to manufacture and transport more productive units.
(140) Apart from the obvious balance of the preferably dissimilar (gradually increased) surfaces of the rotor's vanes, there are also methods to compensate, the rotational and reciprocating masses-movements of the system, caused by the rotating torques that are continuously changing direction, minimizing the vibrations.
(141) In the case of installing more than one unit, every two similar units mounted to a common frame, will rotate synchronized, at the same time, in opposite directions.
(142) In another variation a unit is placed exactly above the other (arrangement in pagoda layout), both units are mounted in a common frame with rotors and shafts laying in the same vertical axis, driven by the same drive mechanism, which transmits, at the same time, opposite rotational torques to both rotors.
(143) Also two units could be installed horizontally, in series, on a single and common base frame with a common drive transmitting opposite rotational torques. Not designed.
(144) In the case of cylindrical reciprocating compressors 506 wherein the movement is linear, there are provided:
(145) a) a mass attached to the drive mechanism which moves, at any time, opposite to the main movement of the compressor shaft 51, or b) (in the case of more than one unit) every two similar and aligned units (with the horizontal shafts 51 laying in the same axis) with a common frame, are moved synchronized, but opposite to each other, having the same drive unit positioned between them and at the center of their straight and aligned arrangement (boxer layout). Not designed.
(146) The compression ratio (CR) adjustment system includes and utilizes all the known techniques of the reciprocating compressors of positive displacement for gases and vapors, such as: the adjusting techniques of the opening and closing pressures of the suction 21.sub.ν and compression 22.sub.ν check-valves, etc.
(147) The adjustment of flow rates is usually done by varying the size of the surface of the vanes, the reciprocating movement frequency, but also by varying the cross-section of: a) the internal by-pass of adjustable sliding openings 123 onto the vane surface or b) the external by-pass ducts with adjustable control-valves, affecting accordantly the recirculated flow rate portion. Not designed.
(148) In reciprocating motion systems of constant frequency (mainly at units of very large sizes), the adjustment of the flow rates is set in discrete steps and rates of the nominal flow, e.g. at 100%, 75%, 50%, 25% or 0% of it.
(149) Applications: a) in the chemical industry and the food industry for the condensation of aqueous solutions by the gradual evaporation and condensation of a substantial part of the water or other solvents, b) in the environment protection by further condensation of the brine rejected from reverse osmosis desalination plants {Zero Liquid Discharge (ZLD)} or by evaporating water from aqueous solutions of toxic and industrial waste in order to reduce their volume and facilitate their transport and neutralization.
(150) Particularly in desalination, wherein due to the highest quality of desalinated water achieved (≥5-6 ppm TDS) it can be used throughout the broad spectrum of the chemical industry where high quality water is required.