Membrane filter and filtering method
10406483 ยท 2019-09-10
Assignee
Inventors
Cpc classification
B01D65/02
PERFORMING OPERATIONS; TRANSPORTING
Y02W10/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B01D2313/26
PERFORMING OPERATIONS; TRANSPORTING
International classification
B01D65/02
PERFORMING OPERATIONS; TRANSPORTING
B01D63/04
PERFORMING OPERATIONS; TRANSPORTING
B01D65/08
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A membrane filter for filtering a liquid to be filtered, the membrane filter including at least one membrane carrier to which membranes are fixed, the membranes allowing a liquid permeate to be filtered out of the liquid, and the membrane carrier includes a permeate collecting chamber to which the membranes are connected in an open manner on the permeate side, and also comprises a permeate outlet for the discharge of the permeate out of the permeate collecting chamber; a gas distribution system which is arranged below the at least one membrane carrier and which has at least one downwardly open and upwardly closed tub which has a wall with downwardly open vertical slots for the distribution of a gas into the liquid to be filtered, at least one gas inlet leading into the gas distribution system. The invention also relates to a method for filtering a liquid.
Claims
1. A membrane filter for filtering a liquid, the membrane filter comprising: at least one membrane carrier at which membranes are attached which are configured to filter a liquid permeate from the liquid wherein the at least one membrane carrier includes a permeate collecting cavity to which the membranes are connected with an open permeate side of the membranes; a permeate outlet for letting the permeate out from the permeate collecting cavity; a gas distribution system arranged below the at least one membrane carrier and including at least one downward open and upward closed tub which includes a wall with downward open vertical slots for distributing a gas into the liquid, and at least one gas inlet into the gas distribution system, wherein the at least one downward open and upward closed tub includes an inner edge that is arranged between two of the downward open vertical slots that are adjacent to each other in at least one vertical cross section of the at least one downward open and upward closed tub, and wherein each section of the inner edge is oriented at an angle of less than 60 relative to horizontal at least in a portion of a lower half of the downward open vertical slots.
2. The membrane filter according to claim 1, wherein the gas distribution system is arranged at a bottom side of the at least one membrane carrier.
3. The membrane filter according to claim 1, wherein the at least one downward open and upward closed tub includes at least one vertical rib which extends from the wall with the downward open vertical slots in an inward direction of the membrane filter and which is arranged between the two of the downward open vertical slots that are adjacent to each other, and wherein an extension of the at least one vertical rib into the at least one tub decreases in a downward direction.
4. The membrane filter according to claim 1, wherein the gas distribution system includes downward open gas distribution channels which adjoin at least a portion of the downward open vertical slots on an outside for forwarding and distributing the gas away from the at least one downward open and upward closed tub.
5. The membrane filter according to claim 4, wherein the gas distribution channels adjoin the downward open vertical slots with a vertical upward offset.
6. The membrane filter according to claim 1, wherein the downward open vertical slots become wider in a downward direction.
7. The membrane filter according to claim I, wherein the downward open vertical slots have cross sectional surfaces with different sizes.
8. The membrane filter according to claim 1, wherein the at least one gas inlet laterally adjoins the at least one downward open and upward closed tub.
9. A method for filtering a liquid in a membrane filter including at least one membrane carrier each having membranes, at least one gas inlet, and a gas distribution system with at least one downward open and upward closed tub which includes a wall with downward open slots, the method comprising the steps: flowing a gas through the at least one gas inlet into the at least one downward open and upward closed tub; filling the at least one downward open and upward closed tub and the downward open slots up to a portion of a height of the downward open slots with a gas cushion formed by the gas; flowing the gas out of the gas cushion through the downward open slots in a laterally outward direction from the at least one downward open and upward closed tub and thus flowing the gas into the liquid at several locations below the at least one membrane carrier; generating a liquid flow caused by the gas at a phase boundary below the gas cushion during a lateral flow of the gas through the downward open slots wherein the liquid flow is parallel to the lateral flow of the gas, generating a rising gas flow in the membrane filter which generates a rising liquid flow in the membrane filter, and flushing the at least one membrane carrier and the membranes attached thereon with the rising liquid flow and the rising gas flow, filtering the liquid through the membranes; and collecting the liquid permeate from the membranes and flowing the liquid permeate out of the membranes; wherein the liquid flow that is generated below the gas cushion flows against an inner edge of the at least one downward open and upward closed tub between adjacent downward open slots in at least one vertical cross section of the at least one downward open and upward closed tub, which cross section is orthogonal to the wall with the downward open slots, wherein the inner edge is oriented at an angle relative to horizontal of less than 60 at least in a portion of a lower half of the downward open slots.
10. The method according to claim 9, wherein the gas after flowing through some of the downward open slots flows through the gas distribution channels into portions of the membrane filter which are further remote in outward direction than the at least one downward open upward closed tub.
11. The method according to claim 9, wherein the gas distribution system is configured at a bottom side of the at least one membrane carrier, and wherein the gas flows around the at least one membrane carrier after flowing into the liquid.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The invention is subsequently described based on embodiments with reference to drawing figures, wherein:
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DETAILED DESCRIPTION OF THE INVENTION
(14) The drawing figures are not to scale. All non stated details of subsequently described membrane filters according to the invention are identical with embodiments of previously described membrane filters according to the invention.
(15)
(16) The hollow fiber membranes 5 are fabric reinforced and have an external diameter of 2.5 mm. They are individually closed at an upper end 7. The tube 6 extends beyond the upper end 7 by a length of 8 cm to 10 cm. The hollow fiber membranes 5 are cast in in a sealing manner in the membrane carrier 4 by a resin layer 9, wherein lumens of the hollow fiber membrane 5 remain open.
(17) The membrane filter 1 has a height 10 of 200 cm the base element 2 has a height 11 of 12 cm and the membrane carrier 4 has a height 12 of 11 cm. The base element 2 and the tube 6 both have an external diameter of 75 mm. The tube 6 has an internal diameter of 68 mm. The base element 2 furthermore includes a gas inlet 13 and a permeate outlet 14.
(18) The membrane carrier 4 is connected with the shell 3 through an anchor location 15. The base element 2 includes a flow cavity 16 between the shell 3 and the main membrane carrier 4 wherein the flow cavity is configured as an annular gap with a width of 9 mm, envelops the membrane carrier 4 and is only interrupted by the anchor location 15. The flow cavity 16 is adjacent in each horizontal sectional view to the shell 3 and also to the membrane carrier 4.
(19) The flow cavity 16 is limited in vertical direction by the overlap portion of the height 11 of the base element 2 and the height 12 of the membrane carrier 4. The base element 2 is open in downward direction and capable of flow through. The flow cavity 16 includes an outlet 17 on top into the tube 6.
(20) The gas inlet 13 is connected with a gas distribution system 18 configured on a bottom side of the membrane carrier 4 wherein the gas distribution system includes a tub 19 that is open in downward direction and closed in upward direction, wherein the tub includes a wall 20 with downward open vertical slots 21. The tub 19 includes an inner edge 22 respectively in a center between adjacent slots 21 in a sectional view that is vertical and orthogonal to the wall 20, wherein the inner edge 22 is a slanted edge over an entire height of the slots 21 wherein an angle 24 of the slanted edge 22 is 40 relative to horizontal. Alternatively the inner edge 22 in a portion of a lower half 23 of the slots 21 can have an angle 24 relative to horizontal that is less than 60 in any point.
(21) The base element 2 furthermore includes a permeate collecting cavity 25 into which the lumens of the hollow fiber membrane lead. The permeate collecting cavity 25 is connected with the permeate outlet 14 of the base element 2.
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(23) The permeate outlet 14 and the gas inlet 13 are arranged in a radially outward extension of the anchor location 15.
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(25) Thus,
(26) A gas 26 is introduced into the base element 2 and the flow cavity 16 through the gas inlet 13 during operations of the membrane filter 1 thus the gas 26 flows through the gas inlet 13 initially into the tub 19. The gas 26 fills the tub 19 up to a portion of the height of the slots 21 and forms a gas cushion 27 in the tub, 19. The gas 26 also fills the slots 21 up to the level of the gas cushion 27 and eventually flows laterally through the portion of the slots 21 that are filled with the gas 26 out of the tube 19 or out of the gas cushion 27 and thus into a liquid 28 that is to be filtered.
(27) Besides the flow cavity 16 the membrane carrier 4 closes the base element 2 completely for the flow through of the liquid 28 and of the gas 26, this means besides the flow cavity 16 there are no additional pass through openings for the gas 26 and the liquid 28 in the base element 2.
(28) Above the base element 2 there are no additional installations in the tube 6 besides the hollow fiber membranes 5. Therefore the hollow fiber membranes 5 float freely in the liquid 28 without impediment and are only fixated at their bases. Thus also hair, fibrous compounds or other contaminants from the liquid 28 cannot be lodged in this portion.
(29) During lateral flow through the slots 21 the gas 26 generates a radially outward oriented liquid flow that is parallel to the lateral gas flow at a face boundary surface below the gas cushion 27. The liquid flows between respective adjacent slots 21 against and inner edge 22 of the wall 20 which has an angle relative to horizontal of less than 60 in each point in the portion of the slots. At this slanted inner edge hair and fibrous compounds included in the liquid 28 to be filtered are stripped off through the outward oriented gas flow and liquid flow which reduces a risk of these contaminants lodging in the membrane filter 1.
(30) After flowing through the slots 21 the gas 26 rises through its buoyancy in the membrane filter 1 and generates an upward flow of the liquid 28. This liquid flow is suctioned into the membrane filter only from below. The gas 26 and the liquid 28 flow through the flow cavity 16 of the base element 2 and jointly flow through the outlet 17 into the tube 6 and above at the tube 6 out of the membrane filter 1.
(31) The strong shear force effect of the two phase flow including the liquid 28 and the gas 26 which rises through the mammoth pumping effect in the membrane filter 1. The membrane carrier 4 is flushed on the outside in the flow cavity 16 of the base element 2 and the hollow fiber membranes 5 are flushed on the outside in the tube 6 and thus coatings and deposits are flushed off from the surfaces of the membrane carrier 4 and of the hollow fiber membranes 5 and are carried out the membrane filter 1.
(32) Between the outside of the hollow fiber membranes 5 and their lumens there is a pressure differential based on which a liquid permeate 29 is filtered out the liquid 28 and flows into the lumens of the hollow fiber membranes 5. The permeate 29 is collected from the lumens of the hollow fiber membranes 5 and then flows through the permeate outlet 14 out of the membrane filter 1.
(33) Through the anchor location 15 the gas 26 is supplied and the permeate 29 that is filtered in the membrane filter 1 is drained.
(34) The gas inlet 13 is flow connected with the flow cavity 16 within the base element 2, so that the base element 2 is flowable from the gas inlet 13 through the tub 19, through the slots 21 and through the flow cavity 16 to the outlet 17.
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(41) The base element 31 has a height 49 of 12 cm and the membrane filter 36 has a height 50 of 212 cm. The hollow fiber membranes 43 are encased at a bottom in the membrane carrier 41 by a resin layer 51 against the liquid 37 to be filtered in a sealing manner, wherein the lumens of the hollow fiber membranes 43 remain open. The number of the illustrated hollow fiber membranes 43 does not correspond to the actual number of the hollow fiber membranes 43. The hollow fiber membranes 43 are individually closed on top and flowed freely on top in the liquid 37 to be filtered besides the lower fixation. The hollow fiber membranes 43 are completely enclosed by the tube 45. The tube 45 protrudes by 10 cm above the upper ends 52 of the hollow fiber membranes 43.
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(43) The flow cavity 53 has bulges 55 that protruded into the membrane carrier 41 up to an anchor 56 of the membrane carrier 41. Thus 6 fingers 57 are formed at the membrane carrier 41 wherein the 6 fingers are connected by the anchor 56 of the membrane carrier 41. The 2 anchors 42, are arranged in an extension of the anchor 56, wherein the gas inlet 46 runs through one anchor location and the permeate outlet 48 runs through the other anchor location. The two anchor locations 42 are the only connections of the membrane carrier 41 with the shell 40. Outfitting the membrane carrier 41 with the hollow fiber membranes 43 is performed in the second membrane filter 36 only in the portion of the fingers 57, wherein the portion between the fingers above the anchor 56 remains recessed for production reasons. The hollow fiber membranes 43 of the second membrane filter 36 are fabric reinforced and have an outer diameter of 2.5 mm.
(44) In the portion of the anchor 56 there is a horizontal section in the base element 39 in which the flow cavity 53 forms two continuous flow channels 58 which have a uniform width 59 of 6 mm in the annular gap in the outer portion of the fingers 57. Also between the fingers 57 the flow channel 58 has the same width 59 of six mm. Since the edges of the fingers 57 are rounded for hydrodynamic reasons the 2 flow channels 58 have a slightly greater width than 6 mm at the edges of the fingers 57. Overall the 2 flow channels 58 have a uniform width of 6 mm on more than 80% of their length.
(45) The flow cavity 53 in each horizontal section is adjacent to the shell 40 and also adjacent to the membrane carrier 41 and is only interrupted by the two anchor locations. The membrane carrier 41 closes the base element 39 completely besides the flow path 53, this means the base element 39 has no additional flow through channels besides the flow cavity 53 for the liquid 37 to be filtered for the gas 38.
(46) The diameter 60 of the base element 39 of the second membrane filter 36 is approximately 208 mm.
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(48) As evident from
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(50) In the second membrane filter 36 the base element 39 includes the gas inlet 46. The gas inlet 46 is connected with a gas distribution system 62 formed at a bottom side of the membrane carrier 41 wherein the gas distribution system 62 includes a downward open and upward closed tube 63 which includes a wall 64 with downward open vertical slots 65 for distributing the gas 38 into the liquid 37 to be filtered. The width of the tub 63 corresponds to the width of the anchor 56 and is formed at its lower side. The gas inlet 46 adjoins laterally directly at the tub 63.
(51) At each second slot 65 a gas conducting channel 66 is externally connected to the tub 63 wherein the gas conducting channel is configured at a bottom side of the finger 57 for conducting the gas 38 away from the tub in a direction towards the shell 40. The other slot 65 at which no gas conducting channel 66 are connected respectively open between two fingers 57 or for the outer fingers 57 between the fingers 57 and the shell 40 on an outside of the anchor 56. Thus the tub 63 has a wall 64 on each of its 2 longitudinal sides wherein the wall 64 respectively includes 13 slots 65. The slot 65 become wider in downward direction in order to also be able to compensate larger variations in the amount of gas that is being supplied.
(52) The width of the slots 65 and thus also their cross sectional surface have different sizes. Thus the volume of the gas 38 is adapted to the surface of the hollow fiber membranes 43 flowing through the slots 65. Accordingly the slots 65 include wider slots 65 below the longer fingers 67 in a center of the base element 39 then the outer slots 65 below the shorter fingers 57. The narrowest slots 65 are the slots that open between the fingers 57. Through the configuration of the gas distribution system 62 with slot 65 and gas conduction channels 66 the gas 38 flows around the membrane carrier 41 after flowing in the liquid 37 to be filtered.
(53) The base element 39 is flowable from the gas inlet 46 through the wall 63 through the slots 65 and through the flow cavity 53 to the outlet 54. The membrane carrier 41 closes the base element 39 besides the flow cavity 53 not only for the flow through of the liquid 37 to be filtered but also for the flow through of the gas 38.
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(57) The tub 63 includes vertical ribs 67 respectively extending in a center between adjacent slots 65 orthogonal to the wall 64. Each rib 67 includes a taper at a bottom which runs towards the wall 64 and thus forms a slanted or rounded inner edge 68 of the tub 63.
(58) Geometrically speaking the tub 63 includes an inner edge 68 respectively extending between adjacent slots 65 in a vertical sectional view wherein the vertical sectional view in this case extends orthogonal to the wall 64 through the rib 67 wherein the inner edge at least in a portion of a lower half 69 of the slot 65 includes in every point an angle 70 relative to horizontal of less than 60 at a level of the half 69 of the slots 65 of 58.
(59) The non illustrated filtration operations of the second membrane filter 56 differs from filtrations operations of the first membrane filter 1 as follows.
(60) The gas 38 flows through the gas inlet 46 into the tub 63 and fills the tub 63 and the slots 65 up to a portion of the height of the slot 65 with a gas cushion. From the gas cushion the gas 38 flows through the slot 65 in laterally outward direction from the tub 63 and thus at plural locations below the membrane carrier 41 into the liquid 37 to be filtered. Thus the gas 38 flows out of the slot 65 into bulges 55 of the flow cavity 53 respectively between two fingers 57 and on the other hand side out of the slot 65 below the finger 57 into the gas conduction channel 66. Through the gas conduction channel 66 the gas 38 flows in outward direction further away from the tub 63 into the outer portion of the membrane filter 36.
(61) During lateral flow through the slots 65 a liquid flow that is oriented parallel to the lateral gas flow is generated at the face boundary below the gas cushion wherein the liquid flow flows against the inner edge 68 of the rib 67. Based on the angle 70 of the inner edge 68 of the tub 63 which is arranged between two slots 65 hair and fibrous compounds can be stripped off when the inner edge 68 is exposed to a flow which significantly reduces a clogging propensity of the membrane filter 36.
(62) After the gas enters the liquid 37 to be filtered the membrane carrier 41 is flowed by the gas 38 and the liquid 37 before the mix from gas 38 and liquid 37 flows around the hollow fibers membranes 43 attached at a top in the membrane carrier 41. Due to the high shear force of the two phase flow the hollow fiber membranes and the membrane carrier 41 are flushed on an outside.
(63) The base element 39 is flowed by the gas 38 starting from the gas inlet 46 through the tub 63 through the slot 65 and through the flow cavity 53 to the outlet 54. Since the flow cavity 53 is always arranged between the shell 40 and the membrane carrier 41 and furthermore protrudes through the bulges 55 also into the inner portion of the membrane filter 36 this generates even gassing of the membrane filter 36 over the entire cross section while avoiding a flow through of small parallel connected flow cavities. Thus over all the blocking propensity of the membrane filter 36 is reduced compared to what is known in the art.
(64) Also the second membrane filter 36 can be set up for submerged operations or dry operations.
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(67) The head element 75 includes a permeate collecting cavity 80 which is flow connected with the lumens of the hollow fiber membranes 74 for collecting the permeate and a permeate outlet 81 for draining the permeate. Furthermore the head element 75 includes a second flow cavity 82 for flowing the gas and the liquid to be filtered and flowing out of the head element 75. The third membrane filter 71 can be used in submerged operations and in dry set up operations.
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(74) In alternative embodiment of the eighth embodiment the ribs of the opposite sides of the tub can also be arranged offset relative to one another so that also narrower tubs are implementable. This however has negative effects for longer tubs with respect to their pressure drop and thus with respect to an even longitudinal flow through of the gas.
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REFERENCE NUMERALS AND DESIGNATIONS
(80) 1 membrane filter
(81) 2 base element
(82) 3 shell
(83) 4 membrane carrier
(84) 5 hollow fiber membrane
(85) 6 tube
(86) 7 upper end
(87) 8 length
(88) 9 resin layer
(89) 10 height membrane filter
(90) 11 height base element
(91) 12 height membrane carrier
(92) 13 gas inlet
(93) 14 permeate outlet
(94) 15 anchor location
(95) 16 flow portion
(96) 17 outlet
(97) 18 gas distribution system
(98) 19 tub
(99) 20 wall
(100) 21 vertical slot
(101) 22 inner edge
(102) 23 lower half
(103) 24 angle
(104) 25 permeate collecting cavity
(105) 26 gas
(106) 27 gas cushion
(107) 28 liquid to be filtered
(108) 29 permeate
(109) 30 surface
(110) 31 gas feed conduit
(111) 32 throttle
(112) 33 permeate conduit
(113) 34 first liquid conductor
(114) 35 second liquid conductor
(115) 36 membrane filter
(116) 37 liquid to be filtered
(117) 38 gas
(118) 39 base element
(119) 40 jacket
(120) 41 membrane carrier
(121) 42 anchor location
(122) 43 hollow fiber membrane
(123) 44 permeate
(124) 45 tube
(125) 46 gas inlet
(126) 47 permeate collecting cavity
(127) 48 permeate outlet
(128) 49 height base element
(129) 50 height membrane filter
(130) 51 resin layer
(131) 52 upper end
(132) 53 flow cavity
(133) 54 outlet
(134) 55 bulge
(135) 56 anchor
(136) 57 finger
(137) 58 flow channel
(138) 59 width
(139) 60 diameter
(140) 61 height of membrane carrier
(141) 62 gas distribution system
(142) 63 tub
(143) 64 wall
(144) 65 vertical slot
(145) 66 gas conducting channel
(146) 67 rib
(147) 68 inner edge
(148) 69 lower half
(149) 70 angle
(150) 71 membrane filter
(151) 72 base element
(152) 73 shell
(153) 74 hollow fiber membrane
(154) 75 head element
(155) 76 shell
(156) 77 membrane carrier
(157) 78 anchor location
(158) 79 resin layer
(159) 80 permeate collecting cavity
(160) 81 permeate outlet
(161) 82 flow cavity
(162) 83 membrane filter
(163) 84 tube
(164) 85 base element
(165) 86 tube insert
(166) 87 opening
(167) 88 head element
(168) 89 hollow fiber membrane
(169) 90 permeate collecting cavity
(170) 91 permeate outlet
(171) 92 membrane filter
(172) 93 tube
(173) 94 head element
(174) 95 tube expansion
(175) 96 membrane carrier
(176) 97 permeate collecting cavity
(177) 98 hollow fiber membrane
(178) 99 permeate outlet
(179) 100 base element
(180) 101 membrane filter
(181) 102 base element
(182) 103 head element
(183) 104 tube
(184) 105 first liquid conductor
(185) 106 second liquid conductor
(186) 107 tub
(187) 108 gas inlet
(188) 109 wall
(189) 110 slot
(190) 111 thickness
(191) 112 inner edge
(192) 113 tub
(193) 114 rib
(194) 115 slot
(195) 116 extension
(196) 117 inner edge
(197) 118 thickness
(198) 119 wall
(199) 120 base element
(200) 121 membrane carrier
(201) 122 membrane
(202) 123 resin layer
(203) 124 permeate collecting cavity
(204) 125 permeate outlet
(205) 126 gas distribution system
(206) 127 tub
(207) 128 gas inlet
(208) 129 wall
(209) 130 slot
(210) 131 rib
(211) 132 inner edge
(212) 133 gas distribution system
(213) 134 tub
(214) 135 wall
(215) 136 slot
(216) 137 gas conducing channel
(217) 138 base
(218) 139 gas inlet
(219) 140 inner edge
(220) 141 gas distribution system
(221) 142 tub
(222) 143 wall
(223) 144 slot
(224) 145 inner edge
(225) 146 gas inlet
(226) 147 gas distribution system
(227) 148 tub
(228) 149 gas inlet