Method and apparatus for manufacturing cleaned substrates or clean substrates which are further processed
10418230 ยท 2019-09-17
Assignee
Inventors
Cpc classification
H01J37/32568
ELECTRICITY
B08B7/0035
PERFORMING OPERATIONS; TRANSPORTING
H01L21/67028
ELECTRICITY
International classification
H01L21/67
ELECTRICITY
B08B7/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Plasma etch-cleaning of substrates is performed by means of a plasma discharge arrangement comprising an electron source cathode (5) and an anode arrangement (7). The anode arrangement (7) comprises on one hand an anode electrode (9) and on the other hand and electrically isolated therefrom a confinement (11). The confinement (11) has an opening (13) directed towards an area (S) of a substrate (21) to be cleaned. The electron source cathode (5) and the anode electrode (9) are electrically supplied by a supply circuit with a supply source (19). The circuit is operated electrically floating.
Claims
1. A vacuum treatment chamber defining a reaction space and comprising: a plasma discharge arrangement comprising an electron source cathode, an anode arrangement and a substrate carrier, said electron source cathode and an anode electrode of said anode arrangement being operationally interconnectable via an electric supply source; said anode electrode having a shape of a two-dimensionally extended plate with a surface area facing said reaction space; a confinement with an inner space and an opening open towards said reaction space and through which said surface area of said anode electrode is exposed to and faces said reaction space, said inner space of said confinement being U-shaped at least in one cross sectional plane through said confinement, and said anode electrode being mounted along a bottom of said confinement, spaced from said confinement and electrically isolated from said confinement, said surface area of said anode electrode extending closer to said bottom of said confinement than to said opening of said confinement, said opening of said confinement opening towards said reaction space and towards the substrate carrier, said electron source cathode being located outside of said confinement, said substrate carrier being mounted within said vacuum chamber and in said reaction space so as to position a surface area of a substrate on said substrate carrier facing said opening and substantially closer to said opening than to said electron source cathode, said substrate carrier being connectable to an electric source.
2. The vacuum treatment chamber of claim 1, wherein said inner space forms a channel transverse to said cross-sectional plane.
3. The vacuum treatment chamber of claim 1, wherein said anode electrode has in said cross-sectional plane an extent W.sub.AN the legs of said U-shaped inner space of said confinement having, from said bottom, an extent L for which there is valid: 0.5w.sub.ANL1.5w.sub.AN.
4. The vacuum treatment chamber of claim 1, wherein said substrate carrier is mounted within said vacuum chamber so as to position said surface area of said substrate at a distance d from a plane defined by said opening and wherein there is valid: 2 cmd10 cm.
5. The vacuum treatment chamber of claim 1, further comprising a movable shutter between said electron source cathode and said substrate carrier, said shutter being drivingly movable from a closed position covering the emitting surface of said electron source cathode to an open position remote from said surface of said cathode.
6. The vacuum treatment chamber of claim 1, wherein said electron source cathode is a sputtering or an arc evaporation target.
7. The vacuum treatment chamber of claim 1, within an etch cleaning apparatus and wherein said etch cleaning apparatus is operatable additionally in the following operating modes: metal ion etch cleaning mode, wherein said electron source cathode emits electrons and source metal and is only partially covered by a shutter between the emitting surface of said cathode and said substrate carrier; a heating mode, wherein said anode electrode is disconnected from said electric supply source and said substrate carrier is operationally connected as an anode via said electric supply source to said electron source cathode; and a coating mode.
8. The vacuum treatment chamber of claim 1, further comprising an auxiliary anode electrode in said vacuum chamber.
9. The vacuum treatment chamber of claim 8, wherein said auxiliary anode is located substantially nearer to said electron source cathode than to said anode arrangement.
10. The vacuum treatment chamber of claim 1, wherein the opening of the confinement opens towards the substrate and the substrate carrier, and away from the electron source cathode.
11. The vacuum treatment chamber of claim 1, wherein said anode arrangement is located between said substrate carrier and said electron source electrode.
12. The vacuum treatment chamber of claim 1, further comprising an electrical supply source interconnecting said electron source cathode and said anode electrode, wherein said electric supply source is a source generating DC output with superimposed pulses.
13. A vacuum treatment apparatus comprising: a vacuum treatment chamber defining a reaction space and in said vacuum treatment chamber; a plasma discharge arrangement comprising an electron source cathode, an anode arrangement and a substrate carrier, said electron source cathode and an anode electrode of said anode arrangement being operationally inter-connectable to an electric supply source; said anode electrode consisting of a shape of a two-dimensionally extended plate comprising one surface area exposed to said reaction space, said one surface area being flat and facing said reaction space, a confinement with an inner space and an opening open towards said reaction space and through which said one surface area of said anode electrode is exposed to and faces said reaction space, said inner space of said confinement being U-shaped at least in one cross sectional plane through said confinement, and said anode electrode being mounted along a bottom of said confinement, spaced from said confinement and electrically isolated from said confinement, said one surface area of said anode electrode extending closer to said bottom of said confinement than to said opening of said confinement, said opening of said confinement opening towards said reaction space and towards the substrate carrier, said electron source cathode being located outside of said confinement, said substrate carrier being mounted within said vacuum chamber so as to position a surface area of a substrate on said substrate carrier adjacent said opening and substantially closer to said opening than to said electron source cathode, said substrate carrier being operationally connected to an electric source.
14. The vacuum treatment apparatus of claim 13, wherein said anode electrode, said electron source cathode and a circuit containing said electric supply source and operationally interconnecting said anode electrode and said electron source cathode are electrically floating.
15. The vacuum treatment apparatus of claim 13, wherein said confinement is connected to an electrical confinement biasing source.
16. The vacuum treatment apparatus of claim 13, further comprising an electrical supply source inter-connecting said electron source cathode and said anode electrode, wherein said electric supply source is a source generating DC output with superimposed pulses.
17. The vacuum treatment apparatus of claim 13, comprising an auxiliary anode electrode in said vacuum chamber and a switching unit enabling operation of said auxiliary anode instead of said anode electrode.
18. The vacuum treatment apparatus of claim 17, wherein said switching unit has a control input which is operationally connected to at least one of an output of a timer and of an output of an arc detector unit.
Description
(1) The invention shall now further be described by examples and with the help of figures. These figures show:
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(13) Electrons generated by the electron source cathode 5 are propelled by the electric field from the emitting surface of the electron source cathode 5 towards the anode electrode 9. Due to the confinement 11 which is operated on an electric potential which is different from the electric potential of the anode electrode 9 in any case, there results, as schematically shown in
(14) A working gas G.sub.cl, e.g. Argon, Krypton, Xenon or a mixture thereof is inlet into the vacuum chamber 1 and is ionised by electron impact. Whenever reactive cleaning is to be performed, additionally, a reactive gas as e.g. Nitrogen, Hydrogen, Oxygen or a mixture thereof, is inlet into the chamber 1.
(15) Due to the increased electron density in the confinement 11 and adjacent to its opening 13 there results in the addressed area an increased ionization rate of the working gas and, in the case of reactive etch-cleaning, an increased activation of the reactive gas. A substrate 21, the surface area S thereof having to be cleaned, is positioned on a substrate carrier 22 adjacent to the opening 13 of the confinement 11 with the surface S pointing towards the opening 13 and thus being exposed to the plasma of increased density in that area. One can say that by means of a confinement 11 an increased plasma density is focussed towards the surface area S, resulting in an increased etching rate, be it reactively or non-reactively. The substrate 21 is thereby operated via substrate carrier 22 on an electric potential which is negative with respect to the plasma potential. This is achieved, as schematically shown in
(16) The inner surfaces of confinement 11 as well as of a protection tube 25 for supply connection 15, which is provided in the embodiment of
(17) The inner space of confinement 11 is shaped in a cross-sectional plane according to the x/y plane as a U, whereby the anode electrode 9 resides adjacent to the bottom of the U, as addressed above, spaced from the bottom and from the legs of the U by at most dark space distance DSD.
(18) In spite of the fact that the electrode arrangement 7 may be configured to have a substantially circular of square opening, in one embodiment as shown in
(19) In one configuration more than one electron source cathodes are provided as schematically shown in
(20) At least an indicia, that such an anode fall of electric potential is present is an anode electrode to chamber wall potential difference of about 10 V to 85 V.
(21) Nevertheless, by such electron bombardment the anode electrode is heavily thermically loaded, which necessitates specific measures. In fact it is the thermical loading of the anode electrode 9, 9a and the efficiency of counter measures, which are decisive for the upper limit of the discharge current density applicable. In spite of the fact that it is clearly feasible to provide, within the anode electrode 9, 9a a system of channels and to feed a heat transport medium through such channels to remove excess heat from the anode electrode, this approach is coupled with substantial constructional complexity and costs.
(22) So as to achieve the high plasma densities coupled to the addressed high discharge current densities and respective high etching rates on the substrate without active anode electrode cooling, the supply source 19 is operated with a DC bias current and superimposed pulses. The plasma discharge between the electron source cathode 5, 5a and the anode electrode 9, 9a which is in fact a low voltage discharge is thus operated as shown in
(23) In a further embodiment and as shown in
(24) Up to now we have discussed the electron source cathode 5 as just providing electrons. Nevertheless, two types of electron source cathodes 5 may be utilized. A first type does in fact substantially exclusively emit electrons as e.g. a hot filament cathode or a hollow cathode electron source.
(25) The second type of electron source cathode 5 is the one by which additionally to electrons source material is emitted into the reaction space. Such sources are e.g. sputter sources including magnetron sputter sources, arc evaporation sources. This type of electron source cathode is schematically represented in
(26) As shown in
(27) Still with an eye on
(28) It has been addressed that the plasma discharge between the electron source cathode 5 and the anode electrode 9, 9a may be said a low voltage plasma discharge. Although this term is perfectly understood by skilled artisans, it is not clearly defined as to what is meant by low. This is clarified by some of the operating parameters as of discharge voltage and discharge current resulting from discharge current density and anode electrode surface, as listed below.
(29) In the following operating parameters which are today recommended are listed: Surface of anode electrode exposed to reaction space and as used today:
(30) TABLE-US-00001 Width w.sub.AN as shown in FIG. 2 in y direction: 8 cm Extent in z direction of FIG. 2: 60 cm W.sub.AN more generically results from the extent of the substrate in z direction and an overlength of the anode electrode on both substrate ends of 5 cm to 10 cm.
(31) TABLE-US-00002 Electron source cathodes 5a: 2 arc evaporator targets Discharge current between each of the 200 A targets and the anode electrode: resulting in a current density at the 0.83 A/cm.sup.2 exposed surface of anode electrode 9a of Confinement: Extent w.sub.CO of the bottom of the U: 8 cm + 2 DSP Length L of the legs of the U: 0.5 w.sub.AN to 1.5 w.sub.AN operated on floating electric potential. Distance d between confinement 2 cm d 10 cm, preferred opening 13 and substrate area 4 cm d 6 cm. S (see FIG. 1): By varying the length L of the legs of the confinement U the etching rate distribution may be adjusted. Etching gases: working gas: Argon, Krypton, Xenon or a mixture thereof. Reactive etching gas: Nitrogen, Hydrogen, Oxygen or a mixture thereof. Total operating pressure: 0.1 Pa to 10 Pa, preferred 0.1 to 3 Pa (all limits included). Discharge low voltage U.sub.AC between electron source cathode and anode electrode: 20 VU.sub.AC100 V, preferred 35 VU.sub.AC70 V which results in a potential difference between the anode electrode and the vacuum chamber wall of between 10 and 85 V, thereby, in preferred operation, of between 20 and 50 V. pulse repetition frequency f: 0.2 Hzf200 KHz Magnetic field H installed to control the etching distribution along the substrate, and/or to control the plasma impedance and thereby e.g. processing rate at given discharge voltage U.sub.AC. Biasing of the substrate: DC of 10 V to 2000 V, more specifically: for etch cleaning 60 V to 1000 V, for metal ion etching 600 V to 2000 V, for coating 10 V to 300 V, thereby superimposing pulses with a repetition frequency of 0 Hz to 500 KHz, thereby preferred in the frequency range of 50 KHz to 300 KHz.
(32) Up to now we have described under the first aspect of the present invention manufacturing cleaned substrates and an apparatus to perform such processing.
(33) By means of
(34) In
(35) A substrate 106 to be treated is provided and in the vacuum chamber 100 biased by a biasing source. The substrate may nevertheless and under a general aspect be deposited on one of the electrodes 102 and 104 as also perfectly known to the skilled artisan.
(36) In such general processing undesired arcing shall be considered which may occur between the electrodes 102 and 104 as e.g. between anode and target of a sputtering source or between either of the electrodes 102 and 104 and substrate 106. Clearly when the electrodes 102 and 104 concomitantly define for an arc evaporating source then arcing between these electrodes is desired arcing, but not arcing between either of the electrodes and the substrate 106.
(37) Under the second aspect of the present invention process damages by undesired arcing are to be prevented. This is achieved by switching that electrode 102 or 104 which is involved in undesired arcing to a respective auxiliary electrode. Thus, according to
(38) Thereby, it will be a matter design and specific application which of the electrodes shall be switched on an auxiliary electrode. E.g. in the case of the two electrodes 102 and 104 being realized by a sputter target and an anode of the respective sputtering source there will be provided an auxiliary cathode rather than an auxiliary anode. If with an eye on
(39) Departing from the generic concept of the present invention under its second aspect and has been explained with the help of
(40) It is perfectly clear that the prevention of processing damages due to undesired arcing as was generically explained in context with
(41) Consequently and according to
(42) Thus, the generic arc prevention approach as has been explained in
(43) In
(44) For facilitating comparison from the
(45) Within the vacuum chamber 1 with an evacuation port 3a there is provided an electron source cathode 5, realized by an arc evaporation target cathode 6. Instead e.g. a thermal emission cathode or a sputter target cathode may be provided, generally an electron source cathode of the second type as addressed above.
(46) The anode arrangement 7 comprises the anode electrode 9 or 9a as well as the confinement 11 or 11a. The confinement 11, 11a is of a metal and is operated on floating electric potential.
(47) The confinement 11, 11a defines for the opening 13, 13a respectively. Via supply connection 15 and a switching unit T1 as well as a switching unit T2 the anode electrode 9, 9a is fed by supply source 19 with respect to the arc evaporation target cathode 6. Substrates 21a are supported on a substrate carrier carousel 22 drivingly rotatable about an axis M by a motor drive 24. On carousel 22 the substrates 21a, cutting tool bodies, are operated on a defined electric potential via switching unit T3 and by biasing supply unit 23.
(48) The magnetic field H is generated by means of the coil arrangement 27. The sputtering target cathode 6 is shielded from the substrates 21a on carousel 22 by means of the controllably movable shutter 29 (see
(49) In this operating mode, in which a low voltage plasma discharge is operated between arc evaporation target cathode 6, acting as an electron source, and anode electrode 9, 9a, the substrates 21a on rotating carousel 22 are etched by working gas ions or possibly by activated reactive gas as was described in context with
(50)
(51) Thereby, the shutter 29 is partly open so that from a metallic arc evaporation target cathode 6, metal particles or ions reach the substrate surface. Thereby, etching of the substrates 21a on revolving carousel 22 is additionally performed by metal ion impact. Prevention of arcing damages is performed as was explained in context with
(52)
(53) In
(54) Whenever for damage prevention the auxiliary anode is activated it is possibly desired to operate such auxiliary anode 9.sub.AUX on an electric potential with respect to the cathode which is different from the electric potential at which the standard anode 9, 9a is operated. As shown in