Method of recycling chitosan and graphene oxide compound

Abstract

A method of creating storing and using recycled graphene oxide materials to create highly resilient objects having desirable qualities of graphene.

Claims

1. A method of producing a quantity of a graphene oxide compound from a graphene oxide object comprised of a chitosan graphene oxide compound comprising the steps of: maximizing solution to solid contact; immersing said graphene oxide object in an acidic solution; creating a homogeneous solution as said graphene oxide object dissolves; and producing a stored graphene oxide compound.

2. The method of claim 1 wherein the step of producing a stored graphene oxide compound further includes the step of evaporating said graphene oxide solution to form a solid.

3. The method of claim 1 wherein the step of producing a stored graphene oxide compound further includes the step of pulverizing said solid to form a powder.

4. The method of claim 1 which further includes the step of storing said graphene oxide compound as a solution.

5. The method of claim 1 wherein the step of producing a stored graphene oxide compound further includes the step of combining a recycled quantity of graphene oxide with a second compound to improve the qualities of said second compound.

6. The method of claim 5 wherein said second compound is concrete.

7. The method of claim 1 wherein said step of maximizing solution to solid contact includes reducing the graphene oxide object into two physical parts.

8. The method of claim 7 which further incudes the step of applying a mechanical process to said graphene oxide object, wherein said mechanical process is selected from a group consisting of punching, shredding and grounding.

9. The method of claim 1, wherein said chitosan graphene oxide compound has a ratio of between two and seven parts of chitosan to each part of graphene.

10. The method of claim 1, wherein said chitosan graphene oxide compound has a ratio of five parts of chitosan to each part of graphene.

11. The method of claim 1 wherein said, graphene oxide object is filter.

12. The method of claim 1 which further includes removing one or more layers of material from said graphene oxide object.

13. The method of claim 1 wherein said solution is an acetic acid solution consisting of 8.3mL of 99% glacial acid per liter of water.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 illustrates an exemplary method for recycling a graphene oxide material.

(2) FIG. 2 illustrates an exemplary method illustrates an exemplary method for recycling a highly resilient graphene oxide filtration membrane, which chitosan graphene oxide (CSGO) filtration membrane recovered from a filtration apparatus.

(3) FIG. 3 (Prior Art) illustrates the structural makeup of graphene oxide and an exemplary oxide group.

(4) FIG. 4 illustrates the cross-linking of graphene oxide and chitosan.

(5) FIG. 5 illustrates an exemplary layered structure of a CGSO filter.

(6) FIG. 6 illustrates a CGSO filter which is spiral shaped.

TERMS OF ART

(7) As used herein, the term cross-linking means binding two materials at the molecular level.

(8) As used herein, the term CSGO means chitosan graphene oxide.

(9) As used herein, the term disk-shaped means a disk-like structure of a filtration membrane.

(10) As used herein, the term filtration membrane means a thin layer of semi-permeable material that separates molecules, particles or substances that pass through it.

(11) As used herein, the term highly-resilient means durable and able to be used for various applications.

(12) As used herein, the term membrane support layer means a structure for supporting a CSGO filter.

(13) As used herein, the term spiral wound is a spiral-like structure of the filtration membrane.

(14) As used herein, the term target thickness means a desired thickness to be achieved for creation of a filtration membrane relative to its intended use.

DETAILED DESCRIPTION OF THE DRAWINGS

(15) FIG. 1 is a flow chart of an exemplary method for recycling graphene oxide material 100. In various embodiments, the method may be applied to graphene oxide objects of any scale and graphene oxide objects comprised of various compositions.

(16) Step 10 is the step of processing a graphene oxide object to maximize solution to solid contact. In various embodiments, this step may include a mechanical or non-mechanical process of punching, shredding and grounding.

(17) Step 20 is the step of immersing a graphene oxide object in an acidic solution. The method of claim 1 wherein said solution is comprised of acetic acid consisting of 8.3 mL of 99% glacial acetic acid per liter of water.

(18) Step 30 is the step of dissolving the graphene oxide object to create a homogeneous solution. In many embodiments, this step will be accomplished by mechanical or non-mechanical stirring.

(19) Step 40 is the step of storing a quantity of reusable graphene oxide compound in a desired physical form. In various embodiments, the reusable graphene oxide compound may be stored as a solution. Other embodiments may include the step the evaporating said graphene oxide solution to form a solid. In still other embodiments, the solid formed from evaporation may be pulverizing said solid to form a powder. The reusable graphene oxide compound produces may be used to create newly manufactured objects and filters or as a compound for repair or coating objects made of any material.

(20) Step 50 (Optional) is the step of combining a recycled quantity of graphene oxide with a second compound to improve the qualities of said second compound. In one embodiment, the second compound may be concrete which is combined with quantity of reusable graphene oxide compound stored as a powder.

(21) FIG. 2 illustrates an exemplary method for recycling a highly resilient graphene oxide filtration membrane, which is a chitosan graphene oxide (CSGO) filtration membrane recovered from a filtration apparatus.

(22) illustrates an exemplary method 200 for recycling a chitosan/graphene oxide filtration apparatus. The steps of this method include the steps of Method 100.

(23) In Method 200, steps 1A and 1B are performed to prepare a filtration apparatus for recycling prior to performing recycling steps of Method 100.

(24) Step 1A is the step of disassembling the filtration apparatus to remove support layers and other material that is not made of graphene oxide from a filtration device.

(25) Step 1B is the step of cleansing the graphene oxide filtration membrane. In one embodiment, this is accomplished backwash filter to remove contaminants from said chitosan/graphene oxide object. In various embodiments, this may also include removing one or more layers of material from said chitosan/graphene oxide object.

(26) Small pieces of support material stuck on the chitosan/graphene MAY placed in the acid reactor. When the chitosan/graphene oxide material is dissolved, the solid support material can be recovered by picking it out or by a large screen filtration.

(27) FIG. 3 (Prior Art) illustrates the structural makeup of graphene oxide and an exemplary oxide group. Graphene is impermeable and membranes constructed from it are not known to be used commercially to produce filtration membranes. The introduction of oxides results in a permeable, cross-linked compound.

(28) FIG. 4 illustrates an exemplary layered structure of a CGSO filter. In the exemplary embodiment, the CSGO filter 100 includes a CSGO filtration membrane 10 that is placed between support layers 11a and 11b. Layers 11a and 11b support the filtration membrane 10 to prevent swelling and deformation.

(29) In the exemplary embodiment shown, the CSGO filtration membrane 10 is placed between two nitrocellulose filters, which provide stability in a cross flow system. Nitrocellulose is selected because it non-reactive with contaminants passing through and is scalable. Other materials with similar characteristics may be substituted.

(30) In other embodiments, the support layers 11a and 11b may be comprised of different material such as paper, glass wool and permeable plastic.

(31) FIG. 5 illustrates a CGSO filter which is spiral shaped. Visible elements of the spiral shaped CSGO filter 102 includes the CGSO filtration membrane 10 and support layers 11a and 11b. As noted, layers 11a and 11b are constructed of a permeable material which supports cross-flow motion of passing fluids, gases, etc.

(32) The spiral shaped CSGO filter 102 may also include a spacing layer 12. The spacing layer 12 is in an optional layer used in the spiral embodiment to create additional spacing for water flow between respective support layers 11a and 11b.

(33) In the exemplary embodiment, the spiral shaped CSGO filter 102 further includes a clean water collection pipe 16. The clean water collection pipe is a structure that allows clean, treated water to be collected and dispersed away from the filter.