Magnetoresistance effect element and magnetic memory device
10410703 ยท 2019-09-10
Assignee
Inventors
- Shunsuke Fukami (Sendai, JP)
- Toru Iwabuchi (Sendai, JP)
- Hideo Ohno (Sendai, JP)
- Tetsuo Endoh (Sendai, JP)
Cpc classification
H01F1/0072
ELECTRICITY
B82Y10/00
PERFORMING OPERATIONS; TRANSPORTING
G01R33/093
PHYSICS
G01R33/098
PHYSICS
G11C11/161
PHYSICS
G11C7/10
PHYSICS
B82Y25/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
G11C11/00
PHYSICS
H01F1/00
ELECTRICITY
G11C7/10
PHYSICS
G11C11/16
PHYSICS
Abstract
A magnetoresistance effect element includes a recording layer containing a ferromagnetic body, and including a first fixed and second magnetization regions having magnetization components fixed substantially in a direction antiparallel to the in-plane direction to each other, and a free magnetization region disposed between the first and second fixed magnetization regions and having a magnetization component invertible in the in-plane direction, a domain wall disposed between the first fixed magnetization region and the free magnetization region, and being movable within the free magnetization region, and a magnetic nanowire having a width of 40 nm or less. The thickness of the recording layer is 40 nm or less and at least half but no more than twofold the width of the magnetic nanowire. The element further includes a barrier layer disposed on the recording layer, and a reference layer disposed on the barrier layer and containing a ferromagnetic body.
Claims
1. A magnetoresistance effect element, comprising: a recording layer containing a ferromagnetic body, the recording layer including a first fixed magnetization region having a magnetization component fixed substantially in an in-plane direction, a second fixed magnetization region having a magnetization component fixed substantially in a direction antiparallel to the in-plane direction of the magnetization component of the first fixed magnetization region, a free magnetization region disposed between the first fixed magnetization region and the second fixed magnetization region, the free magnetization region having a magnetization component that is invertible in the in-plane direction, a domain wall disposed between the first fixed magnetization region and the free magnetization region, and being movable within the free magnetization region, and a magnetic nanowire having a width of 40 nm or less, the recording layer having a thickness of 40 nm or less, the thickness of the recording layer being at least half but no more than twofold the width of the magnetic nanowire; a barrier layer disposed on the recording layer; and a reference layer disposed on the barrier layer and containing a ferromagnetic body.
2. The magnetoresistance effect element according to claim 1, wherein the recording layer contains Ni and Fe, the width of the magnetic nanowire in the recording layer is 30 nm or less, and the thickness of the recording layer is 30 nm or less and at least two-thirds but no more than one and one half times the width of the magnetic nanowire.
3. The magnetoresistance effect element according to claim 1, wherein the recording layer has a first length in a first direction and a second length in a second direction that is perpendicular to the first direction provided that the first length is greater than the second length, and the magnetization component of the free magnetization region is inverted by applying an electrical current through the recording layer in the first direction.
4. The magnetoresistance effect element according to claim 1, wherein the domain wall is formed between the first fixed magnetization region and the free magnetization region or between the second fixed magnetization region and the free magnetization region, depending on direction of the magnetization component of the free magnetization region.
5. The magnetoresistance effect element according to claim 1, further comprising a magnetization fixing layer that fixes at least one of (a) direction of the magnetization component of the first fixed magnetization region and (b) direction of the magnetization component of the second fixed magnetization region.
6. The magnetoresistance effect element according to claim 1, wherein the recording layer includes a pinning site provided either between the first fixed magnetization region and the free magnetization region or between the second fixed magnetization region and the free magnetization region.
7. A magnetic memory device, comprising: the magnetoresistance effect element according to claim 1; a writing unit configured to write data into the magnetoresistance effect element by applying a writing current between the first fixed magnetization region and the second fixed magnetization region through the free magnetization region in the recording layer, to thereby move the domain wall; and a reading unit configured to read out data from the magnetoresistance effect element by applying a current through the barrier layer in a direction parallel to a thickness direction of the magnetoresistance element that is effective to obtain a tunnel resistance.
8. The magnetoresistance effect element according to claim 1, wherein the free magnetization region in the recording layer has a thickness of 40 nm or less, the thickness of the recording layer being at least half but no more than twofold the width of the magnetic nanowire.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
DETAILED DESCRIPTION OF THE INVENTION
(17) Below, a magnetoresistance effect element of an embodiment of the present invention, and a magnetic memory device using such a magnetoresistance effect element will be explained with reference to the figures.
Embodiment 1
(18) Below, a magnetoresistance effect element of Embodiment 1 will be explained with reference to
(19) A magnetoresistance effect element 100 of Embodiment 1 includes a recording layer 10, a barrier layer 20, and a reference layer 30 stacked in this order as shown in the front view of
(20) The recording layer 10 is made of a ferromagnetic body including an element such as Fe, Co, or Ni. Specifically, the recording layer 10 is made of a 3d transition metal such as Fe, Co, and Ni, or an alloy including a 3d transition metal such as FeCo, FeNi, CoNi, FeCoNi, CoFeB, FeB, and CoB. B. C, N, O, Al, Si, P, Ga, Ge, and the like may also be added to achieve a desired electrical property or structure.
(21) Respective ends of the recording layer 10 in the lengthwise direction (X axis direction) are regions with fixed magnetization (magnetic field). The magnetic field on the left side of
(22) The recording layer 10 is a layer having an easy magnetization axis in the in-plane direction. A magnetization direction M11 of the first fixed magnetization region 11 and a magnetization direction M12 of the second fixed magnetization region 12 are substantially fixed. The magnetization direction M11 and the magnetization direction M12 are opposite to each other. On the other hand, a magnetization direction M13 of the free magnetization region 13 can change, and is switched between +X axis direction and X axis direction by the electric current flowing through the recording layer 10 upon data writing.
(23) In the figure, the magnetization direction M11 of the first fixed magnetization region 11 is the +X axis direction, and the magnetization direction M12 of the second fixed magnetization region 12 is the X axis direction, but the magnetization direction M11 and the magnetization direction M12 may also be opposite, respectively. That is, the magnetization direction M11 of the first fixed magnetization region 11 may be the X axis direction, and the magnetization direction M12 of the second fixed magnetization region 12 may be the +X axis direction. The magnetization directions of the first fixed magnetization region 11 and second fixed magnetization region 12 do not have to be exactly along the +/X axis directions, and an error of about +/20 degrees is allowed.
(24) With the configuration described above, a domain wall DW is formed between the first fixed magnetization region 11 and the second fixed magnetization region 12. The position where the domain wall DW is formed is determined by the magnetization direction M13 of the free magnetization region 13.
(25) The wire width (length in the Y axis direction) of the recording layer 10 is 40 nm or less, and is preferably 30 nm or less. The film thickness (thickness in the Z axis direction) of the recording layer 10 is 40 nm or less, and is at least half but no more than twofold the wire width. When the width of the magnetic nanowire is 20 nm, for example, it is preferable that the film thickness be 10 nm or more and 40 nm or less.
(26) The barrier layer 20 is a layer made of an insulator and formed on the recording layer 10. The barrier layer 20 is made of an insulator such as MgO, Al.sub.2O.sub.3, or AIN. If the barrier layer 20 is made of MgO, for example, the film thickness thereof is set to approximately 0.5 nm to 2.0 nm. More preferably, the film thickness is set to approximately 0.8 nm to 1.5 nm. By appropriately selecting the materials for the recording layer 10 and the barrier layer 20, a large tunnel magneto resistance (TMR) can be achieved. From this perspective, it is preferable that the recording layer 10 be CoFeB/MgO, and the barrier layer 20 be FeB/MgO. Alternatively, the recording layer 10 may have a multi-layer structure made of two or more different ferromagnetic layers, and the layer thereof adjacent to the barrier layer 20 may be made of CoFeB or FeB.
(27) In the description above, the barrier layer 20 was formed on top of the recording layer 10, but here, top does not mean the top and bottom of the gravity direction. Thus, forming the barrier layer 20 on top of the recording layer 10 means forming the barrier layer 20 so as to be adjacent to the recording layer 10, for example. The barrier layer 20 does not necessarily have to be in contact with the recording layer 10, for example. Another layer or space may be interposed between the barrier layer 20 and the recording layer 10. This also applies to the relationship between the barrier layer 20 and the reference layer 30.
(28) The reference layer 30 is a layer made of a ferromagnetic body and formed on the barrier layer 20. The magnetization direction M30 of the reference layer 30 is substantially fixed. The reference layer 30 includes Fe, Co, Ni, and the like. In order to fix the magnetization direction more securely, the reference layer 30 may also include an antiferromagnetic layer made of IrMn, PtMn, or the like. In the process of data-reading, information stored is read out in accordance with the magnetization directions of the reference layer 30 and the recording layer 10. In this example, the magnetization direction 30 is fixed in the X axis direction.
(29) In the figure, the reference layer 30 has the same shape as the barrier layer 20 in the X-Y plane, but the respective layers may have different shapes. For example, the barrier layer 20 may have the same shape as the recording layer 10, and the reference layer 30 may be formed to be smaller than that. The reference layer 30 needs to overlap with the free magnetization region 13 of the recording layer 10 in at least a part of the X-Y plane so that information is read out by the tunnel magneto resistance effect.
(30) The length of the recording layer 10 in the X-axis direction is about 50 to 400 nm. In the recording layer 10, the length of the free magnetization region 13 in the X-axis direction is about 40 to 100 nm. The lengths of the first fixed magnetization region 11 and the second fixed magnetization region 12 in the X-axis direction are respectively about 40 to 200 nm. The length of the reference layer 30 in the X-axis direction is about 40 to 100 nm. In Embodiment 1, the reference layer 30 is formed so as not to be larger than the recording layer 10 in the X-Y plane. Thus, the length of the reference layer 30 in the Y-axis direction is no greater than 40 nm.
(31) In order to form the recording layer 10, the barrier layer 20, and the reference layer 30, first, respective films for the recording layer 10, the barrier layer 20, and the reference layer 30 are deposited on a substrate (not shown in the figure) by super high vacuum spattering method or the like. Thereafter, the deposited films are patterned into a desired shape by photolithography or the like. Heat treatment in a magnetic field may also be performed after the thin films are deposited or after the element is formed. In this case, the heat treatment temperature is 250 to 400 degrees, and the magnetic field is 0.2 T or greater and 2 T or smaller.
(32) Below is one example of the configuration of each layer of the magnetoresistance effect element 100: the recording layer 10: CoFeB (20 nm-thick); the barrier layer 20: MgO (1.2 nm-thick); and the reference layer 30 (from the substrate side): CoFeB (1.5 nm-thick), CoFe (1 nm-thick), Ru (0.9 nm-thick), CoFe (2.5 nm-thick), PtMn (20 nm-thick).
(33) Another example of the configuration of each layer of the magnetoresistance effect element 100 is as follows: the recording layer 10: NiFe (9 nm-thick), CoFeB (1 nm-thick); the barrier layer 20: MgO (0.9 nm-thick); and the reference layer 30 (from the substrate side): CoFeB (2 nm-thick), CoFe (1 nm-thick), Ru (0.9 nm-thick), CoFe (3 nm-thick), IrMn (12 nm-thick). In the configuration shown in the example, the reference layer has a multi-layer ferrimagnetic structure, and Ru functions as the coupling layer in the multi-layer ferrimagnetic structure.
(34) The recording layer 10 may have an underlying layer (Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, or W), or a seed layer (Cr, Fe, Ru, Rh, Pd, Ag, Cu, Jr, Pt, or Au) therebelow. The reference layer 30 may have a cap layer (Ta, Ru, or Cu) thereabove. The underlying layer, the seed layer, and the cap layer are formed as necessary in order to improve the contact with the substrate, crystal orientation, electrical conductivity, and anti-corrosion property.
(35) The preferable ranges of the film thickness and dimensions described above were set based on the technical standards of the current semiconductor integrated circuit, and the ranges of film thickness and dimensions that can achieve the effects of the present invention may be modified as the processing technique progresses in the future.
(36) The magnetization direction M13 of the free magnetization region 13 of the recording layer 10 changes between the +X-axis direction and X-axis direction. This changes the resistance state of the respective layers from the recording layer 10 to the reference layer 30 of the magnetoresistance effect element 100 between the high resistance state and the low resistance state. By assigning bit data of 0 and 1 to the respective resistance states, and changing the resistance states, data can be stored in the magnetoresistance effect element 100. When data is to be read out from the magnetoresistance effect element 100, a reading current Jr is given between an electrode (not shown in the figure) formed on the reference layer 30 and the recording layer 10 so that the resistance state (either high resistance state or low resistance state) of the magnetoresistance effect element 100 is detected. This way, data stored in the magnetoresistance effect element 100 is read out.
(37) Below, the reading operation and writing operation will be explained in detail.
(38) First, the reading operation will be explained with reference to
(39) On the other hand, in the state of
(40) The domain wall DW changes the position thereof between the region P1 and the region P2 depending on the magnetization direction M13 of the free magnetization region 13. In other words, the magnetoresistance effect element 100 stores a different type of data depending on the position of the domain wall DW.
(41) In this embodiment, the low resistance state shown in
(42) Next, the writing operation will be explained with reference to
(43) In order to write data 1 into the magnetoresistance effect element 100 that has the data 0 stored therein, the writing current Iw is made to flow in the X axis direction as shown in
(44) On the other hand, in order to write data 0 into the magnetoresistance effect element 100 that has the data 1 stored therein, the writing current Iw is made to slow in the +X axis direction as shown in
(45) The magnetization direction M11 of the first fixed magnetization region 11 and the magnetization direction M12 of the second fixed magnetization region 12 are respectively fixed. Thus, even when the writing current Iw of the +X axis direction is given to the magnetoresistance effect element 100 that has the data 0 stored therein (even when the data 0 is written into), the data rewriting due to the spin transfer torque does not occur, and the domain wall DW does not move. Similarly, even when the writing current Iw of the X axis direction is given to the magnetoresistance effect element 100 that has the data 1 stored therein, the domain wall DW does not move.
(46) The relationship between the direction of the writing current Iw and the moving direction of the domain wall DW varies depending on the materials used for the recording layer 10.
(47) The current pulse width TW shown in
(48) Next, a memory circuit using, as a memory cell, the magnetoresistance effect element 100 having the configuration described above will be explained with reference to
(49)
(50) The magnetoresistance effect element 100 has a three-terminal structure in which a first terminal T1 connected to one end of the recording layer 10, a second terminal T2 is connected to the other end thereof, and a third terminal T3 is connected to the reference layer 30. More specifically, the first terminal Ti is connected to one end of the first fixed magnetization region 11, and the second terminal T2 is connected to one end of the second fixed magnetization region 12.
(51) The third terminal T3 is connected to the ground line GND. The first terminal T1 is connected to the drain of the first transistor Tr1, and the second terminal T2 is connected to the drain of the second transistor Tr2. The gate electrodes of the first transistor Tr1 and the second transistor Tr2 are connected to the word line WL. The source of the first transistor Tr1 is connected to the first bit line BL1 and the source of the second transistor Tr2 is connected to the second bit line BL2.
(52) The magnetoresistance effect element 100 does not have to have the three-terminal structure, and may have a four-terminal structure as shown in
(53) When information is to be written into the magnetoresistance effect element 100, first, an active level signal is applied to the word line WL to turn on the transistors Tr1 and Tr2 so as to select the magnetoresistance effect element 100. In this example, the transistors Tr1 and Tr2 are made of an N-channel MOS transistors. In this case, the word line WL is set to the high level. This turns on the first transistor Tr1 and the second transistor Tr2. On the other hand, one of the first bit line BL1 and the second bit line BL2 is set to the high level, and the other is set to the ground level, depending on the type of data to be written.
(54) Specifically, when data 1 is to be written, the first bit line BL1 is set to the low level, and the second bit line BL2 is set to the high level. This causes the writing current Iw to flow in the direction from the second fixed magnetization region 12 to the first fixed magnetization region 11 (forward direction) as shown in
(55) On the other hand, when the information stored in the magnetoresistance effect element 100 is to be read out, the word line WL is set to the active level so that the first transistor Tr1 and the second transistor Tr2 are turned on. Then both the first bit line BL1 and the second bit line BL2 are set to the high level, or one of the bit lines BL1 and BL2 is set to the high level, and the other is set to the open state. From the bit line that is set to the high level, a current flows from the recording layer 10 to the ground line GND through the barrier layer 20, the reference layer 30, and the third terminal T3. By measuring the size of this current, the size of the resistance in the channel from the recording layer 10 to the reference layer 30, or in other words, the stored data can be obtained.
(56) The configuration and the circuit operation of the magnetic memory cell circuit 200 are merely one example, and may be appropriately modified. For example, the first terminal T1 may be connected to the second fixed magnetization region 12, and the second terminal T2 may be connected to the first fixed magnetization region 11. The ground may be set to a reference voltage instead of the ground voltage. The third terminal may be connected to the third bit line (not shown in the figure), instead of the ground line GND. In this case, when the data is to be read out, the word line WL is set to the high level, the third bit line is set to the high level, and one or both of the first bit line and the second bit line is set to the ground level. In this state, the current flowing from the third bit line to the first bit line BL1 and the second bit line BL2 is measured.
(57) Next, the configuration of a magnetic memory device 300 including a plurality of the magnetic memory cell circuits 200 of
(58) As shown in
(59) The X driver 312 is connected to a plurality of word lines WL, and is configured to receive a row address, decode the row address, and activate the word line WL to allow access (to the high level when the first transistor Tr1 and the second transistor Tr2 are N-channel MOS transistors).
(60) The Y driver 313 functions as a writing means for writing data into the magnetoresistance effect element 100 and a reading means for reading out the data from the magnetoresistance effect element 100. The Y driver 313 is connected to a plurality of first bit lines BL1 and second bit lines BL2. When the data is to be written or read out, the Y driver 313 receives a column address, decodes the column address, and sets the first bit line BL1 and the second bit line BL2 connected to the magnetic memory cell circuit 200 to be accessed to a desired data writing state or reading state.
(61) That is, when the data 1 is to be written, the Y driver sets the first bit line BL1 and the second bit line BL2 connected to the magnetic memory cell circuit 200, in which the data is to be written, to the low level and the high level, respectively. On the other hand, when data 0 is to be written, the first bit line BL1 is set to the high level, and the second bit line BL2 is set to the low level.
(62) When the information stored in the magnetic memory cell circuit 200 is to be read out, the Y driver 313 sets both the first bit line BL1 and the second bit line BL2 to the high level, or sets one of the bit lines BL1 and BL2 to the high level, and the other to the open state. The Y driver 313 then compares the current flowing through the bit lines BL1 and BL2 with the reference value, determines the resistance state of the magnetic memory cell circuit 200 of each column, and reads out the stored data.
(63) The controller 314 controls the X driver 312 and the Y driver 313 when data is written in or read out.
(64) The ground line GND connected to the reference layer 30 of the magnetoresistance effect element 100 is connected to the X driver 312, but as described above, this can be replaced with the read-out bit line connected to the Y driver 313.
(65) In the embodiment described above, the width of the magnetic nanowire and film thickness of the recording layer 10 of the magnetoresistance effect element 100 was set to 40 nm or smaller, and the film thickness was set to at least half but no more than twofold the width of the magnetic nanowire. Below, how limiting the design value of the fire wire of the recording layer 10 to a certain range allows for the domain wall movement with a low threshold current density will be explained.
(66) First, in order to operate a current induced domain wall movement device stably with a low current, it is effective to achieve a low threshold current density. The threshold current density J.sub.c of the current induced domain wall movement is represented by the following formula.
(67)
e: elementary charge
: Dirac's constant
M.sub.s: Saturation magnetization
P: Spin polarization rate
: Domain wall width parameter
H.sub.K: Hard axis anisotropic magnetic field
(68) e and (below the Dirac's constant may be represented by ) are physical constants. Ms and P are parameters determined by the material of the element. and H.sub.K are parameters for the domain wall. Generally, a material with a small saturated magnetization Ms has a small spin polarizability P. Thus, it is difficult to reduce the threshold current density J.sub.c by Ms/P.
(69) This means that in order to reduce the threshold current density J.sub.c, it is effective to use a material that can make smaller the values of the domain wall width parameter and the hard axis anisotropic magnetic field H.sub.K.
(70) The domain wall width parameter has a relationship of w= with the domain wall width w. Also, the domain wall width parameter is represented by the following formula by the exchange stiffness constant A and the effective magnetic field anisotropic constant K.sub.eff in the easy axis direction.
={square root over (A/K.sub.eff)}Formula 2
A: Exchange stiffness constant
K.sub.eff: Effective magnetic anisotropic constant
(71) The hard axis anisotropic magnetic field H.sub.K is the size of the magnetic field that represents the difference in energy when the magnetization direction of the domain wall is oriented to the two directions other than the magnetic easy axis.
(72) In the early stage of the study on the current induced domain wall movement, an NiFe alloy having the magnetization easy axis in the in-plane direction was often used. In the researches at that time, the width of the NiFe magnetic nanowire was in the 100 nm order, and the film thickness was in the 10 nm order. In this case, the domain wall width w is about 100 nm. The hard axis anisotropic magnetic field H.sub.K corresponds to a difference in energy between the case in which the magnetization direction of the domain wall coincides with the Y axis direction as shown in
(73) WO2009/001706 proposes the use of the vertical magnetization method instead of the in-plane magnetization method as a solution to the problem described above. In the vertical magnetization method, the film thickness is set to several nm, and the domain wall width w is set to about 10 nm. The hard axis anisotropic magnetic field H.sub.K corresponds to a difference in energy between the case in which the magnetization direction of the domain wall coincides with the Y axis direction as shown in
(74) However, even in the vertical magnetization method, if the wire width of the magnetic nanowire was further reduced, the domain wall movement with a low current density would not be achieved. If the wire width w is greater than the domain wall width, Bloch domain wall is formed as shown in
(75)
(76) Specifically,
(77)
(78) As described above, the threshold current density J.sub.c is determined by the product of the domain wall width parameter and the hard axis anisotropic magnetic field H.sub.K, and therefore, the threshold current density J.sub.c was obtained based on the resultant value of
(79) As shown in
(80) On the other hand, as shown in
(81) Thus, as shown in
(82) On the other hand, in the in-plane magnetization method, as described in Embodiment 1, the threshold current density can be reduced by limiting the design value of the wire width and film thickness of the magnetic nanowire to a certain range. The hard axis anisotropic magnetic field is a difference between the case in which the magnetization of the domain wall appears on the wt plane as shown in
(83)
(84) Specifically,
(85)
(86)
(87) As shown in
(88) In the in-plane magnetization film, the domain wall width parameter and the hard axis anisotropic magnetic field H.sub.K are determined by the magnetic nanowire width and the film thickness, and show a qualitative tendency of not depending on the material constant almost at all. Thus, this calculation result qualitatively applies to any in-plane magnetization film, even though
(89) This simulation result shows that there is an upper limit on the wire width w to make the hard axis anisotropic magnetic field H.sub.K take the smallest value by forming the magnetic nanowire such that the wire width w and the film thickness t are substantially the same. When the wire width w is 40 nm or greater, even if the wire width w is made to be substantially equal to the film thickness t, the hard axis anisotropic magnetic field H.sub.K does not take the smallest value. This is because, as shown in
(90) On the other hand, when the wire width is 40 nm or less, the domain wall takes the transverse structure as shown in
(91) The effect described above (the hard axis anisotropic magnetic field H.sub.K takes the smallest value) is achieved ideally when the wire width w and the film thickness t are equal to each other, but actually, it is difficult to make the wire width w and the film thickness t completely equal to each other due to processing errors from the ideal shape, variations in magnetic property in places, and the like. However, according to the simulation, when the wire width w and the film thickness t is no greater than 40 nm, and the film thickness is at least half but no more than twofold the wire width, the threshold current density J.sub.c can be 110.sup.12 A/m.sup.2 or smaller.
(92) When the vertical magnetic anisotropy appears at the interface, similar effects can be achieved by making the film thickness t smaller (thinner) than the wire width w. For example, when CoFeB and FeB are used for the recording layer, and MgO is used for the barrier layer, the vertical magnetic anisotropy appears at the interface, but in this case, by making the film thickness t fall within a range of 25% to 75% of the wire width, the maximum effect of the present invention can be achieved.
(93) As shown in
(94)
(95) The upper limit of the current density that can be introduced into the NiFe magnetic nanowire is approximately 310.sup.12 A/m.sup.2. In
(96) As described above, in the magnetoresistance effect element 100 of this embodiment, when the magnetic nanowire width is small, or more specifically, when the wire width is 40 nm or smaller, the domain wall can be moved with a low threshold current density.
(97) Also, because there are not many materials that have the vertical magnetization, there is a limitation of the material selection in the vertical magnetization method, but if the in-plane magnetization method is employed, the broader range of material would be available.
(98) There is no physical constraints on the lower limit of the magnetic nanowire width, and the lower limit value varies depending on the processing technique. In order to make magnetic nanowire smoothly without causing variations, the crystal grain size plays an important role, and therefore, the lower limit value of the wire width is about 5 nm. Also, in the ultra-fine generation of approximately 10 nm or below, a bottom-up approach such as self-organization may be used to form magnetic nanowires, rather than a top-down method such as photolithography. In this case, the wire width need to be large enough for the ferromagnetic property to be expressed. The wire width allowing for the expression of ferromagnetic property largely depends on the material used, but when using a material that has a large exchange interaction, the wire width is about 3 nm. The same lower limited value of the magnetic nanowire width applies to the descriptions below.
Embodiment 2
(99) In order to stably write and read data into and from the magnetoresistance effect element 100 of Embodiment 1, it is necessary to secure the magnetization direction M30 of the reference layer 30. In order to secure the magnetization direction M30 of the reference layer 30, it is effective to form the reference layer 30 of a multi-layer ferromagnetic coupling layer.
(100) Below an embodiment of a magnetoresistance effect element 101 in which the reference layer 30 is made of a multi-layer ferromagnetic coupling layer will be explained with reference to
(101) In Embodiment 2, the reference layer 30 includes a ferromagnetic layer 31, a coupling layer 32, and a ferromagnetic layer 33, which forming a multi-layer structure with ferromagnetic coupling. The ferromagnetic layer 31 and the ferromagnetic layer 33 are coupled with each other via the coupling layer 32 in an anti-ferromagnetic manner. It is preferable to use a ferromagnetic material such as Fe, Co, and NI for the ferromagnetic layer 31 and the ferromagnetic layer 33. It is preferable to use Ru and the like for the coupling layer 32. Other configurations are the same those of Embodiment 1.
(102) With this configuration, when the magnetization direction M13 of the free magnetization region 13 of the recording layer 10 coincides with the magnetization direction M31 of the ferromagnetic layer 31 that is closer to the recording layer 10 than the ferromagnetic layer 33, the magnetoresistance effect element 101 enters the parallel state, i.e., low resistance state. On the other hand, when the magnetization direction M13 of the free magnetization region 13 of the recording layer 10 is opposite to the magnetization direction M31 of the ferromagnetic layer 31, the magnetoresistance effect element 101 enters the anti-parallel state, i.e., the high resistance state.
(103) Similar to Embodiment 1, it is possible to drive the domain wall with a low threshold current density in Embodiment 2.
(104) The present invention is not limited to the embodiments described above, and various modification s are possible. Modification examples and application examples will be explained below.
Modification Example 1
(105) The combination of the resistance levels and data types can be appropriately changed, and it is also possible to assign the data 1 to the low resistance state and the data 0 to the high resistance state.
Modification Example 2
(106) The magnetoresistance effect element 100 may further include a layer that strengthens the magnetization of the first fixed magnetization region 11 and the second fixed magnetization region 12 of the recording layer 10. As shown in
Modification Example 3
(107) Alternatively, as shown in
Modification Example 4
(108) Alternatively, the magnetoresistance effect element 100 may have only one of the first magnetization fixing layer 41 and the second magnetization fixing layer 42. In the example of
(109) The first magnetization fixing layer 41 and the second magnetization fixing layer 42 can be formed of a ferromagnetic material such as Fe, Co, and Ni, or anti-ferromagnetic material such as IrMn, PtMn, and FeMn. Further, the magnetization direction of the first magnetization fixing layer 41 and the first fixed magnetization region 11 does not necessarily have to be parallel to the magnetization direction of the second magnetization fixing layer 42 and the second fixed magnetization region 12, and may be coupled in the anti-parallel direction to secure the magnetization.
Modification Example 5
(110) In Embodiment 1 described above, as shown in
Modification Example 6
(111) In Embodiment 1, the barrier layer 20 and the reference layer 30 are stacked on the upper surface of the free magnetization region 13 of the recording layer 10. This is because it is necessary that at least the reference layer 30 overlaps the free magnetization region 13 of the recording layer 10. However, the multi-layer structure is not limited thereto, and as shown in
Modification Example 7
(112) Furthermore, the recording layer 10 does not necessarily have to be on the bottom, and as shown in
Modification Example 8
(113) In the examples described above, the magnetoresistance effect element 100 includes one reference layer 30, but it is also possible to provide a plurality of reference layers as shown in
Modification Example 9
(114) As shown in
Modification Example 10
(115)
Modification Example 11
(116) The locations of the pin sites are not limited to the example described above. In the example shown in
Modification Example 12
(117) Alternatively, instead of forming the notches in the recording layer 10, the pin sites can be provided by forming regions with different material properties between the first fixed magnetization region 11 and the free magnetization region 13 (14) and between the second fixed magnetization region 12 and the free magnetization region 13 (15), respectively.
(118) Modification Examples 10, 11, and 12 with the pin site can be combined with Modification Examples 8 and 9 in which the magnetoresistance effect element 100 can be used as a multi-value memory or an analog memory. In this case, a pin site is formed inside of the free magnetization region or between the respective free magnetization regions.
(119) In addition to forming pin sites, the domain wall can be stably pinned in the information holding state by appropriately designing the planer shape and cross-sectional shape of the first fixed magnetization region 11 and the second fixed magnetization region 12. For example, as revealed from the simulation results shown in
(120) In one example, the pinning mechanism described above can be achieved by designing the element such that the wire width of the free magnetization region 13 is 15 nm, the film thickness thereof is 15 nm, the wire width of the first fixed magnetization region 11 and the second fixed magnetization region 12 is 35 nm and the film thickness thereof is 15 nm. In another example, the pinning mechanism described above can be achieved by designing the element such that the wire width of the free magnetization region 13 is 20 nm, the film thickness thereof is 20 nm, the wire width of the first fixed magnetization region 11 and the second fixed magnetization region 12 is 20 nm and the film thickness thereof is 9 nm.
Modification Example 13
(121) In the embodiments and modification examples described above, the recording layer 10 had a shape that extended in the lengthwise direction, but the shape of the recording layer 10 is not limited thereto. In the example shown in
Modification Example 14
(122) In the embodiments and modification examples described above, the Y-Z cross-section of the recording layer 10 was a square or rectangle, but the recording layer 10 may have a tapered shape.
(123)
Modification Example 15
(124) In any of Modification Examples 2 to 14, the reference layer 30 may take the multi-layer ferrimagnetic structure described in Embodiment 2.
(125) All of the embodiments described above are for STT-MRAM of the three-terminal (or four) type, but the technical concept of the present invention can also be applied to a race track memory that can be used for a large-capacity storage. That is, it is possible to provide a magnetic memory device that is made of a ferromagnetic body, having a track (recording layer) with a plurality of recording magnetic areas, and configured such that the track has the magnetization easy axis in the magnetic nanowire lengthwise direction, the wire width is 40 nm or less, and the film thickness thereof is at least half but no more than twofold the wire width.
(126) The present invention may have various different embodiments and may be modified in various manners without departing from the broader spirit and scope of the present invention. The embodiments described above are intended to illustrate the present invention, and are not intended to limit the scope of the present invention. That is, the scope of the present invention is not specified by embodiments, but the appended claims. The various modifications implemented within the scope of the appended claims and the spirit and scope of the invention equivalent to the appended claims are considered within the scope of the present invention.
(127) This application is based on Japanese Patent Application No. 2015-98976, filed on May 14, 2015, and is intended to incorporate the specification, claims, drawings and abstract thereof. What is disclosed in said Japanese Patent Application is entirely incorporated by reference herein.