NANOENERGETIC MATERIAL COMPOSITE-BASED SOLID PROPELLANT, METHOD OF PREPARING THE SAME, AND PROJECTILE USING THE SAME
20190300453 ยท 2019-10-03
Assignee
Inventors
Cpc classification
C06B21/0083
CHEMISTRY; METALLURGY
C06B23/007
CHEMISTRY; METALLURGY
C06B33/02
CHEMISTRY; METALLURGY
C06B31/02
CHEMISTRY; METALLURGY
C06B33/00
CHEMISTRY; METALLURGY
F02K9/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
C06B21/00
CHEMISTRY; METALLURGY
C06B33/00
CHEMISTRY; METALLURGY
C06B31/02
CHEMISTRY; METALLURGY
Abstract
Disclosed are a nanoenergetic material composite-based solid propellant, a method of preparing the same, and a projectile using the same. The propellant includes: potassium nitrate-sucrose (KNSU) composite powder; and nanoenergetic material (nEM) composite powder in a solid powder form mixed with the KNSU composite powder to prepare a KNSU/nEM propellant. The method includes: preparing KNSU composite powder; preparing nEM composite powder; and preparing a KNSU/nEM propellant by mixing the KNSU composite powder and the nEM composite powder in a solid powder form. The projectile includes: a clay block; a clay nozzle responsible for releasing the pressure generated by explosion of a propellant; and a propellant lamination area disposed between the clay block and the clay nozzle. Upon ignition of the KNSU/nEM propellant, the nEM composite powder increases the combustion rate and combustion temperature of a potassium nitrate-sucrose (KNSU) propellant.
Claims
1. A nanoenergetic material composite-based solid propellant, comprising: potassium nitrate-sucrose (KNSU) composite powder; and nanoenergetic material (nEM) composite powder in a solid powder form mixed with the potassium nitrate-sucrose (KNSU) composite powder to prepare a KNSU/nEM propellant, wherein upon ignition of the KNSU/nEM propellant, the nanoenergetic material (nEM) composite powder increases the combustion rate and combustion temperature of a potassium nitrate-sucrose (KNSU) propellant.
2. The nanoenergetic material composite-based solid propellant according to claim 1, wherein the potassium nitrate-sucrose (KNSU) composite powder is prepared by physically mixing sucrose (C.sub.12H.sub.22O.sub.11) and potassium nitrate (KNO.sub.3) in a mass ratio of 35 to 65 (C.sub.12H.sub.22O.sub.11:KNO.sub.3=35:65).
3. The nanoenergetic material composite-based solid propellant according to claim 1, wherein the nanoenergetic material (nEM) composite powder is prepared by mixing Al nanoparticles (Al NPs) as a fuel material and CuO nanoparticles (CuO NPs) as an oxidizing material in a mass ratio of 30 to 70 (Al NPs:CuO NPs=30:70).
4. The nanoenergetic material composite-based solid propellant according to claim 1, wherein the KNSU/nEM propellant is KNO.sub.3/C.sub.12H.sub.22O.sub.11/Al/CuO composite powder.
5. The nanoenergetic material composite-based solid propellant according to claim 1, wherein 1 to 5 wt % of the nanoenergetic material (nEM) composite powder is contained in the KNSU/nEM propellant.
6. A method of preparing a nanoenergetic material composite-based solid propellant, comprising: preparing potassium nitrate-sucrose (KNSU) composite powder; preparing nanoenergetic material (nEM) composite powder; and preparing a KNSU/nEM propellant by mixing the potassium nitrate-sucrose (KNSU) composite powder and the nanoenergetic material (nEM) composite powder in a solid powder form, wherein upon ignition of the KNSU/nEM propellant, the nanoenergetic material (nEM) composite powder increases the combustion rate and combustion temperature of a potassium nitrate-sucrose (KNSU) propellant.
7. The method according to claim 6, wherein, in the preparing of potassium nitrate-sucrose (KNSU) composite powder, sucrose (C.sub.12H.sub.22O.sub.11) and potassium nitrate (KNO.sub.3) are ground, dried, and physically mixed in a mass ratio of 35 to 65 (C.sub.12H.sub.22O.sub.11:KNO.sub.3=35:65).
8. The method according to claim 6, wherein, in the preparing of nanoenergetic material (nEM) composite powder, Al nanoparticles (Al NPs) as a fuel material and CuO nanoparticles (CuO NPs) as an oxidizing material are mixed in a mass ratio of 30 to 70 (Al NPs:CuO NPs=30:70).
9. The method according to claim 6, wherein, in the preparing of a KNSU/nEM propellant, KNO.sub.3/C.sub.12H.sub.22O.sub.11/Al/CuO composite powder is prepared.
10. The method according to claim 6, wherein, in the preparing of a KNSU/nEM propellant, the nanoenergetic material (nEM) composite powder is contained in an amount of 1 to 5 wt %.
11. A projectile using a nanoenergetic material composite-based solid propellant, comprising: a clay block disposed at an upper portion thereof; a clay nozzle disposed at a lower portion thereof and responsible for releasing the pressure generated by explosion of a propellant; and a propellant lamination area disposed between the clay block and the clay nozzle, wherein a KNSU/nEM propellant prepared by mixing potassium nitrate-sucrose (KNSU) composite powder and nanoenergetic material (nEM) composite powder is laminated in the propellant lamination area, and upon ignition of the KNSU/nEM propellant, the nanoenergetic material (nEM) composite powder increases the combustion rate and combustion temperature of a potassium nitrate-sucrose (KNSU) propellant.
12. The projectile according to claim 11, wherein a potassium nitrate-sucrose (KNSU) propellant not mixed with the nanoenergetic material (nEM) composite powder and a KNSU/nEM propellant containing the nanoenergetic material (nEM) composite powder are alternately laminated in the propellant lamination area.
13. The projectile according to claim 12, wherein as a result of alternately laminating the potassium nitrate-sucrose (KNSU) propellant not mixed with the nanoenergetic material (nEM) composite powder and the KNSU/nEM propellant containing the nanoenergetic material (nEM) composite powder, a thrust inflection point is generated in a section where a type of a propellant is changed.
14. The projectile according to claim 12, wherein propulsion characteristics of the propellants, such as combustion rate, combustion time, maximum thrust, and average thrust, are controlled by changing the lamination number and lamination order of the propellant materials.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0032] The above and other objects, features and advantages of the present disclosure will become more apparent to those of ordinary skill in the art by describing exemplary embodiments thereof in detail with reference to the accompanying drawings, in which:
[0033]
[0034]
[0035]
[0036]
[0037]
[0038]
[0039]
[0040]
[0041]
[0042]
DETAILED DESCRIPTION
[0043] Hereinafter, preferred embodiments for a nanoenergetic material composite-based solid propellant, a method of preparing the same, and a projectile using the same according to the present disclosure will be described in detail as follows.
[0044] The features and advantages of a nanoenergetic material composite-based solid propellant, a method of preparing the same, and a projectile using the same according to the present disclosure will be explained in detail through embodiments described below.
[0045]
[0046] In the KNSU/nEM composite-based solid propellant of the present disclosure, nanoenergetic materials (nEMs) may be combusted at high speed and high temperature, whereby the combustion rate and combustion temperature of a KNSU propellant may be increased, and complete combustion of the KNSU propellant may be induced.
[0047] To improve the performance of a solid propellant, rapid combustion of the propellant and efficient release of high temperature and pressure generated during combustion are required. Nanoenergetic materials (nEMs) are solid propellants that can meet these requirements.
[0048] According to the present disclosure, a novel solid propellant having improved thrust characteristics as compared to conventional solid propellants was developed by applying nanoenergetic materials to preparation of a solid propellant.
[0049] Specifically, a potassium nitrate-sucrose (KNSU) composite propellant known as a solid propellant was mixed with aluminum nanopowder and copper oxide nanopowder as nanoenergetic materials (nEMs) in a specific ratio to prepare a KNSU/nEM composite-based solid propellant (KNSU/nEM composite propellant). The prepared KNSU/nEM composite-based solid propellant was compared with a conventional KNSU propellant through a small projectile propulsion test to determine whether the thrust of the KNSU/nEM composite-based solid propellant was improved.
[0050] In addition, to perform a thrust test, a motor for projectiles using the KNSU/nEM composite-based solid propellant was manufactured and installed in a small projectile. Through a thrust test, the ceiling of the small projectile, the combustion rate and propulsion time of the propellant, and the like were analyzed. Based on the obtained results, the propulsion characteristics of the propellant were analyzed. As a result, it was confirmed that the propulsion performance of the KNSU/nEM composite-based solid propellant (KNSU/nEM composite propellant) was improved.
[0051] In the present disclosure, to prepare a potassium nitrate-sucrose (KNSU)/nanoenergetic material (nEM) composite-based solid propellant, sucrose (C.sub.12H.sub.22O.sub.11) microparticles having an average diameter of approximately 10 m and potassium nitrate (KNO.sub.3) microparticles having an average diameter of approximately 2 m were used as the components of the potassium nitrate-sucrose (KNSU) propellant.
[0052] In addition, aluminum (Al) nanoparticles having an average diameter of approximately 100 nm as a fuel metal and copper oxide (CuO) nanoparticles having an average diameter of approximately 100 nm as an oxidizing material were used as the components of the nanoenergetic materials (nEMs).
[0053]
[0054] The nanoenergetic material composite-based solid propellant (KNSU/nEM propellant) according to the present disclosure is prepared by mixing KNSU composite powder prepared by physically mixing sucrose (C.sub.12H.sub.22O.sub.11) and potassium nitrate (KNO.sub.3) in a mass ratio of 35 to 65 (C.sub.12H.sub.22O.sub.11:KNO.sub.3=35:65) and nanoenergetic material (nEM) composite powder in a solid powder form prepared by mixing aluminum (Al) nanoparticles as a fuel material and copper oxide (CuO) nanoparticles as an oxidizing material.
[0055] The nanoenergetic material (nEM) composite powder is preferably prepared by mixing Al nanoparticles (Al NPs) and CuO nanoparticles (CuO NPs) in a mass ratio of 30 to 70 (Al NPs:CuO NPs=30:70), without being limited thereto.
[0056] In addition, the KNSU/nEM propellant is KNO.sub.3/C.sub.12H.sub.22O.sub.11/Al/CuO composite powder.
[0057] Preferably, 1 to 5 wt % of the nanoenergetic material (nEM) composite powder is contained in the KNSU/nEM propellant, without being limited thereto.
[0058] In the KNSU/nEM composite-based solid propellant according to the present disclosure, the nanoenergetic materials (nEMs) are combusted at high speed and high temperature, whereby the combustion rate and combustion temperature of the KNSU propellant are increased and complete combustion of the KNSU propellant is induced.
[0059] The preparation process of the nanoenergetic material composite-based solid propellant according to the present disclosure will be described in detail as follows.
[0060]
[0061] First, to prepare a conventional KNSU solid propellant, sucrose (C.sub.12H.sub.22O.sub.11) and potassium nitrate (KNO.sub.3) were ground (S201), dried at 80 C. for 30 minutes, and physically mixed in a mass ratio of 35 to 65 (C.sub.12H.sub.22O.sub.11:KNO.sub.3=35:65) to prepare KNSU composite powder (S202).
[0062] In addition, to prepare the nanoenergetic materials (nEMs), Al nanoparticles (Al NPs) and CuO nanoparticles (CuO NPs) were prepared in a mass ratio of 30 to 70 (Al NPs:CuO NPs=30:70) (S203).
[0063] Then, the Al NPs and the CuO NPs were mixed in an ethanol solution for about 30 minutes by applying ultrasonic energy (ultrasonic output=170 W, ultrasonic frequency=40 kHz) to the Al NPs and the CuO NPs (S204). The generated colloidal fluid was placed in a convection oven and heated at 80 C. for 30 minutes to remove the ethanol solution by evaporation to obtain nEM composite powder (S205).
[0064] Finally, the prepared KNSU composite and nEM powder were physically mixed in a solid powder form to prepare KNSU/nEM (i.e., KNO.sub.3/C.sub.12H.sub.22O.sub.11/Al/CuO) composite powder (S206). Scanning electron microscope (SEM) images of the prepared KNSU and KNSU/nEM composite powders are shown in
[0065] The real photographic images of the KNSU and KNSU/nEM composite powers illustrated in
[0066] (a)(b) of
[0067] In
[0068] As shown in (a)(b) of
[0069] In addition, as shown in (c)(d) of
[0070] The propulsion performance of the nanoenergetic material composite-based solid propellant according to the present disclosure was analyzed as follows.
[0071] To evaluate the propulsion performance of the KNSU/nEM composite-based solid propellant according to the present disclosure upon ignition, as shown in
[0072] In the case of the thrust measurement test, a projectile motor was fixed to an apparatus for thrust measurement, and then when the solid propellant was ignited through a fuse, the generated thrust was measured through a load cell installed in the apparatus for thrust measurement.
[0073] The small projectile was mainly made of a light plastic material, and a parachute was provided in the upper portion of the projectile and a motor for projectiles was installed at the lower end of the projectile.
[0074] The motor for projectiles was made using a PVC pipe. In the PVC pipe, a propellant for generating thrust, a delay layer for controlling the release timing of a parachute, and a black powder for generating pressure required for the release of the parachute were charged. In addition, a clay nozzle was used to eject pressure generated by explosion of the propellant.
[0075] Propellant performance and field propulsion test results for the small projectile are as follows.
[0076] The results of the thrust measurement test for evaluating the performance of the KNSU/nEM composite-based solid propellant are shown in
[0077] The thrust of a motor for projectiles filled with 40 g of each KNSU/nEM (0 & 3 wt %)-based solid propellant was measured.
[0078] It can be seen that, upon ignition, the flame is brighter and larger in the case of the KNSU/nEM (3 wt %) composite propellant than in the case of the KNSU/nEM (0 wt %) composite propellant, and explosive gas is also strongly ejected in the case of the KNSU/nEM (3 wt %) composite propellant.
[0079] As shown in the graph showing thrust measurement results measured by the load cell installed in the thrust measurement system of
[0080] In the total impulse (I.sub.total) comparison graph of
[0081] In the case of total impulse, it can be confirmed that the total impulse (16.3 Ns) of the KNSU/nEM (3 wt %) composite propellant is higher than that (14.4 Ns) of the KNSU/nEM (0 wt %) propellant, showing an approximate 13% increase. In addition, it can be confirmed that the total impulse (total impulse in an area that generates thrust greater than the weight of a projectile) that can be used for propulsion of an actual projectile is increased from 13.3 Ns to 15.7 Ns, showing an approximate 18% increase.
[0082] These results indicate that the nanoenergetic materials (nEMs) in the KNSU/nEM composite-based solid propellant are combusted at high speed and high temperature, leading to a rise in the combustion rate and combustion temperature of the KNSU propellant and complete combustion of the KNSU propellant.
[0083] Based on the thrust measurement results of
[0084]
[0085] It can be confirmed that, compared to the case when the nEMs are not included in the KNSU propellant (i.e., 0 wt % nEMs), when 3 wt % of the nEMs is contained in the KNSU propellant, propulsion altitude, speed, and acceleration over time are significantly improved.
[0086] In addition, the measurement results of the acceleration of a small projectile provided with each KNSU/nEM (0 & 3 wt %) composite-based solid propellant in field testing are shown in
[0087]
[0088] It was confirmed that, after ignition of the projectile motor, the small projectile was successfully propelled with strong exhaust gas ejection, and about 4 seconds after launch, the small projectile reached the maximum altitude point, a parachute was ejected, and the small projectile stably dropped.
[0089] (a)(b) of
[0090] In the case of the KNSU/nEM (3 wt %) composite-based solid propellant, the highest flight altitude was about 81.4 m, showing a higher value than the highest flight altitude (59.1 m) of the KNSU/nEM (0 wt %) solid propellant. That is, compared to the KNSU/nEM (0 wt %) solid propellant, in the case of the KNSU/nEM (3 wt %) solid propellant, the highest flight altitude was increased approximately 38%. In addition, the KNSU/nEM (3 wt %) solid propellant and the KNSU/nEM (0 wt %) solid propellant respectively exhibited maximum accelerations of 8.8 gs and 7.4 gs, showing an approximate 19% increase in the case of the KNSU/nEM (3 wt %) solid propellant compared to the KNSU/nEM (0 wt %) solid propellant.
[0091] In addition, these results are similar to the simulation results shown in
[0092] The structure of a projectile using the nanoenergetic material composite-based solid propellant according to the present disclosure will be described in detail as follows.
[0093]
[0094] As shown in
[0095] The thrust characteristics of the projectile having such a configuration depending on the lamination structure of a solid propellant will be described as follows.
[0096] (a) of
[0097] (b) of
[0098] (c) of
[0099] (d) of
[0100] It can be confirmed that, in the first stage (4 to 6 seconds) in which the propellant containing KNSU (100 wt %) is combusted, a relatively low thrust occurs, and in the second stage (6 to 10 seconds) in which the propellant containing KNSU (96 wt %) and nEMs (4 wt %) is combusted, a high thrust occurs.
[0101] In addition, (e) of
[0102] It can be confirmed that in the first stage (3 to 5 seconds) in which the propellant containing KNSU (96 wt %) and nEMs (4 wt %) is combusted, a very high thrust occurs, and in the second stage (5 to 8 seconds) in which the propellant containing KNSU (100 wt %) is combusted, a somewhat high thrust occurs.
[0103] In addition, (f) of
[0104] These results indicate that the propulsion characteristics of propellants, such as combustion rate, combustion time, maximum thrust, and average thrust, may be controlled depending on the lamination number and lamination order of propellant materials.
[0105] When propellants are laminated, the content of the nanoenergetic material (nEM) composite powder does not have to be constant, and the content of the nanoenergetic material (nEM) composite powder may be changed depending on the purpose of a projectile.
[0106] As described above, according to the present disclosure, a KNSU/nEM composite-based solid propellant was prepared by mixing a conventional potassium nitrate-sucrose (KNSU) solid propellant and nanoenergetic materials (nEMs) including Al nanoparticles and CuO nanoparticles, and a small projectile equipped with a projectile motor charged with the KNSU/nEM composite-based solid propellant was designed and manufactured. Then, through ignition and launch tests performed in a field, it was confirmed that the thrust of the KNSU/nEM composite-based solid propellant was improved.
[0107] Therefore, according to the present disclosure, a novel KNSU/nEM composite solid propellant having improved thrust may be obtained by applying nEMs to a solid propellant. That is, a high performance solid propellant containing nanoenergetic materials may be prepared.
[0108] The nanoenergetic material composite-based solid propellant, the method of preparing the same, and the projectile using the same according to the present disclosure have the following effects.
[0109] First, a solid propellant (KNSU/nEM composite propellant) having improved performance can be prepared by mixing a potassium nitrate-sucrose (KNSU) composite propellant and nanoenergetic materials (nEMs).
[0110] Second, a solid propellant having improved performance including a high combustion rate and excellent heat and pressure emission characteristics can be prepared based on nanoenergetic materials (nEMs).
[0111] Third, a solid propellant prepared based on nanoenergetic materials (nEMs) can be applied to a small projectile. In this case, the propulsion characteristics of the propellant can be analyzed by analyzing the ceiling, the combustion rate of the propellant, and propulsion time to improve the propulsion performance of the small projectile.
[0112] Fourth, in a KNSU/nEM composite-based solid propellant, since combustion of the nanoenergetic materials (nEMs) proceeds at high speed and high temperature, the combustion rate and combustion temperature of the KNSU propellant can be increased, and complete combustion of the KNSU propellant can be induced.
[0113] Fifth, reliable simulation prediction results of a small projectile can be obtained by calculating flight altitude, speed, acceleration, mass change, and the like using a MATLAB program based on the results of measurement of thrust when propelling the small projectile as a pre-launch simulation of the small projectile.
[0114] Sixth, the content of nEMs included in a KNSU propellant with critical significance can be determined by securing the measured thrust data of a small projectile according to change in the content of nEMs included in the KNSU propellant.
[0115] It will be understood by those skilled in the art that various changes may be made in the present disclosure without departing from the spirit and scope of the disclosure as defined by the appended claims.
[0116] In addition, the preferred embodiments should be considered in a descriptive sense only and not for purposes of limitation. Therefore, the scope of the disclosure is defined not by the detailed description of the disclosure but by the appended claims, and all differences within the scope will be construed as being included in the present disclosure.
[0117] The present disclosure relates to preparation of a solid propellant. Specifically, the present disclosure relates to a nanoenergetic material composite-based solid propellant (KNSU/nEM composite propellant) having excellent performance and prepared by mixing a potassium nitrate-sucrose (KNSU) propellant and nanoenergetic materials (nEMs), a method of preparing the nanoenergetic material composite-based solid propellant, and a projectile using the nanoenergetic material composite-based solid propellant.