Filtration device for the filtration of a liquid metal or an alloy thereof, and a filtration method using said filtration device
10434569 ยท 2019-10-08
Assignee
Inventors
- Marcel Gouin (Sherbrooke, CA)
- Maurice Lacasse (Stoke, CA)
- Jay FRITZKE (North East, PA, US)
- Michael Bouchard (Sherbrooke, CA)
Cpc classification
Y02P10/20
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B22D18/04
PERFORMING OPERATIONS; TRANSPORTING
B22D43/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
B22D43/00
PERFORMING OPERATIONS; TRANSPORTING
B22C9/08
PERFORMING OPERATIONS; TRANSPORTING
C22B9/02
CHEMISTRY; METALLURGY
Abstract
Filtration devices are provided with original structural features to allow a better stiffness of the same and prevent the possibility of being distorted and/or driven under the pressure of a flux of liquid metal or an alloy thereof which is passing there through. Said features may consist of a ridge portion extending the periphery of a filtration device, a rim portion provided in double-basket filtration devices, or a particular M shape filtration device.
Claims
1. A filtration device for filtering a liquid metal or an alloy thereof, wherein the filtration device has a lower face, an upper face, a peripheral edge, a main portion, and a peripheral portion surrounding the main portion, the peripheral portion being shaped to form a concave cavity at the upper face and a convex rim at the lower face, wherein the peripheral portion is further provided with a ridge portion surrounding the peripheral portion, and wherein the filtration device is made of a rigidified fabric comprising a plurality of heat resistant fibers or a plurality of threads of heat resistant fibers, impregnated with a composition consisting essentially of a mixture of a product A and a product B: the product A being obtained by polymerisation of saccharide units contained in a mixture consisting essentially of the saccharide units, water and at least one additive selected from the group consisting of acids, inorganic wetting agents, and acid phosphate adhesives; and the product B consisting of at least one inorganic colloidal binding agent, the composition being in a thermoset stage.
2. The filtration device according to claim 1, wherein the main portion is a dome having its summit oriented toward the upper face.
3. The filtration device of claim 2, further provided with an insert made of a magnetisable material for handling of the filtration device with a tool provided with a magnet.
4. The filtration device of claim 3, wherein the heat resistant fibers are glass fibers, silica fibers or a mixture thereof, and wherein the product A is obtained by caramelization of a mixture M comprising sucrose, water, and optionally at least one additive selected from the group consisting of acids, inorganic wetting agents and acid phosphate adhesives.
5. The filtration device according to claim 1, wherein the main portion has a frustoconical shape having its summit oriented toward the upper face.
6. The filtration device of claim 5, further provided with an insert made of a magnetisable material for handling of the filtration device with a tool provided with a magnet.
7. The filtration device of claim 6, wherein the heat resistant fibers are glass fibers, silica fibers or a mixture thereof, and wherein the product A is obtained by caramelization of a mixture M comprising sucrose, water, and optionally at least one additive selected from the group consisting of acids, inorganic wetting agents and acid phosphate adhesives.
8. A filtration device for filtering a liquid metal or an alloy thereof, wherein the filtration device comprises a first basket and a second basket, wherein the first basket has an outer wall and a cavity defined by an inner wall, an end wall and an opening opposite to the end wall, wherein the second basket has an outer wall and a cavity defined by an inner wall, an end wall and an opening opposite to the end wall, wherein the opened end of the first basket is housed in the cavity of the second basket to define a filtration body having a structural shape and orientation and comprising a cavity, an upper face, a lower face, and a side face, wherein when the outer wall of the first basket is sized to fit against the inner wall of the second basket, the outer wall of the second basket corresponds at least in part to the side face of the filtration body, or when the outer wall of the second basket is sized to fit against the inner wall of the first basket, the outer wall of the first basket corresponds at least in part to the side face of the filtration body, wherein the outer wall of the first basket has a top portion and side portion joined by a peripheral portion forming a rim; and the outer wall of the second basket has a bottom portion and a side portion joined by a peripheral portion forming a rim, and wherein the filtration device is made of a rigidified fabric comprising a plurality of heat resistant fibers or a plurality of threads of heat resistant fibers, impregnated with a composition consisting essentially of a mixture of a product A and a product B: the product A being obtained by polymerisation of saccharide units contained in a mixture consisting essentially of the saccharide units, water and at least one additive selected from the group consisting of acids, inorganic wetting agents, and acid phosphate adhesives; and the product B consisting of at least one inorganic colloidal binding agent, the composition being in a thermoset stage.
9. The filtration device according to claim 8, wherein the end wall of the first basket corresponds to the lower face of the filtration device, and the end wall of the second basket corresponds to the upper face of the filtration device.
10. The filtration device according to claim 8, wherein the filtration device further comprises a filtration pad within the cavity.
11. The filtration device of claim 8 further provided with an insert made of a magnetisable material for handling of the filtration device with a tool provided with a magnet.
12. The filtration device of claim 8, wherein the heat resistant fibers are glass fibers, silica fibers or a mixture thereof, and wherein the product A is obtained by caramelization of a mixture M comprising sucrose, water, and optionally at least one additive selected from the group consisting of acids, inorganic wetting agents and acid phosphate adhesives.
13. A filtration device for the filtration of a molten metal or an alloy thereof, wherein the filtration device is a fabric comprising a plurality of metal threads or a fabric comprising a plurality of rigidified heat resistant fibers, the filtration device having a shape that is to be housed within a housing of a casting mold provided with at least one filing inlet, wherein the housing is a parallelepiped, wherein the fabric is defining a M shaped filter, the M shape filter having a pair of parallel branches which are to be respectively substantially coplanar with a pair of opposite end of the parallelepipedic housing, and an arch portion having a tip which is either to be oriented toward the the cavity or opposite to the cavity, and wherein the rigidified fabric of heat resistant fibers obtained by thermosetting a composition consisting essentially of a mixture of a product A and a product B; the product A being obtained by polymerisation of saccharide units contained in a mixture consisting essentially of the saccharide units, water and at least one additive selected from the group consisting of acids, inorganic wetting agents, and acid phosphate adhesives; and the product B consisting of at least one inorganic colloidal binding agent impregnated in a fabric comprising a plurality of heat resistant fibers.
14. The filtration device of claim 13, wherein the tip of the arch portion is to be oriented opposite to the cavity.
15. The filtration device of claim 13, wherein the fabric comprises a plurality of stainless steel threads woven together.
16. The filtration device of claim 13, wherein the filtration device is made of a rigidified fabric comprising a plurality of heat resistant fibers woven together.
17. The filtration device of claim 13, wherein the heat resistant fibers are glass fibers, silica fibers or a mixture thereof, and wherein the product A is obtained by caramelization of a mixture M comprising sucrose, water, and optionally at least one additive selected from the group consisting of acids, inorganic wetting agents and acid phosphate adhesives.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The present invention will be better understood with reference to the following drawings:
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EXAMPLES
Example 1
(24) A composition according to the invention was prepared as follows:
(25) In a first step, a mixture M was prepared by admixing the following ingredients together in a stainless steel container. More particularly, the ingredients of the mixture consist of: Food graded table sucrose (i.e. table sugar) sold by Lantic Inc. under the trade name Lantic (hereinafter called sucrose in the present example). Tap water as available from the Applicant's laboratory facilities located in the city of Sherbrooke, Quebec, Canada. Laboratory grade phosphoric acid 75% wt. (i.e. a mixture of 75 wt % H.sub.3PO.sub.4 and 25 wt % water). Calcium phosphate monobasic sold by Spectrum Chemical Mfg. Corp., including Ca(H.sub.2SO.sub.4).H.sub.2O. Aluminum Ammonium SulfateLab Grade sold by ACP Chemical Inc., including AlNH.sub.4(SO.sub.4).sub.2.2H.sub.2O.
(26) A 1 kg of mixture M containing 55.0 wt % of sucrose; 41.5 wt % of tap water; 1.1 wt % of phosphoric acid 75% wt.; 1.0 wt % aluminium ammonium sulfate; and 1.4 gr (1.4 wt %) calcium phosphate monobasic.
was prepared by adding into a stainless steel container, 550 gr of sucrose, 41.5 gr of tap water, 1.1 gr of phosphoric acid 75%, 1.0 gr of aluminum ammonium sulfate, and 1.4 gr of calcium phosphate monobasic, and then mixed together with a paint mixer until obtaining an homogeneous mixture M.
(27) Then, the resulting homogeneized mixture was subjected to heating until a temperature of 100 C. to 103 C. was reached for at least 5 minutes, to thereby form a caramel defining said product A. Said product A was thereafter allowed to cool at room temperature.
(28) In a second step, 515 gr. of a product B which is a colloidal dispersion of submicron-sized silica particles in the form of tiny spheres, in an alkaline aqueous solution and sold under the trademark NALCO 1144, said NALCO 1144 having the following properties:
(29) TABLE-US-00003 Colloidal Silica as SiO.sub.2: 40%, pH @ 25 C.: 9.9, Average particle Diameter: 14 nm, Specific Gravity: 1.30, Viscosity: 15 cP, and Na.sub.2O 0.45%;
was added to the 1.0 kg of the product A obtained in the previous step, and then ingredients A and B were mixed together with said paint mixer. The mixing was carried out at room temperature until an homogeneous composition was obtained (i.e. about 10 minutes). Said composition was comprising about 66 wt % of the product A and about 34 wt % of the product B.
Example 2
(30) A fabric 107 (see
(31) More particularly, a fabric 104 of glass fibers (see
Example 3
(32) A rigidified, thermoplastic fabric of glass fibers was prepared according to a method wherein a fabric of glass fibers as obtained from example 2 was impregnated with the composition as defined in example 1, to thus obtain a fabric impregnated with said composition.
(33) More particularly, the fabric was successively passed in the a reservoir containing said composition and then between a pair of opposite rubber-rolls of a two-rollers impregnator, as schematically illustrated in the enclosed
(34) More particularly, according to the present example, it is to be noted that a composition 101 was contained in a reservoir 103 located above a pair of rubber-rolls 105. The fabric 107 was passed successively across the composition 101 and then between the pair of opposite rubber-rolls 105, which are pressed one against the other, to push an amount of the composition within the openings of the fabric 107. Then, while exiting the rubber-rolls 103, the pressure against the fabric 107 was stopped, an amount of the composition 101 pushed within the opening 102 (see
(35) The impregnated fabric so obtained was then subjected to a heating treatment in a continuous oven at a temperature of about 160 C. for about 2 minutes to place the composition impregnated therein into a softened thermoplastic state.
(36) Then, the thermosettable fabric so obtained (i.e. impregnated with the composition transformed into a thermoplastic state) was ready to be used for further treatments such as an optional forming the thermoplastic fabric into a desired size and/or shape, and then a thermosetting treatment to thermoset the composition and provide a rigidified fabric by cross-linking of the heat resistant glass fibers. If not used immediately, the fabric may be allowed to cool at room temperature.
Example 4
(37) The fabric impregnated with the composition obtained from example 3, was cut into a piece of 7 inches48 inches, and then was subjected to a thermosetting treatment in an oven at 450 C. for 2 minutes, in order to rigidify the fabric by cross-linking of the glass fibers.
(38) Then, the rigidified fabric so obtained can be used as a filter for liquid metal as such liquid aluminum or aluminum alloy. This rigidified fabric which originates from a 40L type fabric of glass fiber as defined hereinabove, is provided with openings of 0.0255 cm.sup.2. When used for the filtration of liquid aluminum, this filter showed to be as efficient as those of the prior art without the drawbacks.
Example 5
(39) The thermoplastic fabric obtained from example 3, cooled at room temperature, was cut into a piece of 3 inches3 inches and then placed in a hot mold consisting of a pair of opposite mold halves, to thereby soften and mold the piece of fabric into a desired shape by compression-moulding. Then, the shaped fabric was allowed to cool.
(40) Then, the shaped fabric so obtained was ready to be used for further treatments such as a thermosetting treatment to thermoset the composition and provide a rigidified fabric by cross-linking of the heat resistant glass fibers.
Example 6
(41) The shaped fabric obtained from example 5, was subjected to a thermosetting treatment in an oven at 450 C. for 2 minutes, in order to rigidify the fabric by cross-linking of the glass fibers of the threads.
(42) Then, the shaped rigidified fabric so obtained can be used as a filter for liquid metal as such liquid aluminum or aluminum alloy, especially in a low pressure casting process. This shaped rigidified fabric which originates from a 40L type fabric of glass fiber as defined hereinabove, is provided with openings of 0.0255 cm.sup.2. When used for the filtration of liquid aluminum, this filter showed to be as efficient as those of the prior art made of metallic threads, without the drawbacks.
Example 7
(43) The fabric obtained from example 3 was cut into a piece of 3 inches3 inches, and while being still in a softened thermoplastic state, placed in a cold mold consisting of a pair of opposite mold halves, to thereby obtain a fabric into a desired shape by compression-moulding.
(44) Then, the shaped fabric so obtained was subjected to a thermosetting treatment in an oven at 450 C. for 2 minutes, in order to rigidify the fabric by cross-linking of the glass fibers.
(45) Thereafter, the shaped rigidified fabric so obtained can be used as a filter for liquid metal as such liquid aluminum or aluminum alloy, especially in a low pressure casting process. When used for the filtration of liquid aluminum, this filter showed to be as efficient as those of the prior art made of metallic threads, without the drawbacks.
(46) Of course, alternatively, if the fabric obtained from example 3 had cooled at room temperature, said fabric may be reheated to the softened thermoplastic state by any appropriate means.
Example 8
(47) A rigidified fabric of glass fibers F was prepared according to a method wherein a fabric 107 of threads 108 of glass fibers 110 (see
(48) More particularly, and according to the present example and with reference to
(49) The impregnated fabric so obtained was then subjected to a heating treatment in a continuous oven at a temperature of about 160 C. for about 2 minutes to place the composition impregnated therein into a softened thermoplastic state.
(50) Then, the fabric F so obtained (i.e. impregnated with the composition transformed into a thermoplastic state) was ready to be used for further treatments such as an optional forming the thermoplastic fabric into a desired size and/or shape, and then a thermosetting treatment to thermoset the composition and provide a rigidified fabric by cross-linking of the heat resistant glass fibers of the threads. If not used immediately, the fabric may be allowed to cool at room temperature.
Example 9
(51) The fabric F obtained from example 8 and cooled at room temperature, was cut into a piece of 3 inches3 inches and then placed in a hot mold consisting of a pair of opposite mold halves, to thereby soften and mold a filtration device 201a (see
(52) Then, the shaped fabric so obtained was ready to be used for further treatments such as a thermosetting treatment to thermoset the composition and provide a rigidified fabric by cross-linking of the heat resistant glass fibers of the threads of glass fibers.
Example 10
(53) The fabric F obtained from example 8 was cut into a piece of 3 inches3 inch, and while being still in a softened thermoplastic state, placed in a cold mold consisting of a pair of opposite mold halves, to form a filtration device 201a (see
(54) Then, the filtration device 201a was subjected to a thermosetting treatment in an oven at 450 C. for 2 minutes, in order to rigidify the fabric by cross-linking of the glass fibers. Of course, alternatively, if the fabric obtained from example 8 had cooled at room temperature, said fabric may be reheated to the softened thermoplastic state by any appropriate means for moulding, and then subjected to the thermosetting treatment. This filtration device 201a made of said rigidified fabric, which originates from a 40L type fabric of glass fiber as defined hereinabove, is provided with openings of 0.0255 cm.sup.2.
(55) With reference to
a source of pressurized air P entering 205a into the reservoir 203a to displace the liquid aluminum alloy from the reservoir, through the rising channel 225a of the rising tube 213a, the filtration device 201a and the filing inlet 207a, to fill the cavity 209a. After cooling of the liquid aluminum alloy contained in the cavity 209a to form the molded article, and removal of the same form the cavity 209a, the resulting article is provided with the filtration device trapped in a protrusion. The air initially contained in the cavity 209a is evacuated via openings 227a.
(56) The diffuser 211a applies a slight pressure against the main portion 257a of the filtration device 201a, in order to help maintaining the filtration device 201a in place during the priming of the same. Indeed, it is well known that the during the priming phase of a filter, the pressure applied by the liquid starting to flow there through is greater and then said pressure falls when the flow of liquid is established.
(57) More particularly, with reference to
(58) More particularly, with reference to
(59) Optionally, at the center of the main portion 257a, a stainless steel 229a staple can be provided. This staple 229a allows the handling of the filtration device 201a with a tool provided with a magnet, for an easy positioning of the peripheral portion 259a and ridge portion 275a against a corresponding seat portion 223a (especially with a magnetic tool and more preferably with a magnetic tool operated by a robot). Also, the presence of the staple 229a allows to confirm the proper positioning of the filtration device 201a against the seat portion 223a (e.g with X-rays devices).
(60) The particular structure and orientation of the filtration device 201a in the low pressure casting installation 202a allows to efficiently filter the liquid aluminum alloy before filling of the cavity 209a. More particularly, said filtration device 201a showed to be as efficient as those of the prior art made of metallic threads, without the drawbacks.
Example 11
(61) A piece of the fabric (see
(62) The first basket 451a has an outer wall 453a and a cavity 455a defined by an inner wall 457a, an end wall 459a and an opening opposite 461a to the end wall 459a.
(63) Then, another piece of the fabric obtained from example 8, cooled at room temperature, was cut into a piece of 3 inches3 inches and then placed in a hot mold consisting of a pair of opposite mold halves, to thereby soften and mold a second basket 471a (see
(64) The second basket 471a has an outer wall 473a and a cavity 475a defined by an inner wall 477a, an end wall 479a and an opening opposite to the end wall 479a.
(65) The opened end of the first basket 451a is housed within the cavity 475a of the second basket 471a to define a filtration device 401a having a structural shape and orientation and being provided with a cavity 493a, an upper face 495a, a lower face 497a, and a side face 499a. Optionally, as illustrated in
(66) The end wall 459a of the first basket 451a corresponds to the lower face 493a of the filtration body 401a, and the end wall 479a of the second basket 471a corresponds to the upper face 495a of the filtration body 401a. The outer wall 453a of the first basket 451a is sized to be friction fit against the inner wall 477a of the second basket 471a, the outer wall 453a of the second basket 471a corresponds at least in part to the side face 499a of the filtration body 491a (i.e. the filtration device 401a). Alternatively, the outer wall 479a of the second basket 471a can be sized to be friction fit against the inner wall 457a of the first basket 451a, the outer wall 473a of the first basket 471a corresponds at least in part to the side face 499a of the filtration body 491a (i.e. the filtration device 401a).
(67) Then upper face 495a of the filtration device 401a has a main portion 492a and the lower face 497a of the filtration device 401a has a peripheral portion 494a, said main portion 495a being for positioning against a diffuser 411a positioned across a filling inlet 407a of a mold of the low pressure casting installation 402a; and said peripheral portion 494a is for positioning across an upper opening 421a of a rising tube 413a of a low pressure casting installation 402a, said peripheral portion 494a being oriented for positioning against a seat portion 423a of the rising tube 413a surrounding the upper opening 421a.
(68) The first basket and the second basket are each provided with a structural feature that allow to further prevent the filtration device 401a to be deformed by the pressure of a flow of liquid metal or alloy passing there through. More particularly, the first basket 451a has a bottom portion and side portion joined by a peripheral portion 452a forming a rim 454a; and the outer wall of the second basket 471a has a top portion and a side portion joined by a peripheral portion 472a forming a rim 474a.
(69) Then, the filtration device 401a so obtained, which is still in a thermoplastic stage, was ready for further treatments such as a thermosetting treatment to thermoset the composition and provide the filtration device 401a made of a rigidified fabric by cross-linking of the heat resistant glass fibers which forming the threads of the fabric. Preferably, the thermoset filtration device 401a is prepared by submitting the thermoplastic filtration device to a thermosetting treatment in an oven at 450 C. for 2 minutes, in order to rigidify the fabric by cross-linking of the glass fibers forming the threads of the fabric.
(70) Then the filtration device 401a is ready for use for filtering a liquid metal as such liquid aluminum or aluminum alloy, especially in a low pressure casting process. As this filtration device 401a was made of said rigidified fabric, which originates from a 40L type fabric of glass fiber as defined hereinabove, is provided with openings of 0.0255 cm.sup.2. When used for the filtration of liquid aluminum, this filtration device 401a showed to be as efficient as those of the prior art made of metallic threads, without the drawbacks.
(71) More particularly, referring to
a source of pressurized air P entering 405a into the reservoir 403a to displace the liquid aluminum alloy from the reservoir, through the rising channel 425a of the rising tube 413a, the filtration device 401a and the filing inlet 407a, to fill the cavity 409a. After cooling of the liquid aluminum alloy contained in the cavity 409a to form the molded article, and removal of the same form the cavity 409a, the resulting article is provided with the filtration device trapped in a protrusion. The air initially contained in the cavity 409a is evacuated via openings 427a.
(72) The diffuser 411a applies a slight pressure against the main portion 457a in order to help maintaining the filtration device 401a in place during the priming of the same. Indeed, it is well known the during the priming phase of a filtration device, the pressure applied by the liquid starting to flow through said filtration device is greater, and then said pressure falls when the flow of liquid is established. As mentioned above, when used for the filtration of liquid aluminum, this filtration device 401a showed to be as efficient as those of the prior art made of metallic threads, without the drawbacks.
Example 12
(73) The fabric obtained from example 3 was cut into a piece of 5 inches2 inches, and while being still in a softened thermoplastic state, placed in a cold mold consisting of a pair of opposite mold halves, to thereby obtain a fabric into a desired shape by compression-moulding. The fabric so obtained was M shaped.
(74) Then, the M shaped fabric so obtained was subjected to a thermosetting treatment in an oven at 450 C. for 2 minutes, in order to rigidify the fabric by cross-linking of the glass fibers.
(75) Thereafter, the shaped rigidified fabric so obtained can be used as a filter for liquid metal as such liquid aluminum or aluminum alloy, especially in a gravity casting process.
(76) Of course, alternatively, if the fabric obtained from example 3 had cooled at room temperature, said fabric may be reheated to the softened thermoplastic state by any appropriate means.
Example 13
(77) The fabric obtained from example 3 was cut into a piece of 5 inches2 inches, and while being still in a softened thermoplastic state, placed in a hot mold consisting of a pair of opposite mold halves, to thereby obtain a fabric into a M shape by compression-molding. The shaped fabric so obtained was M shaped.
(78) Then, the M shaped fabric was subjected to a thermosetting treatment in an oven at 450 C. for 2 minutes, in order to rigidify the fabric by cross-linking of the glass fibers.
(79) Thereafter, the M shaped rigidified fabric 643 (see
Example 14
(80) This example illustrates the casting of an article made of aluminum in a two-part mold 621. This two-part mold 621 comprises a part 623 and a part 625 (see
(81) As illustrated in
(82) In the present example, said ceramic foam filter 641 was replaced by a M shape filter 643 as obtained from example 13. More particularly, the M shape filter 643 was of such size to have its volume is completely housed within the mold housing 635, with parallel branches 636 substantially coplanar with opposite wall 635a of the housing 635 and the tip of the arch 638 of the M oriented opposite to the mold cavity 629.
(83) Then, liquid aluminum was poured in the opening 637 to flow through the conduit 633, the M shape filter positioned in the housing 635, and cavity filing inlet and the cavity 629 itself. More particularly, this process of pouring liquid aluminum into the mold is called gravity casting process.
(84) Then, once the liquid aluminum has cool, both parts of the two-part mold are separated and the solid article is removed.
(85) The portion of the solid article corresponding to the conduit 633, the housing 635 and containing the M shape filter 621 was separated from the finished article and recovered for recycling purposes. The M shape filter reveals to be efficient without the drawbacks of ceramic foam filters.
(86) The present invention has been described with respect to its preferred embodiments. The description and the drawings are only intended to aid to the understanding of the invention and are not intended to limit its scope. It will be clear to those skilled in the art that numerous variations and modifications can be made to the implementation of the invention without being outside the scope of the invention. Such variations and modifications are covered by the present invention. The invention will be now described in the following claims: