DISTRIBUTION SYSTEM FOR A PROCESS FLUID FOR CHEMICAL AND/OR ELECTROLYTIC SURFACE TREATMENT OF A SUBSTRATE
20240141534 ยท 2024-05-02
Inventors
- Andreas Gleissner (D?briach, AT)
- Georg HOFER (Stadl-Predlitz, AT)
- Marianne Kolitsch-MataIn (Villach, AT)
Cpc classification
C25D17/001
CHEMISTRY; METALLURGY
C25D5/08
CHEMISTRY; METALLURGY
International classification
C25D5/08
CHEMISTRY; METALLURGY
C25D17/00
CHEMISTRY; METALLURGY
Abstract
The disclosure relates to a distribution system for a process fluid for a chemical and/or electrolytic surface treatment of a substrate, comprising: a distribution body, and a substrate holder, wherein the substrate holder has a substrate holder length (L) and a substrate holder width (W) and is configured to hold the substrate to be treated, wherein the distribution body comprises several openings for a process fluid and/or an electric current, wherein the distribution body and the substrate holder are moveable relative to each other, wherein the distribution body has a distribution body length (l) and a distribution body width (w), and wherein the distribution body length (l) is smaller than the substrate holder length (L).
Claims
1. A distribution system for a process fluid for a chemical and/or electrolytic surface treatment of a substrate, comprising: a distribution body, and a substrate holder, wherein the substrate holder has a substrate holder length (L) and a substrate holder width (W) and is configured to hold the substrate to be treated, wherein the distribution body comprises several openings for a process fluid and/or an electric current, wherein the distribution body and the substrate holder are moveable relative to each other, wherein the distribution body has a distribution body length and a distribution body width (w), and wherein the distribution body length is smaller than the substrate holder length (L).
2. The distribution system according to claim 1, comprising at least two distribution bodies being arranged on opposite sides of the substrate holder.
3. The distribution system according to claim 1, wherein the substrate holder length (L) is a multiple of the distribution body length.
4. The distribution system according to claim 1, comprising multiple distribution bodies being arranged adjacent to each other on a side of the substrate holder, wherein the sum of the distribution body length of the multiple distribution bodies is equal to or larger than the substrate holder length (L).
5. The distribution system according to claim 1, wherein the distribution body length amounts to about 50% or less of the substrate holder length (L), preferably about 20% or less of the substrate holder length (L).
6. The distribution system according to claim 1, wherein the distribution body width (w) is essentially equal to or larger than the substrate holder width (W).
7. The distribution system according to claim 1, wherein the distribution body is moveable relative to the substrate holder.
8. The distribution system according to claim 1, wherein the substrate holder is moveable relative to the distribution body.
9. The distribution system according to claim 1, further comprising a drive unit configured to move the distribution body and the substrate holder relative to each other.
10. The distribution system according to claim 9, wherein the drive unit is configured to move the distribution body and the substrate holder parallel or with an angle relative to each other.
11. (canceled)
12. The distribution system according to claim 9, wherein the drive unit is configured to drive the distribution body and/or the substrate holder.
13. The distribution system according to claim 9, wherein the drive unit is configured to drive a relative scanning motion between the distribution body and the substrate holder along the substrate holder length (L).
14. The distribution system according to claim 9, wherein the drive unit is configured to drive a relative agitation motion between the distribution body and the substrate holder along the substrate holder width (W) and/or along the substrate holder length (L).
15. The distribution system according to claim 1, wherein the openings of the distribution body comprise jet holes configured to direct the process fluid in the direction of the substrate holder.
16. The distribution system according to claim 1, wherein the openings of the distribution body comprise drain holes configured to drain off the process fluid from the substrate holder.
17. The distribution system according to claim 1, wherein the distribution body comprises at least one anode (12).
18. The distribution system according to claim 1, wherein the substrate holder and/or the substrate is the cathode.
19. The distribution system according to claim 1, further comprising: a rinsing unit configured to provide a liquid to rinse the substrate holder and/or the substrate, and/or a drying unit configured to provide a gas flow to dry the substrate holder and/or the substrate, wherein the rinsing unit and/or the drying unit is/are arranged at the distribution body or is/are provided as a separate part separate to the distribution body.
20. (canceled)
21. A processing line for a chemical and/or electrolytic surface treatment of a substrate, comprising: at least a distribution system according to claim 1, and at least a plating station, wherein the substrate is guided through the plating station in a transport direction (X), and wherein a surface of the substrate to be treated is arranged substantially perpendicular to the transport direction (X), or wherein the surface of the substrate to be treated is substantially aligned with the transport direction (X).
22. A distribution method for a chemical and/or electrolytic surface treatment of a substrate, comprising: providing a distribution body with several openings for a process fluid and/or an electric current, providing a substrate holder configured to hold the substrate to be treated, wherein the substrate holder has a substrate holder length (L) and a substrate holder width (W), the distribution body has a distribution body length and a distribution body width (w), and the distribution body length is smaller than the substrate holder length (L), and moving the distribution body and the substrate holder relative to each other.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0068] Exemplary embodiments of the disclosure will be described in the following with reference to the accompanying drawings:
[0069]
[0070]
[0071]
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[0073]
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[0075]
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DETAILED DESCRIPTION OF EMBODIMENTS
[0079]
[0080] The substrate holder 2 is of a rectangular shape, a length L of which extends in an X-direction, and a width W extends substantially perpendicular to the length L, in a Y-direction. The distribution body 3 has a rectangular shape having a length 1 and a width w, wherein the length 1 extends in the same direction as the length L of the substrate holder 2, but the length 1 of the distribution body 3 is smaller than the length L of the substrate holder 2. The width w of the distribution body 3 is substantially equal to the width W of the substrate holder 2.
[0081] In this embodiment, the substrate holder 2 is fixed in position and the distribution body 3 is movable relative to the substrate holder along the X-direction, which is shown by the
[0082]
[0083] Further, the distribution body 3 accommodates an anode 12 being one electrode of at least two electrodes to enable electrolytic treatment processes. The substrate holder 2 and/or the substrate 4 may act as a cathode 13 either by accommodating a cathode or by being connected to a cathode. For example, metal may be deposited on the substrate 4 by means of a galvanic reaction. The process fluid 28 is an electrolytic liquid and the electric field generated by the anode 12 and the cathode by means of the arrangement of the distribution body 3 comprising the anode 12 and the substrate 4 functioning as the cathode, always extends through the distribution body 3. By means of a suitable positioning of the distribution body 3 with regard to the substrate 4, regions of the substrate 4 may therefore be approached by the electrolytic liquid with a particularly uniform incoming flow and under a uniform electric field such that a reaction occurs uniformly at these locations.
[0084]
[0085]
[0086] The transport system 5 may be part of a processing line 16 as schematically and exemplarily shown in
[0095] The processing line 16 may comprise more or less processing steps. Additionally or alternatively, some of the processing steps may be included in one single chamber, e.g., the treating, the rinsing and the drying of the substrate 4.
[0096] Next, the substrate 4 enters the plating station 21. At the plating station 21, the substrate 4 is treated by means of the distribution body 3 as described above. When seen in the transport direction X, the length 1 of the distribution body 3 is smaller than the length L of the substrate 4. Thus, for treating the whole surface 8 of the substrate 4, the substrate 4, by means of the substrate holder 2, and/or the distribution body 3 need to be moved. It should be noted that
[0097] According to an exemplary embodiment, the relative movement between the substrate holder 2 holding the substrate 4 and the distribution body 3 is realized by moving the substrate holder 2 holding the substrate 4 relative to the distribution body 3 being mounted in a substantially fixed position. The fixed position means that the distribution body 3 is not moveable in the X-direction but is still capable of performing agitation and therefore, movable in the Y-direction and/or Z-direction.
[0098] The substrate 4 being arranged above the distribution body 3, regarding the Z-direction, is moving along the transport direction X (see also
[0099]
[0100]
[0101] With reference back to
[0102] According to another exemplary embodiment, the relative movement between the substrate holder 2 holding the substrate 4 and the distribution body 3 is realized by moving the distribution body 3 relative to the substrate holder 2 holding the substrate 4, being in a fixed position. The substrate 4 functioning as the cathode may be horizontally immersed in the process fluid 28. Regarding the Z-direction, the distribution body 3 is placed above the substrate 4, substantially parallel to the surface 8 to be treated and is movable in the X-direction allowing scanning the surface 8 of the substrate 4 from one end to the other end in the X-direction for treating the surface 8 of the substrate 4, e.g. by plating of a metal or a metal alloy onto the surface 8. As an alternative, the distribution body may be at least partially immersed, such that the anode 12 is immersed in the process fluid, and moved underneath the substrate holder 2 holding the substrate 4 with the surface 8 directed towards the distribution body 3. As a further alternative, the substrate 4 may be arranged between at least two distribution bodies 3, one distribution body 3 being arranged and moved above the substrate 4 and the other distribution body 3 being arranged and moved underneath the substrate 4.
[0103] In yet another embodiment, instead of placing the distribution body 3 substantially parallel to the surface 8 of the substrate 4, the distribution body 3 is placed substantially non-parallel to the surface 8 of the substrate 4 in order to provide for an additional design parameter to influence the deposition uniformity. Thus, the front face 10 of the distribution body 3 displays a variation in the distance from the substrate 4 in the X-direction.
[0104] For all above described embodiments, the vertical distance between the distribution body 3 and the substrate 4 is predefined for achieving a required electrolyte flow as well as a required current density distribution to obtain a high quality, uniform metal or metal alloy deposition. Further, the scanning speed, meaning the speed with which the relative movement is performed, is defined to mainly achieve the required plating thickness and uniformity distribution for the plating material, e.g. metal or metal alloy. Further, the applied current density, the deposition temperature, as well as the composition of the process fluid 28, e.g. concentration of the metal ions or ions from multiple metal species, are additional parameters for achieving a preferred plating speed and for defining the quality of the deposited layer. The scanning movement may be realized by moving the distribution body 3 and/or the substrate holder 2 by a drive unit (not illustrated).
[0105] Although, the anode 12 is described as being accommodated in the distribution body 3, thereby moving with the distribution body 3, the anode 12 may be provided separately from the distribution body 3 and/or in a stationary position.
[0106] With reference back to
[0107] Instead of performing the relative movement only in one direction once, it is also possible to perform the relative movements as a back-and-forth movement, such that the distribution body 3 may scan the substrate 4 two or multiple times.
[0108] Furthermore, it should be noted that the front face 10 of the distribution body refers to the face directed towards the substrate 4, and the surface 8 refers to the surface to be treated, which is directed towards the distribution body 3. Thus, seen in the Z-direction, when the substrate 4 is arranged above the distribution body 3, the surface 8 to be treated corresponds to the bottom surface of the substrate 4 and the front face 10 corresponds to the top face of the distribution body 3. When the substrate 4 is arranged underneath the distribution body 3, the surface 8 to be treated corresponds to the top surface of the substrate 4 and the front face 10 corresponds to the bottom face of the distribution body 3. In other words, the front face 10 of the distribution body and the surface 8 of the substrate 4 are arranged facing each other.
[0109]
[0118] The processing line 16 may comprise more or less processing steps. Additionally or alternatively, some of the processing steps may be included in one single chamber, e.g., the treating, the rinsing and the drying of the substrate 4.
[0119] Contrary to the exemplary processing line 16 illustrated in
[0120] Thus, according to the exemplary embodiment shown in
[0121] The treating station 21 may be built in a way to enable vertical processing of the substrate 4, wherein the at least one distribution body 3 may be scanning the surface 8 of the substrate 4 from top to bottom or from bottom to top and/or in an agitated mode, back and forth.
[0122] The rinsing station 22 and the drying station 23 may also be built in a vertical design for treating the substrate in a mainly vertical direction.
[0123] In this embodiment, the substrate 4 can be immersed in an electrolyte bath, e.g. in the processing fluid 28, and at least one distribution body 3 is scanning the substrate 4 from top to bottom or from bottom to top. The overall deposition process can also be carried out by a multiple scan repeated from one direction to the other, or through alternate scanning from varying sides of the substrate 4. In this case, the processing fluid 28 is supplied through an immersion-type system, e.g. a separate tank filled with the processing fluid 28 (not illustrated), and/or additionally from within the at least one distribution body 3, dispensing the processing fluid 28 onto at least one of the surfaces 8. The implementation may also include two distribution bodies 3, one on each side, or multiple distribution bodies 3, with more than one on each side. Only the substrate areas in the vicinity of a distribution body are being plated with material.
[0124] Alternatively, the substrate 4 may be supplied with the processing fluid 28 only from within the at least one distribution body 3 dispensing the required processing fluid 28 onto at least one of the surfaces 8.
[0125] According to a further embodiment, the substrate 4 may be supplied with the processing fluid 28 through a processing fluid film being formed by a thin processing fluid film being distributed from the top of the substrate 4 flowing downwards, thereby uniformly wetting the surface 8 to be treated, e.g. like a waterfall of processing fluid 28, and/or from within the at least one distribution body 3, dispensing the processing fluid 28 onto at least one of the surfaces 8.
[0126] In other embodiments, the pre-wetting station 20 and the treating station 21 may be included in the same processing chamber 17, configured to process the substrate 4 in a mainly vertical direction. Additionally, or alternatively, the rinsing station 22, 22 and the drying station 23, 23 may be integrated in one processing chamber 17.
[0127]
[0128] In another embodiment, the processing line 16 only comprises one processing chamber 17 within which the pre-wetting station 20, 20, the plating station 21, 21, the rinsing station 22, 22 and the drying station 23, 23 are arranged such that pre-wetting, plating, rinsing and drying of the substrate 4 is carried out within one processing chamber 17. During pre-wetting, rinsing and drying of the substrate 4, the at least one distribution body 3 can be located in a parking position, e.g. at the bottom of the processing chamber 17.
[0129] In yet another embodiment, a vertical, or partly vertical, or a mixed horizontal and vertical roll-to-roll processing of the substrate 4 may be implemented. In such case, the starting station 18 and the ending station 25 may be designed for supplying and receiving a substantially rectangular substrate 4 with an extremely long length, in a rolled-up status. The processing chambers 17 may be applied especially in a mixed orientation, e.g. the pre-wetting station 20 can be in a mainly horizontal design and operation mode while all the other processing chambers 17 are in a vertical implementation. It may also be possible to arrange the individual processing stations in a way to be able to perform multiple subsequent plating steps to obtain a higher throughput, and/or a better plating uniformity, and/or to deposit or plate different materials in a subsequent manner (see
[0130]
[0131] The first sub-plating station 211 exemplarily and schematically shows the distribution system 1 arranged for vertically processing the substrate 4 double-sided. The second sub-plating station 212 exemplarily and schematically shows the distribution system 1 arranged for horizontally processing the substrate 4 double-sided. Between the first and the second sub-plating stations 211, 212, the substrate 4 is guided at an oblique angle, preferably of 45 degrees. The drying station 23 exemplarily and schematically shows a drying unit 34 arranged for vertically processing the substrate 4 double-sided.
[0132] It is to be noted that the embodiment as shown in
[0133]
[0134] While the disclosure has been illustrated and described in detail in the drawings and foregoing description, such illustration and description are to be considered illustrative or exemplary and not restrictive. The disclosure is not limited to the disclosed embodiments. Other variations to the disclosed embodiments can be understood and effected by those skilled in the art in practicing a claimed disclosure, from a study of the drawings, the disclosure, and the dependent claims.
[0135] In the claims, the word comprising does not exclude other elements or steps, and the indefinite article a or an does not exclude a plurality. A single unit may fulfil the functions of several items re-cited in the claims. The mere fact that certain measures are re-cited in mutually different dependent claims does not indicate that a combination of these measures cannot be used to advantage. Any reference signs in the claims should not be construed as limiting the scope.