Pulse energy generator system
10425991 ยท 2019-09-24
Assignee
Inventors
Cpc classification
C25D5/18
CHEMISTRY; METALLURGY
F24H1/106
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C25D17/00
CHEMISTRY; METALLURGY
H05B3/0004
ELECTRICITY
International classification
C25D5/18
CHEMISTRY; METALLURGY
C25D17/00
CHEMISTRY; METALLURGY
C25D17/10
CHEMISTRY; METALLURGY
Abstract
Apparatus and methods for generating thermal energy from a pulsed DC electric power source utilizing pairs of electrodes disposed in a water medium. Electric pulses are provided at a frequency up to 20 MHz. Efficiencies are obtained when multiple pairs of electrodes are powered by the pulsed DC electric power source. The electrodes may be rods, plates, cylinders, or other useful shapes. The electrodes exposed to water may be a metal or alloy of nickel, platinum, palladium, or tungsten. The DC pulse generator is electrically connected to the electrodes to provide a source of pulsed direct current electric power. The input polarity to the electrodes may be periodically reversed or alternated between the anode and cathode polarity to limit erosion/electroplating of electrode material.
Claims
1. A pulse energy generator system comprising: a wet reactor heater comprising at least one pair of electrodes in contact with water wherein the electrodes comprise an electrode metal that is oxidized and reduced to cause electrode metal oxidation and dissolution and electrode metal electroplating at the electrodes, wherein the electrode metal is selected from nickel, platinum, palladium, and gold; and a DC pulse generator, connected to the electrodes to provide a source of pulsed DC electric power to the electrodes, wherein the pulsed DC electric power level is in the range from 1 to 1500 average watts, wherein the pulse frequency is between 15 Hz and 20 MHz, and wherein the electrodes connected to the DC pulse generator have a first anode and cathode polarity.
2. The pulse energy generator system according to claim 1, further comprising a plurality of pairs of electrodes.
3. The pulse energy generator system according to claim 1, wherein the electrodes are configured rods, cylinders, or plates.
4. The pulse energy generator system according to claim 1, wherein the electrodes are configured as rods having a diameter in the range from 0.15 mm to 6.5 mm.
5. The pulse energy generator system according to claim 1, wherein the electrodes are separated by a distance in the range from about 0.2 mm to about 25 millimeters in the water.
6. The pulse energy generator system according to claim 1, wherein the electrodes have an uninsulated surface exposed to water and wherein from 5 to 20 mm of the uninsulated surface is exposed to water.
7. The pulse energy generator system according to claim 1, further comprising an insulated metal electron shield.
8. The pulse energy generator system according to claim 1, further comprising a switch to reverse the first anode and cathode polarity and cause the electrodes connected to the DC pulse generator to have a second anode and cathode polarity.
9. The pulse energy generator system according to claim 1, wherein the water comprises a solution of electrode metal ions.
10. The pulse energy generator system according to claim 1, wherein the water comprises a saturated solution of electrode metal ions.
11. The pulse energy generator system according to claim 2, wherein the DC pulse generator delivers energy pulses to the plurality of pairs of electrodes sequentially, one pulse at a time, while maintaining an input power, and wherein the DC pulse generator periodically reverses the first anode and cathode polarity of the plurality of pairs of electrodes connected thereto.
12. The pulse energy generator system according to claim 11, wherein the DC pulse generator delivers energy pulses to the plurality of electrode pairs sequentially at a pulse frequency to each pair of electrodes between 30 Hz and 250 KHz.
13. The pulse energy generator system according to claim 11, wherein the DC pulse generator delivers energy pulses to the plurality of electrode pairs sequentially at a pulse frequency to each pair of electrodes between 30 Hz and 20 MHz.
14. The energy generator system according to claim 1, wherein the DC generator provides a pulse frequency less than 25 KHz.
15. The pulse energy generator system according to claim 1, wherein the water comprises potassium carbonate at a concentration up to 0.2 molar.
16. The pulse energy generator system according to claim 1, wherein the DC pulse generator provides a voltage between 125 volts and 10,000 volts.
17. The pulse energy generator system according to claim 1, wherein the DC pulse generator provides a voltage between 125 volts and 1000 volts.
18. The pulse energy generator system according to claim 1, wherein the DC pulse generator provides a pulsed current, voltage, and pulse length having an electric power level between 10 and 1500 watts per pair of electrodes.
Description
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
(1) In order that the manner in which the above-recited, and other features and advantages of the invention are obtained will be readily understood, a more particular description of the invention briefly described above will be rendered by reference to specific embodiments thereof that are illustrated in the appended drawings. Understanding that these drawings depict only typical embodiments of the invention, and are not, therefore, to be considered to be limiting of its scope, the invention will be described and explained with additional specificity and detail through the use of the accompanying drawings in which:
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DETAILED DESCRIPTION OF THE INVENTION
(8) The disclosed invention relates to apparatus and methods for generating energy from a pulsed electric power source. Various aspects and embodiments of the disclosed invention will be described in relation to the Figures.
(9)
(10) The electrode 110 includes a non-conductive or insulating covering 120. The covering 120 may be in the form of a coating or insulating wrap. In one non-limiting embodiment, the insulating covering 120 may be made of ceramic.
(11) In some non-limiting embodiments, the electrode 110 may include an optional electron shield 130. The electron shield 130 has no electrical connection to the electrode 110. The electron shield 130 is made of a conductive material such as metal. The electron shield has a size and shaped configured to shield the electrode 110 from an adjacent electrode. Based upon the size of the electrode 110 mentioned above, the electron shield 130 would have a size of about 25 mm in length and 10 mm width. An electron shield connector 140 may be provided to connect the electron shield to the electrode structure.
(12)
(13) The apparatus 200 includes at least one pair of electrodes 110 having electrode structures 100 as described above. Each electrode 110 is electrically connected to the pulsed DC electric power source 210. Each electrode 110 will have either a cathode or anode polarity during operation. As described herein, the pulsed DC electric power source 210 may periodically reverse the electrode polarity during operation. The electrode structures may be mounted to the housing 220 using an electrode port fixture 250. The electrode port fixture 250 is a mechanical mount for the electrode structure 100 that screws into or otherwise makes a hermetic seal with the reactor housing 220. Preferably only a portion of the electrodes 100 have is exposed to the water within the reactor apparatus 200. The surface of the electrode exposed to water is shown by the letter S.
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(17) The water is contained within a reactor housing 360, which may have a configuration as disclosed herein. The housing may be made of a conductive or non-conducive material. Non-limiting examples of conducive material includes a metal compatible with water. Non-limiting examples of non-conductive include ceramic. The reactor housing 350 preferably includes water inlet and outlet ports to facilitate continuous water heating.
(18) It will be understood that disclosed wet reactor apparatus for generating energy from a pulsed DC electric power source may include multiple pairs of electrodes within a single reactor housing. Alternatively, multiple reactors may be configured in series or in parallel depending on the water heating needs. For instance, if high volume water heating is desired, then multiple reactors in parallel may be preferred. Alternatively, if a higher temperature increase is desired, then configuring multiple reactors in series may be preferred. In some cases, combinations of parallel and series reactors may be desired and within the scope of the disclosed invention.
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(20) The pulse DC electric power supply sequencer control system 520 provides energy pulses to each reactor unit sequentially, one at a time, at the same power input level, regardless if using one reactor or all five reactors. The pulse DC electric power supply sequencer control system includes an electronic switch to drive and sequence the DC pulse to multiple output channels. In one non-limiting embodiment, the reactors receive energy pulses at a frequency of about 1000 Hz and a pulse length of about 10 to 30 microseconds. A longer pulse length will provide more power to the reactor electrodes. Higher frequency pulsing may enable pulsed DC power to be provided to large numbers, even 100 or more reactors.
(21) The reactors 511, 512, 513, 514, and 515 shown in
(22) Producing a DC pulse on electrode materials disposed in water can liberate a compression wave that can produce pressure against the electrode. The resistance of water can also produce heat. Heat and pressure in combination can cause water to enter its critical point where all three phases can coexist. Without being bound by theory, the wet reactor DC pulse energy generator systems disclosed herein, involve the conversion of liquid water to vapor at the critical point and back again to liberate heat.
(23) One aspect of the invention to extend the electrode lifetime is to periodically reverse the anode and cathode polarity. This may stop and reverse the dissolution and electroplating of the electrode material. Another aspect of the invention to extend the electrode lifetime is to saturate the water with electrode material ions.
(24) One aspect to the invention is the use of a metal electron shield for electrodes disposed in the water reactor. The shield helps to uniformly distribute the electric field on to the exposed part of the electrode, thereby reducing voltage and power levels. Another aspect of the shield is to diffuse the electric field in the aqueous solution so the exposed electrode can react more homogenously and allow uniform current density throughout the electrode area. The electrodes can function without a shield. But improved performance has been observed when an electrode shield is used. Specifically, it has been observed that the wet reactor can operate at a lower current, even a third less current, and provide the same performance as a reactor without electrode shields. The electron shields can have any size, shape or configuration to shield the electrode.
(25) In one embodiment of the disclosed invention, the electrodes are configured as parallel metal plates. In one non-limiting embodiment, the plates are made of nickel. In one non-limiting embodiment, the plates are mounted as close to each other as possible, preferably, within 0.5 millimeters. The plates may be of any suitable size and shape. In one non-limiting embodiment, each plate can be 10 centimeters high and 5 centimeters wide. Only the bottom edge of each plate can be exposed to the water, while the rest of the metal plates can be coated with electrical insulating material. Having only the bottom edge of each plate uninsulated and exposed to water can create a very high electric field between the plates.
(26) In one non-limiting embodiment of the wet reactor utilizing pairs of electrodes, the water may include an aqueous salt solution to improve water conductivity. Potassium carbonate is one presently preferred salt solution. A concentration up to 0.2 molar potassium carbonate may be used.
(27) A salt solution containing ions of the metal from which the electrodes are fabricated may also be desirable to inhibit metal stripping from the electrode. For example, if the electrodes are fabricated of nickel, then including nickel ions in the water may be beneficial.
(28) Improved performance has been observed by eliminating plasma formation on the electrode by either decreasing the operating current or increasing the length of the electrode exposed to the aqueous solution.
(29) The following examples and experimental results are given to illustrate various embodiments within the scope of the present disclosure. These are given by way of example only, and it is understood that the following examples are not comprehensive or exhaustive of the many types of embodiments of the present disclosure that can be prepared in accordance with the present disclosure.
(30) In the examples, power input was measured using an oscilloscope and power meters, along with volt meters. It was found that using a 0.01 ohm shunt resistor in line as the input side of the power supply works well, along with power meters. The power supply can be a regulated switch mode power supply, a linear power supply, or batteries, modified with a capacitor and switching transistor, such as FET, IGBT, or Triac, or other switching device.
(31) In the examples, the measured heat energy out into water was determined by measuring temperature change and time. Typically, the experiments operated for approximately 180 seconds, which, when multiplied by 4.18 joules per degree C. per gram of water, can yield an average energy output. The electrode material was also taken into account, and water was insulated to reduce heat loss. This does not take into consideration the energy to dissociate water molecule into hydrogen and oxygen. I microprocessor controlled the pulse rate. The pulse rates ranged from 38 Hz to 131,000 Hz.
Example 1
(32) A pulse energy generator system was prepared that contained a pair of tungsten rod electrodes at 1 mm diameter and spaced 25 mm apart. The electrodes each had an electron field distributor (shield) placed 5 mm from the electrode. The shields were approximately 5 mm square. The tungsten electrodes were connected to a DC pulse generator. The electrodes were placed into 180 grams of 0.2 mole potassium carbonate in water at 32.1 C. The DC pulse generator operated at 60 Hz, with a run time of 180 seconds. The average input power was 10 watt in. The ending water temperature was 39.8 C. Based upon the increase in water temperature, the measured output power was [(7.7 C.)(4.182 J/g.Math. C.)(180 g)]/(180 sec)=32.2 watts or a 3.2 times output.
Example 2
(33) The pulse energy generator system of Example 1 was operated. The electrodes were placed into 140 grams of water at 46 C. The DC pulse generator operated at 38 Hz, 2500 microseconds on and 24000 microseconds off with a run time of 180 seconds. The average input power was 19 watts. The ending water temperature was 81 C. Based upon the increase in water temperature, the measured output power was 113.8 watts based upon the calculation [(35 C.)(4.182 J/g.Math. C.)(140 g)]/(180 sec).
Example 3
(34) A pulse energy generator system similar to Example 1 was prepared with nickel electrodes placed into 145 grams of water with 0.2 molar of potassium carbonate with an initial temperature at 43.1 C. The electrodes were powered by a DC pulse of 26 KHz at 6.4 microseconds pulse width, and an input power of 60 watts. 120 seconds later the ending water temperature was 65.5 C and about 1 gram of water loss showed a heated output of 128 watts out.
Example 4
(35) The pulse energy generator system of Example 3 was operated. The nickel electrodes were place in 140 grams of water containing 0.2 molar of potassium carbonate with an initial temperature of about 40 C. The electrodes were powered by a DC pulse of 50 KHz frequency and pulse width of 11.4 microseconds and input power of 70 watts. The ending temperature was 51.4 C. and 1 gram of water loss was measured. The heated output power was 140 watts out.
(36) While specific embodiments and examples of the present invention have been illustrated and described, numerous modifications come to mind without significantly departing from the spirit of the invention, and the scope of protection is only limited by the scope of the accompanying claims.