Hydrocarbon gas processing
11543180 · 2023-01-03
Assignee
Inventors
- Kyle T. Cuellar (Katy, TX)
- Michael C. Pierce (Erie, CO)
- Scott A. Miller (Midland, TX)
- John D. Wilkinson (Midland, TX)
- Joe T. Lynch (Midland, TX)
- Hank M. Hudson (Midland, TX)
- Andrew F. Johnke (Beresford, SD)
- W. Larry Lewis (Tomball, TX)
Cpc classification
F25J2210/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2235/60
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2270/88
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0238
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2205/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2205/50
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2240/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0242
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0233
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/76
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2245/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2280/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2290/40
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0209
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2215/62
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2215/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J3/0295
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2230/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2240/40
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/74
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2200/80
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2270/08
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F25J2235/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A process and an apparatus are disclosed for a compact processing assembly to improve the recovery of C.sub.2 (or C.sub.3) and heavier hydrocarbon components from a hydrocarbon gas stream. The preferred method of separating a hydrocarbon gas stream generally includes producing at least a substantially condensed first stream and a cooled second stream, expanding both streams to lower pressure, and supplying the streams to a fractionation tower. In the process and apparatus disclosed, the tower overhead vapor is directed to an absorbing means and a heat and mass transfer means inside a processing assembly. A portion of the outlet vapor from the processing assembly is compressed to higher pressure, cooled and substantially condensed in a heat exchange means inside the processing assembly, then expanded to lower pressure and supplied to the heat and mass transfer means to provide cooling. Condensed liquid from the absorbing means is fed to the tower.
Claims
1. An apparatus for the separation of a gas stream, containing methane, C.sub.2 components, C.sub.3 components, and heavier hydrocarbon component into a volatile residue gas fraction and a relatively less volatile fraction containing a major portion of said C.sub.2 components, C.sub.3 components, and heavier hydrocarbon components or said C.sub.3 components and heavier hydrocarbon components, said apparatus comprising (a) a first cooling device to cool said gas stream under pressure to produce a cooled gas stream; (b) a first divider connected to said first cooling device to receive and divide said cooled gas stream into a cooled first stream and a cooled second stream; (c) a second cooling device connected to said first divider to receive and further cool said cooled first stream under pressure to produce an at least partially condensed first stream; (d) a first expansion device connected to said second cooling device to receive said at least partially condensed first stream under pressure and expand said at least partially condensed first stream to a lower pressure, whereby said at least partially condensed first stream is further cooled, thereby forming an expanded further cooled first stream; (e) a distillation column connected to said first expansion device to receive said expanded further cooled first stream at a top feed position, with said distillation column producing at least an overhead vapor stream and a bottom liquid stream; (f) a second expansion device connected to said first divider to receive said cooled second stream under pressure and expand said cooled second stream to said lower pressure, thereby forming an expanded second stream; (g) said distillation column further connected to said second expansion device to receive said expanded second stream at a mid-column feed position; and (h) said distillation column adapted to fractionate at least said expanded farther cooled first stream and said expanded second stream at said lower pressure whereby the components of said relatively less volatile fraction are recovered in said bottom liquid stream and said volatile residue gas fraction is discharged as said overhead vapor stream; wherein said apparatus further includes (1) an absorbing section comprising one or more of packed beds and trays, wherein said absorbing section is housed in a single equipment item processing assembly and connected to said distillation column to receive said overhead vapor stream and contact said overhead vapor stream with a condensed stream, thereby condensing the less volatile components in said overhead vapor stream and forming a partially rectified vapor stream; (2) a rectifying section providing simultaneous heat transfer and mass transfer selected from one or more of a fin and tube type exchanger, a plate type exchanger, a brazed aluminum type exchanger, and other type of heat transfer device, with said rectifying section housed in said single equipment item processing assembly and connected to said absorbing means to receive said partially rectified vapor stream from an upper region of said absorbing section, whereby said partially rectified vapor stream is cooled while simultaneously condensing the less volatile components in said partially rectified vapor stream, thereby forming a further rectified vapor stream and said condensed stream, said recti ring section being further connected to said absorbing section to direct said condensed stream to said absorbing section; (3) a first combiner connected to said rectifying section to receive said further rectified vapor stream and a heated flash expanded stream and form a combined stream; (4) a heat exchanger selected from one or more of a fin and tube type exchanger, a plate type exchanger, a brazed aluminum type exchanger, and other type of heat transfer device connected to said first combiner to receive and heat said combined stream, thereby forming a heated combined stream; (5) a second divider connected to said heat exchanger to receive and divide said heated combined stream into a recycle stream and said volatile residue gas fraction; (6) a compressor connected to said second divider to receive and compress said recycle stream to higher pressure, thereby forming a compressed stream; (7) said heat exchanger further connected to said compressor to receive and cool said compressed stream to substantial condensation, thereby to supply at least a portion of the heating of step (4) and forming a substantially condensed stream; (8) a third expansion device connected to said heat exchanger to receive and expand said substantially condensed stream to said lower pressure, thereby forming, a flash expanded stream; (9) said rectifying section further connected to said third expansion device to receive and heat said flash expanded stream, thereby to supply the cooling of step (2) and forming said heated flash expanded stream; (10) said heat exchanger further connected to said second cooling device to receive and further cool said at least partially condensed first stream under pressure, thereby to supply at least a portion of the heating of step (4) and forming a further cooled substantially condensed first stream; (11) said first expansion device being adapted to connect it to said heat exchanger to receive and expand said further cooled substantially condensed first stream to said lower pressure, thereby forming said expanded further cooled first stream; (12) a second combiner connected to said absorbing section and to said first expansion device to receive a distillation liquid stream from a lower region of said absorbing section and said expanded further cooled first stream and form a combined feed stream, said second combiner being further connected to said distillation column to supply said combined feed stream at said top feed position of said distillation column; (13) said distillation column being adapted to fractionate at least said combined feed stream and said expanded second stream at said lower pressure whereby the components of said relatively less volatile fraction are recovered in said bottom liquid stream.
2. The apparatus according to claim 1 wherein (1) said first cooling device is adapted to cool and partially condense said gas stream under pressure, thereby forming a partially condensed gas stream; (2) a separator is connected to said first cooling device to receive and separate said partially condensed gas stream into a vapor stream and at least one liquid stream; (3) said first divider is adapted to be connected to said separator to receive and divide said vapor stream into at least said cooled first stream and said cooled second stream; (4) a fourth expansion means is, connected to said separator to receive and expand at least a portion of said at least one liquid stream, to said lower pressure, thereby forming an expanded liquid stream, said fourth expansion means being further connected to said distillation column to supply said expanded liquid stream to said distillation column at a lower mid-column feed position below said mid-column feed position; and (5) said distillation column is adapted to fractionate at least said combined feed stream. said expanded second stream, and said expanded liquid stream at said lower pressure whereby the components of said relatively less volatile fraction are recovered in said bottom . liquid stream.
3. The apparatus according to claim 1 wherein (1) said first divider is adapted to divide said vapor stream into at least a cooled vapor stream and said second cooled stream; (2) a third combiner is connected to said first divider and to said separator to receive said cooled vapor stream and at least a portion of said at least one liquid stream and form said cooled first stream; (3) said first heat exchanger is adapted to be connected to said third combiner to receive said cooled first stream: and (4) said fourth expansion means is adapted to receive and expand any remaining portion of said at least one liquid stream to said lower pressure and form said expanded liquid stream.
Description
(1) For a better understanding of the present invention, reference is made to the following examples and drawings. Referring to the drawings:
(2)
(3)
(4)
(5)
(6) In the following explanation of the above figures, tables are provided summarizing flow rates calculated for representative process conditions. In the tables appearing herein, the values for flow rates (in moles per hour) have been rounded to the nearest whole number for convenience. The total stream rates shown in the tables include all non-hydrocarbon components and hence are generally larger than the sum of the stream flow rates for the hydrocarbon components. Temperatures indicated are approximate values rounded to the nearest degree. It should also be noted that the process design calculations performed for the purpose of comparing the processes depicted in the figures are based on the assumption of no heat leak from (or to) the surroundings to (or from) the process. The quality of commercially available insulating materials makes this a very reasonable assumption and one that is typically made by those skilled in the art.
(7) For convenience, process parameters are reported in both the traditional British units and in the units of the Système International d'Unités (SI). The molar flow rates given in the tables may be interpreted as either pound moles per hour or kilogram moles per hour. The energy consumptions reported as horsepower (HP) and/or thousand British Thermal Units per hour (MBTU/Hr) correspond to the stated molar flow rates in pound moles per hour. The energy consumptions reported as kilowatts (kW) correspond to the stated molar flow rates in kilogram moles per hour.
DESCRIPTION OF THE PRIOR ART
(8)
(9) The feed stream 31 is cooled in heat exchanger 10 by heat exchange with cool residue gas (stream 39a), pumped liquid product at 20° F. [−7° C.] (stream 42a), demethanizer reboiler liquids at 0° F. [−18° C.] (stream 41), demethanizer side reboiler liquids at −45° F. [−43° C.] (stream 40), and propane refrigerant. Stream 31a then enters separator 11 at −29° F. [−34° C.] and 795 psia [5,479 kPa(a)] where the vapor (stream 32) is separated from the condensed liquid (stream 33).
(10) The vapor (stream 32) from separator 11 is divided into two streams, 34 and 37. The liquid (stream 33) from separator 11 is optionally divided into two streams, 35 and 38. (Stream 35 may contain from 0% to 100% of the separator liquid in stream 33. If stream 35 contains any portion of the separator liquid, then the process of
(11) The remaining 70% of the vapor from separator 11 (stream 37) enters a work expansion machine 14 in which mechanical energy is extracted from this portion of the high pressure feed. The machine 14 expands the vapor substantially isentropically to the tower operating pressure, with the work expansion cooling the expanded stream 37a to a temperature of approximately −126° F. [−88° C.]. The typical commercially available expanders are capable of recovering on the order of 80-85% of the work theoretically available in an ideal isentropic expansion. The work recovered is often used to drive a centrifugal compressor (such as item 15) that can be used to re-compress the residue gas (stream 39b), for example. The partially condensed expanded stream 37a is thereafter supplied as feed to fractionation tower 17 at an upper mid-column feed point. The remaining separator liquid in stream 38 (if any) is expanded to the operating pressure of fractionation tower 17 by expansion valve 16, cooling stream 38a to −85° F. [−65° C.] before it is supplied to fractionation tower 17 at a lower mid-column feed point.
(12) The demethanizer in tower 17 is a conventional distillation column containing a plurality of vertically spaced trays, one or more packed beds, or some combination of trays and packing. As is often the case in natural gas processing plants, the fractionation tower may consist of two sections. The upper section 17a is a separator wherein the partially vaporized top feed is divided into its respective vapor and liquid portions, and wherein the vapor rising from the lower distillation or demethanizing section 17b is combined with the vapor portion of the top feed to form the cold demethanizer overhead vapor (stream 39) which exits the top of the tower. The lower, demethanizing section 17b contains the trays and/or packing and provides the necessary contact between the liquids falling downward and the vapors rising upward. The demethanizing section 17b also includes reboilers (such as the reboiler and the side reboiler described previously and supplemental reboiler 18) which heat and vaporize a portion of the liquids flowing down the column to provide the stripping vapors which flow up the column to strip the liquid product, stream 42, of methane and lighter components.
(13) The liquid product stream 42 exits the bottom of the tower at 7° F. [−14° C.], based on a typical specification of a methane concentration of 0.5% on a volume basis in the bottom product. It is pumped to higher pressure by pump 21 (stream 42a) and then heated to 95° F. [35° C.] (stream 42b) as it provides cooling of the feed gas in heat exchanger 10 as described earlier. The residue gas (demethanizer overhead vapor stream 39) passes countercurrently to the incoming feed gas in heat exchanger 12 where it is heated from −176° F. [−115° C.] to −47° F. [−44° C.] (stream 39a) and in heat exchanger 10 where it is heated to 113° F. [45° C.] (stream 39b). The residue gas is then re-compressed in two stages. The first stage is compressor 15 driven by expansion machine 14. The second stage is compressor 19 driven by a supplemental power source which compresses the residue gas (stream 39d) to sales line pressure. After cooling to 120° F. [49° C.] in discharge cooler 20, the residue gas product (stream 39e) flows to the sales gas pipeline at 765 psia [5,272 kPa(a)], sufficient to meet line requirements (usually on the order of the inlet pressure).
(14) A summary of stream flow rates and energy consumption for the process illustrated in
(15) TABLE-US-00001 TABLE I (FIG. 1) Stream Flow Summary - Lb. Moles/Hr [kg moles/Hr] Stream Methane Ethane Propane Butanes+ Total 31 17,272 2,734 1,070 657 21,961 32 15,282 1,678 360 76 17,613 33 1,990 1,056 710 581 4,348 34 4,541 499 107 23 5,233 35 298 158 107 87 652 36 4,839 657 214 110 5,885 37 10,741 1,179 253 53 12,380 38 1,692 898 603 494 3,696 39 17,236 90 2 0 17,556 42 36 2,644 1,068 657 4,405 Recoveries* Ethane 96.69% Propane 99.84% Butanes+ 99.99% Power Residue Gas Compression 15,204 HP [24,995 kW] Refrigerant Compression 3,548 HP [5,833 kW] Total Compression 18,752 HP [30,828 kW] *(Based on un-rounded flow rates)
(16)
(17) In this simulation of the process, inlet gas enters the plant at 120° F. [49° C.] and 815 psia [5,617 kPa(a)] as stream 31 and is cooled in heat exchanger 10 by heat exchange with cool residue gas stream 39a and flashed separator liquids (stream 38a). (One consequence of operating the
(18) The vapor (stream 32) from separator 11 is divided into two streams, 34 and 37, and the liquid (stream 33) is optionally divided into two streams, 35 and 38. For the process illustrated in
(19) The remaining 67% of the vapor from separator 11 (stream 37) enters a work expansion machine 14 in which mechanical energy is extracted from this portion of the high pressure feed. The machine 14 expands the vapor substantially isentropically to the tower operating pressure, with the work expansion cooling the expanded stream 37a to a temperature of approximately −103° F. [−75° C.] before it is supplied as feed to fractionation tower 17 at an upper mid-column feed point. The remaining separator liquid in stream 38 (if any) is expanded to slightly above the operating pressure of fractionation tower 17 by expansion valve 16, cooling stream 38a to −61° F. [−51° C.] before it is heated to 103° F. [39° C.] in heat exchanger 10 as described previously, with heated stream 40a then supplied to fractionation tower 17 at a lower mid-column feed point.
(20) Note that when fractionation tower 17 is operated to reject the C.sub.2 components to the residue gas product as shown in
(21) A summary of stream flow rates and energy consumption for the process illustrated in
(22) TABLE-US-00002 TABLE II (FIG. 2) Stream Flow Summary - Lb. Moles/Hr [kg moles/Hr] Stream Methane Ethane Propane Butanes+ Total 31 17,272 2,734 1,070 657 21,961 32 16,003 1,991 498 120 18,835 33 1,269 743 572 537 3,126 34 5,225 650 163 39 6,149 35 457 268 206 193 1,125 36 5,682 918 369 232 7,274 37 10,778 1,341 335 81 12,686 38/40 812 475 366 344 2,001 39 17,272 2,715 116 8 20,338 42 0 19 954 649 1,623 Recoveries* Propane 89.20% Butanes+ 98.81% Power Residue Gas Compression 15,115 HP [24,849 kW] Refrigerant Compression 3,625 HP [5,959 kW] Total Compression 18,740 HP [30,808 kW] *(Based on un-rounded flow rates)
DESCRIPTION OF CO-PENDING APPLICATION
(23) Co-pending application Ser. No. 15/332,723 describes one means of improving the performance of the
(24) Most of the process conditions shown for the
(25) Substantially condensed stream 151b at −171° F. [−113° C.] is then flash expanded through expansion valve 23 to slightly above the operating pressure of fractionation tower 17. During expansion a portion of the stream may be vaporized, resulting in cooling of the total stream. In the process illustrated in
(26) The flash expanded stream 151c is further vaporized as it provides cooling and partial condensation of the partially rectified vapor stream, and exits the heat and mass transfer means in rectifying section 117b at −178° F. [−117° C.]. The heated flash expanded stream discharges into separator section 117d of processing assembly 117 and is separated into its respective vapor and liquid phases. The vapor phase combines with the remaining portion (stream 152) of overhead vapor stream 39 to form a combined vapor stream that enters a mass transfer means in absorbing section 117c of processing assembly 117. The mass transfer means may consist of a plurality of vertically spaced trays, one or more packed beds, or some combination of trays and packing, but could also be comprised of a non-heat transfer zone in a fin and tube type heat exchanger, a plate type heat exchanger, a brazed aluminum type heat exchanger, or other type of heat transfer device, including multi-pass and/or multi-service heat exchangers. The mass transfer means is configured to provide contact between the cold condensed liquid leaving the bottom of the heat and mass transfer means in rectifying section 117b and the combined vapor stream arising from separator section 117d. As the combined vapor stream rises upward through absorbing section 117c, it is contacted with the cold liquid falling downward to condense and absorb C.sub.2 components, C.sub.3 components, and heavier components from the combined vapor stream. The resulting partially rectified vapor stream is then directed to the heat and mass transfer means in rectifying section 117b of processing assembly 117 for further rectification as described previously.
(27) The liquid phase (if any) from the heated flash expanded stream leaving rectifying section 117b of processing assembly 117 that is separated in separator section 117d combines with the distillation liquid leaving the bottom of the mass transfer means in absorbing section 117c of processing assembly 117 to form combined liquid stream 154. Combined liquid stream 154 leaves the bottom of processing assembly 117 and is pumped to higher pressure by pump 24 (stream 154a at −170° F. [−112° C.]). Further cooled stream 36b at −169° F. [−112° C.] is flash expanded through expansion valve 13 to the operating pressure of fractionation tower 17. During expansion a portion of the stream may be vaporized, resulting in cooling of the total stream to −177° F. [−116° C.]. Flash expanded stream 36c then joins with pumped stream 154a to form combined feed stream 155, which then enters fractionation column 17 at the top feed point at −176° F. [−116° C.].
(28) The further rectified vapor stream leaves the heat and mass transfer means in rectifying section 117b of processing assembly 117 at −182° F. [−119° C.] and enters the heat exchange means in cooling section 117a of processing assembly 117. The vapor is heated to −96° F. [−71° C.] as it provides cooling to streams 36a and 151a as described previously. The heated vapor is then discharged from processing assembly 117 as cool residue gas stream 153, which is heated and compressed as described previously for stream 39 in the
(29) A summary of stream flow rates and energy consumption for the process illustrated in
(30) TABLE-US-00003 TABLE III (FIG. 3) Stream Flow Summary - Lb. Moles/Hr [kg moles/Hr] Stream Methane Ethane Propane Butanes+ Total 31 17,272 2,734 1,070 657 21,961 32 15,276 1,676 359 76 17,604 33 1,996 1,058 711 581 4,357 34 3,247 356 76 16 3,742 35 499 264 178 145 1,089 36 3,746 620 254 161 4,831 37 12,029 1,320 283 60 13,862 38 1,497 794 533 436 3,268 39 17,608 179 3 0 18,020 151 1,610 16 0 0 1,647 152 15,998 163 3 0 16,373 154 373 144 3 0 521 155 4,119 764 254 161 5,352 153 17,235 35 0 0 17,499 42 37 2,699 1,070 657 4,462 Recoveries* Ethane 98.70% Propane 100.00% Butanes+ 100.00% Power Residue Gas Compression 14,660 HP [24,101 kW] Refrigerant Compression 3,733 HP [6,137 kW] Reflux Compression 354 HP [582 kW] Total Compression 18,747 HP [30,820 kW] *(Based on un-rounded flow rates)
(31) A comparison of Tables I and III shows that, compared to the
(32) The process of co-pending application Ser. No. 15/332,723 can also be operated to reject nearly all of the C.sub.2 components to the residue gas rather than recovering them in the liquid product. The operating conditions of the
(33) Most of the process conditions shown for the
(34) The flash expanded stream 36b is further vaporized as it provides cooling and partial condensation of the combined vapor stream, and exits the heat and mass transfer means in rectifying section 117b at −83° F. [−64° C.]. The heated flash expanded stream discharges into separator section 117d of processing assembly 117 and is separated into its respective vapor and liquid phases. The vapor phase combines with overhead vapor stream 39 to form the combined vapor stream that enters the mass transfer means in absorbing section 117c as described previously, and the liquid phase combines with the condensed liquid from the bottom of the mass transfer means in absorbing section 117c to form combined liquid stream 154. Combined liquid stream 154 leaves the bottom of processing assembly 117 and is pumped to higher pressure by pump 24 so that stream 154a at −73° F. [−58° C.] can enter fractionation column 17 at the top feed point. The further rectified vapor stream leaves the heat and mass transfer means in rectifying section 117b and discharges from processing assembly 117 at −104° F. [−76° C.] as cold residue gas stream 153, which is then heated and compressed as described previously for stream 39 in the
(35) A summary of stream flow rates and energy consumption for the process illustrated in
(36) TABLE-US-00004 TABLE IV (FIG. 4) Stream Flow Summary - Lb. Moles/Hr [kg moles/Hr] Stream Methane Ethane Propane Butanes+ Total 31 17,272 2,734 1,070 657 21,961 32 15,902 1,943 474 112 18,652 33 1,370 791 596 545 3,309 34 3,263 399 97 23 3,827 35 507 293 221 202 1,224 36 3,770 692 318 225 5,051 37 12,639 1,544 377 89 14,825 38/40 863 498 375 343 2,085 39 13,802 2,765 294 16 17,061 154 300 744 575 241 1,861 153 17,272 2,713 37 0 20,251 42 0 21 1,033 657 1,710 Recoveries* Propane 96.50% Butanes+ 100.00% Power Residue Gas Compression 15,114 HP [24,847 kW] Refrigerant Compression 3,621 HP [5,953 kW] Reflux Compression 0 HP [0 kW] Total Compression 18,735 HP [30,800 kW] *(Based on un-rounded flow rates)
(37) A comparison of Tables II and IV shows that, compared to the
DESCRIPTION OF THE INVENTION
Example 1
(38) In those cases where it is desirable to maximize the recovery of C.sub.2 components in the liquid product (as in the
(39) Most of the process conditions shown for the
(40) Absorbing section 117c inside processing assembly 117 contains a mass transfer means. This mass transfer means may consist of a plurality of vertically spaced trays, one or more packed beds, or some combination of trays and packing, but could also be comprised of a non-heat transfer zone in a fin and tube type heat exchanger, a plate type heat exchanger, a brazed aluminum type heat exchanger, or other type of heat transfer device, including multi-pass and/or multi-service heat exchangers. The mass transfer means is configured to provide contact between cold condensed liquid leaving the bottom of a heat and mass transfer means in rectifying section 117b inside processing assembly 117 and column overhead vapor stream 39 arising from separator section 117d inside processing assembly 117. As the column overhead vapor stream rises upward through absorbing section 117c, it is contacted with the cold liquid falling downward to condense and absorb C.sub.2 components, C.sub.3 components, and heavier components from the vapor stream. The resulting partially rectified vapor stream is then directed to the heat and mass transfer means in rectifying section 117b inside processing assembly 117 for further rectification.
(41) Substantially condensed stream 151e at −178° F. [−117° C.] is flash expanded through expansion valve 23 to slightly above the operating pressure of fractionation tower 17. During expansion a portion of the stream may be vaporized, resulting in cooling of the total stream. In the process illustrated in
(42) The flash expanded stream 151f is further vaporized as it provides cooling and partial condensation of the partially rectified vapor stream, and exits the heat and mass transfer means in rectifying section 117b inside processing assembly 117 at −182° F. [−119° C.]. The heated flash expanded stream then mixes with the further rectified vapor stream to form a combined stream at −181° F. [−119° C.] that is directed to the heat exchange means in cooling section 117a inside processing assembly 117. The combined stream is heated as it provides cooling to streams 151d and 36a as described previously.
(43) The distillation liquid leaving the bottom of the mass transfer means in absorbing section 117c discharges from the bottom of processing assembly 117 (stream 154) and is pumped to higher pressure by pump 24 (stream 154a at −172° F. [−113° C.]). Further cooled substantially condensed stream 36b at −160° F. [−107° C.] is flash expanded through expansion valve 13 to the operating pressure of fractionation tower 17. During expansion a portion of the stream may be vaporized, resulting in cooling of the total stream to −172° F. [−114° C.]. Flash expanded stream 36c then joins with pumped stream 154a to form combined feed stream 155, which enters fractionation column 17 at the top feed point at −172° F. [−114° C.].
(44) The heated combined stream 152 is discharged from the heat exchange means in cooling section 117a inside processing assembly 117 at −80° F. [−62° C.]. It is divided into the previously described stream 151, and into cool residue gas stream 153 which is then heated and compressed as described previously for stream 39 in the
(45) A summary of stream flow rates and energy consumption for the process illustrated in
(46) TABLE-US-00005 TABLE V (FIG. 5) Stream Flow Summary - Lb. Moles/Hr [kg moles/Hr] Stream Methane Ethane Propane Butanes+ Total 31 17,272 2,734 1,070 657 21,961 32 15,233 1,659 353 74 17,537 33 2,039 1,075 717 583 4,424 34 3,961 431 92 19 4,560 35 510 269 179 146 1,106 36 4,471 700 271 165 5,666 37 11,272 1,228 261 55 12,977 38 1,529 806 538 437 3,318 39 17,702 107 3 0 18,041 152 18,860 12 0 0 19,121 151 1,625 1 0 0 1,647 154 467 96 3 0 567 155 4,938 796 273 165 6,233 153 17,235 11 0 0 17,474 42 37 2,723 1,070 657 4,487 Recoveries* Ethane 99.60% Propane 100.00% Butanes+ 100.00% Power Residue Gas Compression 14,093 HP [23,169 kW] Refrigerant Compression 3,916 HP [6,438 kW] Reflux Compression 736 HP [1,210 kW] Total Compression 18,745 HP [30,817 kW] *(Based on un-rounded flow rates)
(47) A comparison of Tables I and V shows that, compared to the prior art of
(48) The improvement in recovery efficiency provided by the present invention over that of the prior art of the
(49) The present invention has the further advantage of using the heat and mass transfer means in rectifying section 117b to simultaneously cool the column overhead vapor stream and condense the heavier hydrocarbon components from it, providing more efficient rectification than using reflux in a conventional distillation column. As a result, more of the C.sub.2 components, C.sub.3 components, and heavier hydrocarbon components can be removed from the column overhead vapor stream using the refrigeration available in flash expanded stream 151f than is possible using conventional mass transfer equipment and conventional heat transfer equipment.
(50) The present invention offers two other advantages over the prior art in addition to the increase in processing efficiency. First, the compact arrangement of processing assembly 117 of the present invention incorporates what would normally be three separate equipment items (the heat exchange means in cooling section 117a, the heat and mass transfer means in rectifying section 117b, and the mass transfer means in absorbing section 117c) into a single equipment item (processing assembly 117 in
(51) One additional advantage of the present invention is how easily it can be incorporated into an existing gas processing plant to effect the superior performance described above. As shown in
(52) The main reason the present invention is more efficient than our co-pending application Ser. No. 15/332,723 depicted in
Example 2
(53) The present invention also offers advantages when product economics favor rejecting the C.sub.2 components to the residue gas product. The present invention can be easily reconfigured to operate in a manner similar to that of our U.S. Pat. Nos. 9,637,428 and 9,927,171 as shown in
(54) When operating the present invention in this manner, many of the process conditions shown for the
(55) For the operating conditions shown in
(56) The flash expanded stream 36b is further vaporized as it provides cooling and partial condensation of the partially rectified vapor stream, and exits the heat and mass transfer means in rectifying section 117b inside processing assembly 117 at −83° F. [−64° C.]. The heated flash expanded stream 36c is then mixed with pumped liquid stream 154a to form combined feed stream 155, which enters fractionation column 17 at the top feed point at −82° F. [−64° C.].
(57) The further rectified vapor stream leaves the heat and mass transfer means in rectifying section 117b inside processing assembly 117 at −104° F. [−76° C.]. Since the heat exchange means in cooling section 117a inside processing assembly 117 has been idled, the vapor simply discharges from processing assembly 117 as cool residue gas stream 153, which is heated and compressed as described previously for stream 39 in the
(58) A summary of stream flow rates and energy consumption for the process illustrated in
(59) TABLE-US-00006 TABLE VI (FIG. 6) Stream Flow Summary - Lb. Moles/Hr [kg moles/Hr] Stream Methane Ethane Propane Butanes+ Total 31 17,272 2,734 1,070 657 21,961 32 15,902 1,943 474 112 18,652 33 1,370 791 596 545 3,309 34 3,263 399 97 23 3,827 35 507 293 221 202 1,224 36 3,770 692 318 225 5,051 37 12,639 1,544 377 89 14,825 38/40 863 498 375 343 2,085 39 13,802 2,765 294 16 17,061 154 300 744 575 241 1,861 155 4,070 1,436 893 466 6,912 153 17,272 2,713 37 0 20,251 42 0 21 1,033 657 1,710 Recoveries* Propane 96.50% Butanes+ 100.00% Power Residue Gas Compression 15,114 HP [24,847 kW] Refrigerant Compression 3,621 HP [5,953 kW] Reflux Compression 0 HP [0 kW] Total Compression 18,735 HP [30,800 kW] *(Based on un-rounded flow rates)
(60) A comparison of Tables II and VI shows that, compared to the prior art, the
Other Embodiments
(61) In the embodiment of the present invention shown in
(62) Some circumstances may favor mounting the liquid pump inside the processing assembly to further reduce the number of equipment items and the plot space requirements. Such embodiments are shown in
(63) Some circumstances may favor locating the processing assembly at a higher elevation than the top feed point on fractionation column 17. In such cases, it may be possible for distillation liquid stream 154 to flow by gravity head and combine with stream 36c so that the resulting combined feed stream 155 then flows to the top feed point on fractionation column 17 as shown in
(64) Some circumstances may favor eliminating cooling section 117a from processing assembly 117, and using a heat exchange means external to the processing assembly for feed cooling, such as heat exchanger 27 shown in
(65) The present invention provides improved recovery of C.sub.2 components, C.sub.3 components, and heavier hydrocarbon components per amount of utility consumption required to operate the process. An improvement in utility consumption required for operating the process may appear in the form of reduced power requirements for compression or re-compression, reduced power requirements for external refrigeration, reduced energy requirements for supplemental heating, or a combination thereof.
(66) While there have been described what are believed to be preferred embodiments of the invention, those skilled in the art will recognize that other and further modifications may be made thereto, e.g. to adapt the invention to various conditions, types of feed, or other requirements without departing from the spirit of the present invention as defined by the following claims.