Method and apparatus for printing on cylindrical objects
11541652 · 2023-01-03
Assignee
Inventors
Cpc classification
B41J11/002
PERFORMING OPERATIONS; TRANSPORTING
B41F17/006
PERFORMING OPERATIONS; TRANSPORTING
B41J3/4073
PERFORMING OPERATIONS; TRANSPORTING
B41J3/40733
PERFORMING OPERATIONS; TRANSPORTING
International classification
B41J3/407
PERFORMING OPERATIONS; TRANSPORTING
B41M1/40
PERFORMING OPERATIONS; TRANSPORTING
B41F13/00
PERFORMING OPERATIONS; TRANSPORTING
B41J11/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
An apparatus is disclosed for printing images on generally cylindrical objects. The apparatus comprises an impression station that includes a movable imaging surface for bearing an ink image; and a transport mechanism for advancing the objects through the impression station, comprising a drive member rotatably connected to a plurality of rotatable mandrels, each for mounting a respective one of the objects, the transport mechanism being configured to cause each object to rotate during passage through the impression station such that, within a nip region of the impression station, the surface of the object makes rolling contact with the imaging surface, thereby causing the ink image to be impressed on the object. An impression platen is provided opposite the imaging surface within the nip region, the impression platen being configured to apply a force, directly or indirectly, to the objects to ensure rolling contact between the objects and the imaging surface.
Claims
1. An apparatus for printing images on generally cylindrical objects, comprising: (i) an impression station that includes a movable imaging surface for bearing an ink image; and (ii) a transport mechanism for advancing the objects through the impression station, comprising a drive member to which a plurality of mandrels is rotatably connected, each mandrel for supporting a respective one of the objects, the transport mechanism being configured to cause each object to rotate during passage through the impression station such that, within a nip region of the impression station, the surface of the object makes rolling contact with the imaging surface, thereby causing the ink image on the imaging surface to be impressed on the surface of the object; wherein (iii) an impression platen is provided within the nip region of the impression station on the opposite side of the objects from the imaging surface, the impression platen being configured to apply a force, directly or by way of the mandrels, to the objects to ensure rolling contact between the objects and the imaging surface and being stationary at least in a direction of movement of the imaging surface within the nip region.
2. The apparatus as claimed in claim 1, wherein the impression platen is configured to apply a force directly to each object, by making rolling contact with a region of the surface of each object diametrically opposite a line of contact between the object and the imaging surface.
3. The apparatus as claimed in claim 1, wherein the impression platen is configured to contact the transport mechanism, so as to urge the mandrels supporting the objects towards the image surface.
4. The apparatus as claimed in claim 1, wherein the imaging surface is that of an endless intermediate transfer member (ITM) of an offset printing system that further comprises an imaging station for depositing at least one ink on the ITM, and a drying station to dry the ink and leave behind a tacky ink image to be transferred at the impression station onto an object, wherein an opposite surface of the ITM rests on a support surface contoured to match the surface of the impression platen.
5. The apparatus as claimed in claim 4, wherein the ITM is advanced through the nip region of the impression station at a speed substantially equal to twice that of the mandrels.
6. The apparatus as claimed in claim 4, wherein the working circumference of the ITM is selected such that said circumference is a whole number multiple of the pitch of the mandrels.
7. The apparatus as claimed in claim 4, wherein the ITM includes at least one seam which is at least a part of a no-print region of the ITM.
8. The apparatus as claimed in claim 4, wherein a skip-feed mechanism is provided so that no object is mounted on a mandrel entering the nip region synchronously with a no-print region.
9. The apparatus as claimed in claim 4, wherein a) the impression platen is concave and the ITM passes in the nip region over a rotating drive or guide roller having a convex support surface; or b) the impression platen is flat and the ITM is guided over a stationary flat support surface; or c) the impression platen is convex and the ITM is guided over a concave support surface.
10. The apparatus as claimed in claim 9, wherein the support surface in contact with the ITM is made of, or coated with, a low-friction material.
11. The apparatus as claimed in claim 9, wherein the impression platen and the support surface are flat and wherein an endless belt encircles the support surface and is disposed between the ITM and the support surface.
12. The apparatus as claimed in claim 4, wherein the ITM is wider than the axial length of two objects, and wherein several drive members interact with a common ITM.
13. The apparatus as claimed in claim 4, wherein the ITM is wider than the axial length of two objects, and wherein several drive members interact with the same ITM at stations staggered along the direction of travel of the ITM.
14. The apparatus as claimed in claim 1, wherein the drive member of the transport mechanism connected to the rotatable mandrels is a flexible endless drive member.
15. The apparatus as claimed in claim 14, wherein the drive member of the transport mechanism is constructed as a toothed belt or as a chain formed of links that are pivotably connected to one another.
16. The apparatus as claimed in claim 14, wherein mandrels are disposed symmetrically on opposite sides of the drive member.
17. The apparatus as claimed in claim 16, wherein the drive member of the transport mechanism is constructed as a chain formed of links that are pivotably connected to one another and wherein the axle of each mandrel is aligned with a pivot pin connecting two links of the chain.
18. The apparatus as claimed in claim 1, wherein the mandrels are releasably secured to the drive member and retained on the drive member by a mechanical detent and/or magnetic attraction.
19. The apparatus as claimed in claim 1, wherein each mandrel includes at least one internal passage for permitting air flow axially along the mandrel, so as to enable objects to be retained on the mandrels by suction, and to be blown off the mandrels pneumatically.
20. The apparatus as claimed in claim 1, wherein a heating station is provided for heating objects, and/or the mandrels, prior to entering the impression station, to cause impression of the ink image onto the surface of the object to occur at an elevated temperature.
21. The apparatus as claimed in claim 1, wherein the transport mechanism is movable away from the impression station to afford access for servicing of the apparatus.
22. A method of printing on the outer surfaces of generally cylindrical objects, which method comprises: (a) mounting each object on a respective mandrel rotatable about an axis, (b) advancing the objects while mounted on the mandrels through an impression station that includes an imaging surface bearing an ink image, and (c) rotating each object about the axis of its respective mandrel during passage through the impression station while urging the object against the imaging surface, such that the surface of the object makes rolling contact with the imaging surface within a nip region, thereby causing the ink image to be impressed on the surface of the object, wherein (d) the object is urged into rolling contact with the imaging surface during passage through the impression station by an impression platen provided in the nip region of the impression station on the opposite side of the objects from the imaging surface, the impression platen being configured to apply a force, directly or by way of the mandrels, to the objects to ensure rolling contact between the surface of the objects and the imaging surface, and being stationary at least in a direction of movement of the imaging surface within the nip region.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Some embodiments of the disclosure will now be described further, by way of example, with reference to the accompanying figures, where like reference numerals or characters indicate corresponding or like components. The description, together with the figures, makes apparent to a person having ordinary skill in the art how some embodiments of the disclosure may be practiced. The figures are for the purpose of illustrative discussion and no attempt is made to show structural details of an embodiment in more detail than is necessary for a fundamental understanding of the disclosure. For the sake of clarity and convenience of presentation, some objects depicted in the figures are not necessarily shown to scale.
(2) In the Figures:
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DETAILED DESCRIPTION
Nip Regions, ITM Support Surfaces and Impression Platens
(15)
(16) As in the apparatus shown in
(17) The contact between the objects 106 and the impression platen 124 causes the objects and their mandrels to rotate such that the objects 106 make rolling contact with the impression platen 124. For rolling contact between the objects 106 and the stationary platen 124, contact with the platen imparts an angular acceleration to the objects, causing them to spin with an angular velocity ω, which is such that ω.r=ν, where r is the radius of the objects and ν is equal to the velocity of drive member 120. For the opposite side of the objects 106 to make rolling contact with the ITM 130, the latter must move with a velocity ω.r+ν, that is to say at twice the speed of the drive member 120.
(18) As the drive member 120 is flexible in the plane of
(19) After the objects have rotated within the nip region through 180°, ink will reside on the surface of the objects in contact with the impression platen 124 and, as the ink may still be tacky, it is desirable for the impression platen 124 to have a low surface energy surface to which the ink will not adhere. Non-limiting examples of such low surface energy materials are silicone, fluorosilicone, ethylene-tetrafluoroethylene and poly-tetrafluoroethylene.
(20) In the embodiment of
(21) The embodiments of
(22) In the embodiment of
(23) The embodiments shown in
(24) It will be noted in all six of the embodiments shown in
(25) The embodiment of
(26) In the embodiment of
(27) The embodiment of
(28) Mandrels Drive Members
(29)
(30)
(31) In the embodiment of
(32) The embodiments shown in
(33) Skip-Feed Mechanism
(34) As mentioned, an ITM suitable for transferring ink images to the outer surfaces of generally cylindrical objects according to the present teachings can be formed of one or more elongated blanket strips. The ends of the strip can be attached to one another by soldering, gluing, taping (e.g., using silicone adhesive strips, Kapton® tape, RTV liquid adhesives or PTFE thermoplastic adhesives with a connective strip overlapping both edges of the strip), or any other method commonly known. Any method of joining the ends of the blanket strip to form a transfer belt may cause a discontinuity, referred to herein as a seam.
(35) The seam can be of different types. In particular, the edges may overlap one another or a patch may be applied to overlie the two ends. In either case, the seam may be subsequently processed, such as by grinding, to reduce its thickness to obtain an ITM having substantially the same thickness along the entire loop. Still the presence of one or more seams in an ITM may affect the print quality of an ink image which may span them. Therefore, in some embodiments, the printing process can be adapted to avoid applying an ink image in an area of the ITM including a seam. The feeding of the objects being printed upon needs to be accordingly discontinued, so that objects are transported through the impression station only synchronously with actual presence of ink images on the image bearing surface. An exemplary method (and device) to achieve this effect, referred to herein as “skip-feed”, will now be described by reference to
(36)
(37) Each mandrel 816, 818 is fitted to the shaft 814 so that it can be pulled on and off simply and yet retained securely when in position. Retention of each mandrel is achieved by the magnet 1216 and/or by a spring-biased detent 1220 located in the shaft 814 adjacent the bearing 1218a proximal to the drive member. Such mounting allows the mandrels 816, 818 to be easily and quickly replaced by smaller ones when printing on smaller objects and enables individual mandrels to be removed when they synchronize with a no-print region of the ITM.
(38) While a magnet has been proposed in the above with reference to
(39) The way in which objects are loaded onto, and unloaded from, the mandrels will now be explained by reference to
(40) As the cradles 1416, 1418 pass under their respective stacks 1430, 1432, objects drop, one at a time, into each cradle aligned with a mandrel. Whether or not an object 106 is allowed to drop out of a stack is determined by an interposer 1510 shown in
(41) The interposer can 1510 be constructed in a variety of ways. In its simplest form, it may operate purely mechanically and take the form of a pivotable shaft having at one end a finger obstructing the descent of objects 106 from a stack and at the other end a sensing lever that rides on the mandrels. If a mandrel is present, then the sensing lever rotates the shaft to displace the finger lying in the path of the falling objects, whereas when no mandrel is present, the finger at the opposite end of the shaft prevents loading of an object onto the associated cradle.
(42) In an alternative embodiment, the interposer may operate electrically and take the form of a solenoid operating a gate at the bottom of each stack. The solenoid may receive signals to close the gate upon detection of the absence of a mandrel by an associated electrical sensor. Alternatively, a pre-programmed digital processor which controls the application of ink images to the ITM may send signals to the interposer 1510 to prevent loading of object at positions that synchronize with no-print regions of the ITM.
(43) The transfer of objects from the cradles 1416, 1418, to the mandrels 816, 818 can be performed mechanically, most simply by a stationary ramp acting on the closed end of the objects 106. However, in some embodiments shown in
(44) To unload the objects from the mandrels, as depicted in
(45) A Printing Apparatus
(46) Referring now to
(47) The objects on which printing is to take place are supplied in the illustrated embodiment from two pairs of stacks, 1830 and 1832, to two loading stations designated 1834a and 1834b, each of which is as previously described by reference to
(48) After an ink image has been impressed on the objects, they may optionally pass again through a pre-treatment station 1842, where the objects may be subjected to a flame, a corona or plasma to prepare them for a varnish coating that can be applied at a varnishing station 1844. After the varnish, if applied, has been dried or otherwise cured such as, for example, by UV exposure or e-beam radiation in drying/curing station 1846, the paths of the two drive members carrying the mandrels once again diverge to take each drive member through a respective one of two unloading stations 1848a and 1848b at which the objects are sent on to further processing stations of the production line. In a production line for beverage cans, the objects may, for example, be internally coated or subsequently have their shape modified, and they may be filled with a beverage before a cap is secured to them to seal their contents.
(49) Drying station 1840 and 1846 may also serve as heating stations for the mandrels and the objects to ensure that the surfaces of the objects enter the impression station at an elevated temperature which, in some embodiments, may be desirable to help ensure complete image transfer. Such pre-heating of the mandrels may also be accomplished by the addition of heaters or heating ovens at any location in the mandrel path, as, in some embodiments, the heat capacity of the mandrels enables them to heat the objects and maintain their elevated temperature even when not continuously exposed to external heat sources. Though any temperature above room temperature may be desirable, preferred mandrel temperatures may be between 30° C. and 100° C.
(50) It will be seen that in
(51) As has previously been explained, the speed of the ITM 1812 needs to be twice that of drive members of the mandrels. However, minor adjustments may be made to the speed of the ITM 1812 or of the drive members to ensure correct synchronization with the objects. Such adjustments to the synchronization are necessary as each of the ITM 1812 and the drive members has a degree of elasticity which requires slight periodic compensation to ensure that the ink images and the objects meet one another in register at the impression station when transfer is effected.
(52) Furthermore, as has previously been mentioned, it is necessary for the length of the ITM 1812 to be a whole number multiple of the pitch between the objects. Since the ITM 1812 is somewhat elastic, tensioning of the ITM 1812 can be used to make minor adjustments to its length. It is for this reason that the ITM 1812 in
(53) While the above-described skip-feeding mechanism for three-dimensional objects has been described in the context of a printing system according to the present teachings, wherein ink images are indirectly applied to the outer surface of generally cylindrical objects, this should not be construed as limiting. Moreover, while the presence of a seam on the ITM could be one reason to desire punctually discontinuing the mounting of objects on mandrels, other motives may exist, for instance, avoiding different types of defects on the ITM or on the objects to be printed upon.
(54) Though not shown in
(55) A skilled person will readily appreciate that the same principles of skip-feeding can be implemented in other printing systems, wherein the objects may have different shapes and/or wherein the ink image may be directly applied (e.g., by ink-jetting suitable ink compositions towards the object outer surface) instead of by contacting an ITM.
Description of Alternative Embodiments
(56) In all the embodiments described above, the objects are directly urged against the ITM at the nip by means of a stationary impression platen in contact with the objects on their opposite side to that in contact with the ITM. However, it is possible to avoid the impression platen coming into contact with the printing surface, if it is instead used to apply a force, via the transport mechanism, to the mandrels. Such embodiment is shown in
(57)
(58) Additional Printing Stations
(59) It is understood that in addition to the transport mechanism and the impression station wherein ink images are impressed on the surface of the object using an impression platen as above-mentioned, a printing apparatus as herein disclosed may further comprise inter alia a conditioning station and/or a cleaning station to respectively treat (e.g., by physical or chemical means) and/or clean the intermediate transfer member (such as illustrated by 36 in
(60) The printing system may additionally, or alternatively, comprise stations wherein the object is processed. By way of non-limiting examples, the printing system may include a forming station where the object can be formed into a generally cylindrical object optionally including a lid at one end, a shaping station where surfaces of the object can be embossed or otherwise modified to include a functional or decorative pattern; a washing station where the object can be degreased or etched (e.g., ahead of printing), a drying station where a wet object can be dried (ahead of and/or following printing), a priming station where a priming composition or treatment (e.g., corona) can be applied to the outer surface of the object prior to printing (e.g., to further the adherence of the ink image to the object), a heating station or a cooling station to modify the object temperature along its path, a curing station (e.g., to cure an ink image transferred to the object), a coating station (e.g., to coat the transferred ink image with a protective or decorative varnish and/or to coat the interior of the object with a lining) and any other finishing station for further processing the printed objects. Any such station located upstream of the impression region can be termed a pre-processing station and any such station located downstream of the impression region can be termed a post-processing station. Such stations are schematically illustrated in
(61) If desired the printing systems of the present disclosure can be connected in-line with a downstream filling system, wherein the printed objects can be filled with their intended content and lids thereafter attached (e.g., seamed by welding) to the filled bodies to seal the contents. All such stations known in the fields of printing and packaging need not be considered in detail in the present context.
(62) Supplementary Information
(63) The interested reader is referred to the following literature for non-limiting examples further illustrating how to implement the present invention and its various embodiments.
(64) U.S. Pat. No. 5,893,016 describes an apparatus for printing images on generally cylindrical objects such as cans, including an image bearing surface having an image thereon and having an impression guide which is generally parallel to and spaced from the image bearing surface, which guide supports the cylindrical objects in rolling contact with the image bearing surface, whereby images are transferred from the image bearing surface to surfaces of the cylindrical objects in contact therewith. In U.S. Pat. No. 5,893,016, the objects are not supported on mandrels and the apparatus is not therefore well suited to printing on cans before they are filled and sealed. Furthermore, the articles are not advanced by a drive member through the printing station, relying instead first on gravity then on friction with the image bearing surface, and there is nothing to prevent the articles from skewing, prior to or during their passage through the printing station.
(65) Printing sub-systems suitable for the apparatuses according to the present teachings are known to the skilled person and need not be detailed herein. Exemplary sub-systems which may be used, in some embodiments, are further detailed in WO 2017/208145 and WO 2017/208146, wherein, as opposed to the present invention, the objects are mounted on mandrels attached to a rigid support, the ink images being transferred in absence of an impression platen.
(66) Consumables suitable for printing methods and apparatuses according to the present teachings include, in addition to the generally cylindrical objects being printed on, at least one of a) ink compositions, b) intermediate transfer members (e.g., continuous belts with or without a seam), and optionally c) conditioning liquids (e.g., for pre-treating the transfer members ahead of ink application), d) cleaning or washing liquids (e.g., for removing ink residuals from transfer members or degreasing the objects), e) priming liquids (e.g., for pre-coating the objects prior to printing), f) coating liquids (e.g., for applying an overcoat covering the ink image on the printed object), g) lining liquids (e.g., for applying a coat to the interior of the object); and h) like compositions readily appreciated by a person skilled in the art of printing.
(67) Such consumables are selected and adapted to any desired particular configuration and operation of the printing method and apparatus. Moreover, the consumables are compatible with one another. For instance, if, during the printing process, the image bearing surface of the ITM is to be exposed to elevated temperature, it should be heat resistant at least to the applied temperature; if the transfer member is a tensioned belt, it should have mechanical resistance at least to the applied tension; if the transfer member is displaced, it should include, on the side opposite the surface upon which ink is deposited, a layer providing suitable friction or lack thereof with underneath guiding systems; and any such consideration readily appreciated by a person skilled in printing allowing use of the consumable under the operating conditions.
(68) Similarly, from a chemical standpoint, the ink compositions need first to be compatible with the intermediate transfer member and/or with a conditioning liquid (if present). They also need to be adapted to the surface of the object the inks are printed on, and/or to be compatible with a priming compound and/or with a coating compound (if any pre- or post-applied to the object). Fundamentally, a material or a chemical composition is compatible with another if it does not prevent its activity or does not reduce it to an extent that would significantly affect the intended purpose. For instance, the ink compositions would not be compatible if, among other things, they swell the imaging surface of the ITM or otherwise distort its characteristics; if they are unable to at least partially transfer from the image bearing outer surface and/or attach to the surface of the object, whether or not pre-coated; if they are unable to attach an overcoat; if they resist cleaning of the printing system and have any like undesired effect. As readily understood, this principle of chemical compatibility of any consumable used herein with any other consumable should preferably guide the selection of all materials necessary for the compositions to be used in a printing system as disclosed herein.
(69) Consumables suitable for printing methods and apparatuses according to the present teachings are known to the skilled person and need not be detailed herein. Exemplary consumables which may be used, in some embodiments, are further detailed in WO 2013/132418 and WO 2017/208152.
(70) Ink compositions suitable for printing methods and apparatuses according to the present teachings are known to the skilled person and need not be detailed herein. Exemplary ink compositions which may be used, in some embodiments, are further detailed in WO 2013/132339, WO 2015/036812 and WO 2015/036865.
(71) Intermediate transfer members suitable for printing methods and apparatuses according to the present teachings are known to the skilled person and need not be detailed herein. Exemplary transfer members which may be used or prepared, in some embodiments, are further detailed in WO 2013/132432, WO 2013/132438, WO 2017/208144 and WO 2017/208155.
(72) Conditioning liquids suitable for printing methods and apparatuses according to the present teachings are known to the skilled person and need not be detailed herein. Exemplary conditioning liquids which may be used, in some embodiments, are further detailed in WO 2013/132339, WO 2015/036864, WO 2015/036960 and WO 2017/208246.
(73) It is appreciated that certain features of the disclosure, which are, for clarity, described in the context of separate embodiments, may also be provided in combination in a single embodiment. Conversely, various features of the disclosure, which are, for brevity, described in the context of a single embodiment, may also be provided separately or in any suitable sub-combination or as suitable in any other described embodiment of the disclosure. Certain features described in the context of various embodiments are not to be considered essential features of those embodiments, unless the embodiment is inoperative without those elements.
(74) Although the present disclosure has been described with respect to various specific embodiments presented herein for the sake of illustration only, such specifically disclosed embodiments should not be considered limiting. Many other alternatives, modifications and variations of such embodiments will occur to those skilled in the art based upon Applicant's disclosure herein. Accordingly, it is intended to embrace all such alternatives, modifications and variations and to be bound only by the spirit and scope of the disclosure and any change which come within their meaning and range of equivalency.
(75) The word “exemplary” is used herein to mean “serving as an example, instance or illustration”. Any example, embodiment, case, instance, or figure/illustration of certain feature(s) described as “exemplary” is not necessarily to be construed as preferred or advantageous over other embodiments and/or to exclude the incorporation of one or more features from other embodiments. Furthermore, a feature which is described as preferred or advantageous in some embodiments, may not necessarily be preferred or advantageous in other embodiments.
(76) As used herein, in the description and claims of the present disclosure, each of the verbs “comprise”, “include” and “have”, and conjugates thereof, are used to indicate that the object or objects of the verb are not necessarily a complete listing of features, members, steps, components, elements or parts of the subject or subjects of the verb.
(77) As used herein, the singular form “a”, “an” and “the” include plural references and mean “at least one” or “one or more” unless the context clearly dictates otherwise. At least one of A and B is intended to mean either A or B, and may mean, in some embodiments, A and B.
(78) Unless otherwise stated, the use of the expression “and/or” between the last two members of a list of options for selection indicates that a selection of one or more of the listed options is appropriate and may be made.
(79) As used herein, unless otherwise stated, adjectives such as “substantially” and “about” that modify a condition or relationship characteristic of a feature or features of an embodiment of the present technology, are to be understood to mean that the condition or characteristic is defined to within tolerances that are acceptable for operation of the embodiment for an application for which it is intended, or within variations expected from the measurement being performed and/or from the measuring instrument being used. When the term “about” precedes a numerical value, it is intended to indicate +/−15%, or +/−10%, or even only +/−5%, and in some instances the precise value. Furthermore, unless otherwise stated, the terms (e.g., numbers) used in an embodiment of the presently disclosed subject matter, even without such adjectives, should be construed as having tolerances which may depart from the precise meaning of the relevant term but would enable the embodiment or a relevant portion thereof to operate and function as described, and/or as understood by a person skilled in the art.
(80) Positional or motional terms such as “upper”, “lower”, “right”, “left”, “bottom”, “below”, “lowered”, “low”, “top”, “above”, “elevated”, “high”, “vertical”, “horizontal”, “backward”, “forward”, “upstream” and “downstream”, as well as grammatical variations thereof, may be used herein for exemplary purposes only, to illustrate the relative positioning, placement or displacement of certain components, to indicate a first and a second component in present illustrations or to do both. Such terms do not necessarily indicate that, for example, a “bottom” component is below a “top” component, as such directions, components or both may be flipped, rotated, moved in space, placed in a diagonal orientation or position, placed horizontally or vertically, or similarly modified.
(81) To the extent necessary to understand or complete the disclosure of the present invention, all publications, patents, and patent applications mentioned herein, including in particular the applications of the Applicant or the Inventor, are expressly incorporated by reference in their entirety for all purposes as is fully set forth herein. Citation or identification of any reference in this application shall not be construed as an admission that such reference is available as prior art to the disclosure.
(82) Certain marks referenced herein may be common law or registered trademarks of third parties. Use of these marks is by way of example and shall not be construed as descriptive or limit the scope of this disclosure to material associated only with such marks.