AVALANCHE PHOTODIODE STRUCTURE
20220416110 · 2022-12-29
Inventors
Cpc classification
H01L31/03046
ELECTRICITY
H01L31/1075
ELECTRICITY
International classification
H01L31/107
ELECTRICITY
H01L31/0304
ELECTRICITY
Abstract
An avalanche photodiode (APD) structure, comprising an absorption layer comprising InGaAs, InGaAlAs, InGaAsP, or an InGaAs/GaAsSb type-II superlattice, an avalanche layer comprising AlGaAsSb, and a transition portion disposed between the absorption layer and the avalanche layer is disclosed. The transition portion comprises a first grading layer of InAlGaAs or InGaAsP and a first field control layer disposed between the first grading layer and the avalanche layer. The first field control layer has a bandgap between the bandgap of the absorption layer and the bandgap of the avalanche layer. In an alternative embodiment, an avalanche photodiode (APD) structure, comprising an absorption layer comprising GaAsSb, an avalanche layer comprising AlGaAsSb, and a transition portion disposed between the absorption layer and the avalanche layer. The transition portion comprises a first grading layer and one or more field control layers having a bandgap between the bandgaps of the absorption layer and the avalanche layer.
Claims
1. An avalanche photodiode (APD) structure, comprising: an absorption layer comprising InGaAs, InGaAlAs, InGaAsP, or an InGaAs/GaAsSb type-II superlattice; an avalanche layer comprising AlGaAsSb; and a transition portion disposed between the absorption layer and the avalanche layer; wherein the transition portion comprises a first grading layer of InAlGaAs or InGaAsP and a first field control layer disposed between the first grading layer and the avalanche layer; and wherein the first field control layer has a bandgap between the bandgap of the absorption layer and the bandgap of the avalanche layer.
2. The APD structure of claim 1, wherein the first field control layer is p-doped.
3. The APD structure of claim 2, wherein the first field control layer is p-doped at a concentration between 1×1017 cm−3 and 1×1018 cm−3, and optionally between 1×1017 cm−3 and 5×1017 cm−3.
4. The APD structure of claim 1, wherein the first field control layer has a thickness between 40 nm and 300 nm
5. The APD structure of claim 1, wherein the first grading layer is graded so as to have an increasing bandgap along the direction from the absorption layer to the avalanche layer.
6. The APD structure of claim 5, wherein the bandgap of the first grading layer increases from that of the absorption layer to that of InAlAs.
7. The APD structure of claim 5, wherein the first grading layer comprises discrete layers of differing bandgaps or a layer having a continuously increasing bandgap.
8. The APD structure of claim 1, comprising a second grading layer of AlGaAsSb disposed between the first field control layer and the avalanche layer.
9. The APD structure of claim 8, wherein the bandgap of the second grading layer increases to that of the avalanche layer.
10. The APD structure of claim 9, wherein the bandgap of the second grading layer increases from that of InAlAs to that of the avalanche layer.
11. The APD structure of any of claim 8, comprising a second field control layer disposed between the second grading layer and the avalanche layer.
12. The APD structure of claim 11, wherein the second field control layer comprises AlGaAsSb.
13. The APD structure of claim 11, wherein the second field control layer is p-doped.
14. The APD structure of claim 1, wherein the avalanche layer comprises AlxGa1−xAsySb1−y where x is between 0.4 and 1, and optionally between 0.85 and 1, and y is chosen to lattice match AlxGa1−xAsySb1−y to InP.
15. The APD structure of claim 1, wherein the absorption layer has a thickness between 500 and 1500 nm, and optionally between 1000 and 1500 nm.
16. The APD structure of claim 1, wherein the avalanche layer has a thickness between 50 and 2000 nm, and optionally between 50 and 1500 nm.
17. The APD structure of claim 1, wherein the first field control layer comprises a material that is lattice-matched to InP.
18. The APD structure of claim 1, wherein the first field control layer comprises InAlAs or InP.
19. The APD structure of claim 1, wherein the first field control layer has a bandgap of 1 eV or greater.
20. An avalanche photodiode (APD) structure, comprising: an absorption layer comprising GaAsSb; an avalanche layer comprising AlGaAsSb; and a transition portion disposed between the absorption layer and the avalanche layer; wherein the transition portion comprises a first grading layer and one or more field control layers disposed between the absorption layer and the avalanche layer, wherein the first grading layer comprises AlxGa1−xAsSb that is graded so that x increases from x=0 to x>0 along a direction from the absorption layer to the avalanche layer, and the one or more field control layers that has a bandgap between the bandgap of the absorption layer and the bandgap of the avalanche layer.
21. The APD structure of claim 20, wherein the avalanche layer comprises AlxGa1−xAsySb1−y where x is between 0.4 and 1, and optionally between 0.85 and 1, and y is chosen to lattice match AlxGa1−xAsySb1−y to InP.
22. The APD structure of claim 20, wherein the first grading layer comprises AlxGa1−xAsySb1−y that is graded so that x increases from 0 to between 0.4 and 1.0 inclusive, and optionally to between 0.85 and 1 inclusive, and y is chosen to lattice match AlxGa1−xAsySb1−y to InP.
23. The APD structure of claim 22, wherein the first grading layer comprises discrete layers of differing bandgaps or a layer having a continuously increasing bandgap.
24. The APD structure of claim 20, wherein the absorption layer has a thickness between 500 and 1500 nm, and optionally between 1000 and 1500 nm.
25. The APD structure of claim 20, wherein the avalanche layer has a thickness between 50 and 2000 nm, and optionally between 50 and 1500 nm.
26. The APD structure claim 20, wherein the one or more field control layers comprise one or more layers of AlGaAsSb.
27. The APD structure of claim 26, wherein the one or more layers of AlGaAsSb is p-doped.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0033] Embodiments of the invention are further described hereinafter with reference to the accompanying drawings, in which:
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DETAILED DESCRIPTION
[0049] Throughout the present specification, the terms avalanche and multiplication are used interchangeably (for example, “avalanche layer” is synonymous with “multiplication layer”).
[0050] A newly identified material, Al.sub.xGa.sub.1−xAs.sub.ySb.sub.1−y, has near ideal avalanche multiplication characteristics yielding very low noise APDs. However, combining a narrow bandgap InGaAs absorption layer with a wide bandgap Al.sub.xGa.sub.1−xAs.sub.ySb.sub.1−y to construct a SAMAPD is challenging, particularly if the chosen Al.sub.xGa.sub.1−xAs.sub.ySb.sub.1−y alloy has a bandgap that is larger than InP or InAlAs. Example compositions of interest are alloys with x=0.4 to 1.0, and optionally 0.85 to 1.0. Y may be chosen to lattice match the alloy to InP. For example, y may be 0.56 when x is 0.85 to ensure lattice matching to InP (e.g. Al.sub.0.85Ga.sub.0.15As.sub.0.56Sb.sub.0.44)
[0051] The relative band offset between various semiconductors lattice matched to InP are shown in
[0052] Under low electric fields (<200 kV/cm), electrons in InGaAs and InAlAs predominantly populate the Γ or L valley, the transport of electrons from InGaAs and InAlAs to AlAsSb is poor. For example, electrons at the minimum of the Γ or L valley in InGaAs require an additional 1.75 and 0.9 eV respectively to enter AlAsSb, as shown in
[0053] While using a typical SAMAPD structure, such as the one shown in
[0054] In accordance with embodiments of the present invention, therefore, the SAMAPD structure is configured such that, under operation, most electrons (or, in some cases, holes) populate the bandstructure zone with minimal band offset. Structures according to certain embodiments of the present invention may be used in either a n-i-p configuration, in which a p-type contact layer is grown on a substrate, or a p-i-n configuration, in which a n-type contact layer is grown on a substrate.
[0055] In one embodiment of the present invention, shown schematically in
[0056] The effect of the first field control layer 118a is that the electric field profile of the SAMAPD structure 110 is altered such that the electrons predominantly populate the X valleys.
[0057] The first field control layer 118a is made of a wider bandgap material relative to the absorption layer 122, and is used to increase the electric field to a suitable value to ensure that electrons are predominantly in X valleys, whilst minimizing tunnelling current. Tunnelling current minimization requires InGaAs to be at an electric field that is below 200 kV/cm but band alignments require the field in InGaAs to be higher, presenting an incompatibility. This incompatibility is addressed by the presence of the first field control layer 118a.
[0058] In certain embodiments, the first field control layer 118a is p-doped. In certain embodiments, the first field control layer 118a is p-doped at a concentration between 1×10.sup.17 cm.sup.−3 and 1×10.sup.18 cm.sup.−3, and optionally between 1×10.sup.17 cm.sup.−3 and 5×10.sup.17 cm.sup.−3. In certain embodiments, the first field control layer 118a has a thickness between 40 nm and 300 nm. In certain embodiments, the first field control 118a layer comprises InAlAs or InP. In certain embodiments, the first field control 118a has a bandgap of 1 eV or greater.
[0059] In certain embodiments, the first grading layer 120a may have a constant bandgap across its thickness. In alternative embodiments, the first grading layer 120a may be graded so as to have an increasing bandgap along the direction from the absorption layer 122 to the avalanche layer 116. In certain embodiments, the grading of the first grading layer 120a may be continuous (e.g. across a thickness of 100 nm) or stepped. For example, a stepped grading may be achieved by a plurality of layers, where each layer has a different bandgap relative to adjacent layers. In certain embodiments, 2 or 3 “step” layers may be provided, where, optionally, each layer may have a thickness of 20 to 50 nm.
[0060] In certain embodiments, the bandgap of the first grading layer 120a increases from that of the absorption layer 122 to that of InAlAs or InP.
[0061] In non-limiting embodiments, the absorption layer 122 comprises intrinsic InGaAs, the first grading layer 120a comprises P.sup.− InGaAlAs, the first field control layer 118a comprises P.sup.+ InAlAs, and the avalanche layer 116 comprises intrinsic AlGaAsSb. The absorption layer 122 may be intrinsic and/or, in some embodiments may have a thickness between 1000 and 1500 nm. The first grading layer 120a may be very lightly p-doped. The first field control layer 118a may be p-doped to allow the electric field in the InAlAs to reach up to 600 kV/cm. The first field control layer 118a may have a thickness between 50 and 100 nm. The avalanche layer 116 may have a thickness of between 50 and 1500 nm. In certain embodiments, the avalanche layer 116 may comprise Al.sub.xGa.sub.1−xAs.sub.ySb.sub.1−y, where x is between 0.4 and 1.0 inclusive and optionally between 0.85 and 1.0 inclusive. In certain embodiments, y may be chosen to lattice match the alloy to InP. In certain embodiments, y may be 0.56 when x is 0.85 to ensure lattice matching to InP (e.g. Al.sub.0.85Ga.sub.0.15As.sub.0.56Sb.sub.0.44).
[0062] In the specific, non-limiting embodiment shown in
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[0064] The intrinsic layer 126 may comprise intrinsic InAlAs and may allow an electric field up to 600 kV/cm. The intrinsic layer 126 may have a thickness between 50 and 200 nm.
[0065] The second grading layer 120b may comprise P.sup.− AlGaAsSb. The second grading layer 120b may be graded in the same manner as described above in relation to the first grading layer 120a. The second grading layer 120b may be graded using AlGaAsSb with a bandgap similar to InAlAs and that increases to the bandgap of Al.sub.xGa.sub.1−xAs.sub.ySb.sub.1−y, where x is between 0.4 and 1.0 inclusive, and optionally to between 0.85 and 1 inclusive. In certain embodiments, y may be chosen to lattice match the alloy to InP. In certain embodiments, y may be 0.56 when x is 0.85 to ensure lattice matching to InP (e.g. Al.sub.0.85Ga.sub.0.15As.sub.0.56Sb.sub.0.44). The second grading layer 120b may have a thickness between 50 and 100 nm. Such a thickness is particularly suited for high speed operation. Other thicknesses may be employed (e.g. thicker for lower speed operation) in alternative embodiments. Indeed, for the avoidance of doubt, all thicknesses referred to in the present specification are non-limiting and alternative embodiments may employ layers of different thicknesses.
[0066] The second field control layer 118b may comprise p-doped Al.sub.xGa.sub.1−xAs.sub.ySb.sub.1−y, where x is between 0.4 and 1.0 inclusive, and optionally to between 0.85 and 1 inclusive. In certain embodiments, y may be chosen to lattice match the alloy to InP. In certain embodiments, y may be 0.56 when x is 0.85 to ensure lattice matching to InP (e.g. Al.sub.0.85Ga.sub.0.15As.sub.0.56Sb.sub.0.44). The second field control layer 118b may have a thickness between 50 and 100 nm.
[0067] The SAMAPD structure 110 may additionally comprise a first contact layer 112 and a second contact layer 124 disposed on opposing sides of the SAMAPD structure 110. The first contact layer 112 may comprise heavily doped N.sup.+ InGaAs. The first contact layer 112 may have a thickness between 10 and 1000 nm. The second contact layer 124 may comprise heavily doped P.sup.++ InGaAs and/or may have a thickness of between 50 and 100 nm.
[0068] The SAMAPD structure 110 may additionally comprise a cladding layer 114 between the first contact layer 112 and the avalanche layer 116. The cladding layer 114 may comprise AlGaAsSb which may be heavily N.sup.+ doped. For example, the cladding layer 114 may comprise Al.sub.xGa.sub.1−xAs.sub.ySb.sub.1−y, where x is between 0.4 and 1.0 inclusive, and optionally to between 0.85 and 1 inclusive. In certain embodiments, y may be chosen to lattice match the alloy to InP. In certain embodiments, y may be 0.56 when x is 0.85 to ensure lattice matching to InP (e.g. Al.sub.0.85Ga.sub.0.15As.sub.0.56Sb.sub.0.44). The cladding layer 114 may have a thickness between 100 and 300 nm.
[0069] Between the second contact layer 124 and the absorption layer 122, there may be provided a barrier layer 128 adjacent the second contact layer 124 and a third grading layer 120c disposed between the barrier layer 128 and the absorption layer 122. The barrier layer 128 may comprise highly doped P+ InAlAs and/or may have a thickness between 100 and 300 nm. The third grading layer 120c may comprise InAlGaAs and may be graded as described above in relation to the first and/or second grading layers 120a, 120b. The third grading layer 120c may comprise very lightly p-doped InAlGaAs with step or continuous bandgap grading between InGaAs and InAlAs. The third grading layer 120c may comprise 2 to 3 layers of 20 to 50 nm thickness (if stepped) or a single layer having a thickness of about 100 nm (if continuously graded).
[0070] If the electric field in the multiplication layer 116 is required to be above 600 kV/cm, then the transition layer 126, the second grading layer 120b and the second field control layer 118b may be required to minimize impact ionization in the first field control layer 118a. In alternative embodiments (e.g. that of
[0071] The electric field in the absorption layer 122 may be kept at or below 150 kV/cm. The first field control layer 118a may allow the electric field to increase to a suitable value (e.g. up to 600 kV/cm) to ensure electrons predominantly populate the X valleys, while minimizing tunnelling current. The second grading layer 120b then allows smooth transport of electrons into the AlGaAsSb. The second field control layer 118b allows electric field to increase to above 600 kV/cm in the avalanche layer 116, while minimizing tunnelling current and impact ionization in the InAlAs field control layer. The value of the electric field required to achieve a certain gain will be determined by the thickness and composition of the Al.sub.xGa.sub.1−xAs.sub.ySb.sub.1−y avalanche layer 116.
[0072] In an alternative embodiment of the invention (shown schematically in
[0073] In certain embodiments, the avalanche layer 216 may comprise Al.sub.xGa.sub.1−xAs.sub.ySb.sub.1−y, where x is between 0.4 and 1.0 inclusive and optionally between 0.85 and 1.0 inclusive. In certain embodiments, y may be chosen to lattice match the alloy to InP. In certain embodiments, y may be 0.56 when x is 0.85 to ensure lattice matching to InP (e.g. Al.sub.0.85Ga.sub.0.15As.sub.0.56Sb.sub.0.44). The avalanche layer 216 may have a thickness between 50 and 1500 nm depending on the noise performance and speed performance required by a given application.
[0074] In certain embodiments, the absorption layer 222 may be intrinsic, but could be lightly doped (n or p type). The absorption layer 222 may have a thickness between 100 and 3000 nm, and optionally between 500 and 1500 nm depending on the quantum efficiency required.
[0075] The first grading layer 220a may have a constant bandgap across its thickness. In alternative embodiments, the first grading layer 220a may be graded so as to have an increasing bandgap along the direction from the absorption layer 222 to the avalanche layer 216. In certain embodiments, the grading of the first grading layer 220a may be continuous (e.g. across a thickness of 100 nm) or stepped. For example, a stepped grading may be achieved by a plurality of layers, where each layer has a different bandgap relative to adjacent layers. In certain embodiments, 2 or 3 “step” layers may be provided, where, optionally, each layer may have a thickness of 20 to 50 nm.
[0076] In the embodiments shown in
[0077] If the electric field in the multiplication layer 216 is required to be above 600 kV/cm, then a transition layer 226, a second grading layer 220b and second field control layer 218b may be required to minimize impact ionization in the first field control layer 218a (e.g. as shown in
[0078] The second grading layer 220b may be provided between the intrinsic layer 226 and the avalanche layer 216. The second grading layer 220b may be provided adjacent to the intrinsic layer 226. The second grading layer 220b may comprise P.sup.− AlGaAsSb. The second grading layer 220b may be graded in the same manner as described above in relation to the first grading layer 220a.
[0079] The second field control layer 218b may be provided between the intrinsic layer 226 and the avalanche layer 216. In the embodiment shown in
[0080] The SAMAPD structure 210 may additionally comprise a first contact layer 212 and a second contact layer 224 disposed on opposing sides of the SAMAPD structure 210. The first contact layer 212 may comprise heavily doped N.sup.+ InGaAs. The first contact layer 212 may have a thickness between 10 and 1000 nm. The second contact layer 224 may comprise heavily doped P.sup.++ InGaAs and/or may have a thickness of between 50 and 100 nm.
[0081] The SAMAPD structure 210 may additionally comprise a cladding layer 214 between the first contact layer 212 and the avalanche layer 216. The cladding layer 214 may comprise Al.sub.xGa.sub.1−xAs.sub.ySb.sub.1−y (where x is between 0.4 and 1, and optionally between 0.85 and 1, and y is chosen to lattice match the alloy to InP) which may be heavily N.sup.+ doped. The cladding layer 214 may have a thickness between 100 and 300 nm.
[0082] Between the second contact layer 224 and the absorption layer 222, there may be provided a blocking layer 228 adjacent the second contact layer 224 and a third grading layer 220c disposed between the blocking layer 228 and the absorption layer 222. The blocking layer 228 may comprise highly doped P.sup.+ AlGaAsSb (i.e. Al.sub.xGaAsSb, where x is between 0 and 1) and/or may have a thickness between 100 and 300 nm. The third grading layer 220c may comprise AlGaAsSb and may be graded as described above in relation to the first and/or second grading layers 220a, 220b. The third grading layer 220c may comprise very lightly p-doped AlGaAsSb with step or continuous bandgap grading between GaAs.sub.0.56Sb.sub.0.44 and Al.sub.xGa.sub.1−xAs.sub.ySb.sub.1−y (where x is between 0.4 and the x value chosen for layer 228, and optionally between 0.85 and 1, and y is chosen to lattice match the alloy to InP). The third grading layer 220c may comprise 2 to 3 layers of 20 to 50 nm thickness (if stepped) or a single layer having a thickness of about 100 nm (if continuously graded).
[0083] With regard to the structure 210 shown in
[0084] The use of GaAsSb as the absorption layer 222 also provides an additional advantage of lower band-to-band tunneling current because of the larger effective mass of 0.055m.sub.o, which is larger than 0.04m.sub.o in InGaAs. Additionally, since no indium is required in this embodiment (in contrast to embodiments including indium), the switch from GaAsSb to AlGaAsSb during growth of the structure 210 is, advantageously, comparably simpler.
[0085] Finally, the AlGaAsSb “step” provided by the transition portion 219 can tolerate higher electric field without significant impact ionization.
[0086] Throughout the description and claims of this specification, the words “comprise” and “contain” and variations of them mean “including but not limited to”, and they are not intended to (and do not) exclude other moieties, additives, components, integers or steps. Throughout the description and claims of this specification, the singular encompasses the plural unless the context otherwise requires. In particular, where the indefinite article is used, the specification is to be understood as contemplating plurality as well as singularity, unless the context requires otherwise.
[0087] Features, integers, characteristics, compounds, chemical moieties or groups described in conjunction with a particular aspect, embodiment or example of the invention are to be understood to be applicable to any other aspect, embodiment or example described herein unless incompatible therewith. All of the features disclosed in this specification (including any accompanying claims, abstract and drawings), and/or all of the steps of any method or process so disclosed, may be combined in any combination, except combinations where at least some of such features and/or steps are mutually exclusive. The invention is not restricted to the details of any foregoing embodiments. The invention extends to any novel one, or any novel combination, of the features disclosed in this specification (including any accompanying claims, abstract and drawings), or to any novel one, or any novel combination, of the steps of any method or process so disclosed.
[0088] The reader's attention is directed to all papers and documents which are filed concurrently with or previous to this specification in connection with this application and which are open to public inspection with this specification, and the contents of all such papers and documents are incorporated herein by reference.