Method to recover LPG and condensates from refineries fuel gas streams
11692772 · 2023-07-04
Assignee
Inventors
Cpc classification
F25J2205/80
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2210/12
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0238
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2205/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/72
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2205/90
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2240/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2260/60
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0242
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2215/64
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2210/62
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0233
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2210/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/70
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2205/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0209
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2205/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2215/62
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2210/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0252
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2205/40
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2240/40
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/74
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2220/62
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0219
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A method to recover hydrocarbonfractions from refineries gas streams involves a pre-cooled heat refinery fuel gas stream mixed with a pre-cooled and expanded supply of natural gas stream in an inline mixer to condense and recover at least C.sub.3.sup.+ fractions upstream of a fractionator. The temperature of the gas stream entering the fractionator may be monitored downstream of the in-line mixer. The pre-cooled stream of high pressure natural gas is sufficiently cooled by flowing through a gas expander that, when mixed with the pre-cooled refinery fuel gas, the resulting temperature causes condensation of heavier hydrocarbon fractions before entering the fractionator. A further cooled, pressure expanded natural gas reflux stream is temperature controlled to maintain fractionator overhead temperature. The fractionator bottoms temperature may be controlled by a circulating reboiler stream.
Claims
1. A method of recovering fractions from a refinery fuel gas stream using a stream of high pressure natural gas from a natural gas distribution pipeline as a source of cooling to condense and fractionate at least C.sub.3.sup.+ fractions from the refinery fuel gas stream, the method comprising the steps of: expanding the stream of high pressure natural gas from the natural gas distribution pipeline at a pipeline pressure to obtain a stream of cold natural gas; using the stream of cold natural gas to cool the refinery fuel gas stream; using a fractionator, separating at least C.sub.3.sup.+ fractions from the cooled refinery fuel gas stream; recovering a liquid stream comprising the at least C.sub.3.sup.+ fractions from a bottom of the fractionator; and recovering a separated fuel gas stream comprising natural gas derived from the refinery fuel gas stream and from the stream of high pressure natural gas, wherein at least a portion of the separated fuel gas stream comprises an overhead stream from the fractionator.
2. The method of claim 1, wherein the at least C.sub.3.sup.+ fractions in the recovered liquid stream comprise C.sub.2.sup.+ fractions.
3. The method of claim 1, further comprising the step of separating hydrogen gas from the refinery fuel gas stream or the overhead stream.
4. The method of claim 3, wherein the hydrogen gas is recovered using a membrane separator or by liquefying a hydrogen-containing gas stream.
5. The method of claim 1, wherein the refinery fuel gas stream is cooled by the stream of cold natural gas in one or more heat exchangers, by direct mixing, or both in one or more heat exchanger and by direct mixing.
6. The method of claim 1, wherein using the fractionator comprises one or more of the following steps: injecting at least one reflux stream at a top of the fractionator to control an overhead stream temperature of the fractionator; providing trays in the fractionator for heat exchange and fractionation; and circulating a stream of natural gas from a lower section of the fractionator through a reboiler circuit to control a fractionator bottom temperature.
7. The method of claim 1, further comprising the step of injecting at least one reflux stream at a top of the fractionator, the at least one reflux stream being derived from the stream of high pressure natural gas, a supply of liquid natural gas, or both the stream of high pressure natural gas and the supply of liquid natural gas.
8. The method of claim 1, wherein at least a portion of the natural gas derived from the stream of high pressure natural gas in the separated fuel gas stream is mixed with the refinery fuel gas stream as a fuel calorific value replacement for the at least C.sub.3.sup.+ fractions separated from the refinery fuel gas stream.
9. The method of claim 1, further comprising a preconditioning step comprising cooling one or more of the following: a temperature of the refinery fuel gas stream prior to being cooled by the stream of cold natural gas, and the stream of high pressure natural gas prior to expansion.
10. The method of claim 9, wherein the preconditioning step comprises using an ambient air exchanger or one or more heat exchangers that are cooled by one or more streams of natural gas from the fractionator.
11. The method of claim 1, further comprising the step of cooling the stream of high pressure natural gas prior to expansion such that the stream of cold natural gas is cooled to cryogenic temperatures, the cryogenic temperatures being used to cool and condense methane from the refinery fuel gas stream.
12. The method of claim 1, wherein the stream of cold natural gas is separated into a liquid stream and a gas stream, the liquid stream being injected into the fractionator and the gas stream being injected into the fractionator or a heat exchanger for cooling the refinery fuel gas stream.
13. The method of claim 1, further comprising the step of separating hydrogen gas from the refinery fuel gas stream.
14. The method of claim 13, wherein separating hydrogen gas comprises passing the refinery fuel gas stream through a membrane separator, or cooling the refinery fuel gas stream to condense hydrocarbon fractions.
15. A refinery fractions recovery plant for recovering liquid fractions from a refinery fuel gas stream using a supply of high pressure natural gas from a natural gas pipeline as a source of cooling to condense at least C.sub.3.sup.+ fractions from the refinery fuel gas stream, the refinery fractions recovery plant comprising: a fuel gas inlet for receiving the refinery fuel gas stream; a fractionator that conditions the refinery fuel gas stream to condense at least C.sub.3.sup.+ fractions; a liquid outlet connected to a bottom of the fractionator for recovering a stream of liquid fractions; a fuel gas outlet that is connected to receive an overhead stream from the fractionator; and a gas expander having an inlet that receives the high pressure natural gas stream from the natural gas pipeline at a pipeline pressure, and an outlet that is connected to inject expanded natural gas at one or more points between the fuel gas inlet and the fuel gas outlet, at least one point being located at or upstream of the fractionator such that the expanded natural gas is used to condition a temperature of the fractionator.
16. The refinery fractions recovery plant of claim 15, wherein the fractionator conditions the refinery fuel gas stream to condense C.sub.2.sup.+ fractions.
17. The refinery fractions recovery plant of claim 15, further comprising a hydrogen separator connected between the fuel gas inlet and the fuel gas outlet for separating hydrogen gas carried by from the refinery fuel gas stream.
18. The refinery fractions recovery plant of claim 17, wherein the hydrogen separator comprises a membrane separator or a condenser that condenses hydrocarbons and a phase separator for separating the hydrogen gas from the condensed hydrocarbons.
19. The refinery fractions recovery plant of claim 15, further comprising one or more heat exchangers upstream of the fractionator that cools the refinery fuel gas stream.
20. The refinery fractions recovery plant of claim 19, wherein the one or more heat exchangers are cooled by ambient air, by the expanded natural gas, or by one or more streams of natural gas from the fractionator.
21. The refinery fractions recovery plant of claim 15, wherein the fractionator further comprises one or more of a group consisting of: at least one reflux stream inlet at a top of the fractionator that controls an overhead temperature of the fractionator; one or more trays for heat exchange and fractionation; and at least one reboiler circuit at a lower section of the fractionator, the at least one reboiler circuit being used to control a fractionator bottom temperature.
22. The refinery fractions recovery plant of claim 15, wherein the fractionator comprises a reflux inlet connected to a supply of liquid natural gas.
23. The refinery fractions recovery plant of claim 15, further comprising a heat exchanger upstream of the gas expander for conditioning a temperature of the high pressure natural gas stream prior to expansion.
24. The refinery fractions recovery plant of claim 15, further comprising a separator for separating the expanded natural gas into a liquid stream and a vapor stream, the liquid stream and the vapor stream being injected at different points.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) These and other features of the invention will become more apparent from the following description in which reference is made to the appended drawings, the drawings are for the purpose of illustration only and are not intended to in any way limit the scope of the invention to the particular embodiment or embodiments shown, wherein:
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DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
(10) The method will now be described with reference to
(11) As set forth above, this method was developed with a view for cold, and cryogenic if required, recovery of heavier hydrocarbon fractions from typical refinery fuel gas streams. In this context, refinery fuel gas streams refers to the streams of hydrocarbons that are produced from the refineries' feedstocks, and that are intended to be used by the same refinery as a fuel source. Refinery fuel gas streams may be produced intentionally, as a byproduct, or as a combination thereof, and typically include methane and heavier hydrocarbons, i.e. C.sub.2.sup.+. Refinery fuel gas streams also typically include hydrogen, which is used in the refining process. Refinery fuel gas streams are typically supplemented by a pressurized natural gas stream from a natural gas distribution system. This pressurized natural gas stream may be used to ensure there is sufficient fuel gas to meet the needs of the refinery, and, in the case of the present methods, may be used to replace the heat value of the hydrocarbons that are removed from the fuel gas stream. Refinery fuel gas streams are not intended to be transported, such as by pipeline or pressurized vessel, to another location as is the case with natural gas in a natural gas distribution system, but are instead intended to be used within the refinery in which they were produced. As will be understood, the process may be expanded or modified to recover hydrogen and lighter hydrocarbons, such as C.sub.3.sup.+ fractions, C.sub.2.sup.+ fractions, hydrogen, or other gas fractions in the refinery fuel gas stream, the separation of which may require the use of cryogenic temperatures, and which may be generated using the principles discussed below. The descriptions of the different methods below should, therefore, be considered as examples.
(12) In general, the method and apparatus described herein uses the pressurized natural gas stream from a natural gas distribution system as a source of coolth as it is expanded. The cooled, expanded natural gas stream interacts with the refinery fuel gas stream to condense and separated different gas fractions that make up the refinery gas stream. This may be a direct interaction, such as by direct mixing inline or in a fractionator, or by way of a heat exchanger. Eventually, some or all of the expanded, and now warmed natural gas from the original pressurized natural gas stream will be part of the fuel gas stream that is produced by this method and apparatus to supplement the refinery fuel gas stream, as well as to make up the lost caloric content due to the removal of certain gas fractions. The streams may be combined by mixing in a cooling step, or by combining the natural gas with the overhead stream from the fractionator, depending on the manner in which the natural gas is used as a source of coolth. In addition to removing heavier hydrocarbons, from the refinery gas stream, hydrogen may also be separated from the refinery gas stream as a separate stream, which can then be recycled into the refinery process, or used for other purposes. This may be done by condensing the hydrocarbon fractions in the refinery gas stream, or by using a membrane separator. As will be understood, the cooling steps and separation may occur at various points throughout the process, while maintaining the refinery fuel gas stream at the initial pressure and without the need of expanding and recompressing the gas stream. Examples of this will be apparent from the discussion below.
(13) Referring to
(14) The refrigerant used in the process is a pre-cooled, pressure-expanded natural gas stream mixed into the refinery fuel gas stream that provides two functions in the process. First, the stream acts as a refrigerant to cool and condense C.sub.3.sup.+ fractions, and second, to simultaneously replace the heating value in the refinery fuel gas stream of the recovered C.sub.3.sup.+ fractions. In the depicted example, high pressure natural gas is supplied through line 24 and pre-cooled in a heat exchanger 17. A slipstream of the pre-cooled gas stream 25 is routed through a gas expander 26. During expansion, for every 1 bar pressure drop the gas temperature drops between 1.5 and 2 degrees Celsius. The cryogenic temperatures generated are dependent on the delta P between streams 7 and 25. Generally, the temperatures may be colder than −100 Celsius. The expansion may be accomplished using an expander valve 32 as shown in
(15) A main feature is the simplicity of the process, which eliminates the use of external refrigeration systems and simultaneously replaces the heating value of the recovered fractions. Another feature is the flexibility of the process to meet various operating conditions since only natural gas is added on demand to meet process operations parameters. The process also provides for a significant savings in energy when compared to other processes since no external refrigeration facilities are employed as in conventional cryogenic refrigeration processes. The process can be applied at any refinery fuel gas plant size.
(16) Referring to
(17) Referring to
(18) Referring to
(19) Referring to
(20) Referring to
(21) Referring to
(22) A refinery fuel gas stream 2 is routed through valve 3 into reboiler heat exchanger 704 to provide heat to fractionator 10 bottoms to control liquids stream 31 composition. The colder refinery fuel gas stream 705 is then compressed by shaft power 729 in compressor 706; the compressed stream 707 is first cooled by ambient air temperature in heat exchanger 708. The ambient cooled refinery rich fuel gas stream 709 is cooled in heat exchanger 710 by a pressurized liquid stream 744. The refinery rich fuel gas stream 711 is then further cooled in heat exchanger 712, where the cooler refinery rich fuel gas stream 713 enters a separator 714. The condensed liquid fractions stream 715 is depressurized by a JT valve 716 and enters fractionator 10 through stream 717. The separated gaseous stream 719, mainly C.sub.2.sup.+ fractions and hydrogen enter membrane unit 720 to separate and recover the hydrogen fraction stream 721. The remaining separated gases are routed through stream 722 to a JT valve 723 and through stream 724 enter fractionator 10. The natural gas stream 24 is first precooled in a heat exchanger 726 by a pressurized liquid stream 741 to get a colder natural gas stream 727. The colder natural gas stream 727 is depressurized in gas expander 728 to generate a cryogenic natural gas stream 730 which is routed to a separator 731 and separated into a condensed natural gas stream 735 and a gaseous cold natural gas stream 732. The condensed natural gas stream 735 is routed to fractionator 10 through a valve 736 as a reflux stream. The gaseous cold natural gas stream 732 is routed through valve 733 and stream 734 into stream 724 to fractionator 10. The fractionator overhead stream 14 gives up its coolth energy to refinery rich fuel gas stream 711 before exiting the unit through stream 743 through valve 21 into the fuel gas header 23. The bottom stream 31 is pressurized in a liquid pump 740 to get pressurized liquid stream 741. The pressurized liquid stream is used to cool the natural gas stream 24 and refinery fuel gas stream 709 before exiting the system through stream 745. It is understood those familiar in the art that membrane unit 720 can be replaced by a PSA unit for hydrogen recovery. Moreover, should hydrogen recovery not be required then unit 720 can be replaced by a gas expander to generate more electricity and colder temperatures in stream 722.
(23) Referring to
(24) In this patent document, the word “comprising” is used in its non-limiting sense to mean that items following the word are included, but items not specifically mentioned are not excluded. A reference to an element by the indefinite article “a” does not exclude the possibility that more than one of the element is present, unless the context clearly requires that there be one and only one of the elements.
(25) The scope of the claims should not be limited by the preferred embodiments set forth in the examples, but should be given a broad purposive interpretation consistent with the description as a whole.